CN106079701A - A kind of mosquito-proof composite wallpaper of mildew-resistant - Google Patents
A kind of mosquito-proof composite wallpaper of mildew-resistant Download PDFInfo
- Publication number
- CN106079701A CN106079701A CN201610443400.9A CN201610443400A CN106079701A CN 106079701 A CN106079701 A CN 106079701A CN 201610443400 A CN201610443400 A CN 201610443400A CN 106079701 A CN106079701 A CN 106079701A
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- Prior art keywords
- mosquito
- layer
- resistant
- proof
- mildew
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/06—Vegetal fibres
- B32B2262/062—Cellulose fibres, e.g. cotton
- B32B2262/065—Lignocellulosic fibres, e.g. jute, sisal, hemp, flax, bamboo
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/306—Resistant to heat
- B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/71—Resistive to light or to UV
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
- B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/716—Degradable
- B32B2307/7163—Biodegradable
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
- B32B2307/7242—Non-permeable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/726—Permeability to liquids, absorption
- B32B2307/7265—Non-permeable
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2607/00—Walls, panels
- B32B2607/02—Wall papers, wall coverings
Landscapes
- Engineering & Computer Science (AREA)
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Abstract
The invention discloses a kind of mosquito-proof composite wallpaper of mildew-resistant, including flame-resistant polyacrylonitrile fiber layer, the back side of described flame-resistant polyacrylonitrile fiber layer is provided with waterproof mildew-resistant layer, described flame-resistant polyacrylonitrile fiber layer be arranged above with antibacterial mosquito-proof layer, described antibacterial mosquito-proof layer is arranged above with mosquito-proof fibrous layer, described mosquito-proof fibrous layer is provided with printed pattern layer, and described printed pattern layer coated thereon has antibacterial and mouldproof layer, described antibacterial and mouldproof layer to be provided with coating layer.The wallpaper safety and environmental protection of the present invention, cheap, economic and practical, there is good antimildew and antibacterial anti-mosquito property, there is promotion and use value.
Description
Technical field
The present invention relates to a kind of wallpaper, especially a kind of mosquito-proof composite wallpaper of mildew-resistant.
Background technology
Wallpaper, also referred to as wallpaper, it is a kind of application house decorative material the most widely.Because it is many that wallpaper has color
Other house decorative materials multiple such as sample, pattern are abundant, luxurious style, safety and environmental protection, easy construction, affordable cannot compare
The feature intended, therefore obtain considerable degree of universal at developed countries and regions such as America and Europe, Southeast Asia, Japan.In recent years, China room
Interior trim finishing is persistently overheating, the wallpaper that had once been given the cold shoulder with its gorgeous new attitude again come into parlor, bedroom, hotel,
Meeting room etc..
In the past, wallpaper comes into the life of people as just a kind of decorative material, and it is required many in dicoration by people
Above aesthetic property, along with the raising of people's living standard, people need the wallpaper wanting high-quality to decorate the life of oneself, people
Other Functional Requirement of wallpaper is also got more and more.
The environment of human living is the significant problem that present society is extremely paid close attention to.In recent years at the construction quality being exposed by the media
In problem, body of wall condensation is gone mouldy and is had become as one of hot issue, and especially China southern Jiangsu, Shanghai one carries, and is in north subtropical
Moistening monsoon climate, the most all can have plum rains season, and plum rain season temperature height, high humidity, air pressure are low, and indoor moisture is dark, ventilates
In the case of poor, can inevitably grow various mycete, according to investigations, between June to November, there is the resident of half in Shanghai
There is Signs of Mould in house, and therefore this is accomplished by the wallpaper mildew resistance to be had for interior decoration, on the one hand can extend wall
Paper service life in wet environment, another convenient protection body of wall, it is to avoid body of wall has wallpaper mouldy, and then avoids the taste of antibacterial
Raw, the environment of the indoor inhabitation of protection, protection resident's is healthy.
It addition, hygrothermal environment, not only cause various antibacterial, the growing of mycete, the when of summer, also can make the number of mosquito
Measuring more, mosquito bite can bring transmission of disease to the mankind, to people healthy come band harm, therefore, it is necessary to make wall
Paper has mosquito-proof effect.
