CN105926498A - Protective fence with surface being coated with drainage layers and manufacturing method - Google Patents
Protective fence with surface being coated with drainage layers and manufacturing method Download PDFInfo
- Publication number
- CN105926498A CN105926498A CN201610313579.6A CN201610313579A CN105926498A CN 105926498 A CN105926498 A CN 105926498A CN 201610313579 A CN201610313579 A CN 201610313579A CN 105926498 A CN105926498 A CN 105926498A
- Authority
- CN
- China
- Prior art keywords
- hydrophobic layer
- guard rail
- layer
- chrome
- zinc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000001681 protective effect Effects 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title abstract description 6
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical group CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 claims abstract description 33
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 16
- 239000011701 zinc Substances 0.000 claims abstract description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 14
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 11
- 239000007788 liquid Substances 0.000 claims abstract description 11
- 230000002209 hydrophobic effect Effects 0.000 claims description 41
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 9
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 8
- 239000011259 mixed solution Substances 0.000 claims description 8
- 238000005422 blasting Methods 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 238000007591 painting process Methods 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 4
- 150000001336 alkenes Chemical class 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 abstract description 10
- 238000000576 coating method Methods 0.000 abstract description 10
- 230000007797 corrosion Effects 0.000 abstract description 7
- 238000005260 corrosion Methods 0.000 abstract description 7
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 229910001868 water Inorganic materials 0.000 abstract description 3
- 230000035699 permeability Effects 0.000 abstract description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- QXYJCZRRLLQGCR-UHFFFAOYSA-N dioxomolybdenum Chemical compound O=[Mo]=O QXYJCZRRLLQGCR-UHFFFAOYSA-N 0.000 description 2
- 238000003618 dip coating Methods 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007590 electrostatic spraying Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 235000003642 hunger Nutrition 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 108700002783 roundabout Proteins 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 230000037351 starvation Effects 0.000 description 1
- 230000003075 superhydrophobic effect Effects 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01F—ADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
- E01F15/00—Safety arrangements for slowing, redirecting or stopping errant vehicles, e.g. guard posts or bollards; Arrangements for reducing damage to roadside structures due to vehicular impact
- E01F15/02—Continuous barriers extending along roads or between traffic lanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
- B05D1/04—Processes for applying liquids or other fluent materials performed by spraying involving the use of an electrostatic field
- B05D1/06—Applying particulate materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/08—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/24—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing hexavalent chromium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Structural Engineering (AREA)
- Civil Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Architecture (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Refuge Islands, Traffic Blockers, Or Guard Fence (AREA)
Abstract
The invention discloses a protective fence with the surface being coated with drainage layers and belongs to the field of protection facilities. The surface of the protective fence sequentially comprises an inorganic zinc-chrome layer, the first drainage layer and the second drainage layer from the inner layer to the outer layer. The first drainage layer is a tetradecanoic acid drainage layer. The second drainage layer is a graphene drainage layer. The corrosion resistance of the protective fence can be greatly improved through a zinc coating, and zinc-chrome liquid has very high permeability and adhesive quality, so that the stability of the coating is ensured. Through the internal and external cooperation of the tetradecanoic acid drainage layer and the graphene drainage layer, drainage is accelerated, and meanwhile water molecules are prevented from entering the coating; and thus the zinc coating is effectively protected, and the corrosion resistance of the protective fence is greatly improved. The invention further discloses a manufacturing method of the protective fence.
Description
Technical field
The present invention relates to a kind of guard rail, be especially a kind of surface and be covered with guard rail and the manufacture method of hydrophobic layer, belong to protective equipment field.
