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CN105820464A - Preparation method and application of high-strength plastic bag material composition and plastic bag - Google Patents

Preparation method and application of high-strength plastic bag material composition and plastic bag Download PDF

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Publication number
CN105820464A
CN105820464A CN201610256457.8A CN201610256457A CN105820464A CN 105820464 A CN105820464 A CN 105820464A CN 201610256457 A CN201610256457 A CN 201610256457A CN 105820464 A CN105820464 A CN 105820464A
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China
Prior art keywords
parts
weight
plastic bag
amount
polyvinyl chloride
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Application number
CN201610256457.8A
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Chinese (zh)
Inventor
陈可夏
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Wuhu Pin Tongsu Industry Science And Technology Ltd
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Wuhu Pin Tongsu Industry Science And Technology Ltd
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Priority to CN201610256457.8A priority Critical patent/CN105820464A/en
Publication of CN105820464A publication Critical patent/CN105820464A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/28Shaping by stretching, e.g. drawing through a die; Apparatus therefor of blown tubular films, e.g. by inflation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a preparation method and application of a high-strength plastic bag material composition and a plastic bag. The high-strength plastic bag material composition comprises the following components in parts by weight: 100 parts of polyvinyl chloride, 30-70 parts of polystyrene, 10-50 parts of wood flour, 10-30 parts of asbestos fiber, 1-5 parts of antimonous oxide, 1-5 parts of stannous octoate and 10-20 parts of kaolin. Due to the design, the plastic bag made of the high-strength plastic bag material composition is relatively good in tension strength in practical use, so that the problems that the service life of the plastic bag is shortened and the use cost is increased as the plastic bag can be propped by too many articles when used are solved.

Description

High-strength plastic bag material composition and preparation method and application of plastic bag
Technical Field
The invention relates to the field of production and preparation of plastic bags, in particular to a high-strength plastic bag material composition, a preparation method of a plastic bag and application of the plastic bag material composition.
Background
The plastic bag is as daily necessities commonly used in daily life, its range of application is extensive, and the frequency of use is high, and often in the use, can be because of the more article of actual need splendid attire in the plastic bag to prop the plastic bag open, lead to its volume increase, at this in-process, often can lead to extremely easily propping it bad in the in-service use because of the tensile strength scheduling problem of plastic bag, lead to the unable use, make the article of splendid attire directly drop even, thereby cause the inconvenience in the use.
Therefore, the present invention provides a high strength plastic bag material composition with high tensile strength and greatly improved use performance, and a method for preparing a plastic bag.
Disclosure of Invention
Aiming at the prior art, the invention aims to overcome the problems that in the prior art, a plastic bag is very easy to be broken in the actual use process due to the fact that the plastic bag is expanded because more articles are contained in the plastic bag according to actual needs, cannot be used and even can directly drop contained articles to cause inconvenience in use because the plastic bag is very easy to be broken due to the problems of tensile strength and the like in the process, so that the high-strength plastic bag material composition and the preparation method of the plastic bag have high tensile strength and greatly improve the use performance.
In order to achieve the purpose, the invention provides a high-strength plastic bag material composition, wherein the composition comprises polyvinyl chloride, polystyrene, wood flour, asbestos fibers, antimony trioxide, stannous octoate and kaolin; wherein,
relative to 100 parts by weight of the polyvinyl chloride, the content of the polystyrene is 30-70 parts by weight, the content of the wood powder is 10-50 parts by weight, the content of the asbestos fiber is 10-30 parts by weight, the content of the antimony trioxide is 1-5 parts by weight, the content of the stannous octoate is 1-5 parts by weight, and the content of the kaolin is 10-20 parts by weight.