And wallpaper function in the market is the most single.Therefore, it is necessary to develop one there is the mosquito-proof performance of mildew-resistant
Multifunctional wallpaper.
Summary of the invention
Goal of the invention: the invention aims to solve the deficiencies in the prior art, it is provided that a kind of mosquito-proof composite of mildew-resistant
Paper.
Technical scheme: in order to realize object above, the present invention is by the following technical solutions.
A kind of mosquito-proof composite wallpaper of mildew-resistant, including flame-resistant polyacrylonitrile fiber layer, described flame-resistant polyacrylonitrile fiber layer
The back side is provided with waterproof mildew-resistant layer, described flame-resistant polyacrylonitrile fiber layer be arranged above with antibacterial mosquito-proof layer, described antibacterial mosquito-proof layer
Being arranged above with mosquito-proof fibrous layer, described mosquito-proof fibrous layer is provided with printed pattern layer, and described printed pattern layer coated thereon has anti-
Bacterium mildew-resistant layer, described antibacterial and mouldproof layer is provided with coating layer；Described waterproof mildew-resistant layer is made up of the material of following mass percent:
Modified polyvinylalcohol: 30-35 part, sodium alginate: 6-8 part, IPBC: 5-7 part, galapectite
Nanotube: 4-6 part, silicone acrylic emulsion: 20-22 part, deionized water: 30-35 part；Described antibacterial and mouldproof layer is by following mass percent
Material composition: modified polyvinylalcohol: 20-22 part, zeolite with carrying silver: 0.5-1 part, chitosan: 4-5 part；Calcium lignosulfonate: 4-
5 parts, camphor leaf extract: 10-15 part, DDAC: 1-1.5 part, pectin and sodium lactate compound: 4-5 part,
Deionized water: 75-80 part.
Preferably, described flame-resistant polyacrylonitrile fiber refers to have the poly-of certain anti-flammability after chemical modification
Tacryl, the concrete preparation method of described flame-resistant polyacrylonitrile fiber is as follows: be 1: 10-1 by polyacrylonitrile fibre by bath raio:
The ratio of 30 is soaked in the hydrazine hydrate solution that mass fraction is 3%, reacts 3-5 hour 80 DEG C of insulated and stirred, takes out polypropylene
Nitrile fiber, washes 3-5 time, vacuum drying, obtains described flame-resistant polyacrylonitrile fiber.
Preferably, described pectin and sodium lactate compound are 5mg/mL hawthorn pectin oligosaccharide and 10mg/mL lactic acid
Compound.
Preferably, described mosquito-proof fiber is mosquito-proof tossa, and its concrete preparation method is: be with butane tetracarboxylic
Acid (BTCA) is cross-linking agent, and sodium hypophosphite (SHP) is catalyst, is grafted on tossa by beta-schardinger dextrin-(β-CD), then
Arrange through Herba Cymbopogonis Citrari extract and obtain.
Preferably, described antibacterial mosquito-proof layer is made up of the material of following mass percent: PE:80-90 part, amine chrysanthemum
Fat: 4-6 part, eugenol: 1-1.5 part, glass fibre: 4-6 part, organo montmorillonite: 4-6 part, octaphenyl eight silsesquioxane: 1-
2 parts, carbon fiber: 1-2 part, kieselguhr: 6-8 part, polyetheretherketonefiber fiber: 2-4 part, chitosan: 4-5 part, dimethyl fumarate: 1-
2 parts, meerschaum: 5-7 part, sorbic acid: 1-1.5 part, softening agent: 1-2 part, retention agent: 0.3-0.5 part, wet strength agent: 1-2 part, second
Alcohol: 5-8 part, deionized water: 30-35 part.
As further preferred scheme, the thickness of described antibacterial mosquito-proof layer is 0.1-0.3mm；
As further preferred scheme, described softening agent is stearic acid triethanolamine ester quaternary, and retention agent is guar gum, wet by force
Agent is PAE resin.
As further preferred scheme, described organo montmorillonite is 3-hexadecane epoxide-2-hydroxypropyl trimethyl chlorination
The organo montmorillonite that ammonium is modified.
