CN105806667B - A Portable Precipitation Isotope Sampler - Google Patents
A Portable Precipitation Isotope Sampler Download PDFInfo
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- CN105806667B CN105806667B CN201610331108.8A CN201610331108A CN105806667B CN 105806667 B CN105806667 B CN 105806667B CN 201610331108 A CN201610331108 A CN 201610331108A CN 105806667 B CN105806667 B CN 105806667B
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/02—Devices for withdrawing samples
- G01N1/10—Devices for withdrawing samples in the liquid or fluent state
- G01N1/20—Devices for withdrawing samples in the liquid or fluent state for flowing or falling materials
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/02—Devices for withdrawing samples
- G01N1/10—Devices for withdrawing samples in the liquid or fluent state
- G01N1/20—Devices for withdrawing samples in the liquid or fluent state for flowing or falling materials
- G01N2001/2007—Flow conveyors
- G01N2001/2021—Flow conveyors falling under gravity
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Abstract
本发明公开了一种便携式降水同位素采样器,包括降水收集漏斗、拦污网、通气孔、进水口、通气软管、输水导管、储水套管、浮标、出水口和固定支架。其主要特征在于:利用可自行启闭的旋转挡板、长而细的通气软管、覆盖水样液面的圆环浮标这三道技术措施来改善采样器对水样密封性,保持采样器内降水样品最真实的同位素特征,为相关研究提供可靠的降水同位素数据。此外,本发明结构简单,体积小巧,造价低廉,非常适宜在野外大面积推广使用。
The invention discloses a portable precipitation isotope sampler, which comprises a precipitation collecting funnel, a trash net, a ventilation hole, a water inlet, a ventilation hose, a water delivery conduit, a water storage casing, a buoy, a water outlet and a fixed bracket. Its main features are: using three technical measures: a rotating baffle that can be opened and closed by itself, a long and thin ventilation hose, and a ring buoy covering the liquid surface of the water sample to improve the airtightness of the sampler to the water sample and keep the sampler The most authentic isotope characteristics of domestic precipitation samples, providing reliable precipitation isotope data for related research. In addition, the invention has the advantages of simple structure, small size and low cost, and is very suitable for popularization and use in large areas in the wild.
Description
技术领域technical field
本发明涉及一种为研究大气降水同位素而设计的野外便携式降水采样器。The invention relates to a field portable precipitation sampler designed for studying atmospheric precipitation isotopes.
背景技术Background technique
同位素水文学是一门应用同位素理论与方法研究水文学问题的学科。从20世纪50年代末提出至今,同位素水文学作为一门独立的学科已得到长足的发展,其研究及应用领域也不断扩大。如今,同位素水文学理论已广泛应用于水文、水资源、水环境及地质等诸多领域,特别在水汽来源、降雨径流关系、干旱半干旱地区的水资源评价、地下水补给、气候变化和水循环等研究领域中,应用尤为普遍。而作为上述研究领域的背景资料和前提基础,降水同位素数据的获取及准确反映就变得尤为重要。由于降水采样器大多设置在野外且降水时间很难预知,所以,每次降水结束后水样都难以及时密封储存并监测分析。水样长时间地暴露在户外,不仅容易发生水分的蒸发还会与外界水分进行交换,从而导致降水样品的同位素含量失真,不能准确反映降水原始的同位素特征。所以,要想准确反映降水的同位素含量,就必须对降水样品进行精细化采集,降水采样器就必须解决好水样蒸发和与外界水分同位素交换的问题。Isotope hydrology is a subject that applies isotope theory and methods to study hydrological problems. Since it was put forward in the late 1950s, isotope hydrology as an independent subject has been greatly developed, and its research and application fields have also been continuously expanded. Today, the theory of isotope hydrology has been widely used in many fields such as hydrology, water resources, water environment and geology, especially in the research of water vapor source, rainfall-runoff relationship, water resource evaluation in arid and semi-arid areas, groundwater recharge, climate change and water cycle. In the field, the application is particularly common. As the background information and premise basis of the above research fields, the acquisition and accurate reflection of precipitation isotope data become particularly important. Since precipitation samplers are mostly set in the field and the precipitation time is difficult to predict, it is difficult to seal and store water samples in time for monitoring and analysis after each precipitation. Water samples are exposed to the outdoors for a long time, not only prone to water evaporation but also exchange with external water, resulting in distortion of isotope content of precipitation samples, which cannot accurately reflect the original isotope characteristics of precipitation. Therefore, in order to accurately reflect the isotope content of precipitation, it is necessary to finely collect precipitation samples, and the precipitation sampler must solve the problems of water sample evaporation and water isotope exchange with the outside world.
