CN105886146A - Environment-friendly hyper-concentrated liquid detergent tablets/particles and preparing method thereof - Google Patents
Environment-friendly hyper-concentrated liquid detergent tablets/particles and preparing method thereof Download PDFInfo
- Publication number
- CN105886146A CN105886146A CN201610379504.8A CN201610379504A CN105886146A CN 105886146 A CN105886146 A CN 105886146A CN 201610379504 A CN201610379504 A CN 201610379504A CN 105886146 A CN105886146 A CN 105886146A
- Authority
- CN
- China
- Prior art keywords
- liquid detergent
- granule
- ultra concentration
- compound enzyme
- environmental protection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/006—Detergents in the form of bars or tablets containing mainly surfactants, but no builders, e.g. syndet bar
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C11D17/065—High-density particulate detergent compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38636—Preparations containing enzymes, e.g. protease or amylase containing enzymes other than protease, amylase, lipase, cellulase, oxidase or reductase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38672—Granulated or coated enzymes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/92—Sulfobetaines ; Sulfitobetaines
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses environment-friendly hyper-concentrated liquid detergent tablets/particles and a preparing method thereof. The environment-friendly hyper-concentrated liquid detergent tablets/particles are prepared from 15-60% of an anion active agent, 10-30% of a nonionic active agent, 1-15% of an ampholytic surfactant, 2-6% of low-molecular weight peptide complex enzyme, 2-6% of a thickening agent, 0.1-0.5% of preservative, 0.1-2% of a lubricating agent, 0.1-2% of filler, 0.1-2% of essence and the balance water. The environment-friendly hyper-concentrated liquid detergent tablets/particles have the advantages that low-molecular weight peptide powder is added into the complex enzyme, then the trigger action on various active matters from the complex enzyme is enhanced, and therefore the dirt removing ability of the active matters is improved greatly; meanwhile, the scientific process of carrying out drying first and then spraying enzyme and liquid detergent tablet/particle production equipment developed and researched autonomously are utilized, and it is effectively ensured that active components of enzyme will not be damaged.
Description
Technical field
The present invention relates to articles for washing technical field, especially relate to the environmental protection ultra concentration liquid detergent that a kind of dirt-removing power is strong
Sheet/granule and preparation method thereof.
Background technology
Liquid detergent is requisite daily cleaning articles for use during people live, and is widely used in tableware, the kitchen range top, kitchen articles
Deng cleaning, ability of cleaning greasy dirt is required height.At present, liquid detergent is all liquid condition, and it is the most convenient not only to carry, and makes packaging
The high expensive of transport, it is often more important that usage amount is difficulty with being precisely controlled.
Not enough in order to solve prior art, inventor have developed a kind of environmental protection ultra concentration liquid detergent sheet/granule, and
Propose a kind of method making this liquid detergent sheet/granule, by independent development produce equipment, make the liquid detergent sheet after drying/
In granule, the content of active matter and effective decontamination composition is the highest can reach more than 90%, and detergency meets and exceeds the most normal
The decontamination standard of liquid detergent, compensate for gaps in market.
Summary of the invention
The present invention provides environmental protection ultra concentration liquid detergent sheet/granule, with solve liquid detergent of the prior art the most portable, bag
The problems such as dress cost of transportation is high, usage amount is the most accurate.
Technical problem solved by the invention realizes by the following technical solutions:
A kind of environmental protection ultra concentration liquid detergent sheet/granule, it is characterised in that this liquid detergent sheet/granule includes following percent mass
The component of ratio:
Accounting is the anion active agent of 15-60%, and described anion active agent is sodium laureth sulfate, dodecyl
Benzene sulfonic acid sodium salt, alpha-olefin sodium sulfonate, 16 SASs, lauroyl sodium isethionate, N-lauroyl sodium hydrogen alpha-aminoglutarate,
One or more mixture of Brij 35 sodium sulfate, potash soap, soda soap etc.；
Accounting is the tween of 10-30%, and described tween is alkylphenol polyoxyethylene, alkyl sugar
One or more mixture of glycosides, cocoanut fatty acid diethanolamide, fatty acid distribution of coconut oil monoethanolamine etc.；
Accounting is the amphoteric surfactant of 1-15%, and described amphoteric surfactant is coco imidoazolinium, cocos nucifera oil acyl
Amine CAB, dodecyl dimethyl azochlorosulfonate propyl lycine, cocoamidopropyl dimethyl glycine betaine, decyl dimethyl
One or more mixture of hydroxypropyl sulfobetaines etc.；
Accounting is the small-molecular peptides compound enzyme of 2-6%；
Accounting is the thickening agent of 2-6%, described thickening agent be xanthan gum, sodium alginate, carrageenan, hydroxymethyl cellulose,
One or more mixture of polyvinyl alcohol etc.；
Accounting is the preservative of 0.1-0.5%, and described preservative is the one of Kazon, phenoxyethanol, lactoperoxidase etc.