Background technology
Along with the development in city, road construction develops the most therewith as one of the face in city, and the development of road guard-rail therein also should not be underestimated.In the construction and maintenance of conventional guard rail, the subject matter run into is the Anticorrosion of guard rail, and it is to make an issue of in the coating of protective guard surface mostly that people solve problem, such as improve starvation ability or can the thickness that coating be improved etc., these can solve the problem that the corrosion-prone problem of guard rail to a certain extent, these are all to solve Anticorrosion by a round-about way, and such indirect antiseptical measure can not reach self-cleaning effect.But, go to solve etching problem for proposing measure actively, the surface of guard rail will be applied to by hydrophobic material, this is always the key point that people ignore, and hydrophobic material can accomplish self-cleaning effect, meanwhile, the corrosion of guard rail base material can also be suppressed on one's own initiative and slow down the Oxidation on surface, under the overall background that science and technology develops rapidly, such technology being applied to the of guard rail own, always this area can not be broken through.
Summary of the invention
The technical problem to be solved is to overcome prior art defect, it is provided that a kind of superficial residence that can effectively prevent hydrone guard rail, and the surface of the probability reducing corrosion is covered with guard rail and the manufacture method of hydrophobic layer.
In order to solve above-mentioned technical problem, the surface that the present invention provides is covered with the guard rail of hydrophobic layer, and described protective guard surface is followed successively by inorganic zinc layers of chrome, the first hydrophobic layer, the second hydrophobic layer from internal layer to outer layer；Described first hydrophobic layer is tetradecanoic acid hydrophobic layer, and described second hydrophobic layer is Graphene hydrophobic layer.
In the present invention, the tetradecanoic acid molar concentration in described tetradecanoic acid hydrophobic layer is 0.2mol/L, ethanol molar concentration is 0.2mol/L, hydrochloric acid molar concentration is 5mol/L.
In the present invention, described inorganic zinc layers of chrome is zinc chrome liquid, and described zinc chrome liquid is made up of the chromate of 25wt%, the zinc metal sheet of 35wt% and 40wt% aluminium flake.
The present invention also provides for the preparation method that above-mentioned surface is covered with the guard rail of hydrophobic layer, comprises the following steps:
1), guard rail is carried out ungrease treatment；
2), protective guard surface is carried out Shot Blasting；
3), the guard rail after Shot Blasting is immersed in zinc chrome liquid, after then drying, solidify and cooling down, forms inorganic zinc layers of chrome；
4), take tetradecanoic acid, hydrochloric acid, ethanol are configured to mixed solution, described tetradecanoic acid molar concentration is 0.2mol/L, and ethanol molar concentration is 0.2mol/L, and hydrochloric acid molar concentration is 5 mol/L；60h-80h in guard rail submergence mixed solution after step 3) being processed, forms the first hydrophobic layer at protective guard surface；
5), with electrostatic painting process at the protective guard surface graphite spraying alkene powder after step 4) process, the second hydrophobic layer is formed.
The present invention having the beneficial effects that compared to prior art: (1), the zinc coat formed by zinc chrome liquid, can be greatly improved guard rail corrosion resistance, and zinc chrome liquid has the highest permeability and tack, it is ensured that the stability of coating；Tetradecanoic acid hydrophobic layer can form the first hydrophobic protective to guard rail, forms uniform ground floor on surface by the method for dip-coating；Graphene the second hydrophobic layer afterwards protects further, utilizes the super hydrophobic performance of Graphene can accelerate the eliminating of protective guard surface moisture, and shortening hydrone is in the time of staying of protective guard surface, thus reduces the probability of corrosion；By tetradecanoic acid hydrophobic layer and the interior fit on of Graphene hydrophobic layer, while accelerating draining, stop hydrone to enter coating, thus be effectively protected zinc coat, use guard rail corrosion resistance to be greatly improved；Meanwhile, hydrophobic layer can also make protective guard surface keep cleaning to a certain extent；(2), present invention process simple, easy to make, it is easy to accomplish.
Detailed description of the invention
Being further elaborated technical scheme below in conjunction with specific embodiment, following embodiment is merely to illustrate rather than is limiting to the claimed invention.
