CN106012217B - A kind of preparation method of latex-free machine-woven carpet - Google Patents
A kind of preparation method of latex-free machine-woven carpet Download PDFInfo
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/60—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the warp or weft elements other than yarns or threads
- D03D15/68—Scaffolding threads, i.e. threads removed after weaving
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47G—HOUSEHOLD OR TABLE EQUIPMENT
- A47G27/00—Floor fabrics; Fastenings therefor
- A47G27/02—Carpets; Stair runners; Bedside rugs; Foot mats
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
- D03D15/47—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D27/00—Woven pile fabrics
- D03D27/02—Woven pile fabrics wherein the pile is formed by warp or weft
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/80—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
本发明一种公开了无乳胶机织地毯的制备方法,该地毯包括基布、绒纱、纬纱和经纱,所述的纬纱为复合纱,所述复合纱由芯纱和包覆层组成,所述的包覆层包括热熔纤维和纳米增强材料,将纳米增强材料浆料以共混改性的方法加入到热熔纤维中,得到包覆层材料,采用该包覆层材料对芯纱进行包覆后得到纬纱;将经纱、纬纱、绒头纱三纱交织后,对其加热后使热熔纤维熔化,粘结绒头纱,经冷却固化和后处理得到所述的地毯,本发明解决了生产和回收地毯过程中的废水污染问题和空气污染问题,有利于环保,采用纳米增强材料,增强了地毯的耐磨性能。
The invention discloses a preparation method of a latex-free woven carpet. The carpet comprises a base cloth, pile yarns, weft yarns and warp yarns. The weft yarn is a composite yarn, and the composite yarn is composed of a core yarn and a covering layer. The covering layer includes hot-melt fiber and nano-reinforcement material, and the nano-reinforcing material slurry is added to the hot-melt fiber by blending and modifying to obtain the covering layer material, and the core yarn is processed by using the covering layer material Weft yarns are obtained after covering; after interweaving the warp yarns, weft yarns and pile yarns, heating them to melt the hot-melt fibers, bonding the pile yarns, cooling and solidifying and post-processing to obtain the carpet, the invention solves the problem of It solves the problem of wastewater pollution and air pollution in the process of producing and recycling carpets, and is conducive to environmental protection. The use of nano-reinforced materials enhances the wear resistance of carpets.
Description
技术领域technical field
本发明属于家居用品领域,尤其是涉及一种无乳胶机织地毯的制备方法。The invention belongs to the field of household products, and in particular relates to a preparation method of a latex-free woven carpet.
背景技术Background technique
随着现代生活水平的提高,对家居装修的舒适性、时尚性、环保性等要求也越来越高。家装中地毯的利用率占了很大一部分。地毯具有保暖调节的功能,大面积地铺垫地毯可以减少室内通过地面散失的热量,阻断地面寒气的侵袭,使人感到温暖舒适。同时具有吸音功能,地毯的丰厚质地与毛绒簇立的表面具备良好的吸音效果,并能适当降低噪声影响,以及舒适功能,由于地毯为富有弹性纤维的织物,有丰满、厚实、松软的质地,所以在上面行走时会产生较好的回弹力,感觉舒适柔软。地毯同时兼具审美功能,质地丰满,外观华美的地毯铺设后地面能显得端庄富丽,获得极好的装饰效果。地毯的种类很多,有羊毛地毯、化纤地毯、皮质地毯、橡胶地毯、自然纤维地毯等等。各自具有自己的特性和优点。With the improvement of modern living standards, the requirements for comfort, fashion, and environmental protection of home decoration are also getting higher and higher. The utilization rate of carpets in home decoration accounts for a large part. Carpets have the function of heat preservation and regulation. Large-area carpets can reduce the heat lost through the ground in the room, block the invasion of cold air on the ground, and make people feel warm and comfortable. At the same time, it has a sound-absorbing function. The rich texture of the carpet and the surface of the plush tufts have a good sound-absorbing effect, and can properly reduce the impact of noise and comfort. Because the carpet is a fabric rich in elastic fibers, it has a plump, thick, and soft texture. , so it will have better resilience when walking on it, and it feels comfortable and soft. At the same time, the carpet has an aesthetic function, and the texture is plump. After the carpet with a gorgeous appearance is laid, the ground can look dignified and rich, and an excellent decorative effect can be obtained. There are many types of carpets, such as wool carpets, chemical fiber carpets, leather carpets, rubber carpets, natural fiber carpets and so on. Each has its own characteristics and advantages.
