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CN105931734A - Porcelainized nano-composite insulating material aluminum alloy fireproof cable - Google Patents

Porcelainized nano-composite insulating material aluminum alloy fireproof cable Download PDF

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Publication number
CN105931734A
CN105931734A CN201610470964.1A CN201610470964A CN105931734A CN 105931734 A CN105931734 A CN 105931734A CN 201610470964 A CN201610470964 A CN 201610470964A CN 105931734 A CN105931734 A CN 105931734A
Authority
CN
China
Prior art keywords
aluminum alloy
layer
nano
fire
fireproof cable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610470964.1A
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Chinese (zh)
Inventor
郑建强
马万安
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HUBEI ZHONGNAN CABLE RESEARCH INSTITUTE Co Ltd
Original Assignee
HUBEI ZHONGNAN CABLE RESEARCH INSTITUTE Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HUBEI ZHONGNAN CABLE RESEARCH INSTITUTE Co Ltd filed Critical HUBEI ZHONGNAN CABLE RESEARCH INSTITUTE Co Ltd
Priority to CN201610470964.1A priority Critical patent/CN105931734A/en
Publication of CN105931734A publication Critical patent/CN105931734A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29Protection against damage caused by extremes of temperature or by flame
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/02Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of metals or alloys
    • H01B1/023Alloys based on aluminium
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/46Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes silicones
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • H01B7/22Metal wires or tapes, e.g. made of steel
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29Protection against damage caused by extremes of temperature or by flame
    • H01B7/295Protection against damage caused by extremes of temperature or by flame using material resistant to flame

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Nanotechnology (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Insulated Conductors (AREA)

Abstract

The invention discloses a porcelainized nano-composite insulating material aluminum alloy fireproof cable. The porcelainized nano-composite insulating material aluminum alloy fireproof cable comprises a conductive core, a fire-resistant insulating layer, a wrapping layer, an armored layer, and a sheath layer, the fire-resistant insulating layer is covered on outside of the conductive core, the wrapping layer is covered on the outside of the fire-resistant insulating layer, the armored layer is covered on the outside of the wrapping layer, and the sheath layer is covered on the outside of the armored layer; the conductive core is made of rare earth high-iron aluminum alloy material, and the fire-resistant insulating layer is made of porcelainized nano-composite fire-resistant silicon rubber insulating material, and the conductive core can be one or more. The porcelainized nano-composite fire-resistant silicon rubber insulating material has good character of being good in elastic of the normal silicon rubber, and is non-toxic, odorless, high and low temperature resistant, ozone ageing resistant, weather ageing resistant, and excellent in electric insulation performance, and has good processing property of the normal high temperature silicon rubber, and is capable of maintaining the soft cable state at the temperature of -40 DEG C to 200 DEG C.

