CN106039940A - Waste acid recovery and utilization device for desulfurization and denitrification of exhaust gas - Google Patents
Waste acid recovery and utilization device for desulfurization and denitrification of exhaust gas Download PDFInfo
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- CN106039940A CN106039940A CN201610643225.8A CN201610643225A CN106039940A CN 106039940 A CN106039940 A CN 106039940A CN 201610643225 A CN201610643225 A CN 201610643225A CN 106039940 A CN106039940 A CN 106039940A
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- gas
- waste acid
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- exhaust gas
- denitration
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/18—Absorbing units; Liquid distributors therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1481—Removing sulfur dioxide or sulfur trioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1493—Selection of liquid materials for use as absorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/56—Nitrogen oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/50—Inorganic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/10—Inorganic absorbents
- B01D2252/103—Water
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
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- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Treating Waste Gases (AREA)
Abstract
The invention discloses a waste acid recovery and utilization device for desulfurization and denitrification of exhaust gas. A gas-liquid separator, a flue dust sweaper device and a plate-type gas-liquid heat exchanger are arranged between an exhaust gas inlet and a dust collector. The flue dust sweaper device is arranged between the exhaust gas inlet and the plate-type gas-liquid heat exchanger. The gas-liquid separator is disposed above the plate-type gas-liquid heat exchanger. An outlet of the dust collector is connected to an inlet of an induced draft fan. An outlet of the induced draft fan is connected to a sulfur dioxide absorbing device, an outlet of which is connected to a desulfurization and denitrification device. The invention has the following advantages: desulfurated and denitrated waste acid can be recovered and utilized on the spot so as to solve recovery and utilization problems of desulfurated and denitrated waste acid; recovery efficiency of waste acid is high, effect is good, and pH value meets the standard of denitration; by the use of residual heat from flue gas, recovery cost of waste acid is greatly reduced; by using on the spot, purchase quantity of a denitration reducing agent and acid is greatly reduced, and denitration cost is greatly decreased; and the device is simple, is convenient to operate, runs stably and is easy to control.
Description
Technical field
The present invention relates to a kind of waste acid recycling device, particularly relate to the waste acid recycling of a kind of exhuast gas desulfurization denitration
Device, belongs to combustion products process field.
Background technology
Nitrogen oxides is the main cause causing chemical fumes, is also the major reason of acid rain.Sulfur dioxide is acid rain
Main cause.Desulfurization and denitration are two vital tasks of waste gas pollution control and treatment.
Desulfurizing method of exhaust gas mainly has dry type, half dry type and wet type desulfurizing.Dry type desulfurizing feeding lime stone, magnesium oxide etc. are dry
Powder desulfurizing agent, directly with waste gas sulfur dioxide react and generate the dry product such as calcium sulfite, magnesium sulfite, then dedusting.Half
The desulfurizer slurries such as dry type desulfurizing feeding lime, magnesium oxide, sodium hydroxide, directly react generation Asia with the sulfur dioxide in waste gas
The dry product such as calcium sulfate, magnesium sulfite, then dedusting.Dry type, the advantage of half dry type desulfurization are to need not water, there is not pulp water and divide
From with water recycle problem；Shortcoming is to react not thorough, and efficiency is low, is front and back required for dedusting, and repeated construction is serious, pressure drop
Greatly, operating cost is high.First wet type desulfurizing sprays waste gas with doctor solution, and the sulfur dioxide in waste gas is transferred to be formed in water Asia
Sulphuric acid, then in the alkali liquor such as feeding lime, magnesium oxide, sodium hydroxide and acid doctor solution, after slag-liquid separation, doctor solution follows
Ring uses.The advantage of wet type desulfurizing is that sulfur dioxide transfer velocity is fast, and efficiency is high, effective；Shortcoming is to consume water, and doctor solution needs
Want slag-liquid separation and recycle.Generally use wet type desulfurizing at present, seldom use dry type and half dry type desulfurization.
The main selective catalytic reduction method of main flow denitration technology (SCR) and SNCR method (SNCR).Its
His technology mainly has the absorption of electronic beam method (EBA), activated coke, normal temperature oxidation reducing process etc..SCR law technology is at catalyst action
Under, reducing agent NH3(liquefied ammonia, ammonia, carbamide etc.) and the NO in flue gasXReaction, by the NO in flue gasXIt is reduced to nitrogen and water.Its
Reactor is arranged between boiler economizer outlet and air preheater entrance, and reaction temperature is typically between 320 DEG C-400 DEG C.
