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CN105907228A - Durable anti-rust paint and preparation method thereof - Google Patents

Durable anti-rust paint and preparation method thereof Download PDF

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Publication number
CN105907228A
CN105907228A CN201610436189.8A CN201610436189A CN105907228A CN 105907228 A CN105907228 A CN 105907228A CN 201610436189 A CN201610436189 A CN 201610436189A CN 105907228 A CN105907228 A CN 105907228A
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parts
paint
durable
acrylic emulsion
antirust
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陆安康
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/082Anti-corrosive paints characterised by the anti-corrosive pigment
    • C09D5/086Organic or non-macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D155/00Coating compositions based on homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C09D123/00 - C09D153/00
    • C09D155/02ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
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  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention belongs to the field of paint and particularly relates to durable anti-rust paint and a preparation method thereof. The paint is prepared from dimethylaniline, pentaerythritol, titanium dioxide, composite latex, quartz sand, iron oxide yellow, anti-rust yellow, zinc phosphate, zinc oxide, silicon-based active glue, ABS resin, phenolic resin, cellulose ether, anti-mold preservative, organic complex, silicon-acrylate emulsion, laurylamine, diethanol amine, polycaprolactone, polydimethyl siloxane, nano carbon, pure acrylic emulsion, citric acid, amino propyl trimethoxy silane, hydroxymethyl cellulose, barite powder and deionized water. By means of the simple formula and the simple process, the anti-rust and anti-corrosion effects are remarkably improved, grinding time is reduced, energy consumption is reduced, and accordingly the novel anti-rust paint stable in performance, safe, environmentally friendly, high in paint film adhesion and high in compactness is prepared at low cost.

Description

Durable antirust paint and preparation method thereof
Technical field
The invention belongs to coating class field, particularly to a kind of durable antirust paint and preparation method thereof.
Background technology
Antirust paint is a kind of chemistry protecting metal surfaces from air, sea water etc. or the coating of electrochemical corrosion.What employing industrial antirust paint protected metal in recent years is most with epoxy zinc-rich paint, owing to the density of metal zinc is bigger, in order to not make zinc powder settling or the sedimentation velocity of the zinc powder that slows down, needs to add a certain amount of sagging inhibitor in paint;The viscosity adding paint of anti-settling agent is consequently increased, and will select the resin (E44) of small-molecular-weight as much as possible when selecting polyamide;In order to be able to meet brushability during construction, substantial amounts of solvent to be added in paint, during construction healthy, the paint of solvent serious harm workman pollute during in dry run, solvent evaporate into air environment, solvent make improve construction cost;After the solidification of small-molecular-weight resin, the fragility of paint film is big, metal heat-expansion shrinkage system greatly when variations in temperature paint film be easily cracked or come off.
CN101429406A discloses a kind of antirusting paint for watercraft, is made up of epoxy resin, butanol, phosphoric acid, antirust agent, thickening agent, dispersant, film former, basic lead chromate silicate, coal tar pitch, V45 bitumen anticorrosive paint thixotropic agent, water.This invention can effectively solve the thixotroping problem of paint, and can improve the paint adhesive force to ferrous materials, and shortcoming is that formula is complicated.
CN101629053A discloses a kind of novel aluminum powder pitch ship bottom paint and preparation method thereof, it is on the basis of traditional asphalt aluminium paint, neutralizes stabilizer and thickening anti-settling agent etc. solve the problems such as aluminium powder in common paint is dimmed, pigment precipitates, construction sagging by adding.The aluminum powder pitch ship bottom paint of this invention has raw material and is easy to get, processes the advantage such as simplicity, steady quality, and shortcoming is that the adhesive force of paint film is poor, comes off, crack performance happens occasionally.
Summary of the invention
In order to solve in prior art, the adhesive force of antirust paint is poor, comes off, crack performance happens occasionally, and the shortcoming that consistency is low, weatherability is weak, and this programme proposes a kind of durable antirust paint and preparation method thereof.
