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CN105851028A - Complex herbicide of prosulfocarb and efficient dimethenamid - Google Patents

Complex herbicide of prosulfocarb and efficient dimethenamid Download PDF

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Publication number
CN105851028A
CN105851028A CN201610338191.1A CN201610338191A CN105851028A CN 105851028 A CN105851028 A CN 105851028A CN 201610338191 A CN201610338191 A CN 201610338191A CN 105851028 A CN105851028 A CN 105851028A
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CN
China
Prior art keywords
dimethenamid
prosulfocarb
herbicidal combinations
herbicidal
weeding composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610338191.1A
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Chinese (zh)
Inventor
唐剑峰
刘杰
额尔敦巴特尔
张�杰
吴雪
刘振邦
乔思佳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WEIFANG ZHONGNONG UNITED CHEMICAL CO Ltd
Original Assignee
WEIFANG ZHONGNONG UNITED CHEMICAL CO Ltd
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Publication date
Application filed by WEIFANG ZHONGNONG UNITED CHEMICAL CO Ltd filed Critical WEIFANG ZHONGNONG UNITED CHEMICAL CO Ltd
Priority to CN201610338191.1A priority Critical patent/CN105851028A/en
Publication of CN105851028A publication Critical patent/CN105851028A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a complex herbicide of prosulfocarb and efficient dimethenamid. The complex herbicide takes prosulfocarb and dimethenamid as effective components; the mass ratio of prosulfocarb to dimethenamid is (1-9):(1-9); the total mass percentage of prosulfocarb and dimethenamid in the weeding composition is 10-90%. The weeding composition can be applied to various gramineaes and broad leaf weeds; with the combination of prosulfocarb and dimethenamid in the weeding composition disclosed by the invention, an excellent synergistic interaction function can be achieved, the weeding composition is applicable to various gramineaes and broad leaf weeds, is wide in herbicide controlling spectrum and long in use time, can be used before and after seedling, and is free of toxic or side effect on crops; the use dosages of prosulfocarb and dimethenamid in the weeding composition disclosed by the invention are remarkably reduced when being compared with that of prosulfocarb or dimethenamid, so that the pesticide residues of pesticide in crops are reduced, and the resistance is retarded.

