CN106048302B - A kind of founding materials for being applied to nuclear power and wind-powered electricity generation and preparation method thereof - Google Patents
A kind of founding materials for being applied to nuclear power and wind-powered electricity generation and preparation method thereof Download PDFInfo
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- CN106048302B CN106048302B CN201610647408.7A CN201610647408A CN106048302B CN 106048302 B CN106048302 B CN 106048302B CN 201610647408 A CN201610647408 A CN 201610647408A CN 106048302 B CN106048302 B CN 106048302B
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- 239000000463 material Substances 0.000 title claims abstract description 41
- 230000005611 electricity Effects 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims description 7
- 239000000956 alloy Substances 0.000 claims abstract description 27
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 24
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 21
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 13
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052746 lanthanum Inorganic materials 0.000 claims abstract description 13
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims abstract description 13
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 12
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 12
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004411 aluminium Substances 0.000 claims abstract description 12
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052802 copper Inorganic materials 0.000 claims abstract description 12
- 239000010949 copper Substances 0.000 claims abstract description 12
- 229910052742 iron Inorganic materials 0.000 claims abstract description 12
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 12
- 239000011572 manganese Substances 0.000 claims abstract description 12
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 12
- 239000002245 particle Substances 0.000 claims abstract description 12
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 12
- 239000011701 zinc Substances 0.000 claims abstract description 12
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 9
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 7
- 239000000919 ceramic Substances 0.000 claims abstract description 6
- 238000005266 casting Methods 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 8
- 230000003068 static effect Effects 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 239000006229 carbon black Substances 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 239000000498 cooling water Substances 0.000 claims description 3
- 238000001514 detection method Methods 0.000 claims description 3
- 238000004033 diameter control Methods 0.000 claims description 3
- 238000007710 freezing Methods 0.000 claims description 3
- 230000008014 freezing Effects 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 239000010687 lubricating oil Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 238000004806 packaging method and process Methods 0.000 claims description 3
- 239000002893 slag Substances 0.000 claims description 3
- 238000003860 storage Methods 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims 1
- 239000000155 melt Substances 0.000 claims 1
- 229910000906 Bronze Inorganic materials 0.000 abstract description 5
- 239000010974 bronze Substances 0.000 abstract description 5
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 abstract description 5
- 238000007670 refining Methods 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000005242 forging Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/06—Alloys based on copper with nickel or cobalt as the next major constituent
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Powder Metallurgy (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
Abstract
The invention discloses a kind of method applied to nuclear power and the founding materials of wind-powered electricity generation is prepared, it is comprised the following steps:By mass percentage, by aluminium:5~7%, iron:2~4%, manganese:0~1.2%, nickel:10~12%, zinc:0.5~2%, copper surplus are placed in main frequency furnace, are heated to 1150 degree and are completely melt rear and are incubated;Nuclear power provided by the invention, wind-powered electricity generation wearing piece material, titanium carbide ceramic particle is added in traditional bronze material, to improve the hardness of cast alloy materials;And the appropriate corresponding rare-earth elements of lanthanum of addition or cerium, for further refining, improving the footpath grain institutional framework of alloy internal material, so that material is on the premise of it further need not forge or be heat-treated, the intensity and hardness of alloy material can be achieved, further meet the requirement of nuclear power, wind-powered electricity generation wearing piece material.
Description
Technical field
The present invention relates to field of alloy material, more particularly to a kind of founding materials and its making applied to nuclear power and wind-powered electricity generation
Method.
Background technology
Bronze material has a performances such as good ductility and malleability, therefore it using relatively broad, it is mainly applied
In the technical field of steam turbine in nuclear power and wind-powered electricity generation, it is particularly used for forging all kinds of valve blocks of shaping, abrasion resisting pump block.But
With greatly developing for Nuclear Power Industry, the market demand is more, more excellent material, due to forging the defects of processing produces so that mesh
Bronze ingot used in preceding can not increasingly meet the needs of domestic and international high standard pump valve class alloy pig.Further, since in material
The reason for portion's structure, by the bronze material of foundry casting, easily produce pore surfaces and be mingled with, be not easy post forming.
