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CN105967750A - High-adsorptivity ceramic and preparation method thereof - Google Patents

High-adsorptivity ceramic and preparation method thereof Download PDF

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Publication number
CN105967750A
CN105967750A CN201610297260.9A CN201610297260A CN105967750A CN 105967750 A CN105967750 A CN 105967750A CN 201610297260 A CN201610297260 A CN 201610297260A CN 105967750 A CN105967750 A CN 105967750A
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parts
weight
powder
nano
tourmaline
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CN105967750B (en
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郑伟阳
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Foshan Shengshi Huangci New Material Co Ltd
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Abstract

The invention discloses high-adsorptivity ceramic. The high-adsorptivity ceramic is prepared from 22-33 parts by weight of diatomite, 25-47 parts by weight of activated carbon powder, 12-21 parts by weight of polyethylene powder, 5-15 parts by weight of zeolite powder, 10-15 parts by weight of water soluble starch, 21-43 parts by weight of tourmaline, 2-3 parts by weight of nano-silver, 1-4 parts by weight of nano-zinc, 5-12 parts by weight of alumina, 0.5-1.2 parts by weight of iron trioxide, 2-11 parts by weight of titanium dioxide, 10-18 parts by weight of calcium oxide and 30-47 parts by weight of kaolin. The invention also discloses a preparation method of the high-adsorptivity ceramic. Water soluble starch is heated to gasify and decompose so that submicron-level micropore ceramic for adsorbing or filtering very fine bacteria is prepared. The active carbon has a porous structure. Through cooperation of active carbon powder and tourmalinite, a shrinkage rate is low, flexural strength is high and formaldehyde and sulfur dioxide harmful substance adsorption rates are high. The nano-silver and alumina can fast form active oxygen for sterilization, algae extermination and organic matter decomposition when contacting with water so that the high-adsorptivity ceramic has good use effects.

