CN105777040A - Novel ceramic tile adhesive and preparation method thereof - Google Patents
Novel ceramic tile adhesive and preparation method thereof Download PDFInfo
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- CN105777040A CN105777040A CN201610203817.8A CN201610203817A CN105777040A CN 105777040 A CN105777040 A CN 105777040A CN 201610203817 A CN201610203817 A CN 201610203817A CN 105777040 A CN105777040 A CN 105777040A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
- C04B28/145—Calcium sulfate hemi-hydrate with a specific crystal form
- C04B28/147—Calcium sulfate hemi-hydrate with a specific crystal form beta-hemihydrate
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00637—Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a novel ceramic tile adhesive. The novel ceramic tile adhesive comprises the following components in parts by weight: 20-35 parts of cement, 25-30 parts of heavy calcium carbonate, 15-20 parts of building plaster, 6-15 parts of bentonite, 9.6-12.5 parts of re-dispersible latex powder, 4.53-7.24 parts of propylene fiber, 2.12-4.53 parts of calcium formate, 3.26-5.63 parts of cellulose ether, 2.31-3.64 parts of starch ether, 1.26-2.68 parts of water reducer, 2.44-3.52 parts of defoaming agent and 1.52-2.72 parts of thixotropy lubricating agent. The ceramic tile adhesive is strong in adhesive strength. Meanwhile, the ceramic tile adhesive disclosed by the invention is excellent in water resistance, temperature resistance, and frost thawing resistance and long in service life.
Description
Technical field
The present invention relates to building material field, be specifically related to a kind of novel ceramic tile bond and preparation method thereof.
Background technology
Tile decorative surface system is one of decorative encasing the most frequently used in China's architectural engineering, have strong shock resistance,
The feature such as good endurance, easy cleaning；But also it is often accompanied with infiltration, hollowing, the puzzlement of several big persistent ailments such as come off.
The most domestic do the conventional bonding of tile decorative surface, pointing has: neat slurry, cement mortar, tile bonding
Agent, silica gel etc..Ceramic tile bond is the material playing cementation between ceramic tile and metope, ground etc.,
Also referred to as binder for face brick or glue for tile, be equipped with multiple additives through machine by cement, filler, polymer latex ramming material
Tool mix homogeneously forms.
The cohesive force of existing ceramic tile bond is weak, easily comes off.
Summary of the invention
In view of this, it is an object of the invention to provide a kind of novel ceramic tile bond.This novel ceramic tile bond
Cohesive force is strong.
For achieving the above object, the technical solution used in the present invention is as follows:
Novel ceramic tile bond, includes following components by weight: cement 20-35 part, ground calcium carbonate 25-30
Part, plaster of Paris 15-20 part, bentonite 6-15 part, redispersable latex powder 9.6-12.5 part, poly-third
Alkene fiber 4.53-7.24 part, calcium formate 2.12-4.53 part, cellulose ether 3.26-5.63 part, starch ether
2.31-3.64 part, water reducer 1.26-2.68 part, defoamer 2.44-3.52 part and thixotropic lubricant
1.52-2.72 part.
Further, described novel ceramic tile bond includes following components by weight: cement 28 parts, heavy carbon
Acid calcium 27 parts, plaster of Paris 18 parts, bentonite 12 parts, redispersable latex powder 11.6 parts, polypropylene
Fiber 5.85 parts, calcium formate 3.33 parts, cellulose ether 4.45 parts, starch ether 2.92 parts, water reducer 1.98
Part, defoamer 2.96 parts and thixotropic lubricant 2.12 parts.