The invention also provides a preparation method of the high-strength plastic bag, wherein the preparation method comprises the following steps: mixing and granulating polyvinyl chloride, polystyrene, wood powder, asbestos fiber, antimony trioxide, stannous octoate and kaolin, and then blowing a film for molding to prepare a high-strength plastic bag; wherein,
the polyvinyl chloride fiber composite material comprises, by weight, 100 parts of polyvinyl chloride, 30-70 parts of polystyrene, 10-50 parts of wood powder, 10-30 parts of asbestos fiber, 1-5 parts of antimony trioxide, 1-5 parts of stannous octoate and 10-20 parts of kaolin.
The invention also provides application of the high-strength plastic bag prepared by the preparation method.
According to the technical scheme, polyvinyl chloride, polystyrene, wood powder, asbestos fibers, antimony trioxide, stannous octoate and kaolin are mixed and granulated according to a certain proportion, and then film blowing molding is carried out to prepare the plastic bag, so that the plastic bag prepared from the materials has high tensile strength in actual use, and the problems of reduced service life and increased use cost caused by the fact that the plastic bag is damaged by too many articles in the use process are further solved.
Additional features and advantages of the invention will be set forth in the detailed description which follows.
Detailed Description
The following describes in detail specific embodiments of the present invention. It should be understood that the detailed description and specific examples, while indicating the present invention, are given by way of illustration and explanation only, not limitation.
The invention provides a high-strength plastic bag material composition, wherein the composition comprises polyvinyl chloride, polystyrene, wood powder, asbestos fiber, antimony trioxide, stannous octoate and kaolin; wherein,
relative to 100 parts by weight of the polyvinyl chloride, the content of the polystyrene is 30-70 parts by weight, the content of the wood powder is 10-50 parts by weight, the content of the asbestos fiber is 10-30 parts by weight, the content of the antimony trioxide is 1-5 parts by weight, the content of the stannous octoate is 1-5 parts by weight, and the content of the kaolin is 10-20 parts by weight.
According to the design, polyvinyl chloride, polystyrene, wood powder, asbestos fibers, antimony trioxide, stannous octoate and kaolin are mixed according to a certain proportion and granulated and then blown to form a plastic bag, so that the plastic bag made of the materials has high tensile strength in actual use, and the problems that the service life is shortened and the use cost is increased due to the fact that the plastic bag is damaged by too many articles in the use process are further solved.
In a preferred embodiment of the present invention, in order to further improve the tensile properties of the manufactured plastic bag, the polystyrene content is 40 to 60 parts by weight, the wood flour content is 20 to 40 parts by weight, the asbestos fiber content is 15 to 25 parts by weight, the antimony trioxide content is 2 to 4 parts by weight, the stannous octoate content is 2 to 4 parts by weight, and the kaolin content is 13 to 17 parts by weight, relative to 100 parts by weight of the polyvinyl chloride.
The polyvinyl chloride may be of the type conventionally used in the art, and its physical and chemical properties may not be further limited, and of course, in a preferred embodiment of the present invention, the average degree of polymerization of the polyvinyl chloride may be further defined as 650-750.
Likewise, in another preferred embodiment of the present invention, the tensile yield strength of the polystyrene may be further selected to be not less than 30 MPa.
In a more preferred embodiment of the present invention, in order to provide better use performance and processability to the finally obtained plastic bag, and further improve the oxidation resistance and the like, the composition may further comprise a processing aid selected from one or more of an antioxidant, an opening agent, a chain extender and an initiator.
Of course, the type of antioxidant may be one conventionally employed in the art, for example, in a preferred embodiment of the present invention, the antioxidant may be selected to be pentaerythritol tetrakis [ β - (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ] in order to further enhance the use properties.
Likewise, in another preferred embodiment of the present invention, the opening agent may be polyethylene wax and/or oleamide.
The invention also provides a preparation method of the high-strength plastic bag, wherein the preparation method comprises the following steps: mixing and granulating polyvinyl chloride, polystyrene, wood powder, asbestos fiber, antimony trioxide, stannous octoate and kaolin, and then blowing a film for molding to prepare a high-strength plastic bag; wherein,
the polyvinyl chloride fiber composite material comprises, by weight, 100 parts of polyvinyl chloride, 30-70 parts of polystyrene, 10-50 parts of wood powder, 10-30 parts of asbestos fiber, 1-5 parts of antimony trioxide, 1-5 parts of stannous octoate and 10-20 parts of kaolin.