A kind of durable antirust paint, includes following raw material, and the parts by weight of raw material are:
nullDimethylaniline 6-18 part,Tetramethylolmethane 9-17 part,Titanium dioxide 21-42 part,Composite emulsion 30-60 part,Quartz sand 25-40 part,Iron oxide yellow 16-25 part,Antirust yellow 8-16 part,Zinc phosphate 15-23 part,Zinc oxide 2-6 part,Silicon-based active glue 8-14 part,ABS resin 25-40 part,Phenolic resin 7-13 part,Cellulose ether 1-11 part,Fungusproof anti-corrosion agent 4-8 part,Organic complex 3-11 part,Silicone acrylic emulsion 7-13 part,Lauryl amine 13-18 part,Diethanolamine 15-30 part,Vinegar 15-20 part in poly-caproic acid,Polydimethylsiloxane 2-4 part,Nano-sized carbon 12-15 part,Pure-acrylic emulsion 3-13 part,Citric acid 4-8 part,3-aminopropyl trimethoxysilane 3-10 part,Hydroxymethyl cellulose 1-15 part,Blanc fixe 1-5 part,Deionized water 10-15 part.
The most specifically optimizing as the present invention program, durable antirust paint also includes sizing material 4-7 part, and the parts by weight of sizing material are: phthalic anhydride 25-35 part, triethylene glycol 10-12 part, 1,3-propanedicarboxylic acid 15-18 part, butantriol 8-10 part, Zinc Oxide 5-7 part, magnesium oxide 3-5 part, neoprene 15-25 part, elastic plastic 70-95 part, softening oil 2-3 part, dimethyl carbonate 15-20 part, ethylbenzene 20-30 part, fire retardant 1-3 part.
The most specifically optimizing as the present invention program, durable antirust paint also includes 2-8 part fire retardant, and the parts by weight of fire retardant are: ammonium low polyphosphate 20-50 part, ammonium phosphate 10-25 part, ammonium pyrophosphate 6-12 part, ammonium sulfate 5-20 part, boric acid 5-10 part, water 10-25 part.
The preparation method of a kind of durable antirust paint, includes following steps:
(1) vinegar in deionized water and composite emulsion, silicon-based active glue, ABS resin, poly-caproic acid is added in stainless steel cauldron, dimethylaniline, antirust Huang, pure-acrylic emulsion, hydroxymethyl cellulose, iron oxide yellow is added under stirring, stirring makes its mix homogeneously, and being uniformly heating to 45-55 DEG C, the heating-up time is 30-50min;
(2) lauryl amine, fungusproof anti-corrosion agent, tetramethylolmethane, polydimethylsiloxane, silicone acrylic emulsion, zinc phosphate, sizing material are put into and joined in paint cylinder, phenolic resin, cellulose ether, zinc oxide, citric acid, diethanolamine, 3-aminopropyl trimethoxysilane is added under the speed of agitator of 100-300r/min, dispersed 5-30min under the rotating speed of 900-1200r/min, high speed dispersion is also ground to below 35um fineness;
(3) being subsequently adding titanium dioxide, quartz sand, organic complex, nano-sized carbon, blanc fixe, fire retardant, low whipping speed is stirring mixing 2-2.5h under 300-600r/min, is ground to fineness≤40 μm with high speed dispersion and grinder after cooling, 8-12 minute;
(4) sampling observation, if paint film is smooth, surface bubble-free, color be within the scope of aberration, then it is assumed that it is qualified to detect, and filters, packs, gets product.
Compared with prior art, the present invention is by rational formula and simple technique, significantly improve antirust, antiseptic effect, and decrease milling time, reduce energy consumption, thus the rust-proof paint of stable performance, safety and environmental protection is prepared with cheap cost, its paint film adhesion is strong, consistency is high, in water, after long-term immersion, the phenomenon such as bubbling, be full of cracks will not occur, also do not come off during frictional impact, weatherability is strong, it is thus possible to steel plate is from the impact of high temperature, high humidity, high salt and chemical attack, and service life is long.
