CN106009114A - Tear-resistant functional rubber material for magnetic modification and preparation method thereof - Google Patents
Tear-resistant functional rubber material for magnetic modification and preparation method thereof Download PDFInfo
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- CN106009114A CN106009114A CN201610621217.3A CN201610621217A CN106009114A CN 106009114 A CN106009114 A CN 106009114A CN 201610621217 A CN201610621217 A CN 201610621217A CN 106009114 A CN106009114 A CN 106009114A
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 54
- 239000005060 rubber Substances 0.000 title claims abstract description 54
- 230000005291 magnetic effect Effects 0.000 title claims abstract description 44
- 239000000463 material Substances 0.000 title claims abstract description 41
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 230000004048 modification Effects 0.000 title abstract description 6
- 238000002715 modification method Methods 0.000 title 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 29
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 12
- 229920001577 copolymer Polymers 0.000 claims abstract description 11
- 229920003244 diene elastomer Polymers 0.000 claims abstract description 11
- 229920000459 Nitrile rubber Polymers 0.000 claims abstract description 9
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 6
- 239000004917 carbon fiber Substances 0.000 claims abstract description 6
- 239000000440 bentonite Substances 0.000 claims abstract description 5
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 5
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000012760 heat stabilizer Substances 0.000 claims abstract description 5
- 229910000420 cerium oxide Inorganic materials 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 21
- 229910002804 graphite Inorganic materials 0.000 claims description 20
- 239000010439 graphite Substances 0.000 claims description 20
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 16
- -1 Polytetrafluoroethylene Polymers 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 11
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 9
- 239000006247 magnetic powder Substances 0.000 claims description 9
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 8
- 239000004115 Sodium Silicate Substances 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- XENVCRGQTABGKY-ZHACJKMWSA-N chlorohydrin Chemical compound CC#CC#CC#CC#C\C=C\C(Cl)CO XENVCRGQTABGKY-ZHACJKMWSA-N 0.000 claims description 8
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 229920001690 polydopamine Polymers 0.000 claims description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 8
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 7
- 239000010426 asphalt Substances 0.000 claims description 5
- 239000000835 fiber Substances 0.000 claims description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 5
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- 239000011230 binding agent Substances 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 239000000306 component Substances 0.000 claims description 4
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 4
- 239000003365 glass fiber Substances 0.000 claims description 4
- 239000008187 granular material Substances 0.000 claims description 4
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims description 4
- 239000004312 hexamethylene tetramine Substances 0.000 claims description 4
- 150000003949 imides Chemical class 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 4
- 239000012286 potassium permanganate Substances 0.000 claims description 4
- 238000010298 pulverizing process Methods 0.000 claims description 4
- 239000001117 sulphuric acid Substances 0.000 claims description 4
- 235000011149 sulphuric acid Nutrition 0.000 claims description 4
- 239000013638 trimer Substances 0.000 claims description 4
- OFGVPLJWXLEAEN-UHFFFAOYSA-N 2,2-dimethylpropoxy-diethoxy-pentylsilane Chemical compound CC(CO[Si](OCC)(OCC)CCCCC)(C)C OFGVPLJWXLEAEN-UHFFFAOYSA-N 0.000 claims description 3
- GFLJTEHFZZNCTR-UHFFFAOYSA-N 3-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OCCCOC(=O)C=C GFLJTEHFZZNCTR-UHFFFAOYSA-N 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 3
- 229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 claims description 3
- 229920002627 poly(phosphazenes) Polymers 0.000 claims description 3
- 229920001228 polyisocyanate Polymers 0.000 claims description 3
- 239000005056 polyisocyanate Substances 0.000 claims description 3
- 239000004575 stone Substances 0.000 claims description 2
- 239000007789 gas Substances 0.000 abstract description 7
- 238000012986 modification Methods 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 238000001179 sorption measurement Methods 0.000 abstract description 3
- 239000002131 composite material Substances 0.000 abstract description 2
- 238000005336 cracking Methods 0.000 abstract description 2
- 239000000428 dust Substances 0.000 abstract description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 abstract 2