Embodiment
1
Surface of the present invention is covered with the guard rail of hydrophobic layer, and the surface of guard rail is followed successively by inorganic zinc layers of chrome, tetradecanoic acid hydrophobic layer and Graphene hydrophobic layer from internal layer to outer layer, and its manufacturing process is:
1, guard rail being immersed in soak at room temperature 20min in alkali liquor, remove the greasy dirt of protective guard surface, the formula of its alkali liquor is sodium hydroxide, sodium carbonate, sodium silicate, water, and the mol ratio of sodium hydroxide, sodium carbonate, sodium silicate and water is 12:4:1:3；
2, make protective guard surface coarse by Shot Blasting technique, such adhesive force improving follow-up coating that processes, prolongation coating life；
3, the guard rail after Shot Blasting is immersed in 30min in zinc chrome liquid, then dries, hot setting cooling down, form inorganic zinc layers of chrome at protective guard surface；Zinc chrome liquid is made up of the chromate of 25wt%, the zinc metal sheet of 35wt% and 40wt% aluminium flake, and zinc metal sheet and aluminium flake obtain lamellar passivation protective guard surface under the effect of chromate.
4, take tetradecanoic acid, hydrochloric acid, ethanol are configured to mixed solution, tetradecanoic acid molar concentration therein is 0.2mol/L, and ethanol molar concentration is 0.2mol/L, and hydrochloric acid molar concentration is 5 mol/L, guard rail is immersed in dip-coating 60h in mixed solution, forms tetradecanoic acid hydrophobic layer at guard rail；
5, using molybdenum dioxide as high-temperature lubricant, with electrostatic painting process graphite spraying alkene powder, the temperature of electrostatic spraying is 150 DEG C, and spray pressure is-0.09 MPa, solidifies 20min, form Graphene hydrophobic layer at guard rail after spraying；Using electrostatic painting process, it utilizes the principle of electrostatic, so that graphene powder self is with electrostatic, strengthens the adhesive force of graphene powder, thus improves the stability of hydrophobic layer,
Embodiment
2
During guard rail is immersed in mixed solution in step 3, time of immersion is 80h；Spray pressure is-0.05 MPa in steps of 5；Remaining step is same as in Example 1.
Embodiment
3
During guard rail is immersed in mixed solution in step 3, time of immersion is 70h；Spray pressure is-0.07 MPa in steps of 5；Remaining step is same as in Example 1.
The technical scheme provided the embodiment of the present invention above is described in detail, principle and the embodiment of the embodiment of the present invention are set forth by specific case used herein, and the explanation of above example is only applicable to help to understand the principle of the embodiment of the present invention；Simultaneously for one of ordinary skill in the art, according to the embodiment of the present invention, all will change in detailed description of the invention and range of application, in sum, this specification content should not be construed as limitation of the present invention.
Claims (4)
1. a surface is covered with the guard rail of hydrophobic layer, it is characterised in that: described protective guard surface is followed successively by inorganic zinc layers of chrome, the first hydrophobic layer, the second hydrophobic layer from internal layer to outer layer；Described first hydrophobic layer is tetradecanoic acid hydrophobic layer, and described second hydrophobic layer is Graphene hydrophobic layer.
Surface the most according to claim 1 is covered with the guard rail of hydrophobic layer, it is characterised in that: the tetradecanoic acid molar concentration in described tetradecanoic acid hydrophobic layer is 0.2mol/L, ethanol molar concentration is 0.2mol/L, hydrochloric acid molar concentration is 5mol/L.
Surface the most according to claim 1 and 2 is covered with the guard rail of hydrophobic layer, it is characterised in that: described inorganic zinc layers of chrome is zinc chrome liquid, and described zinc chrome liquid is made up of the chromate of 25wt%, the zinc metal sheet of 35wt% and 40wt% aluminium flake.