As further preferred version, the preparation method of described organo montmorillonite is: by the inorganic illiteracy that mass ratio is 1:1
De-soil and 3-hexadecane epoxide-2-trimethyl ammonium chloride are dissolved in the ethanol water that mass fraction is 50%, mixing
Uniformly post-heating is to 75 DEG C, reacts 1 hour, filters, filter cake ethanol purge, is drying to obtain described organo montmorillonite.
Wherein: the ethanol water that the inorganic montmorillonite of 1g needs 15-20ml mass fraction to be 50%.
Preferably, the thickness of described waterproof mildew-resistant layer is 0.2-0.4mm.
Preferably, the thickness of described antibacterial and mouldproof layer is 0.1-0.3mm.
Preferably, halloysite nanotubes pipe range is 0.5-1.5 μm.
Preferably, described modified polyvinylalcohol is citric acid-modified polyvinyl alcohol, and its preparation method is: according to matter
Amount number meter, by 9-11 part polyvinyl alcohol, 0.1-0.3 part citric acid, 0.5-1.5 part glycerol, 88-90 part deionized water, 95
At DEG C constant temperature stir 3 hours, then deaerate under-0.1 MPa 1 h, finally at 60 DEG C be dried 3 h i.e. obtain described modification gather
Vinyl alcohol.
Preferably, the preparation method of described camphor leaf extract is as follows: Folium cinnamomi camphorae powder is positioned over quality and divides
In the ethanol water of several 60%, insulated and stirred 2-3 hour at 55 DEG C, then to filter, filter residue, filtrate is in 55 DEG C of decompressions
Distilling and i.e. obtain described camphor leaf extract, during extraction, Folium cinnamomi camphorae powder is V ethanol with the solid-liquid ratio of ethanol water: m tree
Leaf=16: 1.
Preferably, described mosquito-proof fibrolaminar thickness is 0.1-0.3mm.
Preferably, described coating layer is polyethylene film, and thickness is 0.2-0.4mm.Polyethylene has excellent
Moisture resistance so that the moisture resistance of wallpaper is the most superior.
The above-mentioned silicone acrylic emulsion used of the present invention uses commercially available, and can be such as that Nantong is raw reaches the limited public affairs of chemical industry
The SD-528 silicone acrylic emulsion that department produces.
Beneficial effect: compared with prior art, the present invention has a following significance beneficial effect:
1, the wallpaper of the present invention, uses flame-resistant polyacrylonitrile fiber to do wallpaper basic unit, and flame-resistant polyacrylonitrile fiber is to polypropylene
The fiber that nitrile fiber obtains after carrying out flame-retardant modified process, in this, as the basic unit of wallpaper, not only make use of polyacrylonitrile fine
Tie up self excellent elasticity of compression and mothproof, mildew-resistant characteristic, also there is anti-flammability, add the mildew-proof flame retarded of wallpaper on the whole
Performance, be simultaneously provided with waterproof mildew-resistant layer, antibacterial mosquito-proof layer, antibacterial and mouldproof layer, and the antimildew and antibacterial of multi-ensuring wallpaper is mosquito-proof
Property, it is additionally provided with mosquito-proof fibrous layer, further enhancing the anti-mosquito property of wallpaper, used mosquito-proof tossa simultaneously, simultaneously profit
The good moisture absorption and desorption property that has with tossa self, ventilating, hot wet migration, bacteriostasis antibiosis, anti-purple
Outward linear, easily biological-degradable, further enhancing the performance of wallpaper, makes the wallpaper environmental protection of the present invention, economy, it is adaptable to damp and hot
Environment uses；It is additionally provided with coating layer and protects wallpaper further, extend the service life of wallpaper；
2, the reagent environmental protection that each layer of the present invention uses, meets the regulation of GB18585-2001, does not contains the taboo of national regulation
Only the heavy metal antimony of use, arsenic, barium, cadmium, chromium, lead, hydrargyrum, selenium, do not contain formaldehyde, do not contain Vinyl Chloride Monomer, do not result in yet
Secondary pollution；
In a word, the wallpaper of the present invention is a mildew-resistant, mosquito-proof, antibacterial, fire-retardant, deodorization, moistureproof multi-functional environment-protection green wallpaper,
There is promotion and use value.