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 abstract 2
- 229920005558 epichlorohydrin rubber Polymers 0.000 abstract 2
- 229920003048 styrene butadiene rubber Polymers 0.000 abstract 2
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 235000019270 ammonium chloride Nutrition 0.000 abstract 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 description 16
- 239000004033 plastic Substances 0.000 description 15
- 238000005516 engineering process Methods 0.000 description 4
- 239000010445 mica Substances 0.000 description 4
- 229910052618 mica group Inorganic materials 0.000 description 4
- 239000012752 auxiliary agent Substances 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229920001661 Chitosan Polymers 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 230000005294 ferromagnetic effect Effects 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000696 magnetic material Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000002346 layers by function Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- PYNUOAIJIQGACY-UHFFFAOYSA-N propylazanium;chloride Chemical compound Cl.CCCN PYNUOAIJIQGACY-UHFFFAOYSA-N 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000003878 thermal aging Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
- C08L71/03—Polyepihalohydrins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/01—Magnetic additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a tear-resistant functional rubber material for magnetic modification and a preparation method thereof. The tear-resistant functional rubber material for magnetic modification is prepared from epichlorohydrin rubber, butadiene-acrylonitrile rubber, acrylonitrile-butadiene copolymer rubber, diene rubber, styrene-butadiene rubber, regenerated rubber, a heat stabilizer, an adhesive, polydimethyldiallyl ammonium chloride, bentonite and nano cerium oxide. The combination of the epichlorohydrin rubber, butadiene-acrylonitrile rubber, acrylonitrile-butadiene copolymer rubber, diene rubber, styrene-butadiene rubber and regenerated rubber used as main materials greatly enhances the toughness of the material and effectively solves the problem of high cracking rupture tendency of the conveyer belt. The tear-resistant functional rubber material can not generate harmful gases to the human body, has a perfect combination of tear resistance and other properties, and thus, is applicable to various severe working conditions. The nano graphene between every two layers is combined to improve the porosity and specific area of the composite adsorption film and enhance the effect. The asphalt-base carbon fibers are adopted to enhance the mechanical properties of the material, and can greatly adsorb and remove harmful gases and dust substances in the tail gas.
Description
Technical field
The present invention relates to technical field of function materials, particularly relate to a kind of for the modified tear-resistant functional rubber energy material of magnetic
Material and preparation method thereof.
Background technology
Magnetic plastics is a kind of novel high polymer functional material that the seventies grows up, and is modern science and technology fields
One of important foundation material.Magnetic plastics can be divided into structural type and compound two kinds, structural type magnetic plastics by composition
Refer to
Polymer itself has ferromagnetic magnet, and this kind of magnetic plastics is also in the exploratory stage, from practical the most certain
Distance；Compound magnetic plastics refer to the magnet made with plastics or rubber for base material processing, and this kind of magnetic plastics is real
Existing commercialization, the magnetic powder being currently used for filling is mainly ferromagnetic oxide powder and rare earth permanent magnet powder.
At present, most of functional plasticses such as fire retardant antistatic plastic, conductive plastics, wear-resistant plastic, luminescent plastic etc. is all
Achieving the goal by adding various function additives, its functional layer is limited only to top layer, and the function additive of nexine does not the most play
Actual utility, thus cause auxiliary agent to waste, add cost, and auxiliary agent interpolation too much makes material property decline substantially.
Meanwhile, the preparation technology existing defects of current functional material, preparation technology is relatively cumbersome.
For the above-mentioned deficiency of existing capability material, the excellent specific property of magnetic plastics is introduced functional material neck by the present invention
Territory, thus overcome the shortcoming of existing capability material, the performance of modified function material.
Summary of the invention
For overcoming above-mentioned deficiency, the present invention provides a kind of for the modified tear-resistant functional rubber energy material of magnetic and preparation thereof
Method.
