CN106082782B - A kind of preparation method and application for desulfurization flyash energy-conserving and environment-protective construction material adhesive - Google Patents

Abstract

The invention discloses a preparation method and application of an energy-saving and environment-friendly building material adhesive for desulfurization fly ash. salt, succinic anhydride, N-cyclohexyl-p-toluenesulfonamide, N,N-dimethyl-p-nitrosoaniline, 1-amino-5-hydroxy-4-[(1-methylpropyl)amino ]‑8‑nitro‑9,10‑anthraquinone, 1‑anilino‑4‑hydroxyanthraquinone, p-methylthiobenzyl alcohol, gold nanoparticles, 4,4'‑diaminotriphenylmethane, succinic anhydride, 4,4'‑(3,3'‑dichlorobiphenyl‑4,4' dinitrogen)bis(4,5‑dihydro‑5‑oxo‑1‑phenylpyrazole‑3‑carboxylic acid) diethyl benzotriazole-1-tris(trimethylamino)-trifluorophosphate, methyl N-(2-benzimidazolyl)carbamate, α-bromonaphthalene. The invention has the advantages of preventing the saponification of the adhesive, reducing the surface tension of the mixture, and making the adhesion between the mixture stronger; the adhesive has the advantages of stable chemical properties, wide applicability, and high clean ratio of the surface of the molded structure.

Description

A preparation method for an energy-saving and environment-friendly building material binder for desulfurization fly ash and its application

technical field

The invention belongs to the field of new building materials, and in particular relates to a preparation method and application of an adhesive used for desulfurized fly ash energy-saving and environment-friendly building materials.

Background technique

The deficiencies of existing technology:

Scholar Li Junhong used granular binder, desulfurized fly ash and tin slag to burn silicate wall material clinker in a vertical kiln, and mixed an appropriate amount of binder in the raw material to burn out Silicate clinker with good stability, normal setting time and high early strength. But the adhesive is toxic and pollutes the environment.

Scholar Li Wenbin et al. used adhesives and desulfurized fly ash, nickel slag, and coal-research stone ingredients to burn clinker on a shaft kiln, and used fly ash as a mixture to produce ordinary silicate new wall materials, which not only can The reduction of environmental pollution can also reduce the production cost of the new wall material and improve the quality of the new wall material, which has significant social and economic benefits. However, when using adhesives and desulfurized fly ash to burn new wall material clinker, the amount of manganese doped should be controlled at 0.4%-0.6%. Excessive manganese will hinder the firing of clinker, so desulfurized fly ash When the clinker is used as a raw material to burn the clinker, the dosage is small, which has no substantial help for a large amount of desulfurized fly ash that needs to be disposed of urgently.

Scholar Moises Fria et al. mixed 5% and 15% binder and desulfurized fly ash powder into the mortar, and the 7d strength was lower than the benchmark, but the 28d and 90d strengths were close to the benchmark. At the same time, the addition of adhesive and desulfurized fly ash powder reduces the large pores in the new wall material slurry and increases the pores less than 0.01um, making the new wall material slurry in various corrosive media (NaCI solution, artificial seawater and Na2S04 solution) shows poor corrosion resistance, and wall cracking occurs.

The study found that the existing research on the use of binders and desulfurized fly ash as admixtures mainly focused on the case of a small amount of a single fineness, but did not involve large amounts and different finenesses of binders and desulfurization powders Comprehensive research on the mechanical properties and durability of new wall materials, concrete, and coal ash admixtures. At the same time, only simple mechanical grinding has been carried out for low-activity binders and desulfurized fly ash admixtures without other methods. ways to increase its activity.

Scholars used 62.5% granular binder, desulfurized fly ash micropowder, diatomaceous earth, and clay as the basic green body, mixed with waste ceramics, pressurized, dried, and calcined at 1050 ° C to prepare performance indicators. Permeable bricks that meet the requirements of JC/T945-2005 "Permeable Bricks". The study found that the granular binder and desulfurized fly ash have a strong ability to form glass. When the amount of binder and desulfurized fly ash is 30%-40%, it can be prepared together with carbon chromium slag and broken glass. Good decorative glass-ceramic. Granular adhesives and desulfurized fly ash are used in the production of building materials such as seepage bricks and glass-ceramic, although the utilization rate is high, but it is difficult to be popularized in a large area due to cost and process constraints.

