CN105794831A - Insecticidal composition and use thereof - Google Patents
Insecticidal composition and use thereof Download PDFInfo
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- CN105794831A CN105794831A CN201410835491.1A CN201410835491A CN105794831A CN 105794831 A CN105794831 A CN 105794831A CN 201410835491 A CN201410835491 A CN 201410835491A CN 105794831 A CN105794831 A CN 105794831A
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- indoxacarb
- pesticidal combination
- biphenthrin
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
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- Pest Control & Pesticides (AREA)
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- Health & Medical Sciences (AREA)
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Abstract
The invention discloses an insecticidal composition and a use thereof. The insecticidal composition comprises bifenthrin and indoxacarb as active components. The insecticidal composition is used for preventing or controlling animal insects in the fields of protection and sanitation of agriculture, animal health, forest, garden and leisure equipment, and stored products. A weight ratio of bifenthrin to indoxacarb is 1: 100 to 100: 1. The insecticidal composition comprises, by weight, 0.5-100% of bifenthrin and indoxacarb.
Description
Technical field
The present invention relates to a kind of Pesticidal combination, active component is made up of Biphenthrin and indoxacarb.The invention still further relates to Biphenthrin and indoxacarb combines the purposes for preventing or control insect and the method for prevention or control insect.
Background technology
Chemical prevention is agriculturally or public health prevents and an important means of control insect.But, currently used medicament is still satisfied not to the effect of some insect；Further, owing to using insecticide for a long time, a lot of insects have created the resistance to common insecticide.And utilize conventional dose to carry out prevention and control and just become increasingly difficult.Therefore, in the urgent need to developing new method for controlling these insects and medicine.Additionally, also improve constantly currently for insecticide requirement on environment and economic aspect, for instance action spectrum, toxicity, selectivity, rate of application, pesticide residues and favourable preparation ability etc..Additionally, also as produce the problem of resistance possibly for known activity compound, develop and new at least in certain or some, relative to existing medicine, there is the newtype drug of advantage and just become current problem in the urgent need to address.
Biphenthrin (Bifenthrin), chemistry is by name: (1R, S)-cis-(Z)-2,2-dimethyl-3-(chloro-3,3, the 3-tri-fluoro-1-acrylic of 2-) cyclopropane-carboxylic acid-2-methyl-3-phenyl benzyl ester, and structural formula is:
Biphenthrin
Biphenthrin (Bifenthrin) is the pyrethroid insecticides of Fu Meishi company of U.S. exploitation, by suppressing the conduction at insecticide neural axon position to work, insecticide is had and walks quickly and keeps away, knock down, tag and stomach poison function.Insecticidal spectrum is wide, and activity is higher, and drug effect is rapid, and lepidopterous larvae, Homoptera, Orthoptera, Semiptera and demodicid mite class are all had good preventive effect by resistance of rainwater washing against after sprinkling.Suitable in crops such as Folium Camelliae sinensis, Cotton Gossypii, fruit tree, vegetables.But life-time service, insect is easily generated resistance.
Indoxacarb (Indoxacarb), chemistry is by name: 7-chloro-2,3,4a, 5-tetrahydrochysene-2-[methoxycarbonyl (4-Trifluoromethoxyphen-l) carbamoyl] indeno [1,2-e] [1,3,4-] oxadiazines-4a-carboxylate methyl ester, and structural formula is:
Indoxacarb (Indoxacarb) is a kind of insecticide of du pont company's Development and Production, has and tags and stomach poison function, and each instar larvae is all effective.Medicament, by contacting and take food in entrance insect bodies, by blocking the sodium-ion channel in insecticide neurocyte, makes nerve cell loss function；In 0-4 hour, namely insecticide stops taking food, and is benumbed immediately, and the coordination ability of insecticide can decline, and causes that larva falls from crop, dead in 24-60 hour after being typically in medicine.Indoxacarb insecticidal mechanism is unique, is absent from cross resistance with other insecticides；To mammal, domestic animal low toxicity, simultaneously that the beneficial insect such as the non-target organism in environment is very safe, remain low in crop, within after medication the 2nd day, can gather, especially the crop repeatedly gathered such as greengrocery, Folium Camelliae sinensis class are especially suitable for.It is applicable to the tea lesser leafhopper on the crops such as preventing and treating Folium Camelliae sinensis, Fructus Mali pumilae, pears, Fructus Persicae, Fructus Pruni, Caulis et Folium Brassicae capitatae, flower coconut palm class, cabbage mustard, Fructus Lycopersici esculenti, Fructus Capsici, Fructus Cucumidis sativi, little cucumber, Fructus Solani melongenae, Caulis et Folium Lactucae sativae, Cotton Gossypii, Rhizoma Solani tuber osi, Fructus Vitis viniferae, tea geometrid, leaf rollers, carpocapsa pononella, beet armyworm, diamondback moth, Pieris rapae, Prodenia litura, lopper worm, bollworm, oriental tobacco budworm, diamond, colorado potato bug etc..
The activity of the individually oriented compound of Biphenthrin, indoxacarb is good；But, at low rate of application or when using for independent insect, they are not to meet the high request that insecticide, acaricide or nematicide must are fulfilled for.
The typical demand occurred in field of pest control is to need reduce close rate and the reduction of active component or avoid hostile environment or toxicological effects, still allows for effective Pest control simultaneously.Another demand is able to combination and knocks down activity and lasting period, namely in conjunction with snap action and long-acting.
Another difficulty using insecticide is in that to repeat and use uniquely single Pesticidal compound to cause in many cases described reactive compound produces quick selection that is natural or that adapt to drug-fast insect.Accordingly, it would be desirable to contribute to preventing or overcome drug-fast pest control agent.
Summary of the invention
The invention aims to solve above-mentioned technical problem, provide a kind of Pesticidal combination, said composition is by being combined Biphenthrin and indoxacarb, the compositions obtained is made to have gain effect in prevention effect, and expand insecticidal spectrum, improve the snap action to Pest control and long-acting, delay drug-fast generation.
It is an object of the present invention to provide at least one that solve in described problem, such as depressant dose rate, improve activity profile, combine and knock down activity and lasting period, delaying drug resistance.
Therefore, it is an object of the present invention to provide a kind of Pesticidal combination, active component is made up of Biphenthrin and indoxacarb.
One Pesticidal combination of the present invention is to take techniques below scheme to realize:
A kind of Pesticidal combination, active component is made up of Biphenthrin and indoxacarb, and the weight ratio of described Biphenthrin and indoxacarb is 1:100 to 100:1.
A kind of Pesticidal combination, active component is made up of Biphenthrin and indoxacarb, and wherein the weight ratio of Biphenthrin and indoxacarb is 1:50 to 50:1, it is preferable that 1:20 to 20:1, more preferably 1:10 to 10:1.
A kind of Pesticidal combination, active component Biphenthrin and indoxacarb account for described compositions 0.5% to 100% by weight altogether, it is preferable that 1% to 80%, more preferably 5%-60%.
A kind of Pesticidal combination of the present invention, also comprises carrier and/or surfactant.
A kind of Pesticidal combination of the present invention, dosage form is: suspending agent, microcapsule, cream, suspending agent, water dispersible granules, wettable powder, suspension emulsion, aqueous emulsion, suspension seed-coating agent, granule, bait grain.
Present invention also offers a kind of purposes that the Pesticidal combination of the present invention is used for preventing or controlling agricultural pests.
Present invention also offers a kind of purposes being used for the Pesticidal combination of the present invention preventing or control the agricultural pests of invasion and attack plant or plant propagation material.
Described plant propagation material is seedling, rhizome, garden Seedling, cutting or seed.
Described agricultural pests are bollworm, small heart-eating peach worm, oriental fruit months, tetranychus viennensis, Citrus chachiensis Hort. macula lutea stinkbug, eating attraction, vegetable aphid, Pieris rapae, diamondback moth, red spider, the thin moth of tea, Trialeurodes vaporariorum Westwood, tea geometrid, Euproctis pseudoconspersa, leafhopper, beet armyworm, Pieris rapae, Prodenia litura, lopper worm, oriental tobacco budworm, carpocapsa pononella, diamond, beetle.
On the other hand, present invention also offers a kind of prevention or the method controlling agricultural pests, the Pesticidal combination of the present invention is acted on target agricultural pests and/or its environment.
A kind of protect plant in case agricultural pests invasion and attack method, the propagating materials including the Pesticidal combination with target useful plant, target agricultural pests and/or its environment, target useful plant that make the present invention contacts.
A kind of protect plant in case the method for agricultural pests invasion and attack, including separately, sequentially or simultaneously Biphenthrin and indoxacarb.
A kind of prevention or the method controlling agricultural pests, wherein Biphenthrin and indoxacarb are individually the form being formulated compositions.
