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CN105954591A - Soft-magnetic film material surface resistance high flux testing method - Google Patents

Soft-magnetic film material surface resistance high flux testing method Download PDF

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Publication number
CN105954591A
CN105954591A CN201610283377.1A CN201610283377A CN105954591A CN 105954591 A CN105954591 A CN 105954591A CN 201610283377 A CN201610283377 A CN 201610283377A CN 105954591 A CN105954591 A CN 105954591A
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soft magnetic
probe
magnetic film
high flux
soft
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CN201610283377.1A
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Inventor
向勇
臧亮
林辰
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Ningbo International Material Genetic Engineering Research Institute Co Ltd
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Ningbo International Material Genetic Engineering Research Institute Co Ltd
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Priority to CN201610283377.1A priority Critical patent/CN105954591A/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01RMEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES
    • G01R27/00Arrangements for measuring resistance, reactance, impedance, or electric characteristics derived therefrom
    • G01R27/02Measuring real or complex resistance, reactance, impedance, or other two-pole characteristics derived therefrom, e.g. time constant
    • G01R27/08Measuring resistance by measuring both voltage and current

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Hall/Mr Elements (AREA)

Abstract

The invention relates to a soft-magnetic film material surface resistance high flux testing method. The method comprises the steps of: S1, manufacturing soft-magnetic film samples, wherein a high flux combination material ion beam sputtering film deposition system is adopted, the plurality of soft-magnetic film samples different in component are prepared on a toughened glass substrate, and the plurality of soft-magnetic film samples are arranged in an array mode on the toughened glass substrate; S2, providing a high flux resistivity tester which comprises a probe substrate bearing a plurality of groups of four-point probes which are arranged in the array mode corresponding to the plurality of soft-magnetic film samples; S3, testing the resistance performance of the soft-magnetic film samples, wherein the four-point probes contact the soft-magnetic film samples, a current I and a potential difference V are measured, the plurality of soft-magnetic film samples are tested at one time, and a high flux screening technology is adopted to test the soft-magnetic film samples; and S4, calculating the resistivity.

