CN106057389A - Potentiometer - Google Patents
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- CN106057389A CN106057389A CN201610510243.9A CN201610510243A CN106057389A CN 106057389 A CN106057389 A CN 106057389A CN 201610510243 A CN201610510243 A CN 201610510243A CN 106057389 A CN106057389 A CN 106057389A
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Abstract
本发明公开一种电位器,包括:壳体、旋转轴、转动机构一、转动机构二、二维纳米碳片以及设置在二维纳米碳片上的三个碳片端子;壳体包括上壳体和下壳体;转动机构一、转动机构二、二维纳米碳片设置在上壳体和下壳体之间;轴杆的两个平行的平面分别与直边一、直边二相抵持,使旋转轴旋转带动转动机构一和转动机构二,调节电位器的阻值。本发明提供的具有二维纳米碳片的电位器,开关零件少,耐高温性能好,能在高温下不变形,避免了铆接在高温下易变形的不足。二维纳米碳片的电位器的导电性能优良。
The invention discloses a potentiometer, comprising: a housing, a rotating shaft, a rotating mechanism 1, a rotating mechanism 2, a two-dimensional nano-carbon sheet and three carbon sheet terminals arranged on the two-dimensional nano-carbon sheet; the casing includes an upper casing and the lower casing; the first rotating mechanism, the second rotating mechanism, and the two-dimensional nano-carbon sheet are arranged between the upper casing and the lower casing; the two parallel planes of the shaft are opposed to the straight side one and the straight side two respectively, Rotate the rotating shaft to drive the first rotating mechanism and the second rotating mechanism to adjust the resistance value of the potentiometer. The potentiometer with the two-dimensional nano-carbon sheet provided by the present invention has few switch parts, good high temperature resistance, can not be deformed at high temperature, and avoids the disadvantage that riveting is easily deformed at high temperature. The potentiometer of the two-dimensional carbon nanosheet has excellent electrical conductivity.
Description
技术领域technical field
本发明涉及电位器领域,尤其涉及一种电位器。The invention relates to the field of potentiometers, in particular to a potentiometer.
背景技术Background technique
碳膜式电位器广泛应用于多媒体音响、收录机、调音台等电子设备中作音量、音调、平衡控制和电流、电压调节,还可实现遥控调节。Carbon film potentiometers are widely used in multimedia audio, tape recorders, mixers and other electronic equipment for volume, tone, balance control, current, and voltage adjustment, and can also be used for remote control adjustment.
现有技术中,在纳米碳表面接枝约1~20份的化学基团,期望利用这些基团增加与不同主体材料的界面结合,但这有较大的使用局限性,并且不能经受高温环境,纳米碳表面的数量仍然有限,其与聚合物结合时的力量不够大,在复合材料受力拉伸或弯曲时,碳纳米管仍然会滑出,影响正常使用。In the prior art, about 1 to 20 parts of chemical groups are grafted on the surface of nanocarbons. It is expected to use these groups to increase the interface bonding with different host materials, but this has relatively large limitations in use and cannot withstand high temperature environments However, the number of nano-carbon surfaces is still limited, and the strength when it is combined with the polymer is not strong enough. When the composite material is stretched or bent, the carbon nanotubes will still slip out, affecting normal use.
