CN106048644B - A kind of compressibility of hydrogen-containing gas - Google Patents
A kind of compressibility of hydrogen-containing gas Download PDFInfo
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- CN106048644B CN106048644B CN201610639889.7A CN201610639889A CN106048644B CN 106048644 B CN106048644 B CN 106048644B CN 201610639889 A CN201610639889 A CN 201610639889A CN 106048644 B CN106048644 B CN 106048644B
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- 239000007789 gas Substances 0.000 title claims abstract description 81
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 67
- 239000001257 hydrogen Substances 0.000 title claims abstract description 61
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 61
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 36
- RECVMTHOQWMYFX-UHFFFAOYSA-N oxygen(1+) dihydride Chemical compound [OH2+] RECVMTHOQWMYFX-UHFFFAOYSA-N 0.000 claims abstract description 22
- 230000006835 compression Effects 0.000 claims abstract description 20
- 238000007906 compression Methods 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910001868 water Inorganic materials 0.000 claims abstract description 13
- 239000007788 liquid Substances 0.000 claims description 48
- 239000000446 fuel Substances 0.000 claims description 13
- 238000000926 separation method Methods 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 9
- 229910000831 Steel Inorganic materials 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 claims description 3
- 239000010959 steel Substances 0.000 claims description 3
- 230000005611 electricity Effects 0.000 claims description 2
- 238000011084 recovery Methods 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 abstract description 11
- 239000001301 oxygen Substances 0.000 abstract description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 9
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract description 5
- 229910001882 dioxygen Inorganic materials 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 3
- 150000002431 hydrogen Chemical class 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 239000002737 fuel gas Substances 0.000 abstract description 2
- 239000000567 combustion gas Substances 0.000 description 13
- 150000002430 hydrocarbons Chemical class 0.000 description 13
- 238000010586 diagram Methods 0.000 description 12
- 239000000203 mixture Substances 0.000 description 11
- 239000004215 Carbon black (E152) Substances 0.000 description 10
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- 229910052751 metal Inorganic materials 0.000 description 10
- 238000002485 combustion reaction Methods 0.000 description 9
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
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- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
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- 229910021389 graphene Inorganic materials 0.000 description 2
- 208000021760 high fever Diseases 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
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- 239000003345 natural gas Substances 0.000 description 2
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- VIKNJXKGJWUCNN-XGXHKTLJSA-N norethisterone Chemical compound O=C1CC[C@@H]2[C@H]3CC[C@](C)([C@](CC4)(O)C#C)[C@@H]4[C@@H]3CCC2=C1 VIKNJXKGJWUCNN-XGXHKTLJSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
- C25B11/034—Rotary electrodes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/30—Cells comprising movable electrodes, e.g. rotary electrodes; Assemblies of constructional parts thereof
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C5/00—Methods or apparatus for filling containers with liquefied, solidified, or compressed gases under pressures
- F17C5/06—Methods or apparatus for filling containers with liquefied, solidified, or compressed gases under pressures for filling with compressed gases
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
The present invention relates to a kind of gas compression system, belong to new energy field, and in particular to a kind of compressibility of hydrogen-containing gas.The present invention forms a new micel during electrolysis water ion to generation hydrogen or oxygen gas, by the unimolecule of water, hydrogen, oxygen three by molecular linkage, and the higher hydrogen molecule of activity is strapped in micel.Micel is compressed and stored.Security of the present invention is good, is easy to store, and fuel gases calorific value is high, free from environmental pollution.
Description
Technical field
The present invention relates to a kind of gas compression system, belong to new energy field, and in particular to a kind of compression of hydrogen-containing gas
System.
Background technology
The world today is still in the fossil energy economy era using oil, natural gas and coal as the leading energy.This is changed
The stone economy of energy epoch will terminate, and a unprecedented new energy revolution has begun to.Substitute the new energy of fossil energy economy
The new energy economy of economy, in other words rare-view set-up, will be " hydrogen economy ", " low-carbon economy " and its nuclear energy, solar energy, wind
The modernization of the diversification energy such as energy, water energy, biomass energy, underground heat utilizes complementary new energy economy.
