CN106040132A - Reaction kettle for producing white carbon black - Google Patents
Reaction kettle for producing white carbon black Download PDFInfo
- Publication number
- CN106040132A CN106040132A CN201610359864.1A CN201610359864A CN106040132A CN 106040132 A CN106040132 A CN 106040132A CN 201610359864 A CN201610359864 A CN 201610359864A CN 106040132 A CN106040132 A CN 106040132A
- Authority
- CN
- China
- Prior art keywords
- white carbon
- kettle
- paddle
- agitator
- puddler
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 238000006243 chemical reaction Methods 0.000 title abstract description 11
- 239000006229 carbon black Substances 0.000 title abstract 3
- 238000003756 stirring Methods 0.000 claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 claims description 14
- 239000012429 reaction media Substances 0.000 abstract description 8
- 239000000377 silicon dioxide Substances 0.000 abstract description 6
- 238000001556 precipitation Methods 0.000 abstract description 4
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 4
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 3
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 230000035484 reaction time Effects 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 239000007788 liquid Substances 0.000 description 3
- 235000019353 potassium silicate Nutrition 0.000 description 3
- 229960001866 silicon dioxide Drugs 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 238000003916 acid precipitation Methods 0.000 description 2
- 239000001117 sulphuric acid Substances 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 239000007832 Na2SO4 Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- LRCFXGAMWKDGLA-UHFFFAOYSA-N dioxosilane;hydrate Chemical compound O.O=[Si]=O LRCFXGAMWKDGLA-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 230000011218 segmentation Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229960004029 silicic acid Drugs 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0053—Details of the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0053—Details of the reactor
- B01J19/0066—Stirrers
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/113—Silicon oxides; Hydrates thereof
- C01B33/12—Silica; Hydrates thereof, e.g. lepidoic silicic acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/18—Details relating to the spatial orientation of the reactor
- B01J2219/185—Details relating to the spatial orientation of the reactor vertical
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Mixers Of The Rotary Stirring Type (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
The invention discloses a reaction kettle for producing white carbon black. The reaction kettle comprises a kettle body and multiple groups of stirrers which are arranged in the kettle body and used for stirring reaction media in the kettle body, wherein the stirrers include vertical stirrers and horizontal stirrers, and each group of the stirrers is independently controlled through a motor. The reaction kettle for producing the white carbon black has the advantages that the reaction kettle is reasonable in structural design, the reaction media at various positions can be sufficiently and evenly stirred due to the fact that the vertical stirrers and the horizontal stirrers are arranged in the kettle body, the reaction time of the reaction media in a precipitation reactor is shortened, reaction efficiency is increased, and the reaction kettle is low in energy consumption and capable of achieving the large-scale production of silicon dioxide.
Description
Technical field
The present invention relates to synthetic reaction device technical field, produce white carbon reactor particularly to one.
Background technology
Precipitated hydrated silica, also known as white carbon, its chemical formula is SiO2·n H2O.White carbon is rubber industry weight
The supporting material wanted, is used for tire tread by white carbon, can significantly reduce the resistance to rolling of tire, can keep preferable simultaneously
Anti-ice slip and anti-slippery, its wearability only slightly reduces.
Sulfuric acid precipitation method with waterglass as raw material is to have realized the existing of industrialized production white carbon both at home and abroad at present
Technique, the technical characteristics of sulfuric acid precipitation method is: in precipitation reactor, and in certain density waterglass, segmentation adds one
Determining the concentrated sulphuric acid of concentration, and control the pH value in whole course of reaction, reaction equation is: Na2O·mSiO2+H2SO4+n H2O
→ mSiO2(n+1) H2O ↓ +Na2SO4, dilute silicon dioxide oar liquid of gained is filtered out Na through filter wash2SO4Female
Liquid, the silica filter cake obtained is processed through pulp tank and obtains dense silica slurry, and is dried by exsiccator
Realize solid-liquid separation, final prepared product white carbon.
Although it is simple that traditional sedimentation method prepare silicon dioxide technique, but due to waterglass and sulphuric acid in precipitation reactor
Undercompounding, uneven, cause the response time generating silicon dioxide oversize, production efficiency is low, and energy expenditure is big, is difficult to real
Existing large-scale production.
Summary of the invention
For solving problems of the prior art, the invention provides and the stirring of reaction medium can be made the most abundant equal
Even production white carbon reactor.
The purpose of the present invention implements by the following technical programs:
A kind of production white carbon reactor, reacts with being arranged on inside described kettle including kettle in stirring described kettle
The agitator of medium, described agitator is many groups, including vertical stirrer and horizontal agitator, often organizes described agitator and all passes through
Motor independently controls.
