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CN105976965A - Ferrite magnetic core material for communication - Google Patents

Ferrite magnetic core material for communication Download PDF

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Publication number
CN105976965A
CN105976965A CN201610149059.6A CN201610149059A CN105976965A CN 105976965 A CN105976965 A CN 105976965A CN 201610149059 A CN201610149059 A CN 201610149059A CN 105976965 A CN105976965 A CN 105976965A
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CN
China
Prior art keywords
parts
core material
oxide
added
magnetic core
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610149059.6A
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Chinese (zh)
Inventor
徐杰
周福林
张文军
张文献
曾性儒
王玉志
董文龙
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TIANCHANG CITY ZHAOTIAN MAGNETOELECTRICITY TECHNOLOGY Co Ltd
Original Assignee
TIANCHANG CITY ZHAOTIAN MAGNETOELECTRICITY TECHNOLOGY Co Ltd
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Application filed by TIANCHANG CITY ZHAOTIAN MAGNETOELECTRICITY TECHNOLOGY Co Ltd filed Critical TIANCHANG CITY ZHAOTIAN MAGNETOELECTRICITY TECHNOLOGY Co Ltd
Priority to CN201610149059.6A priority Critical patent/CN105976965A/en
Publication of CN105976965A publication Critical patent/CN105976965A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/12Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
    • H01F1/14Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
    • H01F1/147Alloys characterised by their composition
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/006Making ferrous alloys compositions used for making ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/02Making ferrous alloys by powder metallurgy
    • C22C33/0207Using a mixture of prealloyed powders or a master alloy

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Dispersion Chemistry (AREA)
  • Power Engineering (AREA)
  • Magnetic Ceramics (AREA)
  • Soft Magnetic Materials (AREA)

Abstract

The invention discloses a ferrite magnetic core material for communication. The ferrite magnetic core material is prepared from the following raw materials in parts by weight: 64-68 parts of iron trioxide, 31.5-34 parts of manganese oxide, 14.5-16.5 parts of zinc oxide, 2.2-3 parts of gallium oxide, 1.5-2 parts of calcium carbonate, 3-4 parts of nano-diamond, 0.2-0.3 part of dimethyl sulfoxide, 0.2-0.3 part of a flatting agent BYK022, 0.4-0.5 part of propylene glycol alginate, 0.2-0.3 part of polydimethylsiloxane, 2-3 parts of a silane coupling agent kh550, 2-3 parts of polyamide resin, 2-2.5 parts of sodium silicate, 1-2 parts of silica sol, 1-2 parts of polyvinyl alcohol, 2-2.3 parts of molybdenum disulfide, 2-2.5 parts of magnetic carbon powder, 1.4-2 parts of nanometer lanthanum oxide, and proper deionized water. The magnetic core material prepared by the invention is high in saturation flux density and low in magnetic loss; due to the novel production process, the material utilization rate is increased; and the magnetic core material is practical, safe and environment-friendly, and worthy of being popularized.

