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CN105860363A - PVC (polyvinyl chloride) profile and manufacturing method thereof - Google Patents

PVC (polyvinyl chloride) profile and manufacturing method thereof Download PDF

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Publication number
CN105860363A
CN105860363A CN201610379009.7A CN201610379009A CN105860363A CN 105860363 A CN105860363 A CN 105860363A CN 201610379009 A CN201610379009 A CN 201610379009A CN 105860363 A CN105860363 A CN 105860363A
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CN
China
Prior art keywords
pvc
mixture
pvc profile
profile
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610379009.7A
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Chinese (zh)
Inventor
金允明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changshan County Xin Hui Cleaning Supplies Co Ltd
Original Assignee
Changshan County Xin Hui Cleaning Supplies Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Changshan County Xin Hui Cleaning Supplies Co Ltd filed Critical Changshan County Xin Hui Cleaning Supplies Co Ltd
Priority to CN201610379009.7A priority Critical patent/CN105860363A/en
Publication of CN105860363A publication Critical patent/CN105860363A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a PVC (polyvinyl chloride) profile and a manufacturing method thereof. The PVC profile comprises the following raw materials in percentage by weight: 35-40% of PVC, 0.5-1% of stabilizer, 0.1-0.4% of impact-resistance modifier, 0.4-0.8% of lubricating regulator, 0.2-0.4% of whitener, 0.001-0.003% of pigment and the balance of filler. The PVC profile has the advantages of favorable heat stability, favorable long-term stability, excellent weather resistance, excellent acid/alkali resistance, low heat conductivity, favorable heat-insulation effect, low dielectric constant, favorable electric-insulation effect, low machining abrasion, smooth and fine surface and high production efficiency, and is suitable for high-speed extrusion of screw extruders.