Described plaster of Paris is dihydrate gypsum thermal dehydration at a certain temperature, and levigate make with β-half water
Gypsum Fibrosum is the air hardening cementitious materials mainly comprised.Beta-type semi-hydrated gypsum produces the raw material of Gypsum Fibrosum and is mainly sulfur-bearing
The acid natural gypsum (also known as Gypsum Fibrosum) of calcium or the chemical by-product of sulfur acid calcium and ardealite, fluorgypsum,
The waste residues such as boron Gypsum Fibrosum, its chemical formula is CaSO4·2H2O, also referred to as dihydrate gypsum.By natural dihydrate gypsum not
The available different Gypsum Fibrosum kind of calcining at a temperature of Tong.By natural dihydrate gypsum 107-170 DEG C be dried
Under the conditions of heating can obtain plaster of Paris.
Described redispersable latex powder is the spray-dried rear powder body formed of polymer emulsion, also referred to as dry powder glue.
This powder body can be reduced into rapidly emulsion, and the character that holding is identical with initial latex after contact with water,
I.e. after moisture evaporation, this film has high-flexibility, high-weatherability and the high-adhesion to various base materials.
Described calcium formate is also referred to as formic acid calcium, and molecular formula is C2H204Ca, as feed additive, it is adaptable to each
Class animal, has acidifying, mildew-resistant, the effect such as antibacterial, industrial be also used for concrete, grout additive,
The tanning of leather or use as preservative.
Described water reducer is a kind of under conditions of maintaining concrete slump constant, can reduce mixing water amount
Concrete admixture.Mostly belong to anion surfactant, have lignosulfonates, naphthalene sulfonate first
Aldehyde polymer etc..After adding concrete mix, cement granules there is is peptizaiton, its workability can be improved,
Reduce unit consumption of water, improve the mobility of concrete mix；Or minimizing unit cement consumption, save water
Mud.
Further, the particle diameter of described ground calcium carbonate is 80-120 μm.Described ground calcium carbonate is called for short triple superphosphate,
Being ground formed by natural carbonate mineral such as calcite, marble, limestone, the powdery inorganic being conventional is filled out
Material, have that chemical purity is high, inertia big, be difficult to chemical reaction, Heat stability is good, below 400 DEG C not
Decompose, whiteness is high, oil absorbency is low, index of refraction is low, matter is soft, dry, without water of crystallization, the low abrasion of hardness
It is worth the advantages such as little, nontoxic, tasteless, odorless, good dispersion.
Further, described bentonite is mixed according to quality proportioning 4-5:2-3 by sodium bentonite and calcium-base bentonite
Conjunction forms.Described bentonite is the nonmetallic minerals with montmorillonite as main mineral constituent, and smectite structure is
The 2:1 type crystal structure being made up of two silicon-oxy tetrahedron one layer of alumina octahedrals of folder, due to montmorillonite structure cell
There is some cation in the layer structure formed, such as Cu, Mg, Na, K etc., and these cationes with cover de-
The effect of stone structure cell is the most unstable, is easily partially or completely exchanged by other cations, therefore has preferable ion exchangeable.Layer
Between cation be Na+Time claim sodium bentonite；Interlayer cation is Ca2+Time claim calcium-base bentonite；Interlayer sun from
Son is H+Time claim hydrogen-based bentonite (active hargil, natural bleaching soil-Emathlite)；Interlayer cation is organic
Organobentonite is claimed during cation.
Further, the fibre length of described polypropylene fibre is 6-9mm.Described polypropylene fibre is with propylene
The isotactic polypropylene that polymerization obtains is the synthetic fibers of raw material spinning.
Further, it is characterised in that described cellulose ether is hydroxyethyl ether cellulose or hydroxypropylcelluloether ether.
Further, described defoamer is aqueous alkyd resin class defoamer.
Further, described thixotropic lubricant is aluminium-magnesium silicate thixotropic lubricant.Described thixotropic lubricant be through
Special processed, it is adaptable to mineral base (dry mash) system and the powdery rheologic additive of paste system.
Thixotropic lubricant is primarily directed to the improvement of application property in cement based system, open hour and conforming property
Can, increase mortar, plaster, bottom ash, motar and the workability of adhesive and sag resistance, prevent
Self-leveling cement is layered.
