CN106082205A - A kind of method of purifying gold hard rock - Google Patents
A kind of method of purifying gold hard rock Download PDFInfo
- Publication number
- CN106082205A CN106082205A CN201610414071.5A CN201610414071A CN106082205A CN 106082205 A CN106082205 A CN 106082205A CN 201610414071 A CN201610414071 A CN 201610414071A CN 106082205 A CN106082205 A CN 106082205A
- Authority
- CN
- China
- Prior art keywords
- diamond
- magnesium carbonate
- hard rock
- gold hard
- mixture material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims abstract description 22
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title claims abstract description 14
- 239000010931 gold Substances 0.000 title claims abstract description 14
- 229910052737 gold Inorganic materials 0.000 title claims abstract description 14
- 239000011435 rock Substances 0.000 title claims abstract description 14
- 239000010432 diamond Substances 0.000 claims abstract description 46
- 229910003460 diamond Inorganic materials 0.000 claims abstract description 46
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000010439 graphite Substances 0.000 claims abstract description 30
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 30
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims abstract description 21
- 239000001095 magnesium carbonate Substances 0.000 claims abstract description 21
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims abstract description 21
- 239000000463 material Substances 0.000 claims abstract description 21
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 238000005245 sintering Methods 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000002351 wastewater Substances 0.000 abstract description 4
- 238000012545 processing Methods 0.000 abstract description 3
- 238000000746 purification Methods 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 229910003481 amorphous carbon Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000011859 microparticle Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
Landscapes
- Carbon And Carbon Compounds (AREA)
Abstract
A kind of method that the invention discloses purifying gold hard rock, is placed in diamond and graphite mixture material in industrial microwave oven, is simultaneously introduced magnesium carbonate and stirs, sintering temperature is 300～600 DEG C, roasting time is 60min～80min, is subsequently cooled to room temperature, sends into shaking table and isolates diamond.The present invention reduces a large amount of production cost to put into, simultaneously effective improve operative's environment, reduce labor intensity；Optimize environment, eliminate a large amount of tail gas, waste water processing cost.
Description
Technical field
The present invention relates to diamond production technical field, a kind of method particularly belonging to purifying gold hard rock.
Background technology
In China superhard material Industry, the artificially synthesizing diamond now powder catalyst synthesis stem stem techniques that use more, High Temperature High Pressure,
In synthesis stem stem, part graphite is changed into diamond under powder catalyst effect.In diamond post processing purification process, powder
Catalyst diamond synthesizing pellet is after electrochemical process extracts catalyst metal, and gained material is the mixture of diamond and graphite,
Then enter purification of diamond committed step diamond, the separation of graphite.The purification of known synthetic superhard material
In Technology, ore-dressing technique is used to complete the thick purification of diamond according to diamond and the density variation of graphite, but due to water
The factors such as resistance, hydrone surface tension cause diamond particles and graphite microparticles differential settling velocity in water inconspicuous, no
Can fully remove graphite microparticles.According to the chemical characteristic of diamond Yu graphite, traditional handicraft uses the oxidisability of high-temperature high concentration
Acid technique (nitric-sulfuric acid technique, perchloric acid technique etc.) essence removes graphite, reaches the purpose that remove impurity purifies.This method exists
Major defect is: a large amount of uses of high concentration strong acid, and remove impurity creates a large amount of fumes of sulphuric acid and NOx gas while purifying, with
Time produce acid waste water, deteriorate production environment, tail gas, cost for wastewater treatment are high.
Summary of the invention
A kind of method that it is an object of the invention to purifying gold hard rock, decreases a large amount of production cost and puts into, simultaneously effective
Improve operative's environment, reduce labor intensity；Optimize environment, eliminate a large amount of tail gas, waste water processing cost.
Technical scheme is as follows:
A kind of method of purifying gold hard rock, is placed in diamond and graphite mixture material in industrial microwave oven, is simultaneously introduced
Magnesium carbonate stirs, and sintering temperature is 300～600 DEG C, and roasting time is 60min～80min, is subsequently cooled to room temperature, send
Enter shaking table and isolate diamond.
The consumption of described magnesium carbonate is the 8-12% of diamond and graphite mixture material quality.
The consumption of described magnesium carbonate is the 8% of diamond and graphite mixture material quality.
The consumption of described magnesium carbonate is the 12% of diamond and graphite mixture material quality.
The consumption of described magnesium carbonate is the 10% of diamond and graphite mixture material quality.
Compared with the prior art, beneficial effects of the present invention is as follows:
Graphite is removed in the purification that the present invention completes diamond by Physical, it is to avoid high concentration oxidizing acid and supporting height
The use of temperature response system, decreases a large amount of production cost and puts into, simultaneously effective improve operative's environment, reduce work strong
Degree；Optimize environment, eliminate a large amount of tail gas, waste water processing cost.
