CN105909345A - An air intake separation diesel engine CO2 collection system and its working method - Google Patents
An air intake separation diesel engine CO2 collection system and its working method Download PDFInfo
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- 238000000926 separation method Methods 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 title claims abstract description 13
- 239000007789 gas Substances 0.000 claims abstract description 68
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 42
- 238000002485 combustion reaction Methods 0.000 claims abstract description 28
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000001301 oxygen Substances 0.000 claims abstract description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 6
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 14
- 239000002283 diesel fuel Substances 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 2
- 238000004200 deflagration Methods 0.000 claims 1
- 239000003344 environmental pollutant Substances 0.000 abstract description 2
- 231100000719 pollutant Toxicity 0.000 abstract description 2
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 abstract 3
- 238000004140 cleaning Methods 0.000 abstract 2
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 208000000059 Dyspnea Diseases 0.000 description 1
- 206010013975 Dyspnoeas Diseases 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 210000001034 respiratory center Anatomy 0.000 description 1
- 208000013220 shortness of breath Diseases 0.000 description 1
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M25/00—Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2570/00—Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
- F01N2570/10—Carbon or carbon oxides
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Abstract
Description
技术领域 technical field
本发明涉及柴油机技术领域,具体涉及一种进气分离式柴油机CO2收集系统及其工作方法。 The invention relates to the technical field of diesel engines, in particular to an air intake separation type diesel engine CO2 collection system and a working method thereof.
背景技术 Background technique
柴油在柴油机的燃烧室中和空气燃烧后会产生NOx和CO2,其中NOx是空气中的一部分氮气在高温燃烧时生成的。 Diesel will produce NOx and CO 2 after being combusted with air in the combustion chamber of the diesel engine, wherein NOx is produced when part of nitrogen in the air is combusted at high temperature.
其中NOx是形成酸雨的主要污染物,NOx对人体的危害最主要的是刺激人的呼吸中枢,导致呼吸急促,并且随着吸入量增加,并且会引起头痛、神智不清等症状。电厂常针对NOx提出很多脱硝方案,但是这些方法不能应用于车用柴油机上或狭小空间或封闭区间内的柴油机上。 Among them, NOx is the main pollutant that forms acid rain. The most harmful thing of NOx to the human body is to stimulate the human respiratory center, resulting in shortness of breath. Power plants often propose many denitrification solutions for NOx, but these methods cannot be applied to vehicle diesel engines or diesel engines in small spaces or closed areas.
大气中的CO2含量近年来急剧增加还导致了温室效应。过去CO2不被列为环境污染的因素,但是随着环境标准的提高,CO2的危害越来越成为研究的热点。专利(ZL201210119473.4)给出了一种CO2捕集装置的思路,但是没有与柴油机燃烧前的空气处理形成整体方案,为柴油机收集CO2的设计还不充分,实际应用性还需进一步研究。 The dramatic increase in CO2 levels in the atmosphere in recent years has also contributed to the greenhouse effect. In the past, CO 2 was not listed as a factor of environmental pollution, but with the improvement of environmental standards, the harm of CO 2 has increasingly become a research focus. The patent (ZL201210119473.4) gives an idea of a CO 2 capture device, but it does not form an overall solution with the air treatment before diesel engine combustion, and the design for collecting CO 2 for diesel engines is not sufficient, and further research is needed for practical applicability .
因此需要提出一种更具有可行性的整体方案,以实现柴油机中的柴油燃烧后不生成NOx,同时又能解决CO2收集的问题。 Therefore, it is necessary to propose a more feasible overall scheme to realize that the diesel fuel in the diesel engine does not generate NOx after combustion, and at the same time, it can solve the problem of CO 2 collection.
发明内容 Contents of the invention
本发明的目的正是为了解决前面提出的技术问题,提出了一种进气分离式柴油机CO2收集系统,对柴油机燃烧前的空气进行处理以去除氮气,并同时实现了对柴油机排放尾气中的CO2收集。本发明一举实现了柴油机尾气的NOx和CO2零排放,符合现在中国目前节能减排的改革现状。 The purpose of the present invention is just to solve the technical problems raised above, and proposes an air intake separation type diesel engine CO2 collection system, which treats the air before the diesel engine burns to remove nitrogen, and at the same time realizes the CO2 collection system in the exhaust gas of the diesel engine. 2 collection. The invention realizes the NOx and CO2 zero emission of the diesel engine tail gas in one fell swoop, and conforms to the current reform status quo of energy saving and emission reduction in China.