Description

One can porcelain nano-composite insulating materials of aluminum alloy fireproof cable
Technical field
The present invention relates to technical field of electric wires and cables, being specifically related to one can porcelain nano-composite insulating materials of aluminum alloy fireproof cable.
Background technology
Power cable is transmission flare, expands the material of the murther of fire scope, can produce substantial amounts of dense smoke when cable fire, makes rescue work that difficulty to occur, and containing substantial amounts of halogen gas in dense smoke, has increased the weight of the harm to rescue personnel.393 building fires burn to death the analysis of causes of 1464 people according to the U.S., and wherein lethal because of poisoning and anoxia have 1062 people, accounts for the 75.5% of dead sum, is had 359 people by what flame was directly burnt to death, only account for 24.4%.People can be smoked by substantial amounts of smog and poison, it is impossible to departs from on-the-spot and is scorched to death, and also makes scene put out the fire and rescues generation difficulty.
Summary of the invention
The technical problem to be solved is to provide a kind of aluminium alloy fireproof cable of a kind of low cigarette, Halogen, the Important building engineering adapting to environmental requirement that fire-retardant, nontoxic, safety is high, environment friendly and pollution-free, temperature resistant grade is high.
For solving above-mentioned technical problem, the technical solution adopted in the present invention is: one can porcelain nano-composite insulating materials of aluminum alloy fireproof cable, including conductor wire core, refractory insulating layer, belting layer, armor, restrictive coating, it is coated with refractory insulating layer in the outside of conductor wire core, the outside of refractory insulating layer is coated with belting layer, the outside of belting layer is coated with armor, the outside of armor is coated with restrictive coating, described conductor wire core uses rare earth high-iron aluminum alloy materials to make, described refractory insulating layer uses and can make by porcelainization nano combined fire-resistant silicon rubber insulant, described conductor wire core can be one or more.
Preferably, the sectional area of described conductor wire core is 10-400mm2.
Preferably, described conductor wire core can be single round aluminum-alloy wire, it is also possible to being twisted into if being pressed by the dried layer multiply circle soft single line of aluminium alloy, every layer has some with prismatic conductor, and per share have some conductor monofilament to constitute.
Preferably, the geometry of the plurality of conductor wire core is circular.
Preferably, described restrictive coating uses halogen-free intumescent flame-retardant refractory material.
Preferably, described belting layer uses ceramic fireproof silicone rubber composite band material wrapped to form through the most overlapping.
Preferably, described armor uses high-strength aluminum alloy band self-locking armouring mode.
The present invention provides the one can porcelain nano-composite insulating materials of aluminum alloy fireproof cable, can porcelainization nano combined fire-resistant silicon rubber insulant it has possessed the fundamental characteristics of usual silicone rubber good springiness at normal temperatures, there is nontoxic, tasteless, high-low temperature resistant, resistance to ozone aging, weatherable, excellent electrical insulation capability, also possessed the processing characteristics that common high temperature silicone rubber is good, flexible cable state can have been kept at 40 degrees below zero to about 200 degree above freezing.When flame invasion and attack temperature reaches more than 300 degree; rigid sponge ceramic body can be converted to by original soft condition; hardening rear fireproof jointing sheath is internal produces hole; be conducive to insulation; so sponge ceramic body has significantly fire prevention and intercepts the effect of high temperature, thus the internal structure being effectively protected cable does not occur metataxis and electrical property change.
Ceramic fireproof silicone rubber composite tape layers uses ceramic fireproof silicone rubber composite band wrapped to form through the most overlapping, ceramic fireproof silicone rubber composite band is to prolong pressure with ceramic fireproof silicone rubber and high temperature resistance glass fiber cloth for base material to be composited, and starts the hardening housing forming ceramic-like under 350 DEG C of temperatures above.The housing that " ceramic " is hard in case of fire can play the most fire-retardant, fire-resistant, fire prevention, the effect of fire insulation, reaches as high as 3000 DEG C, effective guarantee circuit unimpeded.
Armature of cable layer uses aluminum alloy strip self-locking armouring mode, being totally different from traditional steel-tape armouring structure, this armor has resistance to compression, tension, shock resistance, flexible, corrosion-resistant, lightweight, installation is convenient, can exempt from pipeline or crane span structure installation, insect protected damaged by rats, fire-retardant rank high.
