CN105821350A - Alloy material used for marine drilling platform high-pressure mud discharging system and preparing method thereof - Google Patents
Alloy material used for marine drilling platform high-pressure mud discharging system and preparing method thereof Download PDFInfo
- Publication number
- CN105821350A CN105821350A CN201610442812.0A CN201610442812A CN105821350A CN 105821350 A CN105821350 A CN 105821350A CN 201610442812 A CN201610442812 A CN 201610442812A CN 105821350 A CN105821350 A CN 105821350A
- Authority
- CN
- China
- Prior art keywords
- alloy material
- drilling platform
- marine drilling
- temperature
- platform high
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000956 alloy Substances 0.000 title claims abstract description 62
- 238000005553 drilling Methods 0.000 title claims abstract description 44
- 238000000034 method Methods 0.000 title abstract description 8
- 238000007599 discharging Methods 0.000 title abstract description 4
- 239000000463 material Substances 0.000 claims abstract description 33
- 239000010949 copper Substances 0.000 claims abstract description 26
- 229910052802 copper Inorganic materials 0.000 claims abstract description 24
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 19
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 19
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 18
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 18
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 17
- 229910052733 gallium Inorganic materials 0.000 claims abstract description 17
- 229910052732 germanium Inorganic materials 0.000 claims abstract description 17
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 17
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 17
- 229910052718 tin Inorganic materials 0.000 claims abstract description 16
- 229910052692 Dysprosium Inorganic materials 0.000 claims abstract description 15
- 239000000126 substance Substances 0.000 claims abstract description 15
- 229910052693 Europium Inorganic materials 0.000 claims abstract description 13
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000000137 annealing Methods 0.000 claims abstract description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052742 iron Inorganic materials 0.000 claims abstract description 7
- 229910052751 metal Inorganic materials 0.000 claims abstract description 7
- 239000002184 metal Substances 0.000 claims abstract description 7
- 238000005496 tempering Methods 0.000 claims abstract description 5
- 238000001816 cooling Methods 0.000 claims abstract description 4
- 239000002002 slurry Substances 0.000 claims description 36
- 238000002844 melting Methods 0.000 claims description 12
- 230000008018 melting Effects 0.000 claims description 12
- 229910052749 magnesium Inorganic materials 0.000 claims description 10
- 238000005245 sintering Methods 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 9
- 229910052750 molybdenum Inorganic materials 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- 229910052743 krypton Inorganic materials 0.000 claims description 4
- DNNSSWSSYDEUBZ-UHFFFAOYSA-N krypton atom Chemical compound [Kr] DNNSSWSSYDEUBZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052724 xenon Inorganic materials 0.000 claims description 4
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052756 noble gas Inorganic materials 0.000 claims description 2
- 238000003723 Smelting Methods 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- 229910045601 alloy Inorganic materials 0.000 description 22
- 229910000831 Steel Inorganic materials 0.000 description 21
- 239000010959 steel Substances 0.000 description 21
- 239000011701 zinc Substances 0.000 description 16
- 239000011651 chromium Substances 0.000 description 15
- 238000005260 corrosion Methods 0.000 description 15
- 230000007797 corrosion Effects 0.000 description 14
- 239000011777 magnesium Substances 0.000 description 10
- 238000009413 insulation Methods 0.000 description 8
- 239000003921 oil Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 6
- 238000005266 casting Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 4
- 229910052761 rare earth metal Inorganic materials 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 238000005336 cracking Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 150000002910 rare earth metals Chemical class 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 238000001238 wet grinding Methods 0.000 description 2
- 229910000859 α-Fe Inorganic materials 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- 229910000676 Si alloy Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 241001062472 Stokellia anisodon Species 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000003026 anti-oxygenic effect Effects 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000005347 demagnetization Effects 0.000 description 1
- 238000004512 die casting Methods 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000004781 supercooling Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/26—Methods of annealing
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/04—Making ferrous alloys by melting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/008—Ferrous alloys, e.g. steel alloys containing tin
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/16—Ferrous alloys, e.g. steel alloys containing copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Earth Drilling (AREA)
Abstract
The invention provides an alloy material used for a marine drilling platform high-pressure mud discharging system and a preparing method thereof. The alloy material comprises C, Mn, S, P, Cu, Ga, Mg, Mo, Ge, Sn, Si, Cr, Sb, Zn, Eu and Dy, and the balance Fe; Fe, Mn, Cu, Ga, Mg, Mo, Ge, Sn, Cr, Sb, Zn and RE elementary substances to be smelted are added into a vacuum chamber of a water cooling copper crucible according to the material component ratio, the vacuum chamber is vacuumized, and the elementary substances are smelted at the temperature of 960-980 DEG C; C, S, P and Si are added under the metal smelting condition, heat is preserved, and the mixture is stirred uniformly; under the inert gas pressurization condition, the product is cooled to 630 DEG C for tempering and heated to 950 DEG C for annealing, heat is preserved, and finally the temperature is reduced to the room temperature to obtain the alloy material used for the marine drilling platform high-pressure mud discharging system. The prepared product is good in rust prevention and pressure resistance and not prone to deformation.