Description

A kind of PVC profile and manufacture method thereof
Technical field
The present invention relates to plastic products technology field, particularly to a kind of PVC profile and manufacture method thereof.
Background technology
Section bar (extrudate) be iron or steel and the material with some strength and toughness (as plastics, Aluminium, glass fibre etc.) by rolling, extrusion, what the technique such as casting was made has certain geometrical shape Object.The handle that plastics hair is brushed lightly at present is typically all PVC and passes through extruder for shaping, the most also Belong to PVC profile.Existing plastics hair is brushed lightly typically all PVC handle and is inserted the steel wire being tied with plastics hair, This just requires that PVC handle has good intensity and comfortable feel, may place simultaneously because hair is brushed lightly Using in various environment, this just requires that PVC handle has heat endurance and long-time stability, has Excellent weatherability, resistance to acids and bases, have good effect of heat insulation, there is presently no for plastics hair Brush lightly the special manufacture method of PVC handle and formula.
Summary of the invention
The technical problem to be solved is to provide a kind of PVC with optimization formula comprehensively excellence Section bar and manufacture method thereof.
The present invention solves above-mentioned technical problem and be the technical scheme is that
A kind of PVC profile, comprises following raw material by weight percentage: PVC 35-40%, stable Agent 0.5-1%, anti-impact modifier 0.1-0.4%, lubrication conditioning agent 0.4-0.8%, brightening agent 0.2-0.4%, pigment 0.001-0.003%, surplus are filler.By brightening agent and pigment reasonably than Example proportioning obtains suitable color.
It is further preferred that comprise following raw material by weight percentage: PVC 36.73%, stablize Agent 0.81%, anti-impact modifier 0.29%, lubrication conditioning agent 0.63%, brightening agent 0.31%, pigment 0.002%, surplus is filler.
It is further preferred that described stabilizer is lead sulfate tribasic (being called for short three salt), two seasons penta The mixture of tetrol (DPE), barium stearate, stearic acid composition.Four kinds of compound stabilizers, collaborative Substantially, long-time stability are good in effect.
It is further preferred that described stabilizer proportioning by weight percentage is: lead sulfate tribasic 46%, dipentaerythritol 18%, barium stearate 18%, the mixture of stearic acid 18% composition.
It is further preferred that described anti-impact modifier is haloflex (CPE) and acrylate The mixture that copolymer (ACR) forms.The promotion that ACR is the most frequently used in the processing of PVC product is moulded Change the processing aid of class.It can efficiently control melt fracture phenomena, promotes the gel plasticizing of PVC, carries High plasticizing quality.ACR can reasonably improve the melted torque peace of material in the process of PVC Weighing apparatus torque, shortens the gel fusion time of material, reduces processing temperature.Make by ACR with CPE is compounding With, can there is good intermiscibility with PVC at processing temperatures, promote uniformly to synchronize plasticizing, improve PVC The rheological behaviour of thermoplastic state, improves melt strength, it is to avoid melt fracture, improves the inherent quality of goods And lustrous surface, there is the stability of long-time processing and forming, effectively prevent extrusion and injection time by Produce the surface defects such as filamentary silver in extruded produced pressure oscillation and flowing scar, promote to send out The uniform foam cell of brewage and refinement, improve the uniformity of PVC product quality, such as gloss appearance, resists Zhang Qiangdu, impact strength and elongation at break etc., keep the original premium properties of PVC, add various In work mechanical process, all can promote processing, the most highly effective raising weather resisteant smoothly, substantially reduce each Plant the deposition on processing equipment surface such as additive component such as stabilizer, pigment etc..
It is further preferred that described anti-impact modifier proportioning by weight percentage is: chlorination gathers The mixture of ethene 50%, ACR 50% composition.
It is further preferred that described lubrication conditioning agent proportioning by weight percentage is: Tissuemat E 23% and paraffin 77% composition mixture.The two compounding use is that PVC has more preferable internal lubrication work With, the heat endurance of PVC can also be improved further simultaneously.
It is further preferred that described brightening agent proportioning by weight percentage is: titanium dioxide 95%, increasing The mixture of white powder 5% composition.The preferred OB of whitening powder (main component be 2.5-double-(the 5-tert-butyl group- 2-benzoxazolyl group) thiophene), whiteness height, strong covering power, good stability, acid and alkali-resistance, Mohs are hard Spend low, can partly replace titanium dioxide, reduce product cost;The weatherability of PVC profile can be significantly improved And Antacid effectiveness, extend life of product;With titanium dioxide with the use of, significantly improve the weatherability of product, Extend life of product;The mechanical strength of PVC profile, heat resistance and dimensional stability can be effectively improved Deng;Mohs' hardness is low, and the abrasion to processing equipment is few, with titanium dioxide with the use of, can make processed Journey extruding is more smooth and easy;Thermal conductivity is low, has good effect of heat insulation;Dielectric constant is low, has good Good insulation effect.(chemical name is that 1.4-is double (benzoxazolyl group-2-base) can also to select KCB Naphthalene), OB-1 (chemical name is 2.2 '-(4,4 '-diphenylethyllene-) double benzothiazoles), ER (main component is hexichol and ethylene type derivative compound), (main component is hexichol to DBH-1 Ethylene type derivative compound), (chemical name is that 4.4-is double (5 methyl-2-benzoxazolyl group) to KSB Talan compound), (chemical name is 4 to FP-127, double (the 2-dimethoxy-styryl of 4-- -) biphenyl).