The present invention takes techniques below scheme to realize: a kind of for the modified tear-resistant functional rubber energy material of magnetic
Material, the constitutive material that it includes is: chlorohydrin rubber 50-100 part, nitrile rubber 30-45s part, acrylonitrile-butadiene copolymer rubber
Glue 55-60 part, diene rubber 40-55 part, butadiene-styrene rubber 50-60 part, reclaimed rubber 30-40 part, nano-graphene 10-15 weight
Part, magnetic powder 20-30 weight portion, sodium silicate 5-10 weight portion, magnetic iron oxide 10-20 weight portion, magnetic alumina 4-8 weight
Part, asphalt base carbon fiber powder 30-35 part, non-halogenated organophosphinate 5-7 part, hexamethylenetetramine 8-10 part, trimethyl
Amyl triethoxysilane 2-4 part, conductive mica powder 0.3-0.5 weight portion, conductive nano graphite powder 0.2-0.4 weight portion, many
The trimer 0.8-1 weight portion of isocyanates, polytetrafluoroethylene fibre 1-2 weight portion, nano titanium oxide 8-12 weight portion, poly-
Dopamine 1-5 weight portion, poly phosphazene 2-6 weight portion, magnetic ferroferric oxide granule 12-20 weight portion, 2-phosphoric acid ethamine 4-8 weight
Amount part, polyethylene imide 1-5 weight portion, paraffin 8-12 weight portion, senior aliphat alcohol 7-13 weight portion, ethylenediaminetetraacetic acid
5-9 weight portion, glass fibre 7-13 weight portion, heat stabilizer 6-12 weight portion, binding agent 6-12 weight portion, poly dimethyl diene
Propyl ammonium chloride 1-5 weight portion, bentonite 8-16 weight portion, nano-cerium oxide 1-5 weight portion.
The preparation method of described nano-graphene is: added by concentrated sulphuric acid in graphite, through-20 DEG C ~-10 DEG C low temperature stirrings
5-12 hour, then after 0 DEG C ~ 5 DEG C stirrings 5-12 hour, add potassium permanganate and carry out oxidation reaction to obtain graphite oxide molten
Liquid；To obtain graphite oxide solution is directly added into CTAB, CTAB graphite oxide to be flocculated and modified-reaction obtains modification
Graphite oxide solution；Modified graphite oxide solution is filtered, washs, be vacuum dried 24 hours at 50 DEG C, i.e. obtain nano-graphite
Alkene.
The present invention also provides for a kind of preparation method for the modified tear-resistant functional rubber energy material of magnetic, by following steps
Composition:
(1) magnetic powder, sodium silicate, magnetic iron oxide, magnetic alumina, nano titanium oxide, poly-dopamine dimension are placed in pulverizer
Middle pulverizing, crosses 100-200 mesh sieve, standby as component A；
(2) plasticate, by chlorohydrin rubber, nitrile rubber, acrylonitrile-butadiene copolymer rubber, diene rubber part, butadiene-styrene rubber,
Mix and blend 30min in the plasticator that internal temperature is 120 DEG C put into by reclaimed rubber, obtains component B,
3) mixing, component A, B are put into internal temperature is to add other component, mix and blend 20min in 120 DEG C of mixing rolls；And
30min is vulcanized, it is thus achieved that product places 3h under conditions of 100 DEG C；
4) molding, puts in forming machine by the product of previous step, it is thus achieved that product.The present invention has following useful effect in sum
Really: the present invention is with chlorohydrin rubber, nitrile rubber, acrylonitrile-butadiene copolymer rubber, diene rubber, butadiene-styrene rubber, regeneration rubber
Glue is major ingredient with the use of substantially increasing the toughness of material, effectively solves the situation that conveyer belt is easily broken off, the most relatively
Also will not produce harmful gas under high-temperature high temperature resistant, the performance such as tear-resistant perfectly merges so that energy of the present invention
Enough apply to work under various mal-condition.Obtaining the functional material for magnetic plastics, component preparation is reasonable, method simplicity,