Description
Technical field
The invention belongs to ferrous alloy field, be specifically related to a kind of marine drilling platform high-pressure slurry and discharge system alloy material and preparation method thereof.
Background technology
The increase invested deep-sea exploration and development along with the most each major oil companies, there is the situation that supply falls short of demand in deep water platform, and sign-on rate is at a relatively high, stable more than 95%, day takes price and the most significantly rises.The deep water platform of the most newly-built 3/4 i.e. signs service contract with operator before dispatching from the factory.Along with the newfound increase of deep-sea oil gas and the deepwater field having been found that put into exploitation, deep sea drilling platform will be wellr sold and in short supply.Along with the progressively recovery of global economy, the demand of oil gas is continuously increased by the whole world, and oil price is gradually gone up, and marine Oil Gas Investment and exploration and development will be more active, and the drilling platforms demand peak of a new round will be staged a comeback.If oil price is always maintained at high-order level, and keeping certain marine oil and gas discovery rate, the demand of marine drilling platform is expected to go back up to a high level of comparison.The drilling platforms being suitable for the adverse circumstances such as deep water, ultra-deep-water and polar region will be a major trend of following marine drilling platform market development.
The high-pressure slurry of marine drilling platform is discharged system and is played very important effect in drilling process.The discharge pressure of the slush pump that high-pressure slurry discharges system is the highest, high-pressure slurry starts walking pipeline from the outlet of slush pump, the pressure of high-pressure slurry is very big, in order to overcome mud gravity during travelling, and friction loss and take back the cutting that drill bit scales off.Similarly, due to the characteristic of of reciprocating pump itself, fluctuating to reduce its discharge pressure, outlet has air chamber.Therefore, the material of high-pressure slurry discharge system is particularly significant for marine drilling platform；But, marine drilling platform this still in the most perfect technology, the material of marine drilling platform high-pressure slurry discharge system is in a great extent to be groped and continuous experimental stage, how to select and manufacture good high-pressure slurry antirust, pressure, on-deformable to discharge system material, be when previous urgent problem.
Summary of the invention
In order to overcome above-mentioned deficiency, it is an object of the invention to provide a kind of marine drilling platform high-pressure slurry and discharge system alloy material and preparation method thereof, consider the cost of each composition, optimize the ratio between each composition, find the material prescription that cost performance is the highest, add rare earth metal, it is possible to efficiently solve the problems referred to above.
In order to solve above-mentioned technical problem, the present invention takes following technical scheme:
nullA kind of marine drilling platform high-pressure slurry discharges system alloy material，The material composition of alloy material and mass percent thereof be: C:0.10% ~ 0.25%，Mn:0.50% ~ 0.80%，S:0.03% ~ 0.04%，P:0.03% ~ 0.04%，Cu:0.60% ~ 1.50%，Ga:0.60% ~ 1.50%，Mg:1.30% ~ 1.70%，Mo:0.45% ~ 0.65%，Ge:0.60% ~ 1.50%，Sn:0.30% ~ 0.40%，Si:0.60% ~ 1.50%，Cr:1.0% ~ 1.15%，Sb:0.60% ~ 1.50%，Zn:1.90% ~ 2.20%，RE:0.20% ~ 0.90%，Remaining is Fe.
Further, RE includes, Eu:0.10% ~ 0.45%, Dy:0.10% ~ 0.45%.