本发明提供了一种进气分离式柴油机CO2收集系统,主要包括空气分离器、柴油机、一级气体分离器、水净化器、一级压缩机、二级气体分离器、二级压缩机、三级压缩机和CO2收集器; The invention provides a CO2 collection system for diesel engines with air intake separation, which mainly includes an air separator, a diesel engine, a first-stage gas separator, a water purifier, a first-stage compressor, a second-stage gas separator, a second-stage compressor, and three stage compressor and CO2 collector;
空气分离器的纯氧出口通过管路与柴油机的进气口相连; The pure oxygen outlet of the air separator is connected with the air inlet of the diesel engine through a pipeline;
柴油机的排气管通过管路与一级气体分离器相连; The exhaust pipe of the diesel engine is connected with the primary gas separator through the pipeline;
一级气体分离器具有CO2出口和水汽出口,其中水汽出口连接水净化器,CO2出口 连接一级压缩机; The first-stage gas separator has a CO2 outlet and a water vapor outlet, wherein the water vapor outlet is connected to the water purifier, and the CO2 outlet is connected to the first-stage compressor;
一级压缩机的出气口经管路连接二级气体分离器; The gas outlet of the primary compressor is connected to the secondary gas separator through pipelines;
二级气体分离器的气态水出口经管路连接水净化器; The gaseous water outlet of the secondary gas separator is connected to the water purifier through a pipeline;
二级气体分离器的出气口经管路连接二级压缩机; The gas outlet of the secondary gas separator is connected to the secondary compressor through a pipeline;
二级压缩机的出气口经管路连接三级压缩机; The gas outlet of the secondary compressor is connected to the tertiary compressor through pipelines;
三级压缩机的液体出口连接CO2收集器。 The liquid outlet of the three-stage compressor is connected to the CO2 collector.
其中,空气分离器具有外壳,该外壳顶部设置有空气入口,外壳侧下部设置有分离好的气体出口,所述气体出口包括纯氧出口和其它气体出口。纯氧出口通过管路与柴油机的进气口相连,其它气体出口通入大气。 Wherein, the air separator has a shell, and the top of the shell is provided with an air inlet, and the lower part of the shell side is provided with a separated gas outlet, and the gas outlet includes a pure oxygen outlet and other gas outlets. The pure oxygen outlet is connected with the air inlet of the diesel engine through a pipeline, and the other gas outlets are led into the atmosphere.
其中,柴油机的燃烧室具有柴油喷入口、纯氧入口和纯净水喷入口。 Wherein, the combustion chamber of the diesel engine has a diesel injection inlet, a pure oxygen inlet and a pure water injection inlet.
其中作为优选,一级气体分离器将90%的气态H2O与CO2分离。 Among them, preferably, the primary gas separator separates 90% of gaseous H 2 O from CO 2 .
其中作为优选,CO2进入二级压缩机增压至16bar,然后进入三级压缩机增压至110bar。 Among them, as a preference, CO enters the secondary compressor to pressurize to 16bar, and then enters the third-stage compressor to pressurize to 110bar.
本发明还提供了一种进气分离式柴油机CO2收集系统的工作方法: The present invention also provides a working method of the intake separation type diesel engine CO2 collection system:
空气分离器将空气中的氧气和氮气分离,将氧气送入柴油机的燃烧室与柴油混合燃烧,并在燃烧后期喷入水以降低燃烧温度; The air separator separates the oxygen and nitrogen in the air, sends the oxygen into the combustion chamber of the diesel engine to mix with the diesel for combustion, and injects water in the late stage of combustion to reduce the combustion temperature;
燃烧后产生的气态H2O和CO2进入一级气体分离器,分离后的气态H2O进入水净化器,剩余的气态H2O和CO2经一级气体分离器进入一级压缩机增压,然后送入二级气体分离器; The gaseous H2O and CO2 produced after combustion enter the primary gas separator, the separated gaseous H2O enters the water purifier, and the remaining gaseous H2O and CO2 enter the primary compressor through the primary gas separator pressurized, and then sent to the secondary gas separator;
在二级气体分离器中,分离后的气态H2O进入水净化器回收,分离后的CO2进入二级压缩机增压,然后进入三级压缩机增压变成液态CO2,最终由CO2收集器收集。 In the secondary gas separator, the separated gaseous H 2 O enters the water purifier for recovery, and the separated CO 2 enters the secondary compressor for pressurization, and then enters the tertiary compressor for pressurization to become liquid CO 2 . CO2 collector collection.
作为优选,空气进入空气分离器前进行过滤。 Preferably, the air is filtered before entering the air separator.
作为优选,一级气体分离器与一级压缩机之间设置有冷却装置。 Preferably, a cooling device is arranged between the primary gas separator and the primary compressor.
