CN106046656A - High-power light-stabilized cable material and preparation method thereof - Google Patents
High-power light-stabilized cable material and preparation method thereof Download PDFInfo
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- CN106046656A CN106046656A CN201610503895.XA CN201610503895A CN106046656A CN 106046656 A CN106046656 A CN 106046656A CN 201610503895 A CN201610503895 A CN 201610503895A CN 106046656 A CN106046656 A CN 106046656A
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- 239000000463 material Substances 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000000843 powder Substances 0.000 claims abstract description 22
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims abstract description 14
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000945 filler Substances 0.000 claims abstract description 13
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 7
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 7
- 229940120693 copper naphthenate Drugs 0.000 claims abstract description 7
- SEVNKWFHTNVOLD-UHFFFAOYSA-L copper;3-(4-ethylcyclohexyl)propanoate;3-(3-ethylcyclopentyl)propanoate Chemical compound [Cu+2].CCC1CCC(CCC([O-])=O)C1.CCC1CCC(CCC([O-])=O)CC1 SEVNKWFHTNVOLD-UHFFFAOYSA-L 0.000 claims abstract description 7
- 239000003292 glue Substances 0.000 claims abstract description 7
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 7
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 7
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 229920005989 resin Polymers 0.000 claims abstract description 7
- 239000011347 resin Substances 0.000 claims abstract description 7
- 239000005058 Isophorone diisocyanate Substances 0.000 claims abstract description 6
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 6
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims abstract description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000008117 stearic acid Substances 0.000 claims abstract description 6
- IUTYMBRQELGIRS-UHFFFAOYSA-N boric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OB(O)O.NC1=NC(N)=NC(N)=N1 IUTYMBRQELGIRS-UHFFFAOYSA-N 0.000 claims abstract description 4
- -1 polyethylene Polymers 0.000 claims abstract description 4
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 7
- LBBOQIHGWMYDPM-UHFFFAOYSA-N 2-tert-butylphenol;formaldehyde Chemical compound O=C.CC(C)(C)C1=CC=CC=C1O LBBOQIHGWMYDPM-UHFFFAOYSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 6
- BAECOWNUKCLBPZ-HIUWNOOHSA-N Triolein Natural products O([C@H](OCC(=O)CCCCCCC/C=C\CCCCCCCC)COC(=O)CCCCCCC/C=C\CCCCCCCC)C(=O)CCCCCCC/C=C\CCCCCCCC BAECOWNUKCLBPZ-HIUWNOOHSA-N 0.000 claims description 6
- PHYFQTYBJUILEZ-UHFFFAOYSA-N Trioleoylglycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC PHYFQTYBJUILEZ-UHFFFAOYSA-N 0.000 claims description 6
- 229940106691 bisphenol a Drugs 0.000 claims description 6
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 claims description 6
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 6
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 claims description 6
- 239000000230 xanthan gum Substances 0.000 claims description 6
- 229920001285 xanthan gum Polymers 0.000 claims description 6
- 229940082509 xanthan gum Drugs 0.000 claims description 6
- 235000010493 xanthan gum Nutrition 0.000 claims description 6
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 6
- MSAVICZWFPQFPO-UHFFFAOYSA-N acetic acid;ethene Chemical group C=C.C=C.CC(O)=O MSAVICZWFPQFPO-UHFFFAOYSA-N 0.000 claims description 5
- 229920001038 ethylene copolymer Polymers 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- AJSHDAOMUKXVDC-UHFFFAOYSA-N butan-1-amine;sulfuric acid Chemical compound CCCC[NH3+].OS([O-])(=O)=O AJSHDAOMUKXVDC-UHFFFAOYSA-N 0.000 claims description 4
- SHFJWMWCIHQNCP-UHFFFAOYSA-M hydron;tetrabutylazanium;sulfate Chemical compound OS([O-])(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC SHFJWMWCIHQNCP-UHFFFAOYSA-M 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000007885 magnetic separation Methods 0.000 claims description 3
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- 238000005453 pelletization Methods 0.000 claims description 3
- 238000004537 pulping Methods 0.000 claims description 3
- 238000012216 screening Methods 0.000 claims description 3
- 238000004073 vulcanization Methods 0.000 claims description 3
- XVVZSEXTAACTPS-UHFFFAOYSA-N 5-[hydroxy-(4-nitrophenoxy)phosphoryl]pentanoic acid Chemical compound OC(=O)CCCCP(O)(=O)OC1=CC=C([N+]([O-])=O)C=C1 XVVZSEXTAACTPS-UHFFFAOYSA-N 0.000 claims description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004327 boric acid Substances 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 claims 3
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims 3
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 claims 1
- 229940116364 hard fat Drugs 0.000 claims 1
- 239000012948 isocyanate Substances 0.000 claims 1
