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CN105937012A - Anti-corrosion alloy steel for drilling drill pipe - Google Patents

Anti-corrosion alloy steel for drilling drill pipe Download PDF

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Publication number
CN105937012A
CN105937012A CN201610552343.8A CN201610552343A CN105937012A CN 105937012 A CN105937012 A CN 105937012A CN 201610552343 A CN201610552343 A CN 201610552343A CN 105937012 A CN105937012 A CN 105937012A
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CN
China
Prior art keywords
rhenium
sulfur
alloy steel
ratio
rubidium
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Pending
Application number
CN201610552343.8A
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Chinese (zh)
Inventor
吴用镜
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Individual
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Individual
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Priority to CN201610552343.8A priority Critical patent/CN105937012A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/008Ferrous alloys, e.g. steel alloys containing tin
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/10Ferrous alloys, e.g. steel alloys containing cobalt
    • C22C38/105Ferrous alloys, e.g. steel alloys containing cobalt containing Co and Ni
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/32Ferrous alloys, e.g. steel alloys containing chromium with boron

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Articles (AREA)

Abstract

The invention discloses anti-corrosion alloy steel for a drilling drill pipe. The anti-corrosion alloy steel is prepared from, by mass, 0.28%-0.32% of carbon, 0.16%-0.22% of molybdenum, 0.6%-0.8% of chrome, 0.4%-0.8% of silicon, 1.9%-2.3% of nickel, 0.09%-0.13% of rubidium, 0.11%-0.15% of vanadium, 0.11%-0.15% of boron, 0.03%-0.07% of niobium, 0.05%-0.09% of cobalt, 0.006%-0.008% of nitrogen, 0.01%-0.05% of tin, 0.06%-0.08% of rhenium and sulfur and the balance iron, wherein the mass ratio of rhenium to sulfur is (5-7):1. The alloy steel has the excellent corrosion resistance and is suitable for being used for preparing the drilling drill pipe.