Detailed description of the invention
Hereinafter embodiments of the invention are described in detail, but the multitude of different ways that the present invention can be defined by the claims and cover is implemented;The schematic description and description of the present invention is used for explaining the present invention, is not intended that inappropriate limitation of the present invention.
A kind of durable antirust paint, includes following raw material, and the parts by weight of raw material are:
nullDimethylaniline 6-18 part,Tetramethylolmethane 9-17 part,Titanium dioxide 21-42 part,Composite emulsion 30-60 part,Quartz sand 25-40 part,Iron oxide yellow 16-25 part,Antirust yellow 8-16 part,Zinc phosphate 15-23 part,Zinc oxide 2-6 part,Silicon-based active glue 8-14 part,ABS resin 25-40 part,Phenolic resin 7-13 part,Cellulose ether 1-11 part,Fungusproof anti-corrosion agent 4-8 part,Organic complex 3-11 part,Silicone acrylic emulsion 7-13 part,Lauryl amine 13-18 part,Diethanolamine 15-30 part,Vinegar 15-20 part in poly-caproic acid,Polydimethylsiloxane 2-4 part,Nano-sized carbon 12-15 part,Pure-acrylic emulsion 3-13 part,Citric acid 4-8 part,3-aminopropyl trimethoxysilane 3-10 part,Hydroxymethyl cellulose 1-15 part,Blanc fixe 1-5 part,Deionized water 10-15 part.
The most specifically optimizing as the present invention program, durable antirust paint also includes sizing material 4-7 part, and the parts by weight of sizing material are: phthalic anhydride 25-35 part, triethylene glycol 10-12 part, 1,3-propanedicarboxylic acid 15-18 part, butantriol 8-10 part, Zinc Oxide 5-7 part, magnesium oxide 3-5 part, neoprene 15-25 part, elastic plastic 70-95 part, softening oil 2-3 part, dimethyl carbonate 15-20 part, ethylbenzene 20-30 part, fire retardant 1-3 part.
The most specifically optimizing as the present invention program, durable antirust paint also includes 2-8 part fire retardant, and the parts by weight of fire retardant are: ammonium low polyphosphate 20-50 part, ammonium phosphate 10-25 part, ammonium pyrophosphate 6-12 part, ammonium sulfate 5-20 part, boric acid 5-10 part, water 10-25 part.
The preparation method of a kind of durable antirust paint, includes following steps:
(1) vinegar in deionized water and composite emulsion, silicon-based active glue, ABS resin, poly-caproic acid is added in stainless steel cauldron, dimethylaniline, antirust Huang, pure-acrylic emulsion, hydroxymethyl cellulose, iron oxide yellow is added under stirring, stirring makes its mix homogeneously, and being uniformly heating to 45-55 DEG C, the heating-up time is 30-50min;
(2) lauryl amine, fungusproof anti-corrosion agent, tetramethylolmethane, polydimethylsiloxane, silicone acrylic emulsion, zinc phosphate, sizing material are put into and joined in paint cylinder, phenolic resin, cellulose ether, zinc oxide, citric acid, diethanolamine, 3-aminopropyl trimethoxysilane is added under the speed of agitator of 100-300r/min, dispersed 5-30min under the rotating speed of 900-1200r/min, high speed dispersion is also ground to below 35um fineness;
(3) being subsequently adding titanium dioxide, quartz sand, organic complex, nano-sized carbon, blanc fixe, fire retardant, low whipping speed is stirring mixing 2-2.5h under 300-600r/min, is ground to fineness≤40 μm with high speed dispersion and grinder after cooling, 8-12 minute;
(4) sampling observation, if paint film is smooth, surface bubble-free, color be within the scope of aberration, then it is assumed that it is qualified to detect, and filters, packs, gets product.