Hydrogen elemental form is typically the hydrogen being made up of diatomic molecule, and hydrogen is most light gas, in zero degree and one
Under atmospheric pressure, every liter of hydrogen only has 0.09 grammes per square metre.Equivalent to the 1/14.5 of same volume air weight；Hydrogen easily burns, and is institute
There is (＜ -253 DEG C of the flash-point, it is believed that without flash-point) that flash-point is minimum in material；Hydrogen Ignition minimum energy, only 0.021mJ
(MJ)=0.005mcal (milli calorie), it is the 1/14 of gasoline ignition energy 0.30mJ；Flammable range is most in atmosphere for hydrogen
Greatly, volume content is 4%~75% (gasoline is 1.3%~7.6%)；Burning velocity is most fast in atmosphere for hydrogen, is 250cm/s
(gasoline 45cm/s)；- 252.9 DEG C of the boiling point of hydrogen, -259.1 DEG C of fusing point, close to -273 DEG C of thermodynamic temperature.Hydrogen and oxygen
The quality calorific value (low heat value) of gasification synthesis vapor is highest in all combustibles, reaches 120MJ/kg, is that gasoline is low
2.76 times of combustion value 43.5MJ/kg.Hydrogen and oxygen have many special properties, are optimal cleanings as energy fuel
The energy.
But many intractable problems be present, particularly in storage transport and secure context, also there is many technologies
Obstacle.
First, the cost of water electrolysis hydrogen production is higher.The theoretical capacity of 1kg hydrogen and 0.5kg oxygen is produced at standard conditions
For 2390 (Ah), theoretical power consumption W=I*E=2390/1000*1.23=2.95KWh (1.23V is water decomposition voltage), electricity
Solve groove actual power consumption amount and actual decomposition voltage will be bigger than theoretical value.Practical operation voltage, according to the structure of electrolytic cell and behaviour
Make situation, generally theoretical decomposition voltage 1.5-2 times.Present the mark cubic meter hydrogen of water-electrolytic hydrogen making equipment production 1 and 0.5 mark are vertical
The actual power consumption of square rice oxygen is 5KWh, more than theoretical value.It can be seen that it is higher using the cost of water electrolysis hydrogen production, from economic angle
Degree considers no cost advantage compared with other fuel.
Secondly, the security of hydrogen is poor.Due to hydrogen be a kind of highly volatile, burning, blast material, it is dangerous
Factor is also to limit the subject matter of its application, and experiment shows:(1) combustion limits of hydrogen are very wide in atmosphere, by volume
Hydrogen content reaches 4%~70% with regard to incendivity, wants wide more compared with the combustion limits 1.3%~7.6% of gasoline；(2) point
Combustion hydrogen least energy only needs 0.005mcal, and flame during combustion of hydrogen does not have color to be not easy to find；(3) High Pressure Hydrogen
Gas and low temperature liquid hydrogen are easy to reveal, higher to storage request.
As can be seen here, also there are problems in Hydrogen Energy at present in technical elements such as low cost production, safe storage transports, but
Hydrogen Energy has the advantages of prominent：First, clean environment firendly；Second, raw materials for production are extensive, the dependence for fossil energy can be broken away from,
So how safely and efficiently to prepare, accumulating and application Hydrogen Energy have turned into the world today's suddenly problem to be tackled key problems.
The content of the invention
The technical problems to be solved by the invention are to be directed to cost existing for traditional water-electrolyzing oxy
Height, the problem of security is low, its object is to provide a kind of gas-liquid to exchange uniform, gas discharge is easy, and energy consumption reduces, safety
Reliably, the hydrogen-containing gas for being easy to store and use stores and application method.The gas for compressing to obtain using the system is easy to store,
It is safe, and the fuel gases calorific value used is high, it is free from environmental pollution.