Plant or multiple mixture；
Accounting is the emollient of 1-3%；
Accounting is the essence of 0.1-1%；
Accounting is the filler of 0.1-2%；
The deionized water of surplus.
Wherein, described small-molecular peptides compound enzyme is that small-molecular peptides powder is carried out according to the mixing ratio of 1:4 1:19 with compound enzyme
The complex of mixing, wherein, described compound enzyme is by two in amylase, protease, lipase, cellulase, mannase
Kind or two or more mix.
Described compound enzyme is that amylase, lipase, three kinds of enzymes of protease carry out mixed three according to the mixing ratio of 3:3:4
Unification compound enzyme；
Or, described compound enzyme is amylase, lipase, four kinds of enzymes of mannonase protease mixing according to 2:3:1:4
Composition and division in a proportion carries out mixed four-in-one compound enzyme；
Or, described compound enzyme be cellulase, amylase, lipase, five kinds of enzymes of mannonase protease according to 3:2:
The mixing ratio of 1:1:3 carries out mixed five in one compound enzyme.
The invention allows for the manufacture method of a kind of environmental protection ultra concentration liquid detergent sheet, it is characterised in that this manufacture method
Comprise the following steps:
Step S001, take above-mentioned anion active agent, tween and amphoteric surfactant in proportion and put into
Preparation container in, be stirred continuously, then take in proportion above-mentioned thickening agent, antibacterial, preservative, lubricant, essence, filler and
Appropriate amount of deionized water puts into described preparation container equally, constantly stirs evenly and makes each component be sufficiently mixed, and obtains liquid environment-friendly and surpasses
Concentrate liquid detergent sheet and make raw material；
Step S002, liquid environment-friendly ultra concentration liquid detergent sheet obtained in above-mentioned steps S001 is made raw material it is placed in band
In having the pelletizer of mummification function, carry out moisture evaporation under the condition of high temperature more than 80 degrees Celsius, and prepared water content is not
Ultra concentration type liquid detergent sheet more than 6%；
Step S003, take described small-molecular peptides compound enzyme, and it is carried out dilute with water according to the thinner ratio being not less than 1:0.5
Add after releasing in a kind of flusher；
Step S004, by small-molecular peptides compound enzyme described in the liquid state in flusher described in above-mentioned steps S003, spray
It is sprinkled upon in above-mentioned steps S002 on obtained ultra concentration type liquid detergent sheet surface, and dries.
Further, the invention allows for the manufacture method of a kind of environmental protection ultra concentration liquid detergent grain, this manufacture method
Preamble work is as consistent in the manufacture method of above-mentioned environmental protection ultra concentration liquid detergent sheet, and follow-up work is: will be through above-mentioned steps
Chip solid ultra concentration type liquid detergent sheet after S004 processes puts into comminutor, produces particle diameter and is not less than the granule of 0.1cm
Shape ultra concentration type liquid detergent grain.
The invention have the advantages that: by adding small-molecular peptides powder in compound enzyme, and then strengthen compound enzyme pair
The excitation of each active matter, thus the dirt-removing power of active matter is substantially improved.Meanwhile, the science work of enzyme is sprayed after utilizing first mummification
Liquid detergent sheet/particle manufacture the equipment of skill and independent research, effectively ensure that the active component of enzyme will not be destroyed.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below knot
Conjunction is embodied as illustrating, and the present invention is expanded on further.