A kind of method protecting plant seed, it include making seed prior to seeding and/or after accelerating germination the Pesticidal combination of the present invention with effective dose contact.
The Pesticidal combination of the present invention is for processing the purposes of seed.
Another aspect, present invention also offers described a kind of Pesticidal combination, for preventing or control the purposes of sanitary insect pest.Described sanitary insect pest is red fire ant, Coptotermes formosanus Shtrari., mosquito, fly.
Present invention also offers a kind of prevention or the method controlling sanitary insect pest, including the Pesticidal combination of the present invention being applied to target sanitary insect pest and/or its environment.
The present invention by both composite benefits have following some:
A, insect potentiation is obvious, it is possible to decrease the dosage of two compositions；
B, both use with, solving the problem to insect lasting period Yu quick-acting, thus reducing times for spraying, reducing cost of labor；
C, delayed the generation of resistance: both mechanisms of action and model of action are entirely different, have after combination tag, the effect such as stomach toxicity so that insect is more easy to and is killed, thus having delayed the generation of resistance.
Detailed description of the invention
The present invention unexpected finds: the additivity for insecticidal spectrum not only can be brought to improve with indoxacarb combination Biphenthrin, and the more important thing is, it may be achieved amazing synergism.
Term used herein " synergism " refers to that the insecticidal effect of activating agent of the present invention combination or compositions is more than each activating agent effect sum, and in other words, its effect is superadditivity.It addition, referring also to the defined effect " Isoboles, agraphicrepresentationofsynergisminpesticides " of Tammes method, NetherlandsJournalofPlantPathology, 70 (1964), pages73-80.
A kind of Pesticidal combination, active component is made up of Biphenthrin and indoxacarb, and the weight ratio of described Biphenthrin and indoxacarb is 1:100 to 100:1.
A kind of Pesticidal combination, active component is made up of Biphenthrin and indoxacarb, and wherein the weight ratio of Biphenthrin and indoxacarb is 1:50 to 50:1, it is preferable that 1:20 to 20:1, more preferably 1:10 to 10:1.
In Pesticidal combination of the present invention, the total amount of active compound component can select according to material elements, to realize desired effect, and described factor such as dosage form, object to be administered, application process etc..Biphenthrin and indoxacarb account for described compositions 0.5% to 100% by weight altogether, it is preferable that 1% to 80%, more preferably 5%-60%.
The Pesticidal combination of the present invention also optionally comprises acceptable surfactant and/or extender on agronomy.
According to the present invention, term " filler " refers to can be combined with reactive compound or combine to make it easier for be administered to the naturally occurring or synthetic organic or inorganic compound of object (such as plant, crop or grass class).Therefore, described filler is preferably inertia, at least should be agronomically acceptable.Described filler can be solid or liquid.
Suitable solid carrier is: such as, pulverize and the natural rock such as calcite, marble of classification, Pumex, meerschaum, dolomite, and inorganic and organic dust synthesis granule, and the granule of organic substance such as paper, sawdust, coconut husk, corncob and tobacco stem；
Suitable liquid-carrier is, such as, water, polarity and nonpolar organic chemistry liquid, such as aromatic hydrocarbons and non-aromatic hydro carbons (such as paraffin, alkylbenzene, alkylnaphthalene, chlorobenzene), alcohol and polyhydric alcohol (if suitable, its can also be replace, etherificate and/or esterification), ketone (such as acetone, Ketohexamethylene), esters (including fat and oil) and polyethers, unsubstituted and substituted amine, amide-type, lactams (such as N-alkyl pyrrolidone) and lactone, sulfone class and sulfoxide type (such as dimethyl sulfoxide).
If liquid-carrier used is water, then it be also possible to use such as organic solvent as cosolvent.Suitable liquid flux mainly has: aromatic hydrocarbons is dimethylbenzene, toluene or alkylnaphthalene such as；Chlorinated aromatic hydrocarbons and chlorinated aliphatic hydrocarbon, such as chlorobenzene, vinyl chloride or dichloromethane；Aliphatic hydrocarbon, such as hexamethylene or paraffin such as petroleum distillate；Mineral and vegetable oil；Alcohol such as butanol or ethylene glycol, and their ether and ester；Ketone is acetone, methyl ethyl ketone, methyl iso-butyl ketone (MIBK) or Ketohexamethylene such as；Intensive polar solvent is dimethyl sulfoxide such as.
For making effective ingredient compound emulsifying, dispersion, solubilized, and/or moistening can use surfactant such as can enumerate fatty alcohol-polyoxyethylene ether, polyoxyethylene alkylaryl ether, polyoxyethylene higher fatty acid esters, the phosphate ester of polyoxyethylene alcohol or phenol, the fatty acid ester of polyhydric alcohol, naphthalene sulfonic acid polymer, lignosulfonates, a shape copolymer of macromolecule comb shape, butyl naphthalene sulfonate, alkylaryl sulfonates, sodium alkylsulfosuccinates, oils and fats, fatty alcohol and ethylene oxide condensate, the polyacrylate of alkyltaurate, protein hydrolysate.Suitable oligosaccharide thing or polymer, for instance based on the combination of independent vinyl monomer, acrylic acid, polyoxyethylene and/or polyoxypropylene or itself and such as (polynary) alcohol or (polynary) amine.
For making the dispersion of effective ingredient compound, stabilisation, attachment, such as xanthan gum, aluminium-magnesium silicate, gelatin, starch, methyl cellulose, polyvinyl alcohol, polyvinyl acetate and the adjuvant such as natural phospholipid (such as cephalin and lecithin) and synthetic phospholipid, Bentonite, sodium lignin sulfonate can be used.
Wherein antifreezing agent can be selected for ethylene glycol, propylene glycol, glycerol, sorbitol.The adjuvant of such as naphthalene sulfonic acid polymer, polymeric phosphate etc. can be used as the deflocculant of suspension product.Organic silicon defoamer can be used as defoamer.For improveing the mobility of solid product, the adjuvant such as such as paraffin, stearate, alkylphosphonate can be used.
Operable coloring agent, for instance inorganic pigment, such as ferrum oxide, titanium oxide and Prussian blue；And organic pigment/dyestuff: alizarin dyes, azo dye and metallized phthalocyanine dye；And trace element, for instance iron salt, manganese salt, boron salt, mantoquita, cobalt salt, molybdenum salt and zinc salt.
Optionally, other annexing ingredient can also be comprised, for instance protecting colloid, binding agent, thickening agent, thixotropic agent, penetrating agent, stabilizer, screening agent.
The Pesticidal combination of the present invention can directly use, use using dosage form or as type of service prepared therefrom, such as aerosol, suspending agent, microcapsulated granule, granula subtilis, flowable concentrate, ready to use solution agent, powder, cream, aqueous emulsion, oil emulsion, big granule, microgranule, oil dispersion powder, the miscible mobility concentrate of oil, oil miscible liquids, foam, paste, suspending concentrate, suspension emulsion, solubility concentrate, soluble powder, granule, water-soluble granular and/or tablet, water solube powder, wettable powder, naturally occurring or synthetic material through reactive compound dipping, microcapsule in polymeric material and water-dispersible granule.
In preferred embodiments, described agrochemical composition is cream, suspending agent, seed coat agent, water dispersible granules, wettable powder, suspension emulsion, aerosol, aqueous emulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent, ultra low volume liquids, bait grain.
Described reactive compound can be mixed with conventional additives by known way and prepare by the described preparation of the present invention.Described conventional additives such as conventional extender and solvent or diluent, emulsifying agent, dispersant and/or binding agent or fixative, wetting agent, waterproofing agent, if it is required, drier and coloring agent, stabilizer, pigment, defoamer, preservative, thickening agent, water and other processing aid also can be comprised.
These compositionss not only include can being applicable to pending object immediately such as spraying or dusting equipment by suitable equipment, and be additionally included in be applied to object before need the concentration commercial composition that is diluted.
The Pesticidal combination of the present invention can make, with the form of the compositions of its active compound component, the preparation being suitable to use, it is also possible to uses with the form of the combination of the commercial preparation of its suitable dosage.Can also with other activating agent combined administration, other agents described such as insecticide, attractant, biocide, bactericide, acaricide, nematicide, antifungal, growth regulator, herbicide, safener, fertilizer or semiochemical etc..
Present invention also offers a kind of purposes that the Pesticidal combination of the present invention is used for preventing or controlling agricultural pests, sanitary insect pest.
Present invention also offers a kind of purposes being used for the Pesticidal combination of the present invention preventing or control the agricultural pests of invasion and attack plant or plant propagation material.
Present invention also offers a kind of purposes that the Pesticidal combination of the present invention is used for preventing or controlling sanitary insect pest.