机织威尔顿地毯通过经纱、纬纱、绒头纱三纱交织,经上胶、剪绒等后道工序整理而制成。机织阿克明斯特地毯也是通过经纱、纬纱、绒头纱三纱交织,后经上胶、剪绒等工序整理而成。采用乳胶涂层,在生产和回收地毯时带来一些问题,即废水处理问题及产生难闻的气味。有时,为降低成本,将乳胶粘合层与碳酸钙一起混用,但带来的问题是,焚烧废弃物时,废弃物中含有难燃的填充料。Woven Wilton carpets are made by interlacing warp yarns, weft yarns, and pile yarns, and finishing through subsequent processes such as gluing and shearing. Woven Axminster carpets are also made by interweaving warp, weft and pile yarns, and then finishing by gluing, shearing and other processes. The use of latex coatings poses some problems in the manufacture and recycling of carpets, namely waste water disposal problems and unpleasant odours. Latex adhesive layers are sometimes mixed with calcium carbonate to reduce costs, but this poses a problem when the waste is incinerated with non-flammable fillers.
发明内容Contents of the invention
为解决上述技术问题,本发明提供了一种无乳胶机织地毯及其制备方法。In order to solve the above technical problems, the present invention provides a latex-free woven carpet and a preparation method thereof.
本发明完整的技术方案包括:The complete technical scheme of the present invention comprises:
一种无乳胶机织地毯的制备方法,其特征在于,该地毯包括基布、绒头纱、纬纱和经纱;A kind of preparation method of latex-free woven carpet is characterized in that, this carpet comprises base cloth, pile yarn, weft yarn and warp yarn;
所述的纬纱为复合纱,所述复合纱由芯纱和包覆层组成,所述的包覆层包括热熔纤维和纳米增强材料,所述的纳米增强材料以浆料的方式加入,热熔纤维和纳米增强材料浆料的质量比为(98-99.5):(0.5-2),所述的浆料由纳米碳粉、纳米碳化硼、溶剂和分散剂组成,所述的纳米碳粉的粒径为20-50nm,在纳米增强材料浆料中的质量分数为0.45-0.85%,所述的纳米碳化硼的粒径为10-30nm,在纳米增强材料浆料中的质量分数为0.9-1.1%,分散剂在纳米增强材料浆料中的质量分数为0.8-2%,余量为溶剂;制备方法为:将分散剂加入溶剂,随后将纳米碳粉和纳米碳化硼,在40-60℃下超声分散10-15min,得到所述纳米增强材料浆料;The weft yarn is a composite yarn, and the composite yarn is composed of a core yarn and a covering layer, and the covering layer includes hot-melt fibers and nano-reinforcing materials, and the nano-reinforcing materials are added in the form of slurry, heated The mass ratio of melting fiber and nano reinforcement material slurry is (98-99.5):(0.5-2), and described slurry is made up of nano-carbon powder, nano-boron carbide, solvent and dispersant, and described nano-carbon powder The particle size of the nano-boron carbide is 20-50nm, and the mass fraction in the nano-reinforcement material slurry is 0.45-0.85%. The particle size of the nano-boron carbide is 10-30nm, and the mass fraction in the nano-reinforcement material slurry is 0.9% -1.1%, the mass fraction of the dispersant in the nano-reinforcement material slurry is 0.8-2%, and the balance is a solvent; the preparation method is: add the dispersant to the solvent, and then add nano-carbon powder and nano-boron carbide, at 40- Ultrasonic dispersion at 60°C for 10-15 minutes to obtain the nano-reinforcement material slurry;
随后将纳米增强材料浆料以共混改性的方法加入到热熔纤维中,得到包覆层材料,采用该包覆层材料对芯纱进行包覆后得到纬纱;Then, the nano-reinforcement material slurry is added to the hot-melt fiber by a blending modification method to obtain a cladding layer material, and the core yarn is coated with the cladding layer material to obtain a weft yarn;
将经纱、纬纱、绒头纱三纱交织后,对其加热后使热熔纤维熔化,粘结绒头纱,经冷却固化和后处理得到所述的地毯。After the three yarns of warp, weft and pile are interwoven, they are heated to melt the hot-melt fibers, bond the pile, cool and solidify and post-process to obtain the carpet.