Embodiment 1
A kind of environmental protection ultra concentration liquid detergent sheet/granule, this environmental protection ultra concentration liquid detergent sheet/granule is by following method system
?；
Step S001, take 58 grams of anion active agent Brij 35 sodium sulfate (be called for short AES), nonionic
Activating agent alkylphenol polyoxyethylene 16 grams, amphoteric surfactant coco imidoazolinium 10 grams, put into preparation container not
Disconnected stirring；
Take again thickening agent polyvinyl alcohol 4 grams, preservative phenoxyethanol 0.1 gram, filler corn starch 1 gram, 0.2 gram of essence,
Glycerol 2 grams and appropriate amount of deionized water, put into described preparation container equally, constantly stirs evenly and makes each component be sufficiently mixed,
Raw material is made to liquid environment-friendly ultra concentration liquid detergent sheet/granule；
Step S002, liquid environment-friendly ultra concentration liquid detergent sheet obtained in above-mentioned steps S001/granule is made raw material
It is placed in the pelletizer of band mummification function, carries out moisture evaporation by the high temperature of more than 80 degree, surpass by calculating liquid environment-friendly
Concentrate the thickness of liquid detergent sheet and enter the area in desiccation apparatus, carrying out Based Intelligent Control evaporation time, and then realize liquid ring
Protect the moisture evaporation in ultra concentration liquid detergent sheet, and obtain the water content solid, shaped ultra concentration type liquid detergent sheet less than 6%；
Step S003, take described small-molecular peptides compound enzyme 5 grams, and it is entered according to the thinner ratio being not less than 1:0.5 with water
Adding in a flusher after row dilution, wherein, described small-molecular peptides compound enzyme is according to 1 by small-molecular peptides powder and compound enzyme:
The mixing ratio of 12 carries out the complex mixed, compound enzyme described among these be amylase, lipase, three kinds of enzymes of protease according to
The mixing ratio of 3:3:4 carries out mixed three-in-one compound enzyme；
Step S004, will in flusher described in above-mentioned steps S003 dilution after described small-molecular peptides compound enzyme, spray
It is sprinkled upon in above-mentioned steps S002 on obtained solid, shaped ultra concentration type liquid detergent sheet surface, and dries.
Further, the present embodiment also proposed the manufacture method of a kind of environmental protection ultra concentration liquid detergent grain, this manufacture method
Preamble work as the manufacture method of above-mentioned environmental protection ultra concentration liquid detergent sheet consistent, follow-up work is: will be through above-mentioned steps
Chip solid ultra concentration type liquid detergent sheet after S004 processes puts into comminutor, produces particle diameter and is not less than the granule of 0.1cm
Shape ultra concentration type liquid detergent grain.
In sum, ultra concentration type liquid detergent sheet/granule out made by the present embodiment, its constituent and percentage ratio
As described below:
Above-mentioned ultra concentration type liquid detergent sheet/granule out made by the present embodiment, is had compared with existing product
Unique distinction is: the three-in-one compound enzyme of small-molecular peptides utilizing mixing ratio to be 1:12, comes anion active agent dodecyl alcohol
Polyethenoxy ether sodium sulfate, tween alkylphenol polyoxyethylene and amphoteric surfactant coco imidoazolinium
Active ingredient carry out exciting of maximum capacity, and then promote the solubilization dirt-removing power of above-mentioned activating agent at double.Especially three close
Protease in one compound enzyme, can be by anion active agent Brij 35 under the facilitation of small-molecular peptides
The deoiling of sodium sulfate, detergent power performs to ultimate attainment.
The present embodiment, also by first high temperature mummification, sprays the innovative technology of enzyme the most again, is effectively protected above-mentioned little molecule
The activity of the three-in-one compound enzyme of peptide will not be destroyed by high temperature, and then ensure that the effectiveness of overall efficacy.