Further, material composition and mass percent thereof are: C:0.20%, Mn:0.58%, S:0.04%, P:0.03%, Cu:0.65%, Ga:0.65%, Mg:1.36%, Mo:0.46%, Ge:0.65%, Sn:0.34%, Si:0.65%, Cr:1.10%, Sb:0.65%, Zn:1.92%, Eu:0.25%, Dy:0.25%, remaining is Fe.
Hereinafter, the restriction reason being grouped into the one-tenth of the alloy of employing in the present invention illustrates, and becomes the % related in being grouped into refer to quality %.
C:0.10% ~ 0.25%, C can form solid solution tissue in steel, improve the intensity of steel；Formation carbide tissue, can improve hardness and the wearability of steel.Therefore, C is in steel, and phosphorus content is the highest, and the intensity of steel, hardness are the highest, but plasticity, toughness also can decrease；Otherwise, phosphorus content is the lowest, and the plasticity of steel, toughness are the highest, its intensity, hardness also can decrease, for adapting to ocean condition and job requirements effect, marine drilling platform high-pressure slurry is discharged C content in system material and is defined as 0.10% ~ 0.25% by the present invention, and preferably 0.20%.
Mn:0.50% ~ 0.80%, Mn is interpolation Mn in a kind of weak alloy deoxidizer, is not only advantageous to the corrosion stability of alloy, and the intensity of alloy can also be made to improve, and can reduce hot cracking tendency, improve corrosion resistance and the welding performance of alloy.Along with Mn content increases, alloy strength increases, and discharges the concrete actual specific demand of system for adapting to marine drilling platform high-pressure slurry, and Mn content is defined as 0.50% ~ 0.80% by the present invention, and preferably 0.58%.
P:0.03% ~ 0.04%, P can improve intensity, but seriously reduce plasticity, impact flexibility, cold-bending property and solderability, especially occurring cold short during low temperature, content need to strictly control, and is usually no more than 0.050%, less than 0.045% in Welding Structure, in view of the concrete reality of navigation operation, P content is defined as 0.03% ~ 0.04% by the present invention, and preferably 0.03%.
S:0.03% ~ 0.04%, S can cause alloy hot-short, drop low-alloyed plasticity, impact flexibility, fatigue strength etc., and a certain amount of S Yu Mn forms MnS in steel, is favorably improved the element of machinability.When less than 0.001%, additive effect is insufficient, saturated more than 0.15% additive effect, makes foundry goods produce pore, be difficult to cutting and reduce its toughness, therefore S is defined as 0.03% ~ 0.04%, and preferably 0.04%.
Cu:0.60% ~ 1.50%, copper can improve intensity and the toughness of steel alloy, particularly atmospheric corrosion performance.For adapting to ocean condition and the specific demand of marine drilling platform high-pressure slurry discharge system, Cu content in material is defined as 0.60% ~ 1.50% by the present invention, and preferably 0.65%.
Ga:0.60% ~ 1.50%, Ga plays good deoxidation in steel-making, adds a small amount of Ga in steel, can refine the crystal grain of steel, improves the intensity of steel, improves impact flexibility, improves the antioxygenic property of steel, improves the rustless steel anti-corrosion capability to strong oxidizing property acids.Al also has non-oxidizability and corrosion resistance, and Ga share with chromium, silicon, is remarkably improved high temperature non-scale performance and the ability of high-temperature corrosion resistance of steel.For adapting to nautical climate condition and job requirements effect, Ga content is defined as 0.60% ~ 1.50% by the present invention, and preferably 0.65%.
Mg:1.30% ~ 1.70%, adds a small amount of magnesium in the alloy, can improve intensity and yield limit, improves the machinability of alloy.Alloy containing magnesium has excellent corrosion resistance.For adapting to ocean condition and the specific demand of marine drilling platform high-pressure slurry discharge system, Mg content in alloy material is defined as 1.30% ~ 1.70% by the present invention, and preferably 1.36%.
Mo:0.45% ~ 0.65%, the Mo energy reinforced ferrite of low content, improves intensity and the hardness of steel；Reduce the critical cooling rate of steel, improve the quenching degree of steel；Improving thermostability and the elevated temperature strength of steel, discharge the concrete actual specific demand of system for adapting to marine drilling platform high-pressure slurry, Mo content in material is defined as 0.45% ~ 0.65% by the present invention, and preferably 0.46%.