Embodiment 1
A kind of durable antirust paint, includes following raw material, and the parts by weight of raw material are:
Dimethylaniline 6 parts, tetramethylolmethane 9 parts, titanium dioxide 21 parts, composite emulsion 30 parts, quartz sand 25 parts, iron oxide yellow 16 parts, antirust yellow 8 parts, zinc phosphate 15 parts, zinc oxide 2 parts, 8 parts of silicon-based active glue, ABS resin 25 parts, 7 parts of phenolic resin, cellulose ether 1 part, fungusproof anti-corrosion agent 4 parts, organic complex 3 parts, silicone acrylic emulsion 7 parts, lauryl amine 13 parts, diethanolamine 15 parts, vinegar 15 parts in poly-caproic acid, polydimethylsiloxane 2 parts, nano-sized carbon 12 parts, pure-acrylic emulsion 3 parts, citric acid 4 parts, 3-aminopropyl trimethoxysilane 3 parts, hydroxymethyl cellulose 1 part, blanc fixe 1 part, deionized water 10 parts.
Embodiment 2
A kind of durable antirust paint, includes following raw material, and the parts by weight of raw material are:
Dimethylaniline 18 parts, tetramethylolmethane 17 parts, titanium dioxide 42 parts, composite emulsion 60 parts, quartz sand 40 parts, iron oxide yellow 25 parts, antirust yellow 16 parts, zinc phosphate 23 parts, zinc oxide 6 parts, 14 parts of silicon-based active glue, ABS resin 40 parts, 13 parts of phenolic resin, cellulose ether 11 parts, fungusproof anti-corrosion agent 8 parts, organic complex 11 parts, silicone acrylic emulsion 13 parts, lauryl amine 18 parts, diethanolamine 30 parts, vinegar 20 parts in poly-caproic acid, polydimethylsiloxane 4 parts, nano-sized carbon 15 parts, pure-acrylic emulsion 13 parts, citric acid 8 parts, 3-aminopropyl trimethoxysilane 10 parts, hydroxymethyl cellulose 15 parts, blanc fixe 5 parts, deionized water 15 parts.
Embodiment 3
The parts by weight of sizing material are: phthalic anhydride 25 parts, triethylene glycol 10 parts, 1,3-propanedicarboxylic acid 15 parts, butantriol 8 parts, Zinc Oxide 5 parts, magnesium oxide 3 parts, neoprene 15 parts, elastic plastic 70 parts, softening oil 2 parts, dimethyl carbonate 15 parts, 20 parts of ethylbenzene, fire retardant 1 part.
Embodiment 4
The parts by weight of sizing material are: phthalic anhydride 35 parts, triethylene glycol 12 parts, 1,3-propanedicarboxylic acid 18 parts, butantriol 10 parts, Zinc Oxide 7 parts, magnesium oxide 5 parts, neoprene 25 parts, elastic plastic 95 parts, softening oil 3 parts, dimethyl carbonate 20 parts, 30 parts of ethylbenzene, fire retardant 3 parts.
Embodiment 5
The parts by weight of fire retardant are: ammonium low polyphosphate 20 parts, 10 parts of ammonium phosphate, ammonium pyrophosphate 6 parts, 5 parts of ammonium sulfate, boric acid 5 parts, 10 parts of water.
Embodiment 6
The parts by weight of fire retardant are: ammonium low polyphosphate 50 parts, 25 parts of ammonium phosphate, ammonium pyrophosphate 12 parts, 20 parts of ammonium sulfate, boric acid 10 parts, 25 parts of water.