It is further preferred that described pigment is ultramarine, described filler is stone flour.
The manufacture method of PVC profile, comprises the following steps:
Step one, by the PVC of formula ratio, stabilizer, anti-impact modifier, lubrication conditioning agent, brighten Agent, pigment and filler high-speed stirred 50min;
Step 2, mixture step one obtained add extruder granulation;
Step 3, PVC grain step 2 obtained add extruder trombone slide, i.e. obtain PVC profile, It is particularly suited for hair and brushes lightly handle.
Compared with prior art, the present invention has a following beneficial effect:
The invention of this reality provides formula and the manufacture method of a kind of PVC profile, and this PVC profile heat is steady Qualitative and long-time stability are good, have excellent weatherability, resistance to acids and bases, and thermal conductivity is low, has good Good effect of heat insulation, dielectric constant is low, has good insulation effect, and machining abrasion is few, table The smooth exquisiteness in face, is suitable for screw extruder high speed extrusion, and production efficiency is high.
Detailed description of the invention
Below by specific embodiment, the present invention is described in further detail, the various composition of the present invention Content be the weight of each composition and account for the percentage by weight of PVC profile gross weight and represent.
Embodiment 1
A kind of PVC profile, comprise following raw material by weight percentage: PVC 35%, stabilizer 1%, Anti-impact modifier 0.1%, lubrication conditioning agent 0.8%, brightening agent 0.2%, pigment 0.003%, surplus For filler.
Described stabilizer proportioning by weight percentage is: lead sulfate tribasic 46%, dipentaerythritol 18%, barium stearate 18%, the mixture of stearic acid 18% composition.
Described anti-impact modifier proportioning by weight percentage is: haloflex 50%, acrylic acid The mixture of resin copolymer 50% composition.
Described lubrication conditioning agent proportioning by weight percentage is: Tissuemat E 23% and 77% group of paraffin The mixture become.
Described brightening agent proportioning by weight percentage is: titanium dioxide 95%, whitening powder 5% composition Mixture.
Described pigment is ultramarine, and described filler is stone flour.
The manufacture method of PVC profile, comprises the following steps:
Step one, by the PVC of formula ratio, stabilizer, anti-impact modifier, lubrication conditioning agent, brighten Agent, pigment and filler high-speed stirred 50min;
Step 2, mixture step one obtained add extruder granulation;
Step 3, PVC grain step 2 obtained add extruder trombone slide, i.e. obtain PVC profile.
Embodiment 2
A kind of PVC profile, comprise following raw material by weight percentage: PVC 40%, stabilizer 0.5%, Anti-impact modifier 0.4%, lubrication conditioning agent 0.4%, brightening agent 0.4%, pigment 0.001%, surplus For filler.
Described stabilizer proportioning by weight percentage is: lead sulfate tribasic 46%, dipentaerythritol 18%, barium stearate 18%, the mixture of stearic acid 18% composition.
Described anti-impact modifier proportioning by weight percentage is: haloflex 50%, acrylic acid The mixture of resin copolymer 50% composition.
Described lubrication conditioning agent proportioning by weight percentage is: Tissuemat E 23% and 77% group of paraffin The mixture become.
Described brightening agent proportioning by weight percentage is: titanium dioxide 95%, whitening powder 5% composition Mixture.
Described pigment is ultramarine, and described filler is stone flour.
The manufacture method of PVC profile, comprises the following steps:
Step one, by the PVC of formula ratio, stabilizer, anti-impact modifier, lubrication conditioning agent, brighten Agent, pigment and filler high-speed stirred 50min;
Step 2, mixture step one obtained add extruder granulation;
Step 3, PVC grain step 2 obtained add extruder trombone slide, i.e. obtain PVC profile.
Embodiment 3
A kind of PVC profile, comprises following raw material by weight percentage: PVC 36.73%, stablizes Agent 0.81%, anti-impact modifier 0.29%, lubrication conditioning agent 0.63%, brightening agent 0.31%, pigment 0.002%, surplus is filler.
Described stabilizer is lead sulfate tribasic, dipentaerythritol, barium stearate, stearic acid composition Mixture.
Described stabilizer proportioning by weight percentage is: lead sulfate tribasic 46%, dipentaerythritol 18%, barium stearate 18%, the mixture of stearic acid 18% composition.
Described anti-impact modifier is haloflex and the mixture of ACR composition.
Described anti-impact modifier proportioning by weight percentage is: haloflex 50%, acrylic acid The mixture of resin copolymer 50% composition.
Described lubrication conditioning agent proportioning by weight percentage is: Tissuemat E 23% and 77% group of paraffin The mixture become.
Described brightening agent proportioning by weight percentage is: titanium dioxide 95%, whitening powder 5% composition Mixture.
Described pigment is ultramarine, and described filler is stone flour.
The manufacture method of PVC profile, comprises the following steps:
Step one, by the PVC of formula ratio, stabilizer, anti-impact modifier, lubrication conditioning agent, brighten Agent, pigment and filler high-speed stirred 50min;
Step 2, mixture step one obtained add extruder granulation;
Step 3, PVC grain step 2 obtained add extruder trombone slide, i.e. obtain PVC profile.
The invention of this reality provides formula and the manufacture method of a kind of PVC profile, and this PVC profile heat is steady Qualitative and long-time stability are good, have excellent weatherability, resistance to acids and bases, and thermal conductivity is low, has good Good effect of heat insulation, dielectric constant is low, has good insulation effect, and machining abrasion is few, table The smooth exquisiteness in face, is suitable for screw extruder high speed extrusion, and production efficiency is high.
According to embodiment and comparative example, the present invention is described in detail above, but the present invention is not It is limited to above-described embodiment and comparative example, in the ken that those skilled in the art possess, it is also possible to Make a variety of changes without departing from the inventive concept of the premise.