Ge:0.60% ~ 1.50%, germanium stable chemical nature, under room temperature not with air or water vapor acting, can reinforced ferrite, improve thermostability and corrosion resistance, reduce toughness and plasticity；Fusing point can be reduced in the alloy, improve mobility.For adapting to ocean condition and the specific demand of marine drilling platform high-pressure slurry discharge system, Ge content is defined as 0.60% ~ 1.50% by the present invention, and preferably 0.65%.
Sn:0.30% ~ 0.40%, adds a certain amount of stannum in steel, the resistance to corrosion of meeting raising steel in various degree and wearability.For adapting to ocean condition and the specific demand of marine drilling platform high-pressure slurry discharge system, Sn content in alloy material is defined as 0.30% ~ 0.40% by the present invention, and preferably 0.34%.
Si:0.60% ~ 1.50%, silicon is the essential element of most of diecasting alloys.It can improve the casting character of alloy.Silicon alloy has fabulous casting character and corrosion stability, can carry heavy alloyed high temperature formative nature, reduces shrinkage factor, without hot cracking tendency.For adapting to ocean condition and the specific demand of marine drilling platform high-pressure slurry discharge system, Si content in material is defined as 0.60% ~ 1.50% by the present invention, and preferably 0.65%.
Cr:1.0% ~ 1.15%, chromium can form intermetallic compound in aluminum, hinders forming core and the growth process of recrystallization, has certain invigoration effect to alloy, moreover it is possible to improves alloy ductility and reduces stress corrosion opening cracking maleate sensitivity.But meeting-place increases quenching sensitive, and making anode oxide film is yellow, and Cr content in alloy material is defined as 1.0% ~ 1.15% by the present invention, preferably 1.10%.
Sb:0.60% ~ 1.50%, adds a certain amount of antimony in steel, the resistance to corrosion of meeting raising steel in various degree and wearability.For adapting to ocean condition and the specific demand of marine drilling platform high-pressure slurry discharge system, Sb content in alloy material is defined as 0.60% ~ 1.50% by the present invention, and preferably 0.65%.
Zn:1.90% ~ 2.20%, Zn can improve mobility in the alloy, increases red brittleness, reduces corrosion resistance, therefore should control the content of zinc in prescribed limit.The alloy that zinc content is the highest but has preferable casting character and mechanical performance, machining is relatively good, for adapting to ocean condition and the specific demand of marine drilling platform high-pressure slurry discharge system, Zn content in alloy material is defined as 1.90% ~ 2.20% by the present invention, and preferably 1.92%.
RE:0.20% ~ 0.90%, rare earth element adds in alloy, it is possible to increase the mechanical strength of alloy material and corrosion resistance, increase constitutional supercooling, crystal grain thinning when making alloy casting, reduce secondary intergranular away from, reduce the gas in alloy and be mingled with, and making constituent phases tend to nodularization.Also can reduce smelt surface tension, increase mobility, beneficially casting ingot-forming, processing performance is had a significant impact；Rare earth metal can also eliminate the hydrological environment of magnetic field and complexity and marine drilling platform high-pressure slurry is discharged the harmful effect of system, thus improves the service life of marine drilling platform；Simultaneously under conditions of load is identical, hence it is evident that alleviate structural member weight.For adapting to ocean condition and the specific demand of marine drilling platform high-pressure slurry discharge system, RE content in material is defined as 0.20% ~ 0.90% by the present invention, including Eu:0.10% ~ 0.45%, Dy:0.10% ~ 0.45%, preferably Eu:0.25%, Dy:0.25%.The rare earth metal content used in the present invention is less, but can play good demagnetization and increase the strength of materials, the effect of wearability, advantageously reduces cost.
Another object of the present invention, is the preparation method providing a kind of marine drilling platform high-pressure slurry to discharge system alloy material, and making step is as follows:
Step, will treat that Fe, Mn, Cu, Ga, Mg, Mo, Ge, Sn, Cr, Sb, Zn, RE simple substance of melting, according to material composition ratio, adds in the vacuum chamber of water jacketed copper crucible, evacuation, melted under the conditions of sintering temperature is 960 DEG C ~ 980 DEG C；
Step, under conditions of metal melting, add C, S, P, Si simple substance according to material composition ratio, and be incubated 35min ~ 50min, stir；
Step, at noble gas pressurized conditions borehole cooling to 630 DEG C of tempering, it is incubated 35min ~ 50min, then is warming up to 950 DEG C of annealing, be incubated 35min ~ 50min, be finally cooled to room temperature, obtain marine drilling platform high-pressure slurry and discharge system alloy material finished product.