Halogen-free intumescent flame-retardant refractory protection uses expansion type flame-retarding technology; with nitrogen as host element; in the environment of fire; the sheath material being made up of acid source (dehydrant), carbon source (carbon forming agent) and source of the gas (foaming agent) three part expands rapidly; surface forms the porous carbon froth bed of densification; be securely attached on cable, play good oxygen barrier, heat insulation, press down cigarette and can prevent drippage effect.Halogen-free intumescent flame-retardant refractory material has the function of good flame-retardant smoke inhibition and self-extinguishment, smog will not be produced and there is the hydrogen halide that the corrosivity of " secondary disaster " is the strongest, low cigarette, Halogen, fire-retardant and there is high elongation at break (> 350%) and easy to process.The fire-retardant fireproof effect of halogen-free intumescent flame-retardant protective layer is mainly the low heat conductivity of the heat insulation-foaming structure by foamed char and to thermal-radiating reflection, trapping effect, limits underlying polymer oxygen supply and the releasing of suppression combustibility degraded gas and effectively prevents the melted drippage behavior of polymer combustion generation to reach the effect of fire-retardant fireproof.
Accompanying drawing explanation
The invention will be further described with embodiment below in conjunction with the accompanying drawings:
Fig. 1 is the structural representation of the present invention;
In figure: conductor wire core 1, flame retardant coating insulating barrier 2, belting layer 3, armor 4, restrictive coating 5.
Detailed description of the invention
As shown in Figure 1; one can porcelain nano-composite insulating materials of aluminum alloy fireproof cable; including a cable core and the external protection being coated on outside cable core; cable core is made up of conductor wire core 1, flame retardant coating insulating barrier 2; the employing rare earth high-iron aluminum alloy materials of described conductor wire core 1, refractory insulating layer 2 uses can porcelainization nano combined fire-resistant silicon rubber insulant.Can porcelainization nano combined fire-resistant silicon rubber material it has possessed the fundamental characteristics of usual silicone rubber good springiness at normal temperatures, there is nontoxic, tasteless, high-low temperature resistant, resistance to ozone aging, weatherable, excellent electrical insulation capability, also possessed the processing characteristics that common high temperature silicone rubber is good, flexible cable state can have been kept at 40 degrees below zero to about 200 degree above freezing.When flame invasion and attack temperature reaches more than 300 degree; rigid sponge ceramic body can be converted to by original soft condition; hardening rear fireproof jointing sheath is internal produces hole; be conducive to insulation; so sponge ceramic body has significantly fire prevention and intercepts the effect of high temperature, thus the internal structure being effectively protected cable does not occur metataxis and electrical property change.
Cable external protection is followed successively by belting layer 3, armor 4, restrictive coating 5 from inside to outside; belting layer (3) uses ceramic fireproof silicone rubber composite band material wrapped to form through the most overlapping; armor (4) uses high-strength aluminum alloy band self-locking armouring mode, and restrictive coating (5) uses halogen-free intumescent flame-retardant refractory material.
Belting layer 3 uses ceramic fireproof silicone rubber composite band wrapped to form through the most overlapping, ceramic fireproof silicone rubber composite band is to prolong pressure with ceramic fireproof silicone rubber and high temperature resistance glass fiber cloth for base material to be composited, and starts the hardening housing forming ceramic-like under 350 DEG C of temperatures above.The housing that " ceramic " is hard in case of fire can play the most fire-retardant, fire-resistant, fire prevention, the effect of fire insulation, reaches as high as 3000 DEG C, effective guarantee circuit unimpeded.
Armor 4 uses aluminum alloy strip self-locking armouring mode, being totally different from traditional steel-tape armouring structure, this armor has resistance to compression, tension, shock resistance, flexible, corrosion-resistant, lightweight, installation is convenient, can exempt from pipeline or crane span structure installation, insect protected damaged by rats, fire-retardant rank high.
Restrictive coating 5 uses expansion type flame-retarding technology, with nitrogen as host element, in the environment of fire, the sheath material being made up of acid source (dehydrant), carbon source (carbon forming agent) and source of the gas (foaming agent) three part expands rapidly, surface forms the porous carbon froth bed of densification, be securely attached on cable, play good oxygen barrier, heat insulation, press down cigarette and can prevent drippage effect.Halogen-free intumescent flame-retardant refractory material has the function of good flame-retardant smoke inhibition and self-extinguishment, smog will not be produced and there is the hydrogen halide that the corrosivity of " secondary disaster " is the strongest, low cigarette, Halogen, fire-retardant and there is high elongation at break (> 350%) and easy to process.The fire-retardant fireproof effect of halogen-free intumescent flame-retardant protective layer is mainly the low heat conductivity of the heat insulation-foaming structure by foamed char and to thermal-radiating reflection, trapping effect, limits underlying polymer oxygen supply and the releasing of suppression combustibility degraded gas and effectively prevents the melted drippage behavior of polymer combustion generation to reach the effect of fire-retardant fireproof.
Owing to the present invention is provided with multi-layer fireproofing structure, it is achieved that multiple protection functions, it is ensured that the comprehensive fire protecting performance of invention.
The present invention is not limited to above-mentioned preferred forms; anyone can draw other various forms of products under the enlightenment of the present invention; though but in its shape or structure, make any change, every have same as the present application or akin technical scheme, within all falling within protection scope of the present invention.