The two of the purpose of the present invention are to provide the preparation method of described novel ceramic tile bond agent, and it specifically walks
Suddenly it is:
A. cement, ground calcium carbonate, plaster of Paris and the bentonite of above-mentioned mass parts are put in mixer and stir
Mix 15-18 minute；
B. the redispersable latex powder of above-mentioned mass parts is added in mixture described in step A and stir 3-5 minute；
C. the polypropylene fibre of above-mentioned mass parts, cellulose ether and starch ether are added step B gained mixture
Middle stirring was ground 4-7 minute after 10-15 minute；
D. after calcium formate, defoamer, thixotropic lubricant and the water reducer of above-mentioned mass parts being sequentially added into grinding
Mixture in stir 3-5 minute, obtain described ceramic tile bond.
The present invention also aims to protect described novel ceramic tile bond at concrete mortar metope and ground table
Application in the bonding ceramic tile work progress of face.
The invention has the beneficial effects as follows:
The novel ceramic tile bond cohesive force of the present invention is strong.Meanwhile, the ceramic tile bond of the present invention has excellent
Water-fast, heatproof, freeze-thaw resistance property, service life is strong.
Detailed description of the invention
Embodiment 1
Novel ceramic tile bond, consisting of: the ground calcium carbonate 25kg that cement 35kg, particle diameter are 120 μm,
Plaster of Paris 20kg, bentonite 6kg, redispersable latex powder 12.5kg, fibre length are poly-the third of 9mm
Alkene fiber 4.53kg, calcium formate 4.53kg, hydroxyethyl ether cellulose 5.63kg, starch ether 3.64kg, subtract
Water preparation 1.26kg, aqueous alkyd resin class defoamer 3.52kg and aluminium-magnesium silicate thixotropic lubricant 1.52kg.
Described bentonite is mixed according to quality proportioning 4:3 by sodium bentonite and calcium-base bentonite.
The preparation method of described novel ceramic tile bond agent is:
A. cement, ground calcium carbonate, plaster of Paris and bentonite are put in mixer and stir 18 minutes；
B. redispersable latex powder is added in mixture described in step A and stir 3 minutes；
C. polypropylene fibre, hydroxyethyl ether cellulose and starch ether are added in step B gained mixture and stir
Grind 4 minutes after 15 minutes；
D. by calcium formate, aqueous alkyd resin class defoamer, aluminium-magnesium silicate thixotropic lubricant and water reducer successively
Add in the mixture after grinding and stir 3 minutes, obtain described ceramic tile bond.
Embodiment 2
Novel ceramic tile bond, consisting of: the ground calcium carbonate 30kg that cement 20kg, particle diameter are 80 μm,
Plaster of Paris 15kg, bentonite 15kg, redispersable latex powder 9.6kg, fibre length are poly-the third of 6mm
Alkene fiber 7.24kg, calcium formate 2.12kg, hydroxypropylcelluloether ether 3.26kg, starch ether 2.31kg, subtract
Water preparation 2.68kg, aqueous alkyd resin class defoamer 2.44kg and aluminium-magnesium silicate thixotropic lubricant 2.72kg.
Described bentonite is mixed according to quality proportioning 5:2 by sodium bentonite and calcium-base bentonite.
The preparation method of described novel ceramic tile bond agent is:
A. cement, ground calcium carbonate, plaster of Paris and bentonite are put in mixer and stir 15 minutes；
B. redispersable latex powder is added in mixture described in step A and stir 5 minutes；
C. polypropylene fibre, hydroxypropylcelluloether ether and starch ether are added in step B gained mixture and stir
Grind 7 minutes after 10 minutes；
D. by calcium formate, aqueous alkyd resin class defoamer, aluminium-magnesium silicate thixotropic lubricant and water reducer successively
Add in the mixture after grinding and stir 5 minutes, obtain described ceramic tile bond.
