CN105907269A - Water-based coating for sports equipment and preparation method thereof - Google Patents
Water-based coating for sports equipment and preparation method thereof Download PDFInfo
- Publication number
- CN105907269A CN105907269A CN201610367946.0A CN201610367946A CN105907269A CN 105907269 A CN105907269 A CN 105907269A CN 201610367946 A CN201610367946 A CN 201610367946A CN 105907269 A CN105907269 A CN 105907269A
- Authority
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- China
- Prior art keywords
- sports equipment
- water paint
- water
- agent
- model
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 49
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 238000000576 coating method Methods 0.000 title abstract description 18
- 239000011248 coating agent Substances 0.000 title abstract description 17
- 239000003973 paint Substances 0.000 claims abstract description 39
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 27
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 13
- 239000004645 polyester resin Substances 0.000 claims abstract description 12
- 229920001225 polyester resin Polymers 0.000 claims abstract description 11
- 239000006260 foam Substances 0.000 claims abstract description 10
- 239000003112 inhibitor Substances 0.000 claims abstract description 10
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 10
- 239000000080 wetting agent Substances 0.000 claims abstract description 9
- 239000008367 deionised water Substances 0.000 claims abstract description 4
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 4
- 238000002156 mixing Methods 0.000 claims description 34
- 238000003756 stirring Methods 0.000 claims description 24
- 239000013530 defoamer Substances 0.000 claims description 16
- 239000002002 slurry Substances 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000006185 dispersion Substances 0.000 claims description 10
- 239000004408 titanium dioxide Substances 0.000 claims description 7
- 239000002270 dispersing agent Substances 0.000 claims description 6
- 229920003180 amino resin Polymers 0.000 claims description 5
- 238000010296 bead milling Methods 0.000 claims description 5
- 239000004576 sand Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 4
- 239000006184 cosolvent Substances 0.000 claims description 3
- 229920002521 macromolecule Polymers 0.000 claims description 2
- 240000002853 Nelumbo nucifera Species 0.000 claims 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 claims 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 claims 1
- 230000008901 benefit Effects 0.000 abstract description 5
- 230000006750 UV protection Effects 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 239000003643 water by type Substances 0.000 description 6
- 230000007613 environmental effect Effects 0.000 description 5
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical group CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 4
- 239000012972 dimethylethanolamine Substances 0.000 description 4
- 238000007689 inspection Methods 0.000 description 4
- 238000003556 assay Methods 0.000 description 3
- -1 butyl glycol ethers Chemical class 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a water-based coating for sports equipment. The water-based coating is prepared from the following components in parts by weight: 24-25 parts of water-based saturated polyester resin, 1-2 parts of ammonia neutralizing agent, 4-5 parts of curing agent, 0.2-0.3 part of wetting agent, 0.2-0.3 part of antifoaming agent, 0.3-0.4 part of leveling agent, 0.1-0.2 part of foam inhibitor, 52-53 parts of water-based white paste and 15-16 parts of deionized water. The water-based coating is environment-friendly, economical and durable; and a paint film has the advantages of high hardness, good flexibility, impact resistance, ultraviolet resistance and the like. The invention also provides a preparation method of the water-based coating for sports equipment.
Description
Technical field
The invention belongs to technical field of coatings, be specifically related to a kind of water paint for sports equipment and preparation side thereof
Method.
Background technology
In recent years, environment for human survival is increasingly severe, and atmospheric pollution is also on the rise.Along with the earth is faced with more and more tighter
High atmospheric pollution, Overseas Government is the strictest to the control of coating products Volatile organic emissions.China is locomotorium
Material big producing country, most finished product be all exportation abroad market, particularly American-European countries be main, thus inevitable ground
Face the relevant laws and regulations that the states such as America and Europe are harsh, and China has put into effect many laws and regulations the most successively, not only from row
Political affairs management is still from improving punitive burden of taxation, and purpose is still in order to develop toward environmental protection direction in guiding industry.But, mesh
Front commercially available coating volatility is relatively strong, and taste is relatively big, and indices is unsatisfactory for the relevant laws and regulations of American-European countries, does not also meet
The development prospect that China is current.
