CN1058764C - Photosensitive bleaching agent containing photosensitive compound and its preparing method - Google Patents
Photosensitive bleaching agent containing photosensitive compound and its preparing method Download PDFInfo
- Publication number
- CN1058764C CN1058764C CN96104687A CN96104687A CN1058764C CN 1058764 C CN1058764 C CN 1058764C CN 96104687 A CN96104687 A CN 96104687A CN 96104687 A CN96104687 A CN 96104687A CN 1058764 C CN1058764 C CN 1058764C
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- CN
- China
- Prior art keywords
- photosensitive
- sodium
- agent
- bleach
- porphine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000007844 bleaching agent Substances 0.000 title claims abstract description 58
- 150000001875 compounds Chemical class 0.000 title claims abstract description 29
- 238000000034 method Methods 0.000 title description 8
- -1 bicyclic porphin derivative Chemical class 0.000 claims abstract description 23
- 102000004190 Enzymes Human genes 0.000 claims abstract description 14
- 108090000790 Enzymes Proteins 0.000 claims abstract description 14
- 239000003381 stabilizer Substances 0.000 claims abstract description 13
- 239000003599 detergent Substances 0.000 claims abstract description 12
- 239000006260 foam Substances 0.000 claims abstract description 11
- 239000000080 wetting agent Substances 0.000 claims abstract description 8
- JZRYQZJSTWVBBD-UHFFFAOYSA-N pentaporphyrin i Chemical compound N1C(C=C2NC(=CC3=NC(=C4)C=C3)C=C2)=CC=C1C=C1C=CC4=N1 JZRYQZJSTWVBBD-UHFFFAOYSA-N 0.000 claims abstract description 6
- 150000003839 salts Chemical class 0.000 claims abstract description 6
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 3
- 238000004061 bleaching Methods 0.000 claims description 12
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 9
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 9
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 9
- 229910052708 sodium Inorganic materials 0.000 claims description 9
- 239000011734 sodium Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 8
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 7
- 229910021536 Zeolite Inorganic materials 0.000 claims description 6
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000010457 zeolite Substances 0.000 claims description 6
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 4
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- 239000002250 absorbent Substances 0.000 claims description 2
- 230000002745 absorbent Effects 0.000 claims description 2
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 claims description 2
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 claims description 2
- 235000010265 sodium sulphite Nutrition 0.000 claims description 2
- 239000007983 Tris buffer Substances 0.000 claims 3
- 239000004615 ingredient Substances 0.000 claims 3
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 claims 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 2
- GDCXBZMWKSBSJG-UHFFFAOYSA-N azane;4-methylbenzenesulfonic acid Chemical compound [NH4+].CC1=CC=C(S([O-])(=O)=O)C=C1 GDCXBZMWKSBSJG-UHFFFAOYSA-N 0.000 claims 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
- 229920000388 Polyphosphate Polymers 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims 1
- BSZPYRJQDZNENV-UHFFFAOYSA-N [Na].c1cc2cc3ccc(cc4ccc(cc5ccc(cc1n2)[nH]5)n4)[nH]3 Chemical compound [Na].c1cc2cc3ccc(cc4ccc(cc5ccc(cc1n2)[nH]5)n4)[nH]3 BSZPYRJQDZNENV-UHFFFAOYSA-N 0.000 claims 1
- 239000000440 bentonite Substances 0.000 claims 1
- 229910000278 bentonite Inorganic materials 0.000 claims 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims 1
- STDOYGZZOMEMCG-UHFFFAOYSA-N butanedioic acid;2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethanol Chemical compound OC(=O)CCC(O)=O.OCCOCCOCCOCCO STDOYGZZOMEMCG-UHFFFAOYSA-N 0.000 claims 1
- 150000007942 carboxylates Chemical class 0.000 claims 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 1
- 239000001205 polyphosphate Substances 0.000 claims 1
- 235000011176 polyphosphates Nutrition 0.000 claims 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 claims 1