Embodiment 3
Novel ceramic tile bond, consisting of: the ground calcium carbonate 27kg that cement 28kg, particle diameter are 100 μm,
Plaster of Paris 18kg, bentonite 12kg, redispersable latex powder 11.6kg, fibre length are the poly-of 8mm
Tacryl 5.85kg, calcium formate 3.33kg, hydroxypropylcelluloether ether 4.45kg, starch ether 2.92kg,
Water reducer 1.98kg, aqueous alkyd resin class defoamer 2.96kg and aluminium-magnesium silicate thixotropic lubricant 2.12kg.
Described bentonite is mixed according to quality proportioning 4:2 by sodium bentonite and calcium-base bentonite.
The preparation method of described novel ceramic tile bond agent is:
A. cement, ground calcium carbonate, plaster of Paris and bentonite are put in mixer and stir 156 minutes；
B. redispersable latex powder is added in mixture described in step A and stir 4 minutes；
C. polypropylene fibre, hydroxypropylcelluloether ether and starch ether are added in step B gained mixture and stir
Grind 6 minutes after 12 minutes；
D. by calcium formate, aqueous alkyd resin class defoamer, aluminium-magnesium silicate thixotropic lubricant and water reducer successively
Add in the mixture after grinding and stir 4 minutes, obtain described ceramic tile bond.
Comparative example 1
Novel ceramic tile bond, consisting of: the ground calcium carbonate 26kg that cement 21kg, particle diameter are 84 μm,
Plaster of Paris 19kg, bentonite 7kg, redispersable latex powder 10.2kg, fibre length are poly-the third of 7mm
Alkene fiber 4.62kg, calcium formate 4.51kg, hydroxyethyl ether cellulose 3.45kg, starch ether 2.43kg, subtract
Water preparation 1.36kg and aluminium-magnesium silicate thixotropic lubricant 1.68kg.
Described bentonite is mixed according to quality proportioning 5:3 by sodium bentonite and calcium-base bentonite.
The preparation method of described novel ceramic tile bond agent is:
A. cement, ground calcium carbonate, plaster of Paris and bentonite are put in mixer and stir 16 minutes；
B. redispersable latex powder is added in mixture described in step A and stir 5 minutes；
C. polypropylene fibre, hydroxyethyl ether cellulose and starch ether are added in step B gained mixture and stir
Grind 5 minutes after 11 minutes；
D. the mixture after calcium formate, aluminium-magnesium silicate thixotropic lubricant and water reducer being sequentially added into grinding stirs
Mix 3 minutes, obtain described ceramic tile bond.
Comparative example 2
Novel ceramic tile bond, consisting of: the ground calcium carbonate 29kg that cement 33kg, particle diameter are 115 μm,
Plaster of Paris 19kg, bentonite 14kg, redispersable latex powder 12.4kg, fibre length are the poly-of 8mm
Tacryl 7.19kg, calcium formate 2.18kg, hydroxypropylcelluloether ether 3.26-5.63kg, starch ether 3.57kg,
Water reducer 2.55kg, aqueous alkyd resin class defoamer 2.53kg and aluminium-magnesium silicate thixotropic lubricant 2.74kg.
Described bentonite is mixed according to quality proportioning 4:2 by sodium bentonite and calcium-base bentonite.
The preparation method of described novel ceramic tile bond agent is:
A. cement, ground calcium carbonate, plaster of Paris and bentonite are put in mixer and stir 17 minutes；
B. redispersable latex powder is added in mixture described in step A and stir 3 minutes；
C. hydroxypropylcelluloether ether and starch ether are added and grind after step B gained mixture stirs 14 minutes
6 minutes；
D. by polypropylene fibre, calcium formate, aqueous alkyd resin class defoamer, aluminium-magnesium silicate thixotropic lubricant
It is sequentially added in the mixture after grinding stirring 4 minutes with water reducer, obtains described ceramic tile bond.