Description

A kind of communication ferrite core material
Technical field
The present invention relates to Ferrite Material technical field, particularly relate to a kind of communication ferrite core material.
Background technology
Along with developing rapidly of electronic information technology, metal magnetic powder core is widely used in the fields such as line filter, outputting inductance and Switching Power Supply, metal magnetic powder core be magnetic powder particles is mixed homogeneously with non magnetic dielectric after a compressing class soft magnetic materials, be broadly divided into ferrocart core, ferrum silica magnetic particle core, high magnetic flux powder core, Fe-Si-Al magnetic core, ferrum tantnickel powder core, ferrum nickel molybdenum powder core and amorphous nano-crystalline powder core.After being mixed with dielectric by ferromagnetic powder granule, carry out suppressing and a kind of soft-magnetic composite material of obtaining is referred to as metal magnetic powder core.Ferromagnetic powder granule after insulating wrapped at its Surface Creation one layer of dielectric insulating film, can effectively improve the resistivity of powder core, reduce eddy-current loss, therefore under metal magnetic powder core is applicable to higher frequency, metal magnetic powder core has become as the ingredient that soft magnetic materials is important, there is the advantages such as higher saturation induction density, good frequency characteristic and permanent magnetic conduction due to it, in modern science and technology field, powder core is widely used in the equipment such as telecommunications, radar, on and off switch as inductance filter, choking-winding.Along with communication technology and the digitized development of electronic product, soft magnetic ferrite and element are proposed new requirement, telecommunications industry needs FERRITE CORE to have low core loss and high magnetic permeability now, to meet the miniaturization of present electric equipment and high efficiency requirement, existing magnetic core is difficult to meet above-mentioned requirements, at present, continuous upgrading along with circuit, electronic component in circuit requires that electric current is higher, and after needing pcrmeability height, saturation flux density height, extra current bias field, pcrmeability declines little magnetics.Metallic magnet opposing ferrite magnet has higher saturation flux density, and metal material is taken as the material of main part of magnet as new use object.But miniaturization, the lightening development along with electronic product, it is desirable to electronic component miniaturization the most therewith, lightening.However as the miniaturization of magnet, in metal material often there is the problem that insulation impedance is low, mechanical strength is low in the material of high magnetic permeability.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of communication ferrite core material.
The present invention is achieved by the following technical solutions:
A kind of communication ferrite core material, it is made up of the raw material of following weight portion: iron sesquioxide 64-68, manganese oxide 31.5-34, zinc oxide 14.5-16.5, gallium oxide 2.2-3, calcium carbonate 1.5-2, Nano diamond 3-4, dimethyl sulfoxide 0.2-0.3, levelling agent BYK0220.2-0.3, alginic acid diol ester 0.4-0.5, polydimethylsiloxane 0.2-0.3, silane coupler kh5502-3, polyamide 2-3, sodium silicate 2-2.5, Ludox 1-2, polyvinyl alcohol 1-2, molybdenum bisuphide 2-2.3, magnetic carbon powder 2-2.5, nano lanthanum oxide 1.4-2, deionized water is appropriate.
Described a kind of communication ferrite core material, is made up of step in detail below:
(1) iron sesquioxide, manganese oxide, zinc oxide and gallium oxide are mixed, it is then added in ball mill wear into fine powder, silane coupler kh550 deionized water is diluted to the solution that solubility is 4-6%, add levelling agent BYK022, dimethyl sulfoxide, polydimethylsiloxane and alginic acid diol ester mix homogeneously, magnetic carbon powder and nano lanthanum oxide is added with 600-800 rev/min of lower dispersed with stirring 6-10min when being heated to 50-60 DEG C, standby after cooling;
(2) nanometer of above-mentioned preparation is mixed liquid to spray in fine powder, then fine powder is placed in baking oven at 110-120 DEG C baking 30-45min, at 230-250 DEG C, then dry 7-10min, be then cooled to room temperature;