- 239000000741 silica gel Substances 0.000 claims 1
- 229910002027 silica gel Inorganic materials 0.000 claims 1
- 229940057950 sodium laureth sulfate Drugs 0.000 claims 1
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 claims 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims 1
- 239000006081 fluorescent whitening agent Substances 0.000 abstract description 9
- 238000002360 preparation method Methods 0.000 abstract description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 4
- 239000001301 oxygen Substances 0.000 abstract description 4
- 229910052760 oxygen Inorganic materials 0.000 abstract description 4
- 239000000049 pigment Substances 0.000 abstract description 4
- 239000004094 surface-active agent Substances 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 244000005700 microbiome Species 0.000 abstract description 3
- 229920000642 polymer Polymers 0.000 abstract description 2
- 230000009977 dual effect Effects 0.000 abstract 1
- 239000000796 flavoring agent Substances 0.000 abstract 1
- 235000019634 flavors Nutrition 0.000 abstract 1
- 125000002950 monocyclic group Chemical group 0.000 abstract 1
- 230000002087 whitening effect Effects 0.000 abstract 1
- 239000004744 fabric Substances 0.000 description 14
- 238000005406 washing Methods 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 239000000843 powder Substances 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- TVHALOSDPLTTSR-UHFFFAOYSA-H hexasodium;[oxido-[oxido(phosphonatooxy)phosphoryl]oxyphosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O TVHALOSDPLTTSR-UHFFFAOYSA-H 0.000 description 6
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- 239000003086 colorant Substances 0.000 description 5
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 5
- 230000005284 excitation Effects 0.000 description 5
- 229960001922 sodium perborate Drugs 0.000 description 5
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
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- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
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- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 3
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- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
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- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 239000004577 thatch Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical group CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
本发明提供一种含光敏化合物的光敏漂白剂及其制备方法。其主要组成是：a、基料：单环卟吩和双环卟吩衍生物光敏化合物，b、漂白增效剂：硅酸钠等无机盐、以及酶等；c、润湿剂；表面活性剂以及烯属酸聚合物等；d、稳泡剂；e、荧光增白剂和香精。它的特点，一是经济，利用自然界的太阳光能和空气中的氧，来分解色素、污渍及微生物，达到洁白卫生的目的；二是可以同时发挥酶及漂白剂的双重活力作用。本产品可以单独作为漂白剂使用，也可以配合各类商品洗涤剂进行洗涤漂白。The invention provides a photosensitive bleach containing a photosensitive compound and a preparation method thereof. Its main components are: a. base material: monocyclic porphine and bicyclic porphin derivative photosensitive compound, b. bleach synergist: sodium silicate and other inorganic salts, and enzymes, etc.; c. wetting agent; surfactant And olefinic acid polymers, etc.; d, foam stabilizer; e, fluorescent whitening agent and flavor. Its characteristics are, first, economical, using natural sunlight and oxygen in the air to decompose pigments, stains and microorganisms to achieve the purpose of whitening and sanitation; second, it can simultaneously exert the dual vitality of enzymes and bleaching agents. This product can be used alone as a bleaching agent, or it can be washed and bleached with various commercial detergents.
Description
The present invention relates to a kind of photosensitive bleaching agent that contains light-sensitive compound, be mainly used in the preparation laundry detergent compositions, it increases the bleaching washing function of washing agent.
Can both the abutment surface active power of not all dirt, wetting power, emulsifying ability, mechanical force, and physical force etc. washes, such as, tea, coffee, vegetable colours such as fruit juice must lean on chemical reaction power, as bleaching agent, pigment molecular is broken into colourless fragment remove.