Comparative example 3
Enter with formula described in the application for a patent for invention embodiment 1 of Publication No. CN104860601A and conventional method
Prepared by row ceramic tile bond.Specifically, a kind of ceramic tile bond, by mass fraction ratio it is: portland cement
60 parts, quartz sand 45 parts, Paris white 28 parts, redispersible latex powder 3 parts, polypropylene fibre 0.8
Part, hydroxypropyl methyl cellulose ether 2 parts, lignocellulose 2 parts, desulfurated plaster 5 parts, rubber powder 3 parts.
Said components is put into mix and blend 15 minutes in mixer, obtains described ceramic tile bond.
Ceramic tile bond performance test
Embodiment 1-3 (respectively experimental group 1-3) and comparative example 1-3 (respectively matched group 1-3) are made
The standby ceramic tile bond obtained carries out performance detection, and testing result is as shown in the table:
Thus proving, the ceramic tile bond cohesive force of the present invention is strong.Meanwhile, the ceramic tile bond of the present invention has
Excellent water-fast, heatproof, freeze-thaw resistance property, service life is strong.
Finally illustrating, above example is only in order to illustrate technical scheme and unrestricted, although ginseng
According to preferred embodiment, the present invention is described in detail, it will be understood by those within the art that, permissible
Technical scheme is modified or equivalent, without deviating from technical solution of the present invention objective and
Scope, it all should be contained in the middle of scope of the presently claimed invention.
Claims (10)
1. novel ceramic tile bond, it is characterised in that include following components by weight: cement
20-35 part, ground calcium carbonate 25-30 part, plaster of Paris 15-20 part, bentonite 6-15
Part, redispersable latex powder 9.6-12.5 part, polypropylene fibre 4.53-7.24 part, formic acid
Calcium 2.12-4.53 part, cellulose ether 3.26-5.63 part, starch ether 2.31-3.64 part, subtract
Water preparation 1.26-2.68 part, defoamer 2.44-3.52 part and thixotropic lubricant 1.52-2.72 part.
Novel ceramic tile bond the most according to claim 1, it is characterised in that by weight
Part includes following components: cement 28 parts, ground calcium carbonate 27 parts, plaster of Paris 18 parts,
Bentonite 12 parts, redispersable latex powder 11.6 parts, polypropylene fibre 5.85 parts, formic acid
Calcium 3.33 parts, cellulose ether 4.45 parts, starch ether 2.92 parts, water reducer 1.98 parts, disappear
Infusion 2.96 parts and thixotropic lubricant 2.12 parts.
Novel ceramic tile bond the most according to claim 1, it is characterised in that described heavy
The particle diameter of matter calcium carbonate is 80-120 μm.
Novel ceramic tile bond the most according to claim 1, it is characterised in that described swollen
Profit soil is mixed according to quality proportioning 4-5:2-3 by sodium bentonite and calcium-base bentonite.
Novel ceramic tile bond the most according to claim 1, it is characterised in that described poly-
The fibre length of tacryl is 6-9mm.
Novel ceramic tile bond the most according to claim 1, it is characterised in that described fibre
Dimension element ether is hydroxyethyl ether cellulose or hydroxypropylcelluloether ether.
Novel ceramic tile bond the most according to claim 1, it is characterised in that described
Defoamer is aqueous alkyd resin class defoamer.
Novel ceramic tile bond the most according to claim 1, it is characterised in that described tactile
Change lubricant is aluminium-magnesium silicate thixotropic lubricant.