The content of the invention
In order to solve the above problems, it is applied to nuclear power and the founding materials of wind-powered electricity generation and its making side the invention provides a kind of
Method, can either improve the intensity and hardness of material, and can enough avoid founding materials because forge and caused by ftracture situation, reduce
Material caused porosity in casting process.
In order to achieve the above object, the technical solution adopted by the present invention is as follows:
A kind of method applied to nuclear power and the founding materials of wind-powered electricity generation is prepared, it is comprised the following steps:
1), by mass percentage, by aluminium:5~7%, iron:2~4%, manganese:0~1.2%, nickel:10~12%, zinc:
0.5~2%, copper:Surplus is placed in main frequency furnace, is heated to 1150 degree and is completely melt rear and is incubated;
2), by mass percentage, by rare-earth elements of lanthanum or cerium:0.05~0.2%, it is molten to be added to the alloy being incubated
Among liquid, open vibrating device and agitating device, vibrating device vibration frequency are:15 times/second, agitating device stir speed (S.S.) are:
150 revs/min, mixing time is:10~15 minutes;
3), according to mass percent meter, by titanium carbide granule of the particle diameter less than 50 microns:9~11%, it is molten to be added to alloy
Among liquid, while it is again stirring for, stir speed (S.S.) is 350 revs/min, mixing time 10~15 minutes;
4), the alloy solution for stirring completion is transferred among cast insulation stove, is stirred for the third time, mixing time is
5~10 minutes, speed was 450 revs/min;
5), static 3~5 minutes of the alloy solution completed will be stirred, and samples detection, it has been determined that composition setting range it
It is interior;After composition is qualified, melt is directly introduced by crystallizer using mozzle, coating lubricating oil in crystallizer, covering 3 in burner hearth~
Chance of the carbon black of 5 cm thicks to reduce oxidation and give birth to slag;
6), cast with horizontal casting method, alloy pig external diameter is 200 millimeters, and casting speed is 3 ms/h, selective freezing device
It highly it is 200 millimeters, cooling water pressure is 0.2 megapascal (MPa), and dummy ingot temperature control is 1100~1150 degree;
7), during horizontal casting, the distance between graphite cannula bottom cylindrical and crystallizer wall are about 10~15 millimeters, this
Open metal bath surface enters crystallizer in the case where keeping under certain static pressure, and ingot casting surface is into microwave wave-like, but than relatively round
Sliding, extrusion ingot length is 2000 millimeters/;
8) length that long material alloy pig sawing is 500 millimeters/, glazing ingot machine, are removed into surface scale and all kinds of folders
Debris, external diameter control are 195 millimeters, and tolerance is +/- 0.5 millimeter, packaging and storage.
Further, the mass percent of each component in step 1) is:Aluminium:6%, iron:2.5%, manganese:0.6%, nickel:
10.8%, zinc:0.8%, copper:Surplus, the mass percent of lanthanum or cerium in step 2) are:0.09%, the carbonization in step 3)
The mass percent of titanium particle is:9.5%.
Further, the mass percent of each component in step 1) is:Aluminium:6.5%, iron:3%, manganese:0.9%, nickel:
11.2%, zinc:1.2%, copper:Surplus, the mass percent of lanthanum or cerium in step 2) are:0.1%, the titanium carbide in step 3)
The mass percent of particle is:10%.
Further, the mass percent of each component in step 1) is:Aluminium:6.8%, iron:3.5%, manganese:1.1%,
Nickel:11.8%, zinc:1.8%, copper:Surplus, the mass percent of lanthanum or cerium in step 2) are:0.18%, the carbon in step 3)
Change titanium particle mass percent be:10.5%.
Present invention also offers a kind of founding materials applied to nuclear power and wind-powered electricity generation, the material using foregoing method come
Prepare.