Accompanying drawing explanation
Fig. 1 is the structural representation of the embodiment of the present invention；
In figure: 1-waterproof mildew-resistant layer, 2-flame-resistant polyacrylonitrile fiber layer, the antibacterial mosquito-proof layer of 3-, the mosquito-proof fibrous layer of 4-, 5--print
Embossed layers, 6-antibacterial and mouldproof layer, 7-coating layer.
Detailed description of the invention
Below in conjunction with embodiment, technical solution of the present invention is described in further detail and completely.
Embodiment 1
A kind of mosquito-proof composite wallpaper of mildew-resistant, including flame-resistant polyacrylonitrile fiber layer 2, the back of the body of described flame-resistant polyacrylonitrile fiber layer 2
Face is provided with waterproof mildew-resistant layer 1, described flame-resistant polyacrylonitrile fiber layer 2 be arranged above with antibacterial mosquito-proof layer 3, described antibacterial mosquito-proof layer
3 are arranged above with mosquito-proof fibrous layer 4, and described mosquito-proof fibrous layer 4 is provided with printed pattern layer 5, described printed pattern layer 5 coated thereon
Antibacterial and mouldproof layer 6, described antibacterial and mouldproof layer 6 is had to be provided with coating layer 7.
Wherein:
Waterproof mildew-resistant layer 1 is made up of the material of following mass percent: modified polyvinylalcohol: 30 parts, sodium alginate: 6 parts, 3-
Iodo-2-propynyl butyl carbamate: 5 parts, halloysite nanotubes: 4 parts, silicone acrylic emulsion: 20 parts, deionized water: 30 parts；Anti-
The thickness of water mildew-resistant layer 1 is 0.2mm.
Antibacterial mosquito-proof layer 3 is made up of the material of following mass percent: PE:80 part, tetramethrin: 4 parts, eugenol: 1 part,
Glass fibre: 4 parts, organo montmorillonite: 4 parts, octaphenyl eight silsesquioxane: 1 part, carbon fiber: 1 part, kieselguhr: 6 parts, polyethers
Ether ketone fiber: 2 parts, chitosan: 4 parts, dimethyl fumarate: 1 part, meerschaum: 5 parts, sorbic acid: 1 part, softening agent: stearic acid
Triethanol amine ester quat: 1 part, retention agent: guar gum: 0.3 part, wet strength agent: PAE resin: 1 part, ethanol: 5 parts, deionization
Water: 30 parts；The thickness of antibacterial mosquito-proof layer 3 is 0.3mm.
The thickness of mosquito-proof fibrous layer 4 is 0.1mm.
Antibacterial and mouldproof layer 6 is made up of the material of following mass percent: modified polyvinylalcohol: 20 parts, zeolite with carrying silver: 0.5
Part, chitosan: 4 parts, calcium lignosulfonate: 4 parts, camphor leaf extract: 10 parts, DDAC: 1 part, pectin
With sodium lactate compound: 4 parts, deionized water: 75 parts；The thickness of antibacterial and mouldproof layer 6 is 0.1mm.
Coating layer 7 is polyethylene film, and thickness is 0.2mm.
Embodiment 2
A kind of mosquito-proof composite wallpaper of mildew-resistant, including flame-resistant polyacrylonitrile fiber layer 2, the back of the body of described flame-resistant polyacrylonitrile fiber layer 2
Face is provided with waterproof mildew-resistant layer 2, described flame-resistant polyacrylonitrile fiber layer 2 be arranged above with antibacterial mosquito-proof layer 3, described antibacterial mosquito-proof layer
3 are arranged above with mosquito-proof fibrous layer 4, and described mosquito-proof fibrous layer 4 is provided with printed pattern layer 5, described printed pattern layer 5 coated thereon
Antibacterial and mouldproof layer 6, described antibacterial and mouldproof layer 6 is had to be provided with coating layer 7.
Wherein:
Waterproof mildew-resistant layer 2 is made up of the material of following mass percent: modified polyvinylalcohol: 33 parts, sodium alginate: 7 parts, 3-
Iodo-2-propynyl butyl carbamate: 6 parts, halloysite nanotubes: 5 parts, silicone acrylic emulsion: 21 parts, deionized water: 33 parts；Anti-
The thickness of water mildew-resistant layer 2 is 0.3mm.