Detailed description of the invention
The method of 1 one kinds of purifying gold hard rocks of embodiment, is placed in diamond and graphite mixture material in industrial microwave oven,
Being simultaneously introduced magnesium carbonate to stir, sintering temperature is 300～600 DEG C, and roasting time is 60min～80min, is subsequently cooled to
Room temperature, sends into shaking table and isolates diamond, and the consumption of described magnesium carbonate is the 8% of diamond and graphite mixture material quality.
The purity of the diamond recording the present embodiment is 99.95%.
The method of 2 one kinds of purifying gold hard rocks of embodiment, is placed in diamond and graphite mixture material in industrial microwave oven,
Being simultaneously introduced magnesium carbonate to stir, sintering temperature is 300～600 DEG C, and roasting time is 60min～80min, is subsequently cooled to
Room temperature, sends into shaking table and isolates diamond, and the consumption of described magnesium carbonate is the 10% of diamond and graphite mixture material quality.
The purity of the diamond recording the present embodiment is 99.97%.
The method of 3 one kinds of purifying gold hard rocks of embodiment, is placed in diamond and graphite mixture material in industrial microwave oven,
Being simultaneously introduced magnesium carbonate to stir, sintering temperature is 300～600 DEG C, and roasting time is 60min～80min, is subsequently cooled to
Room temperature, sends into shaking table and isolates diamond, and the consumption of described magnesium carbonate is the 12% of diamond and graphite mixture material quality,
The purity of the diamond recording the present embodiment is 99.94%.
Its principle of the present invention is that after magnesium carbonate mixes with graphite mixture material with diamond, magnesium carbonate adheres to, penetrates into stone
Inside ink granule, during high-temperature process, magnesium carbonate decomposes to give off carbon dioxide, and the carbon dioxide drastically produced makes inclusion enclave graphite
Grain deform upon, become loose porous, use microwave heating, according to microwave have selectivity heating feature, utilize graphite and
Amorphous carbon more absorbs the feature of microwave under microwave field than diamond, rapidly heating diamond surface and free remaining stone
Ink and amorphous carbon, form the more conveying that " focus " becomes, and diamond be indifferent owing to absorbing microwave, and temperature is the highest, shape
Become " cold " center " thus to avoid diamond oxidized, reduce its bulk density, increase its molecular tension in water, who
Water buoyancy, and diamond particles quality is tight, physics, chemical change does not occurs, now carries out cleaning table separation, can be easily
Realize the magnesium oxide after bulk rear graphite granule and magnesium carbonate decompose and separate with diamond with current, reach accurate and purify Buddha's warrior attendant
The purpose of stone.
The ultimate principle of the present invention, principal character and advantages of the present invention have more than been shown and described.The technology of the industry
Personnel, it should be appreciated that the present invention is not restricted to the described embodiments, simply illustrating this described in above-described embodiment and description
The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, and these become
Change and improvement both falls within scope of the claimed invention.Claimed scope by appending claims and
Equivalent defines.
Claims (5)
1. the method for a purifying gold hard rock, it is characterised in that diamond and graphite mixture material are placed in industrial microwave oven,
Being simultaneously introduced magnesium carbonate to stir, sintering temperature is 300～600 DEG C, and roasting time is 60min～80min, is subsequently cooled to
Room temperature, sends into shaking table and isolates diamond.
The method of purifying gold hard rock the most according to claim 1, it is characterised in that the consumption of described magnesium carbonate is diamond
8-12% with graphite mixture material quality.
The method of purifying gold hard rock the most according to claim 2, it is characterised in that the consumption of described magnesium carbonate is diamond
With graphite mixture material quality 8%.
The method of purifying gold hard rock the most according to claim 2, it is characterised in that the consumption of described magnesium carbonate is diamond
With graphite mixture material quality 12%.
The method of purifying gold hard rock the most according to claim 2, it is characterised in that the consumption of described magnesium carbonate is diamond
With graphite mixture material quality 10%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610414071.5A CN106082205A (en) | 2016-06-13 | 2016-06-13 | A kind of method of purifying gold hard rock |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610414071.5A CN106082205A (en) | 2016-06-13 | 2016-06-13 | A kind of method of purifying gold hard rock |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106082205A true CN106082205A (en) | 2016-11-09 |
Family
ID=57845352
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610414071.5A Pending CN106082205A (en) | 2016-06-13 | 2016-06-13 | A kind of method of purifying gold hard rock |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106082205A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108190883A (en) * | 2018-03-09 | 2018-06-22 | 郑州航空工业管理学院 | A kind of method of purification of diamond |
| CN111154552A (en) * | 2018-11-08 | 2020-05-15 | 中国科学院宁波材料技术与工程研究所 | Diamond surface cleaning solution and application thereof |
-
2016
- 2016-06-13 CN CN201610414071.5A patent/CN106082205A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108190883A (en) * | 2018-03-09 | 2018-06-22 | 郑州航空工业管理学院 | A kind of method of purification of diamond |
| CN111154552A (en) * | 2018-11-08 | 2020-05-15 | 中国科学院宁波材料技术与工程研究所 | Diamond surface cleaning solution and application thereof |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161109 |