Further, stepIn, when the temperature of sintering is 960 DEG C ~ 970 DEG C, RE consists of Eu.
Further, stepIn, when the temperature of sintering is 970 DEG C ~ 980 DEG C, RE consists of Eu and Dy.
Further, stepParticularly as follows:
A, under Krypton or xenon atmosphere, under the pressurized conditions that pressure is 35MPa ~ 50MPa, be cooled to 630 DEG C of tempering with the speed of 35 DEG C/min ~ 50 DEG C/min, be incubated 15min ~ 40min；
B, again with the ramp of 35 DEG C/min ~ 50 DEG C/min to 950 DEG C of annealing, be incubated 15min ~ 40min；
C, finally it is cooled to room temperature, obtains marine drilling platform compressed air system alloy material finished product.
The invention have the advantage that
Marine drilling platform high-pressure slurry provided by the present invention discharges system alloy material finished product, and the material of preparation has good performance antirust, pressure, on-deformable.
Detailed description of the invention
The specific embodiment of the present invention given below, is used for being described in further detail the present invention.
Embodiment 1
Raw material components:
C:0.20%, Mn:0.58%, S:0.04%, P:0.03%, Cu:0.65%, Ga:0.65%, Mg:1.36%, Mo:0.46%, Ge:0.65%, Sn:0.34%, Si:0.65%, Cr:1.10%, Sb:0.65%, Zn:1.92%, Eu:0.25%, Dy:0.25%, remaining is Fe.
It is prepared via a method which:
Step, will treat that Fe, Mn, Cu, Ga, Mg, Mo, Ge, Sn, Cr, Sb, Zn, Eu, Dy simple substance of melting, according to material composition ratio, adds in the vacuum chamber of water jacketed copper crucible, evacuation, melted under the conditions of sintering temperature is 975 DEG C；
Step, under conditions of metal melting, add C, P, S, Si simple substance according to material composition ratio, stir, and be incubated 36min；
StepUnder the conditions of Krypton pressurization 47MPa, it is cooled to 630 DEG C with the rate of temperature fall of 44 DEG C/min, insulation 36min, it is warming up to 950 DEG C of insulation 36min annealing with the heating rate of 44 DEG C/min again, is finally down to room temperature with the rate of temperature fall of 44 DEG C/min and obtains marine drilling platform high-pressure slurry discharge system alloy material finished product.
Embodiment 2
Raw material components:
C:0.10%, Mn:0.50%, S:0.03%, P:0.03%, Cu:0.60%, Ga:0.60%, Mg:1.30%, Mo:0.45%, Ge:0.60%, Sn:0.30%, Si:0.60%, Cr:1.0%, Sb:0.60%, Zn:1.90%, Eu:0.20%, remaining is Fe.
It is prepared via a method which:
Step, will treat that Fe, Mn, Cu, Ga, Mg, Mo, Ge, Sn, Cr, Sb, Zn, Eu simple substance of melting, according to material composition ratio, adds in the vacuum chamber of water jacketed copper crucible, evacuation, melted under the conditions of sintering temperature is 960 DEG C；
Step, under conditions of metal melting, add C, P, S, Si simple substance according to material composition ratio, stir, and be incubated 35min；
StepUnder the conditions of Krypton pressurization 35MPa, it is cooled to 630 DEG C with the rate of temperature fall of 35 DEG C/min, insulation 35min, it is warming up to 950 DEG C of insulation 35min annealing with the heating rate of 35 DEG C/min again, is finally down to room temperature with the rate of temperature fall of 35 DEG C/min and obtains marine drilling platform high-pressure slurry discharge system alloy material finished product.
Embodiment 3
Raw material components:
C:0.25%, Mn:0.80%, S:0.04%, P:0.04%, Cu:1.50%, Ga:1.50%, Mg:1.70%, Mo:0.65%, Ge:1.50%, Sn:0.40%, Si:1.50%, Cr:1.15%, Sb:1.50%, Zn:2.20%, Eu:0.45%, Dy:0.45%, remaining is Fe.