Embodiment 2
A kind of environmental protection ultra concentration liquid detergent sheet/granule, this environmental protection ultra concentration liquid detergent sheet/granule is by following method system
Make；
Step S001, by anion active agent alpha-olefin sodium sulfonate (be called for short AOS) 25 grams, (letter of 16 SASs
Claim SAS) 10 grams, lauroyl sodium isethionate (being called for short Yi Jiebang A) 15 grams, thus form gross mass be 45 grams, mixing ratio be
The mixed type anion active agent of 5:2:3；
Tween alkyl polyglucoside 12 grams and fatty acid distribution of coconut oil diglycollic amide 16 grams is mixed, thus forms
The mixed type tween that gross mass is 28 grams, mixing ratio is 3:4；
By amphoteric surfactant cocoamidopropyl dimethyl glycine betaine (being called for short CAB) 9 grams and dodecyl dimethyl
Azochlorosulfonate propyl lycine 3 grams mixes, thus form gross mass be 12 grams, mixing ratio be the mixed type amophoteric surface active of 3:1
Agent；
Anion active agent, tween and the amphoteric surfactant of above-mentioned mixed type are put into preparation hold
In device and be stirred continuously, then take thickening agent carrageenan and 3 grams of the mixture of polyvinyl alcohol, preservative lactoperoxidase 0.1 gram,
0.1 gram of aromatic essence, glycerol 1 gram, filler corn starch 2 grams and appropriate amount of deionized water, put into described preparation container equally
In, constantly stir evenly and make each component be sufficiently mixed, obtaining liquid environment-friendly ultra concentration liquid detergent sheet/granule and make raw material；
Step S002, liquid environment-friendly ultra concentration liquid detergent sheet obtained in above-mentioned steps S001/granule is made raw material
It is placed in the pelletizer of band mummification function, carries out moisture evaporation by the high temperature of more than 80 degree, and by calculating liquid environment-friendly
Area in the thickness of ultra concentration liquid detergent sheet and entrance desiccation apparatus, carrys out Based Intelligent Control evaporation time, and then realizes liquid
Moisture evaporation in environmental protection ultra concentration liquid detergent sheet, and obtain the water content solid, shaped ultra concentration type liquid detergent sheet less than 6%；
Step S003, take described small-molecular peptides compound enzyme 5 grams, and it is entered according to the thinner ratio being not less than 1:0.5 with water
Adding in a flusher after row dilution, wherein, described small-molecular peptides compound enzyme is according to 1 by small-molecular peptides powder and compound enzyme:
The mixing ratio of 10 carries out the complex mixed, and compound enzyme described among these is amylase, lipase, mannonase albumen
Four kinds of enzymes of enzyme carry out mixed four-in-one compound enzyme according to the mixing ratio of 2:3:1:4；
Step S004, will in flusher described in above-mentioned steps S003 dilution after described small-molecular peptides compound enzyme, spray
It is sprinkled upon in above-mentioned steps S002 on obtained solid, shaped ultra concentration type liquid detergent sheet surface, and dries:
Further, the present embodiment also proposed the manufacture method of a kind of environmental protection ultra concentration liquid detergent grain, this manufacture method
Preamble work as the manufacture method of above-mentioned environmental protection ultra concentration liquid detergent sheet consistent, follow-up work is: will be through above-mentioned steps
Chip solid ultra concentration type liquid detergent sheet after S004 processes puts into comminutor, produces particle diameter and is not less than the granule of 0.1cm
Shape ultra concentration type liquid detergent grain.
In sum, ultra concentration type liquid detergent sheet/granule out made by the present embodiment, its constituent and percentage ratio
As described below:
Above-mentioned ultra concentration type liquid detergent sheet/granule out made by the present embodiment, is had compared with existing product
Unique distinction is: by the anion active agent alpha-olefin sodium sulfonate that compatibility is excellent, 16 SASs, Laurel
Acyl sodium isethionate three mix according to the mixing ratio of 5:2:3, thus formed and multiple spot is had Synergistic
Mixed type anion active agent except effect；
Equally, by alkyl polyglucoside and fatty acid distribution of coconut oil diglycollic amide are carried out compatibility according to the mixing ratio of 3:4, and then
Form the more efficient mixed type tween of collaborative dirt-removing power；
Also by by cocoamidopropyl dimethyl glycine betaine and dodecyl dimethyl azochlorosulfonate propyl lycine according to 3:1's
Mixing ratio carries out compatibility, thus forms the mixed type amphoteric surfactant that collaborative dirt-removing power is higher；
Further, four kinds of enzymes in small-molecular peptides four-in-one compound enzyme are utilized, under the synergism of small-molecular peptides so that on
The dirt-removing power stating various mixed type activating agent obtains accelerating and double lifting again.