发明内容Contents of the invention
为了克服上述现有技术中的不足,本发明的目的在于,提供一种电位器,包括:壳体、旋转轴、转动机构一、转动机构二、二维纳米碳片以及设置在二维纳米碳片上的三个碳片端子;所述二维纳米碳片包括组分含量为:金属氧化物纳米管5份~10份、导电碳黑或石墨含量为10份~20份、氧化锆纳米粉体的含量为3份~6份、活性炭为10份~30份、纳米活性炭纤维为20份~30份,纳米金属镍粉体为1份~3份、碳氮前驱体为5份~30份、聚乙烯为15份~20份、沥青溶于二甲苯为15份~30份;In order to overcome the deficiencies in the above-mentioned prior art, the object of the present invention is to provide a potentiometer, including: a housing, a rotating shaft, a rotating mechanism 1, a rotating mechanism 2, a two-dimensional nano-carbon sheet, and a two-dimensional nano-carbon Three carbon terminals on the chip; the two-dimensional nano-carbon sheet includes the following components: 5-10 parts of metal oxide nanotubes, 10-20 parts of conductive carbon black or graphite, zirconia nano-powder The content is 3-6 parts, activated carbon is 10-30 parts, nano-activated carbon fiber is 20-30 parts, nano-metal nickel powder is 1-3 parts, carbon-nitrogen precursor is 5-30 parts, 15-20 parts for polyethylene, 15-30 parts for asphalt dissolved in xylene;
所述二维纳米碳片表面设有导涂层,导涂层上部设有量涂层,量涂层上部设有聚图层;The surface of the two-dimensional carbon nanosheet is provided with a conductive coating, the upper part of the conductive coating is provided with a quantitative coating, and the upper part of the quantitative coating is provided with an accumulation layer;
所述导涂层的材料为未参杂的二氧化钛和氧化锌的组合物或者组合掺杂了包括钙,镉,钆,锗,铯,铜,镍,银,铝,锂,金,铟,三氧化二钽,氧化锡,氧化钨,硒化锌,硫化镉或硫化锌在内的金属纳米颗粒;The material of the conductive coating is a combination of undoped titanium dioxide and zinc oxide or a combination of calcium, cadmium, gadolinium, germanium, cesium, copper, nickel, silver, aluminum, lithium, gold, indium, three Metal nanoparticles including tantalum oxide, tin oxide, tungsten oxide, zinc selenide, cadmium sulfide or zinc sulfide;
所述量涂层的材料为掺杂了包括钙,镉,钆,锗,铯,铜,镍,银,铝,锂,金,铟,三氧化二钽,氧化锡,氧化钨,硒化锌,硫化镉或硫化锌在内的金属纳米颗粒;The amount of coating material is doped with calcium, cadmium, gadolinium, germanium, cesium, copper, nickel, silver, aluminum, lithium, gold, indium, tantalum trioxide, tin oxide, tungsten oxide, zinc selenide , metal nanoparticles including cadmium sulfide or zinc sulfide;
所述聚图层的材料为掺杂了掺杂的材料为P型氮化镓,氧化镍,三氧化二铬,二硫化钼,聚(N-乙烯基咔唑)(PVK),聚(N,N'-二苯基-N,N'-二(间甲苯基)联苯胺)(poly-TPD),联苯(CBP),N,N'-偏(1-萘基;)-N,N'-联苯-1,1'-联苯-4,4'-二元胺(α-NPD),4,40,400-三(N-咔唑基)三苯胺(TCTA)的组合;The material of the poly layer is doped with doped materials such as P-type gallium nitride, nickel oxide, chromium oxide, molybdenum disulfide, poly(N-vinyl carbazole) (PVK), poly(N ,N'-diphenyl-N,N'-bis(m-tolyl)benzidine) (poly-TPD), biphenyl (CBP), N,N'-partial(1-naphthyl;)-N, A combination of N'-biphenyl-1,1'-biphenyl-4,4'-diamine (α-NPD), 4,40,400-tris(N-carbazolyl)triphenylamine (TCTA);
所述壳体包括上壳体和下壳体;转动机构一、转动机构二、二维纳米碳片设置在上壳体和下壳体之间;The casing includes an upper casing and a lower casing; the first rotating mechanism, the second rotating mechanism, and the two-dimensional carbon nanosheet are arranged between the upper casing and the lower casing;
所述上壳体、下壳体、转动机构一、转动机构二、二维纳米碳片的中心分别设有中心孔,旋转轴依次穿过上壳体中心孔、转动机构一中心孔、二维纳米碳片中心孔、转动机构二中心孔、下壳体中心孔,固定在下壳体中心孔上;The center of the upper shell, the lower shell, the first rotating mechanism, the second rotating mechanism, and the two-dimensional nano-carbon sheet are respectively provided with a central hole, and the rotating shaft passes through the central hole of the upper casing, the first central hole of the rotating mechanism, and the two-dimensional The central hole of the carbon nano sheet, the second central hole of the rotating mechanism, and the central hole of the lower shell are fixed on the central hole of the lower shell;
所述转动机构一边缘上均匀分布有五个凸台,所述转动机构二边缘上均匀分布有五个凸台,所述转动机构一与所述转动机构二的凸台位置相对应;Five bosses are evenly distributed on the first edge of the rotating mechanism, and five bosses are evenly distributed on the second edge of the rotating mechanism, and the positions of the bosses of the first rotating mechanism correspond to the positions of the second rotating mechanism;
所述旋转轴设有轴帽和轴杆,轴杆设有两个平行的平面,转动机构一的中心孔设有两个相平行的直边一,转动机构二的中心孔设有两个相平行的直边二,轴杆的两个平行的平面分别与直边一、直边二相抵持,使所述旋转轴旋转带动转动机构一和转动机构二,调节电位器的阻值。The rotating shaft is provided with a shaft cap and a shaft rod, the shaft rod is provided with two parallel planes, the central hole of the rotating mechanism 1 is provided with two parallel straight sides 1, and the central hole of the rotating mechanism 2 is provided with two parallel planes. The parallel straight side 2 and the two parallel planes of the shaft are opposed to the straight side 1 and the straight side 2 respectively, so that the rotation of the rotating shaft drives the rotation mechanism 1 and the rotation mechanism 2 to adjust the resistance value of the potentiometer.