Embodiment 7
The preparation method of a kind of durable antirust paint, includes following steps:
(1) vinegar in deionized water and composite emulsion, silicon-based active glue, ABS resin, poly-caproic acid is added in stainless steel cauldron, dimethylaniline, antirust Huang, pure-acrylic emulsion, hydroxymethyl cellulose, iron oxide yellow is added under stirring, stirring makes its mix homogeneously, and being uniformly heating to 45 DEG C, the heating-up time is 30min;
(2) lauryl amine, fungusproof anti-corrosion agent, tetramethylolmethane, polydimethylsiloxane, silicone acrylic emulsion, zinc phosphate, sizing material are put into and joined in paint cylinder, phenolic resin, cellulose ether, zinc oxide, citric acid, diethanolamine, 3-aminopropyl trimethoxysilane is added under the speed of agitator of 100r/min, dispersed 5-30min under the rotating speed of 900r/min, high speed dispersion is also ground to 35um fineness;
(3) being subsequently adding titanium dioxide, quartz sand, organic complex, nano-sized carbon, blanc fixe, fire retardant, low whipping speed is stirring mixing 2h under 300r/min, is ground to fineness 40 μm with high speed dispersion and grinder after cooling, 8 minutes;
(4) sampling observation, if paint film is smooth, surface bubble-free, color be within the scope of aberration, then it is assumed that it is qualified to detect, and filters, packs, gets product.
Embodiment 8
The preparation method of a kind of durable antirust paint, includes following steps:
(1) vinegar in deionized water and composite emulsion, silicon-based active glue, ABS resin, poly-caproic acid is added in stainless steel cauldron, dimethylaniline, antirust Huang, pure-acrylic emulsion, hydroxymethyl cellulose, iron oxide yellow is added under stirring, stirring makes its mix homogeneously, and being uniformly heating to 55 DEG C, the heating-up time is 50min;
(2) lauryl amine, fungusproof anti-corrosion agent, tetramethylolmethane, polydimethylsiloxane, silicone acrylic emulsion, zinc phosphate, sizing material are put into and joined in paint cylinder, phenolic resin, cellulose ether, zinc oxide, citric acid, diethanolamine, 3-aminopropyl trimethoxysilane is added under the speed of agitator of 300r/min, dispersed 30min under the rotating speed of 1200r/min, high speed dispersion is also ground to 5um fineness;
(3) being subsequently adding titanium dioxide, quartz sand, organic complex, nano-sized carbon, blanc fixe, fire retardant, low whipping speed is stirring mixing 2.5h under 600r/min, is ground to fineness 5 μm with high speed dispersion and grinder after cooling, 12 minutes;
(4) sampling observation, if paint film is smooth, surface bubble-free, color be within the scope of aberration, then it is assumed that it is qualified to detect, and filters, packs, gets product.
Zinc phosphate is the avirulence pollution-free rustproof pigment of new generation that antirust corrosive effect is excellent; it has the strongest condensation ability with ferric ion; the radical ion of this zinc phosphate and the iron anode of hull bottom steel plate react the fine and close protecting film that can be formed based on iron phosphate, water insoluble, hardness is high and adhesive force is excellent;The high activity of zinc phosphate also enables it to generate complex with other Action of Metal Ions multiple, and therefore rustless property is the most remarkable;Meanwhile, zinc phosphate, as a kind of white rust resisting pigment, also can be mixed colours and unrestricted as required;In the Asphalt ship-bottom anti-rust paint of the present invention, preferred size is the zinc phosphate of 300-1200 mesh;Most preferably composite superfine zinc phosphate, the latter refers to the slight yellow powdery thing being mainly made up of zinc phosphate, iron phosphate, aluminium oxide and silicon dioxide, it is antirust, antiseptic effect is more preferable, can obtain by being purchased approach, the preferably composite superfine zinc phosphate of Hebei province's Mancheng County Xinlong source Chemical Co., Ltd., its residue on sieve (325 mesh)≤1.0%;The present invention selects zinc phosphate particularly composite superfine zinc phosphate to substitute smelting zinc oxide commonly used in tradition ship bottom anticorrosion paint, is not only able to significantly improve antirust, antiseptic effect, it is also possible to reduces milling time, reduce energy consumption, the most more safety and environmental protection.