Description

A kind of soft magnetic material film sheet resistance high flux method of testing
[technical field]
The present invention relates to a kind of physical quantity method of testing, particularly relate to a kind of soft magnetism Thin-film material surface resistance high flux method of testing.
[background technology]
Soft magnetic material film becomes at write head, perpendicular magnetic recording medium, thin film The aspect such as depressor and inductance component is widely used.Traditional ferrite Thin-film material has high resistivity and an advantage of high pcrmeability, but saturated magnetic Change intensity the lowest, especially when operating frequency close to time, its pcrmeability is drastically Decline, but under low saturation magnetization, low resistivity, hot conditions Crystallization tendency, low Curie temperature make pcrmeability frequency spectrum generation multiple resonance, Heat stability is deteriorated.Ferrocobalt thin film has high saturation magnetization, but It is special that low resistivity and big magnetostriction make it difficult to obtain good soft magnetism Property.
The high efficiency of electronic device, high frequency, low-dimensional and low-loss such one Soft magnetic material film is proposed higher by the development trend of individual " two high two low " Requirement, the highest saturation magnetization, low coercivity, high resistivity, High pcrmeability, high ferromagnetic resonance frequency etc..Especially recent years, The unit single magnetic from original single farmland district till now that records of disk is received Rice grain, recording mode by recorded present perpendicular recording in original face, These all make the packing density of disk exponentially rise.The increasing of magnetic recording density Add the development on the one hand having benefited from magnetic head, on the other hand have benefited from the magnetic of high-quality The exploitation of material.Soft magnetic material film is as the substrate of perpendicular magnetic recording medium Layer, to have high resistivity at high frequencies, plays increase magnetic flux and makes write Magnetic head preferably writes information to record the effect of medium.
The most conventional mode is to prepare soft magnetic material film, then by four spies The resistance of every piece of soft magnetic material film tested by pin tester, therefore tests substantial amounts of During many ratios component soft magnetic material film, testing efficiency is low, labor intensive cost Greatly, test period is long, also easily produces experiment by mistake in substantial amounts of test simultaneously Difference.
[summary of the invention]
During for overcoming existing test multielement, many ratios soft magnetic material film, need The skills such as wanting single sample to test one by one, therefore efficiency is low, and cost is high, time-consuming length Art problem, the present invention provides a kind of soft magnetic material film sheet resistance high pass to measure Method for testing.
The present invention solves the technical scheme of technical problem, and to be to provide a kind of soft magnetism thin Membrane material sheet resistance high flux method of testing, including step S1, makes soft magnetism Film sample: use high flux combined material ion beam sputtering thin film deposition system System, prepares the soft magnetic film that multiple constituent content is different on safety glass substrate Sample, plurality of soft magnetic film sample array on safety glass substrate sets Put;Step S2, it is provided that a high flux resistivity tester: it includes a probe Substrate, carries and at most organizes four probes, and described many groups four probes are thin with multiple soft magnetisms The corresponding array of membrane sample is arranged;Step S3, test soft magnetic film sample electricity Resistive energy: by four probe contact soft magnetic film samples, detected current value I and electricity Potential difference V, disposable test the plurality of soft magnetic film sample, and use high pass Soft magnetic film sample is tested by amount triage techniques;And step S4, calculate electricity Resistance rate.
Preferably, described four probe arrays are the arrays of eight row eight row, often Eight group of four probe configuration one power supply of row, an ammeter, a potential difference meter.
Preferably, described often organize four probes include the first probe, the second probe, 3rd probe and the 4th probe, the first probe and the 4th probe connect power supply, and Connect ammeter, the second probe and the 3rd probe and connect potential difference meter, four probes During contact soft magnetic film sample, soft magnetic film sample has electric current to pass through, interior Portion produces potential difference.
Preferably, described first probe and the spacing of the second probe, the second probe With the spacing of the 3rd probe, the spacing of the 3rd probe and the 4th probe is equal.
Preferably, described safety glass substrate length × a width of 80mm × 80mm.
Preferably, soft magnetic film sample length × a width of 10mm of described preparation × 10mm。
Preferably, in described step S4, one component of one group of four probe contact contains The soft magnetic film sample of amount, according to described potential difference V recorded and current value I, Use formula ρ=2 π SV (B0I)-1Calculate soft magnetic film sample resistivity, wherein ρ is soft magnetic film sample resistivity, and S is adjacent probe spacing, B0For revising Coefficient.
Compared with prior art, one soft magnetic material film sheet resistance of the present invention High flux method of testing has the advantage that employing high flux combined material ion Beam sputtering thin film deposition system can disposably prepare the soft magnetism of multiple constituent content Film sample, multiple soft magnetic film sample array formulas arrange, facilitate subsequent high pass Amount resistivity meter test, is also beneficial to the softest by the fast data search recorded Magnetic thin film sample, four probe array formulas of high flux resistivity tester are arranged, Can be with soft magnetic film sample one_to_one corresponding engaged test, by many on probe substrate Organize four probes to contact with corresponding many groups soft magnetic film sample respectively, disposably survey Obtain current value I and potential difference V of described many group soft magnetic film samples.By record Potential difference, current value and resistivity computing formula, can calculate soft magnetic film sample The resistivity of product, according to test result, can search the group of required resistivity Divide content soft magnetic film sample.Thus it is low to solve testing efficiency, cost is high, The problems such as time-consuming length, can also decrease experimental error simultaneously.