With low cost, environmental protection, manufacturing process will not be peeling phenomenon and enhance the durability of guaranteeing the quality of material, be greatly reinforced
The close-coupled degree of material, prepared functional material stable performance, safety are good, have higher magnetic advantages, the most greatly
Big improves the functional of magnetic plastics product and persistency, reduces the consumption of auxiliary agent the most to a great extent, saves
Cost is less to the performance impact of plastic substrate so that it is preferably to maintain original performance and intensity, it is adaptable to push away on a large scale
Extensively.The reinforcing agents such as the rock gangue of interpolation, conductive mica powder, conductive nano graphite powder can improve resistant to thermal aging cracking performance,
Thus improve casting efficiency, reduce casting cost.Photocatalyst and degradable poly chitosan lactate is selected to prepare filter fiber film,
There is the dual-use function of adsorbed gas colloidal sol and volatile organic matter, the advantage with Degradable environment protection, the chitosan of employing because of
For molecular band positive charge, can be with the antibacterial of adsorption site negative charge so that it is there is sterilizing function；Structurally, difference it is prepared for straight
The fibrous membrane layer of footpath and hole, in conjunction with nano-graphene between layers, improves hole and the specific surface of composite adsorption film
Amass, enhance effect.The mechanical property that the present invention uses asphalt base carbon fiber to enhance material can be adsorbed and clearly greatly
Except the harmful gas in tail gas and dust material
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below in conjunction with
Detailed description of the invention, is expanded on further the present invention.
Embodiment 1 one kinds is for modified tear-resistant functional rubber energy material of magnetic and preparation method thereof
A kind of for the modified tear-resistant functional rubber energy material of magnetic, the constitutive material that it includes is: chlorohydrin rubber 50 parts, Ding Qing
Rubber 30 parts, acrylonitrile-butadiene copolymer rubber 55 parts, diene rubber 40 parts, 50 parts of butadiene-styrene rubber, reclaimed rubber 30 parts,
Nano-graphene 10 weight portion, magnetic powder 20 weight portion, sodium silicate 5 weight portion, magnetic iron oxide 10 weight portion, magnetic alumina 4
Weight portion, 6 parts of asphalt base carbon fiber powder, non-halogenated organophosphinate 5 parts, hexamethylenetetramine 8 parts, tri-methyl-amyl three
Ethoxysilane 2 parts, conductive mica powder 0.3 weight portion, conductive nano graphite powder 0.2 weight portion, the trimer of polyisocyanates
0.8 weight portion, polytetrafluoroethylene fibre 1 weight portion, nano titanium oxide 8 weight portion, poly-dopamine 1 weight portion, poly phosphazene 2 weight
Amount part, magnetic ferroferric oxide granule 12 weight portion, 2-phosphoric acid ethamine 4 weight portion, polyethylene imide 1 weight portion, paraffin 8 weight
Amount part, senior aliphat alcohol 7 weight portion, ethylenediaminetetraacetic acid 5 weight portion, glass fibre 7 weight portion, heat stabilizer 6 weight portion,
Binding agent 6 weight portion, PDDA 1 weight portion, bentonite 8 weight portion, nano-cerium oxide 1 weight portion.
The preparation method of described nano-graphene is: added by concentrated sulphuric acid in graphite, little through-20 DEG C ~-10 DEG C low temperature stirring 5-12
Time, then after 0 DEG C ~ 5 DEG C stirrings 5-12 hour, addition potassium permanganate carries out oxidation reaction and obtains graphite oxide solution；Will
In graphite oxide solution, it is directly added into CTAB, CTAB graphite oxide is flocculated and modified-reaction obtains modified graphite oxide
Solution；Modified graphite oxide solution is filtered, washs, be vacuum dried 24 hours at 50 DEG C, i.e. obtain nano-graphene.