In a preferred embodiment of the present invention, in order to further improve the tensile property of the manufactured plastic bag, the polystyrene is used in an amount of 40 to 60 parts by weight, the wood flour is used in an amount of 20 to 40 parts by weight, the asbestos fiber is used in an amount of 15 to 25 parts by weight, the antimony trioxide is used in an amount of 2 to 4 parts by weight, the stannous octoate is used in an amount of 2 to 4 parts by weight, and the kaolin is used in an amount of 13 to 17 parts by weight, relative to 100 parts by weight of the polyvinyl chloride.
The polyvinyl chloride and the polystyrene are as described above and will not be described in detail herein.
Of course, in another preferred embodiment of the present invention, in order to further improve the use performance and the processing performance of the plastic bag, the preparation method may further include adding a processing aid selected from one or more of an antioxidant, an opening agent, a chain extender and an initiator for mixing. The antioxidant and the opening agent are as described above and will not be described in detail herein.
The invention also provides application of the high-strength plastic bag prepared by the preparation method.
The present invention will be described in detail below by way of examples. In the following examples, the polyvinyl chloride is a commercial product of the brand name S-700 supplied by shanghai napu plastic co ltd, the polystyrene is a commercial product of the brand name 525 supplied by shanghai kaxi plastic chemical co ltd, the antioxidant is an antioxidant of the brand name 1010 supplied by Qingdao asa chemical co ltd (the component is pentaerythrityl tetrakis [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ], the opener is a commercial oleamide of the brand name hmanide supplied by hamamengshi chemical co ltd, the chain extender is a commercial chain extender of the patting new material E-300 supplied by foshan jinggan co ltd, the initiator is a commercial initiator of the brand name UV-819 supplied by huai am bi chemical co ltd, and the wood flour, the antimony fiber, the asbestos trioxide are obtained by the same method as described in shanghai, The stannous octoate and the kaolin are conventional commercial products.
Example 1
100g of polyvinyl chloride, 40g of polystyrene, 20g of wood powder, 15g of asbestos fibers, 2g of antimony trioxide, 2g of stannous octoate, 13g of kaolin, 1g of antioxidant, 1g of opening agent, 0.5g of chain extender and 0.1g of initiator are mixed, granulated and blown to form the high-strength plastic bag A1.
Example 2
100g of polyvinyl chloride, 60g of polystyrene, 40g of wood powder, 25g of asbestos fiber, 4g of antimony trioxide, 4g of stannous octoate, 17g of kaolin, 3g of antioxidant, 3g of opening agent, 2g of chain extender and 1g of initiator are mixed, granulated and blown to form the high-strength plastic bag A2.
Example 3
100g of polyvinyl chloride, 50g of polystyrene, 30g of wood powder, 20g of asbestos fiber, 3g of antimony trioxide, 3g of stannous octoate, 15g of kaolin, 2g of antioxidant, 2g of opening agent, 1g of chain extender and 0.5g of initiator are mixed, granulated and blown to form the high-strength plastic bag A3.
Example 4
The preparation was carried out according to the preparation method of example 1, except that 30g of polystyrene was used, 10g of wood flour was used, 10g of asbestos fiber was used, 1g of antimony trioxide was used, 1g of stannous octoate was used, 10g of kaolin was used, and no antioxidant, opening agent, spreading agent and initiator were added to prepare the high-strength plastic bag a 4.
Example 5
The preparation method is as in example 2, except that the polystyrene is used in an amount of 70g, the wood flour is used in an amount of 50g, the asbestos fiber is used in an amount of 30g, the antimony trioxide is used in an amount of 5g, the stannous octoate is used in an amount of 5g, the kaolin is used in an amount of 20g, and an antioxidant, an opening agent, a spreading agent and an initiator are not added, so that the high-strength plastic bag A5 is prepared.