Scholar Wang Chong et al. compounded the finely ground blocky binder with desulfurized fly ash and slag to prepare cementitious materials. The strength of cementitious materials generally shows a decreasing trend.

Scholar Amit Rai et al. crushed air-cooled block binder and desulfurized fly ash into concrete aggregates. The binder and desulfurized fly ash aggregates meet the requirements of the IS 3 83:1990 standard, and suggested that it can be It is used in nonstructural concrete, but the effect of this aggregate on concrete properties has not been studied. Moreover, the adhesive is flammable and explosive, and has damage to equipment.

Contents of the invention

In order to solve the deficiencies in the prior art, the present invention provides an adhesive for desulfurized fly ash energy-saving and environmentally friendly building materials, which is composed of the following components in proportions by weight: 221.432 to 446.838 parts of cationic water, fatty alcohol polycyclic 13.569-55.930 parts of sodium oxyethane ether sulfate, 16.813-125.192 parts of succinic anhydride, 12.899-29.545 parts of N-cyclohexyl p-toluenesulfonamide, 15.216-72.49 parts of N,N-dimethyl-p-nitrosoaniline Parts, 1-amino-5-hydroxy-4-[(1-methylpropyl)amino]-8-nitro-9,10-anthraquinone 18.406～79.475 parts, 1-phenylamino-4-hydroxyanthraquinone 15.440-38.578 parts, 12.513-57.446 parts of p-methylthiobenzyl alcohol, 20.144-75.405 parts of gold nanoparticles, 13.708-55.433 parts of 4,4'-diaminotriphenylmethane, 3.239-46.49 parts of succinic anhydride, 4,4' -(3,3'-dichlorobiphenyl-4,4'dinitrogen)bis(4,5-dihydro-5-oxo-1-phenylpyrazole-3-carboxylic acid)diethyl ester 4.151～40.338 Parts, 15.520-55.163 parts of benzotriazole-1-tris(trimethylamino)-trifluorophosphate, 22.446-66.379 parts of methyl N-(2-benzoimidazolyl)carbamate, the mass concentration is 12.244ppm-279.451 45.383 to 99.684 parts of α-bromonaphthalene in ppm.

Further, it is composed of the following components in parts by weight: 222.432-445.838 parts of cationic water, 14.569-54.930 parts of fatty alcohol polyethylene oxide ether sulfate sodium salt, 17.813-124.192 parts of succinic anhydride, N-cyclohexyl 13.899~28.545 parts of p-toluenesulfonamide, 16.216~71.49 parts of N,N-dimethyl-p-nitrosoaniline, 1-amino-5-hydroxy-4-[(1-methylpropyl)amino]- 19.406-78.475 parts of 8-nitro-9,10-anthraquinone, 16.440-37.578 parts of 1-anilino-4-hydroxyanthraquinone, 13.513-56.446 parts of p-methylthiobenzyl alcohol, 21.144-74.405 parts of gold nanoparticles, 4,4'-diaminotriphenylmethane 14.708~54.433 parts, succinic anhydride 4.239~45.49 parts, 4,4'-(3,3'-dichlorobiphenyl-4,4'double nitrogen)bis(4,5 -Dihydro-5-oxo-1-phenylpyrazole-3-carboxylic acid) diethyl ester 5.151~39.338 parts, benzotriazole-1-tris(trimethylamino)-trifluorophosphate 16.520~54.163 parts, 23.446-65.379 parts of methyl N-(2-benzimidazolyl)carbamate, 46.383-98.684 parts of α-bromonaphthalene with a mass concentration of 13.244ppm-278.451ppm.