Further, described vertical stirrer is vertically arranged in inside described kettle, including puddler and stirring paddle, described
Puddler top is fixed on described kettle top, and described stirring paddle is many groups, is separately positioned on the axially distinct position of described puddler
Put.
Further, described vertical stirrer is many groups, is uniformly arranged on inside described kettle.
Further, described stirring paddle includes that multi-disc paddle, described paddle are folding paper paddle.
Further, described horizontal agitator is arranged in described kettle internal side wall, and described agitator includes puddler
With stirring paddle, described puddler is vertically arranged with described kettle sidewall.
Further, the puddler of described horizontal agitator is fixed on described reactor sidewall, and described stirring paddle is arranged
In described puddler end.
Further, the stirring paddle of described horizontal agitator is formed by organizing paddle more, and described paddle is arcwall face.
Further, described horizontal agitator includes two row being arranged on differing heights, and two row agitators be arranged in parallel.
Further, described parallel agitator of often going includes 4 groups, is uniformly arranged in described kettle sidewall circumference.
Further, described vertical stirrer is non-interference with described horizontal agitator.
The invention has the beneficial effects as follows:
Production white carbon reactor disclosed in this invention, reasonable in design, by arranging vertical stirrer in kettle
With horizontal agitator, the reaction medium of each position all being carried out well-beaten effect, the stirring making reaction medium is more abundant
Uniformly, shorten the response time of reaction medium in precipitation reactor, improve reaction efficiency, and energy consumption is low, it is possible to achieve two
The large-scale production of silicon oxide.
Accompanying drawing explanation
Fig. 1 is production white carbon reactor cross-sectional view disclosed in this invention.
Wherein:
1-kettle, 2-ear mount, 3-air inlet, 4-acid inlet, 5-tremie pipe, 6-puddler, 7-horizontal agitator motor, 8-level
Agitator puddler, 9-horizontal agitator puddler, 10-vertical stirrer puddler, 11-exhaustor, 12-refers to agitator electricity
Machine, 13-water inlet pipe.
Detailed description of the invention
Specific embodiments of the present invention is described in detail below in conjunction with the accompanying drawings.
As it is shown in figure 1, a kind of raw white carbon reactor, including kettle 1, kettle 1 be provided above exhaustor 11 with
Water inlet pipe 13, is provided with ear mount 2, exhaustor 3 and acid inlet tube 4 on the middle outer wall of kettle 1, is provided with blanking below kettle 1
Pipe 5.
Being internally provided with the agitator of reaction medium in stirred tank body at kettle 1, agitator is many groups, including vertically
Agitator and horizontal agitator, often group agitator is all independently controlled by motor.
It is internal that vertical stirrer is vertically arranged in kettle 1, and including puddler 6 and stirring paddle 10, puddler 3 top is fixed on
Kettle 1 top, stirring paddle 10 is many groups, is separately positioned on the axially distinct position of puddler 6.In the present embodiment, vertically stir
Device is 4 groups, is uniformly arranged on kettle 1 internal.Stirring paddle 10 includes multi-disc paddle, and paddle is folding paper paddle.
Horizontal agitator is arranged in kettle 1 internal side wall, and agitator includes puddler 8 and stirring paddle 9, puddler 8 with
Kettle 1 sidewall is vertically arranged and is fixed on kettle sidewall, and stirring paddle 9 is arranged on puddler 8 end.The stirring of horizontal agitator
Oar 9 is formed by organizing paddle more, and paddle is arcwall face.
In the present embodiment, horizontal agitator includes two row being arranged on differing heights, and two row agitators be arranged in parallel.Often
The parallel agitator of row includes 4 groups, is uniformly arranged in kettle 1 sidewall circumference.Properly functioning for ensureing reactor, vertical stirrer
Non-interference with horizontal agitator.
Finally it is noted that the foregoing is only the preferred embodiments of the present invention, it is not limited to the present invention,
Although being described in detail the present invention with reference to previous embodiment, for a person skilled in the art, it still may be used
So that the technical scheme described in foregoing embodiments to be modified, or wherein portion of techniques feature is carried out equivalent.
All within the spirit and principles in the present invention, any modification, equivalent substitution and improvement etc. made, should be included in the present invention's
Within protection domain.
Claims (10)
1. produce a white carbon reactor, including kettle be arranged on inside described kettle in stirring described kettle anti-
Answer the agitator of medium, it is characterised in that: described agitator is many groups, including vertical stirrer and horizontal agitator, often organizes institute
State agitator all independently to be controlled by motor.
A kind of production white carbon reactor the most according to claim 1, it is characterised in that: described vertical stirrer is vertical
Being arranged on inside described kettle, including puddler and stirring paddle, described puddler top is fixed on described kettle top, described in stir
Mixing oar is many groups, is separately positioned on the axially distinct position of described puddler.