Blanc fixe mainly as filler, plays increase film thickness, intensity, wearability, the effect of resistance to ag(e)ing in the Asphalt ship-bottom anti-rust paint of the present invention;Preferred size is the blanc fixe of 300-1200 mesh;Most preferably granularity is the blanc fixe of 800 mesh.
The present invention is by rational formula and simple technique, significantly improve antirust, antiseptic effect, and decrease milling time, reduce energy consumption, thus prepare the rust-proof paint of stable performance, safety and environmental protection with cheap cost, its paint film adhesion is strong, consistency is high, after long-term immersion, the phenomenon such as bubbling, be full of cracks will not occur in water, also not come off during frictional impact, weatherability is strong, being thus able to the steel plate impact from high temperature, high humidity, high salt and chemical attack, service life is long.
It should be noted last that, above detailed description of the invention is only in order to illustrate technical scheme and unrestricted, although the present invention being described in detail with reference to preferred embodiment, it will be understood by those within the art that, technical scheme can be modified or equivalent, without deviating from the spirit and scope of technical solution of the present invention, it all should be contained in the middle of scope of the presently claimed invention 。

Claims (4)

1. a durable antirust paint, it is characterised in that include following raw material, the parts by weight of raw material are:
nullDimethylaniline 6-18 part,Tetramethylolmethane 9-17 part,Titanium dioxide 21-42 part,Composite emulsion 30-60 part,Quartz sand 25-40 part,Iron oxide yellow 16-25 part,Antirust yellow 8-16 part,Zinc phosphate 15-23 part,Zinc oxide 2-6 part,Silicon-based active glue 8-14 part,ABS resin 25-40 part,Phenolic resin 7-13 part,Cellulose ether 1-11 part,Fungusproof anti-corrosion agent 4-8 part,Organic complex 3-11 part,Silicone acrylic emulsion 7-13 part,Lauryl amine 13-18 part,Diethanolamine 15-30 part,Vinegar 15-20 part in poly-caproic acid,Polydimethylsiloxane 2-4 part,Nano-sized carbon 12-15 part,Pure-acrylic emulsion 3-13 part,Citric acid 4-8 part,3-aminopropyl trimethoxysilane 3-10 part,Hydroxymethyl cellulose 1-15 part,Blanc fixe 1-5 part,Deionized water 10-15 part.
The durable antirust paint of one the most according to claim 1, it is characterised in that described durable antirust paint also includes sizing material 4-7 part, the parts by weight of described sizing material are: phthalic anhydride 25-35 part, triethylene glycol 10-12 part, 1,3-propanedicarboxylic acid 15-18 part, butantriol 8-10 part, Zinc Oxide 5-7 part, magnesium oxide 3-5 part, neoprene 15-25 part, elastic plastic 70-95 part, softening oil 2-3 part, dimethyl carbonate 15-20 part, ethylbenzene 20-30 part, fire retardant 1-3 part.
The durable antirust paint of one the most according to claim 1, it is characterised in that described durable antirust paint also includes fire retardant, the parts by weight of described fire retardant are: ammonium low polyphosphate 20-50 part, ammonium phosphate 10-25 part, ammonium pyrophosphate 6-12 part, ammonium sulfate 5-20 part, boric acid 5-10 part, water 10-25 part.