The present invention also provides for a kind of preparation method for the modified tear-resistant functional rubber energy material of magnetic, by following steps
Composition:
(1) magnetic powder, sodium silicate, magnetic iron oxide, magnetic alumina, nano titanium oxide, poly-dopamine dimension are placed in pulverizer
Middle pulverizing, crosses 100-200 mesh sieve, standby as component A；
(2) plasticate, by chlorohydrin rubber, nitrile rubber, acrylonitrile-butadiene copolymer rubber, diene rubber part, butadiene-styrene rubber,
Mix and blend 30min in the plasticator that internal temperature is 120 DEG C put into by reclaimed rubber, obtains component B,
3) mixing, component A, B are put into internal temperature is to add other component, mix and blend 20min in 120 DEG C of mixing rolls；And
30min is vulcanized, it is thus achieved that product places 3h under conditions of 100 DEG C；
4) molding, puts in forming machine by the product of previous step, it is thus achieved that product.
Embodiment 2 one kinds is for modified tear-resistant functional rubber energy material of magnetic and preparation method thereof
A kind of for the modified tear-resistant functional rubber energy material of magnetic, the constitutive material that it includes is: chlorohydrin rubber 100 parts, fourth
Fine rubber 45 parts, acrylonitrile-butadiene copolymer rubber 60 parts, diene rubber 55 parts, 60 parts of butadiene-styrene rubber, reclaimed rubber 30-
40 parts, nano-graphene 15 weight portion, magnetic powder 30 weight portion, sodium silicate 10 weight portion, magnetic iron oxide 20 weight portion, magnetic oxygen
Change aluminum 8 weight portion, 8 parts of asphalt base carbon fiber powder, non-halogenated organophosphinate 7 parts, hexamethylenetetramine 10 parts, trimethyl
Amyl triethoxysilane 4 parts, conductive mica powder 0.5 weight portion, conductive nano graphite powder 0.4 weight portion, polyisocyanates
Trimer 1 weight portion, polytetrafluoroethylene fibre 2 weight portion, nano titanium oxide 12 weight portion, poly-dopamine 5 weight portion, poly-phosphine
Nitrile 6 weight portion, magnetic ferroferric oxide granule 20 weight portion, 2-phosphoric acid ethamine 8 weight portion, polyethylene imide 5 weight portion, stone
Wax 12 weight portion, senior aliphat alcohol 13 weight portion, ethylenediaminetetraacetic acid 9 weight portion, glass fibre 13 weight portion, heat stabilizer
12 weight portions, binding agent 12 weight portion, PDDA 5 weight portion, bentonite 16 weight portion, nano oxidized
Cerium 5 weight portion.The preparation method of described nano-graphene is: added by concentrated sulphuric acid in graphite, stirs through-20 DEG C ~-10 DEG C low temperature
Mix 5-12 hour, then after 0 DEG C ~ 5 DEG C stirrings 5-12 hour, add potassium permanganate and carry out oxidation reaction to obtain graphite oxide molten
Liquid；To obtain graphite oxide solution is directly added into CTAB, CTAB graphite oxide to be flocculated and modified-reaction obtains modification
Graphite oxide solution；Modified graphite oxide solution is filtered, washs, be vacuum dried 24 hours at 50 DEG C, i.e. obtain nano-graphite
Alkene.
The present invention also provides for a kind of preparation method for the modified tear-resistant functional rubber energy material of magnetic, by following steps
Composition:
(1) magnetic powder, sodium silicate, magnetic iron oxide, magnetic alumina, nano titanium oxide, poly-dopamine dimension are placed in pulverizer
Middle pulverizing, crosses 100-200 mesh sieve, standby as component A；
(2) plasticate, by chlorohydrin rubber, nitrile rubber, acrylonitrile-butadiene copolymer rubber, diene rubber part, butadiene-styrene rubber,
Mix and blend 30min in the plasticator that internal temperature is 120 DEG C put into by reclaimed rubber, obtains component B,
3) mixing, component A, B are put into internal temperature is to add other component, mix and blend 20min in 120 DEG C of mixing rolls；And
30min is vulcanized, it is thus achieved that product places 3h under conditions of 100 DEG C；
4) molding, puts in forming machine by the product of previous step, it is thus achieved that product.
The above is embodiments of the invention, therefore all according to the structure described in the present patent application scope, feature and principle institute
The equivalence change done or modification, in the range of being all included in present patent application.
