CN105838237B - A kind of preparation method of rubber high wear resistance coatings - Google Patents
A kind of preparation method of rubber high wear resistance coatings Download PDFInfo
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- CN105838237B CN105838237B CN201610395693.8A CN201610395693A CN105838237B CN 105838237 B CN105838237 B CN 105838237B CN 201610395693 A CN201610395693 A CN 201610395693A CN 105838237 B CN105838237 B CN 105838237B
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- 238000000576 coating method Methods 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 229920001971 elastomer Polymers 0.000 title claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 39
- 238000003756 stirring Methods 0.000 claims abstract description 22
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 239000008367 deionised water Substances 0.000 claims abstract description 12
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 12
- 239000013556 antirust agent Substances 0.000 claims abstract description 9
- 239000002562 thickening agent Substances 0.000 claims abstract description 9
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 8
- 229920005989 resin Polymers 0.000 claims abstract description 8
- 239000011347 resin Substances 0.000 claims abstract description 8
- 239000000080 wetting agent Substances 0.000 claims abstract description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920003180 amino resin Polymers 0.000 claims abstract description 7
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920002635 polyurethane Polymers 0.000 claims abstract description 7
- 239000004814 polyurethane Substances 0.000 claims abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 8
- 229920002545 silicone oil Polymers 0.000 claims description 7
- 239000000440 bentonite Substances 0.000 claims description 6
- 229910000278 bentonite Inorganic materials 0.000 claims description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 6
- 239000010445 mica Substances 0.000 claims description 6
- 229910052618 mica group Inorganic materials 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000005543 nano-size silicon particle Substances 0.000 claims description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 5
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 239000003963 antioxidant agent Substances 0.000 claims description 3
- 230000003078 antioxidant effect Effects 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 3
- 229920002401 polyacrylamide Polymers 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- -1 polysiloxanes Polymers 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 2
- 239000013522 chelant Substances 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 239000003973 paint Substances 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 4
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- 238000010276 construction Methods 0.000 abstract description 3
- 238000005034 decoration Methods 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 230000006641 stabilisation Effects 0.000 abstract description 2
- 238000011105 stabilization Methods 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention relates to paint field more particularly to a kind of preparation methods of rubber high wear resistance coatings, include the following steps：（1）Acrylic acid modified polyurethane, water-compatible amino resin, water-based fluorocarbon resin, antifoaming agent, wetting agent, antirust agent and deionized water are added sequentially in stirred tank, stir 20 ~ 30min；（2）Auxiliary agent, aqueous drier are sequentially added, is dispersed with stirring 30 ~ 40 min；（3）Levelling agent is added in, is dispersed with stirring 10 ~ 20min；（4）Water-based thickener is added in, adjusts viscosity, stirs 20 ~ 30min.The present invention has many advantages, such as excellent protected decoration effect, excellent rust-preventing characteristic and water resistance, resistance to ag(e)ing, flexibility, performance stabilization, strong adhesive force；Preparation method of the present invention is simple, environment friendly convenient is compared in safe, free from environmental pollution, construction, safe and nontoxic, will not damage to human body using water as medium.
Description
Technical field
The present invention relates to paint field more particularly to a kind of preparation methods of rubber high wear resistance coatings.
Background technology
As coatings industry and coating process develop to low stainization, water paint increasingly rises.Water paint subtracts
Organic solvent is lacked to be endangered caused by environment with polluting, has ensured the health of operating personnel, reduced the production of coating
Cost takes safety measures and is transported convenient for factory, while is convenient for the cleaning of tool again.Safe and environment-friendly, nuisanceless, volatility
Organic matter (VOC) discharges few green environmental friendly coatings, has very much the necessity developed, before also having a wide range of applications
Scape.It is every with water as solvent or to make the coating of decentralized medium, it all can be described as water paint.Water paint is situated between using water as dispersion
Matter, only with a small amount of hypotoxicity alcohol ethers organic solvent, safety and environmental protection economizes on resources, and eliminates the danger that fire occurs during construction
It is dangerous, advantageously reduce atmosphere pollution.Water paint is very good to material surface adaptability, can equally be applied in wet environment
Work, coating adhesion are strong.