优选地,所述转动机构一设有胶垫一,所述转动机构二设有胶垫二;Preferably, the first rotating mechanism is provided with a rubber pad 1, and the second rotating mechanism is provided with a rubber pad 2;
所述胶垫一与所述二维纳米碳片接触;The rubber pad one is in contact with the two-dimensional carbon nanosheet;
所述胶垫二与所述二维纳米碳片接触。The second rubber pad is in contact with the two-dimensional carbon nanosheet.
优选地,所述碳氮前驱体包括:选自于由尿素、二聚氰胺、三聚氰胺以及它们各自与低维纳米碳的混合物组成的组中的至少一种。Preferably, the carbon and nitrogen precursors include: at least one selected from the group consisting of urea, dicyandiamide, melamine, and their respective mixtures with low-dimensional nanocarbons.
优选地,纳米金属为Al、或Ni、或Li、或Zn、或Cu、或Ti、或Fe中的一种或几种。Preferably, the nano metal is one or more of Al, or Ni, or Li, or Zn, or Cu, or Ti, or Fe.
优选地,金属氧化物纳米管为Al2O3、或ZrO2、或TiO2、或MnO2、或V2O5中的一种或几种,其孔径范围为1nm~100nm。Preferably, the metal oxide nanotube is one or more of Al2O3, or ZrO2, or TiO2, or MnO2, or V2O5, and its pore size ranges from 1 nm to 100 nm.
优选地,所述活性炭的粒度在1nm~80μm范围内,比表面积为500m2/g~2000m2/g,密度为1.0g/cm3~1.5g/cm3。Preferably, the particle size of the activated carbon is in the range of 1nm-80μm, the specific surface area is 500m2/g-2000m2/g, and the density is 1.0g/cm3-1.5g/cm3.
优选地,所述活性炭的密度为0.3g/cm3~1.0g/cm3,中微孔>40%,中微孔为30nm~60nm范围的孔。Preferably, the density of the activated carbon is 0.3g/cm3-1.0g/cm3, the mesopores are >40%, and the mesopores are pores in the range of 30nm-60nm.
优选地,所述碳氮前驱体中,氮在所述碳氮前驱体中的质量百分比为20份~30份。Preferably, in the carbon-nitrogen precursor, the mass percentage of nitrogen in the carbon-nitrogen precursor is 20-30 parts.
从以上技术方案可以看出,本发明具有以下优点:As can be seen from the above technical solutions, the present invention has the following advantages:
在二维纳米碳片中,纳米金属和纳米活性炭纤维提高碳基材料的导电性能,降低电极材料的内阻,同时引入金属氧化物纳米管,在提高碳基电极材料的有效比表面积的基础上,利用纳米碳基材料表面和金属氧化物纳米管表面的纳米协同效应,大大增加了活性物质表面积的利用率。In two-dimensional carbon nanosheets, nano-metals and nano-activated carbon fibers improve the conductivity of carbon-based materials, reduce the internal resistance of electrode materials, and introduce metal oxide nanotubes at the same time to improve the effective specific surface area of carbon-based electrode materials. , using the nano-synergistic effect of the surface of the nano-carbon-based material and the surface of the metal oxide nanotube, greatly increasing the utilization of the surface area of the active material.