In order to solve the above problems, according to an aspect of the invention, there is provided a kind of compressibility of hydrogen-containing gas, bag
Include：Compression set, the air inlet of the compression set are connected with the hydrogen molecule restraint device equipped with ionized water；The hydrogen molecule beam
Tie up and electric rotating pole plate is provided with device, exciting device is provided with the electric rotating pole plate.
Optimization, a kind of compressibility of above-mentioned hydrogen-containing gas, the exciting device intrinsic frequency follows formula：
In formula：F is exciting device intrinsic frequency；H is exciting device thickness；L is exciting device length；E is exciting device
Modulus of elasticity；P is exciting device density.
Optimization, a kind of compressibility of above-mentioned hydrogen-containing gas, the compression set includes：Gas compression chamber, it is described
The air inlet of gas compression chamber is connected with hydrogen molecule restraint device, and its outlet is connected with holding vessel；It is provided with the holding vessel
Manometer system.
Optimization, a kind of compressibility of above-mentioned hydrogen-containing gas, the hydrogen molecule restraint device is water ion electrolysis dress
Put；The water ion electrolysis unit includes：Electrolysis unit housing, and the positive-negative electrode plate being arranged in electrolysis unit housing；
Electric rotating pole plate is provided between the positive-negative electrode plate, exciting device is provided with the electric rotating pole plate.
Optimize, a kind of compressibility of above-mentioned hydrogen-containing gas, pass through radiating tube at the top of the electrolysis unit housing
Gas-liquid separation control tank is connected, the liquids recovery outlet of the gas-liquid separation control tank passes through system pipeline and electrolysis unit housing
Inside be connected；The gas vent of the gas-liquid separation control tank is connected with fuel vapor treating device.
Optimization, a kind of compressibility of above-mentioned hydrogen-containing gas, the gas-liquid separation, which controls, is provided with low pressure limit on tank
Press table, high pressure pressure limiting table, safety valve, material adding mouth.
Optimization, a kind of compressibility of above-mentioned hydrogen-containing gas, the radiating tube is the ripple equipped with air-cooled paddle fan
Pipe.
Optimization, a kind of compressibility of above-mentioned hydrogen-containing gas, in addition to gas reformation device, the gas reformation dress
Put including：Gas reformation device tank body；Reformation liquid is filled in the gas reformation device tank body, gas is provided with the reformation liquid
Liquid switching layer；Wherein, by micel gas during use
The gas for leading to gas reformation device tank interior immerses reformation body and is exported combustion again after gas-liquid switching layer
Gas reformer tank body.
Optimization, a kind of compressibility of above-mentioned hydrogen-containing gas, the gas-liquid switching layer is corpus fibrosum and/or steel wire
Ball.
Optimization, a kind of compressibility of above-mentioned hydrogen-containing gas, the corpus fibrosum is felt, glass fibre, abnormity modeling
Expect the one or more in particle.
Therefore, compared with prior art, the present invention has advantages below：
(1) security is good：Unimolecule hydrogen or oxygen gas and hydrone be reassembled into through hydrogen bond by excitation principle new
Micel, ignition temperature belong to quick-fried contracting burning more than 3500 Celsius temperatures, and relative explosion type fires in the space of closing
Burn safety and stability；
(2) it is easy to store：Between -90 DEG C~-190 DEG C a temperature spot for new molecule is liquefied as liquid combustion simultaneously
Material；200kg/cm can be born3Pressure above simultaneously stores any change of properties does not occur for a long time；
(3) it is more environmentally-friendly：Not sulfur-bearing S and nitrogen N compositions, calorific value is up to 11000~51000 kilocalorie (Kcal/m3), relatively often
For advising fuel, energy-conservation and economy can save more than 50%, have that clean environment firendly, calorific value be high, multiduty feature.