Description

One creeps into drilling rod corrosion-resisting alloy steel
Technical field
The invention belongs to creep into drilling rod field, be specifically related to one and creep into drilling rod corrosion-resisting alloy steel.
Background technology
Drilling rod is the afterbody steel pipe with a chain for binding criminals stricture of vagina, is used for connecting rig landscape apparatus and being positioned at drilling well bottom boring mill equipment or bottom outlet dress Put.The purposes of drilling rod is that drilling mud is transported to drill bit, and improves, reduces or rotate bottom outlet device together with drill bit.Drilling rod Allow for bearing huge interior external pressure, distort, bend and vibrate.
In engineering higher to the requirement creeping into drilling rod steel, both needed that there is wearability, there is a need to corrosion resistance.
Summary of the invention
It is an object of the invention to provide one and creep into drilling rod corrosion-resisting alloy steel.
The above-mentioned purpose of the present invention is achieved by techniques below scheme:
One creeps into drilling rod corrosion-resisting alloy steel, and its chemical composition and each mass percent be: carbon 0.28~0.32%, molybdenum 0.16~0.22%, chromium 0.6~0.8%, silicon 0.4~0.8%, nickel 1.9~2.3%, rubidium 0.09~0.13%, vanadium 0.11~0.15%, boron 0.11~0.15%, niobium 0.03~0.07%, cobalt 0.05~0.09%, nitrogen 0.006~0.008%, stannum 0.01~0.05%, rhenium and sulfur are altogether 0.06~0.08%, the ratio of mass percent shared by rhenium and sulfur is 5~7:1, and remaining is ferrum.
Further, described creep into drilling rod corrosion resisting alloy steel chemical composition and each mass percent be: carbon 0.30%, Molybdenum 0.19%, chromium 0.7%, silicon 0.6%, nickel 2.1%, rubidium 0.11%, vanadium 0.13%, boron 0.13%, niobium 0.05%, cobalt 0.07%, Nitrogen 0.007%, stannum 0.03%, rhenium and sulfur totally 0.07%, the ratio of mass percent shared by rhenium and sulfur is 6:1, and remaining is ferrum.
Further, described creep into drilling rod corrosion resisting alloy steel chemical composition and each mass percent be: carbon 0.28%, Molybdenum 0.16%, chromium 0.6%, silicon 0.4%, nickel 1.9%, rubidium 0.09%, vanadium 0.11%, boron 0.11%, niobium 0.03%, cobalt 0.05%, Nitrogen 0.006%, stannum 0.01%, rhenium and sulfur totally 0.06%, the ratio of mass percent shared by rhenium and sulfur is 5:1, and remaining is ferrum.
Further, described creep into drilling rod corrosion resisting alloy steel chemical composition and each mass percent be: carbon 0.32%, Molybdenum 0.22%, chromium 0.8%, silicon 0.8%, nickel 2.3%, rubidium 0.13%, vanadium 0.15%, boron 0.15%, niobium 0.07%, cobalt 0.09%, Nitrogen 0.008%, stannum 0.05%, rhenium and sulfur totally 0.08%, the ratio of mass percent shared by rhenium and sulfur is 7:1, and remaining is ferrum.
Advantages of the present invention:
The steel alloy that the present invention provides has the decay resistance of excellence, is suitable for preparation and creeps into drilling rod.
Detailed description of the invention
Further illustrate the essentiality content of the present invention below in conjunction with embodiment, but do not limit scope with this.To the greatest extent The present invention is explained in detail by pipe with reference to preferred embodiment, it will be understood by those within the art that, can be to the present invention Technical scheme modify or equivalent, without deviating from the spirit and scope of technical solution of the present invention.
Embodiment 1: corrosion-resisting alloy steel
Chemical composition and each mass percent be: carbon 0.30%, molybdenum 0.19%, chromium 0.7%, silicon 0.6%, nickel 2.1%, rubidium 0.11%, vanadium 0.13%, boron 0.13%, niobium 0.05%, cobalt 0.07%, nitrogen 0.007%, stannum 0.03%, rhenium and sulfur totally 0.07%, The ratio of mass percent shared by rhenium and sulfur is 6:1, and remaining is ferrum.
Embodiment 2: corrosion-resisting alloy steel
Chemical composition and each mass percent be: carbon 0.28%, molybdenum 0.16%, chromium 0.6%, silicon 0.4%, nickel 1.9%, rubidium 0.09%, vanadium 0.11%, boron 0.11%, niobium 0.03%, cobalt 0.05%, nitrogen 0.006%, stannum 0.01%, rhenium and sulfur totally 0.06%, The ratio of mass percent shared by rhenium and sulfur is 5:1, and remaining is ferrum.
Embodiment 3: corrosion-resisting alloy steel
Chemical composition and each mass percent be: carbon 0.32%, molybdenum 0.22%, chromium 0.8%, silicon 0.8%, nickel 2.3%, rubidium 0.13%, vanadium 0.15%, boron 0.15%, niobium 0.07%, cobalt 0.09%, nitrogen 0.008%, stannum 0.05%, rhenium and sulfur totally 0.08%, The ratio of mass percent shared by rhenium and sulfur is 7:1, and remaining is ferrum.
Embodiment 4: corrosion-resisting alloy steel
Chemical composition and each mass percent be: carbon 0.30%, molybdenum 0.19%, chromium 0.7%, silicon 0.6%, nickel 2.1%, rubidium 0.11%, vanadium 0.13%, boron 0.13%, niobium 0.05%, cobalt 0.07%, nitrogen 0.007%, stannum 0.03%, rhenium and sulfur totally 0.07%, The ratio of mass percent shared by rhenium and sulfur is 5:1, and remaining is ferrum.
Embodiment 5: corrosion-resisting alloy steel
Chemical composition and each mass percent be: carbon 0.30%, molybdenum 0.19%, chromium 0.7%, silicon 0.6%, nickel 2.1%, rubidium 0.11%, vanadium 0.13%, boron 0.13%, niobium 0.05%, cobalt 0.07%, nitrogen 0.007%, stannum 0.03%, rhenium and sulfur totally 0.07%, The ratio of mass percent shared by rhenium and sulfur is 7:1, and remaining is ferrum.
Embodiment 6: comparative example
Chemical composition and each mass percent be: carbon 0.30%, molybdenum 0.19%, chromium 0.7%, silicon 0.6%, nickel 2.1%, rubidium 0.11%, vanadium 0.13%, boron 0.13%, niobium 0.05%, cobalt 0.07%, nitrogen 0.007%, stannum 0.03%, rhenium and sulfur totally 0.07%, The ratio of mass percent shared by rhenium and sulfur is 4:1, and remaining is ferrum.
Embodiment 7: comparative example
Chemical composition and each mass percent be: carbon 0.30%, molybdenum 0.19%, chromium 0.7%, silicon 0.6%, nickel 2.1%, rubidium 0.11%, vanadium 0.13%, boron 0.13%, niobium 0.05%, cobalt 0.07%, nitrogen 0.007%, stannum 0.03%, rhenium and sulfur totally 0.07%, The ratio of mass percent shared by rhenium and sulfur is 8:1, and remaining is ferrum.
Embodiment 8: effect example
The steel alloy of the embodiment 1~7 prepared has been carried out corrosion-resistant test.The steel alloy of embodiment 1~7 is respectively put into In the potassium hydroxide solution of the NaCl solution of 5wt%, the sulfuric acid solution of 10wt% and 10wt%, minute is 1 year.
Result see table.
The NaCl solution of 5wt% The sulfuric acid solution of 10wt% The potassium hydroxide of 10wt%
Embodiment 1 0.0001mm/ 0.002mm/ 0.001mm/
Embodiment 4 0.0002mm/ 0.002mm/ 0.001mm/
Embodiment 5 0.0002mm/ 0.002mm/ 0.001mm/
Embodiment 6 0.0009mm/ 0.011mm/ 0.009mm/
Embodiment 7 0.0010mm/ 0.013mm/ 0.009mm/
Embodiment 2,3 test result is basically identical with embodiment 4,5.
The steel alloy that the present invention provides has the decay resistance of excellence, is suitable for preparation and creeps into drilling rod.
The effect of above-described embodiment indicates that the essentiality content of the present invention, but does not limit protection scope of the present invention with this. It will be understood by those within the art that, technical scheme can be modified or equivalent, and not take off Essence and protection domain from technical solution of the present invention.