Claims (2)
1. one kind is used for the modified tear-resistant functional rubber energy material of magnetic, it is characterised in that the constitutive material that it includes is: chloropharin
Rubber 50-100 part, nitrile rubber 30-45s part, acrylonitrile-butadiene copolymer rubber 55-60 part, diene rubber 40-55 part,
Butadiene-styrene rubber 50-60 part, reclaimed rubber 30-40 part, nano-graphene 10-15 weight portion, magnetic powder 20-30 weight portion, sodium silicate
5-10 weight portion, magnetic iron oxide 10-20 weight portion, magnetic alumina 4-8 weight portion, asphalt base carbon fiber powder 30-35 part,
Non-halogenated organophosphinate 5-7 part, hexamethylenetetramine 8-10 part, tri-methyl-amyl triethoxysilane 2-4 part, conduction cloud
Female powder 0.3-0.5 weight portion, conductive nano graphite powder 0.2-0.4 weight portion, the trimer 0.8-1 weight portion of polyisocyanates,
Polytetrafluoroethylene fibre 1-2 weight portion, nano titanium oxide 8-12 weight portion, poly-dopamine 1-5 weight portion, poly phosphazene 2-6 weight
Amount part, magnetic ferroferric oxide granule 12-20 weight portion, 2-phosphoric acid ethamine 4-8 weight portion, polyethylene imide 1-5 weight portion,
Paraffin 8-12 weight portion, senior aliphat alcohol 7-13 weight portion, ethylenediaminetetraacetic acid 5-9 weight portion, glass fibre 7-13 weight
Part, heat stabilizer 6-12 weight portion, binding agent 6-12 weight portion, PDDA 1-5 weight portion, bentonite
8-16 weight portion, nano-cerium oxide 1-5 weight portion；
The preparation method of described nano-graphene is: added by concentrated sulphuric acid in graphite, through-20 DEG C ~-10 DEG C low temperature stirring 5-12
Hour, then after 0 DEG C ~ 5 DEG C stirrings 5-12 hour, addition potassium permanganate carries out oxidation reaction and obtains graphite oxide solution；Will
Obtain graphite oxide solution is directly added into CTAB, CTAB graphite oxide to be flocculated and modified-reaction obtains modified oxidized stone
Ink solution；Modified graphite oxide solution is filtered, washs, be vacuum dried 24 hours at 50 DEG C, i.e. obtain nano-graphene.
A kind of preparation method for the modified tear-resistant functional rubber energy material of magnetic the most according to claim 1, it is special
Levy and be: comprise the steps of:
(1) magnetic powder, sodium silicate, magnetic iron oxide, magnetic alumina, nano titanium oxide, poly-dopamine dimension are placed in pulverizer
Middle pulverizing, crosses 100-200 mesh sieve, standby as component A；
(2) plasticate, by chlorohydrin rubber, nitrile rubber, acrylonitrile-butadiene copolymer rubber, diene rubber part, butadiene-styrene rubber,
Mix and blend 30min in the plasticator that internal temperature is 120 DEG C put into by reclaimed rubber, obtains component B,
3) mixing, component A, B are put into internal temperature is to add other component, mix and blend 20min in 120 DEG C of mixing rolls；And
30min is vulcanized, it is thus achieved that product places 3h under conditions of 100 DEG C；
4) molding, puts in forming machine by the product of previous step, it is thus achieved that product.
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| CN106901544A (en) * | 2017-03-18 | 2017-06-30 | 匠仙（上海）床垫科技有限公司 | A kind of built-in spring structure of mattress |
| CN108752662A (en) * | 2018-06-29 | 2018-11-06 | 佛山市高明区爪和新材料科技有限公司 | A kind of preparation method of magnetosensitive rubber |
| CN111825892A (en) * | 2020-06-01 | 2020-10-27 | 上海烯望材料科技有限公司 | Melanin and graphene composite material modified latex material and preparation method thereof |
| CN113943418A (en) * | 2021-11-12 | 2022-01-18 | 天津大学 | A kind of rubber-based ionomer and magnetic composite material using the ionomer as matrix and preparation method |
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