A kind of production white carbon reactor the most according to claim 2, it is characterised in that: described vertical stirrer is many
Group, is uniformly arranged on inside described kettle.
A kind of production white carbon reactor the most according to claim 2, it is characterised in that: described stirring paddle includes multi-disc
Paddle, described paddle is folding paper paddle.
A kind of production white carbon reactor the most according to claim 1, it is characterised in that: described horizontal agitator is arranged
In described kettle internal side wall, described agitator includes that puddler and stirring paddle, described puddler hang down with described kettle sidewall
Straight setting.
A kind of production white carbon reactor the most according to claim 5, it is characterised in that: stirring of described horizontal agitator
Mixing bar to be fixed on described reactor sidewall, described stirring paddle is arranged on described puddler end.
A kind of production white carbon reactor the most according to claim 5, it is characterised in that: stirring of described horizontal agitator
Mixing oar and formed by organizing paddle more, described paddle is arcwall face.
A kind of production white carbon reactor the most according to claim 5, it is characterised in that: described horizontal agitator includes
Being arranged on two row of differing heights, two row agitators be arranged in parallel.
The most according to claim 8 a kind of produce white carbon reactor, it is characterised in that: described often go parallel stirring
Device includes 4 groups, is uniformly arranged in described kettle sidewall circumference.
The most according to claim 1 a kind of produce white carbon reactor, it is characterised in that: described vertical stirrer with
Described horizontal agitator is non-interference.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610359864.1A CN106040132A (en) | 2016-05-27 | 2016-05-27 | Reaction kettle for producing white carbon black |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610359864.1A CN106040132A (en) | 2016-05-27 | 2016-05-27 | Reaction kettle for producing white carbon black |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106040132A true CN106040132A (en) | 2016-10-26 |
Family
ID=57175492
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610359864.1A Pending CN106040132A (en) | 2016-05-27 | 2016-05-27 | Reaction kettle for producing white carbon black |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106040132A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113164894A (en) * | 2018-11-29 | 2021-07-23 | 北欧化工股份公司 | Method for providing a homogeneous slurry containing particles |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU631187A1 (en) * | 1977-04-27 | 1978-11-10 | Московский Институт Химического Машиностроения | Apparatus for obtaining |
| CN102765728A (en) * | 2012-08-08 | 2012-11-07 | 确成硅化学股份有限公司 | Precipitation reactor for producing highly dispersed silicon dioxide |
| CN203291860U (en) * | 2013-06-15 | 2013-11-20 | 王公元 | Stirring reaction kettle |
| CN104016358A (en) * | 2014-06-20 | 2014-09-03 | 福建远翔化工有限公司 | Production equipment and production method of white carbon black |
| CN204485836U (en) * | 2014-12-25 | 2015-07-22 | 重庆市华旭能源科技有限公司 | Acid tolerance response device |
| CN204619986U (en) * | 2015-05-12 | 2015-09-09 | 宁波大学 | A kind of highly effective reaction still |
| CN204891635U (en) * | 2015-09-06 | 2015-12-23 | 厦门高时实业有限公司 | Rostone diamond stone building stones agitating unit |
-
2016
- 2016-05-27 CN CN201610359864.1A patent/CN106040132A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU631187A1 (en) * | 1977-04-27 | 1978-11-10 | Московский Институт Химического Машиностроения | Apparatus for obtaining |
| CN102765728A (en) * | 2012-08-08 | 2012-11-07 | 确成硅化学股份有限公司 | Precipitation reactor for producing highly dispersed silicon dioxide |
| CN203291860U (en) * | 2013-06-15 | 2013-11-20 | 王公元 | Stirring reaction kettle |
| CN104016358A (en) * | 2014-06-20 | 2014-09-03 | 福建远翔化工有限公司 | Production equipment and production method of white carbon black |
| CN204485836U (en) * | 2014-12-25 | 2015-07-22 | 重庆市华旭能源科技有限公司 | Acid tolerance response device |
| CN204619986U (en) * | 2015-05-12 | 2015-09-09 | 宁波大学 | A kind of highly effective reaction still |
| CN204891635U (en) * | 2015-09-06 | 2015-12-23 | 厦门高时实业有限公司 | Rostone diamond stone building stones agitating unit |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113164894A (en) * | 2018-11-29 | 2021-07-23 | 北欧化工股份公司 | Method for providing a homogeneous slurry containing particles |
| CN113164894B (en) * | 2018-11-29 | 2023-03-28 | 北欧化工股份公司 | Method for providing a homogeneous slurry containing particles |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161026 |
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| RJ01 | Rejection of invention patent application after publication |