The Pesticidal combination of the present invention runs into animal pest suitable in preventing and treating agricultural, gardening, animal husbandry, forestry, garden and Relexing device, the protection of Stored Product and health field, particularly insecticide, arthropod, parasitic worm, nematicide and Mollusca.The Pesticidal combination of the present invention shows to the good toleration of plant, to the hypotoxicity of warm blooded species and good Environmental compatibility simultaneously.Normal sensitive and resistance kind there is is activity, there is activity all or special stage of development.Above-mentioned insect includes:
From Isopoda, for instance tide worm (Oniscusaselluse), Armadillidium (Armadillidiumvulgare), and speckle Armadillidium (Porcellioscaber).
From Diplopoda, for instance Blaniuusguttulatus.
From chilopoda, for instance DIWUGONG (Geophiluscarpophagus) and common house centipede dragonfly (Scutigeraspp.).
From Symphyla, for instance clean symphilid (Scutigerellaimmaculate).
From Thysanoptera, for instance silverfiss (Lepismasaccharina).
From Collembola, for instance Onychiurus arcticus (Onychiurusarmatus).
From Orthoptera, such as Scapipedus (Achetadomesticus), Gryllotalpa spp (Gryllotalpaspp.), torrid zone Locustamigratoria (Linnaeus) (Locustamigratoriamigratorioides), the negative locust of long volume belongs to (Melanoplusspp.), and desert locust (Schistocercagregaria).
From Blattaria, for instance oriental cockroach (Blattaorientalis), periplaneta americana (PeriplanetaAmericana), leucophaea maderae (Leucophaeamaderae), Groton bug (Blattellagermanica).
From Dermaptera, for instance European earwig (Forficulaauricularia).
From Isoptera, for instance Reticulitermes.
From Anoplura, for instance body louse (Pediculushumanuscorporis), blind louse belongs to, and long volume louse belongs to, Trichodectes, Damalinia.
From Thysanoptera, for instance greenhouse Hercinothrips spp (Hercinothripsfemoralis), cotton thrips (Thripstabaci), Thripspalmi and Frankliniellaaccidentalis.
From Heteroptera, for instance Eurygasterspp belongs to, middle red cotton bug (Dysdercusintermedius), lace bug (Piesmaquadrata) intended by Radix Betae, and the smelly stinkbug in temperate zone (Cimexlectularius), red abdomen hunts stinkbug (Rhodniusprolixus) and Triatoma.
nullFrom Homoptera，Such as Caulis et Folium Brassicae capitatae aleyrodid (Aleurodesbrassicae),Bemisia tabaci (Bemisiatabaci),Trialeurodes vaporariorum Westwood (Trialeurodesvaporariorum),Cotten aphid (Aphisgossypii),Brevicoryne brassicae (Brevicorynebrassicae),Tea deer hidden tumor volume aphid (Cryptomyzusribis),Black bean aphid (Brevicorynebrassicae),Apple aphid (Aphispomi),Apple aphid (Eriosomalanigerum),Mealy plum aphid (Hyalopterusarundinis),Grape phylloxera (Phylloxeravastatrix)，Pemphigus，Grain aphid (Macrosiphumavenae)，Tumor volume Aphis，Hops tumor volume aphid (Phorodo)，Rice green leafhopper (Nephotettixcincticeps)，Brown apricot scale (Lecanium
Corni), Fructus oleae europaeae helmet (Saissetiaoleae), rice small brown rice planthopper (Laodelphaxstriatellus), brown back rice plant hopper (Nilaparvatalugens), California red scale (Aonidiel1aaurantii), Folium seu Cortex Nerii circle a red-spotted lizard (Aspidiotushederae), mealybug belongs to and Psylla spp.
nullFrom Lepidoptera，Such as pink bollworm (Pectinophoragossypiella)，Loose looper (Bupaluspiniarius)，Winter geometrid moth (Chemimatobiabrumata),Lithoclletisblancardela,Fructus Pruni pseudocerasi ermine moth (Hyponomeutapadella),Diamondback moth (Plutellaxylostella)，Tent caterpillar (Malacosomaneustria)，Pornography and drug moth (Euproctischrysorrhoea)，Euproctis，Cotton shot hole of leaf lyonetid (Bucculatrixthurberiella)，Fructus Citri tangerinae leaf miner (Phyllocnistiscitrella)，Agrotis，Cutworm belongs to，Brown Noctua，Earias insulana (Eariasinsulana)，Noctua，Lopper worm (Mamestrabrassicae)，Small noctuid (Panolisflammea)，Noctua，Cabbage looper (Trichoplusiani)，Carpocapsa pononella (Carpocapsapomonella)，Pier，Snout moth's larva belongs to (Pyraustlla)，Bag casemaking clothes moth (Tineolabisselliella)，Etting moth (TineaPellionella)，Brown oecophorid (Hofmannophilapseudospretella)，Yellow tail leaf roller (Cacoeciapodana)，Choristoneura fumigerana (Choristoneurafumiferana)，The slow-witted moth-eaten moth (Clysiaambiguella) of Fructus Vitis viniferae,Tea yellow leaf curl moth (Homonamagnanima)，The green leaf roller of oak (Tortrixviridana),Volume snout moth's larva belongs to，Oulema oryzae (Oulemaoryzae).
nullFrom coleoptera，Such as furniture death watch beetle (Anobiumpunctatum)，Lesser grain borer (Rhizoperthadominica),Bruchidiusobtectus，Bean weevil (Acanthoscelidesobtectus)，House longhorn beetle (Hylotrupesbajulus)，Folium Et Cacumen Alni Japonicae purple flea beetle (Agelasticaalni)，Colorado potato bug (Leptinotarsadecemlineata)，Radix Cochleariae officinalis ape chrysomelid (Phaedoncochleariae)，Chrysomelid genus，Brassica campestris L orchid flea beetle (Psylliodeschrysocephala)，Mexican bean ladybird (Epi1achnavarivestis)，Hidden wing first belongs to，Saw breast ostomatid (Oryzaephilussurinamensis),Weevil belongs to，Sitophilus，Vine black ear is as (Otiorrhynchussulcatus)，Banana spider base weevil (Cosmopolitessordidus)，Caulis et Folium Brassicae capitatae English weevil (Ceuthorrhynchusassimilis)，Alfalfa weevil (Hyperapostica)，Khapra beetle belongs to，Speckle khapra beetle belongs to，Anthrenus，Hair is moth-eaten to be belonged to，Powder moth belongs to，Pollen beetle (Meligethesaeneus)，Spider
First belongs to, golden yellow ptinid (Niptushololeucus), wheat ptinid (Gibbiumpsylloides), Tribolium, Cabot's Tragopan (Tenebriomolitor), click beetle belongs to, acupuncture needle Eimeria, angle Gold Testudinis (Melolonthamelolontha), chafer in June (Amphimallonsolstitialis), brown New Zealand rib wing gill Gold Testudinis (Costelytra
Zealandica) and rice water as (Lissorhoptrusoryzophilus).
From Hymenoptera, for instance Neodiprion spp belongs to, tenthredinidae, field ant belongs to, MonomoriumMayr (Monomoriumpharaonis) and Vespa.
nullFrom Diptera，Such as Aedes，Speckle Anopheles，Culex，Drosophila yellow gorilla (Drosophilamelanogaster)，Musca，Male servant fly belongs to，Calliphora erythrocephala (Calliphoraerythrocephala)，Lucilia sericata belongs to，Carysomyia，Cuterbrid belongs to，Gasterophilus，Hippobosca，Chela fly belongs to，Nose fly belongs to，Hypoderma，Pituophis，Tannia belongs to，March fly belongs to (Bibiohortulanus),Sweden's straw rope (Oscinellafrit)，Wheat fly belongs to，Beet fly (Pegomyiahyoscyami)，Mediterranean fruitfly (Ceratitiscapitata)，Dacus oleae (Dacusoleae) and Europe daddy-longlegs (Tipulapaludosa)，Hylemyia，And Hippelates.
From Siphonaptera, for instance Xenopsyllacheopis (Xenopsyllacheopis) and angle leaf sage Mus.
From Arachnoidea, such as scorpion (Scorpiomaurus), black widow (Latrodectusmactans), Acarus siro (Acarussiro), hidden genus, blunt port belongs to, Dermanyssus gallinae (Dermanyssysgallinae), tea deer wart demodicid mite (Eriophyesribis), citrus rust mite (Phyllocoptrutaoleivora), Boophilus, carrapato belongs to, Amblyomma, glass eye Ticks belongs to, hard Ticks belongs to, Acarus tritici belongs to, Rhizoma Zingiberis Recens demodicid mite belongs to, acaricide belongs to, the compacted genus of line, Bryobia praetiosa (Bryobiapraetiosa), red spider belongs to, the compacted genus of red autumnal leaves, point tenthredinidae, short whisker Acarapis.