Although rubber has preferable wear-resisting property, during use also can by a large amount of external force and
Friction, coating is needed to be protected, but its face coat not only will have soft elastic effect, will also can weight, friction,
Under the effect of the external force such as wiping stroke, the coating on surface is locally not easy to be scratched, destroys, is ageing-resistant.
Invention content
In order to solve the above technical problems, the object of the present invention is to provide a kind of preparation sides of rubber high wear resistance coatings
Method.
The present invention adopts the following technical scheme that：
A kind of preparation method of rubber high wear resistance coatings, it is characterised in that include the following steps：
（1）By acrylic acid modified polyurethane, water-compatible amino resin, water-based fluorocarbon resin, antifoaming agent, wetting agent, antirust agent
And deionized water is added sequentially in stirred tank, under 800~1000r/min speed conditions, stirs 20~30min；
（2）Auxiliary agent, aqueous drier are sequentially added, under 1000~1200r/min speed conditions, it is dispersed with stirring 30~
40min；
（3）Levelling agent is added in, under 1000~1200r/min speed conditions, is dispersed with stirring 10~20min；
（4）Water-based thickener is added in, adjusts viscosity, under 800~1000r/min speed conditions, 20~30min of stirring is
It can；
Wherein, each component composition parts by weight are calculated as：
16-20 parts of acrylic acid modified polyurethane, 15-20 parts of water-compatible amino resin, 10-15 parts of water-based fluorocarbon resin, defoaming
0.3-0.5 parts of agent, drier 0.5-1 parts aqueous, 0.5-1.5 parts of water-based thickener, 0.5-1.5 parts of antirust agent, levelling agent 0.1-0
.5 part, 0.1-0.5 parts of wetting agent, 18-22 parts of auxiliary agent, deionized water surplus；
The auxiliary agent is made of following raw materials in part by weight：2 parts of bentonite, 3 parts of mica, 5 parts of nano silicon dioxide, stearic acid
5 parts of zinc, 0.5 part of antioxidant 1010,60 parts of hydrophilic silicone oil, 20 parts of natural emulsion, deionized water surplus.
Wherein hydrophilic silicone oil is selected from the Goon1260 of Dongguan Jiahong Silicone Technology Co., Ltd..
Wherein natural emulsion is three tree natural emulsions of Thailand.
Specifically, the preparation method of the auxiliary agent is：By bentonite, mica, nano silicon dioxide, zinc stearate, antioxygen
Agent 1010 is mixed to join in deionized water, and stirring and dissolving at being 60-80 DEG C in temperature adds in natural emulsion and hydrophilic silicone oil,
Continue to stir 1-2h to get auxiliary agent.
Specifically, the water-based thickener for carboxymethyl cellulose acid sodium and polyacrylamide in mass ratio（1-3）：（1-
2）Composition.
Specifically, polysiloxanes of the antifoaming agent for modification, model：FY-BW500.
Specifically, levelling agent be fluorin modified crylic acid ester levelling agent, model：A-1377.
Specifically, wetting agent is hyperbranched polyether, model：W-225.
Specifically, aqueous drier be aqueous composite drier, model：YS-01.
Specifically, antirust agent is metallo-chelate, model：SHYT5179.
The device have the advantages that：
（1）The present invention has excellent protected decoration effect, excellent rust-preventing characteristic and water resistance, performance stabilization, adhesive force
The advantages that strong.
（2）The resin that the present invention uses has preferable synergistic effect, can increase adhesive force of the coating to base material, improves
Processability.
（3）The auxiliary agent that the present invention uses can further improve the resistance to ag(e)ing, weatherability and anti-friction of coating,
With preferable flexibility.
（4）Preparation method of the present invention is simple, environment friendly convenient is compared in safe, free from environmental pollution, construction, using water as medium, peace
Entirely, it is nontoxic, will not damage to human body.
Specific embodiment
Presently in connection with embodiment, the present invention is described in further detail.