Existing chlorine bleaches is typically clorox, although its bleaching power is strong, poor stability in processing and storage particularly has infringement to dyestuff and fabric when using.Chinese patent CN 1066465 has announced a kind of domestic bleaching water, is characterized in that hypochlorous sodium is a main component, adds Quadrafos, and metaphosphate, phosphate are as water softener, and NaOH is as stabilizing agent.Its principal component clorox is not very favourable to the dyestuff and the fiber of fabric.In oxygen-bearing bleaching agent, be typically SODIUM PERCARBONATE and sodium perborate.The former advantage is that discoloration is strong, and serviceability temperature is low, but stable non-constant.After water-soluble, one hour will be ineffective, and alkalescence is crossed also can cause its inefficacy by force.China is to the research of long-acting sodium percarbonate start to walk [liuYun, etc, 4
ThWorld Conference on Detergent (Strategy for 21
StCentury), Montrux, Switzerland, 1998.10].Although sodium perborate does not have destruction to fabric and dyestuff, serviceability temperature is only applicable to hot wash up to 90 ℃.The appearance of bleach-activating has reduced the serviceability temperature of sodium perborate, but generally still more than normal temperature.Because the loss of the active oxygen of peralcohol, the interpolation total amount of bleaching agent and activator is up to 20% (US 5415668).Trace meter can increase the activity of sodium perborate by catalysis, as iron, and molybdenum, tungsten, vanadium, manganese etc.But because the bleaching of sodium perborate is to realize by the hydrogen peroxide that produces, the metal ion that is added catalyzing hydrogen peroxide too decomposes, thereby must add stabilizing agent, as the magnesium silicate of abundant dispersion, or make itself and chelating agent form complex compound, reduce the side effect of heavy metal.The method of adding magnesium silicate is difficult actually to be realized.And the structure of the chelate of transition metal more complicated often has certain degree of difficulty in preparation.As 1,4 of manganese, 7-trimethyl-1,4, the dinuclear complex of 7-three nitrogen nonanes (U.S. Pat 5,280,117):
Mn(MeTACN)(OCH
3)
3(PF
6)
(ME-TACN:1,4,7-trimethyl-1,4,7-three nitrogen are appointed alkane)
The principal component of photosensitive bleaching agent involved in the present invention is monocycle porphines and dicyclo porphine derivative, and it absorbs abundant existence the in the Nature, and the sunlight energy of free supply, and it is passed to non-existent nowhere oxygen molecule in the air.Make it to be excited to excitation state, thereby oxidation pigment, spot and microorganism reach the purpose of pure white health from ground state.Therefore bleaching agent efficient is very high, contains one thousandth to ten thousand/just can reach the purpose of obvious bleaching in the treatment fluid, has saved cost greatly.Photosensitive bleaching agent can also kill fabric fibre surface and inner microorganism, makes fabric sanitation and hygiene more.
The bleaching mechanism of monocycle porphines that this photosensitive bleaching agent is related and dicyclo porphines light-sensitive compound is:
At first, light-sensitive compound absorbs solar energy becomes excitation state:
1、
This excitation state light-sensitive compound passes to airborne oxygen molecule with energy, makes it to become excitation state:
2、
The oxygen molecule of this excitation state has very high energy, immediately with spot and pigment, and microbial action, making it becomes colourless fragment, thereby makes fabric bleaching and sterilization:
3、
In addition, known enzyme is to remove protein, effective washing agent additive of fat type soil, but because itself is lived protein, so the above is all kinds of chloride, oxygen-bearing bleaching agent all has in various degree lethal effect to enzyme, so just limited in the past bleaching agent and the common use of enzyme.And this photosensitive bleaching agent does not only have lethal effect to enzyme, and also has certain synergy when coexisting with enzyme sometimes.
The object of the present invention is to provide a kind of photosensitive bleaching agent that contains light-sensitive compound, can improve the detergent bleach function of washing agent.It can use separately, also can cooperate commercially available detergent to use, so that according to the character of washings, makes full use of the energy of sunshine.
This photosensitive bleaching agent is characterized in that having following composition:
A, base-material: monocycle porphines and dicyclo porphines light-sensitive compound, its feature such as structural formula I:
X in the formula be (N=) or (=CY-); Y is H, alkyl, cycloalkyl, aralkyl, aryl, or heterocycle; Each R is H, or alkyl, cycloalkyl, and aralkyl, aryl, or heterocycle, and adjacent group can link to each other; A is two H atoms, or Cd (II), Mg (II), Ca (II), A1 (III), Sc (III), Cu (II), Zn (II), Sn (IV); B is an anion in the formula, CATION, nonionic or amphion; M be the B group counter ion; S is the number of solubility group in the formula; N among the formula II is 1,2,3.
If B is a CATION, then M is an anion; If B is an anion, then M is sun.