9. the preparation method of the novel ceramic tile bond agent described in claim 1, it is characterised in that
Concretely comprise the following steps:
A. cement, ground calcium carbonate, plaster of Paris and the bentonite of above-mentioned mass parts are put into mixed
Conjunction machine stirs 15-18 minute；
B. the redispersable latex powder of above-mentioned mass parts is added in mixture described in step A and stir
Mix 3-5 minute；
C. the polypropylene fibre of above-mentioned mass parts, cellulose ether and starch ether are added step B institute
Obtain and grind 4-7 minute after mixture stirs 10-15 minute；
D. calcium formate, defoamer, thixotropic lubricant and the water reducer of above-mentioned mass parts are added successively
Enter in the mixture after grinding and stir 3-5 minute, obtain described ceramic tile bond.
10. the novel ceramic tile bond described in any one of claim 1-8 is at concrete mortar wall
Application in face and floor surface bonding ceramic tile work progress.
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106810105A (en) * | 2016-12-30 | 2017-06-09 | 苏州泰如新材料科技有限公司 | A kind of concrete additive |
| CN106986590A (en) * | 2017-03-27 | 2017-07-28 | 王中华 | A kind of ceramic tile adhesive mortar, its preparation method and ceramic tile adhesion technique |
| CN107619231A (en) * | 2017-09-28 | 2018-01-23 | 贵州益新装配式新型建材有限公司 | A kind of high strength china tile adhesive and preparation method thereof |
| CN109133718A (en) * | 2018-11-09 | 2019-01-04 | 广西里尔新材料有限公司 | A kind of bi-component porcelain tendre adhesive glue |
| CN110028269A (en) * | 2019-05-17 | 2019-07-19 | 郭保军 | A kind of strength glue for tile essence |
| CN110683814A (en) * | 2019-11-21 | 2020-01-14 | 江门大光明粘胶有限公司 | Ceramic tile dry powder gum and preparation method thereof |
| CN111592316A (en) * | 2020-05-25 | 2020-08-28 | 贵州省昊越新型材料科技有限公司 | Gypsum heat-insulating mortar |
| CN112062519A (en) * | 2020-09-03 | 2020-12-11 | 北京华阳众信建材有限公司 | High-weather-resistance ceramic tile binder and preparation method and construction method thereof |
| CN112125631A (en) * | 2020-09-27 | 2020-12-25 | 广东粤固建材科技有限公司 | Damp-proof ceramic tile binder and preparation method thereof |
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| CN116496053A (en) * | 2022-12-07 | 2023-07-28 | 广东薄可涂环保科技有限公司 | Novel decorative micro-cement material and use method thereof |
| CN116730691A (en) * | 2023-05-25 | 2023-09-12 | 东莞市欧丽亚环保材料有限公司 | Ceramic tile adhesive and preparation method |
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|---|---|---|---|---|
| CN106810105A (en) * | 2016-12-30 | 2017-06-09 | 苏州泰如新材料科技有限公司 | A kind of concrete additive |
| CN106986590A (en) * | 2017-03-27 | 2017-07-28 | 王中华 | A kind of ceramic tile adhesive mortar, its preparation method and ceramic tile adhesion technique |
| CN106986590B (en) * | 2017-03-27 | 2018-03-20 | 河南泰鑫节能科技有限公司 | A kind of ceramic tile adhesive mortar, its preparation method and ceramic tile adhesion technique |
| CN107619231A (en) * | 2017-09-28 | 2018-01-23 | 贵州益新装配式新型建材有限公司 | A kind of high strength china tile adhesive and preparation method thereof |
| CN109133718A (en) * | 2018-11-09 | 2019-01-04 | 广西里尔新材料有限公司 | A kind of bi-component porcelain tendre adhesive glue |
| CN110028269A (en) * | 2019-05-17 | 2019-07-19 | 郭保军 | A kind of strength glue for tile essence |
| CN110683814A (en) * | 2019-11-21 | 2020-01-14 | 江门大光明粘胶有限公司 | Ceramic tile dry powder gum and preparation method thereof |
| CN111592316A (en) * | 2020-05-25 | 2020-08-28 | 贵州省昊越新型材料科技有限公司 | Gypsum heat-insulating mortar |
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