Antibacterial mosquito-proof layer 3 is made up of the material of following mass percent: PE:85 part, tetramethrin: 5 parts, eugenol: 1.3
Part, glass fibre: 5 parts, organo montmorillonite: 5 parts, octaphenyl eight silsesquioxane: 1.5 parts, carbon fiber: 1.5 parts, kieselguhr: 7
Part, polyetheretherketonefiber fiber: 3 parts, chitosan: 4.5 parts, dimethyl fumarate: 1.5 parts, meerschaum: 6 parts, sorbic acid: 1.3 parts,
Softening agent: stearic acid triethanolamine ester quaternary: 1.5 parts, retention agent: guar gum: 0.4 part, wet strength agent: PAE resin: 1-.5
Part, ethanol: 6.5 parts, deionized water: 33 parts；The thickness of antibacterial mosquito-proof layer 3 is 0.2mm.
The thickness of mosquito-proof fibrous layer 4 is 0.2mm.
Antibacterial and mouldproof layer 6 is made up of the material of following mass percent: modified polyvinylalcohol: 21 parts, zeolite with carrying silver: 0.8
Part, chitosan: 4.5 parts, calcium lignosulfonate: 4.5 parts, camphor leaf extract: 13 parts, DDAC: 1.3
Part, pectin and sodium lactate compound: 4.5 parts, deionized water: 780 parts；The thickness of antibacterial and mouldproof layer 6 is 0.2mm.
Coating layer 7 is polyethylene film, and thickness is 0.3mm.
Embodiment 3
A kind of mosquito-proof composite wallpaper of mildew-resistant, including flame-resistant polyacrylonitrile fiber layer 2, the back of the body of described flame-resistant polyacrylonitrile fiber layer 2
Face is provided with waterproof mildew-resistant layer 2, described flame-resistant polyacrylonitrile fiber layer 2 be arranged above with antibacterial mosquito-proof layer 3, described antibacterial mosquito-proof layer
3 are arranged above with mosquito-proof fibrous layer 4, and described mosquito-proof fibrous layer 4 is provided with printed pattern layer 5, described printed pattern layer 5 coated thereon
Antibacterial and mouldproof layer 6, described antibacterial and mouldproof layer 6 is had to be provided with coating layer 7.
Wherein:
Waterproof mildew-resistant layer 2 is made up of the material of following mass percent: modified polyvinylalcohol: 35 parts, sodium alginate: 8 parts, 3-
Iodo-2-propynyl butyl carbamate: 7 parts, halloysite nanotubes: 6 parts, silicone acrylic emulsion: 22 parts, deionized water: 35
Part；The thickness of waterproof mildew-resistant layer 2 is 0.4mm.
Antibacterial mosquito-proof layer 3 is made up of the material of following mass percent: PE:90 part, tetramethrin: 6 parts, eugenol:
1.5 parts, glass fibre: 6 parts, organo montmorillonite: 6 parts, octaphenyl eight silsesquioxane: 2 parts, carbon fiber: 2 parts, diatom
Soil: 8 parts, polyetheretherketonefiber fiber: 4 parts, chitosan: 5 parts, dimethyl fumarate: 2 parts, meerschaum: 7 parts, sorbic acid:
1.5 parts, softening agent: stearic acid triethanolamine ester quaternary: 2 parts, retention agent: guar gum: 0.5 part, wet strength agent: PAE resin:
2 parts, ethanol: 8 parts, deionized water: 35 parts；The thickness of antibacterial mosquito-proof layer 3 is 0.3mm.
The thickness of mosquito-proof fibrous layer 4 is 0.3mm.
Antibacterial and mouldproof layer 6 is made up of the material of following mass percent: modified polyvinylalcohol: 22 parts, zeolite with carrying silver: 1
Part, chitosan: 5 parts, calcium lignosulfonate: 5 parts, camphor leaf extract: 15 parts, DDAC: 1.5
Part, pectin and sodium lactate compound: 5 parts, deionized water: 80 parts；The thickness of antibacterial and mouldproof layer 6 is 0.3mm.