Beneficial effects of the present invention are:Nuclear power provided by the invention, wind-powered electricity generation wearing piece material, in traditional bronze material
Titanium carbide ceramic particle is added, to improve the hardness of cast alloy materials;And the appropriate corresponding rare-earth elements of lanthanum of addition or
Cerium, for further refining, improving the footpath grain institutional framework of alloy internal material, so that material need not forged further
Or on the premise of heat treatment, you can realize the intensity and hardness of alloy material, further meet nuclear power, wind-powered electricity generation wearing piece material
The requirement of material.It also avoid simultaneously original alloy material because forge and caused by ftracture situation, further reduce material and casting
The caused porosity during making, so as to save production cost, improves production efficiency.
Embodiment
Below in conjunction with embodiments of the invention, the technical scheme in the embodiment of the present invention is clearly and completely retouched
State, it is clear that described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.Based on the present invention
In embodiment, the every other implementation that those of ordinary skill in the art are obtained under the premise of creative work is not made
Example, belongs to the scope of protection of the invention.
Embodiment 1
A kind of preparation method applied to nuclear power and the founding materials of wind-powered electricity generation, it comprises the following steps:
1), according to proportioning by aluminium:6%th, iron:2.5%th, manganese:0.6%th, nickel:10.8%th, zinc:0.8%th, copper:The matter of surplus
Percentage is measured, raw material is configured, is placed in main frequency furnace, 1150 degree is heated to and is completely melt rear and is incubated;
2), by rare-earth elements of lanthanum or cerium:0.09%, by percentage to the quality, it is added to the alloy solution being incubated and works as
In, open vibrating device and agitating device, vibrating device vibration frequency are:15 times/second, agitating device stir speed (S.S.) are:150
Rev/min, mixing time is:10~15 minutes;
3), particle diameter is less than to 50 microns of titanium carbide:9.5%, by percentage to the quality, it is added among alloy solution,
It is again stirring for simultaneously, stir speed (S.S.) is 350 revs/min, mixing time 10~15 minutes;
4), the alloy solution for stirring completion is transferred among cast insulation stove, is stirred for the third time, mixing time is
5~10 minutes, speed was 450 revs/min;
5), static 3~5 minutes of the alloy solution completed will be stirred, and samples detection, with ensure composition setting range it
It is interior;After composition is qualified, melt is directly introduced by crystallizer using mozzle, coating lubricating oil in crystallizer, covering 3 in burner hearth~
Chance of the carbon black of 5 cm thicks to reduce oxidation and give birth to slag;
6), cast with horizontal casting method, alloy pig external diameter is 200 millimeters, and casting speed is 3 ms/h, selective freezing device
It highly it is 200 millimeters, cooling water pressure is 0.2 megapascal (MPa), and dummy ingot temperature control is 1100~1150 degree;
7), during horizontal casting, the distance between graphite cannula bottom cylindrical and crystallizer wall are about 10~15 millimeters, this
Open metal bath surface enters crystallizer in the case where keeping under certain static pressure, and ingot casting surface is into microwave wave-like, but than relatively round
Sliding, extrusion ingot length is 2000 millimeters/;
8) length that long material alloy pig sawing is 500 millimeters/, glazing ingot machine, are removed into surface scale and all kinds of folders
Debris, external diameter control are 195 millimeters, and tolerance is +/- 0.5 millimeter, packaging and storage.
Embodiment 2
Embodiment 2 is only different in terms of raw material proportioning from embodiment 1, and other aspects are identicals.Therefore, below
Only it will be illustrated with regard to difference.
The percentage of each composition in step 1) is:Aluminium:6.5%th, iron:3%th, manganese:0.9%th, nickel:11.2%th, zinc:
1.2%th, copper:Surplus.
The mass percent of rare-earth elements of lanthanum or cerium in step 2) is:0.1%.
The mass percent of titanium carbide in step 3) is:10%.
According to the present embodiment 2, effect substantially the same manner as Example 1 can be played.