[accompanying drawing explanation]
Fig. 1 is one soft magnetic material film sheet resistance high flux of the present invention test The operating process schematic diagram of method.
Fig. 2 is one soft magnetic material film sheet resistance high flux of the present invention test Method provides soft magnetic material film schematic diagram to be tested, including 64 The constituent content difference soft magnetic film sample of 10mm × 10mm.
Fig. 3 is one soft magnetic material film sheet resistance high flux of the present invention test The high flux resistivity tester structural representation that method uses.
Fig. 4 is a soft magnetic film sample resistance performance test signal shown in Fig. 2 Figure.
Fig. 5 is one soft magnetic material film sheet resistance high flux of the present invention test Method integrated testability schematic diagram.
[detailed description of the invention]
In order to make the purpose of the present invention, technical scheme and advantage are more clear bright In vain, below in conjunction with accompanying drawing and embodiment, the present invention is carried out the most in detail Explanation.Should be appreciated that specific embodiment described herein is only in order to explain The present invention, is not intended to limit the present invention.
Soft magnetic materials (soft magnetic material) is when magnetization occurs Coercivity is not more than the material of 100A/m, and such material is referred to as soft magnetic bodies. Soft magnetic materials has the magnetic material of low-coercivity and high magnetic permeability, it is easy to magnetic Change, be also easy to demagnetization, be widely used in electrical equipment and electronic equipment.Typical case Soft magnetic materials, the maximum intensity of magnetization can be realized by minimum external magnetic field, Applying most soft magnetic materials is ferro-silicium (stalloy) and various soft magnetism Ferrite etc..Wherein coercivity (coercive force, represent with Hc) is Refer to magnetic material after saturated magnetization, its magnetic induction when external magnetic field returns to zero Intensity B does not fall back on zero, only at former magnetizing field rightabout plus certain The magnetic field of size just can make magnetic induction return to zero, and this magnetic field is referred to as coercive Magnetic field, also known as coercivity.
Refer to Fig. 1, one soft magnetic material film sheet resistance high pass of the present invention Weight testing method includes step S1, makes soft magnetic film sample;Step S2, One high flux resistivity tester is provided;Step S3, tests soft magnetic film sample Product resistive performance;And step S4, calculate resistivity.Its specific embodiments For:
Step S1, makes soft magnetic film sample: refer to Fig. 2, it is provided that a steel Change glass substrate 10, use high flux combined material ion beam sputtering thin film to sink Long-pending system prepares the soft magnetic film sample 101 of many ratios component.In high flux group Condensation material ion beam sputtering thin film deposition system prepare intracavity, configure ferrum, cobalt Two targets on the workbench of carrying target, safety glass substrate 10 is long × A width of 80mm × 80mm is fixed on the sample stage of base, and mask plate is fixed on Between sample stage and target, according to the demand of soft magnetic film sample 101, select Suitable mask plate, target is positioned at above mask plate, and base is rotatable, and carries On dynamic sample stage, safety glass substrate 10 rotates, and mask plate is provided with aperture, Different mask plate little hole number thereon are different with aperture.Combine at this high flux Material ions beam sputtering thin film deposition system, starts base and makes safety glass substrate 10 horizontal directions rotate, by ion beam sputtering target, at safety glass base Sheet 10 surface deposition is prepared as soft magnetic film sample 101.
High flux combined material ion beam sputtering thin film deposition system is for height Special efficient coating apparatus prepared by flux combined material chip.This system uses Brand-new fine vacuum, multi cavity design thinking, change target and in situ by storage target in situ Heat treatment integrates, and the ion beam being equipped with assisting ion source deposition spatters Penetrate system, it is achieved that high homogeneity, high-compactness, high-purity, high-resolution Combined material chip prepare.This system includes sputtering chamber, storage target chamber, changes target Chamber, situ heat treatment chamber and sample cavity, accurately control continuous moving mask system, Sputtering of materials is made to arrive the number of times of sample area different with the time such that it is able at steel The gradient preparing the most up to a million different components on change glass substrate 10 is sunk The soft magnetic film samples 101 such as long-pending, sequential aggradation.
At safety glass substrate 10 surface deposition 64 10mm × 10mm of preparation Soft magnetic film sample 101, is 1-64 by from left to right number consecutively, forms eight The array of row eight row, soft magnetic film sample 101 constituent content is different, component bag Including ferrum, cobalt and oxygen, Qi Zhongtie, cobalt and oxygen mass percent scope are respectively as follows: 60-70%, 29-39%, 0-1%, soft magnetic film sample 101 thicknesses of layers is 0.1mm。
Step S2, it is provided that a high flux resistivity tester 1: refer to Fig. 3, High flux resistivity tester 1 include probe substrate 11, four probe 13, Power supply 15, ammeter 17 and potential difference meter 19.Probe substrate 11 is used for holding Carrying many groups four probes 13, the present embodiment is 64 groups, is the array of eight row eight row Arrange, corresponding with multiple soft magnetic film samples 101, one group of four probe 13 Including first probe the 131, second probe 132 being from left to right arranged in order, 3rd probe the 133, the 4th probe 134, is metal material, is arranged on one On bar straight line, and the first probe 131 and spacing of the second probe 132, the Two probe 131 and the spacing of the 3rd probe 132, the 3rd probe 131 and the 4th The spacing of probe 132 is the most equal, and eight group of four probe 13 of every a line configures an electricity Source 15, ammeter 17 and a potential difference meter 19, the first probe 131 and Four probes 134 switch on power 15, and connect ammeter 17, the second probe 132 Connecting potential difference meter 19 with the 3rd probe 133, one group of four probe 13 tests one The soft magnetic film sample 101 of individual ratio component.