Summary of the invention
In order to overcome the deficiencies in the prior art, it is an object of the invention to provide a kind of aqueous for sports equipment and be coated with
Material, the environmental protection of this water paint, economy, durable, paint film has the advantages such as hardness is high, flexible, impact resistance, UV resistant.
The present invention also provides for the preparation method of a kind of water paint for sports equipment.
Realize the purpose of the present invention to reach by adopting the following technical scheme that:
A kind of water paint for sports equipment, it is to be prepared from by the component of following weight portion meter:
Preferably, described aqueous saturated polyester resin be Guangzhou Chan Xie macromolecule company limited produce model be WP-
The polyester resin of 530-75%.
Preferably, described firming agent be Ineos group company of Britain produce model be INEOS-R747 methyl-etherified amino
The firming agent of resin.
Preferably, described wetting agent is the moistening that Germany wins that the model that wound industrial group Di Gao company produces is TEGO-270
Agent.
Preferably, described defoamer be the model that Byk Chemie GmbH of Germany produces be the defoamer of BYK-028.
Preferably, described levelling agent be the model that EFKA auxiliary chemicals company of Holland produces be the levelling of EFKA-3772
Agent.
Preferably, described foam inhibitor be US Air gasification chemical product company limited produce model be Air Product-
The foam inhibitor of 104E.
Preferably, described aqueous white slurry is to be prepared from by the component of following weight portion meter:
Wherein, described titanium dioxide be the model that Ishihara Sangyo Kaisha, Ltd. of Japan produces be the titanium dioxide of CR-80;Described point
Powder is the dispersant that Germany wins that the model that wound industrial group Di Gao company produces is 750W;Described defoamer is Germany's Bi Keization
The model that company produces is the defoamer of BYK-028;Described cosolvent is the butyl glycol ether that LG-DOW company produces;Institute
State the ammonia nertralizer that the model that ammonia nertralizer is the production of LG-DOW company is DMEA.
Preferably, described aqueous white slurry is to be prepared from according to the following steps:
1) by proportioning by titanium dioxide, dispersant, defoamer, cosolvent, water, the mixing of ammonia nertralizer, mixed liquor is obtained;
2) mixed liquor stirring under high speed dispersion agent mixing, mixing speed is 1000r/min-1500r/min, during stirring
Between 0.3-0.7h, obtain stir liquid;
3) inserting in horizontal sand mill by stirring liquid, bead mill processes 3-5 time, prepares aqueous white slurry.
The present invention also provides for the preparation method of a kind of water paint for sports equipment, and step is as follows:
1) 24-25 part aqueous saturated polyester resin is added container, be then stirred with high speed dispersor, while stirring
Progressively dropping 1-2 part ammonia nertralizer, mixing speed is 500r/min-900r/min, and after 3-5min, test mixing liquid pH value exists
Between 7.5-8.5, stop stirring, carry out next step operation;
2) in container, 4-5 part firming agent, 0.2-0.3 part wetting agent, 0.3-0.4 part levelling agent, 0.2-are added the most successively
0.3 portion of defoamer, 0.1-0.2 part foam inhibitor, be then stirred with high speed dispersor, and mixing speed is 500r/min-900r/
Min, disperses 3-5 minute;
3) in container, add 52-53 part aqueous white slurry again, be eventually adding 15-16 part deionized water, continue dispersion 10-
15 minutes, test pH value, between 7.5-8.5, i.e. prepared water paint.