Further, the present invention also discloses a method for preparing an adhesive for desulfurized fly ash energy-saving and environment-friendly building materials, which includes the following steps in parts by weight:

Step 1: In the reactor, add cationic water and sodium salt of fatty alcohol polyethylene oxide ether sulfate, start the mixer in the reactor, set the speed at 14.228rpm-60.306rpm, start the heater in the reactor, Raise the temperature to 29.959℃～30.994℃, add succinic anhydride, N-cyclohexyl p-toluenesulfonamide, and stir evenly, carry out esterification reaction for 6.21～17.349 hours; then add N,N-dimethyl - p-nitrosoaniline, 1-amino-5-hydroxyl-4-[(1-methylpropyl)amino]-8-nitro-9,10-anthraquinone, adjust the pH value of the solution in the reaction kettle The range is between 4.8900 and 8.9457;

Step 2: Separately take 1-anilino-4-hydroxyanthraquinone, p-methylthiobenzyl alcohol, and gold nanoparticles, pulverize and grind them, and pass through a 401.38-501.96 mesh screen, mix them evenly, and use a grazing incidence small-angle X Radiation scattering irradiation, the energy of which is 3.416MeV-31.229MeV, the dose is 51.470kGy-91.828kGy, and the irradiation time is 15.200-40.867 minutes, to obtain a mixture of the three with changed properties;

Step 3: Add the mixture obtained in Step 2 to 4,4'-diaminotriphenylmethane with a mass concentration of 16.760ppm to 246.936ppm, and flow it into the reactor at a flow rate of 151.822mL/min to 879.690mL/min; start the reactor mixer, set the speed at 20.800rpm~60.263rpm; add succinic anhydride after stirring evenly, raise the temperature to 50.180°C~87.288°C, and feed helium with a ventilation rate of 5.260m3/min~46.519m3 /min, heat preservation and standing for 40.904~70.214 minutes; start the reactor mixer again, the speed is 15.18rpm~60.386rpm, add 4,4'-(3,3'-dichlorobiphenyl-4,4'double nitrogen)bis (4,5-dihydro-5-oxo-1-phenylpyrazole-3-carboxylic acid) diethyl ester, so that the hydrophilic-lipophilic balance value of the reaction solution is 5.46483～10.90881, and the heat preservation is 39.20～79.680 minute;

The 4th step: start the stirrer in the reactor, set the rotating speed as 12.444rpm～79.501rpm, add benzotriazole-1-tris(trimethylamino)-trifluorophosphate, N-( 2-Benzimidazolyl) methyl carbamate, then add α-bromonaphthalene with a mass concentration of 12.488ppm to 279.824ppm, set the temperature in the reactor to 90.670°C to 146.540°C, and the pressure to 0.12.442MPa to 0.13 .703MPa, the reaction time is 5.89-30.375 hours; after that, the pressure is lowered to 0MPa, the temperature is lowered to 54.12.129°C-59.12.241°C, and the material is discharged to obtain an energy-saving and environmentally friendly building material adhesive for desulfurization fly ash.

Further, the particle size of the gold nanoparticles is 20.838 μm˜30.930 μm.

Further, the present invention also discloses the application of an adhesive for desulfurized fly ash energy-saving and environment-friendly building materials; the adhesive is mainly used for bonding building materials containing desulfurized fly ash, Adhesive treatment of mixtures.

Further, the various mixtures are one or more of desulfurized fly ash, cement, lime, silica sand, gypsum, sand, stone, coal gangue, construction waste, river, lake and sea mud, metallurgical and chemical waste residue, and clay kind.

Further, the adhesive for desulfurized fly ash energy-saving and environmentally friendly building materials is used in conjunction with a diluent, and the mass ratio of the adhesive for desulfurized fly ash energy-saving and environmentally friendly building materials to the diluent is 1: 441.192-881.545; the diluent is one of polyurethane, amidoimide polyurethane, and modified chlorinated polyether.