If B is an anion, then be sulfonic group, sulfate, phosphate, carboxylic acid group, or the polyoxyethylene ether of sulfonic acid or sulfuric acid replacement, its counter ion M is alkali-metal salt, ammonium ion or alkyl phosphate ion; If B is a CATION, then be ammonium ion or alkyl phosphate ion, its counter ion M is halogen ion or p-methyl benzenesulfonic acid base.
If B is a nonionic, then B is polyoxyethylene groups, sulfuric acid single ethanol amide, sulfuric acid diglycollic amide, sulfonic acid single ethanol amide, sulfonic acid diglycollic amide, polyethylene glycol dicarboxylic acid monoesters etc.
The synthetic route of some monocycle porphines light-sensitive compound that this photosensitive bleaching agent is related is as follows:
The synthetic route of the dicyclo porphines light-sensitive compound that this photosensitive bleaching agent is related is as follows:
B, bleach boosters: inorganic salts such as silicate, Quadrafos, citrate, sulfate, sulphite, 4A zeolite, boron-moisten soil, perborate, carbonate, Bio-sil and enzyme etc.Powdery and liquid detergent can be used as bleach boosters.
C, wetting agent: anion surfactant, non-ionic surface active agent, ethylenic unsaturated acid copolymer etc., super absorbent resin ester etc.
If anion surfactant then is an alkylbenzenesulfonate, fatty alcohol polyoxyethylene ether sulfate, aliphatic alcohol polyethenoxy ether carboxylate, α-Xi Jihuangsuanyan etc.; If non-ionic surface active agent then is a fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, glyceryl monostearate, sorbitan fatty acid esters, sucrose fatty ester etc.; The ethylenic unsaturated acid copolymer is maleic anhydride and polymerizing acrylic acid thing (molecular weight 2,000-20,000) etc.
D, foam stabilizer: higher aliphatic (C
10-C
22), higher fatty acids (C
10-C
22) and fatty acid amide (C
10-C
22) etc.;
E, fluorescent whitening agent and essence.
Fluorescent whitening agent: talan biphenyl sulfonate type, as CBS[4,4 '-two (2-sulfonic acid styrene) biphenyl], or the talan sulfonate type, as VBL[4,4 '-two (4-hydroxyethylamines-6-anilino--1,3,5-triazine-2 base) amino-talan-2,2 '-sodium disulfonate], BST[4,4 '-two (2,5-disulfobenzene amido)-4-morpholinyls-1,3,5-triazine-2-base is amino] talan-2,2 ' sodium disulfonate etc.
This photosensitive bleaching agent contains following component:
Weight ratio is the light-sensitive compound of 0.01-60%;
Weight ratio is the bleach boosters of 1-99.9%;
Weight ratio is the wetting agent of 0-40%;
Weight ratio is the foam stabilizer (when anion surfactant was 0, foam stabilizer was 0) of 0-8%;
Fluorescent whitening agent, colorant, preservative agent and the essence of trace convention amount.
Wherein this photosensitive bleaching agent comprises liquid photosensitive bleaching agent and solid photosensitive bleaching agent.The liquid photosensitive bleaching agent contains:
Weight ratio is the light-sensitive compound of 0.01-30%;
Weight ratio is the bleach boosters of 1-40%;
Weight ratio is the wetting agent of 0-40%;
Weight ratio is the foam stabilizer (when anion surfactant was 0, foam stabilizer was 0) of 0-5%;
Fluorescent whitening agent, colorant, preservative agent and the essence of trace convention amount.
The solid photosensitive bleaching agent, contain:
Weight ratio is the light-sensitive compound of 0.01-60%;
Weight ratio is the bleach boosters of 40-99.9%;
Weight ratio is the wetting agent of 0-40%;
Weight ratio is the foam stabilizer (when anion surfactant was 0, foam stabilizer was 0) of 0-8%;
Fluorescent whitening agent, preservative agent, colorant and the essence of trace convention amount.