Coating layer 7 is polyethylene film, and thickness is 0.4mm.
Flame-resistant polyacrylonitrile fiber in above-described embodiment, is to be prepared via a method which and obtain: by polyacrylonitrile fibre
It is soaked in the hydrazine hydrate solution that mass fraction is 3% in the ratio that bath raio is 1: 20, reacts 4 hours 80 DEG C of insulated and stirred, take
Go out polyacrylonitrile fibre, wash 5 times, vacuum drying, obtain described flame-resistant polyacrylonitrile fiber.
Mosquito-proof fiber in above-described embodiment uses mosquito-proof tossa, is to be prepared via a method which and obtain: be first
Tossa is placed in 60 DEG C containing 110 g/L BTCAs (BTCA), 4 g/L sodium hypophosphite (SHP), 70 g/L β-ring
In the hot water of dextrin (β-CD), bath raio 1: 50, stirring makes it be completely dissolved, and rolls (pick-up rate 100 %) through two leachings two, 170 DEG C of roastings
Drying 3 min, then 60 DEG C of washing 10 min, cold water is washed, and obtains the tossa that beta-schardinger dextrin-is modified after drying；Then will obtain
The modified tossa of beta-schardinger dextrin-be placed in the ethanol water that mass fraction is 80% containing 10 g/L Herba Cymbopogonis Citrari extracts
In, bath raio is bath raio 1: 10,30 DEG C of constant temperature oscillation 2 h, and being then rolled to liquid carrying rate is to dry under 100 %, room temperature i.e. to obtain mosquito-proof Huang
Flaxen fiber.
Described Herba Cymbopogonis Citrari extract be Herba Cymbopogonis Citrari is positioned in the ethanol of 80% immersion 7-8h after, then through aseptic filtration
Rear prepared, it is 100-400mg/mL that prepared Herba Cymbopogonis Citrari takes the concentration of thing.
Modified polyvinylalcohol in above-described embodiment, is to be prepared via a method which and obtain: according to mass fraction meter, by 10
Part polyvinyl alcohol, 0.2 part of citric acid, 1 part of glycerol, 89 parts of deionized waters, at 95 DEG C, constant temperature stirs 3 hours, then-0.1
Deaerate under MPa 1 h, is finally dried 3 h at 60 DEG C and i.e. obtains described modified polyvinylalcohol.
Camphor leaf extract in above-described embodiment, is to be prepared via a method which and obtain: be positioned over by Folium cinnamomi camphorae powder
In the ethanol water of mass fraction 60%, insulated and stirred 2-3 hour at 55 DEG C, then to filter, filter residue, filtrate is in 55
DEG C decompression distill and is i.e. obtained described camphor leaf extract, and during extraction, the solid-liquid ratio of Folium cinnamomi camphorae powder and ethanol water is V second
Alcohol: m leaves=16: 1.
Organo montmorillonite in above-described embodiment, is to be prepared via a method which and obtain:
Inorganic montmorillonite and 3-hexadecane epoxide-2-trimethyl ammonium chloride that mass ratio is 1:1 are dissolved in quality and divide
Number be 50% ethanol water in (ethanol water that the inorganic montmorillonite of 1g needs 15-20ml mass fraction to be 50%), mixing
Uniformly post-heating is to 75 DEG C, reacts 1 hour, filters, filter cake ethanol purge, is drying to obtain described organo montmorillonite.
The processing technology of the wallpaper of example wallpaper routinely time above-mentioned, through paste producing, coating, is dried, prints, sends out
Bubble, embossing, cooling, trimming, rolling.
The wallpaper prepared according to above-described embodiment meets the regulation of GB18585-2001, do not contain national regulation forbid make
Heavy metal antimony, arsenic, barium, cadmium, chromium, lead, hydrargyrum, selenium, do not contain formaldehyde, do not contain Vinyl Chloride Monomer.