- 150000002513 isocyanates Chemical class 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 2
- HLMLWEGDMMDCDW-UHFFFAOYSA-N 2-butylphenol;formaldehyde Chemical group O=C.CCCCC1=CC=CC=C1O HLMLWEGDMMDCDW-UHFFFAOYSA-N 0.000 abstract 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 abstract 1
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 229920001568 phenolic resin Polymers 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000012774 insulation material Substances 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229920001596 poly (chlorostyrenes) Polymers 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/307—Other macromolecular compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/18—Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
- H01B7/1835—Sheaths comprising abrasive charges
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/28—Protection against damage caused by moisture, corrosion, chemical attack or weather
- H01B7/2813—Protection against damage caused by electrical, chemical or water tree deterioration
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a high-power light-stabilized cable material and a preparation method thereof. The high-power light-stabilized cable material is prepared from the following raw materials in parts by weight: 3-5 parts of bisphenol A, 2-3 parts of stearic acid, 30-40 parts of ABS resin, 12-16 parts of polyvinyl chloride resin, 6-8 parts of ABS high-glue powder, 1-2 parts of an antioxidant 1035, 2-4 parts of a maleic anhydride grafted vinyl-vinyl acetate copolymer, 5-6 parts of boric acid melamine, 5-7 parts of polyethylene wax, 3-4 parts of copper naphthenate, 3-5 parts of diphenylmethane diisocyanate, 2-4 parts of isophorone diisocyanate, 2-3 parts of magnesium oxide, 4-6 parts of tertiary butyl phenol-formaldehyde resin and 8-12 parts of filling agents. The formula and the preparation method of the high-power light-stabilized cable material are simple; and by adding multiple filling agents, the light stability resistance and the chemical resistance of the cable material are increased, and meanwhile, the cable material has good mechanical property and wide economic prospects.
Description
Technical field
The present invention relates to the technical field of a kind of CABLE MATERIALS, use up stable CABLE MATERIALS and system thereof particularly to one is high-power
Preparation Method.
Background technology
Along with developing rapidly of China's expanding economy and communications industry, the usage amount of powerful device gets more and more,
The serviceability of cable is just had higher requirement by this.The tolerance power of cable and inner wire maximum temperature and ambient temperature
Difference linear, and the maximum operating temperature of inner wire is limited by cable insulation material, the permanent worker of cable insulation material
It is exactly the highest permission operating temperature of inner wire as temperature, but the most most CABLE MATERIALS does not the most have outstanding resistance to
High-temperature behavior, it is impossible to meet the demand of present powerful device.Therefore the present inventor by design new cable material formula and
Technique, creates the novel cable material being suitable for high-power use.
Summary of the invention
The present invention compensate for the deficiencies in the prior art, it is provided that one is high-power uses up stable CABLE MATERIALS and preparation method thereof.
Technical scheme is as follows:
CABLE MATERIALS of the present invention is prepared by the raw materials in: bisphenol-A 3-5, stearic acid 2-3, ABS resin 30-40, polychlorostyrene second
Olefine resin 12-16, ABS high glue powder 6-8, antioxidant 10351-2, maleic anhydride grafted ethene-acetate ethylene copolymer 2-4, boron
Acid tripolycyanamide 5-6, Tissuemat E 5-7, copper naphthenate 3-4, methyl diphenylene diisocyanate 3-5, isophorone two isocyanide
Acid esters 2-4, magnesium oxide 2-3, t-Butylphenol formaldehyde resin 4-6, filler 8-12；
Described filler is prepared by the raw materials in: 4-butyl ammonium hydrogen sulfate 3-5, glycerol trioleate 6-10, nonyl
Phenol polyethenoxy ether 4-6, EVA polymer 8-12, isoamyl rubber powder 5-8, xanthan gum 2-3, hydroxyethyl methylacrylate 6-8, red phosphorus
2-3, fine silica powder 3-5, Tetramethylammonium hydroxide 8-10, zirconium oxide 1-3, not Sang Shi 1-2；Its preparation method is by EVA
Polymer and isoamyl rubber powder put in high-speed mixer, and 400-600 rev/min mixes 8-12 minute, and gained material is standby；Again will not
Sang Shi calcines 3-5 hour at being placed in 1200-1400 DEG C, is ground into powder after cooling, then with above gained mixed material, the tetrabutyl
Ammonium hydrogen sulfate, glycerol trioleate, NPE, hydroxyethyl methylacrylate, xanthan gum, Tetramethylammonium hydroxide
Stir pulping after mixing, gained serosity is mixed with red phosphorus, fine silica powder, zirconium oxide and is placed on pelletize 20-in vulcanization bed
40 minutes.