It is prepared via a method which:
Step, will treat that Fe, Mn, Cu, Ga, Mg, Mo, Ge, Sn, Cr, Sb, Zn, Eu, Dy simple substance of melting, according to material composition ratio, adds in the vacuum chamber of water jacketed copper crucible, evacuation, melted under the conditions of sintering temperature is 980 DEG C；
Step, under conditions of metal melting, add C, P, S, Si simple substance according to material composition ratio, stir, and be incubated 50min；
StepUnder the conditions of xenon pressurization 50MPa, it is cooled to 630 DEG C with the rate of temperature fall of 50 DEG C/min, insulation 50min, it is warming up to 950 DEG C of insulation 50min annealing with the heating rate of 50 DEG C/min again, is finally down to room temperature with the rate of temperature fall of 50 DEG C/min and obtains marine drilling platform high-pressure slurry discharge system alloy material finished product.
Embodiment 4
Raw material components:
C:0.18%, Mn:0.65%, S:0.035%, P:0.035%, Cu:1.10%, Ga:1.10%, Mg:1.55%, Mo:0.51%, Ge:1.10%, Sn:0.35%, Si:1.10%, Cr:1.08%, Sb:1.10%, Zn:2.05%, Eu:0.275%, Dy:0.275%, remaining is Fe.
It is prepared via a method which:
Step, will treat that Fe, Mn, Cu, Ga, Mg, Mo, Ge, Sn, Cr, Sb, Zn, Eu, Dy simple substance of melting, according to material composition ratio, adds in the vacuum chamber of water jacketed copper crucible, evacuation, melted under the conditions of sintering temperature is 970 DEG C；
Step, under conditions of metal melting, add C, P, S, Si simple substance according to material composition ratio, stir, and be incubated 43min；
StepUnder the conditions of xenon pressurization 43MPa, it is cooled to 630 DEG C with the rate of temperature fall of 43 DEG C/min, insulation 43min, it is warming up to 950 DEG C of insulation 33min annealing with the heating rate of 43 DEG C/min again, is finally down to room temperature with the rate of temperature fall of 43 DEG C/min and obtains marine drilling platform high-pressure slurry discharge system alloy material finished product.
Experimental example 1
Wear resistence contrast test:
The marine drilling platform high-pressure slurry that the embodiment of the present invention 1 ~ 4 prepares is discharged system alloy material and is done slurry (quartz sand+water) wet grinding test on jetting type erosive-corrosive wear testing machine with ordinary high pressure mud discharge system alloy material, and make the corrosion resistance test of material, performance is shown in Table 1.
Table 1 wear resistence and hardness balance's result of the test
| Material | Anticorrosive multiplying power | The wear-resistant multiplying power of wet grinding | Hardness (HB) |
| Ordinary high pressure mud discharges system material | 1.0 | 1.0 | 140 |
| Embodiment 1 prepares alloy material | 2.75 | 1.79 | 187 |
| Embodiment 2 prepares alloy material | 2.70 | 1.77 | 185 |
| Embodiment 3 prepares alloy material | 2.74 | 1.75 | 183 |
| Embodiment 4 prepares alloy material | 2.75 | 1.76 | 182 |
Experimental example 2
Compared with the marine drilling platform high-pressure slurry discharge system alloy material embodiment of the present invention 1 ~ 4 prepared discharges system material with ordinary high pressure mud, its results of property such as table 2 below.
Table 2 base metal characteristic performance compares
From above-mentioned test example, the properties of alloy material of the present invention is above ordinary high pressure mud and discharges system alloy material, the special material consumption preparing alloy of the present invention is few, and relative cost is low, is more suitable for discharging system alloy material for marine drilling platform high-pressure slurry.
These are only the preferred embodiments of the present invention and experimental example, be not limited to the present invention, for a person skilled in the art, the present invention can have various modifications and variations.All within the spirit and principles in the present invention, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.