The present embodiment, also by first high temperature mummification, sprays the innovative technology of enzyme the most again, is effectively protected above-mentioned little molecule
The activity of peptide four-in-one compound enzyme will not be destroyed by high temperature, and then ensure that the effectiveness of overall efficacy.
Embodiment 3
A kind of environmental protection ultra concentration liquid detergent sheet/granule, this environmental protection ultra concentration liquid detergent sheet/granule is by following method system
Make；
Step S001, by 21 grams of anion active agent Brij 35 sodium sulfate (be called for short AES), N-Laurel
Acyl group sodium hydrogen alpha-aminoglutarate 39 grams mixes, thus form gross mass be 60 grams, mixing ratio be the mixed type anion active of 7:13
Agent；
By tween alkylphenol polyoxyethylene 6 grams, alkyl polyglucoside 9 grams, thus form gross mass and be 15 grams, mix
Composition and division in a proportion is the mixed type tween of 2:3；
Anion active agent and the tween of above-mentioned mixed type are put into preparation container and are stirred continuously,
Take amphoteric surfactant decyl dimethyl hydroxypropyl sulfobetaines 10 grams, thickening agent polyvinyl alcohol 3 grams, preservative breast again
Peroxidase 0.1 gram, 0.2 gram of aromatic essence, glycerol 1 gram, filler corn starch 2 grams and appropriate amount of deionized water, equally
Put into described preparation container, constantly stir evenly and make each component be sufficiently mixed, obtain liquid environment-friendly ultra concentration liquid detergent sheet/granule
Make raw material；
Step S002, liquid environment-friendly ultra concentration liquid detergent sheet obtained in above-mentioned steps S001/granule is made raw material
It is placed in the pelletizer of band mummification function, carries out moisture evaporation by the high temperature of more than 80 degree, surpass by calculating liquid environment-friendly
Concentrate the thickness of liquid detergent sheet and enter the area in desiccation apparatus, carrying out Based Intelligent Control evaporation time, and then realize liquid ring
Protect the moisture evaporation in ultra concentration liquid detergent sheet, and obtain the water content solid, shaped ultra concentration type liquid detergent sheet less than 6%；
Step S003, take described small-molecular peptides compound enzyme 5 grams, and it is entered according to the thinner ratio being not less than 1:0.5 with water
Adding in a flusher after row dilution, wherein, described small-molecular peptides compound enzyme is according to 1:4 by small-molecular peptides powder and compound enzyme
Mixing ratio carry out the complex that mixes, the most described compound enzyme is cellulase, amylase, lipase, mannonase egg
White five kinds of enzymes of enzyme carry out mixed five in one compound enzyme according to the mixing ratio of 3:2:1:1:3；
Step S004, will in flusher described in above-mentioned steps S003 dilution after described small-molecular peptides compound enzyme, spray
It is sprinkled upon in above-mentioned steps S002 on obtained solid, shaped ultra concentration type liquid detergent sheet surface, and dries:
Further, the present embodiment also proposed the manufacture method of a kind of environmental protection ultra concentration liquid detergent grain, this manufacture method
Preamble work as the manufacture method of above-mentioned environmental protection ultra concentration liquid detergent sheet consistent, follow-up work is: will be through above-mentioned steps
Chip solid ultra concentration type liquid detergent sheet after S004 processes puts into comminutor, produces particle diameter and is not less than the granule of 0.1cm
Shape ultra concentration type liquid detergent grain.
In sum, ultra concentration type liquid detergent sheet/granule out made by the present embodiment, its constituent and percentage ratio
As described below:
Above-mentioned ultra concentration type liquid detergent sheet/granule out made by the present embodiment, is had compared with existing product
Unique distinction is: by by anion active agent Brij 35 sodium sulfate and N-lauroyl sodium hydrogen alpha-aminoglutarate two
Person mixes according to the mixing ratio of 7:13, thus the mixed type anion that formation has Synergistic removal effect to spot is lived
Property agent；
Equally, by by tween alkylphenol polyoxyethylene and alkyl polyglucoside according to the mixing ratio of 2:3
Carry out hybrid combination, and then form the mixed type tween that collaborative dirt-removing power is more efficient；
Further, five kinds of enzymes in small-molecular peptides five in one compound enzyme are utilized, under the synergism of small-molecular peptides so that on
The dirt-removing power stating various activating agent obtains accelerating and double lifting again.