The beneficial effects of the present invention is:
1, the water paint economy, durable of the present invention, especially this water paint uses water as solvent and disperse medium,
Dilute with water can use, to air almost without pollution, it is to avoid the poisonous and harmful of organic solvent, environmental protection, energy-conservation strong
Health;
2, the water paint of the present invention utilizes aqueous saturated polyester resin as matrix resin, collocation methyl-etherified amino tree
Fat, is prepared as high performance water paint, and this paint film has the advantages such as hardness is high, flexible, impact resistance, UV resistant;Aqueous
Aqueous white slurry in coating may be used for preparing the coating of different colours, and the coating gloss made is bright-coloured, and service life is long;
3, the preparation method step of the water paint of the present invention is simple, and preparation process required time is short, the most extensive work
Industry produces, application, and the water paint environmental protection that this preparation method is prepared, it is possible to promote China's sports equipment industry
Steadily, develop in a healthy way, strengthen the competitiveness of China's sports equipment.
Detailed description of the invention
Below, in conjunction with detailed description of the invention, the present invention is described further:
Embodiment 1
A kind of water paint for sports equipment, the preparation method of this water paint, step is as follows:
1) by weight 24 parts of aqueous saturated polyester resins are added container, be then stirred with high speed dispersor, limit
Stirring limit progressively drips 1 part of ammonia nertralizer, and mixing speed is 500r/min, and after 3min, test mixing liquid pH value, 7.8, stops
Only stirring, carries out next step operation;
2) adding 4 parts of models the most successively in container is the firming agent of INEOS-R747 methyl-etherified amino resins, 0.2 part of type
Number be the wetting agent of TEGO-270,0.3 part of model be the levelling agent of EFKA-3772,0.2 part of model be BYK-028 defoamer,
0.1 part of model is the foam inhibitor of Air Product-104E, is then stirred with high speed dispersor, and mixing speed is 500r/
Min, disperses 3 minutes;
3) in container, add 52 parts of aqueous white slurries again, be eventually adding 15 parts of deionized waters, continue dispersion 10 minutes, survey
Examination pH value, 7.9, i.e. prepares water paint.
Wherein, step 3) in aqueous white slurry be to be prepared from according to the following steps:
The most by weight by 70 parts of models be the titanium dioxide of CR-80,3 parts of models be that the dispersant of 750W, 0.1 part of model are
The defoamer of BYK-028,5 parts of butyl glycol ethers, 14.6 parts of deionized waters, 0.1 part of model are the ammonia nertralizer mixing of DMEA,
To mixed liquor;
B., mixed liquor stirs under high speed dispersion agent mixing, and mixing speed is 1000r/min, mixing time 0.3h,
To stirring liquid;
C. inserting in horizontal sand mill by stirring liquid, bead mill processes 3 times, prepares aqueous white slurry.
Embodiment 2
A kind of water paint for sports equipment, the preparation method of this water paint, step is as follows:
1) by weight 25 parts of aqueous saturated polyester resins are added container, be then stirred with high speed dispersor, limit
Stirring limit progressively drips 2 parts of ammonia nertralizers, and mixing speed is 700r/min, and after 5min, test mixing liquid pH value, 8.4, stops
Only stirring, carries out next step operation;
2) adding 5 parts of models the most successively in container is the firming agent of INEOS-R747 methyl-etherified amino resins, 0.3 part of type
Number be the wetting agent of TEGO-270,0.4 part of model be the levelling agent of EFKA-3772,0.3 part of model be BYK-028 defoamer,
0.2 part of model is the foam inhibitor of Air Product-104E, is then stirred with high speed dispersor, and mixing speed is 700r/
Min, disperses 4 minutes;
3) in container, add 53 parts of aqueous white slurries again, be eventually adding 16 parts of deionized waters, continue dispersion 12 minutes, survey
Examination pH value, 7.9, i.e. prepares water paint.
