CN105778586A - 一种光固化漆 - Google Patents
一种光固化漆 Download PDFInfo
- Publication number
- CN105778586A CN105778586A CN201610285522.XA CN201610285522A CN105778586A CN 105778586 A CN105778586 A CN 105778586A CN 201610285522 A CN201610285522 A CN 201610285522A CN 105778586 A CN105778586 A CN 105778586A
- Authority
- CN
- China
- Prior art keywords
- parts
- paint
- curing
- photo
- photocuring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003973 paint Substances 0.000 title claims abstract description 21
- 238000000016 photochemical curing Methods 0.000 title claims abstract description 18
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 24
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 24
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 10
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims abstract description 8
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims abstract description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 9
- 229910052802 copper Inorganic materials 0.000 claims description 9
- 239000010949 copper Substances 0.000 claims description 9
- 239000002105 nanoparticle Substances 0.000 claims description 9
- OQOGEOLRYAOSKO-UHFFFAOYSA-N 1,1-dichloro-1-nitroethane Chemical compound CC(Cl)(Cl)[N+]([O-])=O OQOGEOLRYAOSKO-UHFFFAOYSA-N 0.000 claims description 7
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 239000011863 silicon-based powder Substances 0.000 claims description 7
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 4
- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 claims description 4
- YLHXLHGIAMFFBU-UHFFFAOYSA-N methyl phenylglyoxalate Chemical compound COC(=O)C(=O)C1=CC=CC=C1 YLHXLHGIAMFFBU-UHFFFAOYSA-N 0.000 claims description 4
- 244000028419 Styrax benzoin Species 0.000 claims description 2
- 235000000126 Styrax benzoin Nutrition 0.000 claims description 2
- 235000008411 Sumatra benzointree Nutrition 0.000 claims description 2
- 229960002130 benzoin Drugs 0.000 claims description 2
- 235000019382 gum benzoic Nutrition 0.000 claims description 2
- 238000001723 curing Methods 0.000 abstract description 7
- 238000005260 corrosion Methods 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 4
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000010422 painting Methods 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- VBHXIMACZBQHPX-UHFFFAOYSA-N 2,2,2-trifluoroethyl prop-2-enoate Chemical compound FC(F)(F)COC(=O)C=C VBHXIMACZBQHPX-UHFFFAOYSA-N 0.000 abstract 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 abstract 1
- 230000009965 odorless effect Effects 0.000 abstract 1
- -1 perfluoroalkyl ethyl methacrylate Chemical compound 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000011527 polyurethane coating Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