作为优选,纯氧与柴油在柴油机混合燃烧的末段对燃烧室喷水以防止暴燃。 As a preference, pure oxygen and diesel oil are sprayed with water to the combustion chamber at the end of the mixed combustion of the diesel engine to prevent sudden combustion.
本发明通过空气分离得到纯氧,在柴油机中与柴油混合燃烧生成H2O和CO2,提高了柴油机的做功能力,同时也消除了NOx和固体颗粒物的生成。其中H2O经过水净化器得到回收,CO2经过三次压缩机,压力提高而后液化CO2由收集器收集,彻底解决了柴油机燃烧产生污染的问题,实现了柴油机的零排放。 The invention obtains pure oxygen through air separation, and mixes and burns with diesel in a diesel engine to generate H 2 O and CO 2 , which improves the working ability of the diesel engine and eliminates the formation of NO x and solid particles. Among them, H 2 O is recovered through the water purifier, CO 2 is passed through the compressor three times, the pressure is increased, and then the liquefied CO 2 is collected by the collector, which completely solves the problem of pollution caused by diesel engine combustion and realizes zero emission of diesel engine.
附图说明 Description of drawings
图1是本发明一种进气分离式柴油机CO2收集系统的总体方案流程图。 Fig. 1 is a flow chart of the overall scheme of an air intake separation type diesel engine CO 2 collection system of the present invention.
图中:1、空气分离器,2、柴油机,3、一级气体分离器,4、水净化器,5、一级压缩机,6、二级气体分离器,7、二级压缩机,8、三级压缩机,9、CO2收集器。 In the figure: 1. Air separator, 2. Diesel engine, 3. Primary gas separator, 4. Water purifier, 5. Primary compressor, 6. Secondary gas separator, 7. Secondary compressor, 8 , Three-stage compressor, 9, CO 2 collector.
具体实施方式 detailed description
下面结合附图对本发明作进一步详细描述: Below in conjunction with accompanying drawing, the present invention is described in further detail:
参见附图1,本发明的一种进气分离式柴油机CO2收集系统,主要包括空气分离器1、柴油机2、一级气体分离器3、水净化器4、一级压缩机5、二级气体分离器6、二级压缩机7、三级压缩机8和CO2收集器9。 Referring to accompanying drawing 1, a kind of intake separation type diesel engine CO2 collection system of the present invention mainly comprises air separator 1, diesel engine 2, primary gas separator 3, water purifier 4, primary compressor 5, secondary gas Separator 6, secondary compressor 7, tertiary compressor 8 and CO2 collector 9.
空气分离器1具有外壳,该外壳顶部设置有空气入口,外壳侧下部设置有分离好的气体出口。气体出口包括纯氧出口和其它气体出口,其中,纯氧出口通过管路与柴油机2的进气口相连。其它气体出口通入大气。 The air separator 1 has a shell, the top of the shell is provided with an air inlet, and the lower part of the shell side is provided with a separated gas outlet. The gas outlet includes a pure oxygen outlet and other gas outlets, wherein the pure oxygen outlet is connected to the air inlet of the diesel engine 2 through a pipeline. Other gas outlets lead to the atmosphere.
柴油机2的燃烧室具有柴油喷入口、纯氧入口和纯净水喷入口。柴油机2的排气管经管路与一级气体分离器3相连。 The combustion chamber of the diesel engine 2 has a diesel injection inlet, a pure oxygen inlet and a pure water injection inlet. The exhaust pipe of the diesel engine 2 is connected with the primary gas separator 3 through pipelines.
一级气体分离器3具有CO2出口和水汽出口,其中水汽出口连接水净化器4,CO2出口连接一级压缩机5。 The primary gas separator 3 has a CO2 outlet and a water vapor outlet, wherein the water vapor outlet is connected to the water purifier 4, and the CO2 outlet is connected to the primary compressor 5.
一级压缩机5的出气口经管路连接二级气体分离器6。二级气体分离器6的气态水出口经管路连接水净化器4。 The gas outlet of the primary compressor 5 is connected to the secondary gas separator 6 through a pipeline. The gaseous water outlet of the secondary gas separator 6 is connected to the water purifier 4 through a pipeline.
二级气体分离器6的出气口经管路连接二级压缩机7,二级压缩机7的出气口经管路连接三级压缩机8,三级压缩机8的液体出口连接CO2收集器9。 The gas outlet of the secondary gas separator 6 is connected to the secondary compressor 7 through a pipeline, the gas outlet of the secondary compressor 7 is connected to the tertiary compressor 8 through a pipeline, and the liquid outlet of the tertiary compressor 8 is connected to the CO collector 9.