Embodiment 3
Embodiment 3 is only different in terms of raw material proportioning from Examples 1 and 2, and other aspects are identicals.Therefore,
Only it will be illustrated below with regard to difference.
The percentage of each composition in step 1) is:Aluminium:6.8%th, iron:3.5%th, manganese:1.1%th, nickel:11.8%th, zinc:
1.8%th, copper:Surplus.
The mass percent of rare-earth elements of lanthanum or cerium in step 2) is:0.18%.
The mass percent of titanium carbide in step 3) is:10.5%.
According to the present embodiment 3, the effect essentially identical with Examples 1 and 2 can be played.
Material experiment data performance contrast table:
As can be known from the above table, the material cast by the present invention, the hardness of material is improved, reduces the stomata of material
Rate.
Embodiment described above only expresses embodiments of the present invention, and its description is more specific and detailed, but can not
Therefore it is interpreted as the limitation to the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art,
Without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection model of the present invention
Enclose.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (5)
- A kind of 1. preparation method applied to nuclear power and the founding materials of wind-powered electricity generation, it is characterised in that:It is comprised the following steps:1), by mass percentage, by aluminium:5~7%, iron:2~4%, manganese:0~1.2%, nickel:10~12%, zinc:0.5~ 2%, copper:Surplus is placed in main frequency furnace, is heated to 1150 degree and is completely melt rear and is incubated;2), by mass percentage, by rare-earth elements of lanthanum or cerium:0.05~0.2%, it is added to the alloy molten solution being incubated It is central, open vibrating device and agitating device, vibrating device vibration frequency are:15 times/second, agitating device stir speed (S.S.) are:150 Rev/min, mixing time is:10~15 minutes;3), according to mass percent meter, by titanium carbide ceramic particle of the particle diameter less than 50 microns:9~11%, it is added to alloy and melts Among liquid, while it is again stirring for, stir speed (S.S.) is 350 revs/min, mixing time 10~15 minutes;4), by stir complete alloy molten solution be transferred among cast insulation stove, be stirred for the third time, mixing time be 5~ 10 minutes, speed was 450 revs/min;5), static 3~5 minutes of the alloy molten solution for completing stirring, and sample detection, it has been determined that composition is within setting range; After composition is qualified, melt is directly introduced by crystallizer using mozzle, coating lubricating oil in crystallizer, 3~5 lis of covering in burner hearth Chance of the meter Hou Du carbon black to reduce oxidation and give birth to slag;6), cast with horizontal casting method, alloy pig external diameter is 200 millimeters, and casting speed is 3 ms/h, selective freezing device height For 200 millimeters, cooling water pressure is 0.2 megapascal (MPa), and dummy ingot temperature control is 1100~1150 degree;7), during horizontal casting, the distance between graphite cannula bottom cylindrical and crystallizer wall are about 10~15 millimeters, and this is open Metal bath surface enters crystallizer in the case where keeping under certain static pressure, and ingot casting surface is but rounder and more smooth into microwave wave-like, casts Ingot length is 2000 millimeters/;8) length that long material alloy pig sawing is 500 millimeters/, glazing ingot machine, are removed into surface scale and each type impurity, External diameter control is 195 millimeters, and tolerance is +/- 0.5 millimeter, packaging and storage.
- 2. the preparation method according to claim 1 applied to nuclear power and the founding materials of wind-powered electricity generation, it is characterised in that:Step 1) mass percent of each component in is:Aluminium:6%, iron:2.5%, manganese:0.6%, nickel:10.8%, zinc:0.8%, copper:It is remaining Measure, the mass percent of lanthanum or cerium in step 2) is:0.09%, the mass percent of the titanium carbide ceramic particle in step 3) For:9.5%.
- 3. the preparation method according to claim 1 applied to nuclear power and the founding materials of wind-powered electricity generation, it is characterised in that:Step 1) mass percent of each component in is:Aluminium:6.5%, iron:3%, manganese:0.9%, nickel:11.2%, zinc:1.2%, copper:It is remaining Measure, the mass percent of lanthanum or cerium in step 2) is:0.1%, the mass percent of the titanium carbide ceramic particle in step 3) For:10%.