现有的降水采样器大多数都与外界环境相联通,最多是缩小蒸发面积,达到减少部分水分蒸发的目的,但无法完全阻止收集水样的蒸发、扩散以及与外界水分子的交换,不能满足降水同位素采样的要求。还有一些电机驱动的自动降水采样器,其虽然在传感器和电子控制器的控制下,根据降水是否发生而自行启闭密封盖,减少收集水样的蒸发、扩散以及与外界水分子的交换,但该系列装置结构复杂,造价昂贵,体积大,故障率高,很难在野外推广使用。故现在急需提供一种科学的便携式降水同位素采样装置。Most of the existing precipitation samplers are connected with the external environment. At most, the evaporation area is reduced to achieve the purpose of reducing part of the water evaporation, but it cannot completely prevent the evaporation, diffusion and exchange with the external water molecules of the collected water samples. Requirements for isotope sampling of precipitation. There are also some motor-driven automatic precipitation samplers, although under the control of sensors and electronic controllers, they can open and close the sealing cover automatically according to whether precipitation occurs, so as to reduce the evaporation, diffusion and exchange with external water molecules of collected water samples. However, this series of devices has complex structure, high cost, large volume and high failure rate, so it is difficult to popularize and use them in the field. Therefore, there is an urgent need to provide a scientific portable precipitation isotope sampling device.
发明内容Contents of the invention
为了解决现有降水采样装置所存在的缺陷和不足,本发明旨在提供一种结构简单,密封性好,造价低廉,适宜在野外推广使用的便携式降水同位素采样器。该采样器确保其方便在野外采集降水的同时,能有效防止水样污染、蒸发及与外界水汽同位素的交换,从而获得真实可靠的降水同位素数据。为了实现上述目的,本发明采取如下的技术方案来实现:In order to solve the defects and deficiencies of existing precipitation sampling devices, the present invention aims to provide a portable precipitation isotope sampler with simple structure, good sealing performance and low cost, which is suitable for popularization and use in the field. The sampler ensures that it is convenient to collect precipitation in the field, and at the same time, it can effectively prevent water sample pollution, evaporation and exchange with external water vapor isotopes, so as to obtain true and reliable precipitation isotope data. In order to achieve the above object, the present invention takes the following technical solutions to achieve:
一种便携式降水同位素采样器,主要包括降水收集漏斗、拦污网、通气孔、进水口、通气软管、输水导管、储水套管、浮标、出水口和固定支架。所述的降水收集漏斗位于整个采样器的最上部,漏斗上截面为圆形开口,下端有一大一小两个同心圆连接口,外侧大口与储水套管连接,内部小口与进水口连接。所述的拦污网为不锈钢薄片筛网,安装于收集漏斗内。所述的进水口上端与收集漏斗连接,下端与输水导管连接。所述的浮标为外环直径略小于储水套管内径,内环直径略大于输水导管外径的塑料圆环,套在输水导管上,可沿输水导管上下移动。所述的储水套管上端与收集漏斗下端接口相连,下端与出水口相连,起到保护内部构件和储水的目的。所述的通气软管为长度大,内径小的硅胶软管,其一端与通气孔连接,并以储水套管为中心轴螺旋式缠绕固定。所述的采样器可套装在固定支架上,固定支架底部为钢钉构造,便于采样器安装在野外。A portable precipitation isotope sampler mainly includes a precipitation collecting funnel, a trash net, a ventilation hole, a water inlet, a ventilation hose, a water delivery conduit, a water storage sleeve, a buoy, a water outlet and a fixed bracket. The precipitation collecting funnel is located at the top of the entire sampler. The upper section of the funnel is a circular opening, and the lower end has two concentric connection ports, one large and one small. The outer large port is connected to the water storage casing, and the inner small port is connected to the water inlet. The trash-blocking net is a stainless steel sheet screen installed in the collecting funnel. The upper end of the water inlet is connected with the collecting funnel, and the lower end is connected with the water delivery conduit. The buoy is a plastic ring whose outer diameter is slightly smaller than the inner diameter of the water storage casing and whose inner diameter is slightly larger than the outer diameter of the water delivery conduit. It is set on the water delivery conduit and can move up and down along the water delivery conduit. The upper end of the water storage casing is connected to the lower end of the collecting funnel, and the lower end is connected to the water outlet, so as to protect internal components and store water. The ventilation hose is a silicone hose with a large length and a small inner diameter, one end of which is connected to the ventilation hole, and is wound and fixed in a spiral manner with the water storage casing as the central axis. The sampler can be set on the fixed bracket, and the bottom of the fixed bracket is made of steel nails, which is convenient for the sampler to be installed in the field.