4. the preparation method of a durable antirust paint, it is characterised in that include following steps:
(1) vinegar in deionized water and composite emulsion, silicon-based active glue, ABS resin, poly-caproic acid is added in stainless steel cauldron, dimethylaniline, antirust Huang, pure-acrylic emulsion, hydroxymethyl cellulose, iron oxide yellow is added under stirring, stirring makes its mix homogeneously, and being uniformly heating to 45-55 DEG C, the heating-up time is 30-50min;
(2) lauryl amine, fungusproof anti-corrosion agent, tetramethylolmethane, polydimethylsiloxane, silicone acrylic emulsion, zinc phosphate, sizing material are put into and joined in paint cylinder, phenolic resin, cellulose ether, zinc oxide, citric acid, diethanolamine, 3-aminopropyl trimethoxysilane is added under the speed of agitator of 100-300r/min, dispersed 5-30min under the rotating speed of 900-1200r/min, high speed dispersion is also ground to below 35um fineness;
(3) being subsequently adding titanium dioxide, quartz sand, organic complex, nano-sized carbon, blanc fixe, fire retardant, low whipping speed is stirring mixing 2-2.5h under 300-600r/min, is ground to fineness≤40 μm with high speed dispersion and grinder after cooling, 8-12 minute;
(4) sampling observation, if paint film is smooth, surface bubble-free, color be within the scope of aberration, then it is assumed that it is qualified to detect, and filters, packs, gets product.
CN201610436189.8A 2016-06-20 2016-06-20 Durable anti-rust paint and preparation method thereof Pending CN105907228A (en)

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Publication number Priority date Publication date Assignee Title
CN106590095A (en) * 2016-12-05 2017-04-26 钦州市钦南区生产力促进中心 Antirust paint and preparation method thereof
CN106752636A (en) * 2016-12-13 2017-05-31 张世平 A kind of door and window high temperature resistant protective paint and preparation method thereof
FR3070980A1 (en) * 2017-09-13 2019-03-15 Laboratoires Labema LIQUID CORROSION INHIBITOR, HAVING ANTI <FLASH-RUST> PROPERTIES> &gt; AND IMPROVING THE ADHESION AND RESISTANCE TO LONG-TERM CORROSION OF AQUEOUS PHASE COATINGS
CN109988483A (en) * 2019-03-26 2019-07-09 安徽省欣雨环卫机械有限公司 A kind of electronic automobile-used low temperature resistant crack resisting coating of environmental sanitation and preparation method thereof

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CN102977665A (en) * 2012-11-02 2013-03-20 铜陵市明诚铸造有限责任公司 Metal antirust paint containing modified pure acrylic emulsion, and its preparation method
CN104073107A (en) * 2014-07-21 2014-10-01 湖州三利漆业有限公司 Textured paint
CN104119761A (en) * 2013-04-27 2014-10-29 湖南互力达涂料科技有限公司 Environmentally-friendly water-based paint and preparation method thereof

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DE59300677D1 (en) * 1992-12-03 1995-11-02 Consortium Elektrochem Ind Pigments with colors depending on the viewing angle, their production and use.
CN102977665A (en) * 2012-11-02 2013-03-20 铜陵市明诚铸造有限责任公司 Metal antirust paint containing modified pure acrylic emulsion, and its preparation method
CN104119761A (en) * 2013-04-27 2014-10-29 湖南互力达涂料科技有限公司 Environmentally-friendly water-based paint and preparation method thereof
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106590095A (en) * 2016-12-05 2017-04-26 钦州市钦南区生产力促进中心 Antirust paint and preparation method thereof
CN106752636A (en) * 2016-12-13 2017-05-31 张世平 A kind of door and window high temperature resistant protective paint and preparation method thereof
FR3070980A1 (en) * 2017-09-13 2019-03-15 Laboratoires Labema LIQUID CORROSION INHIBITOR, HAVING ANTI <FLASH-RUST> PROPERTIES> &gt; AND IMPROVING THE ADHESION AND RESISTANCE TO LONG-TERM CORROSION OF AQUEOUS PHASE COATINGS
WO2019053172A1 (en) * 2017-09-13 2019-03-21 Laboratoires Labema Liquid corrosion inhibitor
CN109988483A (en) * 2019-03-26 2019-07-09 安徽省欣雨环卫机械有限公司 A kind of electronic automobile-used low temperature resistant crack resisting coating of environmental sanitation and preparation method thereof

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Application publication date: 20160831