- 4. the preparation method according to claim 1 applied to nuclear power and the founding materials of wind-powered electricity generation, it is characterised in that:Step 1) mass percent of each component in is:Aluminium:6.8%, iron:3.5%, manganese:1.1%, nickel:11.8%, zinc:1.8%, copper: Surplus, the mass percent of lanthanum or cerium in step 2) are:0.18%, the quality percentage of the titanium carbide ceramic particle in step 3) Number is:10.5%.
- It is 5. a kind of applied to nuclear power and the founding materials of wind-powered electricity generation, it is characterised in that:The material uses any in claim 1-4 It is prepared by the method described in.
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CN201610647408.7A CN106048302B (en) | 2016-08-09 | 2016-08-09 | A kind of founding materials for being applied to nuclear power and wind-powered electricity generation and preparation method thereof |
PCT/CN2016/108069 WO2018028089A1 (en) | 2016-08-09 | 2016-11-30 | Casting material for nuclear power and wind power and manufacturing method therefor |
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CN106048302B (en) * | 2016-08-09 | 2018-01-02 | 苏州天兼新材料科技有限公司 | A kind of founding materials for being applied to nuclear power and wind-powered electricity generation and preparation method thereof |
CN106636728A (en) * | 2016-12-19 | 2017-05-10 | 苏州天兼新材料科技有限公司 | Cast bronze alloy material and preparation method thereof |
CN108559868A (en) * | 2018-05-30 | 2018-09-21 | 苏州金仓合金新材料有限公司 | A kind of cast alloy materials and preparation method thereof for electric machinery wearing piece |
CN114990369B (en) * | 2022-07-28 | 2022-11-18 | 鼎镁新材料科技股份有限公司 | Method for preparing aluminum alloy bicycle rim from secondary aluminum |
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JPS63274729A (en) * | 1987-04-30 | 1988-11-11 | Furukawa Electric Co Ltd:The | Copper alloy for electronic and electrical appliance |
JPH0830234B2 (en) * | 1987-07-24 | 1996-03-27 | 古河電気工業株式会社 | High strength and high conductivity copper alloy |
JPH0959730A (en) * | 1995-08-21 | 1997-03-04 | Mitatsukusu:Kk | Copper alloy for heat resistant metal mold such as metal mold for glass forming |
CN1300355C (en) * | 2003-12-16 | 2007-02-14 | 兰州理工大学 | Aluminium and bronze alloy and process for preparing same |
JP4472979B2 (en) * | 2003-12-17 | 2010-06-02 | トヨタ自動車株式会社 | Wear-resistant copper-based alloy for overlaying |
JP4538813B2 (en) * | 2006-05-29 | 2010-09-08 | Dowaホールディングス株式会社 | Connector and charging socket using copper-based alloy material |
CN101643867B (en) * | 2009-08-28 | 2011-11-23 | 镇江汇通金属成型有限公司 | High-performance casting copper alloy and preparation method thereof |
CN102628118B (en) * | 2012-04-25 | 2013-11-27 | 苏州金仓合金新材料有限公司 | Wrought alloy pig for nuclear steam turbine and manufacturing method thereof |
CN102994801A (en) * | 2012-11-26 | 2013-03-27 | 中国铝业股份有限公司 | Alloy material applicable to inert anode of metal molten salt electrolytic cell |
CN105039779A (en) * | 2015-07-06 | 2015-11-11 | 浙江海帆机械有限公司 | Nickel-copper alloy and preparation process for same |
CN105177348A (en) * | 2015-10-30 | 2015-12-23 | 苏州列治埃盟新材料技术转移有限公司 | High-strength titanium carbide copper-based composite material and preparation method thereof |
CN106048302B (en) * | 2016-08-09 | 2018-01-02 | 苏州天兼新材料科技有限公司 | A kind of founding materials for being applied to nuclear power and wind-powered electricity generation and preparation method thereof |
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