The present embodiment, again by first high temperature mummification, sprays the innovative technology of enzyme the most again, is effectively protected above-mentioned little point
The activity of sub-peptide five in one compound enzyme will not be destroyed by high temperature, and then ensure that the effectiveness of overall efficacy.
Detersive efficiency contrast experiment
Take environmental protection ultra concentration liquid detergent sheet/granule out made by above-mentioned 3 kinds of embodiments, with current commercial type
Liquid liquid detergent carries out contrast test, respectively from removing fatty oil, olive oil, soybean oil, Oleum Arachidis hypogaeae semen, Camellia oil, Oleum Brassicae campestris,
Several oil stains such as oil smoke aggregation carry out comparative evaluation with the detersive efficiency of greasy dirt, result such as following table.
Above-mentioned experiment finds, the environmental protection ultra concentration liquid detergent sheet/granule made by 3 kinds of embodiments provided by the present invention
Every detersive efficiency is above current existing liquid detergent.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.The technology of the industry
Personnel, it should be appreciated that the present invention is not restricted to the described embodiments, simply illustrating this described in above-described embodiment and description
The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, and these become
Change and improvement both falls within scope of the claimed invention.Claimed scope by appending claims and
Equivalent defines.
Claims (8)
1. environmental protection ultra concentration liquid detergent sheet/granule, it is characterised in that this liquid detergent sheet/granule includes the group of following mass percent
Point:
Accounting is the anion active agent of 15-60%, and described anion active agent is sodium laureth sulfate, detergent alkylate sulphur
Acid sodium, alpha-olefin sodium sulfonate, 16 SASs, lauroyl sodium isethionate, N-lauroyl sodium hydrogen alpha-aminoglutarate, 12
Alkyl alcohol ethoxylates sodium sulfate, potash soap, one or more mixture of soda soap；
Accounting is the tween of 10-30%, described tween be alkylphenol polyoxyethylene, alkyl polyglucoside,
Cocoanut fatty acid diethanolamide, one or more mixture of fatty acid distribution of coconut oil monoethanolamine；
Accounting is the amphoteric surfactant of 1-15%, and described amphoteric surfactant is coco imidoazolinium, coconut oleoyl amine third
Base glycine betaine, cocoamidopropyl dimethyl glycine betaine, dodecyl dimethyl azochlorosulfonate propyl lycine, decyl dimethyl hydroxypropyl
One or more mixture of base sulfobetaines；
Accounting is the small-molecular peptides compound enzyme of 2-6%；
Accounting is the thickening agent of 2-6%, and described thickening agent is xanthan gum, sodium alginate, carrageenan, hydroxymethyl cellulose, poly-second
One or more mixture of enol；
Accounting is the preservative of 0.1-0.5%, and described preservative is Kazon, phenoxyethanol, the one of lactoperoxidase or many
Plant mixture；
Accounting is the emollient of 1-3%；
Accounting is the essence of 0.1-1%；
Accounting is the filler of 0.1-2%；
The deionized water of surplus.
Environmental protection ultra concentration liquid detergent sheet/granule the most according to claim 1, it is characterised in that this environmental protection ultra concentration is washed clean
Constituent and mass percent after essence sheet/granule drying are as described below:
。
Environmental protection ultra concentration liquid detergent sheet/granule the most according to claim 1, it is characterised in that this environmental protection ultra concentration is washed clean
Constituent and mass percent after essence sheet drying/granule are as described below:
。
Environmental protection ultra concentration liquid detergent sheet/granule the most according to claim 1, it is characterised in that this environmental protection ultra concentration is washed clean
Constituent and mass percent after essence sheet/granule drying are as described below:
。
5. according to the environmental protection ultra concentration liquid detergent sheet/granule described in claim 1-4 any claim, it is characterised in that institute
Stating small-molecular peptides compound enzyme is the complex that small-molecular peptides powder carries out according to the mixing ratio of 1:4 1:19 with compound enzyme mixing, its
In, described compound enzyme is by two or more mixing in amylase, protease, lipase, cellulase, mannase
Form.