A preparation method and application of an adhesive for desulfurization fly ash energy-saving and environment-friendly building materials disclosed in the patent of the present invention has the advantages of:

(1) When adopting a kind of binder for desulfurized coal ash energy-saving and environment-friendly building materials according to the present invention, firstly the binder saponifies the raw material so that moisture is separated from the raw material; secondly, desulfurized fly ash and Other ingredients disperse, absorb, mix;

(2) A kind of binder used for desulfurization fly ash energy-saving and environment-friendly building materials of the present invention can greatly reduce the surface tension of the binder on the mixed raw material, thereby producing multiple functions such as lubrication, penetration, emulsification, dispersion, etc., thereby Make the mixed material adhere firmly;

(3) The adhesive used for desulfurization fly ash energy-saving and environment-friendly building materials according to the present invention has stable chemical properties, wide application, wide pH range, high adhesion rate, good adhesion, and clean surface of building molding materials Advantages of higher ratio;

(4) A kind of adhesive used for desulfurization fly ash energy-saving and environment-friendly building materials described in the present invention will not produce precipitation after use and will not pollute the surrounding environment; apply a kind of desulfurized powder used in the present invention Coal ash is an energy-saving and environmentally friendly building material binder, with simple equipment requirements and low operating costs.

Description of drawings

Fig. 1 is a graph showing the variation of the adhesion firmness rate of the embodiment and the control example under different reaction time conditions.

Fig. 2 is a graph showing the variation of the adhesive stability rate of the embodiment and the comparative example under different reaction time conditions.

Fig. 3 is a graph showing the variation of the natural degradation rate of the adhesive in the examples and the control example under different reaction time conditions.

detailed description

The following examples further illustrate the content of the present invention, but should not be construed as limiting the present invention. Without departing from the spirit and essence of the present invention, the modifications and substitutions made to the methods, steps or conditions of the present invention all belong to the scope of the present invention. Unless otherwise specified, the technical means used in the embodiments are conventional means well known to those skilled in the art.

Example 1

According to the following steps, a kind of binder for desulfurization fly ash energy-saving and environment-friendly building materials of the present invention is prepared, and in parts by weight:

Step 1: In the reaction kettle, add 221.432 parts of cationic water and 13..569 parts of fatty alcohol polyethylene oxide ether sulfate sodium salt, start the mixer in the reaction kettle, set the speed at 14.228rpm, start the reaction kettle Heater to raise the temperature to 29.959°C, add 16.813 parts of succinic anhydride, 12.899 parts of N-cyclohexyl p-toluenesulfonamide, and stir evenly, carry out esterification reaction for 6.21 hours; then add N,N- 15.216 parts of dimethyl-p-nitrosoaniline, 18.406 parts of 1-amino-5-hydroxyl-4-[(1-methylpropyl)amino]-8-nitro-9,10-anthraquinone, adjusted The pH value of the solution in the reactor reaches 4.8900;

Step 2: Take another 15.440 parts of 1-anilino-4-hydroxyanthraquinone, 12.513 parts of p-methylthiobenzyl alcohol, and 20.144 parts of gold nanoparticles, grind them, and pass through a 401.38 mesh screen. Incident small-angle X-ray scattering irradiation, the energy is 3.416MeV, the dose is 51.470kGy, and the irradiation time is 15.200 minutes, a mixture of the three with changed properties is obtained;

Step 3: Add the mixture obtained in Step 2 to 13.708 parts of 4,4'-diaminotriphenylmethane with a mass concentration of 16.760ppm, and flow it into the reactor at a flow rate of 151.822mL/min; start Reactor mixer, set the speed at 20.800rpm; after stirring evenly, add 3.239 parts of succinic anhydride, raise the temperature to 50.180°C, inject helium gas with a ventilation rate of 5.260m3/min, and keep it for 40.904 minutes; start the reactor mixer again, Rotate at 15.18rpm, add 4,4'-(3,3'-dichlorobiphenyl-4,4'dinitrogen)bis(4,5-dihydro-5-oxo-1-phenylpyrazole- 4.151 parts of 3-formic acid) diethyl esters, the hydrophilic-lipophilic equilibrium value of its reaction solution was 5.46483, and the insulation was left standstill for 39.20 minutes;

The 4th step: start the stirrer in the reactor, set the rotating speed as 12.444rpm, add 15.520 parts of benzotriazole-1-tris(trimethylamino)-trifluorophosphate in the reactor while stirring, N-(2 -22.446 parts of methyl benzimidazolyl) carbamate, then add 45.383 parts of α-bromonaphthalene with a mass concentration of 12.488ppm, set the temperature in the reactor to 90.670°C, the pressure to 0.12442MPa, and the reaction time to be 5.89 hours After that, the pressure is lowered to 0MPa, the temperature is lowered to 54.12129° C., and the material is discharged to obtain an energy-saving and environmentally friendly building material binder for desulfurization fly ash.