Description

A kind of pottery of high adsorption and preparation method thereof
Technical field
The present invention relates to a kind of pottery, the pottery of a kind of high adsorption.
Background technology
Along with development and the growth in the living standard of society, people are more and more higher to the requirement of quality of life, the drink of clean and safe It it is the guarantee of the quality of life of people with water.The drinking water obtaining clean safety has become worldwide focus.Water is each The main carriers of class pathogen transmission, the 80% of mankind's illnesses is relevant with water pollution.At present, the pollution of water is on the rise, All there is pollution in various degree in the subsoil water of the surface water such as rivers and lakes and some areas, the water shortage problem of water quality causes The extensive concern of people.Absorption method is to remove one of effective ways of pollutant in polluted-water.Absorption be by adsorbate and Intermolecular Van der Waals force, electrostatic force, hydrogen bond and the chemical bond of adsorbent etc. act on, thing adsorbate being adsorbed onto on adsorbent Physicochemical phenomenon, people have begun to use various adsorbing material, and pottery is a kind of adsorbing material that people commonly use, but existing The adsorptivity having pottery is the highest, it is impossible to meet the use demand of people.
Summary of the invention
It is an object of the invention to provide the pottery of a kind of high adsorption, with the problem solving to propose in above-mentioned background technology.
For achieving the above object, the present invention provides following technical scheme:
The pottery of a kind of high adsorption, is made up of according to the raw material of weight portion following: kieselguhr 22-33 part, activated carbon powder 25-47 Part, polyethylene powder 12-21 part, zeolite powder 5-15 part, water soluble starch 10-15 part, tourmaline 21-43 part, nanometer silver 2-3 part, Nano-Zinc 1-4 part, aluminium oxide 5-12 part, iron sesquioxide 0.5-1.2 part, titanium dioxide 2-11 part, calcium oxide 10-18 part and Kaolin 30-47 part.
As the further scheme of the present invention: be made up of according to the raw material of weight portion following: kieselguhr 25-33 part, activated carbon Powder 32-47 part, polyethylene powder 16-21 part, zeolite powder 9-15 part, water soluble starch 12-15 part, tourmaline 29-43 part, Nanometer silver 2.4-3 part, Nano-Zinc 2-4 part, aluminium oxide 8-12 part, iron sesquioxide 0.8-1.2 part, titanium dioxide 5-11 Part, calcium oxide 13-18 part and Kaolin 36-47 part.
As the further scheme of the present invention: be made up of according to the raw material of weight portion following: 29 parts of kieselguhr, activated carbon powder 39 parts, polyethylene powder 18 parts, zeolite powder 12 parts, water soluble starch 14 parts, 36 parts of tourmaline, nanometer silver 2.8 parts, Nano-Zinc 3 parts, aluminium oxide 10 parts, iron sesquioxide 1 part, titanium dioxide 8 parts, calcium oxide 15 parts and Kaolin 41 Part.
The preparation method of the pottery of described high adsorption, specifically comprises the following steps that
Step one, puts into tourmaline pulverizer pulverizing and within 10-15 minute, obtains tourmaline powder, then by tourmaline powder, activated carbon Powder and Kaolin are uniformly mixed, and in ball mill, ball milling is 600-1350 mesh, obtain the first mixed material；
Step 2, adds deionized water in water soluble starch and mix homogeneously obtains starch solution, adds in agitator Starch solution, nanometer silver, Nano-Zinc, aluminium oxide, iron sesquioxide, titanium dioxide and calcium oxide, at 45-85 degree Celsius At a temperature of stir with the rotating speed of 120-240r/min and then to cool down for 0.4-1.2 hour, obtain mixed solution；
Step 3, by kieselguhr, zeolite powder and polyethylene powder mix homogeneously, obtains the second mixed material；
Step 4, adds the first mixed material, the second mixed material and mixed solution, with 180-300r/min in agitator Rotating speed stir 1-3 hour, then use comminutor carry out pelletize；
Step 5, soaks the granule made 10-15 hour in deionized water, is carried out and maturation process, in temperature For the baking oven of 110-160 degree Celsius is incubated 1-4 hour；
Step 6, puts into the granule of drying in Muffle furnace and sinters, and sinters 3-5 hour between 550-850 degree Celsius, Then i.e. can get finished product being cooled to room temperature.
Compared with prior art, the invention has the beneficial effects as follows: the pottery of high adsorption prepared by the present invention, utilize water solublity After heating starch, gasification is decomposed, and makes the pottery with submicron order micropore, can adsorb or that filter sizes is the most tiny is thin The materials such as bacterium；Activated carbon is loose structure, uses activated carbon powder and tourmaline to coordinate, and shrinkage factor is low, and High anti bending strength is right The adsorption rate of the harmful substance such as formaldehyde, sulfur dioxide is high；Use the material such as nanometer silver, aluminium oxide, rapid when meeting with aqueous phase Generation can sterilize, algae removal and the active oxygen of decomposing organic matter, and using effect is good.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the technical scheme of this patent is described in more detail.
Embodiment 1
The pottery of a kind of high adsorption, is made up of according to the raw material of weight portion following: 22 parts of kieselguhr, activated carbon powder 25 parts, Polyethylene powder 12 parts, zeolite powder 5 parts, water soluble starch 10 parts, 21 parts of tourmaline, nanometer silver 2 parts, Nano-Zinc 1 Part, aluminium oxide 5 parts, iron sesquioxide 0.5 part, titanium dioxide 2 parts, calcium oxide 10 parts and Kaolin 30 parts.
The preparation method of the pottery of described high adsorption, specifically comprises the following steps that
Step one, puts into tourmaline pulverizer pulverizing and within 10 minutes, obtains tourmaline powder, then by tourmaline powder, activated carbon powder Being uniformly mixed with Kaolin, in ball mill, ball milling is 600 mesh, obtains the first mixed material；
Step 2, adds deionized water in water soluble starch and mix homogeneously obtains starch solution, adds in agitator Starch solution, nanometer silver, Nano-Zinc, aluminium oxide, iron sesquioxide, titanium dioxide and calcium oxide, at 45 degrees Celsius At a temperature of stir with the rotating speed of 120r/min and then to cool down for 0.4 hour, obtain mixed solution；