SNCR law technology NH3, the reducing agent such as carbamide spray into the region that in-furnace temperature is 850～1100 DEG C, reducing agent with in flue gas
NOxCarry out selective reaction, NOxIt is reduced to nitrogen and water.SCR and SNCR technology be required for specific reaction temperature condition and
Strict automatically controls, and the reaction of reducing agent deficiency is not thorough, and instead excess produces the escaping of ammonia increases nitrogen oxides, results in process
Effect reduces.The high energy particle that electronic beam method utilizes electron accelerator to produce irradiates flue gas so that it is SO2And NOxOxidation generates sulphuric acid
And nitric acid, then react generation ammonium sulphate and nitric acid ammonia with the ammonia added.This technology does not has waste water, it is not necessary to catalyst, to flue gas
Condition change strong adaptability, but power consumption is big, is not also suitable for large-scale application.Active coke absorption method activated coke carries out cigarette
Desulfurization and denitrogenation while gas.SO2Being adsorbed by activated coke, by hot recycling, product is converted into the pairs such as sulfur, sulphuric acid, chemical fertilizer
Product.NOXIt is under conditions of ammonification, generates water and nitrogen through the catalytic action of activated coke and enter air again.This technology does not has
Waste water, it is not necessary to catalyst, changes strong adaptability, but operation is more complicated flue gas condition, and side-product produces complexity, carbon consumption
Greatly, tower pressure drop is big.NO is first oxidized to NO by normal temperature oxidation reducing process2, then by NO2Transfer to water becomes HNO3, finally utilize
H2SO3By HNO3It is reduced into N2Discharge.This technical matters process is similar with desulfurization, it is not necessary to reducing agent, suitable to flue gas condition change
Ying Xingqiang, moreover it is possible to noxious substances such as simultaneous oxidation two English and remove removing heavy metals etc., operating cost is low, and difficult point is oxidation and also
Former control.
Containing substantial amounts of dust, carbon dioxide, sulfur dioxide and nitrogen oxides in coal combustion exhaust, need to carry out dedusting, take off
Sulfur, denitration process.Normal temperature oxidation reduction denitration needs substantial amounts of oxidant, reducing agent sulfurous acid and nertralizer alkali, wet type desulfurizing
Producing substantial amounts of sulfurous acid, need a large amount of alkali, coal combustion exhaust typically requires desulphurization denitration.Current desulfurizing and denitrifying process has no
There are report and the data of waste acid recycling.
Summary of the invention
It is an object of the invention to overcome weak point in prior art, and provide the spent acid of a kind of exhuast gas desulfurization denitration to return
Receipts utilize device.
The waste acid recycling device of this exhuast gas desulfurization denitration, including exhaust gas inlet, dust arrester, air-introduced machine, waste gas
Be provided with gas-liquid separator between import and dust arrester, flue dust inhales sweeping device, board-like gas-liquid heat-exchange, exhaust gas inlet and board-like gas
Be provided with flue dust between liquid heat exchanger and inhale sweeping device, board-like gas-liquid heat-exchange be arranged over gas-liquid separator, dust arrester exports
Being connected with air-introduced machine import, air-introduced machine outlet connects apparatus for absorbing SO 2, and the outlet of apparatus for absorbing SO 2 connects de-
Sulfur denitrification apparatus.
It is provided with absorbing liquid elevator pump between described board-like gas-liquid heat-exchange and apparatus for absorbing SO 2.
The invention has the advantages that:
1. the spent acid of desulphurization denitration reclaims on the spot and utilizes, and solves recovery and the utilization of desulphurization denitration spent acid on the spot；
2. waste acidity recovery efficiency is high, and effective, pH value has reached the requirement of denitration.
3. utilize fume afterheat, greatly reduce waste acidity recovery cost；
4. local use, greatly reduces denitrification reducing agent and the amount of purchase of acid, greatly reduces denitration cost；
5. device is simple, easy to operate, stable, controls easily.
Accompanying drawing explanation
Fig. 1 is the structural representation of the waste acid recycling device of exhuast gas desulfurization denitration.
Labelling in figure: 1-gas-liquid separator, 2-flue dust blow device, the board-like gas-liquid heat-exchange of 3-, 4-sulfur dioxide absorb
Device, 5-absorbing liquid elevator pump, 6-exhaust gas inlet, 7-dust arrester, 8-air-introduced machine, 9-desulfuring and denitrifying apparatus.
Detailed description of the invention
Below in conjunction with the accompanying drawings the waste acid recycling device of exhuast gas desulfurization denitration is further described.