Parasitic plant nematicide includes such as Pratylenchidae and belongs to, Radopholus similis Throne (Radopholussimilis), fuller's teasel Ditylenchus dipsaci (Ditylenchusdipsaci), Tylenchulus Semipenetrans (Tylenchulussemipenetrans), Heterodera, ball Heterodera, Meloidogyne, Aphelenchoides, minute hand Turbatrix, Xiphinema, and burr Turbatrix, remote spring dragonfly belongs to.
The Pesticidal combination of the present invention is particularly well-suited to preventing and treating " biting " insect, and these insects specifically include following insect:
nullFrom Lepidoptera，Such as pink bollworm (Pectinophoragossypiella)，Loose looper (Bupaluspiniarius)，Winter geometrid moth (Cheimatobiabrumata),Lithocolletisblancardel1a，Fructus Pruni pseudocerasi ermine moth (Hyponomeutapadella),Diamondback moth (Plutellaxylostella)，Tent caterpillar (Malacosomaneustria),Pornography and drug moth (Euproctischrysorrhoea)，Euproctis，Cotton shot hole of leaf lyonetid (Bucculatrixthurberlella)，Fructus Citri tangerinae leaf miner (Phyllocnistiscitrella)，Agrotis,Cutworm belongs to，Brown Noctua，Egyptian complete just brill (Eariasinsulana)，Noctua，Lopper worm (Mamestrabrassicae)，Small noctuid (Panolisflammea)，Noctua，Powder pattern moth (Trichoplusiani)，Carpocapsa pononella (Carpocapsapomonella)，Pier，Snout moth's larva belongs to，Pyraustanubilalis,Anagasta kuehniella (Ephestiakuehniella)，Radix Et Rhizoma Rhei snout moth's larva (Gal1eriamellonella)，Bag casemaking clothes moth (Tineolabisselliella)，Etting moth (Tineapellionella)，Brown oecophorid (Hofmannophilapseudospretella)，Yellow tail leaf roller (Cacoeciapodana),Capuareticulana，Choristoneura fumigerana (Choristoneurafumiferana)，The slow-witted moth-eaten moth (Clysiaambiguella) of Fructus Vitis viniferae,Tea yellow leaf curl moth (Homonamagnanima)，The green leaf roller of oak (Tortrixviridana),Volume snout moth's larva belongs to，Oulema oryzae (Oulemaoryzae).
nullFrom coleoptera，Such as furniture death watch beetle (Anobiumpunctatum)，Lesser grain borer (Rhizoperthadominica),Bruchidiusobtectus，Bean weevil (Acanthoscelidesobtectus)，House longhorn beetle (Hylotrupesbajulus)，Folium Et Cacumen Alni Japonicae purple flea beetle (Agelasticaalni)，Colorado potato bug (Leptinotarsadecemlineata)，Radix Cochleariae officinalis ape chrysomelid (Phaedoncochleariae)，Chrysomelid genus，Brassica campestris L orchid flea beetle (Psylliodeschrysocephala)，Mexican bean ladybird (Epilachnavarivestis)，Hidden wing first belongs to，Saw breast ostomatid (Oryzaephilussurinamensis),Weevil belongs to，Sitophilus，During vine black ear beak (Otiorrhynchussulcatus)，Banana spider base weevil (Cosmopolitessordidus)，Caulis et Folium Brassicae capitatae English weevil (Ceuthorrhynchusassimilis)，Alfalfa weevil (Hyperapostica)，Khapra beetle belongs to，Speckle khapra beetle belongs to，Anthrenus，Hair is moth-eaten to be belonged to，Powder moth belongs to，Pollen beetle (Meligethesaeneus)，Spider
First belongs to, golden yellow ptinid (Niptushololeucus), wheat ptinid (Gibbiumpsylloides), Tribolium, Cabot's Tragopan (Tenebriomolitor), click beetle belongs to, acupuncture needle Eimeria, angle Gold Testudinis (Melolonthamelolontha), chafer in June (Amphimallonsolstitialis), brown New Zealand rib wing gill Gold Testudinis, angle Gold Testudinis (Costelytrazealandica) and rice water are as (Lissorhoptrusoryzophilus).
A kind of Pesticidal combination containing Biphenthrin and indoxacarb of the present invention is particularly well-suited to preventing and treating " sucking " insect, and these insects specifically include following insect:
nullFrom Homoptera，Such as Caulis et Folium Brassicae capitatae aleyrodid (Aleurodesbrassicae)，Bemisia tabaci (Bemisiatabaci)，Trialeurodes vaporariorum Westwood (Trialeurodesvaporariorum)，Cotten aphid (Aphisgossypii)，Brevicoryne brassicae (Brevicorynebrassicae)，Tea deer hidden tumor volume aphid (Cryptomyzusribis)，Black bean aphid (Aphisfabae)，Apple aphid (Aphispomi)，Apple aphid (Eriosomalanigerum)，Mealy plum aphid (Hyalopterusarundinis)，Grape phylloxera (Phylloxeravastatrix)，Wart cotten aphid belongs to，Grain aphid (Macrosiphumavenae)，Tumor volume Aphis，Hops tumor volume aphid (Phorodonhumuli)，Foxtail millet Rhopalosiphum spp (Rhopalosiphumpadi)，Leafhopper belongs to (Cicadellidae)，Rice green leafhopper (Nephotettixcincticeps)，Brown apricot scale (Lecaniumcorni)，Fructus oleae europaeae helmet (Saissetiaoleae)，Rice small brown rice planthopper (Laodelphaxstriatellus)，Brown back rice plant hopper (Nilaparvatalugens)，California red scale (Aonidiellaaurantii)，Folium seu Cortex Nerii circle a red-spotted lizard (Aspidiotushederae)，Mealybug belongs to and Psylla spp.
Preferably, the Pesticidal combination of the present invention is suitable to the agricultural pests such as preventing and treating bollworm, small heart-eating peach worm, oriental fruit months, tetranychus viennensis, Citrus chachiensis Hort. macula lutea stinkbug, eating attraction, vegetable aphid, Pieris rapae, diamondback moth, red spider, the thin moth of tea, Trialeurodes vaporariorum Westwood, tea geometrid, Euproctis pseudoconspersa, leafhopper, beet armyworm, Pieris rapae, Prodenia litura, lopper worm, oriental tobacco budworm, carpocapsa pononella, diamond, beetle.
Preferably, the Pesticidal combination of the present invention is suitable to the sanitary insect pests such as preventing and treating Coptotermes formosanus Shtrari., red fire ant, mosquito, fly.
On the other hand, present invention also offers a kind of prevention or the method controlling agricultural pests, sanitary insect pest, the Pesticidal combination of the present invention is acted on target agricultural pests, sanitary insect pest and/or its environment.
The present invention also provide for a kind of protect plant in case agricultural pests, sanitary insect pest invasion and attack method, the propagating materials including the Pesticidal combination with target useful plant, target pest and/or its environment, target useful plant that make the present invention contacts.
The implication of plant herein is interpreted as all plants and plant population.Plant is maybe maybe can can pass through, by biotechnology and genetic engineering method, the plant that the combination of these methods obtains by conventional breeding and method for optimizing.Described plant includes transgenic plant, also includes the plant variety that can be subject to plant breeder's power (plantbreeders'rights) protection or not be protected.
May be used for present invention protection, and use the useful plant of Pesticidal combination according to the present invention and include: cereal is Semen Tritici aestivi, Herba bromi japonici, Fructus Hordei Vulgaris, black Semen Tritici aestivi and rye (Secale cereale L.) such as, and Semen Maydis, Sorghum vulgare Pers. He Li, rice；Radix Betae, such as sugar beet or fodder beet；Fruit, for instance apple class fruit, drupe, tree nut or soft water fruit, such as Fructus Mali pumilae, pears, Fructus Pruni salicinae, Fructus Persicae, Fructus Musae, Semen Armeniacae Amarum, Semen Juglandis, Fructus Pistaciae Verae, Fructus Pruni pseudocerasi or berry, such as Fructus Fragariae Ananssae or blackberry；Legume is Kidney bean, Semen Pisi sativi or Semen sojae atricolor such as；Oil crop, such as Brassica campestris L, Caulis et Folium Brassicae junceae, Fructus Canarii albi, Helianthi, Semen Ricini, cocoa tree or Semen arachidis hypogaeae；Cucurbitaceous plant, such as Fructus Cucurbitae moschatae, Cucurbita pepo L., Fructus Cucumidis sativi or Fructus Melo；Fibre plant, such as Cotton Gossypii, Caulis et Folium Lini, Fructus Cannabis or Corchorus olitorius L.；Citrus fruit, such as Fructus Citri tangerinae, Fructus Citri Limoniae, grapefruit or Fructus Citri tangerinae；Vegetable is Herba Spinaciae, Caulis et Folium Lactucae sativae, Germinatus Phragmitis, Brassica oleracea L.var.capitata L., Radix Dauci Sativae, Bulbus Allii Cepae, Fructus Lycopersici esculenti, Capsicum tetragonum, Rhizoma Solani tuber osi or sweetbell redpepper such as；Lauraceae, such as American Avocado Tree, Cortex Cinnamomi or Camphora；And Nicotiana tabacum L., nut, coffee, Fructus Solani melongenae, Caulis Sacchari sinensis, Camellia sinensis, Fructus Piperis, vine, Flos lupuli (Flos Humuli Lupuli), Plantaginaceae, lactiferous plant, lawn, lawn, fodder grasses, and ornamental plant, such as Petunia, Herba Violae Hortensis and Flos Impatientis；And shrub, broad leaf tree and aithullium, such as coniferous tree.