本发明具有以下优点和积极效果:The present invention has the following advantages and positive effects:
本发明采用3道技术措施来满足降水同位素采样要求,分别是旋转挡板,通气软管和浮标。当降水汇入进水口时,旋转挡板受侧向水压力影响打开进水口,当降水结束后,挡板受重力及内部磁块吸力影响关闭进水口,从而控制采样器内空气流动性,抑制收集水样的蒸发与扩散。通气软管采用长2m,内径3mm的硅胶软管,其不仅平衡了采样器内、外气压,使降水顺畅汇入采样器,还由于其长度长,内径小,减小了采样器内外水汽的浓度梯度,抑制了内外水汽的扩散与交换。圆环浮标安装于储水管内部,随水样液面自由浮动,不仅减小了水样与空气的接触面积和蒸发面积,抑制了水样在采样器内部的再蒸发和再扩散,还可作为储水管壁上雨量刻度的水量指针,方便降雨量的读取。本发明下端采用旋钮式出水口设计,方便水样转移至密封瓶内带回实验室内测量分析。The present invention adopts three technical measures to meet the requirements of precipitation isotope sampling, which are respectively a rotating baffle, a ventilation hose and a buoy. When precipitation flows into the water inlet, the rotating baffle is affected by the lateral water pressure to open the water inlet. When the precipitation ends, the baffle is affected by gravity and the suction of the internal magnetic block to close the water inlet, thereby controlling the air flow in the sampler and inhibiting Collect water samples for evaporation and diffusion. The ventilation hose adopts a silicone hose with a length of 2m and an inner diameter of 3mm. It not only balances the internal and external air pressure of the sampler, so that the precipitation can flow into the sampler smoothly, but also reduces the water vapor inside and outside the sampler due to its long length and small inner diameter. The concentration gradient inhibits the diffusion and exchange of water vapor inside and outside. The ring buoy is installed inside the water storage pipe and floats freely with the liquid surface of the water sample, which not only reduces the contact area and evaporation area between the water sample and the air, but also inhibits the re-evaporation and re-diffusion of the water sample inside the sampler, and can also be used as a The water volume pointer on the rain scale on the wall of the water storage pipe is convenient for reading the rainfall. The lower end of the present invention adopts a knob-type water outlet design, which facilitates the transfer of water samples to the sealed bottle and brings them back to the laboratory for measurement and analysis.
此外,本发明结构简单,密封性好,体积小巧,造价低廉,非常适宜在野外大面积使用。In addition, the invention has the advantages of simple structure, good sealing performance, small size and low cost, and is very suitable for large-area use in the field.