The waste acid recycling device of this exhuast gas desulfurization denitration, including exhaust gas inlet 6, dust arrester 7, air-introduced machine 8, useless
Be provided with gas-liquid separator 1 between gas import 6 and dust arrester 7, flue dust inhales sweeping device 2, board-like gas-liquid heat-exchange 3, exhaust gas inlet 6
And be provided with between board-like gas-liquid heat-exchange 3 flue dust inhale sweeping device 2, board-like gas-liquid heat-exchange 3 be arranged over gas-liquid separator 2,
Dust arrester 7 outlet is connected with air-introduced machine 8 import, and air-introduced machine 8 outlet connects apparatus for absorbing SO 24, and sulfur dioxide absorbs
The outlet of device 4 connects desulfuring and denitrifying apparatus 9.It is provided with absorbing liquid between board-like gas-liquid heat-exchange 3 and apparatus for absorbing SO 24
Elevator pump 5.
The waste acid recycling device of this exhuast gas desulfurization denitration is by gas-liquid separator 1, flue dust blow device 2, board-like gas
Liquid heat exchanger 3, apparatus for absorbing SO 24, absorbing liquid elevator pump 5 etc. form；Hot waste gas first passes around exhaust gas inlet 6 and enters plate
Formula gas-liquid heat-exchange 3 carries out gas-liquid vapor liquid heat exchange, enters dust arrester 7 dedusting after hot waste gas cooling, and the waste gas after dedusting enters
Entering apparatus for absorbing SO 24, the sulfur dioxide in flue gas transfers to be formed in absorbing liquid sulfurous acid, and waste gas enters desulphurization denitration
Device 9；Fresh water (FW) or doctor solution initially enter, as absorbing liquid, the sulfur dioxide shape that apparatus for absorbing SO 24 absorbs in flue gas
Becoming sulfurous acid, absorbing liquid elevator pump 5 deliver to board-like gas-liquid heat-exchange 3, absorbing liquid heat absorption heats up and evaporates, and gas-liquid mixture passes through
Gas-liquid separator 1 carries out gas-liquid separation, and gas returns to apparatus for absorbing SO 24, and liquid returns to board-like gas-liquid heat-exchange 3, plate
Dope in formula gas-liquid heat-exchange 3 delivers to the desulfuring and denitrifying apparatus 9 reducing agent utilization as denitration；Board-like gas-liquid heat-exchange 3 gas
The dust of phase surface is fallen into ash bucket by flue dust blow device 2 purging.
For fume emission, the sulfur dioxide concentration in flue gas is the highest, is far longer than discharge standard；For acid recovery, cigarette
Sulfur dioxide concentration in gas is the lowest, and absorbing liquid pH value can only achieve 3-4, how to bring up to meet requirement by absorbing liquid pH value
1 key problem in technology that the following is desulphurization denitration waste acid recycling.In the present invention, the sulfur dioxide in flue gas, through absorbing, is inhaled
Receiving liquid pH value and reach 3, absorbing liquid is warmed to 100 DEG C of evaporation and concentration by the waste heat of recycling flue gas, absorbing liquid pH value reach 1 with
Under, absorbing liquid acid concentration has reached the requirement of denitration, it is achieved that the spent acid of desulphurization denitration reclaims on the spot and utilizes,
Sulfur dioxide in recovered flue gas produces the sulfurous acid reducing agent as denitration.
The present invention relates to F23J combustion products process field, the chemically and physically chemistry specifically utilizing sulfur dioxide is special
Property, theoretical according to gas transfer, chemistry and evaporation and concentration, define the waste acid recycling device of waste gas exhuast gas desulfurization denitration,
Sulfur dioxide generation sulfurous acid in recovered flue gas, as the reducing agent of denitration, is greatly saved reducing agent and antacid desulfurization
The consumption of agent, greatly reduces the operating cost of flue gas desulfurization and denitrification.