所述的芯纱为满足地毯需要的各种纤维长丝纱或短纤维纱。The core yarn is various filament yarns or short fiber yarns meeting the needs of the carpet.
所述热熔纤维的熔点在110-170℃,且低于用于该地毯上的其它纤维的软化温度。The melting point of the hot-melt fiber is 110-170°C, which is lower than the softening temperature of other fibers used in the carpet.
所述的热熔纤维选自聚丙烯、聚酰胺纤维、聚醋纤维、聚烯烃纤维、聚氯乙烯纤维或其组合。The hot-melt fiber is selected from polypropylene, polyamide fiber, polyester fiber, polyolefin fiber, polyvinyl chloride fiber or combinations thereof.
所述的溶剂为乙醇,分散剂为PVP。The solvent is ethanol, and the dispersant is PVP.
所述加热方式为热空气加热、热滚筒加热、或远红外加热。The heating method is hot air heating, hot roller heating, or far infrared heating.
所述的方法所制备的地毯。The carpet prepared by the method.
本发明相对于现有技术的优点在于:不采用传统的乳胶粘合层,解决了生产和回收地毯过程中的废水污染问题和空气污染问题,有利于环保,采用纳米增强材料,增强了地毯的耐磨性能,并且该增强材料采用浆料方式配制,提高了分散度,降低了团聚程度,有效的保证了地毯的性能均匀。Compared with the prior art, the present invention has the advantages of not using the traditional latex adhesive layer, solving the problems of waste water pollution and air pollution in the process of producing and recycling carpets, and being conducive to environmental protection, and adopting nano-reinforced materials to enhance the strength of the carpet. Wear resistance, and the reinforcing material is prepared in the form of slurry, which improves the degree of dispersion, reduces the degree of agglomeration, and effectively ensures the uniform performance of the carpet.
附图说明Description of drawings
图1为本发明的无乳胶机织地毯的结构示意图。Fig. 1 is the structural representation of latex-free machine-woven carpet of the present invention.
图2为用于纬纱的复合包芯纱示意图。Figure 2 is a schematic diagram of a composite corespun yarn used for a weft yarn.
图中:1-绒头纱,2-基布,3-纬纱,4-经纱,5-包覆层,6-芯纱。In the figure: 1-pile yarn, 2-base fabric, 3-weft yarn, 4-warp yarn, 5-covering layer, 6-core yarn.
具体实施方式detailed description
下面结合附图和具体实施方式对本发明做进一步说明。The present invention will be further described below in conjunction with the accompanying drawings and specific embodiments.
如图1-2所示,一种无乳胶机织地毯的制备方法,该地毯包括基布2、绒头纱1、纬纱3和经纱4;As shown in Figure 1-2, a kind of preparation method of latex-free woven carpet, this carpet comprises base cloth 2, pile yarn 1, weft yarn 3 and warp yarn 4;
所述的纬纱为复合纱,所述复合纱由芯纱5和包覆层5组成,所述的包覆层包括热熔纤维和纳米增强材料,所述热熔纤维的熔点在110-170℃,可以是聚丙烯、聚酰胺纤维、聚醋纤维、聚烯烃纤维、聚氯乙烯纤维等。所述热粘合长丝纤维或短纤维的熔点低于用于该地毯上的其它纤维的软化温度,如果地毯中有棉、麻、丝、毛等非热熔纤维,其热熔纤维的熔点要保证在加热熔化时段不对所述的非热熔纤维造成损伤,热熔纤维的软化温度要高于90℃,熔点的优选的方案应该在110℃—160℃。The weft yarn is a composite yarn, and the composite yarn is composed of a core yarn 5 and a covering layer 5, and the covering layer includes hot-melt fibers and nano-reinforced materials, and the melting point of the hot-melt fibers is 110-170°C , can be polypropylene, polyamide fiber, polyester fiber, polyolefin fiber, polyvinyl chloride fiber, etc. The melting point of the thermally bonded filament fibers or short fibers is lower than the softening temperature of other fibers used in the carpet. If there are non-heat-melting fibers such as cotton, hemp, silk, and wool in the carpet, the melting point of the heat-melting fibers To ensure that the non-hot-melt fibers are not damaged during the heating and melting period, the softening temperature of the hot-melt fibers should be higher than 90°C, and the preferred solution for the melting point should be 110°C-160°C.