本发明涉及涂料技术领域，具体是关于一种光固化漆，按重量份数计包括以下组分：全氟烷基乙基甲基丙烯酸酯50‑60份、甲基丙烯酰胺25‑35份、三羟甲基丙烷三丙烯酸酯10‑14份、乙酸乙酯20‑25份、正硅酸乙酯20‑30份、乙二醇20‑30份、丙烯酸三氟乙酯5‑10份、光引发剂0.5‑2份、纳米铜粉5‑7份、硅微粉5‑6份。本发明固化速度快，可在常温固化，生产效率高，制造方便、固化产物性能好，固化后制得的试样具有优异的附着力、抗划伤性及耐腐蚀性，涂装形成的漆膜成亚光色、成膜厚且广、硬度高、环保无气味、固化速度快，同时也具有在零摄氏度下固化的特性。
Description
技术领域
本发明涉及涂料技术领域，具体是关于一种光固化漆。
背景技术
丙烯酸聚氨酯涂料主要成膜物质含羟基树脂，因其具有优良物理机械能力和优良的保光、保色、耐候性等特点而广泛应用于高耐化学性能的产品外壳的涂装，例如该热固性光固化罩光漆可以用于包装、一般工业的涂装体系中，例如广泛应用于自行车、摩托车、汽车、电冰箱、洗衣机、电风扇、仪器、仪表、精密机械和IT产品表面的涂装。
由于施加的表层涂层在光滑度和光泽度方面需具有出色的外观，并且需具有出色的耐腐蚀性，因而需要重施用的涂层具有出色的附着性，即出色的再涂附着性。然而，现有技术中已知的热固性丙烯酸涂料组合物，难以形成同时具有出色外观、耐腐蚀、耐高温、耐磨且附着性强的表层涂层。
发明内容
为了解决现有技术中的上述技术问题，本发明的目的在于提供一种具有固化快和环保无气味的光固化漆。
为了实现上述发明目的，本发明所述的一种光固化漆，按重量份数计包括以下组分：全氟烷基乙基甲基丙烯酸酯50-60份、甲基丙烯酰胺25-35份、三羟甲基丙烷三丙烯酸酯10-14份、乙酸乙酯20-25份、正硅酸乙酯20-30份、乙二醇20-30份、丙烯酸三氟乙酯5-10份、光引发剂0.5-2份、纳米铜粉5-7份、硅微粉5-6份。
进一步的，所述光固化漆，按重量份数计包括以下组分：全氟烷基乙基甲基丙烯酸酯54份、甲基丙烯酰胺30份、三羟甲基丙烷三丙烯酸酯11份、乙酸乙酯22份、正硅酸乙酯25份、乙二醇25份、丙烯酸三氟乙酯8份、光引发剂1.5份、纳米铜粉5.5份、硅微粉5-6份。
进一步的，所述光引发剂采用安息香双甲醚、2-羟基-2-甲基-1-苯基丙酮（UV-1173）和苯甲酰甲酸甲酯（MBF）中一种或多种。
进一步的，所述纳米铜粉粒度为900-1000目。
与现有技术相比，本发明具有以下有益效果：本发明固化速度快，可在常温固化，生产效率高，制造方便、固化产物性能好，固化后制得的试样具有优异的附着力、抗划伤性及耐腐蚀性，涂装形成的漆膜成亚光色、成膜厚且广、硬度高、环保无气味、固化速度快，同时也具有在零摄氏度下固化的特性。
具体实施方式
以下对本发明的优选实施例进行详细的描述。
实施例1
一种光固化漆，按重量份数计包括以下组分：全氟烷基乙基甲基丙烯酸酯50份、甲基丙烯酰胺25份、三羟甲基丙烷三丙烯酸酯10份、乙酸乙酯20份、正硅酸乙酯20份、乙二醇20份、丙烯酸三氟乙酯5份、光引发剂0.5份、纳米铜粉5份、硅微粉5份。
实施例2
一种光固化漆，按重量份数计包括以下组分：全氟烷基乙基甲基丙烯酸酯54份、甲基丙烯酰胺30份、三羟甲基丙烷三丙烯酸酯11份、乙酸乙酯22份、正硅酸乙酯25份、乙二醇25份、丙烯酸三氟乙酯8份、光引发剂1.5份、纳米铜粉5.5份、硅微粉5-6份。
实施例3
一种光固化漆，按重量份数计包括以下组分：全氟烷基乙基甲基丙烯酸酯60份、甲基丙烯酰胺35份、三羟甲基丙烷三丙烯酸酯14份、乙酸乙酯25份、正硅酸乙酯30份、乙二醇30份、丙烯酸三氟乙酯10份、光引发剂2份、纳米铜粉7份、硅微粉6份。
尽管这里参照本发明的解释性实施例对本发明进行了描述，上述实施例仅为本发明较佳的实施方式，本发明的实施方式并不受上述实施例的限制，应该理解，本领域技术人员可以设计出很多其他的修改和实施方式，这些修改和实施方式将落在本申请公开的原则范围和精神之内。
Claims (4)
1.一种光固化漆，其特征在于：按重量份数计包括以下组分：全氟烷基乙基甲基丙烯酸酯50-60份、甲基丙烯酰胺25-35份、三羟甲基丙烷三丙烯酸酯10-14份、乙酸乙酯20-25份、正硅酸乙酯20-30份、乙二醇20-30份、丙烯酸三氟乙酯5-10份、光引发剂0.5-2份、纳米铜粉5-7份、硅微粉5-6份。
2.根据权利要求1所述光固化漆，其特征在于：按重量份数计包括以下组分：全氟烷基乙基甲基丙烯酸酯54份、甲基丙烯酰胺30份、三羟甲基丙烷三丙烯酸酯11份、乙酸乙酯22份、正硅酸乙酯25份、乙二醇25份、丙烯酸三氟乙酯8份、光引发剂1.5份、纳米铜粉5.5份、硅微粉5-6份。
3.根据权利要求1所述光固化漆，其特征在于：所述光引发剂采用安息香双甲醚、2-羟基-2-甲基-1-苯基丙酮（UV-1173）和苯甲酰甲酸甲酯（MBF）中一种或多种。
4.根据权利要求1所述光固化漆，其特征在于：所述纳米铜粉粒度为900-1000目。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610285522.XA CN105778586A (zh) | 2016-05-04 | 2016-05-04 | 一种光固化漆 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610285522.XA CN105778586A (zh) | 2016-05-04 | 2016-05-04 | 一种光固化漆 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105778586A true CN105778586A (zh) | 2016-07-20 |
Family
ID=56400440