能经受高温环境,提高纳米碳与聚合物结合的力度,扩充了二维纳米碳片在各个领域的应用。It can withstand high temperature environment, improve the strength of the combination of nano-carbon and polymer, and expand the application of two-dimensional nano-carbon sheet in various fields.
附图说明Description of drawings
为了更清楚地说明本发明的技术方案,下面将对描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to illustrate the technical solution of the present invention more clearly, the accompanying drawings that need to be used in the description will be briefly introduced below. Obviously, the accompanying drawings in the following description are only some embodiments of the present invention. As far as people are concerned, other drawings can also be obtained based on these drawings on the premise of not paying creative work.
图1为具有二维纳米碳片的电位器的整体结构图;Fig. 1 is the overall structural diagram of the potentiometer with two-dimensional nanocarbon sheet;
图2为具有二维纳米碳片的电位器的爆炸图。Figure 2 is an exploded view of a potentiometer with two-dimensional carbon nanosheets.
具体实施方式detailed description
为使得本发明的发明目的、特征、优点能够更加的明显和易懂,下面将运用具体的实施例及附图,对本发明保护的技术方案进行清楚、完整地描述,显然,下面所描述的实施例仅仅是本发明一部分实施例,而非全部的实施例。基于本专利中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其它实施例,都属于本专利保护的范围。In order to make the purpose, features and advantages of the present invention more obvious and understandable, the technical solutions protected by the present invention will be clearly and completely described below using specific embodiments and accompanying drawings. Obviously, the implementation described below Examples are only some embodiments of the present invention, but not all embodiments. Based on the embodiments in this patent, all other embodiments obtained by persons of ordinary skill in the art without creative efforts fall within the protection scope of this patent.
本实施例提供一种电位器,请参阅图1和图2所示,包括:壳体1、旋转轴3、转动机构一4、转动机构二6、二维纳米碳片5以及设置在二维纳米碳片5上的三个碳片端子2;壳体1包括上壳体11和下壳体12;转动机构一4、转动机构二6、二维纳米碳片5设置在上壳体11和下壳体12之间;This embodiment provides a potentiometer, as shown in Fig. 1 and Fig. 2, including: a housing 1, a rotating shaft 3, a rotating mechanism 4, a rotating mechanism 2 6, a two-dimensional carbon nanosheet 5 and a two-dimensional Three carbon sheet terminals 2 on the carbon nanosheet 5; the housing 1 includes an upper casing 11 and a lower casing 12; a rotating mechanism one 4, a rotating mechanism two 6, and two-dimensional carbon nanosheets 5 are arranged on the upper casing 11 and the lower casing 12; Between the lower housing 12;
上壳体11、下壳体12、转动机构一4、转动机构二6、二维纳米碳片5的中心分别设有中心孔,旋转轴3依次穿过上壳体11中心孔、转动机构一4中心孔、二维纳米碳片5中心孔、转动机构二6中心孔、下壳体12中心孔,固定在下壳体12中心孔上;The centers of the upper casing 11, the lower casing 12, the first rotating mechanism 4, the second rotating mechanism 6, and the two-dimensional nano-carbon sheet 5 are respectively provided with a central hole, and the rotating shaft 3 passes through the central hole of the upper casing 11 and the first rotating mechanism successively. 4 central holes, 5 central holes of the two-dimensional nano-carbon sheet, 6 central holes of the rotating mechanism, 12 central holes of the lower casing, fixed on the 12 central holes of the lower casing;
转动机构一4边缘上均匀分布有五个凸台,转动机构二6边缘上均匀分布有五个凸台,转动机构一4与转动机构二6的凸台位置相对应;There are five bosses evenly distributed on the edge of the first rotating mechanism 4, and five bosses are evenly distributed on the edge of the second rotating mechanism 6, and the positions of the bosses of the first rotating mechanism 4 and the second 6 of the rotating mechanism are corresponding;
旋转轴3设有轴帽和轴杆,轴杆设有两个平行的平面,转动机构一4的中心孔设有两个相平行的直边一,转动机构二6的中心孔设有两个相平行的直边二,轴杆的两个平行的平面分别与直边一、直边二相抵持,使旋转轴3旋转带动转动机构一4和转动机构二6,调节电位器的阻值。The rotating shaft 3 is provided with a shaft cap and a shaft rod, and the shaft rod is provided with two parallel planes. Parallel straight side two, two parallel planes of the shaft rod are held against straight side one and straight side two respectively, so that the rotating shaft 3 rotates to drive the turning mechanism one 4 and the turning mechanism two 6 to adjust the resistance value of the potentiometer.