Comparative example 1
The preparation was carried out according to the preparation method of example 3 except that the polystyrene was used in an amount of 10g, the wood flour was used in an amount of 5g, the asbestos fiber was used in an amount of 5g, the antimony trioxide was used in an amount of 0.5g, the stannous octoate was used in an amount of 0.5g, and the kaolin was used in an amount of 5g, to obtain a plastic bag D1.
Comparative example 2
The preparation was carried out according to the preparation method of example 3 except that the polystyrene was used in an amount of 100g, the wood flour was used in an amount of 80g, the asbestos fiber was used in an amount of 50g, the antimony trioxide was used in an amount of 10g, the stannous octoate was used in an amount of 10g, and the kaolin was used in an amount of 40g, to obtain a plastic bag D2.
Comparative example 3
And (3) granulating pure polyvinyl chloride, and then blowing a film for molding to obtain the plastic bag D3.
Test example
The tensile strength and elongation at break of A1-A5 and D1-D3 prepared above were measured according to GB/T1040.2, respectively, and the results are shown in Table 1.
TABLE 1
Numbering Tensile Strength (MPa) Elongation at Break (%)
A1 56.2 360
A2 52.3 358
A3 51.6 376
A4 32.6 215
A5 33.1 223
D1 13.5 125
D2 15.6 153
D3 12.1 110
The preferred embodiments of the present invention have been described in detail, however, the present invention is not limited to the specific details of the above embodiments, and various simple modifications may be made to the technical solution of the present invention within the technical idea of the present invention, and these simple modifications are within the protective scope of the present invention.
It should be noted that the various technical features described in the above embodiments can be combined in any suitable manner without contradiction, and the invention is not described in any way for the possible combinations in order to avoid unnecessary repetition.
In addition, any combination of the various embodiments of the present invention is also possible, and the same should be considered as the disclosure of the present invention as long as it does not depart from the spirit of the present invention.

Claims (10)

1. A high-strength plastic bag material composition is characterized by comprising polyvinyl chloride, polystyrene, wood powder, asbestos fiber, antimony trioxide, stannous octoate and kaolin; wherein,
relative to 100 parts by weight of the polyvinyl chloride, the content of the polystyrene is 30-70 parts by weight, the content of the wood powder is 10-50 parts by weight, the content of the asbestos fiber is 10-30 parts by weight, the content of the antimony trioxide is 1-5 parts by weight, the content of the stannous octoate is 1-5 parts by weight, and the content of the kaolin is 10-20 parts by weight.
2. The composition as claimed in claim 1, wherein the polystyrene is contained in an amount of 40 to 60 parts by weight, the wood flour is contained in an amount of 20 to 40 parts by weight, the asbestos fiber is contained in an amount of 15 to 25 parts by weight, the antimony trioxide is contained in an amount of 2 to 4 parts by weight, the stannous octoate is contained in an amount of 2 to 4 parts by weight, and the kaolin is contained in an amount of 13 to 17 parts by weight, relative to 100 parts by weight of the polyvinyl chloride.
3. The composition as claimed in claim 1 or 2, wherein the polyvinyl chloride has an average degree of polymerization of 650-750;
the tensile yield strength of the polystyrene is not lower than 30 MPa.
4. The composition of claim 1 or 2, wherein the composition further comprises a processing aid selected from one or more of an antioxidant, a opener, a chain extender, and an initiator.
5. The composition of claim 4, wherein the antioxidant is pentaerythritol tetrakis [ β - (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ];
the opening agent is polyethylene wax and/or oleamide.