Step S3, tests soft magnetic film sample resistance performance: first by high flux Resistivity tester 1 preheats, estimation soft magnetic film sample 101 resistance or resistance The scope of rate, and scope arranges suitable range according to this, then places soft magnetism thin Membrane sample 101, by four probes 13 and the soft magnetic film sample 101 of array arrangement Contact, the power supply 15 that the first probe 131 is connected with the 4th probe 134 provides Constant current, makes soft magnetic film sample 101 have electric current to pass through, the most internal product Give birth to potential difference, from ammeter 17 read current value I, from potential difference meter 19 Read potential difference V.
Why use four probe method to measure resistance, be because four probe 13 Hes Soft magnetic film sample 101 has a contact resistance, this contact resistance when contacting Very big, if measure electric current with the first probe 131 and the 4th probe 134 simultaneously And potential difference, contact resistance will affect the result of measurement.Second probe 132 With the voltage that the 3rd between probe 133 is that potential difference meter 19 uses penalty method to measure , as long as there is no letting out of electric current between the second probe 132 and the 3rd probe 133 Dew, it becomes possible to avoid contact with the error that resistance brings, improves the precision measured. This method of testing utilizes accelerated test that soft magnetic film sample 101 is carried out high pass Amount screening, directly disposably completes multiple soft magnetic film sample in the same time 101 resistive performance tests.High flux screening (High throughput Screening, HTS) technology refers to the experiment with molecular level and cellular level Based on method, using microplate format as experimental tool carrier, grasp with automatization Make system and perform process of the test, with sensitive quick detecting instrument collection experiment knot Really data, analyze and process experimental data with computer, at same time detecting number With the soft magnetic film sample 101 of ten million, and with the associated databases support obtained The technical system of operating, it has trace, the feature such as quick, sensitive and accurate.
Refer to Fig. 5, high flux resistivity tester 1 tests soft magnetic film sample Whole structure figure during product 101, the point 103 in soft magnetic film sample 101 When testing soft magnetic film sample 101 for high flux resistivity tester 1, four visit Pin 13 and the contact position of soft magnetic film sample 101.
Step S4, calculates resistivity: use high flux resistivity tester 1 Soft magnetic film sample 101 resistivity is tested, according to the first probe 131 And the electric current I recorded between the 4th probe 134 and the second probe 132 and the 3rd spy Potential difference V recorded between pin 133, it is possible to calculate the electricalresistivityρ of thin film:
C = 2 π ( 1 D 1 + 1 D 2 - 1 D 1 + D 2 - 1 D 2 + D 3 ) - 1
ρ=CV/I (2-1)
Wherein C is probe coefficient, maker be measured probe spacing After determine, and being supplied to user, D1 is the first probe 131 and the second probe Spacing between 132, D2 is between the second probe 132 and the 3rd probe 133 Spacing, D3 is the spacing between the 3rd probe 133 and the 4th probe 134, four Individual probe equidistantly arranges, and represents by adjacent probe spacing S, therefore D1=D2=D3=S.
C=2 π S
ρ=2 π SV/I (2-2)
Formula (2-2) is to derive, when the geometry of sample when sample infinity Size is more many times greater than the spacing of probe, can regard infinitely great as, therefore can be by Formula ρ=2 π SV/I calculates the resistivity of sample;If sample is not nothing Poor big, but thickness, lateral dimension is certain, at this moment utilizes four probe method to measure During resistivity, cannot directly use formula (2-2), further analyze Show, as long as formula (2-2) being introduced suitable correction in four probe method Coefficient B0, B0Size and probe spacing with soft magnetic film sample 101 Correction function and sample shape is relevant with measurement position correction function (can be by accordingly Several tables check in), now:
ρ=2 π SV (B0I)-1 (2-3)
Therefore the resistivity of soft magnetic film sample can be calculated by formula (2-3).
Compared with prior art, one soft magnetic material film sheet resistance of the present invention High flux method of testing has the advantage that employing high flux combined material ion Beam sputtering thin film deposition system can disposably prepare the soft magnetism of multiple constituent content Film sample 101, multiple soft magnetic film sample 101 arrays are arranged, after convenience Continuous high flux resistivity meter 1 is tested, and is also beneficial to by the fast data search recorded Corresponding soft magnetic film sample 101, four probes of high flux resistivity tester 1 13 arrays are arranged, and can contact with soft magnetic film sample 101 one_to_one corresponding.Will Many groups of four probes 13 on probe substrate 11 are thin with corresponding many groups soft magnetism respectively Membrane sample 101 contacts, and disposably records described many group soft magnetic film samples 101 Current value I and potential difference V.By the potential difference recorded, current value and resistivity Computing formula, can calculate the resistivity of soft magnetic film sample 101, Ke Yigen According to test result, search the constituent content soft magnetic film sample of required resistivity 101.Thus it is low to solve testing efficiency, the problems such as cost is high, time-consuming length, Experimental error can also be decreased simultaneously.
The foregoing is only present pre-ferred embodiments, not in order to limit The present invention, all any amendments made within principle of the present invention, equivalent Within protection scope of the present invention all should being comprised with improvement etc..