The preparation method of liquid photosensitive bleaching agent carries out by the following method:
At first that light-sensitive compound is soluble in water at 20-50 ℃, stirred 20-60 minute, add Quadrafos, sulfate, silicate, Quadrafos, citrate, sulfate, sulphite, sodium alkyl benzene sulfonate, fatty alcohol polyoxyethylene ether sulfate, salts substances such as aliphatic alcohol polyethenoxy ether carboxylate, stirred 1-2.5 hour, and made abundant dissolving, this is a solution A; Then with fluorescent whitening agent, non-ionic surface active agent, materials such as polymer add the aqueous solution at 50-80 ℃, stir 30-70 minute, and this is a solution B; A and two kinds of solution mixing of B stirring were cooled to below 45 ℃ after 50-70 minute, add essence, last, add water to predetermined.
The preparation method of the photosensitive fabric bleaching agent of solid carries out by the following method:
1, at first light-sensitive compound is pulverized with ball mill, this is component A;
2, again with Quadrafos, sulfate, salts substances such as silicate, Quadrafos, citrate, sulfate, sulphite, sodium alkyl benzene sulfonate are pulverized in ball mill, and this is a B component;
3,30-80 ℃ of dissolving, this is component C with usefulness low amounts of water such as the wetting agent of non-salt, foam stabilizer, fluorescent whitening agent (be no more than gross weight 6%);
4, small powders such as essence are made a spot of ethanol water, this is component D;
5, with component A, B, C, D mix in rotary drum and are finished product.Also can be processed into particle with kneader.
If adopt the 4A zeolite during preparation solid photosensitive bleaching agent, Bio-sil, fluffy profit soil, or washing powder is the prescription of bleach boosters, then at first with light-sensitive compound at the 20-50 ℃ of aqueous solution of making 1%-10%, mix the back with zeolite etc. and in thin film evaporator, steam and remove moisture, mix in rotary drum with other components again, or be sprayed on other the component, or directly in rotary drum, mix.
This photosensitive bleaching agent can add running water separately fabric is bleached, also can cooperate any washing agent to use, also can when making washing agent, join in the conventional prescription, handling bath raio (ratio of light-sensitive compound and bleaching liquid or cleaning solution) is 1: 2,000-1: 100,000, can receive tangible bleaching effect.
Washing methods can soak fabric in the sun, also airing in the sun.The bleaching degree and sunny degree weather and the length of airing time, and the degree of polluting is relevant.Sunlight is sufficient more, and the airing time is long more, and it is serious more that fabric pollutes, and clean result is remarkable more.
Example I-V: the composition of photosensitive bleaching agent
The listed prescription of following table is % by weight:
| Raw material | I | II | III | IV | V |
| Two porphines 5,10,15-three (4-sulphenyl)-20-[4-[3-[4-[10,15,20-three (4-sulphenyl)-5-porphines base] phenoxy group] propoxyl group] phenyl] porphines sodium sulfonate (DTPPS 6) (light-sensitive compound A) | 2.0 | ||||
| 5,10,15,20-four (front three aminophenyl) porphines paratoluenesulfonic acid ammonium salt (light-sensitive compound B) | 1.0 | 3.0 | |||
| 5,10,15,20-four p-hydroxybenzene porphines, four polyethylene glycol succinates (light-sensitive compound C) | 3.0 | ||||
| The blue or green zinc four sulfo group diglycollic amides (light-sensitive compound D) of phthalein | 2.0 | ||||
| Dodecanol polyoxyethylene ether carboxylic acid sodium (EO 3) | 11.0 | ||||
| Neopelex | 30.0 | 20.0 | |||
| The dodecyl alcohol polyoxyethylene ether sodium sulfate | 15.0 | ||||
| Dodecanol polyoxyethylene ether (EO 6-9) | 5.0 | 20.0 | |||
| The glycerol monostearate | 5.0 | ||||
| I-octadecanol polyoxyethylene ten pentaethers | 2.0 | 5.0 | |||
| Sodium sulphate | 10.0 | Surplus |
| Sodium phosphate trimer | 18.0 | 30.0 | |||
| Sodium metasilicate | 5.0 | 10.0 | 8.0 | ||
| The 4A zeolite | 30.0 | 22.0 | |||
| Sodium sulfite | 5.0 | ||||
| Sodium carboxymethylcellulose | 5.0 | ||||
| Granulated detergent | 47.0 | ||||
| Acrylic acid/copolymer-maleic anhydride | 0.8 | 5.0 | |||
| High hydroscopic resin | 0.3 | ||||
| Protease | 2.5 | 5.0 | |||
| Lipase | 2.5 | ||||
| Fluorescent whitening agent, preservative agent, essence, colorant | Trace | Trace | Trace | Trace | Trace |
| Water | 8.0 | Surplus | Surplus | 7.0 | 6.0 |
Example VI: application examples (bleach merely and cooperate commodity washing powder detergent bleach)
Be equipped with in the basin of one liter of running water in bleaching agent shown in 0.25ml (1) the formula I I is added, place under the outdoor sunlight, put into 60 * 60cm
2The coffee soiled cotton, a same in addition soiled cotton is put into the running water of the same volume of no bleaching agent, thing was rinsed two cloth specimens well after 120 minutes with running water in contrast, pressed driedly, or soaked airing in the sun after 30 minutes.The cloth specimen that soaks in bleaching agent compares with the whiteness (sweet thatch whiteness) of contrast cloth specimen, and whiteness obviously increases, and Δ Δ R is 2.7-7.2 (Δ Δ R is that range estimation in 1.5 o'clock has notable difference).