本发明提供的电位器,开关零件少,耐高温性能好,能在高温下不变形,避免了铆接在高温下易变形的不足。二维纳米碳片的电位器的导电性能优良。The potentiometer provided by the invention has few switch parts, good high temperature resistance, can not be deformed at high temperature, and avoids the disadvantage that riveting is easily deformed at high temperature. The potentiometer of the two-dimensional carbon nanosheet has excellent electrical conductivity.
转动机构一4设有胶垫一,转动机构二6设有胶垫二;胶垫一与二维纳米碳片5接触;胶垫二与二维纳米碳片5接触。减少转动机构一4和转动机构二6相对于二维纳米碳片5的磨损,延长电位器的使用时间,保证电位器的使用性能。Rotating mechanism one 4 is provided with rubber pad one, and rotating mechanism two 6 is provided with rubber pad two; rubber pad one is in contact with two-dimensional nano-carbon sheet 5; rubber pad two is in contact with two-dimensional nano-carbon sheet 5. Reduce the wear of the first rotating mechanism 4 and the second rotating mechanism 6 relative to the two-dimensional nano-carbon sheet 5, prolong the service time of the potentiometer, and ensure the performance of the potentiometer.
二维纳米碳片包括组分含量为:金属氧化物纳米管5份~10份、导电碳黑或石墨含量为10份~20份、氧化锆纳米粉体的含量为3份~6份、活性炭为10份~30份、纳米活性炭纤维为20份~30份,纳米金属镍粉体为1份~3份、碳氮前驱体为5份~30份、聚乙烯为15份~20份、沥青溶于二甲苯为15份~30份;The two-dimensional nano-carbon sheet includes the following components: 5-10 parts of metal oxide nanotubes, 10-20 parts of conductive carbon black or graphite, 3-6 parts of zirconia nano-powder, activated carbon 10-30 parts for nano-activated carbon fiber, 1-3 parts for nano-metal nickel powder, 5-30 parts for carbon-nitrogen precursor, 15-20 parts for polyethylene, asphalt Soluble in xylene is 15-30 parts;
所述二维纳米碳片表面设有导涂层,导涂层上部设有量涂层,量涂层上部设有聚图层;The surface of the two-dimensional carbon nanosheet is provided with a conductive coating, the upper part of the conductive coating is provided with a quantitative coating, and the upper part of the quantitative coating is provided with an accumulation layer;
所述导涂层的材料为未参杂的二氧化钛和氧化锌的组合物或者组合掺杂了包括钙,镉,钆,锗,铯,铜,镍,银,铝,锂,金,铟,三氧化二钽,氧化锡,氧化钨,硒化锌,硫化镉或硫化锌在内的金属纳米颗粒;The material of the conductive coating is a combination of undoped titanium dioxide and zinc oxide or a combination of calcium, cadmium, gadolinium, germanium, cesium, copper, nickel, silver, aluminum, lithium, gold, indium, three Metal nanoparticles including tantalum oxide, tin oxide, tungsten oxide, zinc selenide, cadmium sulfide or zinc sulfide;
所述量涂层的材料为掺杂了包括钙,镉,钆,锗,铯,铜,镍,银,铝,锂,金,铟,三氧化二钽,氧化锡,氧化钨,硒化锌,硫化镉或硫化锌在内的金属纳米颗粒;The amount of coating material is doped with calcium, cadmium, gadolinium, germanium, cesium, copper, nickel, silver, aluminum, lithium, gold, indium, tantalum trioxide, tin oxide, tungsten oxide, zinc selenide , metal nanoparticles including cadmium sulfide or zinc sulfide;