The wallpaper prepared according to above-described embodiment, carries out mildew resistance test to it, and concrete method of testing is: by 30x60 milli
The wallpaper of rice be exposed to containing escherichia coli, Salmonella, staphylococcus aureus suspension in, be placed in beneficially mushroom raw
Long environment (temperature 25 DEG C, relative humidity 85%), this environment tackles the wet environment of daily household, including the Huang that south is common
Rainy season gas, after one month, wallpaper surface occurs without macula lutea and mildew, and this explanation wallpaper has superior mildew resistance.
The wallpaper prepared according to above-described embodiment, carries out antibiotic property test to it, with reference to JISZ2801:2000 " antibacterial system
The detection of product anti-microbial property and evaluation)) standard detects, and carries out antibacterial to common escherichia coli, staphylococcus aureus
Test, experimental result display the present invention wallpaper to escherichia coli, staphylococcus aureus bacteriostasis rate all up to 99.99%；Tool
There is superior bacteriostasis antibiosis.
The wallpaper prepared according to above-described embodiment, carries out anti-mosquito property test to it: by GB/T 30,126 2013 " weaving
The detection of the mosquito-proof performance of product and evaluation " and GB/T 13917.9 2009 " agriculture chemical registration hygienic insecticide indoor pharmacodynamic test and
Evaluate the 9th part: repellant " it is carried out mosquito-proof measure of merit, the scattering ratio of this mosquito-proof fiber needle fabric dialogue stricture of vagina yellow-fever mosquito reaches
95.92%, this explanation wallpaper has superior anti-mosquito property.
It addition, the wallpaper prepared according to above-described embodiment, carrying out anti-flammability test, test result shows, its UL-94 hangs down
Direct combustion burns and reaches V-0 level, and LOI reaches more than 30, has good anti-flammability.In addition, the wallpaper of the present invention also has
Good deodorization, moisture resistance, in a word, the wallpaper of the present invention is a mildew-resistant, mosquito-proof, antibacterial, fire-retardant, deodorization, moistureproof many merits
Energy environment-friendly and green wallpaper, has promotion and use value.
Finally need it is pointed out here that: be the most only the part preferred embodiment of the present invention, it is impossible to be interpreted as this
The restriction of bright protection domain, some nonessential improvement that those skilled in the art makes according to the foregoing of the present invention and
Adjustment belongs to protection scope of the present invention.
Claims (10)
1. the mosquito-proof composite wallpaper of mildew-resistant, it is characterised in that: include flame-resistant polyacrylonitrile fiber layer, described fire-retardant polyacrylonitrile
The fibrolaminar back side is provided with waterproof mildew-resistant layer, described flame-resistant polyacrylonitrile fiber layer be arranged above with antibacterial mosquito-proof layer, described anti-
The mosquito-proof layer of bacterium is arranged above with mosquito-proof fibrous layer, and described mosquito-proof fibrous layer is provided with printed pattern layer, above described printed pattern layer
Being coated with antibacterial and mouldproof layer, described antibacterial and mouldproof layer is provided with coating layer；Described waterproof mildew-resistant layer is by following mass percent
Material forms: modified polyvinylalcohol: 30-35 part, sodium alginate: 6-8 part, IPBC: 5-7
Part, halloysite nanotubes: 4-6 part, silicone acrylic emulsion: 20-22 part, deionized water: 30-35 part；Described antibacterial and mouldproof layer is by following
The material composition of mass percent: modified polyvinylalcohol: 20-22 part, zeolite with carrying silver: 0.5-1 part, chitosan: 4-5 part, wooden
Element sulfoacid calcium: 4-5 part, camphor leaf extract: 10-15 part, DDAC: 1-1.5 part, pectin is multiple with sodium lactate
Join thing: 4-5 part, deionized water: 75-80 part.
The mosquito-proof composite wallpaper of mildew-resistant the most according to claim 1, it is characterised in that: described flame-resistant polyacrylonitrile fiber refers to
Having the polypropylene fibre of certain anti-flammability after chemical modification, the concrete preparation method of described flame-resistant polyacrylonitrile fiber is such as
Under: polyacrylonitrile fibre is soaked in the hydrazine hydrate solution that mass fraction is 3% in the ratio that bath raio is 1: 10-1: 30,
80 DEG C of insulated and stirred are reacted 3-5 hour, take out polyacrylonitrile fibre, wash 3-5 time, and vacuum drying obtains described flame-retardant polypropylene
Alkene nitrile fiber.