(3) it is heated to melting by polyamide; add Nano diamond, molybdenum bisuphide and calcium carbonate to stir; in the product mixing and stirring prepared with step (2); it is added in comminutor make 100-200 mesh afterwards and accounts for 30Wt%; 200-300 mesh accounts for 40Wt%; 300-400 mesh accounts for 20Wt%, and more than 400 mesh accounting for the ratio of 10Wt%, to carry out particle diameter proportioning standby;
(4) sodium silicate is added the deionized water dilution of 10 times amount; add Ludox, polyvinyl alcohol stirs, and granule prepared by step (3) is added thereto evacuation and makes vacuum exceed-0.9 atmospheric pressure, keep 3 minutes; rear taking-up; dry, put into mould, be orientated in magnetic field and be pressed into base substrate under 1.5-2GPa; sinter at 860-960 DEG C under argon shield; insulation 2-2.5h, is tempered 1-1.5h at 750-800 DEG C, the most available.
nullThe invention have the advantage that metal magnetic mixed grinding is become fine powder by the present invention,Make to be uniformly dispersed between composition,Stable performance,And itself is had anticorrosive property、High temperature oxidation resistance and the lanthana of heat stability and magnetic carbon powder are coated in the mechanical property that core material is greatly improved、Shock resistance、High tenacity and adhesion strength,Insulation adhesive material is used to be coated on its surface again,Strengthen the bond strength between granule,And intercept intergranular eddy current,Reduce the eddy-current loss of core material,Good stability of the dimension when using different particle diameter proportionings to make sintering,Volume shrinkage is little,Dimensioning accuracy is high,Finally make further insulation processing,Insulating properties is improve in the case of not changing pcrmeability,Reduce core loss,Core material saturation flux density prepared by the present invention is big,Low magnetic consumes,New production technology improves stock utilization,Improve production efficiency,There is practicality、Safety、The feature of environmental protection,It is worthy to be popularized.
Detailed description of the invention
A kind of communication ferrite core material, is made up of the raw material of following weight portion (kilogram): iron sesquioxide 64, manganese oxide 31.5, zinc oxide 14.5, gallium oxide 2.2, calcium carbonate 1.5, Nano diamond 3, dimethyl sulfoxide 0.2, levelling agent BYK0220.2, alginic acid diol ester 0.4, polydimethylsiloxane 0.2, silane coupler kh5502, polyamide 2, sodium silicate 2, Ludox 1, polyvinyl alcohol 1, molybdenum bisuphide 2, magnetic carbon powder 2, nano lanthanum oxide 1.4, deionized water are appropriate.
Described a kind of communication ferrite core material, is made up of step in detail below:
(1) iron sesquioxide, manganese oxide, zinc oxide and gallium oxide are mixed, it is then added in ball mill wear into fine powder, silane coupler kh550 deionized water is diluted to the solution that solubility is 4%, add levelling agent BYK022, dimethyl sulfoxide, polydimethylsiloxane and alginic acid diol ester mix homogeneously, magnetic carbon powder and nano lanthanum oxide is added with 600 revs/min of lower dispersed with stirring 6min when being heated to 50 DEG C, standby after cooling;
(2) nanometer of above-mentioned preparation is mixed liquid to spray in fine powder, then fine powder is placed in baking oven at 110 DEG C baking 30min, at 230 DEG C, then dry 7min, be then cooled to room temperature;
(3) it is heated to melting by polyamide; add Nano diamond, molybdenum bisuphide and calcium carbonate to stir; in the product mixing and stirring prepared with step (2); it is added in comminutor make 100 mesh afterwards and accounts for 30Wt%; 200 mesh account for 40Wt%; 300 mesh account for 20Wt%, and more than 400 mesh accounting for the ratio of 10Wt%, to carry out particle diameter proportioning standby;
(4) sodium silicate is added the deionized water dilution of 10 times amount; add Ludox, polyvinyl alcohol stirs, and granule prepared by step (3) is added thereto evacuation and makes vacuum exceed an atmospheric pressure, keep 3 minutes; rear taking-up; dry, put into mould, be orientated in magnetic field and be pressed into base substrate under 1.5GPa; sinter at 860 DEG C under argon shield; insulation 2h, is tempered 1h at 750 DEG C, the most available.
The soft magnetic ferrite prepared according to specific embodiment, carries out performance test to it, and result is as follows:
Tensile strength is 168N, and the intensity of magnetization is 264Am2/kg, maximum magnetic flux core loss (100Kc, 200mT): 311KW/m3, and saturation induction density is 1.1T, and coercivity is 7.8Oe, and Curie temperature is > 240 DEG C.