Description

Prosulfocarb and dimethenamidP complex weedicide
Technical field
The present invention relates to technical field of pesticide, a kind of containing prosulfocarb and the Herbicidal combinations of dimethenamid and Its application.
Background technology
In the arviculture ploughed, need to remove suppression crop growth or the weeds of harvest, even if at bare place In, efficiently control weeds and be also advantageous for effective utilization of bare place, therefore, the control of weeds is being ploughed and in bare place is being all Necessary, in recent years, various herbicides are widely used, but weeds is of a great variety, when the germination of various weeds and growth Phase is different, and its preventing and treating is over a long time, therefore, prevents and treats all of weeds by the distribution of a herbicide the most difficult, because of This, a kind of broad weed-killing spectrum, also effective to the weeds grown, can maintain over a period to come and press down grass effect, simultaneously to work The herbicide of thing safety is urgently studied.
Summary of the invention
For solving the problems referred to above, it is an object of the invention to provide a kind of containing prosulfocarb with the Herbicidal combinations of dimethenamid And application.
The present invention for achieving the above object, is achieved through the following technical solutions:
A kind of containing prosulfocarb with the Herbicidal combinations of dimethenamid, this Herbicidal combinations is to be with prosulfocarb and dimethenamid Effective ingredient, wherein the mass ratio of prosulfocarb and dimethenamid is 1 ~ 9:1 ~ 9;Prosulfocarb and dimethenamid are at Herbicidal combination Gross mass percentage composition in thing is 10 ~ 90%.
Preferably, the dosage form of Herbicidal combinations is cream, aqueous emulsion, suspension emulsion, granule;Prosulfocarb and dimethenamid Gross mass percentage composition in Herbicidal combinations is 10 ~ 80%.
Preferably, the mass ratio of prosulfocarb and dimethenamid is 1 ~ 4:1 ~ 4.
Preferably, being calculated in mass percent, Herbicidal combinations is by prosulfocarb 75%, dimethenamid 5%, sulfonated castor oil 6%, calcium dodecyl benzene sulfonate 2% and 150# solvent naphtha 12% is configured to cream.
Preferably, being calculated in mass percent, Herbicidal combinations is to be gathered by prosulfocarb 20%, dimethenamid 10%, alkyl phenol Oxygen vinyl Ether phosphate ester 4%, polyoxyethylene ether block copolymers 5%, solvent naphtha 150# 10%, propylene glycol 5% and deionized water 46% It is configured to aqueous emulsion.
Preferably, Herbicidal combinations is by prosulfocarb 20%, dimethenamid 25%, spectrasolv DMDA 5%, sulphuric acid Salt 2%, EO-PO block copolymer 2%, polycarboxylate 2%, propylene glycol 4%, xanthan gum 0.2%, Kazon 0.4%, polysiloxane compound 0.3% and deionized water 39.1% preparation suspension emulsion.
Preferably, being calculated in mass percent, Herbicidal combinations is by prosulfocarb 7%, dimethenamid 2%, ethanol 2%, 12 Alkyl sodium sulfate 1%, sodium lignin sulfonate 3%, white carbon 5% and the granule of attapulgite 80% preparation.
Present invention additionally comprises containing prosulfocarb and the application of the Herbicidal combinations of dimethenamid, for various grass tree sections and wealthy Leaf weeds.
The present invention have the advantage that compared to existing technology the present invention containing prosulfocarb and the Herbicidal combination of dimethenamid The combination of thing has the synergistic function of excellence, it is adaptable to various grass tree sections and broad leaved weed, broad weed-killing spectrum, use age Long, before can be used for Seedling, it is also possible at the initial stage after Seedling, crop is had no side effect;The present invention's is careless containing prosulfocarb and diformazan thiophene The more single prosulfocarb of using dosage of the Herbicidal combinations of amine or dimethenamid compare substantially reduction, thus reduce pesticide Pesticide residues in crop, have delayed the generation of resistance;The present invention containing prosulfocarb and the Herbicidal combinations of dimethenamid Can use after emerging, it is possible to crop is shown the highest safety, thus has extraordinary on preventing and treating resistant weed Effect;
The Herbicidal combinations containing prosulfocarb and dimethenamid of the present invention can make used additives be prepared as preparation common on pesticide Kind, such as suspending agent, water preparation, aqueous emulsion, microemulsion, water dispersible granules, cream, suspension seed-coating agent, dispersibles oil preparation, granule With the agricultural such as microcapsule suspending agent can accept all formulations of pesticide of using.
Detailed description of the invention
It is an object of the invention to provide a kind of containing prosulfocarb and the Herbicidal combinations of dimethenamid and application, by following skill Art scheme realizes:
A kind of containing prosulfocarb with the Herbicidal combinations of dimethenamid, this Herbicidal combinations is to be with prosulfocarb and dimethenamid Effective ingredient, wherein the mass ratio of prosulfocarb and dimethenamid is 1 ~ 9:1 ~ 9;Prosulfocarb and dimethenamid are at Herbicidal combination Gross mass percentage composition in thing is 10 ~ 90%.
Preferably, the dosage form of Herbicidal combinations is cream, aqueous emulsion, suspension emulsion, granule;Prosulfocarb and dimethenamid Gross mass percentage composition in Herbicidal combinations is 10 ~ 80%.
Preferably, the mass ratio of prosulfocarb and dimethenamid is 1 ~ 4:1 ~ 4.
Preferably, being calculated in mass percent, Herbicidal combinations is by prosulfocarb 75%, dimethenamid 5%, sulfonated castor oil 6%, calcium dodecyl benzene sulfonate 2% and 150# solvent naphtha 12% is configured to cream.
Preferably, being calculated in mass percent, Herbicidal combinations is to be gathered by prosulfocarb 20%, dimethenamid 10%, alkyl phenol Oxygen vinyl Ether phosphate ester 4%, polyoxyethylene ether block copolymers 5%, solvent naphtha 150# 10%, propylene glycol 5% and deionized water 46% It is configured to aqueous emulsion.