Specifically comprising the following steps that of the preparation of described CABLE MATERIALS
(1) by bisphenol-A, stearic acid, antioxidant 1035, maleic anhydride grafted ethene-acetate ethylene copolymer, boric acid melamine
After amine, Tissuemat E, methyl diphenylene diisocyanate, isophorone diisocyanate, t-Butylphenol formaldehyde mixed with resin
Ground by three-roll grinder, standby；
(2) by step 1 gained material and ABS resin, Corvic, ABS high glue powder, copper naphthenate, magnesium oxide, filler
And leftover materials join in high-speed mixer and mix 6-10 minute with 650-800 rev/min；
(3) step 2 gained material input double screw extruder being carried out extruding pelletization, the temperature of extruder controls as feeding section
135-145 DEG C, melt zone 160-170 DEG C, homogenizing zone 215-225 DEG C, head 170-180 DEG C, die orifice 180-190 DEG C, screw rod turns
Speed is 15-30 rev/min；
(4) by step 3 products obtained therefrom metering packing after screening magnetic separation.
Beneficial effects of the present invention:
The central idea of the present invention is that invention one is applicable to powerful CABLE MATERIALS, has the corrosion-resistant ageing-resistant of excellence simultaneously
Etc. performance.
The cable material formula of the present invention and preparation method are simple, and the interpolation of multiple filler adds the resistance to optics of CABLE MATERIALS
Stablize and chemical proofing, there is good mechanical property simultaneously, have the biggest economic outlook.
Filler uses multiple exotic material, and adds finished product by the mixing of EVA polymer Yu isoamyl rubber powder
The performance such as wear-resistance and oil-resistance.
Specific embodiments
Below in conjunction with detailed description below, the present invention is described in further detail:
The raw material weighing following weight portion (kg) is made: bisphenol-A 4, stearic acid 2, ABS resin 35, Corvic 14, ABS
High glue powder 7, antioxidant 10351, maleic anhydride grafted ethene-acetate ethylene copolymer 3, boric acid tripolycyanamide 5, Tissuemat E 6,
Copper naphthenate 3, methyl diphenylene diisocyanate 4, isophorone diisocyanate 3, magnesium oxide 2, t-Butylphenol formaldehyde tree
Fat 5, filler 10；
Described filler is made up of the raw material of following weight portion (kg): 4-butyl ammonium hydrogen sulfate 4, glycerol trioleate 8, nonyl phenol
Polyoxyethylene ether 5, EVA polymer 10, isoamyl rubber powder 7, xanthan gum 2, hydroxyethyl methylacrylate 7, red phosphorus 2, silicon dioxide are micro-
Powder 4, Tetramethylammonium hydroxide 9, zirconium oxide 2, not Sang Shi 2；Its preparation method is EVA polymer and isoamyl rubber powder to be put at a high speed
In mixer, 500 revs/min mix 10 minutes, and gained material is standby；Mo Sangshi is placed at 1300 DEG C calcining 4 hours, cooling again
After be ground into powder, then with above gained mixed material, 4-butyl ammonium hydrogen sulfate, glycerol trioleate, Nonyl pheno
Pulping is stirred, by gained serosity and red phosphorus, dioxy after the mixing of ether, hydroxyethyl methylacrylate, xanthan gum, Tetramethylammonium hydroxide
The mixing of SiClx micropowder, zirconium oxide is placed on pelletize 30 minutes in vulcanization bed.