Claims (7)

1. a soft magnetic material film sheet resistance high flux method of testing, it is special Levy and be, including:
Step S1, make soft magnetic film sample: use high flux combined material from Sub-beam sputtering thin film deposition system, prepares multiple component on safety glass substrate The soft magnetic film sample that content is different, plurality of soft magnetic film sample is at tempering On glass substrate, array is arranged;
Step S2, it is provided that a high flux resistivity tester: it includes a probe Substrate, carries and at most organizes four probes, and described many groups four probes are thin with multiple soft magnetisms The corresponding array of membrane sample is arranged;
Step S3, tests soft magnetic film sample resistance performance: by four probe contacts Soft magnetic film sample, detected current value I and potential difference V, described in disposable test Multiple soft magnetic film samples, and use High Throughput Screening Assay to soft magnetic film sample Product are tested;
And step S4, calculate resistivity.
2. a kind of soft magnetic material film sheet resistance as claimed in claim 1 is high Flux test method, it is characterised in that: described four probe arrays are eight row eight row Array, often eight group of four probe configuration one power supply of row, an ammeter, a current potential Difference meter.
3. a kind of soft magnetic material film sheet resistance as claimed in claim 1 is high Flux test method, it is characterised in that: described four probes of often organizing include the first spy Pin, the second probe, the 3rd probe and the 4th probe, the first probe and the 4th is visited Pin connects power supply, and connects ammeter, and the second probe and the 3rd probe connect electricity Tentiometer, during four probe contact soft magnetic film samples, soft magnetic film sample has electricity Stream passes through, the most internal generation potential difference.
4. a kind of soft magnetic material film sheet resistance as claimed in claim 3 is high Flux test method, it is characterised in that: described first probe and the second probe Spacing, the second probe and the spacing of the 3rd probe, the 3rd probe and the 4th probe Spacing equal.
5. a kind of soft magnetic material film sheet resistance as claimed in claim 1 is high Flux test method, it is characterised in that: described safety glass substrate length × a width of 80mm×80mm。
6. a kind of soft magnetic material film sheet resistance as claimed in claim 1 is high Flux test method, it is characterised in that: the soft magnetic film sample of described preparation is long × a width of 10mm × 10mm.
7. a kind of soft magnetic material film sheet resistance as claimed in claim 1 is high Flux test method, it is characterised in that: in step S4, one group of four probe contact The soft magnetic film sample of one constituent content, according to described potential difference V recorded With current value I, use formula ρ=2 π SV (B0I)-1Calculate soft magnetic film sample electricity Resistance rate, wherein ρ is soft magnetic film sample resistivity, and S is adjacent probe spacing, B0For correction factor.
CN201610283377.1A 2016-04-29 2016-04-29 Soft-magnetic film material surface resistance high flux testing method Pending CN105954591A (en)

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CN108627546A (en) * 2018-04-16 2018-10-09 北京工业大学 A kind of method for real-time measurement and device of nano-multilayer film modulation ratio
CN108802102A (en) * 2018-07-18 2018-11-13 北京铂阳顶荣光伏科技有限公司 A kind of detection method and system of coating quality
CN111157884A (en) * 2020-01-03 2020-05-15 中广核工程有限公司 Relay resistance measurement system and method
CN111796148A (en) * 2020-07-31 2020-10-20 上海华力微电子有限公司 Resistance test structure
CN112051452A (en) * 2020-07-27 2020-12-08 山东天岳先进材料科技有限公司 High-precision graphite crucible resistivity testing device and method
CN114034743A (en) * 2021-11-19 2022-02-11 山东钢铁集团日照有限公司 Method for measuring surface resistance of cold-rolled passivated steel plate

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Publication number Priority date Publication date Assignee Title
CN108627546A (en) * 2018-04-16 2018-10-09 北京工业大学 A kind of method for real-time measurement and device of nano-multilayer film modulation ratio
CN108802102A (en) * 2018-07-18 2018-11-13 北京铂阳顶荣光伏科技有限公司 A kind of detection method and system of coating quality
CN111157884A (en) * 2020-01-03 2020-05-15 中广核工程有限公司 Relay resistance measurement system and method
CN112051452A (en) * 2020-07-27 2020-12-08 山东天岳先进材料科技有限公司 High-precision graphite crucible resistivity testing device and method
CN111796148A (en) * 2020-07-31 2020-10-20 上海华力微电子有限公司 Resistance test structure
CN114034743A (en) * 2021-11-19 2022-02-11 山东钢铁集团日照有限公司 Method for measuring surface resistance of cold-rolled passivated steel plate

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Application publication date: 20160921