所述聚图层的材料为掺杂了掺杂的材料为P型氮化镓,氧化镍,三氧化二铬,二硫化钼,聚(N-乙烯基咔唑)(PVK),聚(N,N'-二苯基-N,N'-二(间甲苯基)联苯胺)(poly-TPD),联苯(CBP),N,N'-偏(1-萘基;)-N,N'-联苯-1,1'-联苯-4,4'-二元胺(α-NPD),4,40,400-三(N-咔唑基)三苯胺(TCTA)的组合;The material of the poly layer is doped with doped materials such as P-type gallium nitride, nickel oxide, chromium oxide, molybdenum disulfide, poly(N-vinyl carbazole) (PVK), poly(N ,N'-diphenyl-N,N'-bis(m-tolyl)benzidine) (poly-TPD), biphenyl (CBP), N,N'-partial(1-naphthyl;)-N, A combination of N'-biphenyl-1,1'-biphenyl-4,4'-diamine (α-NPD), 4,40,400-tris(N-carbazolyl)triphenylamine (TCTA);
所述转动机构一设有胶垫一,所述转动机构二设有胶垫二;The first rotating mechanism is provided with a rubber pad 1, and the second rotating mechanism is provided with a rubber pad 2;
所述胶垫一与所述二维纳米碳片接触;The rubber pad one is in contact with the two-dimensional carbon nanosheet;
所述胶垫二与所述二维纳米碳片接触。The second rubber pad is in contact with the two-dimensional carbon nanosheet.
所述碳氮前驱体包括:选自于由尿素、二聚氰胺、三聚氰胺以及它们各自与低维纳米碳的混合物组成的组中的至少一种。The carbon-nitrogen precursor includes: at least one selected from the group consisting of urea, dicyandiamide, melamine and their respective mixtures with low-dimensional nano-carbon.
纳米金属为Al、或Ni、或Li、或Zn、或Cu、或Ti、或Fe中的一种或几种。The nano metal is one or more of Al, or Ni, or Li, or Zn, or Cu, or Ti, or Fe.
金属氧化物纳米管为Al2O3、或ZrO2、或TiO2、或MnO2、或V2O5中的一种或几种,其孔径范围为1nm~100nm。The metal oxide nanotube is one or more of Al2O3, or ZrO2, or TiO2, or MnO2, or V2O5, and its pore diameter ranges from 1nm to 100nm.
所述活性炭的粒度在1nm~80μm范围内,比表面积为500m2/g~2000m2/g,密度为1.0g/cm3~1.5g/cm3。The particle size of the activated carbon is in the range of 1nm-80μm, the specific surface area is 500m2/g-2000m2/g, and the density is 1.0g/cm3-1.5g/cm3.
所述活性炭的密度为0.3g/cm3~1.0g/cm3,中微孔>40%,中微孔为30nm~60nm范围的孔。The density of the activated carbon is 0.3g/cm3-1.0g/cm3, the mesopores are more than 40%, and the mesopores are pores in the range of 30nm-60nm.
所述碳氮前驱体中,氮在所述碳氮前驱体中的质量百分比为20份~30份。In the carbon-nitrogen precursor, the mass percentage of nitrogen in the carbon-nitrogen precursor is 20-30 parts.
本说明书中各个实施例采用递进的方式描述,每个实施例重点说明的都是与其他实施例的不同之处,各个实施例之间相同相似部分互相参考即可。Each embodiment in this specification is described in a progressive manner, each embodiment focuses on the differences from other embodiments, and the same and similar parts of each embodiment can be referred to each other.
对所公开的实施例的上述说明,使本领域专业技术人员能够实现或使用本发明。对这些实施例的多种修改对本领域的专业技术人员来说将是显而易见的,本文中所定义的一般原理可以在不脱离本发明的精神或范围的情况下,在其它实施例中实现。因此,本发明将不会被限制于本文所示的这些实施例,而是要符合与本文所公开的原理和新颖特点相一致的最宽的范围。The above description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the general principles defined herein may be implemented in other embodiments without departing from the spirit or scope of the invention. Therefore, the present invention will not be limited to the embodiments shown herein, but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.
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