附图说明Description of drawings
图1(a)为本发明的结构示意图;图1(b)为本发明的纵向剖视图;Fig. 1 (a) is a structural representation of the present invention; Fig. 1 (b) is a longitudinal sectional view of the present invention;
图2(a)为本发明收集漏斗及通气管的结构示意图;图2(b)为本发明收集漏斗及通气管的纵向剖视图;Fig. 2 (a) is the structural representation of collecting funnel and ventilation pipe of the present invention; Fig. 2 (b) is the longitudinal sectional view of collecting funnel and ventilation pipe of the present invention;
图3(a)为本发明进水口的结构示意图;图3(b)为本发明进水口的纵向剖视图;Fig. 3 (a) is the structural representation of water inlet of the present invention; Fig. 3 (b) is the longitudinal sectional view of water inlet of the present invention;
图4(a)为本发明出水口的结构示意图;图4(b)为本发明出水口的纵向剖视图;图4(c)为本发明出水口旋钮开关的结构示意图;Fig. 4 (a) is the structural representation of the water outlet of the present invention; Fig. 4 (b) is the longitudinal sectional view of the water outlet of the present invention; Fig. 4 (c) is the structural representation of the water outlet knob switch of the present invention;
图5为本发明的安装示意图;Fig. 5 is the installation schematic diagram of the present invention;
图6为本发明安装在野外的整体结构示意图;Fig. 6 is a schematic diagram of the overall structure of the present invention installed in the field;
图中标记分别表示:1为降水收集漏斗,2为拦污网,3为通气孔,4为进水口,5为通气软管,6为输水导管,7为储水套管,8为浮标,9为出水口,10为旋钮开关,11为进水口挡板,12为固定支架。The marks in the figure respectively indicate: 1 is the precipitation collection funnel, 2 is the trash net, 3 is the vent hole, 4 is the water inlet, 5 is the ventilation hose, 6 is the water delivery conduit, 7 is the water storage casing, and 8 is the buoy , 9 is a water outlet, 10 is a knob switch, 11 is a water inlet baffle, and 12 is a fixed bracket.
具体实施方式Detailed ways
下面结合附图对本发明作进一步的详细说明。The present invention will be further described in detail below in conjunction with the accompanying drawings.
如图1所示,所述的输水导管(6)为内径20mm,长680mm的有机玻璃管,其上端与进水口(4)套接。所述的浮标(8)为外环直径48mm,内环直径24mm,厚15mm的塑料圆环,其外环直径略小于储水套管内径,内环直径略大于输水导管外径,套在输水导管(6)上,漂浮于水样液面,随水样液面高低而上下浮动。所述的储水套管(7)为内径50mm,长700mm的有机玻璃管,其上端与收集漏斗(1)套接,下端与出水口(9)套接,管壁标有降水量刻度,可直接进行降水量的读取。As shown in Fig. 1, described water delivery conduit (6) is the plexiglass tube of 20mm inner diameter, long 680mm, and its upper end is socketed with water inlet (4). The buoy (8) is a plastic ring with an outer ring diameter of 48 mm, an inner ring diameter of 24 mm, and a thickness of 15 mm. On the water delivery conduit (6), it floats on the liquid surface of the water sample, and floats up and down with the level of the liquid sample water. The water storage sleeve (7) is an organic glass tube with an inner diameter of 50mm and a length of 700mm, the upper end of which is socketed with the collecting funnel (1), the lower end is socketed with the water outlet (9), and the pipe wall is marked with a precipitation scale. Precipitation can be read directly.
如图2所示,所述的降水收集漏斗(1)为高密度聚乙烯材质,位于该采样器的最上部,漏斗上截面为直径100mm的圆形开口,漏斗口管壁呈刃状,利于切割雨滴,精确集雨量。漏斗中部有一横向突出的圆柱形通气孔(3),用于平衡采样器内外气压。漏斗下端有一大一小两个同心圆接口,外侧大口用于连接储水套管(7),内部小口用于连接进水口(4)。所述的拦污网(2)为不锈钢钢丝制成的孔隙为2mm*2mm的薄片筛网,置于降水收集漏斗(1)内,防止树叶等杂物掉入采样器内影响降水收集。所述的通气软管(5)为长2m,内径3mm的硅胶软管,其一端与通气孔(3)连接,并以储水套管(7)为中心轴螺旋式缠绕固定。As shown in Figure 2, the described precipitation collection funnel (1) is made of high-density polyethylene material and is positioned at the top of the sampler. Cuts raindrops for precise rainfall collection. There is a horizontally protruding cylindrical air hole (3) in the middle of the funnel, which is used to balance the air pressure inside and outside the sampler. The lower end of the funnel has two concentric circle connections, one large and one small, the outer large opening is used to connect the water storage casing (7), and the inner small opening is used to connect the water inlet (4). The trash-stop (2) is a sheet screen made of stainless steel wire with a pore size of 2mm*2mm, which is placed in the precipitation collection funnel (1) to prevent leaves and other debris from falling into the sampler to affect precipitation collection. The ventilation hose (5) is a silicone hose with a length of 2m and an inner diameter of 3mm, one end of which is connected to the ventilation hole (3), and is wound and fixed in a spiral manner with the water storage sleeve (7) as the central axis.