Claims (2)
1. a waste acid recycling device for exhuast gas desulfurization denitration, including exhaust gas inlet (6), dust arrester (7), air-introduced machine
(8), it is characterised in that: be provided with between exhaust gas inlet (6) and dust arrester (7) gas-liquid separator (1), flue dust inhale sweeping device (2),
Board-like gas-liquid heat-exchange (3), is provided with flue dust and inhales sweeping device (2) between exhaust gas inlet (6) and board-like gas-liquid heat-exchange (3), board-like
Gas-liquid heat-exchange (3) be arranged over gas-liquid separator (1), dust arrester (7) outlet is connected with air-introduced machine (8) import, air inducing
Machine (8) outlet connects apparatus for absorbing SO 2 (4), and the outlet of apparatus for absorbing SO 2 (4) connects desulfuring and denitrifying apparatus
(9)。
The waste acid recycling device of exhuast gas desulfurization denitration the most according to claim 1, described board-like gas-liquid heat-exchange
And between apparatus for absorbing SO 2 (4), be provided with absorbing liquid elevator pump (5) (3).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610643225.8A CN106039940A (en) | 2016-08-08 | 2016-08-08 | Waste acid recovery and utilization device for desulfurization and denitrification of exhaust gas |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610643225.8A CN106039940A (en) | 2016-08-08 | 2016-08-08 | Waste acid recovery and utilization device for desulfurization and denitrification of exhaust gas |
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| CN106039940A true CN106039940A (en) | 2016-10-26 |
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| CN201610643225.8A Pending CN106039940A (en) | 2016-08-08 | 2016-08-08 | Waste acid recovery and utilization device for desulfurization and denitrification of exhaust gas |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20210220772A1 (en) * | 2019-10-29 | 2021-07-22 | Huaneng Clean Energy Research Institute | Flue gas low-temperature adsorption denitrification method |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101108303A (en) * | 2007-08-02 | 2008-01-23 | 武汉凯迪电力环保有限公司 | Wet-type ammonia process flue gas purifying technique for jointly removing multipollutant and system thereof |
| EP1184622B1 (en) * | 2000-09-01 | 2008-07-02 | Institut Francais Du Petrole | Method of generating heat with reduced emission of sulphur oxides and low absorbant consumption |
| CN101837237A (en) * | 2009-12-29 | 2010-09-22 | 中国恩菲工程技术有限公司 | Flue gas desulphurization system |
| CN101879404A (en) * | 2010-07-12 | 2010-11-10 | 华东理工大学 | A resource-based flue gas desulfurization and denitrification method |
| KR101110661B1 (en) * | 2009-06-30 | 2012-03-13 | 한국전력공사 | System for separrating acid gas in the power plant equipment |
| CN102974181A (en) * | 2012-11-14 | 2013-03-20 | 江苏中显集团有限公司 | Flue gas dedusting and desulfurization and denitrification craft and special device thereof |
| CN103977673A (en) * | 2014-05-28 | 2014-08-13 | 祥云县黄金工业有限责任公司 | Gold ore roasting tail gas recovery technology |
| CN105056741A (en) * | 2015-08-27 | 2015-11-18 | 北京市环境保护科学研究院 | Method and device for reduction absorption treatment of pollutants in natural gas boiler smoke |
| CN105214457A (en) * | 2014-06-05 | 2016-01-06 | 魏雄辉 | A kind of fume desulfuring and denitrifying Processes and apparatus |
| CN205886543U (en) * | 2016-08-08 | 2017-01-18 | 辽宁信威环保科技有限公司 | Waste acid recycling of desulphurization of exhaust gas denitration utilizes device |
-
2016
- 2016-08-08 CN CN201610643225.8A patent/CN106039940A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1184622B1 (en) * | 2000-09-01 | 2008-07-02 | Institut Francais Du Petrole | Method of generating heat with reduced emission of sulphur oxides and low absorbant consumption |
| CN101108303A (en) * | 2007-08-02 | 2008-01-23 | 武汉凯迪电力环保有限公司 | Wet-type ammonia process flue gas purifying technique for jointly removing multipollutant and system thereof |
| KR101110661B1 (en) * | 2009-06-30 | 2012-03-13 | 한국전력공사 | System for separrating acid gas in the power plant equipment |
| CN101837237A (en) * | 2009-12-29 | 2010-09-22 | 中国恩菲工程技术有限公司 | Flue gas desulphurization system |
| CN101879404A (en) * | 2010-07-12 | 2010-11-10 | 华东理工大学 | A resource-based flue gas desulfurization and denitrification method |
| CN102974181A (en) * | 2012-11-14 | 2013-03-20 | 江苏中显集团有限公司 | Flue gas dedusting and desulfurization and denitrification craft and special device thereof |
| CN103977673A (en) * | 2014-05-28 | 2014-08-13 | 祥云县黄金工业有限责任公司 | Gold ore roasting tail gas recovery technology |
| CN105214457A (en) * | 2014-06-05 | 2016-01-06 | 魏雄辉 | A kind of fume desulfuring and denitrifying Processes and apparatus |
| CN105056741A (en) * | 2015-08-27 | 2015-11-18 | 北京市环境保护科学研究院 | Method and device for reduction absorption treatment of pollutants in natural gas boiler smoke |
| CN205886543U (en) * | 2016-08-08 | 2017-01-18 | 辽宁信威环保科技有限公司 | Waste acid recycling of desulphurization of exhaust gas denitration utilizes device |
Non-Patent Citations (1)
| Title |
|---|
| 杨建初等: "《循环经济读本》", 31 October 2011 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20210220772A1 (en) * | 2019-10-29 | 2021-07-22 | Huaneng Clean Energy Research Institute | Flue gas low-temperature adsorption denitrification method |
| US11925898B2 (en) * | 2019-10-29 | 2024-03-12 | Huaneng Clean Energy Research Institute | Flue gas low-temperature adsorption denitrification method |
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Application publication date: 20161026 |