4. surface described in claim 1 is covered with the preparation method of guard rail of hydrophobic layer, it is characterised in that comprise the following steps:
1), guard rail is carried out ungrease treatment；
2), protective guard surface is carried out Shot Blasting；
3), the guard rail after Shot Blasting is immersed in zinc chrome liquid, after then drying, solidify and cooling down, forms inorganic zinc layers of chrome；
4), take tetradecanoic acid, hydrochloric acid, ethanol are configured to mixed solution, described tetradecanoic acid molar concentration is 0.2mol/L, and ethanol molar concentration is 0.2mol/L, and hydrochloric acid molar concentration is 5 mol/L；60h-80h in guard rail submergence mixed solution after step 3) being processed, forms the first hydrophobic layer；
5), with electrostatic painting process at the protective guard surface graphite spraying alkene powder after step 4) process, the second hydrophobic layer is formed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610313579.6A CN105926498B (en) | 2016-05-12 | 2016-05-12 | Surface is covered with the protective fence and production method of hydrophobic layer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610313579.6A CN105926498B (en) | 2016-05-12 | 2016-05-12 | Surface is covered with the protective fence and production method of hydrophobic layer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105926498A true CN105926498A (en) | 2016-09-07 |
| CN105926498B CN105926498B (en) | 2019-02-22 |
Family
ID=56835714
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610313579.6A Active CN105926498B (en) | 2016-05-12 | 2016-05-12 | Surface is covered with the protective fence and production method of hydrophobic layer |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105926498B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108332582A (en) * | 2018-01-26 | 2018-07-27 | 南京新奥环保技术有限公司 | A kind of white air temperature vaporizer of release |
| CN108325802A (en) * | 2017-01-19 | 2018-07-27 | 毅铭兴源新钢科技（北京）有限公司 | A kind of zinc steel railing, rail compression spring graphene surface aseptic technic |
| CN109403245A (en) * | 2018-09-10 | 2019-03-01 | 天津大学 | Road guard air cleaning unit |
| CN111410921A (en) * | 2020-05-02 | 2020-07-14 | 冯亿生 | Composite protective film |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6325107B1 (en) * | 1994-12-29 | 2001-12-04 | Usui Kokusai Sangyo Kaisha Limited | Metal pipeline having a protective coating layer for an automobile |
| CN2746039Y (en) * | 2004-10-27 | 2005-12-14 | 王震宇 | Guard rail having anticorrosion layer |
| CN200988950Y (en) * | 2006-08-16 | 2007-12-12 | 徐州正菱涂装有限公司 | High way railing with reinforced zinc base composite coating layer system |
| CN101205704A (en) * | 2006-12-22 | 2008-06-25 | 徐州正菱涂装有限公司 | Reforming technique for old coated express-way guard-rail plates |
| CN101250861A (en) * | 2008-03-12 | 2008-08-27 | 张家港市亚东高频焊接型钢制造有限公司 | Nano antisepsis protection fence upright |
| CN101942654A (en) * | 2010-10-27 | 2011-01-12 | 东南大学 | Method for immersing superhydrophobic surface of aluminum alloy in one step |
| CN102643967A (en) * | 2012-05-01 | 2012-08-22 | 中国石油大学(华东) | Preparation method of steel bionic multiscale dewatering function surface |
| CN204451380U (en) * | 2015-01-29 | 2015-07-08 | 贵州电网公司输电运行检修分公司 | A kind of super-hydrophobic band rust coating structure being suitable for wet weather metal rust preventing |
-
2016
- 2016-05-12 CN CN201610313579.6A patent/CN105926498B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6325107B1 (en) * | 1994-12-29 | 2001-12-04 | Usui Kokusai Sangyo Kaisha Limited | Metal pipeline having a protective coating layer for an automobile |
| CN2746039Y (en) * | 2004-10-27 | 2005-12-14 | 王震宇 | Guard rail having anticorrosion layer |
| CN200988950Y (en) * | 2006-08-16 | 2007-12-12 | 徐州正菱涂装有限公司 | High way railing with reinforced zinc base composite coating layer system |
| CN101205704A (en) * | 2006-12-22 | 2008-06-25 | 徐州正菱涂装有限公司 | Reforming technique for old coated express-way guard-rail plates |
| CN101250861A (en) * | 2008-03-12 | 2008-08-27 | 张家港市亚东高频焊接型钢制造有限公司 | Nano antisepsis protection fence upright |