Claims (10)

1. a PVC profile, it is characterised in that comprise following raw material by weight percentage: PVC 35-40%, stabilizer 0.5-1%, anti-impact modifier 0.1-0.4%, lubrication conditioning agent 0.4-0.8%, Brightening agent 0.2-0.4%, pigment 0.001-0.003%, surplus are filler.
PVC profile the most according to claim 1, it is characterised in that comprise following by weight hundred The raw material of proportion by subtraction meter: PVC 36.73%, stabilizer 0.81%, anti-impact modifier 0.29%, lubrication Conditioning agent 0.63%, brightening agent 0.31%, pigment 0.002%, surplus are filler.
PVC profile the most according to claim 1 and 2, it is characterised in that: described stabilizer For lead sulfate tribasic, dipentaerythritol, barium stearate, the mixture of stearic acid composition.
PVC profile the most according to claim 3, it is characterised in that: described stabilizer is by weight Amount percentages proportioning be: lead sulfate tribasic 46%, dipentaerythritol 18%, barium stearate 18%, The mixture of stearic acid 18% composition.
PVC profile the most according to claim 1 and 2, it is characterised in that: described shock resistance Modifying agent is haloflex and the mixture of ACR composition.
PVC profile the most according to claim 5, it is characterised in that: described impact modification Agent proportioning by weight percentage is: haloflex 50%, ACR 50% composition Mixture.
PVC profile the most according to claim 1 and 2, it is characterised in that: described lubrication is adjusted Joint agent proportioning by weight percentage is: Tissuemat E 23% and the mixture of paraffin 77% composition.
PVC profile the most according to claim 1 and 2, it is characterised in that: described brightening agent Proportioning by weight percentage is: the mixture of titanium dioxide 95%, whitening powder 5% composition.
PVC profile the most according to claim 1 and 2, it is characterised in that: described pigment is Ultramarine, described filler is stone flour.
10. a manufacture method for PVC profile according to claim 1 and 2, its feature exists In, comprise the following steps:
Step one, by the PVC of formula ratio, stabilizer, anti-impact modifier, lubrication conditioning agent, brighten Agent, pigment and filler high-speed stirred 50min;
Step 2, mixture step one obtained add extruder granulation;
Step 3, PVC grain step 2 obtained add extruder trombone slide, i.e. obtain PVC profile.
CN201610379009.7A 2016-05-24 2016-05-24 PVC (polyvinyl chloride) profile and manufacturing method thereof Pending CN105860363A (en)

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Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107652575A (en) * 2017-09-27 2018-02-02 苏州富通高新材料科技股份有限公司 A kind of section bar and its preparation technology for landscape flower box
CN107686616A (en) * 2017-09-26 2018-02-13 苏州富通高新材料科技股份有限公司 A kind of section bar and its technique for connecting groove
CN108164868A (en) * 2017-12-25 2018-06-15 王升瑶 PVC profile and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101948593A (en) * 2010-09-13 2011-01-19 建德市双剑工具有限公司 Granule formula for rare-earth two-color bar handle
CN102863711A (en) * 2011-07-06 2013-01-09 中国石油化工股份有限公司 Heat-resisting PVC high impact-resisting tubular product and preparation method thereof
CN104710703A (en) * 2013-12-12 2015-06-17 天津德昊超微新材料有限公司 Special material for automobile injection-moulded handle
CN105385067A (en) * 2015-12-16 2016-03-09 无锡嘉弘塑料科技有限公司 Folding-whitening-free high-weather-resistance hard PVC extrusion profile black pellet and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101948593A (en) * 2010-09-13 2011-01-19 建德市双剑工具有限公司 Granule formula for rare-earth two-color bar handle
CN102863711A (en) * 2011-07-06 2013-01-09 中国石油化工股份有限公司 Heat-resisting PVC high impact-resisting tubular product and preparation method thereof
CN104710703A (en) * 2013-12-12 2015-06-17 天津德昊超微新材料有限公司 Special material for automobile injection-moulded handle
CN105385067A (en) * 2015-12-16 2016-03-09 无锡嘉弘塑料科技有限公司 Folding-whitening-free high-weather-resistance hard PVC extrusion profile black pellet and preparation method thereof

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* Cited by examiner, † Cited by third party
Title
张玉龙等: "《塑料制品配方与制备手册》", 31 January 2015, 机械工业出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107686616A (en) * 2017-09-26 2018-02-13 苏州富通高新材料科技股份有限公司 A kind of section bar and its technique for connecting groove
CN107652575A (en) * 2017-09-27 2018-02-02 苏州富通高新材料科技股份有限公司 A kind of section bar and its preparation technology for landscape flower box
CN108164868A (en) * 2017-12-25 2018-06-15 王升瑶 PVC profile and preparation method thereof

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Application publication date: 20160817