Wherein the particle size of the gold nanoparticles is 20.838 μm.

In the application, the adhesive for desulfurized fly ash energy-saving and environmentally friendly building materials needs to be used in conjunction with a diluent, and the mass ratio of the adhesive for desulfurized fly ash energy-saving and environmentally friendly building materials to the diluent is 1:441.192; the diluent is: polyurethane.

Example 2

According to the following steps, a kind of binder for desulfurization fly ash energy-saving and environment-friendly building materials of the present invention is prepared, and in parts by weight:

Step 1: In the reactor, add 446.838 parts of cationic water and 55.930 parts of fatty alcohol polyethylene oxide ether sulfate sodium salt, start the mixer in the reactor, set the speed at 60.306rpm, and start the heater in the reactor , to raise the temperature to 30.994°C, add 125.192 parts of succinic anhydride, 29.545 parts of N-cyclohexyl-p-toluenesulfonamide, and stir evenly, carry out esterification reaction for 17.349 hours; then add N,N-dimethyl -72.49 parts of p-nitrosoaniline, 79.475 parts of 1-amino-5-hydroxyl-4-[(1-methylpropyl)amino]-8-nitro-9,10-anthraquinone, adjusted in the reaction kettle pH of the solution to 8.9457;

Step 2: Take another 38.578 parts of 1-anilino-4-hydroxyanthraquinone, 57.446 parts of p-methylthiobenzyl alcohol, and 75.405 parts of gold nanoparticles, pulverize and grind them, and pass through a 501.96 mesh screen. Incident small-angle X-ray scattering radiation, the energy is 31.229MeV, the dose is 91.828kGy, and the irradiation time is 40.867 minutes, a mixture of the three with changed properties is obtained;

Step 3: Add the mixture obtained in Step 2 to 55.433 parts of 4,4'-diaminotriphenylmethane with a mass concentration of 246.936ppm, and flow it into the reactor at a flow rate of 879.690mL/min; start Reactor mixer, set the speed at 60.263rpm; after stirring evenly, add 46.49 parts of succinic anhydride, raise the temperature to 87.288°C, inject helium with a ventilation rate of 46.519m3/min, and keep it for 70.214 minutes; start the reactor mixer again, Rotate at 60.386rpm, add 4,4'-(3,3'-dichlorobiphenyl-4,4'dinitrogen)bis(4,5-dihydro-5-oxo-1-phenylpyrazole- 40.338 parts of 3-formic acid) diethyl esters, the hydrophilic-lipophilic equilibrium value of its reaction solution was 10.90881, and the insulation was left standstill for 79.680 minutes;

The 4th step: start the stirrer in the reactor, set the rotating speed as 79.501rpm, add 55.163 parts of benzotriazole-1-tris(trimethylamino)-trifluorophosphate in the reactor while stirring, N-(2 -66.379 parts of methyl carbamate, then add 99.684 parts of α-bromonaphthalene with a mass concentration of 279.824ppm, set the temperature in the reactor to 146.540°C, the pressure to 0.13703MPa, and the reaction time to be 30.375 hours After that, the pressure is lowered to 0MPa, the temperature is lowered to 59.12241° C., and the material is discharged to obtain an energy-saving and environmentally friendly building material binder for desulfurization fly ash.

Wherein the particle diameter of the gold nanoparticles is 30.930 μm.

In the application, the adhesive for desulfurized fly ash energy-saving and environmentally friendly building materials needs to be used in conjunction with a diluent, and the mass ratio of the adhesive for desulfurized fly ash energy-saving and environmentally friendly building materials to the diluent is 1:881.545; the diluent is: modified chlorinated polyether.