所述的纳米增强材料以浆料的方式加入,热熔纤维和纳米增强材料浆料的质量比为(98-99.5):(0.5-2),所述的浆料由纳米碳粉、纳米碳化硼、乙醇和PVP组成,所述的纳米碳粉的粒径为20-50nm,在纳米增强材料浆料中的质量分数为0.6%,所述的纳米碳化硼的粒径为10-30nm,在纳米增强材料浆料中的质量分数为1.0%,PVP在纳米增强材料浆料中的质量分数为1.5%,余量为乙醇;将PVP加入乙醇,随后将纳米碳粉和纳米碳化硼,在50℃下超声分散15min,得到所述纳米增强材料浆料;The nano-reinforcement material is added in the form of a slurry, and the mass ratio of the hot-melt fiber and the nano-reinforcement material slurry is (98-99.5): (0.5-2), and the slurry is composed of nano-carbon powder, nano-carbonized Boron, ethanol and PVP, the particle size of the nano-carbon powder is 20-50nm, the mass fraction in the nano-reinforcement material slurry is 0.6%, the particle size of the nano-boron carbide is 10-30nm, in The massfraction in the nano-reinforced material slurry is 1.0%, the massfraction of PVP in the nano-reinforced material slurry is 1.5%, and the balance is ethanol; PVP is added to ethanol, followed by nano-carbon powder and nano-boron carbide, at 50 Ultrasonic dispersion for 15 minutes at °C to obtain the nano-reinforcement material slurry;
随后将纳米增强材料浆料以共混改性的方法加入到热熔纤维中,得到包覆层材料,采用该包覆层材料对芯纱进行包覆后得到纬纱;Then, the nano-reinforcement material slurry is added to the hot-melt fiber by a blending modification method to obtain a cladding layer material, and the core yarn is coated with the cladding layer material to obtain a weft yarn;
采用绒头纱1为纯毛纱,经纱4为10/90涤棉混纺10s/3股线,纬纱3的芯纱6为40/60涤棉混纺10s/6股线,包覆层5为带有纳米增强材料的聚酯热粘合长丝,其熔点为110℃。将经纱、纬纱、绒头纱三纱交织后,热空气加热,加热温度为130—160℃,使热熔纤维熔化,粘结绒头纱,经冷却定型后处理后得到无乳胶威尔顿机织地毯。The pile yarn 1 is pure wool yarn, the warp yarn 4 is 10/90 polyester-cotton blended 10s/3 strands, the core yarn 6 of weft yarn 3 is 40/60 polyester-cotton blended 10s/6 strands, and the covering layer 5 is with Polyester thermally bonded filaments of nanoreinforcement with a melting point of 110°C. After interweaving the warp, weft and pile yarns, heat the hot air at a temperature of 130-160°C to melt the hot-melt fibers, bond the pile yarns, and obtain a latex-free Wilton machine after cooling and shaping. Woven rugs.
以上所述,仅是本发明的较佳实施例,并非对本发明作任何限制,凡是根据本发明技术实质对以上实施例所作的任何简单修改、变更以及等效结构变化,均仍属于本发明技术方案的保护范围内。The above are only preferred embodiments of the present invention, and do not limit the present invention in any way. All simple modifications, changes and equivalent structural changes made to the above embodiments according to the technical essence of the present invention still belong to the technical aspects of the present invention. within the scope of protection of the scheme.
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CN108577461A (en) * | 2018-04-23 | 2018-09-28 | 朱东洋 | A kind of preparation method of no latex carpet |
CN115710794A (en) * | 2022-11-28 | 2023-02-24 | 滨州东方地毯有限公司 | Carpet hot-pressing device for latex-free woven carpet and carpet preparation method |
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CN101671903A (en) * | 2008-09-12 | 2010-03-17 | 海马集团公司 | Method for producing PP silks and PP bottom double-layer carpet |
CN103722848A (en) * | 2012-10-14 | 2014-04-16 | 常州博朗凯德织物有限公司 | Highly fire-retardant fabric |
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