Wherein, step 3) in aqueous white slurry be to be prepared from according to the following steps:
The most by weight by 70 parts of models be the titanium dioxide of CR-80,5 parts of models be that the dispersant of 750W, 0.2 part of model are
The defoamer of BYK-028,10 parts of butyl glycol ethers, 21.8 parts of deionized waters, 0.2 part of model are the ammonia nertralizer mixing of DMEA,
Obtain mixed liquor;
B., mixed liquor stirs under high speed dispersion agent mixing, and mixing speed is 1200r/min, mixing time 0.5h,
To stirring liquid;
C. inserting in horizontal sand mill by stirring liquid, bead mill processes 4 times, prepares aqueous white slurry.
Embodiment 3
A kind of water paint for sports equipment, the preparation method of this water paint, step is as follows:
1) by weight 24.4 parts of aqueous saturated polyester resins are added container, are then stirred with high speed dispersor,
The most progressively 1.5 parts of ammonia nertralizers of dropping, mixing speed is 900r/min, and after 5min, test mixing liquid pH value exists
8.1, stop stirring, carry out next step operation;
2) add in container the most successively 4.5 parts of models be the firming agent of INEOS-R747 methyl-etherified amino resins, 0.28
Part model be the wetting agent of TEGO-270,0.36 part of model be the levelling agent of EFKA-3772,0.24 part of model be BYK-028
Defoamer, 0.15 part of model are the foam inhibitors of Air Product-104E, are then stirred with high speed dispersor, mixing speed
For 900r/min, disperse 5 minutes;
3) in container, add 52.3 parts of aqueous white slurries again, be eventually adding 15.8 parts of deionized waters, continue dispersion 15 points
Clock, test pH value, 7.7, i.e. prepares water paint.
Wherein, step 3) in aqueous white slurry be to be prepared from according to the following steps:
The most by weight by 70 parts of models be the titanium dioxide of CR-80,4 parts of models be the dispersant of 750W, 0.15 part of model
Be the defoamer of BYK-028,7 parts of butyl glycol ethers, 18 parts of deionized waters, 0.16 part of model be the ammonia nertralizer mixing of DMEA,
Obtain mixed liquor;
B., mixed liquor stirs under high speed dispersion agent mixing, and mixing speed is 1500r/min, mixing time 0.7h,
To stirring liquid;
C. inserting in horizontal sand mill by stirring liquid, bead mill processes 5 times, prepares aqueous white slurry.
Embodiment 1-3 is carried out coating and coating inspection, the method for inspection as shown in Table 1:
Table one coating and coating inspection method
The assay of embodiment 1-3 is as shown in Table 2:
The coating of table two embodiment 1-3 and coating inspection result
By the assay of table two it can be seen that every assay of the water paint of embodiment 1-3 is the most qualified, because of
This, the present invention utilizes aqueous saturated polyester resin as matrix resin, collocation methyl-etherified amino resins, is prepared as high performance use
In the water paint of sports equipment, this coating has the advantage such as economy, environmental protection, paint film has that hardness is high, flexible, impact resistance,
The advantages such as UV resistant.
For a person skilled in the art, can technical scheme as described above and design, make other each
Plant corresponding change and deformation, and all these changes and deforms the protection model that all should belong to the claims in the present invention
Within enclosing.
Claims (10)
1. the water paint for sports equipment, it is characterised in that it is to be prepared from by the component of following weight portion meter:
A kind of water paint for sports equipment the most according to claim 1, it is characterised in that described aqueous is saturated poly-
Ester resin be the model that Guangzhou Chan Xie macromolecule company limited produces be the polyester resin of WP-530-75%.
A kind of water paint for sports equipment the most according to claim 1, it is characterised in that described firming agent is English
The model that Ineos group company of state produces is the firming agent of INEOS-R747 methyl-etherified amino resins.
A kind of water paint for sports equipment the most according to claim 1, it is characterised in that described wetting agent is moral
State wins the wetting agent that the model that wound industrial group Di Gao company produces is TEGO-270.
A kind of water paint for sports equipment the most according to claim 1, it is characterised in that described defoamer is moral
The model that Byk Chemie GmbH of state produces is the defoamer of BYK-028.