With the Pesticidal combination of the present invention, the process of plant is made directly with conventional treatment method or is undertaken by acting on its environment, habitat or storage areas, described conventional treatment method such as impregnates, carry out watering, spray, atomizing, broadcast sowing, dust, mist formation, broadcast sowing, foam, be coated with, be coated with, the mode such as drip irrigation uses (foliage applying) to the blade of plant, the frequency and consumption used can be regulated so that it is adapt to the degree encroached on by described agricultural pests.
The Pesticidal combination of the present invention is also suitable for propagating materials such as seed, fruit, tuber or the kernel or plant cutting of protection plant not by the infringement of harmful organism particularly insecticide and acarid.Can before administration with this propagating materials of compositions-treated, for instance dress seed prior to seeding.Also by soaking kernel in fluid composition or being coated kernel with solid composite, active component is applied on kernel (being coated).When propagating materials being applied to that such as seed is broadcast in ditch in seeding process, it is possible to said composition is applied to application site.Processing method and the plant propagation material being processed as of plant propagation material are all further subject matters of the present invention by these.
Term " plant propagation material " is interpreted as referring to all plant parts having fertility, for instance seed, and vegetable matter such as cuttage bar or tuber (such as Rhizoma Solani tuber osi).Therefore, plant part used herein includes plant propagation material.It is mentioned that such as seed (in the narrow sense), root, fruit, tuber, bulb, rhizome and plant part.The germination plant suppressed after germinateing from soil or after emerging and effective plant be also it can be mentioned that.Young plant can be undertaken all by dipping before transplantation or Local treatment is protected.
Plant part and the plant organ grown subsequently are any parts of the plant produced by plant propagation material such as seed.Plant part, plant organ and plant can also benefit from by compositions is applied to plant propagation material protection plant avoid plant disease.Certain plants part and some plant organ grown subsequently can also regard plant propagation material as, himself can use (or process) by compositions；Thus the plant produced by treated plant part and treated plant organ, other plant part and other plant organ can also be benefited from avoids insect pest of the plant by compositions is applied to certain plants part and certain plants Organoprotective plant.
In order to process plant propagation material particularly seed, also by impregnating tuber or grain in succession with the liquid preparation of each active component, or by with the wet or dry preparation coating combined, thus active component being administered on seed (coating).
The Pesticidal combination of the present invention is applied to seed with itself or suitable dosage form.Preferably, seed is processed at steady state, does not cause any infringement so that process.The process of seed generally can be carried out any time between gathering and sowing.Generally it has to be noticed that the amount of the amount and/or other additive that are applied to the present composition of seed is chosen as the germination without influence on seed or without compromising on gained plant during seed treatment.
A kind of method protecting seed, it include making seed prior to seeding and/or after accelerating germination the Pesticidal combination of the present invention with cooperative effective quantity contact.
The invention still further relates to the seed that a kind of Pesticidal combination using the present invention processes.
The Pesticidal combination of the present invention can be applied to the environment of plant growing, habitat or storage areas.The environment of plant growing, habitat refer to the supporter making crops take root, growing, such as: soil, water etc., concrete raw material can use such as sand, Pumex, Vermiculitum, kieselguhr, agar, gelling material, polymer substance, asbestos, wood flour, bark etc..Preferred soil.
The method using medicament in soil, such as liquid preparation it is diluted in water or does not dilute the medium method in rice seedling bed of root or the seedling being directly applied to plant, the method being disseminated to by granule in the root of plant or the rice seedling bed of seedling has the method being sprayed in soil by powder, water dispersible granules etc. prior to seeding and mixing with soil entirety, before sowing or be sprayed in implantation hole, seed furrow by after powder, water-dispersible grain dilution agent before serike body, carrying out the method etc. sowed.
The method of the present invention additionally provide with separately, sequentially or simultaneously reactive compound described in mode combined administration.It is common and favourable that the compositions of the present invention or activating agent combination are generally used with following dosage:
-leaf portion is processed: 0.1-10000g/ha, it is preferable that 5-1000g/ha, more preferably 10-50g/ha；For using for dipping or instillation, described dosage even also can reduce, particularly when using inert base such as asbestos or perlite；
-for seed treatment: 2-200g/100kg seed, preferred 3-150g/100kg seed；
-for soil treatment: 0.1-10000g/ha, it is preferable that 1-5000g/ha.
Above-mentioned dosage is only general exemplary dose, and actual those skilled in the art can according to practical situation and needs when using, and character and insect pest situation especially in accordance with pending plant or crop adjust rate of application.
On the other hand, the process of the present invention also can produce following super additive effect: improve plant growing, improve to the toleration of high temperature or low temperature, improve to arid or to the toleration of water or soil salt content, improve Flowering quality, make to gather easier, accelerate ripe, improve productivity of gathering, improve the quality of harvested products and/or improve its nutritive value, improve bin stability and/or its processing characteristics of harvested products.
Moreover, it has been discovered that the insect destroying industrial materials is had effective insecticidal action by the Pesticidal combination of the present invention.
Propose following insecticide as an example and preferably, but be not limited to this:
nullColeoptera is North America house longhorn beetle (Hyloptrupesbajulus) such as，Green tiger Anoplophorae seu Aprionae (Chlorophoruspilosis)，Furniture death watch beetle，Report dead material death watch beetle (during Xestobiumrufovillosu，Class wing death watch beetle (Ptilinuspecticornis),Dendrobiumpertinex，Pine bud branch death watch beetle (Ernobiusmol1is)，Pine product death watch beetle (Priobiumcarpini)，Lyctus brunneus Stephens (Lyctusbrunneus)，Powder moth-eaten (Lyctusafricanus),South powder moth-eaten (Lyctusplanicollis)，Quercitron moth-eaten (Lyctuslinearis)，Powder moth-eaten (Lyctuspubescens)，Breast powder moth-eaten (Trogoxylonaequale)，Minthea rugicollis (Minthesrugicollis)，Material bark beetle belongs to，Wood strip bark beetle belongs to，Coffee black long moth-eaten (Apatemonachus),Bostrychuscapucins，Brown different long wing moth-eaten (Heterobostrychusbrunneus)，Spine length moth belongs to，Bamboo pole powder length moth-eaten (Dinoderusminutus).
Dermaptera, for instance blue black wood wasp (Sirexjuvencus), the big wood wasp of PiceameyeriRehd. Et Wils. (Urocerusgigas), Urocerus gigas toiganus (Urocerusgigastaignus), big wood wasp (Urocerusaugur).
nullCoptotermes formosanus Shtrari.，Such as kalotermitid (Kalotermesflavicollis)，Fiber crops head heap sand Coptotermes formosanus Shtrari. (Cryptotermesbrevis)，The Indian-Pakistani different Coptotermes formosanus Shtrari. of structural wood (Heterotermesindicola)，American-European reticulitermes flavipe (Reticulitermesflavipes)，Reticulitermes flavipe (Reticulitermessantonensis)，Reticulitermes flavipe (Reticulitermeslucifugus)，Mastotermes darwiniensis (Mastotermesdarwiniensis)，Nevada Gu Coptotermes formosanus Shtrari. (Zootermopsisnevadensis)，Workers of Coptotermes formosanus Shiraki (Coptotermesformosanus).
Thread tail order, such as Lepisma saccarina (Lepismasaccharina).
Industrial materials herein are understood to mean that non-living material such as preferred polymers, binding agent, glue, paper and plate, leather, timber, timber-work and coating.It is intended to protect it from the material particularly preferably timber of insect infestations and woodworking article.
Timber and woodworking article that available Pesticidal combination of the present invention or the mixture containing said composition are protected are understood to mean that such as:
Construction timber, wooden frame, railroad tie, bridge member, breakwater, wooden vehicles, box, pallet, container, phone mast, timber partition, wooden window and door, plywood, create card, joinery, or be generally used for building construction or the joiner's timber-work of building.