Claims (7)

1. one kind can porcelain nano-composite insulating materials of aluminum alloy fireproof cable, including conductor wire core (1), refractory insulating layer (2), belting layer (3), armor (4), restrictive coating (5), it is coated with refractory insulating layer (2) in the outside of conductor wire core (1), the outside of refractory insulating layer (2) is coated with belting layer (3), the outside of belting layer (3) is coated with armor (4), the outside of armor (4) is coated with restrictive coating (5), it is characterized in that: described conductor wire core (1) uses rare earth high-iron aluminum alloy materials to make, described refractory insulating layer (2) uses and can make by porcelainization nano combined fire-resistant silicon rubber insulant, described conductor wire core (1) can be one or more.
The most according to claim 1, one can porcelain nano-composite insulating materials of aluminum alloy fireproof cable, it is characterised in that: the sectional area of described conductor wire core (1) is 10-400mm2.
The most according to claim 1, one can porcelain nano-composite insulating materials of aluminum alloy fireproof cable, it is characterized in that: described conductor wire core (1) can be single round aluminum-alloy wire, it is twisted into if can also be pressed by the dried layer multiply circle soft single line of aluminium alloy, every layer has some with prismatic conductor, and per share have some conductor monofilament to constitute.
The most according to claim 1, one can porcelain nano-composite insulating materials of aluminum alloy fireproof cable, it is characterised in that: the geometry of the plurality of conductor wire core (1) is circular.
The most according to claim 1, one can porcelain nano-composite insulating materials of aluminum alloy fireproof cable, it is characterised in that: described restrictive coating (5) uses halogen-free intumescent flame-retardant refractory material.
The most according to claim 1, one can porcelain nano-composite insulating materials of aluminum alloy fireproof cable, it is characterised in that: described belting layer (3) uses ceramic fireproof silicone rubber composite band material wrapped to form through the most overlapping.
The most according to claim 1, one can porcelain nano-composite insulating materials of aluminum alloy fireproof cable, it is characterised in that: described armor (4) uses high-strength aluminum alloy band self-locking armouring mode.
CN201610470964.1A 2016-06-27 2016-06-27 Porcelainized nano-composite insulating material aluminum alloy fireproof cable Pending CN105931734A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610470964.1A CN105931734A (en) 2016-06-27 2016-06-27 Porcelainized nano-composite insulating material aluminum alloy fireproof cable

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Application Number Priority Date Filing Date Title
CN201610470964.1A CN105931734A (en) 2016-06-27 2016-06-27 Porcelainized nano-composite insulating material aluminum alloy fireproof cable

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201576467U (en) * 2009-11-03 2010-09-08 上海索谷电缆集团有限公司 Environment-friendly, low-smoke halogen-free and flame-retardant polyolefine insulated cable
CN202534408U (en) * 2012-01-18 2012-11-14 青岛中核能线缆科技有限公司 Fireproof cable equipped with S-shape aluminum alloy self-locking sheath
CN103489525A (en) * 2013-09-13 2014-01-01 江苏远洋东泽电缆股份有限公司 Ship and warship protection cable high in current carrying capacity and low in surface temperature rise and manufacture method thereof
US20140008098A1 (en) * 2012-07-05 2014-01-09 Prysmian S.P.A. Electrical cable resistant to fire, water and mechanical stresses
CN104425072A (en) * 2013-09-10 2015-03-18 上海永进特种电缆有限公司 Rare-earth high-iron-aluminum-alloy environment-friendly nanometer refuge floor fire resisting cable
CN205692611U (en) * 2016-06-27 2016-11-16 湖北中南电缆研究所有限公司 One can porcelain nano-composite insulating materials of aluminum alloy fireproof cable

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201576467U (en) * 2009-11-03 2010-09-08 上海索谷电缆集团有限公司 Environment-friendly, low-smoke halogen-free and flame-retardant polyolefine insulated cable
CN202534408U (en) * 2012-01-18 2012-11-14 青岛中核能线缆科技有限公司 Fireproof cable equipped with S-shape aluminum alloy self-locking sheath
US20140008098A1 (en) * 2012-07-05 2014-01-09 Prysmian S.P.A. Electrical cable resistant to fire, water and mechanical stresses
CN104425072A (en) * 2013-09-10 2015-03-18 上海永进特种电缆有限公司 Rare-earth high-iron-aluminum-alloy environment-friendly nanometer refuge floor fire resisting cable
CN103489525A (en) * 2013-09-13 2014-01-01 江苏远洋东泽电缆股份有限公司 Ship and warship protection cable high in current carrying capacity and low in surface temperature rise and manufacture method thereof
CN205692611U (en) * 2016-06-27 2016-11-16 湖北中南电缆研究所有限公司 One can porcelain nano-composite insulating materials of aluminum alloy fireproof cable

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Application publication date: 20160907

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