Be applied to be added with the running water of 3g/l panda brand washing powder with quadrat method, the cloth specimen that soaks in being added with the washing powder water of photosensitive bleaching agent is apparently higher than the person that only is added with washing powder.
Be applied to two kinds with quadrat method and be added with the super running water of imitating concentrated detergent powder of 1g/l, Δ Δ R is 3.0-6.3.
The difference of bleaching degree and fine degree and the length of airing time, and the degree of polluting is relevant.
Example VII A: application examples (synergy of photosensitive bleaching agent and enzyme)
Prescription 1 and every liter of running water of formula I II add photosensitive bleaching agent and are respectively 0.125g and 0.085g, bleach and add the detergent bleach of washing powder merely by the example VI same procedure.Tester is the same prescription that does not contain the same prescription of enzyme and do not contain photosensitive bleaching agent.
Result is 3.82-7.20 (A value) for the Δ Δ R value that promptly contains enzyme and contain the prescription of light-sensitive compound again, and do not contain enzyme, the prescription Δ Δ R value that only contains light-sensitive compound is 2.5-6.20 (B value), only contains enzyme but the Δ Δ R value that do not contain light-sensitive compound is 0.81-3.71 (C value).
For every group of test, always have A greater than B and A greater than C; General A is not less than B+C, and A is greater than (B+C) 2 more than the whiteness value sometimes.
Claims (4)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96104687A CN1058764C (en) | 1996-04-22 | 1996-04-22 | Photosensitive bleaching agent containing photosensitive compound and its preparing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96104687A CN1058764C (en) | 1996-04-22 | 1996-04-22 | Photosensitive bleaching agent containing photosensitive compound and its preparing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1137591A CN1137591A (en) | 1996-12-11 |
| CN1058764C true CN1058764C (en) | 2000-11-22 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96104687A Expired - Fee Related CN1058764C (en) | 1996-04-22 | 1996-04-22 | Photosensitive bleaching agent containing photosensitive compound and its preparing method |
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| US6277337B1 (en) * | 1998-07-21 | 2001-08-21 | Gambro, Inc. | Method and apparatus for inactivation of biological contaminants using photosensitizers |
| CN103695192A (en) * | 2013-11-28 | 2014-04-02 | 南通市通州区大达麻纺织有限公司 | Bactericidal disinfectant for sheet and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1045124A (en) * | 1989-02-22 | 1990-09-05 | 普罗格特-甘布尔公司 | The stable liquid detergent compositions that contains SYNTHETIC OPTICAL WHITNER |
-
1996
- 1996-04-22 CN CN96104687A patent/CN1058764C/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1045124A (en) * | 1989-02-22 | 1990-09-05 | 普罗格特-甘布尔公司 | The stable liquid detergent compositions that contains SYNTHETIC OPTICAL WHITNER |
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| Publication number | Publication date |
|---|---|
| CN1137591A (en) | 1996-12-11 |
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