Example 3

According to the following steps, a kind of binder for desulfurization fly ash energy-saving and environment-friendly building materials of the present invention is prepared, and in parts by weight:

Step 1: In the reactor, add 222.432 parts of cationic water and 14.838 parts of fatty alcohol polyethylene oxide ether sulfate sodium salt, start the mixer in the reactor, set the speed at 15.569rpm, and start the heater in the reactor , to raise the temperature to 30.930°C, add 17.813 parts of succinic anhydride, 13.192 parts of N-cyclohexyl p-toluenesulfonamide, and stir evenly, carry out esterification reaction for 7.899 hours; then add N,N-dimethyl -16.545 parts of p-nitrosoaniline, 19.216 parts of 1-amino-5-hydroxyl-4-[(1-methylpropyl)amino]-8-nitro-9,10-anthraquinone, adjusted in the reaction kettle The pH of the solution ranges to 5.449;

Step 2: Take another 16.406 parts of 1-anilino-4-hydroxyanthraquinone, 13.475 parts of p-methylthiobenzyl alcohol, and 21.440 parts of gold nanoparticles, grind them, and pass through a 402.578 mesh screen. Incident small-angle X-ray scattering irradiation, the energy is 4.513MeV, the dose is 52.446kGy, and the irradiation time is 16.144 minutes, a mixture of the three with changed properties is obtained;

Step 3: Add the mixture obtained in Step 2 to 14.708 parts of 4,4'-diaminotriphenylmethane with a mass concentration of 17.405ppm, and flow it into the reactor at a flow rate of 152.433mL/min; start Reactor mixer, the set speed is 21.239rpm; after stirring evenly, add 4.49 parts of succinic anhydride, heat up to 51.151°C, inject helium with a ventilation rate of 6.338m3/min, and keep it for 41.520 minutes; start the reactor mixer again, Rotate at 16.163rpm, add 4,4'-(3,3'-dichlorobiphenyl-4,4'dinitrogen)bis(4,5-dihydro-5-oxo-1-phenylpyrazole- 5.446 parts of 3-formic acid) diethyl esters, the hydrophilic-lipophilic equilibrium value of its reaction solution was 6.46379, and the insulation was left standstill for 40.244 minutes;

The 4th step: start the stirrer in the reactor, set the rotating speed as 13.451rpm, add 16.383 parts of benzotriazole-1-tris(trimethylamino)-trifluorophosphate in the reactor while stirring, N-(2 -23.684 parts of methyl benzimidazolyl) carbamate, then add 46.838 parts of α-bromonaphthalene with a mass concentration of 13.432ppm, set the temperature in the reactor to 91.569°C, the pressure to 0.13930MPa, and the reaction time to be 6.813 hours Afterwards, the pressure is lowered to 0MPa, the temperature is lowered to 55.12192° C., and the material is discharged to obtain an energy-saving and environmentally friendly building material binder for desulfurization fly ash.

Wherein the particle diameter of the gold nanoparticles is 21.899 μm.

In the application, the adhesive for desulfurized fly ash energy-saving and environmentally friendly building materials needs to be used in conjunction with a diluent, and the mass ratio of the adhesive for desulfurized fly ash energy-saving and environmentally friendly building materials to the diluent is 1:442.545; the diluent is: amidoimide polyurethane.

Comparative example

As a control example, a commercially available adhesive of a certain brand was used to carry out application experiments in the adhesive treatment of various mixtures for building materials containing desulfurized fly ash.

Example 4

The adhesive obtained in Examples 1 to 3 and the comparative example are used for building materials containing desulfurized fly ash to carry out application tests in various mixture adhesive treatments, wherein the mass ratio of adhesive to diluent is 1: 442.545, the diluent is polyurethane, and the treatment time is 20 to 120 hours. After the treatment, parameters such as the porosity of the molding material, the rate of adhesion firmness, the rate of thermal insulation improvement of the adhesive material, and the surface cleanliness ratio of the molding material are analyzed. The data are shown in Table 1.