Pesticidal combination can former state, use with the form of concentrate or conventional formulation such as powder, granule, solution, suspending agent, Emulsion or paste.
Above-mentioned preparation can be prepared in a way known, for instance by by reactive compound and at least one solvent or diluent, emulsifying agent, dispersant and/or binding agent or fixative, waterproofing agent, need time desiccant and UV stabilizer and coloring agent when needing and pigment and other processing aids mix.
Pesticidal combination or concentrate for protecting timber and timber-work contains the reactive compound of the present invention that concentration is 0.0001-95wt%, particularly 0.01-60wt%.
The consumption of compositions or concentrate depends on the kind of insecticide and quantity and medium.Optimum amount in all cases can be determined by dispenser campaign, but the reactive compound according to the materials'use 0.0001-20wt% of desire protection, preferred 0.001-10wt% is generally sufficient.
The Pesticidal combination of the present invention is also applied for preventing and treating and closes the animal pest, particularly insecticide, Aranea and acarid in space, described closing space such as house, factory floor, office, cabin etc..They can be used for preventing and treating these insects in domestic insecticide products, and they are to sensitive and resistance kind and all of stage of development is had activity.These insects include:
Scorpionida, for instance pincers exhaust (Buthusoccitanus).
Acarina, for instance adobe tick, stick up edge sharp-edged Ticks, Bryobia, Dermanyssus gallinae, family food sweet demodicid mite, tampan tick, brown dog tick, trombiculid (Trombiculaalfreddugesi), Neutrombiculaautumnalis, dermatophagoides pteronyssinus, dust mite.
Araneida, for instance cockle spider section, Yuan Zhu section.
Opiliones, for instance intend scorpion class (Pseudoscorpioneschelifer), Pseudoscorpionescheiridium, Opilionesphalangium.
Isopoda, for instance tide worm, Armadillidium.
Foot order again, for instance tool zebra land, mountain cricket Eimeria.
Lip foot order, for instance DIWUGONG belongs to.
Zygentoma order, for instance comb lepismae saccharinae genus, Lepisma saccarina, Lepismodesinquilinus.
Blattaria, for instance oriental cockroach, Groton bug, Blatella (Blattel1aasahinai), leucophaea maderae, angle abdomen Lian genus, wood Lian genus, Australian cockroach, periplaneta americana, the big Lian of brown patch, Peroplaneta fluligginosa, long hair cockroach.
Saltatoria, for instance family Shuai.
Dermaptera, for instance European earwig.
Isoptera, for instance kalotermitid belongs to, Reticulitermes.
Worm order, for instance Lepinatus belongs to, powder breathes heavily Eimeria.
Coleoptera, for instance Anthrenus, fur moth belongs to, and khapra beetle belongs to, long head lesser grain borer, hidden instep cuckoo Eimeria, Ptinus, lesser grain borer, grain weevil, rice weevil, sitophilus zea-mais, Stegobium paniceum.
Diptera, for instance Aedes aegypti, Aedes albopictus, Aedestaeniorhynchus, Anopheles, calliphora erythrocephala, great number sarcophagid, Culex quinquefasciatus, sharp and rounded sounds storehouse grave, Culextarsalis, slow-witted fly belongs to, Fannia canicularis, housefly, Bai Ling belongs to, sarcophagid (Sarcophagacarnaria), Simulium, male servant chela fly, daddy-longlegs (Tipulapaludosa).
Lepidoptera, for instance lesser wax-moth, galleria mellonella waxmoth, India Gu phycitid, rain moth, bag rain moth, curtain rain moth.
Siphonaptera, for instance dog comb head louse, Ctenocephalides felis felis, humanlice, chigo, Xanthopsyllacheopis.
Hymenoptera, for instance blazoning back of a bow ant, bright hair ant, black wool ant, Lasiusumbratus, MonomoriumMayr, Paravespula belongs to, Pavement Ant.
Anoplura, for instance head louse, body louse, pubic louse.
Heteroptera, for instance cimex hemipterus, bed bug, phodnius prolixus, invade and harass vertebra and hunt stinkbug.
The Pesticidal combination of the present invention can as aerosol, without pressure spray product such as pump spraying and atomizer spray, automatic mist formation system, aerosol generator, foam, gel, there is cellulose or vaporizer that the vaporizer product of evaporating plate, liquid evaporator, gel and film evaporator, propeller that polymer is made drive, do not consume energy or passive type vapo(u)rization system, catch baby's worm paper, catch moth bag and insect-catching glue, as drawing agent or powder, in the bait formulation that sprays or bait formulation position.
Example of formulations
Embodiment 1:2% Biphenthrin+10% indoxacarb suspending agent
Biphenthrin 2%
Indoxacarb 10%
Methyl naphthalene sulfonate formaldehyde condensate 10%
Xanthan gum 1%
Bentonite 1%
Glycerol 5%
Water complements to 100%
By each components such as active component, dispersant, wetting agent and the water ratio mix homogeneously according to formula, ground and/or after high speed shear, obtain 2% Biphenthrin+10% indoxacarb suspending agent.
Embodiment 220% Biphenthrin+4% indoxacarb wettable powder
Biphenthrin 20%
Indoxacarb 4%
Sodium lauryl sulphate 2%
Sodium lignin sulfonate 5%
White carbon 10%
Kaolin complements to 100%
Active component, various auxiliary agent and filler etc. are pressed the proportional components mixing of formula, after ultra-fine pulverizer disintegrating, namely obtains 20% Biphenthrin+4% indoxacarb wettable powder.
Embodiment 30.2% Biphenthrin+20% indoxacarb aqueous emulsion
Biphenthrin 0.2%
Indoxacarb 20%
N-Methyl pyrrolidone 15%
Calcium dodecyl benzene sulfonate 5%
Ethoxylated castor oil 5%
Water complements to 100%
Former medicine, solvent, emulsifying agent are added together, make to be dissolved into homogeneous oil phase；Water-soluble component and water are mixed and prepares aqueous phase；Under high velocity agitation, oil phase is mixed with water, prepare 0.2% Biphenthrin+20% indoxacarb aqueous emulsion.
Embodiment 43.5% Biphenthrin+1.5% indoxacarb water dispersible granule
Biphenthrin 3.5%
Indoxacarb 1.5%
Sodium lignin sulfonate 4%
Sodium lauryl sulphate 5%
White Carbon black 10%
Kaolin complements to 100%
By active component, dispersant, wetting agent, disintegrating agent and filler in the ratio mix homogeneously of formula, become wettable powder through comminution by gas stream, add a certain amount of water mixing extruding and make material.3.5% Biphenthrin+1.5% indoxacarb water dispersible granule is obtained after drying screening.
Embodiment 520% Biphenthrin+0.2% indoxacarb suspending agent
Biphenthrin 20%
Indoxacarb 0.2%
Methyl naphthalene sulfonate formaldehyde condensate 10%
Xanthan gum 1%
Bentonite 1%
Glycerol 5%
Water complements to 100%
By each components such as active component, dispersant, wetting agent and water in the ratio mix homogeneously of formula, ground and/or after high speed shear, obtain 20% Biphenthrin+0.2% indoxacarb suspending agent.
Embodiment 67.5% Biphenthrin+2.5% indoxacarb suspending agent
Biphenthrin 7.5%
Indoxacarb 2.5%
Methyl naphthalene sulfonate formaldehyde condensate 5%
Xanthan gum 1%
Bentonite 1%
Glycerol 5%
Water complements to 100%
By each components such as active component, dispersant, wetting agent and water in the ratio mix homogeneously of formula, ground and/or after high speed shear, obtain 7.5% Biphenthrin+2.5% indoxacarb suspending agent.
Embodiment 71% Biphenthrin+10% indoxacarb wettable powder
Biphenthrin 1%
Indoxacarb 10%
Sodium lauryl sulphate 10%
Sodium lignin sulfonate 5%
White carbon 10%
Kaolin complements to 100%
Said components is mixed in proportion, and grinds, pulverize, prepare into wettable powder.
Embodiment 850% Biphenthrin+1% indoxacarb suspending agent
Biphenthrin 50%
Indoxacarb 1%
Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthan gum 1%
Bentonite 1%
Glycerol 5%
Water complements to 100%
Above-mentioned each component is mixed in proportion, and through sand milling, prepares into suspending agent.
Embodiment 930% Biphenthrin+20% indoxacarb aqueous emulsion
Oil phase:
Biphenthrin 30%
Indoxacarb 20%
Methyl oleate 38%
Polystyrene 3.7%
Aqueous phase:
Xanthan gum 0.07%
The sodium salt 1% of the LOMAR PWA EINECS 246-676-2-formaldehyde condensation products of sulfonation
Antibacterial 0.2%
Water complements to 100%
Biphenthrin and indoxacarb are dissolved in methyl oleate, add polystyrene and obtain oil phase；Aqueous phase is obtained according to the component mix homogeneously in formula；Under agitation oil phase is added aqueous phase and obtain aqueous emulsion.