Step 3, by kieselguhr, zeolite powder and polyethylene powder mix homogeneously, obtains the second mixed material；
Step 4, adds the first mixed material, the second mixed material and mixed solution, with 180r/min's in agitator Rotating speed stirs 1 hour, then uses comminutor to carry out pelletize；
Step 5, soaks the granule made 10 hours in deionized water, is carried out and maturation process, in temperature is The baking oven of 110 degrees Celsius is incubated 1 hour；
Step 6, puts into the granule of drying in Muffle furnace and sinters, and sinters 3 hours at 550 degrees Celsius, then in cooling Finished product is i.e. can get to room temperature.
Embodiment 2
The pottery of a kind of high adsorption, is made up of according to the raw material of weight portion following: 25 parts of kieselguhr, activated carbon powder 32 parts, Polyethylene powder 16 parts, zeolite powder 9 parts, water soluble starch 12 parts, 29 parts of tourmaline, nanometer silver 2.4 parts, Nano-Zinc 2 Part, aluminium oxide 8 parts, iron sesquioxide 0.8 part, titanium dioxide 5 parts, calcium oxide 13 parts and Kaolin 36 parts.
The preparation method of the pottery of described high adsorption, specifically comprises the following steps that
Step one, puts into tourmaline pulverizer pulverizing and within 12 minutes, obtains tourmaline powder, then by tourmaline powder, activated carbon powder Being uniformly mixed with Kaolin, in ball mill, ball milling is 850 mesh, obtains the first mixed material；
Step 2, adds deionized water in water soluble starch and mix homogeneously obtains starch solution, adds in agitator Starch solution, nanometer silver, Nano-Zinc, aluminium oxide, iron sesquioxide, titanium dioxide and calcium oxide, at 58 degrees Celsius At a temperature of stir with the rotating speed of 170r/min and then to cool down for 0.8 hour, obtain mixed solution；
Step 3, by kieselguhr, zeolite powder and polyethylene powder mix homogeneously, obtains the second mixed material；
Step 4, adds the first mixed material, the second mixed material and mixed solution, with 230r/min's in agitator Rotating speed stirs 1.8 hours, then uses comminutor to carry out pelletize；
Step 5, soaks the granule made 12 hours in deionized water, is carried out and maturation process, in temperature is The baking oven of 130 degrees Celsius is incubated 1-4 hour；
Step 6, puts into the granule of drying in Muffle furnace and sinters, and sinters 3.7 hours at 680 degrees Celsius, then cold But finished product is i.e. can get to room temperature.
Embodiment 3
The pottery of a kind of high adsorption, is made up of according to the raw material of weight portion following: 29 parts of kieselguhr, activated carbon powder 39 parts, Polyethylene powder 18 parts, zeolite powder 12 parts, water soluble starch 14 parts, 36 parts of tourmaline, nanometer silver 2.8 parts, Nano-Zinc 3 parts, aluminium oxide 10 parts, iron sesquioxide 1 part, titanium dioxide 8 parts, calcium oxide 15 parts and Kaolin 41 parts.
The preparation method of the pottery of described high adsorption, specifically comprises the following steps that
Step one, puts into tourmaline pulverizer pulverizing and within 15 minutes, obtains tourmaline powder, then by tourmaline powder, activated carbon powder Being uniformly mixed with Kaolin, in ball mill, ball milling is 1100 mesh, obtains the first mixed material；
Step 2, adds deionized water in water soluble starch and mix homogeneously obtains starch solution, adds in agitator Starch solution, nanometer silver, Nano-Zinc, aluminium oxide, iron sesquioxide, titanium dioxide and calcium oxide, at 74 degrees Celsius At a temperature of stir with the rotating speed of 210r/min and then to cool down for 1 hour, obtain mixed solution；
Step 3, by kieselguhr, zeolite powder and polyethylene powder mix homogeneously, obtains the second mixed material；
Step 4, adds the first mixed material, the second mixed material and mixed solution, with 280r/min's in agitator Rotating speed stirs 3 hours, then uses comminutor to carry out pelletize；
Step 5, soaks the granule made 15 hours in deionized water, is carried out and maturation process, in temperature is The baking oven of 145 degrees Celsius is incubated 4 hours；
Step 6, puts into the granule of drying in Muffle furnace and sinters, and sinters 5 hours at 730 degrees Celsius, then in cooling Finished product is i.e. can get to room temperature.
Embodiment 4
The pottery of a kind of high adsorption, is made up of according to the raw material of weight portion following: 33 parts of kieselguhr, activated carbon powder 47 parts, Polyethylene powder 21 parts, zeolite powder 15 parts, water soluble starch 15 parts, 43 parts of tourmaline, nanometer silver 3 parts, Nano-Zinc 4 Part, aluminium oxide 12 parts, iron sesquioxide 1.2 parts, titanium dioxide 11 parts, calcium oxide 18 parts and Kaolin 47 parts.
The preparation method of the pottery of described high adsorption, specifically comprises the following steps that
Step one, puts into tourmaline pulverizer pulverizing and within 15 minutes, obtains tourmaline powder, then by tourmaline powder, activated carbon powder Being uniformly mixed with Kaolin, in ball mill, ball milling is 1350 mesh, obtains the first mixed material；
Step 2, adds deionized water in water soluble starch and mix homogeneously obtains starch solution, adds in agitator Starch solution, nanometer silver, Nano-Zinc, aluminium oxide, iron sesquioxide, titanium dioxide and calcium oxide, at 85 degrees Celsius At a temperature of stir with the rotating speed of 240r/min and then to cool down for 1.2 hours, obtain mixed solution；
Step 3, by kieselguhr, zeolite powder and polyethylene powder mix homogeneously, obtains the second mixed material；
Step 4, adds the first mixed material, the second mixed material and mixed solution, with 300r/min's in agitator Rotating speed stirs 3 hours, then uses comminutor to carry out pelletize；
Step 5, soaks the granule made 15 hours in deionized water, is carried out and maturation process, in temperature is The baking oven of 160 degrees Celsius is incubated 4 hours；
Step 6, puts into the granule of drying in Muffle furnace and sinters, and sinters 5 hours, then exist between 850 degrees Celsius It is cooled to room temperature and i.e. can get finished product.
Above the better embodiment of this patent is explained in detail, but this patent is not limited to above-mentioned embodiment, In the ken that those of ordinary skill in the art is possessed, it is also possible to make each on the premise of without departing from this patent objective Plant change.