Embodiment 1
A kind of preparation method of rubber high wear resistance coatings, it is characterised in that include the following steps：
（1）By acrylic acid modified polyurethane, water-compatible amino resin, water-based fluorocarbon resin, antifoaming agent, wetting agent, antirust agent
And deionized water is added sequentially in stirred tank, under 800~1000r/min speed conditions, stirs 20~30min；
（2）Auxiliary agent, aqueous drier are sequentially added, under 1000~1200r/min speed conditions, it is dispersed with stirring 30~
40min；
（3）Levelling agent is added in, under 1000~1200r/min speed conditions, is dispersed with stirring 10~20min；
（4）Water-based thickener is added in, adjusts viscosity, under 800~1000r/min speed conditions, 20~30min of stirring is
It can；
Wherein, each component composition parts by weight are calculated as：
16 parts of acrylic acid modified polyurethane, 15 parts of water-compatible amino resin, 10 parts of water-based fluorocarbon resin, 0.3 part of antifoaming agent, type
Number：0.5 part of FY-BW500, aqueous drier, model：YS-01, carboxymethyl cellulose acid sodium and polyacrylamide in mass ratio 1：1
0.5 part of 0.5 part of water-based thickener, the antirust agent of composition, model：0.1 part of SHYT5179, levelling agent, model：A-1377, wetting
0.1 part of agent, model：W-225,18 parts of auxiliary agent, deionized water surplus；
Auxiliary agent is made of following raw materials in part by weight：2 parts of bentonite, 3 parts of mica, 5 parts of nano silicon dioxide, zinc stearate 5
Part, 0.5 part of antioxidant 1010,60 parts of hydrophilic silicone oil, 20 parts of natural emulsion, deionized water surplus.
Wherein, the preparation method of auxiliary agent is：By bentonite, mica, nano silicon dioxide, zinc stearate, antioxidant 1010
It is mixed to join in deionized water, stirring and dissolving at being 60-80 DEG C in temperature adds in natural emulsion and hydrophilic silicone oil, continues to stir
1-2h is mixed to get auxiliary agent.
Embodiment 2-5 is substantially the same manner as Example 1, difference such as table 1.
Table 1
By film performance such as table 2 obtained by above-mentioned formula
Table 2
Using above-mentioned desirable embodiment according to the present invention as enlightenment, by above-mentioned description, relevant staff is complete
Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.The technology of this invention
Property range is not limited to the content on specification, it is necessary to determine its technical scope according to right.
Claims (8)
1. a kind of preparation method of rubber high wear resistance coatings, it is characterised in that include the following steps：
（1）By acrylic acid modified polyurethane, water-compatible amino resin, water-based fluorocarbon resin, antifoaming agent, wetting agent, antirust agent and go
Ionized water is added sequentially in stirred tank, under 800 ~ 1000r/min speed conditions, stirs 20 ~ 30min；
（2）Auxiliary agent, aqueous drier are sequentially added, under 1000 ~ 1200r/min speed conditions, it is dispersed with stirring 30 ~
40 min；
（3）Levelling agent is added in, under 1000 ~ 1200r/min speed conditions, is dispersed with stirring 10 ~ 20min；
（4）Water-based thickener is added in, adjusts viscosity, under 800 ~ 1000r/min speed conditions, 20 ~ 30min of stirring is
It can；
Wherein, each component composition parts by weight are calculated as：
16-20 parts of acrylic acid modified polyurethane, 15-20 parts of water-compatible amino resin, 10-15 parts of water-based fluorocarbon resin, antifoaming agent
0.3-0.5 parts, drier 0.5-1 parts aqueous, 0.5-1.5 parts of water-based thickener, 0.5-1.5 parts of antirust agent, levelling agent 0.1-0.5
Part, 0.1-0.5 parts of wetting agent, 18-22 parts of auxiliary agent, deionized water surplus；
The auxiliary agent is made of following raw materials in part by weight：2 parts of bentonite, 3 parts of mica, 5 parts of nano silicon dioxide, zinc stearate 5
Part, 0.5 part of antioxidant 1010,60 parts of hydrophilic silicone oil, 20 parts of natural emulsion, deionized water surplus.