Claims (2)

1. a communication ferrite core material, it is characterized in that, it is made up of the raw material of following weight portion: iron sesquioxide 64-68, manganese oxide 31.5-34, zinc oxide 14.5-16.5, gallium oxide 2.2-3, calcium carbonate 1.5-2, Nano diamond 3-4, dimethyl sulfoxide 0.2-0.3, levelling agent BYK0220.2-0.3, alginic acid diol ester 0.4-0.5, polydimethylsiloxane 0.2-0.3, silane coupler kh5502-3, polyamide 2-3, sodium silicate 2-2.5, Ludox 1-2, polyvinyl alcohol 1-2, molybdenum bisuphide 2-2.3, magnetic carbon powder 2-2.5, nano lanthanum oxide 1.4-2, deionized water is appropriate.
A kind of communication ferrite core material, it is characterised in that be made up of step in detail below:
(1) iron sesquioxide, manganese oxide, zinc oxide and gallium oxide are mixed, it is then added in ball mill wear into fine powder, silane coupler kh550 deionized water is diluted to the solution that solubility is 4-6%, add levelling agent BYK022, dimethyl sulfoxide, polydimethylsiloxane and alginic acid diol ester mix homogeneously, magnetic carbon powder and nano lanthanum oxide is added with 600-800 rev/min of lower dispersed with stirring 6-10min when being heated to 50-60 DEG C, standby after cooling;
(2) nanometer of above-mentioned preparation is mixed liquid to spray in fine powder, then fine powder is placed in baking oven at 110-120 DEG C baking 30-45min, at 230-250 DEG C, then dry 7-10min, be then cooled to room temperature;
(3) it is heated to melting by polyamide; add Nano diamond, molybdenum bisuphide and calcium carbonate to stir; in the product mixing and stirring prepared with step (2); it is added in comminutor make 100-200 mesh afterwards and accounts for 30Wt%; 200-300 mesh accounts for 40Wt%; 300-400 mesh accounts for 20Wt%, and more than 400 mesh accounting for the ratio of 10Wt%, to carry out particle diameter proportioning standby;
(4) sodium silicate is added the deionized water dilution of 10 times amount; add Ludox, polyvinyl alcohol stirs, and granule prepared by step (3) is added thereto evacuation and makes vacuum exceed-0.9 atmospheric pressure, keep 3 minutes; rear taking-up; dry, put into mould, be orientated in magnetic field and be pressed into base substrate under 1.5-2GPa; sinter at 860-960 DEG C under argon shield; insulation 2-2.5h, is tempered 1-1.5h at 750-800 DEG C, the most available.
CN201610149059.6A 2016-03-16 2016-03-16 Ferrite magnetic core material for communication Pending CN105976965A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN201610149059.6A CN105976965A (en) 2016-03-16 2016-03-16 Ferrite magnetic core material for communication

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108640669A (en) * 2018-06-20 2018-10-12 陕西理工大学 A kind of high performance ferrite magnetic material and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005259751A (en) * 2004-03-09 2005-09-22 Neomax Co Ltd Ferrite magnet and manufacturing method thereof
CN103172359A (en) * 2013-03-25 2013-06-26 海宁联丰磁业股份有限公司 Manganese zinc power ferrite magnetic powder core and preparation method thereof
CN104891982A (en) * 2015-04-24 2015-09-09 马鞍山科信咨询有限公司 Rare earth high-magnetic-permeability soft magnetic ferrite and preparation method thereof
CN105097168A (en) * 2015-08-10 2015-11-25 天长市昭田磁电科技有限公司 Magnetic core material to which rare earth element is added

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005259751A (en) * 2004-03-09 2005-09-22 Neomax Co Ltd Ferrite magnet and manufacturing method thereof
CN103172359A (en) * 2013-03-25 2013-06-26 海宁联丰磁业股份有限公司 Manganese zinc power ferrite magnetic powder core and preparation method thereof
CN104891982A (en) * 2015-04-24 2015-09-09 马鞍山科信咨询有限公司 Rare earth high-magnetic-permeability soft magnetic ferrite and preparation method thereof
CN105097168A (en) * 2015-08-10 2015-11-25 天长市昭田磁电科技有限公司 Magnetic core material to which rare earth element is added

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108640669A (en) * 2018-06-20 2018-10-12 陕西理工大学 A kind of high performance ferrite magnetic material and preparation method thereof

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Application publication date: 20160928

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