Specifically comprising the following steps that of the preparation of described CABLE MATERIALS
(1) by bisphenol-A, stearic acid, antioxidant 1035, maleic anhydride grafted ethene-acetate ethylene copolymer, boric acid melamine
After amine, Tissuemat E, methyl diphenylene diisocyanate, isophorone diisocyanate, t-Butylphenol formaldehyde mixed with resin
Ground by three-roll grinder, standby；
(2) by step 1 gained material and ABS resin, Corvic, ABS high glue powder, copper naphthenate, magnesium oxide, filler
And leftover materials join in high-speed mixer and mix 8 minutes with 700 revs/min；
(3) step 2 gained material input double screw extruder being carried out extruding pelletization, the temperature of extruder controls as feeding section
140 DEG C, melt zone 165 DEG C, homogenizing zone 220 DEG C, head 175 DEG C, die orifice 185 DEG C, screw speed is 20 revs/min；
(4) by step 3 products obtained therefrom metering packing after screening magnetic separation.
The CABLE MATERIALS hot strength of the present invention is 16.3MPa after tested, and elongation at break is 403%, and oxygen index (OI) is 28%,
220 DEG C × 168h hot air aging after-drawing change rate of strength is less than 9.6%, and extension at break rate of change is less than 8.2%, at 20mol/
After soaking 168h in 24 DEG C in L hydrochloric acid solution, elongation at break is 328%, in 24 DEG C of immersions in 20mol/L sodium hydroxide solution
After 168h, elongation at break is 336%.
Claims (2)
1. high-power use up stable CABLE MATERIALS for one kind, it is characterised in that be prepared by the raw materials in: bisphenol-A 3-5, hard
Fat acid 2-3, ABS resin 30-40, Corvic 12-16, ABS high glue powder 6-8, antioxidant 10351-2, maleic anhydride connect
Branch ethylene-vinyl acetate copolymer 2-4, boric acid tripolycyanamide 5-6, Tissuemat E 5-7, copper naphthenate 3-4, diphenyl methane two
Isocyanates 3-5, isophorone diisocyanate 2-4, magnesium oxide 2-3, t-Butylphenol formaldehyde resin 4-6, filler 8-12；
Described filler is prepared by the raw materials in: 4-butyl ammonium hydrogen sulfate 3-5, glycerol trioleate 6-10, nonyl
Phenol polyethenoxy ether 4-6, EVA polymer 8-12, isoamyl rubber powder 5-8, xanthan gum 2-3, hydroxyethyl methylacrylate 6-8, red phosphorus
2-3, fine silica powder 3-5, Tetramethylammonium hydroxide 8-10, zirconium oxide 1-3, not Sang Shi 1-2；Its preparation method is by EVA
Polymer and isoamyl rubber powder put in high-speed mixer, and 400-600 rev/min mixes 8-12 minute, and gained material is standby；Again will not
Sang Shi calcines 3-5 hour at being placed in 1200-1400 DEG C, is ground into powder after cooling, then with above gained mixed material, the tetrabutyl
Ammonium hydrogen sulfate, glycerol trioleate, NPE, hydroxyethyl methylacrylate, xanthan gum, Tetramethylammonium hydroxide
Stir pulping after mixing, gained serosity is mixed with red phosphorus, fine silica powder, zirconium oxide and is placed on pelletize 20-in vulcanization bed
40 minutes.
2. use up stable CABLE MATERIALS according to high-power described in claims 1, it is characterised in that the concrete steps of preparation method
As follows:
(1) by bisphenol-A, stearic acid, antioxidant 1035, maleic anhydride grafted ethene-acetate ethylene copolymer, boric acid melamine
After amine, Tissuemat E, methyl diphenylene diisocyanate, isophorone diisocyanate, t-Butylphenol formaldehyde mixed with resin
Ground by three-roll grinder, standby；
(2) by step 1 gained material and ABS resin, Corvic, ABS high glue powder, copper naphthenate, magnesium oxide, filler
And leftover materials join in high-speed mixer and mix 6-10 minute with 650-800 rev/min；
(3) step 2 gained material input double screw extruder being carried out extruding pelletization, the temperature of extruder controls as feeding section
135-145 DEG C, melt zone 160-170 DEG C, homogenizing zone 215-225 DEG C, head 170-180 DEG C, die orifice 180-190 DEG C, screw rod turns
Speed is 15-30 rev/min；
(4) by step 3 products obtained therefrom metering packing after screening magnetic separation.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111234409A (en) * | 2020-01-17 | 2020-06-05 | 浙江大学 | Auxiliary agent master batch for polyvinyl chloride modification and preparation method thereof |
-
2016
- 2016-06-30 CN CN201610503895.XA patent/CN106046656A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111234409A (en) * | 2020-01-17 | 2020-06-05 | 浙江大学 | Auxiliary agent master batch for polyvinyl chloride modification and preparation method thereof |
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Application publication date: 20161026 |