A kind of water paint for sports equipment the most according to claim 1, it is characterised in that described levelling agent is lotus
The model that blue EFKA auxiliary chemicals company produces is the levelling agent of EFKA-3772.
A kind of water paint for sports equipment the most according to claim 1, it is characterised in that described foam inhibitor is beautiful
The model that air chemical products company limited of state produces is the foam inhibitor of Air Product-104E.
A kind of water paint for sports equipment the most according to claim 1, it is characterised in that described aqueous white is starched
It is to be prepared from by the component of following weight portion meter:
A kind of water paint for sports equipment the most according to claim 8, it is characterised in that described aqueous white is starched
It is to be prepared from according to the following steps:
1) by proportioning by titanium dioxide, dispersant, defoamer, cosolvent, deionized water, the mixing of ammonia nertralizer, mixed liquor is obtained;
2) mixed liquor stirring under high speed dispersion agent mixing, mixing speed is 1000r/min-1500r/min, mixing time
0.3-0.7h, obtains stirring liquid;
3) inserting in horizontal sand mill by stirring liquid, bead mill processes 3-5 time, prepares aqueous white slurry.
10. a preparation method for the water paint for sports equipment as described in any one of claim 1-9, its feature exists
In, step is as follows:
1) 24-25 part aqueous saturated polyester resin is added container, be then stirred with high speed dispersor, the most progressively
Dropping 1-2 part ammonia nertralizer, mixing speed is 500r/min-900r/min, and after 3-5min, test mixing liquid pH value is at 7.5-
Between 8.5, stop stirring, carry out next step operation;
2) in container, 4-5 part firming agent, 0.2-0.3 part wetting agent, 0.3-0.4 part levelling agent, 0.2-0.3 part are added the most successively
Defoamer, 0.1-0.2 part foam inhibitor, be then stirred with high speed dispersor, and mixing speed is 500r/min-900r/min,
Disperse 3-5 minute;
3) in container, add 52-53 part aqueous white slurry again, be eventually adding 15-16 part deionized water, continue dispersion 10-15 and divide
Clock, test pH value, between 7.5-8.5, i.e. prepares water paint.
Priority Applications (1)
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CN201610367946.0A CN105907269A (en) | 2016-05-26 | 2016-05-26 | Water-based coating for sports equipment and preparation method thereof |
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CN201610367946.0A CN105907269A (en) | 2016-05-26 | 2016-05-26 | Water-based coating for sports equipment and preparation method thereof |
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Family
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CN201610367946.0A Pending CN105907269A (en) | 2016-05-26 | 2016-05-26 | Water-based coating for sports equipment and preparation method thereof |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107033753A (en) * | 2017-05-03 | 2017-08-11 | 阜南县邰氏宇崴运动器材有限公司 | A kind of safety cap protection paint vehicle and preparation method thereof |
CN107099224A (en) * | 2017-05-03 | 2017-08-29 | 阜南县邰氏宇崴运动器材有限公司 | A kind of sports equipment protects paint vehicle coating process |
TWI764357B (en) * | 2020-11-04 | 2022-05-11 | 孫宗霞 | Water-based metal and plastic coating based on water-based saturated polyester resin |
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Title |
---|
周波等: "水性饱和聚酯在卷材涂料中的应用研究", 《第8届国际彩板及涂料用树脂技术研讨会论文集》 * |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107033753A (en) * | 2017-05-03 | 2017-08-11 | 阜南县邰氏宇崴运动器材有限公司 | A kind of safety cap protection paint vehicle and preparation method thereof |
CN107099224A (en) * | 2017-05-03 | 2017-08-29 | 阜南县邰氏宇崴运动器材有限公司 | A kind of sports equipment protects paint vehicle coating process |
TWI764357B (en) * | 2020-11-04 | 2022-05-11 | 孫宗霞 | Water-based metal and plastic coating based on water-based saturated polyester resin |
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