Brief description of the drawings
Fig. 1 is high heating value combustion gas composition principle figure；
Fig. 2 is that high heating value combustion gas prepares control system；
Fig. 3 is the high heating value combustion gas preparation system schematic diagram with combustion gas compression set；
Fig. 4 is water ion electrolysis unit and compressed gas device connection diagram；
Fig. 5 is the high heating value combustion gas preparation system schematic diagram with gas reformation device；
Fig. 6 is the connection diagram of water ion electrolysis unit and gas reformation device and burner；
Fig. 7 is the schematic diagram using two direct-current generating devices and the unilateral combination of water ion electrolysis unit；
Fig. 8 is the schematic diagram using single direct-current generating device and the unilateral combination of water ion electrolysis unit；
Fig. 9 is water ion electrolysis unit schematic diagram；
Figure 10 is water ion electrolysis unit partial schematic diagram；
Figure 11-1 is the electric rotating pole plate schematic front view of water ion electrolysis unit；
Figure 11-2 is the electric rotating pole plate schematic side view of water ion electrolysis unit；
Figure 11-3 is the exciting device connection diagram of the electric rotating pole plate of water ion electrolysis unit；
Figure 12-1 is the positive-negative electrode plate schematic front view of water ion electrolysis unit；
Figure 12-2 is the positive-negative electrode plate schematic side view of water ion electrolysis unit；
Figure 13 is direct-current generating device schematic diagram；
Figure 14-1 is the rotor magnet schematic front view of direct-current generating device；
Figure 14-2 is the rotor magnet schematic side view of direct-current generating device；
Figure 15-1 is the stator metal dish schematic front view of direct-current generating device；
Figure 15-2 is the stator metal dish schematic side view of direct-current generating device；
Figure 16 is the chromatography result schematic diagram of embodiment 1；
Figure 17 is that the chromatography of embodiment 1 records.
In figure：
Direct-current generating device 1, housing 1-1, rotor magnet 1-2, stator metal dish 1-3, fixture 1-4, insulating support 1-
5；Water ion electrolysis unit 2, moving axis 2-1, insulating disc 2-2, electrolysis unit housing 2-3, electric rotating pole plate 2-4, exciting device 2-
4-1, fixing bolt 2-4-2, radiating tube 2-5, gas-liquid separation control tank 2-6, low pressure pressure limiting table 2-7, high pressure pressure limiting table 2-8, peace
Full valve 2-9, material adding mouth 2-10, gas vent 2-11, electrolyte 2-12, system pipeline 2-13, air-cooled paddle fan 2-14, it is
System circulating pump 2-15, insulation electroplax 2-16, positive-negative electrode plate 2-17, combustion gas compression set 3, manometer system 3-1, holding vessel
3-2；Motor 4；Gas reformation device 5, gas reformation device tank body 5-1, reform liquid 5-2, gas-liquid switching layer 5-3；Burner
6。
Embodiment
Below by embodiment, and with reference to accompanying drawing, technical scheme is described in further detail.
First, preparation method
As shown in figure 1, the preparation method schematic diagram for the present invention.Existing water-electrolyzing oxy is produced
Raw hydrogen or oxygen gas is the mixed gas of elementary gas, and hydrogen-oxygen elementary gas is mixed certain potential safety hazard.
The method of the present invention in electrolysis water ionization to during producing hydrogen or oxygen gas, by water, hydrogen, oxygen three
Unimolecule forms a new micel by molecular linkage, and the higher hydrogen molecule of activity is strapped in micel.Therefore, newly
Micel in hydrogen-oxygen molecular ratios it is sufficiently stable, be reduced into water during burning, belong to quick-fried contracting burning, it is quick-fried in the space of closing
The relative explosion type burning of contracting burning is foolproof.
The ignition temperature of new micel can be liquefied as liquid fuel, Ke Yicheng more than 3500 Celsius temperatures
By 200kg/cm3Any change of properties does not occur for pressure above, long-term storage.
When implementing this method, KOH, concentration 5%-30% can be selected in electrolyte, the formula of micel caused by bonding
For (H3O+-O2-OH--H2)n, wherein：1≤n≤36.
It is to include hydrocarbon C to reform liquidxH2x+2And/or hydrocarbon oxygen mixes compound CxH2x+2O reformation liquid.May be used also
To add quantum carbon element additive.Wherein, quantum carbon element be 0.3nm-1.0nm graphene liquid, the basic ginseng of quantum carbon element liquid
Number is：PH is 1.8-2.2；Electromotive force ORP is 280mv-380mv；Electrical conductivity is 1.2ms/cm-5.0ms/cm；Solid content is
0.1%-0.8%.