本发明还提供了一种进气分离式柴油机CO2收集系统的工作方法,具体描述如下: The present invention also provides a working method of an air intake separation type diesel engine CO2 collection system, which is specifically described as follows:
如图1所示,空气分离器1将空气中的氧气和氮气分离,将氧气送入柴油机2的燃烧室与柴油混合燃烧,并在燃烧后期喷入水以降低燃烧温度,防止爆震,有利于提高做功效率;燃烧后产生的气态H2O和CO2,进入一级气体分离器3;一级气体分离器3将90%的气态H2O与CO2分离,分离后的H2O进入水净化器4经过冷凝、净化并回收;剩余10%的气态H2O和CO2经一级气体分离器3进入一级压缩机5增压至4bar,然后送入二级气体分离器6;在二级气体分离器6中气态H2O和CO2彻底分离,分离后的气态H2O进入水净化器4回收,CO2进入二级压缩机7增压至16bar,然后进入三级压缩机8增压至110bar变成液态CO2,最终由CO2收集器9收集。 As shown in Figure 1, the air separator 1 separates the oxygen and nitrogen in the air, sends the oxygen into the combustion chamber of the diesel engine 2 to mix with the diesel fuel, and sprays water in the later stage of combustion to reduce the combustion temperature and prevent knocking, which is beneficial Improve work efficiency; gaseous H 2 O and CO 2 produced after combustion enter primary gas separator 3; primary gas separator 3 separates 90% of gaseous H 2 O from CO 2 , and the separated H 2 O enters The water purifier 4 is condensed, purified and recovered; the remaining 10% of gaseous H 2 O and CO 2 enters the primary compressor 5 through the primary gas separator 3 and pressurizes to 4 bar, and then is sent to the secondary gas separator 6; Gaseous H2O and CO2 are completely separated in the secondary gas separator 6, and the separated gaseous H2O enters the water purifier 4 for recovery, and CO2 enters the secondary compressor 7 to pressurize to 16bar, and then enters the tertiary compression Machine 8 is pressurized to 110bar to become liquid CO 2 , which is finally collected by CO 2 collector 9 .
作为优选的技术方案,空气进入空气分离器1前需进行过滤。 As a preferred technical solution, the air needs to be filtered before entering the air separator 1 .
作为优选的技术方案,一级气体分离器3与一级压缩机5之间设置有冷却装置,即剩余10%的气态H2O和CO2经一级气体分离器3进入一级压缩机5之前需要进行冷却至适宜温度,以保证一级压缩机5能够正常工作。 As a preferred technical solution, a cooling device is provided between the primary gas separator 3 and the primary compressor 5, that is, the remaining 10% gaseous H2O and CO enter the primary compressor 5 through the primary gas separator 3 It needs to be cooled to an appropriate temperature before, so as to ensure that the primary compressor 5 can work normally.
本发明通过空气分离得到纯氧,在柴油机中与柴油混合燃烧生成H2O和CO2,提高了柴油机的做功能力,同时也消除了NOx和固体颗粒物的生成,并采用多级压缩的方法回收了液态CO2,彻底解决了柴油机燃烧产生污染的问题,实现了柴油机的零排放。 The invention obtains pure oxygen through air separation, and mixes and combusts it with diesel oil in a diesel engine to generate H2O and CO2 , which improves the working ability of the diesel engine and eliminates the generation of NOx and solid particles at the same time, and adopts multi-stage compression The method recovers liquid CO 2 , completely solves the problem of pollution caused by diesel engine combustion, and realizes zero emission of diesel engine.
本发明系统的柴油机作为动力驱动装置可用于狭小空间或封闭区间内,如坑道、隧道等。同时,也可用于发电用柴油机上,用于分布式发电、小区供热等。或者也可以用于车辆上。 The diesel engine of the system of the present invention can be used as a power drive device in narrow spaces or closed areas, such as tunnels and tunnels. At the same time, it can also be used on diesel engines for power generation, distributed power generation, district heating, etc. Or it can also be used on vehicles.
本发明不限于以上对实施例的描述,本领域技术人员根据本发明揭示的内容,在本发明基础上不必经过创造性劳动所进行的改进和修改,比如空气分离器和水净化器的选择设置等,都应该在本发明的保护范围之内。 The present invention is not limited to the above description of the embodiments, those skilled in the art according to the content disclosed by the present invention, on the basis of the present invention, it is not necessary to carry out improvement and modification through creative work, such as the selection of air separators and water purifiers, etc. , should be within the protection scope of the present invention.
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CN106968760B (en) * | 2017-04-26 | 2023-02-28 | 青岛双瑞海洋环境工程股份有限公司 | Ship exhaust gas desulfurization, denitrification and decarburization integrated system |
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