如图3所示,所述的进水口(4)为高密度聚乙烯材质,上端与收集漏斗(1)连接,下端与输水导管(6)连接,进水口(4)下部有一沿水平轴旋转的挡板(11),挡板下端内置永久磁铁块,进水口(4)下端管壁内置铁块,当降水汇入进水口(4)时,挡板(11)受侧向水压力影响,沿水平轴上旋打开进水口(4),当进水口(4)无水时,挡板(11)受重力及下端磁块吸力影响,沿水平轴下旋关闭进水口(4)。As shown in Figure 3, the water inlet (4) is made of high-density polyethylene, the upper end is connected to the collecting funnel (1), the lower end is connected to the water delivery conduit (6), and the lower part of the water inlet (4) has a horizontal axis Rotating baffle (11), built-in permanent magnet block at the lower end of the baffle, and built-in iron block at the lower end of the water inlet (4), when the precipitation flows into the water inlet (4), the baffle (11) is affected by the lateral water pressure , unscrew the water inlet (4) along the horizontal axis, and when the water inlet (4) was anhydrous, the baffle plate (11) was affected by gravity and the suction force of the lower end magnetic block, and turned down the water inlet (4) along the horizontal axis.
如图4所示,所述的出水口(9)为高密度聚乙烯材质,内安装一旋钮开关(10),可通过旋转旋钮开关(10)达到启闭出水口(9)的目的。As shown in Figure 4, the water outlet (9) is made of high-density polyethylene, and a rotary switch (10) is installed inside, and the purpose of opening and closing the water outlet (9) can be achieved by rotating the rotary switch (10).
如图5、图6所示,将上述构件经严格清洗干净并干燥后,依次连接好安装在1.3m高的固定支架(12)上,以避免降水时周围地面水体溅入采样器内,造成水样污染。当有降水到来时,雨水就会通过拦污筛网(2),由收集漏斗(1)汇聚,汇流到进水口(4)处,挡板(11)受侧向水压力影响,沿水平轴上旋打开进水口(4),挡板(11)可根据雨强大小,自动控制进水口(4)开口大小。降水结束,挡板(11)受重力及磁吸力作用自动下落,关闭进水口(4)。工作人员可在收集水样时旋转出水口(9)的旋钮开关(10)达到启闭出水口(9)的目的,用配套的瓶子密封储存水样,并移至实验室内测量和分析。储水套管(7)管壁上标有降水量刻度,可根据浮标(8)位置直接进行降水量的读取。As shown in Figure 5 and Figure 6, after the above-mentioned components are strictly cleaned and dried, they are connected and installed on the fixed bracket (12) with a height of 1.3m in sequence, so as to prevent the surrounding ground water from splashing into the sampler during precipitation, causing Water sample contamination. When there is precipitation, the rainwater will pass through the trash screen (2), be gathered by the collection funnel (1), and flow to the water inlet (4). The baffle (11) is affected by the lateral water pressure and moves along the horizontal axis Upswing opens the water inlet (4), and the baffle plate (11) can automatically control the water inlet (4) opening size according to the intensity of the rain. Precipitation finishes, and baffle plate (11) falls automatically by gravity and magnetic attraction effect, closes water inlet (4). The worker can rotate the knob switch (10) of the water outlet (9) to achieve the purpose of opening and closing the water outlet (9) when collecting the water sample, seal and store the water sample with a matching bottle, and move it to the laboratory for measurement and analysis. The precipitation scale is marked on the pipe wall of the water storage casing (7), and the precipitation can be directly read according to the position of the buoy (8).
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