In this method, the exciting device intrinsic frequency for exciting follows formula：
In formula：F is exciting device (intrinsic) frequency；H is exciting device thickness mm；L is exciting device length mm；E is sharp
Vibrating device modulus of elasticity；P is exciting device density；Wherein, excited frequency adjusts between 10-3000Hz.
2nd, preparation system
The invention provides safe high fever value combustion gas preparation system.It is described in detail below.
1st, overall structure
As shown in figures 2-6, the overall structure of system includes：Direct-current generating device 1, water ion electrolysis unit 2, combustion gas compression
Device 3, gas reformation device 5.
Fig. 2 is the control system of the system.The control system is for time point, pressure, temperature, material supply, compression
Combustion gas parameter, combustion parameter etc. carry out data acquisition and carry out automatic management.
2nd, compression set
As shown in Figure 3-4, micel caused by exciting can be compressed by compression set and be stored when the system is electrolysed.Bag
Include：Manometer system 3-1, holding vessel 3-2 and the gas compression being connected with the gas vent 2-11 of water ion electrolysis unit 2
Chamber.Compressed gas system is conventional equipment, and pressure limit 20.7-24.8Mpa, holding vessel 3-2 are calibrating gas tank.
3rd, reformer
As seen in figs. 5-6, in burning, it is necessary to be reformed to micel.By gas after reformer tank body 5-1
Burnt into burner 6, the burner 6 is conventional equipment.
It can be reformed using multiple reformers 5.It is provided with reformer tank body 5-1 and reforms liquid 5-2 and gas-liquid
Switching layer 5-3.It is hydrocarbon to reform liquid 5-2.Gas-liquid switching layer 5-3 is corpus fibrosum, such as felt, glass fibre, abnormity
Plastic grain；Steel wire lump can also be used as gas-liquid switching layer 5-3.The gas led to inside reformer exchanges by gas-liquid
It is exported again after layer.
It is to include hydrocarbon C to reform liquid 5-2xH2x+2And/or hydrocarbon oxygen mixes compound CxH2x+2O reformation liquid.Also
0.1%-1.0% quantum carbon element additive can be added.Wherein, quantum carbon element be 0.3nm-1.0nm graphene liquid, quantum
The basic parameter of carbon liquid is：PH is 1.8-2.2；Electromotive force ORP is 280mv-380mv；Electrical conductivity is 1.2ms/cm-5.0ms/
cm；Solid content is 0.1%-0.8%.
Gas after reformation includes CxH2x+2Gas, wherein, 15>x>0.Specifically include following volume constituents:
H2：20%~60%；O2：10%~30%；CnH2n+2(5>n≧1)：15%~30%；CnH2n+2(n≧6)：5%
~25%.
High heating value combustion gas not sulfur-bearing S and nitrogen N compositions prepared by the technical solution adopted in the present invention, calorific value is up to 11000
~51000 kilocalorie Kcal/m3。
4th, electrolysis unit
As Figure 7-8, in electrolysis, the present embodiment can be electrolysed using two direct-current generating devices 1, such as Fig. 7
It is shown；It can also be electrolysed using single direct-current generating device 1, as shown in Figure 8.Both select according to operating mode.
Water ion electrolysis unit is as shown in figs9-12.Water ion electrolysis unit 2 includes moving axis 2-1, insulating disc 2-2, housing
2-3, electric rotating pole plate 2-4, exciting device 2-4-1, radiating tube 2-5 are at least one set of or multigroup, gas-liquid separation controls tank 2-6, low
Pressure pressure limiting table 2-7, high pressure pressure limiting table 2-8, safety valve 2-9, material adding mouth 2-10, gas vent 2-11, electrolyte 2-12, it is
Road 2-13 under the overall leadership, air-cooled paddle fan 2-14, system circulation pump 2-15, positive-negative electrode plate 2-17.