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610285522.XA Pending CN105778586A (zh) | 2016-05-04 | 2016-05-04 | 一种光固化漆 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105778586A (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106590444A (zh) * | 2016-11-30 | 2017-04-26 | 四川中塑高分子材料有限公司 | 一种耐酸碱运动地板胶粘剂 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5073585A (en) * | 1987-08-14 | 1991-12-17 | Basf Aktiengesellschaft | Aqueous coating materials based on secondary dispersions of carboxyl-containing copolymers of acrylates or methacrylates |
| CN101787238A (zh) * | 2009-12-31 | 2010-07-28 | 江南大学 | 一种高耐污隔热型uv固化氟涂料的制备方法 |
| CN103305044A (zh) * | 2013-06-17 | 2013-09-18 | 丹阳市佳美化工有限公司 | 光固化罩光漆 |
| JP2014098088A (ja) * | 2012-11-14 | 2014-05-29 | Toagosei Co Ltd | 活性エネルギー線硬化型金属防蝕コーティング剤組成物 |
| CN104194613A (zh) * | 2014-08-13 | 2014-12-10 | 江苏宏泰高分子材料有限公司 | 可重涂的紫外光固化彩色一涂银粉涂料及其制备方法 |
-
2016
- 2016-05-04 CN CN201610285522.XA patent/CN105778586A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5073585A (en) * | 1987-08-14 | 1991-12-17 | Basf Aktiengesellschaft | Aqueous coating materials based on secondary dispersions of carboxyl-containing copolymers of acrylates or methacrylates |
| CN101787238A (zh) * | 2009-12-31 | 2010-07-28 | 江南大学 | 一种高耐污隔热型uv固化氟涂料的制备方法 |
| JP2014098088A (ja) * | 2012-11-14 | 2014-05-29 | Toagosei Co Ltd | 活性エネルギー線硬化型金属防蝕コーティング剤組成物 |
| CN103305044A (zh) * | 2013-06-17 | 2013-09-18 | 丹阳市佳美化工有限公司 | 光固化罩光漆 |
| CN104194613A (zh) * | 2014-08-13 | 2014-12-10 | 江苏宏泰高分子材料有限公司 | 可重涂的紫外光固化彩色一涂银粉涂料及其制备方法 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106590444A (zh) * | 2016-11-30 | 2017-04-26 | 四川中塑高分子材料有限公司 | 一种耐酸碱运动地板胶粘剂 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| MY193339A (en) | Transparent resin substrate | |
| CN105263967A (zh) | 包含硅氧烷低聚物和无机微粒的固化性组合物 | |
| CN108546540B (zh) | 一种玻璃基材用紫外光固化转印胶的制备方法 | |
| CN108276900A (zh) | 镀膜涂料系统及具有仿陶瓷效果的金属件产品 | |
| CN102161862A (zh) | 一种uv光固化聚氨酯丙烯酸树脂组合物 | |
| CN104559698B (zh) | 一种用于静电喷涂的耐黄变uv透明底漆 | |
| WO2006122308A3 (en) | Antireflective coating compositions and methods for depositing such coatings | |
| CN108084900B (zh) | 一种二维码薄膜及其制备工艺 | |
| CN104448984A (zh) | 一种热固性丙烯酸罩光漆及其制备方法 | |
| IN2015DN01999A (zh) | ||
| CN104356927B (zh) | 一种uv固化抗静电涂料 | |
| CN103396714B (zh) | 真空电镀专用清漆 | |
| CN105778586A (zh) | 一种光固化漆 | |
| CN103992736A (zh) | 水性(uv)紫外光固化木器底着色透明木器涂料及施工工艺 | |
| CN104098942A (zh) | 纳米耐磨涂料及使用该纳米耐磨涂料的地砖 | |
| CN103305044B (zh) | 光固化罩光漆 | |
| CN106010146A (zh) | 免打磨uv底漆 | |
| CN105778587A (zh) | 一种低温光固化漆 | |
| CN102746786A (zh) | 一种紫外光固化弹性亮光面漆涂料及其生产方法 | |
| CN103319970B (zh) | 仿电镀银涂料 | |
| WO2012121401A3 (en) | Nanoimprinting method | |
| CN105820721A (zh) | 一种双组份紫外光光固化涂料 | |
| CN105733416A (zh) | 一种环保型紫外光固化粉末涂料 | |
| CN106634543A (zh) | 一种uv辊涂附着力白底 | |
| CN103911066A (zh) | 铝合金表面高附着力紫外光固化喷涂哑光面漆涂料 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160720 |