As can be seen from Table 1, a kind of binder for desulfurization fly ash energy-saving and environment-friendly building materials according to the present invention has the same porosity of the molding material, the rate of bonding firmness, the rate of thermal insulation improvement of the adhesive material, and the surface cleanness ratio of the molding material. Higher than products produced by prior art.

In addition, as shown in Figures 1 to 3, it is a kind of adhesive used for desulfurization fly ash energy-saving and environmental protection building materials of the present invention and the comparative example, and the test data statistics of the change with the use time. It can be seen from the figure that the technical indicators of Examples 1-3 are much better than the products produced by the prior art in terms of adhesion firmness rate, adhesive stability rate, adhesive natural degradation rate and other technical indicators.

Claims (7)

1. one kind is used for desulfurization flyash energy-conserving and environment-protective construction material adhesive, it is characterised in that by following components by weight Number proportioning composition：221.432~446.838 parts of cationic water, poly alkyl alcohol ethylene oxide ether sulfates sodium salt 13.569~ 55.930 parts, 16.813~125.192 parts of succinic anhydride, 12.899~29.545 parts of N- cyclohexyls para toluene sulfonamide, N, N- Dimethyl -15.216~72.49 parts of p- nitrosoaniline, 1- amino -5- hydroxyls -4- [(1- methyl-propyls) amino] -8- nitre 18.406~79.475 parts of base -9,10- anthraquinone, 15.440~38.578 parts of 1- phenylamino -4- hydroxy-anthraquiones, to methylthio phenyl first 12.513~57.446 parts of alcohol, 20.144~75.405 parts of gold nano particulate, 4,4'- diaminourea triphenylmenthanes 13.708~ 55.433 parts, 3.239~46.49 parts of succinic anhydride, 4,4'- (the dual nitrogen of 3,3'- dichlorobenzenes -4,4') double (4,5- dihydro -5- Oxo -1- Phenylpyrazole -3- formic acid) 4.151~40.338 parts of diethylester, the fluorophosphoric acid of BTA -1- three (dimethylamino)-three 15.520~55.163 parts of ester, 22.446~66.379 parts of N- (2- benzimidazolyls) methyl carbamate, mass concentration are 45.383~99.684 parts of 12.244ppm~279.451ppm alpha-bromonaphthalene.

2. one kind according to claim 1 is used for desulfurization flyash energy-conserving and environment-protective construction material adhesive, it is characterised in that Matched and formed in parts by weight by following components：222.432~445.838 parts of cationic water, poly alkyl alcohol oxirane ether sulphur 14.569~54.930 parts of acid sodium-salt, 17.813~124.192 parts of succinic anhydride, N- cyclohexyls para toluene sulfonamide 13.899~ 28.545 parts, N, N- dimethyl -16.216~71.49 parts of p- nitrosoaniline, 1- amino -5- hydroxyls -4- [(1- methyl-props Base) amino] 19.406~78.475 parts of -8- nitros -9,10- anthraquinone, 1- phenylamino -4- hydroxy-anthraquiones 16.440~37.578 Part, to 13.513~56.446 parts of methylthio phenyl methanol, 21.144~74.405 parts of gold nano particulate, 4,4'- diaminourea triphens 14.708~54.433 parts of methane, 4.239~45.49 parts of succinic anhydride, 4,4'- (the dual nitrogen of 3,3'- dichlorobenzenes -4,4') are double (4,5- dihydro -5- oxo -1- Phenylpyrazole -3- formic acid) 5.151~39.338 parts of diethylester, (the front three ammonia of BTA -1- three Base) 16.520~54.163 parts of-trifluoro phosphate, 23.446~65.379 parts of N- (2- benzimidazolyls) methyl carbamate, Mass concentration is 13.244ppm~278.451ppm 46.383~98.684 parts of alpha-bromonaphthalene.