Wherein, insulating disc 2-2 is arranged at both sides inside housing 2-3；Positive-negative electrode plate 2- is set respectively on the inside of insulating disc 2-2
17.Electric rotating pole plate 2-4 is arranged between two pieces of positive-negative electrode plate 2-17 by moving axis 2-1.
Wherein, electric rotating pole plate 2-4 is at least a piece of, and electrode group, every interval 1-10mm can also be made up of multi-disc.Often
Piece electric rotating pole plate 2-4 devices have several exciting devices 2-4-1, exciting device 2-4-1 to pass through fixing bolt 2-4-2
It is fixed on electric rotating pole plate 2-4.
Electric rotating pole plate 2-4 is rotated in electrolyte 2-12 with a fixed angular speed, and in positive-negative electrode plate 2-17 electrode
In the presence of power supply DC+ and DC-, hydro-electrolytic hydroxide gas is produced.
Electric rotating pole plate 2-4 drives exciting device 2-4-1 to produce exciting in rotation, and exciting device intrinsic frequency follows public affairs
Formula：
In formula：F is exciting device intrinsic frequency；H is exciting device thickness mm；L is exciting device length mm；E is exciting
Device elastic modulus G Pa；P exciting device density g/cm3；Excited frequency adjusts between 10-3000Hz.On exciting device just
Hydrogen and oxygen electrolyzing gas caused by negative pole caused unimolecule hydrogen or oxygen gas and hydrone, passes through in the presence of excited frequency
Hydrogen bond is reassembled into new micel.Exciting device 2-4-1 in the present invention can select exciting piece.
New micel and electrolyte reach gas-liquid separation control tank 2-6 by radiating tube 2-5 and carry out gas-liquid separation, separation
Gas afterwards is responsible for keeping pressure in 0.01- by exporting 2-11 outputs, low pressure pressure limiting table 2-7 and high pressure pressure limiting table 2-8
Run between 1.0Mpa, material adding mouth 2-10 is responsible for adding replenisher and additive, and safety valve 2-9 is controlled in 1.5-
2.0Mpa, pipeline 2-13 are system automatic cycle pipeline, can open the circulation pump 2-15 according to working conditions such as temperature controls.
5th, TRT
As illustrated in figs. 13-15, it includes direct-current generating device：It is housing 1-1, rotor magnet 1-2, stator metal dish 1-3, solid
Determine part 1-4, insulator support 1-5, motor 4.The guide line connection of metal dish top is DC-, metal dish central shaft guided bone couples
Formed for DC+.Rotor magnet disk 1-2 is conducting metal disk, and metal can be copper and copper alloy either conducting metal, extremely
One or more pieces few compositions；Rotor magnet 1-2 is high magnetic flux magnet, magnetic flux between 0.5-1.2T teslas, two panels it
Between at least accompany one or more pieces stator metal dish 1-3 composition.
Frequency modulation motor 4 provides the kinetic energy of certain rotating speed, and being converted to specified DC electrolysis power supply by direct-current generating device 1 supplies
Feed water ion electrolysis unit 2.
6th, implementation result
High heating value combustion gas prepared by the technical solution adopted in the present invention belongs to quick-fried contracting burning, the quick-fried contracting in the space of closing
The relative explosion type burning of burning is fool proof, and the property for the safety and stability having is better than other exchangeabilities；New micel exists
One temperature spot is liquefied as liquid fuel simultaneously；Ignition temperature is more than 3500 Celsius temperatures；200kg/cm can be born3More than
Pressure simultaneously stores any change of properties does not occur for a long time.
High heating value combustion gas and other conventional fuels prepared by the technical solution adopted in the present invention are compared as follows：
Table 1- reformed gas are compared with the calorific value and CO2 emissions of different fuel
| Fuel type | Quantity KG | Calorific value Kcal | CO2CER % |
| LPG | 1 | 11000 | 20 |
| Heavy oil | 1 | 10000 | 75 |
| Diesel oil | 1 | 9600 | 60 |
| Coal | 1 | 5000 | 90 |
| Electric energy | 1KW | 860 | Conversion |
| Natural gas | 1 | 8000 | 20 |
| The present invention reforms gas | 1 | 11000-51000 | Less than 5% |
Below can excessively several embodiments beneficial effects of the present invention are verified.