Claims (4)

1. one kind is crept into drilling rod corrosion-resisting alloy steel, it is characterised in that its chemical composition and each mass percent be: carbon 0.28~0.32%, molybdenum 0.16~0.22%, chromium 0.6~0.8%, silicon 0.4~0.8%, nickel 1.9~2.3%, rubidium 0.09~0.13%, vanadium 0.11~0.15%, boron 0.11~0.15%, niobium 0.03~0.07%, cobalt 0.05~0.09%, nitrogen 0.006~0.008%, stannum 0.01~0.05%, Rhenium and sulfur totally 0.06~0.08%, the ratio of mass percent shared by rhenium and sulfur is 5~7:1, and remaining is ferrum.
The most according to claim 1 creep into drilling rod corrosion-resisting alloy steel, it is characterised in that its chemical composition and each matter Amount percentage ratio is: carbon 0.30%, molybdenum 0.19%, chromium 0.7%, silicon 0.6%, nickel 2.1%, rubidium 0.11%, vanadium 0.13%, boron 0.13%, niobium 0.05%, cobalt 0.07%, nitrogen 0.007%, stannum 0.03%, rhenium and sulfur totally 0.07%, percent mass shared by rhenium and sulfur The ratio of ratio is 6:1, and remaining is ferrum.
The most according to claim 1 creep into drilling rod corrosion-resisting alloy steel, it is characterised in that its chemical composition and each matter Amount percentage ratio is: carbon 0.28%, molybdenum 0.16%, chromium 0.6%, silicon 0.4%, nickel 1.9%, rubidium 0.09%, vanadium 0.11%, boron 0.11%, niobium 0.03%, cobalt 0.05%, nitrogen 0.006%, stannum 0.01%, rhenium and sulfur totally 0.06%, percent mass shared by rhenium and sulfur The ratio of ratio is 5:1, and remaining is ferrum.
The most according to claim 1 creep into drilling rod corrosion-resisting alloy steel, it is characterised in that its chemical composition and each matter Amount percentage ratio is: carbon 0.32%, molybdenum 0.22%, chromium 0.8%, silicon 0.8%, nickel 2.3%, rubidium 0.13%, vanadium 0.15%, boron 0.15%, niobium 0.07%, cobalt 0.09%, nitrogen 0.008%, stannum 0.05%, rhenium and sulfur totally 0.08%, percent mass shared by rhenium and sulfur The ratio of ratio is 7:1, and remaining is ferrum.
CN201610552343.8A 2016-07-11 2016-07-11 Anti-corrosion alloy steel for drilling drill pipe Pending CN105937012A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106854734A (en) * 2016-11-23 2017-06-16 安徽瑞鑫自动化仪表有限公司 A kind of temperature sensor corrosion-and high-temp-resistant steel alloy and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000070113A1 (en) * 1999-05-18 2000-11-23 The Atri Group Ltd. Iron-silicon alloy and alloy product, exhibiting improved resistance to hydrogen embrittlement and method of making the same
JP2007254881A (en) * 2006-02-27 2007-10-04 Jfe Steel Kk Marine corrosion resistant steel
US20080302501A1 (en) * 2005-11-29 2008-12-11 Nicolas Binot Steel for Hot Tooling, and Part Produced From Said Steel, Method for the Production Thereof, and Uses of the Same
CN102892910A (en) * 2010-05-10 2013-01-23 新日铁住金株式会社 High-strength steel sheet and method for producing same
CN103732775A (en) * 2011-07-27 2014-04-16 新日铁住金株式会社 High-strength cold-rolled steel sheet with excellent stretch flangeability and precision punchability, and process for producing same
CN105537796A (en) * 2014-10-23 2016-05-04 株式会社神户制钢所 Ship welding joint with excellent corrosion resistance

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000070113A1 (en) * 1999-05-18 2000-11-23 The Atri Group Ltd. Iron-silicon alloy and alloy product, exhibiting improved resistance to hydrogen embrittlement and method of making the same
US20080302501A1 (en) * 2005-11-29 2008-12-11 Nicolas Binot Steel for Hot Tooling, and Part Produced From Said Steel, Method for the Production Thereof, and Uses of the Same
JP2007254881A (en) * 2006-02-27 2007-10-04 Jfe Steel Kk Marine corrosion resistant steel
CN102892910A (en) * 2010-05-10 2013-01-23 新日铁住金株式会社 High-strength steel sheet and method for producing same
CN103732775A (en) * 2011-07-27 2014-04-16 新日铁住金株式会社 High-strength cold-rolled steel sheet with excellent stretch flangeability and precision punchability, and process for producing same
CN105537796A (en) * 2014-10-23 2016-05-04 株式会社神户制钢所 Ship welding joint with excellent corrosion resistance

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106854734A (en) * 2016-11-23 2017-06-16 安徽瑞鑫自动化仪表有限公司 A kind of temperature sensor corrosion-and high-temp-resistant steel alloy and preparation method thereof

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Application publication date: 20160914