A kind of 3. preparation side for desulfurization flyash energy-conserving and environment-protective construction material adhesive according to claim 1 or 2 Method, it is characterised in that by weight, comprise the following steps：

1st step：In a kettle, cationic water and poly alkyl alcohol ethylene oxide ether sulfates sodium salt are added, is started in reactor Mixer, setting speed are 14.228rpm~60.306rpm, start the heater in reactor, temperature is risen to 29.959 DEG C ~30.994 DEG C, succinic anhydride, N- cyclohexyl para toluene sulfonamides are added, and is stirred, progress esterification 6.21~ 17.349 hours；Add N, N- dimethyl-p- nitrosoaniline, 1- amino -5- hydroxyls -4- [(1- first in a kettle afterwards Base propyl group) amino] -8- nitro -9,10- anthraquinones, the pH value range of solution in reactor is adjusted between 4.8900~8.9457；

2nd step：It is another to take 1- phenylamino -4- hydroxy-anthraquiones, to methylthio phenyl methanol, gold nano particulate, attrition grinding is carried out, and lead to 401.38~501.96 eye mesh screens are crossed, are irradiated after being well mixed using glancing incidence small angle x-ray scattering (SAXS), its energy is 3.416MeV~31.229MeV, dosage are 51.470kGy~91.828kGy, irradiation time is 15.200~40.867 minutes, Obtain three's mixture of character change；

3rd step：The mixture that 2nd step obtains is added into the 4,4'- diaminourea that mass concentration is 16.760ppm~246.936ppm In triphenylmenthane, cocurrent is added in reactor, and flow acceleration is 151.822mL/min~879.690mL/min；Start reactor Mixer, setting speed are 20.800rpm~60.263rpm；Succinic anhydride is added after stirring, is warming up to 50.180 DEG C ~87.288 DEG C, it is 5.260m3/min~46.519m3/min to be passed through helium throughput, and insulation stands 40.904~70.214 points Clock；Reactor mixer is again started up, rotating speed is 15.18rpm~60.386rpm, 4,4'- of addition (3,3'- dichlorobenzene -4, The dual nitrogen of 4') double (4,5- dihydro -5- oxo -1- Phenylpyrazole -3- formic acid) diethylesters, make the hydrophile-lipophile balance of its reaction solution It is worth for 5.46483~10.90881, insulation stands 39.20~79.680 minutes；

4th step：Start the mixer in reactor, setting speed is 12.444rpm~79.501rpm, while stirring to reaction (the dimethylamino)-trifluoro phosphates of addition BTA -1- three in kettle, N- (2- benzimidazolyls) methyl carbamate, afterwards Add the alpha-bromonaphthalene that mass concentration is 12.488ppm~279.824ppm, set temperature in reactor as 90.670 DEG C~ 146.540 DEG C, pressure is 0.12442MPa~0.13703MPa, and the reaction time is 5.89~30.375 hours；It is depressurized to afterwards 0MPa, 54.12129 DEG C~59.12241 DEG C dischargings are cooled to, that is, obtain one kind and be used for desulfurization flyash energy-conserving and environment-protective Building wood Expect adhesive.

4. a kind of preparation method for desulfurization flyash energy-conserving and environment-protective construction material adhesive according to claim 3, Characterized in that, the particle diameter of the gold nano particulate is 20.838 μm~30.930 μm.

5. a kind of application for desulfurization flyash energy-conserving and environment-protective construction material adhesive according to claim 1, it is led It is applied to：For the adhesion process of a variety of mixtures.

6. a kind of application for desulfurization flyash energy-conserving and environment-protective construction material adhesive according to claim 5, it is special Sign is that a variety of mixtures are desulfurization flyash, cement, lime, gypsum, sand, stone, gangue, architecture sediment, rivers lake It is a variety of in ooze, metallurgy and chemical sludge, clay.

7. a kind of application for desulfurization flyash energy-conserving and environment-protective construction material adhesive according to claim 5, it is special Sign is that described one kind is used cooperatively for desulfurization flyash energy-conserving and environment-protective construction material adhesive with diluent, and one kind is used for Desulfurization flyash energy-conserving and environment-protective construction material adhesive is 1 with diluent fit quality ratio:441.192~881.545；It is described dilute Releasing agent is：One kind in polychlorostyrene urethane, amide imide polyurethane, modified chlorinated polyethers.