Embodiment 1
The electron ion of water：The H ionized out3O++HO-Proton hydrate and hydroxide ion
Compounding substances combined reformation with hydrocarbon alkane.
Electrolyte 2-12 is 5%-30% from KOH concentration, from 15%.Reforming liquid 2-21 and selecting includes C1-C5 alcohol alkane
Mixture.
The hydrocarbon structure molecular gas composition prepared by method in the present embodiment 1 is detected and analyzed, its chromatogram point
It is as shown in figure 16 to analyse result；Chromatography record is as shown in figure 17.Detection and analysis result show that gas is by a variety of hydrocarbon structures
Composition, calorific value ＞ 12000Kcal/m3。
Embodiment 2
The electron ion of water：The H ionized out3O++HO-Proton hydrate and hydroxide ion
Compounding substances combined reformation with hydrocarbon alkane.
Electrolyte 2-12 is 5%-30% from KOH concentration, from 20%.It is hydrocarbon to reform liquid 2-21, is selected
C3-C8 paraffins mixtures.
Hydrocarbon structure molecular gas composition is as shown in the table before and after reformation.It is same as can be seen from the table, more components
Hydrocarbon structure calorific value ＞ 30000Kcal/m3.
Hydrocarbon structure molecular gas constituent analysis table before and after table 2- is reformed
Embodiment 3
The electron ion of water：The H ionized out3O++HO-Proton hydrate and hydroxide ion
Compounding substances combined reformation with hydrocarbon alkane.
Electrolyte 2-12 is 5%-30% from KOH concentration, from 30%.It is hydrocarbon to reform liquid 2-21, is selected
C5-C12 alcohol alkane mixtures.The hydrocarbon structure calorific value ＞ 50000Kcal/m of more components3。
Example shows, safe high fever value combustion gas of the invention is clean energy resource, and existing any conventional fuel compares all
There is very outstanding effects of energy saving and emission reduction.It was found from actual achievement of burning, for relatively conventional fuel, energy-conservation and economy can save
More than 50%；The effectively discharge of the pernicious gas such as control NOX, SOX, CO2, burning and exhausting can emission reduction more than 60%.The present invention
The example above is not limited to, is applicable to all applications of combustion field.Such as, conventional commercial burning；Fuel under high pressure storage tank；Liquefaction accumulating
Etc..
Embodiment above is only that the preferred embodiment of the present invention is described, and not the scope of the present invention is entered
Row limits, and on the premise of design spirit of the present invention is not departed from, those of ordinary skill in the art do to technical scheme
The various modifications gone out and improvement, it all should fall into the protection domain of claims of the present invention determination.
Specific embodiment described herein is only to spirit explanation for example of the invention.Technology belonging to the present invention is led
The technical staff in domain can be made various modifications or supplement to described specific embodiment or be replaced using similar mode
Generation, but without departing from the spiritual of the present invention or surmount scope defined in appended claims.
Claims (9)
1. a kind of compressibility of hydrogen-containing gas, including：Compression set, it is characterised in that the air inlet of the compression set with
Hydrogen molecule restraint device equipped with ionized water is connected；Electric rotating pole plate, the rotation are provided with the hydrogen molecule restraint device
Exciting device is provided with battery lead plate；Wherein, the exciting device intrinsic frequency follows formula：
<mrow>
<mi>f</mi>
<mo>=</mo>
<mfrac>
<mrow>
<mn>0.162</mn>
<mi>h</mi>
</mrow>
<msup>
<mi>L</mi>
<mn>2</mn>
</msup>
</mfrac>
<msqrt>
<mfrac>
<mi>E</mi>
<mi>P</mi>
</mfrac>
</msqrt>
</mrow>
In formula：F is exciting device intrinsic frequency；H is exciting device thickness；L is exciting device length；E is exciting device elasticity
Modulus；P is exciting device density.