2. a kind of preparation method of rubber high wear resistance coatings as described in claim 1, it is characterised in that：The auxiliary agent
Preparation method be：Bentonite, mica, nano silicon dioxide, zinc stearate, antioxidant 1010 are mixed to join deionized water
In, stirring and dissolving at being 60-80 DEG C in temperature adds in natural emulsion and hydrophilic silicone oil, continues to stir 1-2h to get auxiliary agent.
3. a kind of preparation method of rubber high wear resistance coatings as described in claim 1, it is characterised in that：It is described aqueous
Thickener for carboxymethyl cellulose acid sodium and polyacrylamide in mass ratio（1-3）：（1-2）Composition.
4. a kind of preparation method of rubber high wear resistance coatings as described in claim 1, it is characterised in that：The defoaming
Agent is modified polysiloxanes.
5. a kind of preparation method of rubber high wear resistance coatings as described in claim 1, it is characterised in that：The levelling
Agent is fluorin modified crylic acid ester levelling agent.
6. a kind of preparation method of rubber high wear resistance coatings as described in claim 1, it is characterised in that：The wetting
Agent is hyperbranched polyether.
7. a kind of preparation method of rubber high wear resistance coatings as described in claim 1, it is characterised in that：It is described aqueous
Drier is aqueous composite drier.
8. a kind of preparation method of rubber high wear resistance coatings as described in claim 1, it is characterised in that：The antirust
Agent is metallo-chelate.
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| CN106366835A (en) * | 2016-08-29 | 2017-02-01 | 扬州纽特游艺器材有限公司 | Coating with high antibacterial property for surfaces of sports equipment |
| CN106700754A (en) * | 2016-12-08 | 2017-05-24 | 滁州思达机电有限责任公司 | Isolating paint for inner wall of outer housing of high-performance electric meter box |
| CN107163827B (en) * | 2017-06-29 | 2019-03-19 | 苏州安特实业有限公司 | A kind of preparation method of the aqueous polyurethane wear-resistant paint modified based on nanometer sheet zeolite powder |
| CN109303365A (en) * | 2018-09-23 | 2019-02-05 | 南通嘉得利安全用品有限公司 | Method for reinforcing dipped gloves tiger's jaw |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4945123A (en) * | 1988-02-02 | 1990-07-31 | Kinugawa Rubber Industrial Co., Ltd. | Coating composition for treating surface of high molecular elastic material |
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| CN103756539A (en) * | 2013-12-30 | 2014-04-30 | 苏州市邦成电子科技有限公司 | Wear-resistant paint for rubber |
| CN104987818A (en) * | 2015-06-01 | 2015-10-21 | 广东华兹卜化学工业有限公司 | A kind of water-based wood paint with high hardness and high abrasion resistance and preparation method thereof |
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2016
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| US4945123A (en) * | 1988-02-02 | 1990-07-31 | Kinugawa Rubber Industrial Co., Ltd. | Coating composition for treating surface of high molecular elastic material |
| CN101153139A (en) * | 2007-09-03 | 2008-04-02 | 东莞市贝特利新材料有限公司 | High-wear-resistance PU (polyurethane) ink for silicon rubber surface |
| CN102533083A (en) * | 2012-01-12 | 2012-07-04 | 上海集宝材料科技有限公司 | Aqueous polyurethane slot wear-resisting paint as well as preparation and application thereof |
| CN103756539A (en) * | 2013-12-30 | 2014-04-30 | 苏州市邦成电子科技有限公司 | Wear-resistant paint for rubber |
| CN104987818A (en) * | 2015-06-01 | 2015-10-21 | 广东华兹卜化学工业有限公司 | A kind of water-based wood paint with high hardness and high abrasion resistance and preparation method thereof |
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| CN105838237A (en) | 2016-08-10 |
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Denomination of invention: A preparation method of high wear-resistant coating for rubber products Effective date of registration: 20230130 Granted publication date: 20180619 Pledgee: Yizheng Sub branch of Postal Savings Bank of China Co.,Ltd. Pledgor: YANGZHOU DONGXING RUBBER Co.,Ltd. Registration number: Y2023980031648 |
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