Embodiment 1020% Biphenthrin+1% indoxacarb wettable powder
Biphenthrin 20%
Indoxacarb 1%
Sodium lignin sulfonate 4%
Sodium lauryl sulfate 2%
The silicic acid 1% of high degree of dispersion
Kaolin complements to 100%
Said components is mixed in proportion, and grinds, pulverize, prepare into wettable powder.
Embodiment 111% Biphenthrin+20% indoxacarb coated granule
Biphenthrin 1%
Indoxacarb 20%
Polyethylene Glycol 3%
The silicic acid 1% of high degree of dispersion
Calcium carbonate complements to 100%
In a mixer, by levigate active component even spread to by the carrier of Polyethylene Glycol moistening.Dust-free coated granules agent can be obtained in this way.
Embodiment 1260% Biphenthrin+20% indoxacarb wettable powder
Biphenthrin 60%
Indoxacarb 20%
Sodium lauryl sulphate 3%
Sodium lignin sulfonate 3%
White carbon 5%
Kaolin complements to 100%
Said components is mixed in proportion, and grinds, pulverize, prepare into wettable powder.
Embodiment 1320% Biphenthrin+40% indoxacarb extrusion granule
Biphenthrin 20%
Indoxacarb 40%
Sodium lignin sulfonate 4%
Carboxymethyl cellulose 2%
Kaolin complements to 100%
Active component is mixed with auxiliary agent and grinds, mixture water-wet.This mixture is extruded, then dries in the air stream.
Embodiment 141% Biphenthrin+50% indoxacarb suspending agent
Biphenthrin 1%
Indoxacarb 50%
Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthan gum 1%
Bentonite 1%
Glycerol 5%
Water complements to 100%
Above-mentioned each component is mixed in proportion, and through sand milling, prepares into suspending agent.
Embodiment 1510% Biphenthrin+20% indoxacarb microcapsule suspension-suspendinagent agent
ATLOXTM49134%
Citric acid 0.05%
Catalyst 0.1%
Water 13%
Biphenthrin 10%
PAPI1.35%
Methyl oleate 5%
ATLOXTM491316%
Dispersant LFH0.3%
Defoamer 0.16%
Carbamide 8.4%
Indoxacarb 20%
Water complements to 100%
Oil phase PAPI, indoxacarb and methyl oleate formed adds containing ATLOXTMIn the aqueous solution of 4913, form emulsion.Then heating insulation are 50oCatalyst reaction is added 2 hours under C.The microcapsule of indoxacarb is obtained after cooling.
ATLOXTM4913, dispersant LFH, defoamer, carbamide, Biphenthrin and water mix in proportion, and through sand milling, prepare into suspending agent.
The microcapsule of the indoxacarb obtained is added in the aqueous suspension agent of Biphenthrin, be uniformly mixing to obtain 10% Biphenthrin+20% indoxacarb microcapsule suspension suspending agent.
Embodiment 165% Biphenthrin+15% indoxacarb suspended emulsion
Biphenthrin 5%
Indoxacarb 15%
SOLVESSOTM20030%
Ethoxylated castor oil 4%
Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthan gum 1%
Bentonite 1%
Glycerol 5%
Water complements to 100%
Biphenthrin is dissolved in SOLVESSOTMIn 200, add ethoxylated castor oil, obtain the cream of Biphenthrin；By indoxacarb, fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium, above-mentioned each component mixes in proportion, and through sand milling, prepares into suspending agent.
Oil phase containing Biphenthrin is joined in the suspending agent containing indoxacarb, obtains suspended emulsion.
Embodiment 1710% Biphenthrin+10% indoxacarb cream
Biphenthrin 10%
Indoxacarb 10%
Ethoxylated castor oil 5%
Calcium dodecyl benzene sulfonate 3%
SOLVESSOTM100 complement to 100%
Above-mentioned each component being mixed, stirring is to obtaining transparent homogeneous phase.
Embodiment 181% Biphenthrin+0.01% indoxacarb bait grain
Biphenyl polyester 1%
Indoxacarb 0.01%
Bait 60%
Corn starch complements to 100%
After said components mix homogeneously, become wettable powder through comminution by gas stream, add a certain amount of water mixing extruding and make material acquisition bait grain.
Embodiment 190.05% Biphenthrin+0.05% indoxacarb bait grain
Biphenyl polyester 0.05%
Indoxacarb 0.05%
Bait 80%
Corn starch complements to 100%
After said components mix homogeneously, become wettable powder through comminution by gas stream, add a certain amount of water mixing extruding and make material acquisition bait grain.
Embodiment 205% Biphenthrin+5% indoxacarb suspension seed-coating agent
Biphenthrin 5%
Indoxacarb 5%
Fatty alcohol-polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthan gum 1%
Bentonite 1%
Glycerol 5%
PVP-K301%
Water complements to 100%
Above-mentioned each component is mixed in proportion, and through sand milling, prepares into suspension seed-coating agent.
Embodiment 2150% Biphenthrin+50% indoxacarb
Biphenthrin 50%
Indoxacarb 50%
By Biphenthrin and indoxacarb proportionally mix homogeneously.
Biological test example
The good parasite killing of a kind of Pesticidal combination of the present invention and kill acarid effect and be found in the following example.Although independent reactive compound shows shortcoming in it acts on, but compositions exhibits more than the effect simply adding sum of each effect.When the effect of active compound combinations exceedes the summation of the effect when each reactive compound is individually used, there is collaborative parasite killing and acaricidal action.The predictive role of the particular combination of two kinds of reactive compounds can use so-called " Colby formula " (referring to S.R.Colby, " CalculatingSynergisticandAntagonisticResponsesofHerbicid eCombinations ", Weeds1967,15,20-22) calculated as below: if
X kills rate when to use consumption be mg/ha or reactive compound A that concentration is mppm, is expressed as accounting for the percentage rate of untreated control,
Y kills rate when to use consumption be ng/ha or reactive compound B that concentration is nppm, is expressed as accounting for the percentage rate of untreated control,
E kills rate when to use consumption be m and ng/ha or reactive compound A and B that concentration is m and nppm, is expressed as accounting for the percentage rate of untreated control,
So
If the parasite killing fatality rate of reality exceedes value of calculation, then the lethal effect of compositions is to surpass to add sum, namely there is synergism.In this case, the rate of killing actually observed must be over the value using the expection that above-mentioned formula calculates to kill rate value (E).
Test example 1
Tea lesser leafhopper is tested
Solvent 7 weight portion dimethylformamide
Emulsifying agent 2 weight portion alkaryl polyglycol ether
For manufacturing the appropriate formulation of reactive compound, 1 Parts by weight Active compound solvent with described amount and emulsifying agent are mixed, with water, concentrate is diluted to desired concn.
By being impregnated in the active agent preparations wishing concentration by the Folium Camelliae sinensis of tea lesser leafhopper severe infections, it is processed.
After the desired time, measure mortality rate %.100% represents that all tea lesser leafhoppers are killed；0% indicates and is killed without tea lesser leafhopper.The mortality rate measured uses " Colby formula " to be calculated.
Show in this test, for instance compared with individually using with reactive compound, the activity of the Pesticidal combination display Synergistic of the present invention.
Table 1
The activity of the *=discovery found
The * calculated=be suitable for the activity that Colby formula calculates
Test example 2
Bollworm is tested
Solvent 7 weight portion dimethylformamide
Emulsifying agent 2 weight portion alkaryl polyglycol ether
For manufacturing the appropriate formulation of reactive compound, 1 Parts by weight Active compound solvent with described amount and emulsifying agent are mixed, with water, concentrate is diluted to desired concn.
By being impregnated in the active agent preparations wishing concentration by the cotton leaf of bollworm severe infections, it is processed.
After the desired time, measure mortality rate %.100% represents that all bollworms are killed；0% indicates and is killed without bollworm.The mortality rate measured uses " Colby formula " to be calculated.
Show in this test, for instance compared with individually using with reactive compound, the activity of the Pesticidal combination display Synergistic of the present invention.
Table 2
The activity of the *=discovery found
The * calculated=be suitable for the activity that Colby formula calculates
Test example 3
Red spider is tested
Solvent 7 weight portion dimethylformamide
Emulsifying agent 2 weight portion alkaryl polyglycol ether
For manufacturing the appropriate formulation of reactive compound, 1 Parts by weight Active compound solvent with described amount and emulsifying agent are mixed, with water, concentrate is diluted to desired concn.