6. A preparation method of a high-strength plastic bag is characterized by comprising the following steps: mixing and granulating polyvinyl chloride, polystyrene, wood powder, asbestos fiber, antimony trioxide, stannous octoate and kaolin, and then blowing a film for molding to prepare a high-strength plastic bag; wherein,
the polyvinyl chloride fiber composite material comprises, by weight, 100 parts of polyvinyl chloride, 30-70 parts of polystyrene, 10-50 parts of wood powder, 10-30 parts of asbestos fiber, 1-5 parts of antimony trioxide, 1-5 parts of stannous octoate and 10-20 parts of kaolin.
7. The preparation method according to claim 6, wherein the polystyrene is used in an amount of 40 to 60 parts by weight, the wood flour is used in an amount of 20 to 40 parts by weight, the asbestos fiber is used in an amount of 15 to 25 parts by weight, the antimony trioxide is used in an amount of 2 to 4 parts by weight, the stannous octoate is used in an amount of 2 to 4 parts by weight, and the kaolin is used in an amount of 13 to 17 parts by weight, relative to 100 parts by weight of the polyvinyl chloride.
8. The production method according to claim 6 or 7, wherein the polyvinyl chloride has an average polymerization degree of 650-750;
the tensile yield strength of the polystyrene is not lower than 30 MPa.
9. The preparation method according to claim 6 or 7, wherein the preparation method further comprises adding a processing aid for mixing, wherein the processing aid is selected from one or more of an antioxidant, a mouth-opening agent, a chain extender and an initiator; wherein,
the antioxidant is tetra [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid ] pentaerythritol ester;
the opening agent is polyethylene wax and/or oleamide.
10. Use of a high-strength plastic bag produced by the method according to any one of claims 6 to 9.
CN201610256457.8A 2016-04-25 2016-04-25 Preparation method and application of high-strength plastic bag material composition and plastic bag Pending CN105820464A (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107964189A (en) * 2017-12-14 2018-04-27 全椒县三安塑业有限公司 A kind of preparation method of low smell plastic bag
CN108690361A (en) * 2018-06-21 2018-10-23 上海赫得环境科技股份有限公司 A kind of preparation method of edible polybag

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Publication number Priority date Publication date Assignee Title
CN101484521A (en) * 2006-05-01 2009-07-15 Bnt福思生物降解聚合物有限公司 Novel biodegradable polymer composition useful for the preparation of biodegradable plastic and a process for the preparation of said composition
CN104725739A (en) * 2015-03-14 2015-06-24 芜湖众力部件有限公司 Sunshine-resistant and ageing-resistant modified plastic and preparation method thereof
CN105061947A (en) * 2015-08-17 2015-11-18 苏州凯欧曼新材料科技有限公司 Stretch-resistant and break-resistant composite PVC material and preparation method thereof
CN105086215A (en) * 2015-07-27 2015-11-25 合肥市深朝电子有限公司 Automobile cable insulating material and preparation method thereof
CN105585792A (en) * 2014-10-21 2016-05-18 孙宝林 High-elasticity thin film and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101484521A (en) * 2006-05-01 2009-07-15 Bnt福思生物降解聚合物有限公司 Novel biodegradable polymer composition useful for the preparation of biodegradable plastic and a process for the preparation of said composition
CN105585792A (en) * 2014-10-21 2016-05-18 孙宝林 High-elasticity thin film and preparation method thereof
CN104725739A (en) * 2015-03-14 2015-06-24 芜湖众力部件有限公司 Sunshine-resistant and ageing-resistant modified plastic and preparation method thereof
CN105086215A (en) * 2015-07-27 2015-11-25 合肥市深朝电子有限公司 Automobile cable insulating material and preparation method thereof
CN105061947A (en) * 2015-08-17 2015-11-18 苏州凯欧曼新材料科技有限公司 Stretch-resistant and break-resistant composite PVC material and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107964189A (en) * 2017-12-14 2018-04-27 全椒县三安塑业有限公司 A kind of preparation method of low smell plastic bag
CN108690361A (en) * 2018-06-21 2018-10-23 上海赫得环境科技股份有限公司 A kind of preparation method of edible polybag

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