| CN101942654A (en) * | 2010-10-27 | 2011-01-12 | 东南大学 | Method for immersing superhydrophobic surface of aluminum alloy in one step |
| CN102643967A (en) * | 2012-05-01 | 2012-08-22 | 中国石油大学(华东) | Preparation method of steel bionic multiscale dewatering function surface |
| CN204451380U (en) * | 2015-01-29 | 2015-07-08 | 贵州电网公司输电运行检修分公司 | A kind of super-hydrophobic band rust coating structure being suitable for wet weather metal rust preventing |
Non-Patent Citations (2)
| Title |
|---|
| 邹志武等: "《达克罗技术》", 《汽车工艺与材料》 * |
| 龚佑宁等: "《石墨烯及其在金属防腐中应用的研究进展》", 《中国舰船研究》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108325802A (en) * | 2017-01-19 | 2018-07-27 | 毅铭兴源新钢科技（北京）有限公司 | A kind of zinc steel railing, rail compression spring graphene surface aseptic technic |
| CN108332582A (en) * | 2018-01-26 | 2018-07-27 | 南京新奥环保技术有限公司 | A kind of white air temperature vaporizer of release |
| CN109403245A (en) * | 2018-09-10 | 2019-03-01 | 天津大学 | Road guard air cleaning unit |
| CN111410921A (en) * | 2020-05-02 | 2020-07-14 | 冯亿生 | Composite protective film |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105926498B (en) | 2019-02-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105926498A (en) | Protective fence with surface being coated with drainage layers and manufacturing method | |
| CN104178757B (en) | Chromium-free composite passivator for hot-dip galvanized steel sheet and preparation and application methods of composite passivator | |
| CN105220138A (en) | Weather-resistant steel surface rust layer stabilizing treatment agent | |
| CN102719821A (en) | Composite nanometer silane film for preventing corrosion on metal surface and film forming method thereof | |
| CN108396315B (en) | A kind of treatment agent for rapid formation of stabilized rust layer on the surface of weathering steel and using method thereof | |
| CN104195615B (en) | A kind of preparation method of anticorrosion aluminium section bar | |
| CN110029338A (en) | The preparation method of heat zinc coating plate surface covering liquid and resistance to high humidity Passivated Hot Galvanizing Plate | |
| CN104030727B (en) | Cement-based material surface penetration protective agent and preparation method thereof | |
| CN104130616A (en) | Dry coal gas cabinet body internal and external corrosion-prevention method | |
| CN102634784B (en) | Surface treatment method of nuclear bridge | |
| CN105951024A (en) | Preparation method for composite coating on surface of protective guard | |
| CN101161857A (en) | Aluminum alloy surface treatment method | |
| CN105153877A (en) | Anticorrosive coating for grounding down conductor | |
| CN204749400U (en) | A composite biocoating for steel construction | |
| CN113969399A (en) | Weather-resistant steel rust layer stabilizing treatment solution and treatment method | |
| CN105296998A (en) | Control method of surface cracks of passivated membrane of chromium-free passivated galvanized plate | |
| CN105925966A (en) | Protective fence coated with phytic acid conversion film layer and production method | |
| CN104194544A (en) | Anticorrosive paint used for hot-galvanized angle steel tower | |
| CN105970216B (en) | The protective fence and preparation method on surface coating tin finishes surface | |
| CN113957381A (en) | Protective coating for guardrail and other metal components and preparation method thereof | |
| US6709707B2 (en) | Removal of Ormosil films from metal substrates | |
| CN106010088A (en) | Zinc steel fence and method for manufacturing same | |
| CN208040878U (en) | Powder zincizing preservative treatment auxiliary connection | |
| CN104549959A (en) | Spray technology of aluminum alloy door/window section | |
| CN107794476A (en) | A kind of corrosion resisting steel structural member |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Protective fence with hydrophobic layer on the surface and its production method Granted publication date: 20190222 Pledgee: Jiangsu Jurong Rural Commercial Bank Co.,Ltd. New Century Branch Pledgor: JIANGSU GUGELANSHAN PROTECTIVE FACILITIES CO.,LTD. Registration number: Y2024980006523 |