Preferably, Herbicidal combinations is by prosulfocarb 20%, dimethenamid 25%, spectrasolv DMDA 5%, sulphuric acid Salt 2%, EO-PO block copolymer 2%, polycarboxylate 2%, propylene glycol 4%, xanthan gum 0.2%, Kazon 0.4%, polysiloxane compound 0.3% and deionized water 39.1% preparation suspension emulsion.
Preferably, being calculated in mass percent, Herbicidal combinations is by prosulfocarb 7%, dimethenamid 2%, ethanol 2%, 12 Alkyl sodium sulfate 1%, sodium lignin sulfonate 3%, white carbon 5% and the granule of attapulgite 80% preparation.
Present invention additionally comprises containing prosulfocarb and the application of the Herbicidal combinations of dimethenamid, for various grass tree sections and wealthy Leaf weeds, including Semen Euphorbiae, Agrostis, Lolium, Echinochloa, Waterplantain, short Rhizoma sagittariae sagittifoliae, cyperus iria, Chenopodium, Amaranthus, rain For a long time the crop such as Pittosporum, Veronica field common weed, can be used for the preventing and treating of crop Tanaka's resistant weed, can be used for cereal crops, Control of weeds in corn field, wheatland, rice terrace and potato fields, can use before Seedling, it is possible to after Seedling, the initial stage uses, to work Thing safety is high.
The Herbicidal combinations containing prosulfocarb and dimethenamid of the present invention can be processed into suspending agent, water preparation, aqueous emulsion, micro- Emulsion, water dispersible granules, cream, suspension seed-coating agent, suspension emulsion, dispersible oil preparation, granule, microcapsule suspending agent, microcapsule suspension- The agriculturals such as suspending agent can accept all formulations of pesticide used, the occupation mode of compositions, can be seed dressing or kind attached bag The most acceptable mode that the pesticidal preparations such as clothing, ditch spread, spraying use.
Below in conjunction with specific embodiment, the invention will be further described.
Embodiment 1
A kind of containing prosulfocarb with the Herbicidal combinations of dimethenamid, by prosulfocarb 5%, dimethenamid 5%, sulfonated castor oil 1% Form with deionized water 89%.
Embodiment 2
A kind of containing prosulfocarb with the Herbicidal combinations of dimethenamid, by prosulfocarb 5%, dimethenamid 45%, sulfonated castor oil 5% and ethanol 45% form.
Embodiment 3
A kind of containing prosulfocarb with the Herbicidal combinations of dimethenamid, by prosulfocarb 40%, dimethenamid 5%, detergent alkylate Sulfoacid calcium 2%, xanthan gum 3% and deionized water 50% form.
Embodiment 4
A kind of containing prosulfocarb with the Herbicidal combinations of dimethenamid, by prosulfocarb 45%, dimethenamid 45%, ten ethanol 2%, Xanthan gum 3% and sodium lignin sulfonate 5% form.
Embodiment 5
A kind of containing prosulfocarb with the Herbicidal combinations of dimethenamid, it is by prosulfocarb 75%, dimethenamid 5%, sulfonation Semen Ricini Oil 6%, calcium dodecyl benzene sulfonate 2% and 150# solvent naphtha 12% is configured to cream.
Embodiment 6
A kind of containing prosulfocarb with the Herbicidal combinations of dimethenamid, it is to be gathered by prosulfocarb 20%, dimethenamid 10%, alkyl phenol Oxygen vinyl Ether phosphate ester 4%, polyoxyethylene ether block copolymers 5%, solvent naphtha 150# 10%, propylene glycol 5% and deionized water 46% It is configured to aqueous emulsion.
Embodiment 7
A kind of containing prosulfocarb with the Herbicidal combinations of dimethenamid, it is by prosulfocarb 20%, dimethenamid 25%, N, N-diformazan Base decyl amide 5%, sulfate 2%, EO-PO block copolymer 2%, polycarboxylate 2%, propylene glycol 4%, xanthan gum 0.2%, Kazon 0.4%, polysiloxane compound 0.3% and the suspension emulsion of deionized water 39.1% preparation.
Embodiment 8
A kind of containing prosulfocarb with the Herbicidal combinations of dimethenamid, it is by prosulfocarb 7%, dimethenamid 2%, ethanol 2%, ten Sodium dialkyl sulfate 1%, sodium lignin sulfonate 3%, white carbon 5% and the granule of attapulgite 80% preparation.
The Herbicidal combinations of embodiment 1 ~ 8 is carried out tests below.
1. test before Seedling
Sowing weed seed and wheat seed respectively in planting tray, environmental condition is greenhouse suitable condition, and culture matrix is battalion Support soil.Herbicide (composition forms and prosulfocarb, dimethenamidP, the independent form of dimethenamid) is executed by the Seedling last stage For soil surface.Application dosage is determined according to environmental condition and edaphic condition, selects optium concentration.At 2 ~ 4 Zhou Houping (100%=plant is the most dead to estimate this test result;0%=is to plant plant-less toxicity effect), result of the test is as shown in table 1.
Result of the test table before table 1 Seedling
2.
3. test after Seedling
After Seedling, test mode is chosen as wheat paddock field experiment, carries out under conditions of soil moisture content is saturated.2 ~ 3 leaf after Seedling Phase, by herbicide (composition forms and prosulfocarb, the independent form of dimethenamid), it is applied to subject plant (weeds).Use Dosage is determined according to environmental condition and edaphic condition, selects optium concentration.This test of later evaluation in 10 ~ 22 days, (100% made The most dead with=plant;0% effect=plant-less toxicity effect).Investigate the herbicide impact on wheat crop simultaneously.Use 20 It effect is as shown in table 2.
The effect table of 20 days used by table 2
Being shown by the result of table 2, the prosulfocarb of the present invention is applied in combination with dimethenamid, has obvious synergistic function, The two is applied in combination, and reduces the dosage being used alone a kind of composition, and active component total using dosage step-down, prevents weeds Effect is significantly improved.
Prosulfocarb is applied in combination with dimethenamid, and lower to environment harmful effect, residual quantity is less;With single benzyl grass Red or dimethenamid is compared, and synergistic function is obvious, and under the conditions of identical using dosage, preventive effect is the most excellent.Make in recommendation With under dosage, prosulfocarb and dimethenamid are fool proof to Semen Tritici aestivi, and have good preventive effect to weeds.