Environmental protection ultra concentration liquid detergent sheet/granule the most according to claim 5, it is characterised in that described compound enzyme is starch
Enzyme, lipase, three kinds of enzymes of protease carry out mixed three-in-one compound enzyme according to the mixing ratio of 3:3:4；
Or, described compound enzyme is that amylase, lipase, four kinds of enzymes of mannonase protease are according to the mixing of 2:3:1:4
Ratio carries out mixed four-in-one compound enzyme；
Or, described compound enzyme be cellulase, amylase, lipase, five kinds of enzymes of mannonase protease according to 3:2:1:1:
The mixing ratio of 3 carries out mixed five in one compound enzyme.
7. the manufacture method of environmental protection ultra concentration liquid detergent sheet/granule, it is characterised in that this manufacture method comprises the following steps:
Step S001, in proportion take anion active agent described in the claims 14 any one, tween,
And amphoteric surfactant put into preparation container, be stirred continuously, then take the claims 14 any one in proportion
Described thickening agent, preservative, lubricant, essence, filler and appropriate amount of deionized water puts into described preparation container equally,
Constantly stir evenly and make each component be sufficiently mixed, obtaining liquid environment-friendly ultra concentration liquid detergent sheet and make raw material；
Step S002, liquid environment-friendly ultra concentration liquid detergent sheet obtained in above-mentioned steps S001 is made raw material it is placed in dry
Change in the pelletizer of function, carry out moisture evaporation under the condition of high temperature more than 80 degrees Celsius, and prepared water content is less than
The ultra concentration type liquid detergent sheet of 6%；
Step S003, take described small-molecular peptides compound enzyme, and after itself and water are diluted according to the thinner ratio being not less than 1:0.5
Add in a kind of flusher；
Step S004, by small-molecular peptides compound enzyme described in the liquid state in flusher described in above-mentioned steps S003, be sprayed at
On ultra concentration type liquid detergent sheet surface obtained in above-mentioned steps S002, and dry.
The manufacture method of environmental protection ultra concentration liquid detergent sheet/granule the most according to claim 7, it is characterised in that will pass through
Chip solid ultra concentration type liquid detergent sheet after described step S004 processes puts into comminutor, produces particle diameter and is not less than
The graininess ultra concentration type liquid detergent grain of 0.1cm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610379504.8A CN105886146A (en) | 2016-06-01 | 2016-06-01 | Environment-friendly hyper-concentrated liquid detergent tablets/particles and preparing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610379504.8A CN105886146A (en) | 2016-06-01 | 2016-06-01 | Environment-friendly hyper-concentrated liquid detergent tablets/particles and preparing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105886146A true CN105886146A (en) | 2016-08-24 |
Family
ID=56710451
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610379504.8A Pending CN105886146A (en) | 2016-06-01 | 2016-06-01 | Environment-friendly hyper-concentrated liquid detergent tablets/particles and preparing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105886146A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106381239A (en) * | 2016-08-28 | 2017-02-08 | 江苏云瀚股份有限公司 | Eco-friendly automobile glass cleaning agent and preparation technology thereof |
| CN107164113A (en) * | 2017-04-25 | 2017-09-15 | 李汝良 | A kind of kitchen piece |
| CN107929104A (en) * | 2017-12-25 | 2018-04-20 | 深圳市芭格美生物科技有限公司 | A kind of three-in-one wash and maintenance liquid of biology enzyme and preparation method thereof |
| CN108034529A (en) * | 2017-12-29 | 2018-05-15 | 广州馨香日用化工有限公司 | A kind of cleaning agent |
| CN108300623A (en) * | 2018-03-02 | 2018-07-20 | 胡小玲 | Granular laundry agent and preparation method thereof |
| CN108559677A (en) * | 2018-06-01 | 2018-09-21 | 湖南中禹利晟环保科技有限公司 | A kind of concentrated type liquid detergent and preparation method thereof |
| CN109957466A (en) * | 2017-12-23 | 2019-07-02 | 青岛麦迪尔生物工程有限公司 | A kind of melon and fruit dish washing detergent |