Claims (7)
- null1. a marine drilling platform high-pressure slurry discharges system alloy material，It is characterized in that，The material composition of described alloy material and mass percent thereof be: C:0.10% ~ 0.25%，Mn:0.50% ~ 0.80%，S:0.03% ~ 0.04%，P:0.03% ~ 0.04%，Cu:0.60% ~ 1.50%，Ga:0.60% ~ 1.50%，Mg:1.30% ~ 1.70%，Mo:0.45% ~ 0.65%，Ge:0.60% ~ 1.50%，Sn:0.30% ~ 0.40%，Si:0.60% ~ 1.50%，Cr:1.0% ~ 1.15%，Sb:0.60% ~ 1.50%，Zn:1.90% ~ 2.20%，RE:0.20% ~ 0.90%，Remaining is Fe.
- Alloy material the most according to claim 1, it is characterised in that described RE includes, Eu:0.10% ~ 0.45%, Dy:0.10% ~ 0.45%.
- Alloy material the most according to claim 1, it is characterised in that described material composition and mass percent thereof be: C:0.20%, Mn:0.58%, S:0.04%, P:0.03%, Cu:0.65%, Ga:0.65%, Mg:1.36%, Mo:0.46%, Ge:0.65%, Sn:0.34%, Si:0.65%, Cr:1.10%, Sb:0.65%, Zn:1.92%, Eu:0.25%, Dy:0.25%, remaining is Fe.
- 4. the preparation method according to alloy material described in any one of claim 1 ~ 3, it is characterised in that making step is as follows:Step, will treat that Fe, Mn, Cu, Ga, Mg, Mo, Ge, Sn, Cr, Sb, Zn, RE simple substance of melting, according to material composition ratio, adds in the vacuum chamber of water jacketed copper crucible, evacuation, melted under the conditions of sintering temperature is 960 DEG C ~ 980 DEG C；Step, under conditions of metal melting, add C, S, P, Si simple substance according to material composition ratio, and be incubated 35min ~ 50min, stir；Step, at noble gas pressurized conditions borehole cooling to 630 DEG C of tempering, it is incubated 35min ~ 50min, then is warming up to 950 DEG C of annealing, be incubated 35min ~ 50min, be finally cooled to room temperature, obtain marine drilling platform high-pressure slurry and discharge system alloy material finished product.
- Preparation method the most according to claim 4, it is characterised in that stepIn, when the temperature of described sintering is 960 DEG C ~ 970 DEG C, RE consists of Eu.
- Preparation method the most according to claim 4, it is characterised in that stepIn, when the temperature of described sintering is 970 DEG C ~ 980 DEG C, RE consists of Eu and Dy.
- Preparation method the most according to claim 4, it is characterised in that described stepParticularly as follows:A, under Krypton or xenon atmosphere, under the pressurized conditions that pressure is 35MPa ~ 50MPa, be cooled to 630 DEG C of tempering with the speed of 35 DEG C/min ~ 50 DEG C/min, be incubated 15min ~ 40min；B, again with the ramp of 35 DEG C/min ~ 50 DEG C/min to 950 DEG C of annealing, be incubated 15min ~ 40min；C, finally it is cooled to room temperature, obtains marine drilling platform compressed air system alloy material finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610442812.0A CN105821350A (en) | 2016-06-21 | 2016-06-21 | Alloy material used for marine drilling platform high-pressure mud discharging system and preparing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610442812.0A CN105821350A (en) | 2016-06-21 | 2016-06-21 | Alloy material used for marine drilling platform high-pressure mud discharging system and preparing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105821350A true CN105821350A (en) | 2016-08-03 |
Family
ID=56532186
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610442812.0A Pending CN105821350A (en) | 2016-06-21 | 2016-06-21 | Alloy material used for marine drilling platform high-pressure mud discharging system and preparing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105821350A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107916360A (en) * | 2017-11-14 | 2018-04-17 | 郑媛媛 | A kind of production technology of high-strength abrasion-proof safety valve |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101928886A (en) * | 2010-07-15 | 2010-12-29 | 南京钢铁股份有限公司 | Corrosion resistant steel for cargo oil tanks and application thereof |
| CN104011234A (en) * | 2011-12-27 | 2014-08-27 | 杰富意钢铁株式会社 | Hot-rolled steel sheet and process for manufacturing same |
| CN104159680A (en) * | 2012-03-06 | 2014-11-19 | 杰富意钢铁株式会社 | Warm hot press molding method and automobile frame parts |
-
2016