Claims (4)

1. the pottery of a high adsorption, it is characterised in that be made up of according to the raw material of weight portion following: kieselguhr 22-33 Part, activated carbon powder 25-47 part, polyethylene powder 12-21 part, zeolite powder 5-15 part, water soluble starch 10-15 part, electrically Stone 21-43 part, nanometer silver 2-3 part, Nano-Zinc 1-4 part, aluminium oxide 5-12 part, iron sesquioxide 0.5-1.2 part, dioxy Change titanium 2-11 part, calcium oxide 10-18 part and Kaolin 30-47 part.
The pottery of high adsorption the most according to claim 1, it is characterised in that by the following raw material according to weight portion Composition: kieselguhr 25-33 part, activated carbon powder 32-47 part, polyethylene powder 16-21 part, zeolite powder 9-15 part, water solublity Starch 12-15 part, tourmaline 29-43 part, nanometer silver 2.4-3 part, Nano-Zinc 2-4 part, aluminium oxide 8-12 part, three oxidations Two ferrum 0.8-1.2 parts, titanium dioxide 5-11 part, calcium oxide 13-18 part and Kaolin 36-47 part.
The pottery of high adsorption the most according to claim 1, it is characterised in that by the following raw material according to weight portion Composition: 29 parts of kieselguhr, activated carbon powder 39 parts, polyethylene powder 18 parts, zeolite powder 12 parts, water soluble starch 14 parts, 36 parts of tourmaline, nanometer silver 2.8 parts, Nano-Zinc 3 parts, aluminium oxide 10 parts, iron sesquioxide 1 part, titanium dioxide 8 Part, calcium oxide 15 parts and Kaolin 41 parts.
4. the preparation method of the pottery of the high adsorption as described in claim 1-3 is arbitrary, it is characterised in that specifically walk Rapid as follows:
Step one, puts into tourmaline pulverizer pulverizing and within 10-15 minute, obtains tourmaline powder, then by tourmaline powder, activated carbon Powder and Kaolin are uniformly mixed, and in ball mill, ball milling is 600-1350 mesh, obtain the first mixed material；
Step 2, adds deionized water in water soluble starch and mix homogeneously obtains starch solution, adds in agitator Starch solution, nanometer silver, Nano-Zinc, aluminium oxide, iron sesquioxide, titanium dioxide and calcium oxide, at 45-85 degree Celsius At a temperature of stir with the rotating speed of 120-240r/min and then to cool down for 0.4-1.2 hour, obtain mixed solution；
Step 3, by kieselguhr, zeolite powder and polyethylene powder mix homogeneously, obtains the second mixed material；
Step 4, adds the first mixed material, the second mixed material and mixed solution, with 180-300r/min in agitator Rotating speed stir 1-3 hour, then use comminutor carry out pelletize；
Step 5, soaks the granule made 10-15 hour in deionized water, is carried out and maturation process, in temperature For the baking oven of 110-160 degree Celsius is incubated 1-4 hour；
Step 6, puts into the granule of drying in Muffle furnace and sinters, and sinters 3-5 hour between 550-850 degree Celsius, Then i.e. can get finished product being cooled to room temperature.
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