By being impregnated in the active agent preparations wishing concentration by the Citrus leaves of red spider severe infections, it is processed.
After the desired time, measure mortality rate %.100% represents that all red spiders are killed；0% indicates and is killed without red spider.The mortality rate measured uses " Colby formula " it is calculated.
Show in this test, for instance compared with individually using with reactive compound, the activity of the Pesticidal combination display Synergistic of the present invention.
Table 3
The activity of the *=discovery found
The * calculated=be suitable for the activity that Colby formula calculates
Test example 4
Trialeurodes vaporariorum is tested
Solvent 7 weight portion dimethylformamide
Emulsifying agent 2 weight portion alkaryl polyglycol ether
For manufacturing the appropriate formulation of reactive compound, 1 Parts by weight Active compound solvent with described amount and emulsifying agent are mixed, with water, concentrate is diluted to desired concn.
By being impregnated in the active agent preparations wishing concentration by the tomato leaf of trialeurodes vaporariorum severe infections, it is processed.
After the desired time, measure mortality rate %.100% represents that all trialeurodes vaporariorums are killed；0% indicates and is killed without trialeurodes vaporariorum.The mortality rate measured uses " Colby formula " it is calculated.
Show in this test, for instance compared with individually using with reactive compound, the activity of the Pesticidal combination display Synergistic of the present invention.
Table 4
The activity of the *=discovery found
The * calculated=be suitable for the activity that Colby formula calculates
Test example 5
Diamondback moth is tested
Solvent 7 weight portion dimethylformamide
Emulsifying agent 2 weight portion alkaryl polyglycol ether
For manufacturing the appropriate formulation of reactive compound, 1 Parts by weight Active compound solvent with described amount and emulsifying agent are mixed, with water, concentrate is diluted to desired concn.
By being impregnated in the active agent preparations wishing concentration by the cabbage leaves of diamondback moth severe infections, it is processed.
After the desired time, measure mortality rate %.100% represents that all diamondback moths are killed；0% indicates and is killed without diamondback moth.The mortality rate measured uses " Colby formula " it is calculated.
Show in this test, for instance compared with individually using with reactive compound, the activity of the Pesticidal combination display Synergistic of the present invention.
Table 5
The activity of the *=discovery found
The * calculated=be suitable for the activity that Colby formula calculates
Test example 6
Fly is tested
Solvent 7 weight portion dimethylformamide
Emulsifying agent 2 weight portion alkaryl polyglycol ether
For manufacturing the appropriate formulation of reactive compound, 1 Parts by weight Active compound solvent with described amount and emulsifying agent are mixed, with water, concentrate is diluted to desired concn.
A certain amount of fly worm is placed in the space of each closing.With the reactive compound wishing concentration, it is processed.
After the desired time, measure mortality rate %.100% represents that all flies are killed；0% indicates and is killed without fly.The mortality rate measured uses " Colby formula " it is calculated.
Show in this test, for instance compared with individually using with reactive compound, the activity of the Pesticidal combination display Synergistic of the present invention.
Table 6
The activity of the *=discovery found
The * calculated=be suitable for the activity that Colby formula calculates
Test example 7
Coptotermes formosanus Shtrari. is tested
Solvent 7 weight portion dimethylformamide
Emulsifying agent 2 weight portion alkaryl polyglycol ether
For manufacturing the appropriate formulation of reactive compound, 1 Parts by weight Active compound solvent with described amount and emulsifying agent are mixed, with water, concentrate is diluted to desired concn.
It will be processed in the active agent preparations wish concentration by the timber pickling of Coptotermes formosanus Shtrari. Eroded.
After the desired time, measure mortality rate %.100% represents that all Coptotermes formosanus Shtrari. are killed；0% indicates and is killed without Coptotermes formosanus Shtrari..The mortality rate measured uses " Colby formula " it is calculated.
Show in this test, for instance compared with individually using with reactive compound, the activity of the Pesticidal combination display Synergistic of the present invention.
Table 7
The activity of the *=discovery found
The * calculated=be suitable for the activity that Colby formula calculates.
Claims (19)
1. a Pesticidal combination, it is characterised in that: active component is made up of Biphenthrin and indoxacarb, and wherein the weight ratio of Biphenthrin and indoxacarb is 1:100 to 100:1.
2. a kind of Pesticidal combination according to claim 1, it is characterised in that: the weight ratio of described Biphenthrin and indoxacarb is 1:50 to 50:1.
3. a kind of Pesticidal combination according to claim 1, it is characterised in that: the weight ratio of described Biphenthrin and indoxacarb is 1:20 to 20:1.
4. a kind of Pesticidal combination according to claim 1, it is characterised in that: the weight ratio of described Biphenthrin and indoxacarb is 1:10 to 10:1.
5. a kind of Pesticidal combination according to claim 1, it is characterised in that: the weight ratio of described Biphenthrin and indoxacarb is 1:5 to 5:1.
6. a kind of Pesticidal combination according to claim 1, it is characterised in that: described Biphenthrin and indoxacarb account for described compositions 0.5% to 100% by weight altogether.
7. a kind of Pesticidal combination according to claim 1, it is characterised in that: described Biphenthrin and indoxacarb account for described compositions 1% to 80% by weight altogether.
8. a kind of Pesticidal combination according to claim 1, it is characterised in that: described Biphenthrin and indoxacarb account for described compositions 5% to 60% by weight altogether.
9. a kind of Pesticidal combination according to claim 1, it is characterised in that: also comprise carrier and/or surfactant.
10. a kind of Pesticidal combination according to claim 1, it is characterised in that: dosage form is: suspending agent, microcapsule, cream, suspending agent, water dispersible granules, wettable powder, suspension emulsion, aqueous emulsion, suspension seed-coating agent, granule, bait grain.
11. the Pesticidal combination described in claim 1 is for preventing or control the purposes of agricultural pests.
12. the Pesticidal combination described in claim 1 is for preventing or control to attack the purposes of the agricultural pests of plant or plant propagation material.
13. purposes according to claim 11, it is characterised in that: described agricultural pests are bollworm, small heart-eating peach worm, oriental fruit months, tetranychus viennensis, Citrus chachiensis Hort. macula lutea stinkbug, eating attraction, vegetable aphid, Pieris rapae, diamondback moth, red spider, the thin moth of tea, trialeurodes vaporariorum, tea geometrid, Euproctis pseudoconspersa, leafhopper, beet armyworm, Pieris rapae, Prodenia litura, lopper worm, oriental tobacco budworm, carpocapsa pononella, diamond, beetle.
14. purposes according to claim 12, it is characterised in that: described plant propagation material is seedling, rhizome, garden Seedling, cutting or seed.
15. a prevention or the method controlling agricultural pests, it is characterised in that: the Pesticidal combination described in claim 1 is acted on target agricultural pests and/or its environment.
16. one kind protect plant in case agricultural pests invasion and attack method, it is characterised in that: the propagating materials of the Pesticidal combination described in claim 1 with target useful plant, target agricultural pests and/or its environment, target useful plant is contacted.
17. the method protecting plant seed, it is characterised in that: it includes making seed prior to seeding and/or contacting with the Pesticidal combination described in claim 1 after accelerating germination.
18. the Pesticidal combination described in claim 1 prevents or controls the purposes of sanitary insect pest.
19. a prevention or the method controlling sanitary insect pest, it is characterised in that: the Pesticidal combination described in claim 1 is applied to target sanitary insect pest and/or its environment.
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| CN201410835491.1A CN105794831B (en) | 2014-12-30 | 2014-12-30 | A kind of Pesticidal combination and application thereof |
| CN201711426135.4A CN107897202A (en) | 2014-12-30 | 2014-12-30 | A kind of Pesticidal combination and application thereof |
| PCT/CN2015/099649 WO2016107568A1 (en) | 2014-12-30 | 2015-12-30 | Insecticidal composition and uses thereof |
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| CN108294052A (en) * | 2018-02-12 | 2018-07-20 | 平南县兴民龙藤茶业专业合作社 | A kind of Synergistic insecticidal composition of prevention tea geometrid |
| CN108294056A (en) * | 2018-02-12 | 2018-07-20 | 平南县兴民龙藤茶业专业合作社 | A kind of synergetic pesticide composition of prevention tea geometrid |
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| TW202200008A (en) * | 2020-03-17 | 2022-01-01 | 美商富曼西公司 | Processes for preparing suspension concentrate formulations comprising pesticidal mixtures |
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| CN108294056A (en) * | 2018-02-12 | 2018-07-20 | 平南县兴民龙藤茶业专业合作社 | A kind of synergetic pesticide composition of prevention tea geometrid |
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| CN105794831B (en) | 2018-12-18 |
| CN107897202A (en) | 2018-04-13 |
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