- 2016-06-21 CN CN201610442812.0A patent/CN105821350A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101928886A (en) * | 2010-07-15 | 2010-12-29 | 南京钢铁股份有限公司 | Corrosion resistant steel for cargo oil tanks and application thereof |
| CN104011234A (en) * | 2011-12-27 | 2014-08-27 | 杰富意钢铁株式会社 | Hot-rolled steel sheet and process for manufacturing same |
| CN104159680A (en) * | 2012-03-06 | 2014-11-19 | 杰富意钢铁株式会社 | Warm hot press molding method and automobile frame parts |
Non-Patent Citations (5)
| Title |
|---|
| （美）戴维斯等编著: "《金属手册案头卷 上册 原书第2版》", 31 January 2011, 北京：机械工业出版社 * |
| 朱志强，许玉宇，顾伟主编；王国新，王卫忠，王慧等副主编: "《钢分析化学与物理检测》", 30 June 2013 * |
| 沈宁福等: "《新编金属材料手册》", 28 February 2003, 科学出版社 * |
| 王振东等: "《感应炉冶炼500问》", 31 March 2009, 北京：机械工业出版社 * |
| 轧制技术及连轧自动化国家重点实验室: "《大热输入焊接用钢组织控制技术研究与应用》", 30 September 2014, 北京：冶金工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107916360A (en) * | 2017-11-14 | 2018-04-17 | 郑媛媛 | A kind of production technology of high-strength abrasion-proof safety valve |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6765448B2 (en) | Non-directional silicon steel sheet with high magnetic induction and low iron loss and its manufacturing method | |
| CN102925743B (en) | A kind of unleaded wear-resistant copper alloy | |
| CN104711493B (en) | Nickel-saving type contains rare earth and barium diphase stainless steel alloy material and preparation method thereof | |
| CN103741057B (en) | The high steel plate of resistance to marine environment of a kind of low density and production technique thereof | |
| CN103741056B (en) | A kind of ocean environment of resistance to South Sea production technique of corrosion resistant plate | |
| CN110724872A (en) | High manganese austenitic steel with ultralow-temperature impact toughness and manufacturing method of hot rolled plate thereof | |
| CN103517998A (en) | Heat-resistant austenitic stainless steel having excellent cyclic oxidation resistance | |
| CN105648354A (en) | Alloy material for seawater cooling system of marine drilling platform and manufacturing method of alloy material | |
| CN109338214B (en) | High-strength high-toughness steel for rock drilling tool and production method thereof | |
| CN103484777B (en) | Austenitic manganese steel and preparation method of same | |
| CN106893911A (en) | A kind of high-strength temperature-resistant Al Cu line aluminium alloys and preparation method thereof | |
| KR20240155914A (en) | High strength and high toughness steel with long service life and wall thickness ≥ 600 mm for valve body of submarine Christmas tree, and heat treatment method and manufacturing method thereof | |
| CN110088343A (en) | Austenitic steel and its manufacturing method with excellent surface characteristic | |
| JP4289109B2 (en) | High strength stainless steel pipe for oil well with excellent corrosion resistance | |
| CN105821350A (en) | Alloy material used for marine drilling platform high-pressure mud discharging system and preparing method thereof | |
| CN105671451A (en) | Alloy material for seawater cooling system of marine drilling platform and preparation method of alloy material | |
| CN105821312A (en) | Lining plate for low-carbon and medium-alloy wet ball mill and preparation method thereof | |
| CN110724874A (en) | High-manganese austenitic steel with corrosion and wear resistance and preparation method of hot rolled plate | |
| CN105886905A (en) | Alloy material for compressed air system of marine drilling platform and preparation method of alloy material | |
| CN105821320A (en) | Alloy material for marine drilling platform brine system and preparing method thereof | |
| CN105839023A (en) | Alloy material for marine well drilling platform well drilling water system and preparing method for alloy material | |
| CN106756464A (en) | A kind of preparation method of large size Austria iron body ductile iron abrading-ball | |
| RU2337170C2 (en) | Austenite iron with globular graphite | |
| CN105671409A (en) | Alloy material for bilges system of marine drilling platform and preparation method of alloy material | |
| CN113802061B (en) | 355 MPa-grade carbon steel for prolonging service life of coating and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160803 |