| CN113232378A (en) * | 2021-04-29 | 2021-08-10 | 姚杰 | Multifunctional tablet and its preparation process |
| CN116194562A (en) * | 2022-12-21 | 2023-05-30 | 广州洁生日化有限公司 | a washing tablet |
| US12281285B1 (en) | 2024-09-12 | 2025-04-22 | Guangzhou Joyson Cleaning Products Co., Ltd. | Detergent tablet free of SLS surfactant and preparation method thereof |
-
2016
- 2016-06-01 CN CN201610379504.8A patent/CN105886146A/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106381239A (en) * | 2016-08-28 | 2017-02-08 | 江苏云瀚股份有限公司 | Eco-friendly automobile glass cleaning agent and preparation technology thereof |
| CN107164113A (en) * | 2017-04-25 | 2017-09-15 | 李汝良 | A kind of kitchen piece |
| CN109957466A (en) * | 2017-12-23 | 2019-07-02 | 青岛麦迪尔生物工程有限公司 | A kind of melon and fruit dish washing detergent |
| CN107929104A (en) * | 2017-12-25 | 2018-04-20 | 深圳市芭格美生物科技有限公司 | A kind of three-in-one wash and maintenance liquid of biology enzyme and preparation method thereof |
| CN108034529A (en) * | 2017-12-29 | 2018-05-15 | 广州馨香日用化工有限公司 | A kind of cleaning agent |
| CN108300623A (en) * | 2018-03-02 | 2018-07-20 | 胡小玲 | Granular laundry agent and preparation method thereof |
| CN108559677A (en) * | 2018-06-01 | 2018-09-21 | 湖南中禹利晟环保科技有限公司 | A kind of concentrated type liquid detergent and preparation method thereof |
| CN113232378A (en) * | 2021-04-29 | 2021-08-10 | 姚杰 | Multifunctional tablet and its preparation process |
| CN116194562A (en) * | 2022-12-21 | 2023-05-30 | 广州洁生日化有限公司 | a washing tablet |
| CN116194562B (en) * | 2022-12-21 | 2024-12-06 | 广州洁生日化有限公司 | A washing tablet |
| US12281285B1 (en) | 2024-09-12 | 2025-04-22 | Guangzhou Joyson Cleaning Products Co., Ltd. | Detergent tablet free of SLS surfactant and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105886146A (en) | Environment-friendly hyper-concentrated liquid detergent tablets/particles and preparing method thereof | |
| CN105886145A (en) | Super-concentrated washing piece and preparation method thereof | |
| CN102414305B (en) | Manufacture of high active detergent particles | |
| CN106010820A (en) | Plant enzyme environment-friendly laundry detergent sheet and preparation method thereof | |
| CN105796385A (en) | Environment-friendly super-concentrated hair washing tablets/granules and preparation method thereof | |
| TW460575B (en) | Detergent particles and method for producing the same | |
| CN105969550A (en) | Washing tablet | |
| CN105969549A (en) | Environmentally friendly super-concentrated bath tablets and particles and preparation method thereof | |
| CN106038352A (en) | Environment-friendly super-concentrated hand washing slices/granules and manufacturing method thereof | |
| CN106350284A (en) | Laundry gel beads for washing real silk fabrics and preparation method of laundry gel beads | |
| CN102021086A (en) | Natural plant detergent and preparation method thereof | |
| CN106350268A (en) | Laundry condensate bead and preparation method thereof | |
| CN102864037A (en) | Heavy-duty liquid composite detergent | |
| CN102925305B (en) | Water-based cleaning agent for silicone grease and silicone oil | |
| CN109097215A (en) | A kind of environment-friendly type Laundry soap powder composition and preparation method thereof | |
| CN106381234A (en) | Brightening laundry bead and preparation method thereof | |
| CN108048245A (en) | Natural concentrated type foam tableware detergent | |
| CN106318667A (en) | Excellent bactericidal washing laundry condensate bead and preparing method thereof | |
| CN101942082B (en) | Preparation method for powdery AES or AES mixture | |
| CN111466374A (en) | Pesticide soluble granule and preparation method thereof | |
| CN102660407A (en) | A novel detergent for pesticide residue on vegetables and fruits | |
| CN105349276A (en) | Disinfecting washing agent | |
| CN101946794B (en) | Cypermethrin water emulsion and preparation method thereof | |
| CN108048225A (en) | A kind of environment friendly and pollution-free washing powder and preparation method thereof | |
| CN106566732A (en) | Phosphorus-free, fluorescent agent-free and preservative-free super-concentrated capsule granule laundry detergent, preparation method and use method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160824 |
|
| WD01 | Invention patent application deemed withdrawn after publication |