The mosquito-proof composite wallpaper of mildew-resistant the most according to claim 1, it is characterised in that: described pectin with sodium lactate compound is
5mg/mL hawthorn pectin oligosaccharide and the compound of 10mg/mL lactic acid.
The mosquito-proof composite wallpaper of mildew-resistant the most according to claim 1, it is characterised in that: described mosquito-proof fiber is that mosquito-proof Corchorus olitorius L. is fine
Dimension, its concrete preparation method is: being with BTCA as cross-linking agent, sodium hypophosphite is catalyst, by grafted by beta cyclodextrin
On tossa, then obtain through the arrangement of Herba Cymbopogonis Citrari extract.
The mosquito-proof composite wallpaper of mildew-resistant the most according to claim 1, it is characterised in that: PE:80-90 part, tetramethrin: 4-6 part,
Eugenol: 1-1.5 part, glass fibre: 4-6 part, organo montmorillonite: 4-6 part, octaphenyl eight silsesquioxane: 1-2 part, carbon is fine
Dimension: 1-2 part, kieselguhr: 6-8 part, polyetheretherketonefiber fiber: 2-4 part, chitosan: 4-5 part, dimethyl fumarate: 1-2 part, Hai Pao
Stone: 5-7 part, sorbic acid: 1-1.5 part, softening agent: 1-2 part, retention agent: 0.3-0.5 part, wet strength agent: 1-2 part, ethanol: 5-8
Part, deionized water: 30-35 part.
The mosquito-proof composite wallpaper of mildew-resistant the most according to claim 5, it is characterised in that: described softening agent is stearic acid three ethanol
Amine ester quat, retention agent is guar gum, and wet strength agent is PAE resin.
The mosquito-proof composite wallpaper of mildew-resistant the most according to claim 5, it is characterised in that: described organo montmorillonite is 3-hexadecane
The organo montmorillonite that epoxide-2-trimethyl ammonium chloride is modified.
The mosquito-proof composite wallpaper of mildew-resistant the most according to claim 7, it is characterised in that: the preparation method of described organo montmorillonite
For: inorganic montmorillonite and 3-hexadecane epoxide-2-trimethyl ammonium chloride that mass ratio is 1:1 are dissolved in mass fraction
It is in the ethanol water of 50%, mix homogeneously post-heating to 75 DEG C, reacts 1 hour, filters, filter cake ethanol purge, be dried i.e.
Organo montmorillonite described in.
The mosquito-proof composite wallpaper of mildew-resistant the most according to claim 1, it is characterised in that: described modified polyvinylalcohol is citric acid
Modified polyvinylalcohol, its preparation method is: according to mass fraction meter, by 9-11 part polyvinyl alcohol, 0.1-0.3 part citric acid,
0.5-1.5 part glycerol, 88-90 part deionized water, at 95 DEG C, constant temperature stirs 3 hours, and then deaerate under-0.1 MPa 1 h,
Last 3 h that are dried at 60 DEG C i.e. obtain described modified polyvinylalcohol.
The mosquito-proof composite wallpaper of mildew-resistant the most according to claim 1, it is characterised in that: the preparation of described camphor leaf extract
Method is as follows: be positioned in the ethanol water of mass fraction 60% by Folium cinnamomi camphorae powder, insulated and stirred 2-3 hour at 55 DEG C,
Then filtering, filter residue, filtrate is distilled in 55 DEG C of decompressions and is i.e. obtained described camphor leaf extract, Folium cinnamomi camphorae powder during extraction
It is V ethanol with the solid-liquid ratio of ethanol water: m leaves=16: 1.
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| CN201610443400.9A CN106079701A (en) | 2016-06-21 | 2016-06-21 | A kind of mosquito-proof composite wallpaper of mildew-resistant |
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| CN201610443400.9A CN106079701A (en) | 2016-06-21 | 2016-06-21 | A kind of mosquito-proof composite wallpaper of mildew-resistant |
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| CN201610443400.9A Pending CN106079701A (en) | 2016-06-21 | 2016-06-21 | A kind of mosquito-proof composite wallpaper of mildew-resistant |
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Application publication date: 20161109 |