2. the compressibility of a kind of hydrogen-containing gas according to claim 1, it is characterised in that the compression set includes：
Gas compression chamber, the air inlet of the gas compression chamber are connected with hydrogen molecule restraint device, and it is exported and holding vessel (3-2) phase
Even；Manometer system (3-1) is provided with the holding vessel (3-2).
A kind of 3. compressibility of hydrogen-containing gas according to claim 1, it is characterised in that the hydrogen molecule restraint device
For water ion electrolysis unit (2)；The water ion electrolysis unit (2) includes：Electrolysis unit housing (2-3), and it is arranged on electricity
Solve the positive-negative electrode plate (2-17) in device case (2-3)；Electric rotating pole plate is provided between the positive-negative electrode plate (2-17)
(2-4), exciting device (2-4-1) is provided with the electric rotating pole plate (2-4).
A kind of 4. compressibility of hydrogen-containing gas according to claim 3, it is characterised in that the electrolysis unit housing
The top of (2-3) connects gas-liquid separation by radiating tube (2-5) and controls tank (2-6), the liquid of the gas-liquid separation control tank (2-6)
Body recovery outlet is connected by system pipeline (2-13) with the inside of electrolysis unit housing (2-3)；The gas-liquid separation controls tank
The gas vent (2-11) of (2-6) is connected with fuel vapor treating device.
5. the compressibility of a kind of hydrogen-containing gas according to claim 4, it is characterised in that the gas-liquid separation controls tank
Low pressure pressure limiting table (2-7), high pressure pressure limiting table (2-8), safety valve (2-9), material adding mouth (2-10) are provided with (2-6).
6. the compressibility of a kind of hydrogen-containing gas according to claim 4, it is characterised in that the radiating tube (2-5) is
Bellows equipped with air-cooled paddle fan (2-14).
7. the compressibility of a kind of hydrogen-containing gas according to claim 1, it is characterised in that also filled including gas reformation
Put, the gas reformation device includes：Gas reformation device tank body (5-1)；Filled in the gas reformation device tank body (5-1)
Liquid (5-2) is reformed, gas-liquid switching layer (5-3) is provided with the reformation liquid (5-2)；Wherein, micel gas is led to during use
The gas internal to gas reformation device tank body (5-1), which immerses, to be reformed body (5-2) and is led again after gas-liquid switching layer (5-3)
Go out gas reformation device tank body (5-1).
A kind of 8. compressibility of hydrogen-containing gas according to claim 7, it is characterised in that the gas-liquid switching layer (5-
3) it is corpus fibrosum and/or steel wire lump.
A kind of 9. compressibility of hydrogen-containing gas according to claim 8, it is characterised in that the corpus fibrosum be felt,
One or more in glass fibre.
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| CN201610639889.7A CN106048644B (en) | 2016-08-07 | 2016-08-07 | A kind of compressibility of hydrogen-containing gas |
| KR1020197002387A KR20190021414A (en) | 2016-08-07 | 2016-08-09 | Method and system for producing safe, high calorific fuel gas |
| US16/323,729 US20190177628A1 (en) | 2016-08-07 | 2016-08-09 | Method and system for preparing fuel gas with high heat value and safety |
| PCT/CN2016/094187 WO2018027565A1 (en) | 2016-08-07 | 2016-08-09 | Method and system for preparing safe high heating value fuel gas |
| JP2019526352A JP2019528365A (en) | 2016-08-07 | 2016-08-09 | Safe high calorific fuel gas production method and system |
| EP16912020.1A EP3495457A4 (en) | 2016-08-07 | 2016-08-09 | Method and system for preparing safe high heating value fuel gas |
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| US4265721A (en) * | 1980-05-05 | 1981-05-05 | Hackmyer Saul A | Commercial hydrogen gas production by electrolysis of water while being subjected to microwave energy |
| CN101970724A (en) * | 2007-05-31 | 2011-02-09 | 罗托布斯特联合股份有限公司 | Device and method for production of hydrogen |
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