Claims (8)

1. one kind contains prosulfocarb and the Herbicidal combinations of dimethenamid, it is characterised in that: this Herbicidal combinations is with prosulfocarb Being effective ingredient with dimethenamid, wherein the mass ratio of prosulfocarb and dimethenamid is 1 ~ 9:1 ~ 9;Prosulfocarb and diformazan thiophene Grass amine gross mass percentage composition in Herbicidal combinations is 10 ~ 90%.
It is the most according to claim 1 containing prosulfocarb with the Herbicidal combinations of dimethenamid, it is characterised in that: Herbicidal combination The dosage form of thing is cream, aqueous emulsion, suspension emulsion, granule;Prosulfocarb and the dimethenamid gross mass in Herbicidal combinations Percentage composition is 10 ~ 80%.
The most according to claim 1 containing prosulfocarb with the Herbicidal combinations of dimethenamid, it is characterised in that: prosulfocarb and The mass ratio of dimethenamid is 1 ~ 4:1 ~ 4.
It is the most according to claim 1 containing prosulfocarb with the Herbicidal combinations of dimethenamid, it is characterised in that: with quality hundred Mark meter, Herbicidal combinations is by prosulfocarb 75%, dimethenamid 5%, sulfonated castor oil 6%, calcium dodecyl benzene sulfonate 2% He 150# solvent naphtha 12% is configured to cream.
It is the most according to claim 1 containing prosulfocarb with the Herbicidal combinations of dimethenamid, it is characterised in that: with quality hundred Mark meter, Herbicidal combinations is by prosulfocarb 20%, dimethenamid 10%, alkylphenol polyoxyethylene phosphate ester 4%, polyoxy second Alkene ether block copolymers 5%, solvent naphtha 150# 10%, propylene glycol 5% and deionized water 46% are configured to aqueous emulsion.
It is the most according to claim 1 containing prosulfocarb with the Herbicidal combinations of dimethenamid, it is characterised in that: with quality hundred Mark meter, Herbicidal combinations is by prosulfocarb 20%, dimethenamid 25%, spectrasolv DMDA 5%, sulfate 2%, EO- PO block copolymer 2%, polycarboxylate 2%, propylene glycol 4%, xanthan gum 0.2%, Kazon 0.4%, polysiloxane compound 0.3% and going The suspension emulsion of ionized water 39.1% preparation.
It is the most according to claim 1 containing prosulfocarb with the Herbicidal combinations of dimethenamid, it is characterised in that: with quality hundred Mark meter, Herbicidal combinations is by prosulfocarb 7%, dimethenamid 2%, ethanol 2%, sodium lauryl sulphate 1%, lignin sulfonic acid Sodium 3%, white carbon 5% and the granule of attapulgite 80% preparation.
8. described in claim 1 containing prosulfocarb and the application of the Herbicidal combinations of dimethenamid, it is characterised in that: for each Plant grass tree section and broad leaved weed.
CN201610338191.1A 2016-05-20 2016-05-20 Complex herbicide of prosulfocarb and efficient dimethenamid Pending CN105851028A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610338191.1A CN105851028A (en) 2016-05-20 2016-05-20 Complex herbicide of prosulfocarb and efficient dimethenamid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101080172A (en) * 2004-12-17 2007-11-28 辛根塔参与股份公司 Herbicidal composition
US20120058896A1 (en) * 2006-12-21 2012-03-08 Kumiai Chemical Industry Co., Ltd. Herbicidal composition

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101080172A (en) * 2004-12-17 2007-11-28 辛根塔参与股份公司 Herbicidal composition
US20120058896A1 (en) * 2006-12-21 2012-03-08 Kumiai Chemical Industry Co., Ltd. Herbicidal composition

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
叶贵标: "除草剂作用机理分类法及其应用", 《农药科学与管理》 *

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Application publication date: 20160817