CN105754765B - A kind of electronic component cleaning agent - Google Patents
A kind of electronic component cleaning agent Download PDFInfo
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- CN105754765B CN105754765B CN201610213084.6A CN201610213084A CN105754765B CN 105754765 B CN105754765 B CN 105754765B CN 201610213084 A CN201610213084 A CN 201610213084A CN 105754765 B CN105754765 B CN 105754765B
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- Prior art keywords
- electronic component
- cleaning agent
- hydrofluoroether
- low
- agent
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- 239000012459 cleaning agent Substances 0.000 title claims abstract description 24
- 239000003960 organic solvent Substances 0.000 claims abstract description 11
- 230000002378 acidificating effect Effects 0.000 claims abstract description 9
- 150000001412 amines Chemical class 0.000 claims abstract description 9
- 239000003381 stabilizer Substances 0.000 claims abstract description 9
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 8
- MOBNLCPBAMKACS-UHFFFAOYSA-N 2-(1-chloroethyl)oxirane Chemical compound CC(Cl)C1CO1 MOBNLCPBAMKACS-UHFFFAOYSA-N 0.000 claims abstract description 6
- 125000005227 alkyl sulfonate group Chemical group 0.000 claims abstract description 6
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 6
- 239000011734 sodium Substances 0.000 claims abstract description 6
- 239000013530 defoamer Substances 0.000 claims abstract description 5
- DCEMCPAKSGRHCN-UHFFFAOYSA-N oxirane-2,3-dicarboxylic acid Chemical compound OC(=O)C1OC1C(O)=O DCEMCPAKSGRHCN-UHFFFAOYSA-N 0.000 claims abstract description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 claims description 6
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical group NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 3
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 3
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- 229940043237 diethanolamine Drugs 0.000 claims description 3
- CCIVGXIOQKPBKL-UHFFFAOYSA-M ethanesulfonate Chemical compound CCS([O-])(=O)=O CCIVGXIOQKPBKL-UHFFFAOYSA-M 0.000 claims description 3
- UTEFBSAVJNEPTR-RGEXLXHISA-N loprazolam Chemical group C1CN(C)CCN1\C=C/1C(=O)N2C3=CC=C([N+]([O-])=O)C=C3C(C=3C(=CC=CC=3)Cl)=NCC2=N\1 UTEFBSAVJNEPTR-RGEXLXHISA-N 0.000 claims description 3
- 229960003019 loprazolam Drugs 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 125000001153 fluoro group Chemical group F* 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims 1
- 230000003750 conditioning effect Effects 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 16
- 239000002904 solvent Substances 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 abstract description 3
- 239000006260 foam Substances 0.000 abstract description 3
- 230000009931 harmful effect Effects 0.000 abstract description 3
- 231100000053 low toxicity Toxicity 0.000 abstract description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical group FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 229910052731 fluorine Inorganic materials 0.000 description 5
- 239000011737 fluorine Substances 0.000 description 5
- -1 hydrogen Fluorine ethers Chemical class 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- RHQDFWAXVIIEBN-UHFFFAOYSA-N Trifluoroethanol Chemical compound OCC(F)(F)F RHQDFWAXVIIEBN-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of electronic component cleaning agent, including following component:Poly-epoxy succinic acid, APG alkyl polyglycosides, acidic cleaner, SAS sodium secondary alkyl sulfonate, hydrofluoroether, water-soluble organic amine pH adjusting agent, defoamer, methyl epichlorohydrin, stabilizer and organic solvent.The present invention provides a kind of electronic component cleaning agent, the cleaning agent is that primary solvent and other components are engaged using ODP as 0 hydrofluoroether class, meet environmental protection, low toxicity, the requirement of low temperature chamber effect, which has good cleaning performance, while foam is low, it is corrosion-free, volatilize small, residual is few, and viscosity is low, electronic component can be cleaned well, while harmful effect will not be caused to electronic component.
Description
Technical field
The present invention relates to a kind of cleaning agent, and specifically, the present invention relates to a kind of electronic component cleaning agent.
Background technology
In the production process of the electronic component of electronics industry manufacture, electronic component needs the glue surface before assembling
The dirts such as trace, welding assisted agent residuals remove, and it is essential technical process to carry out cleaning to component using detergent, are cleaning this
During a little materials may some need manual operation or implement in closed space, these requirements not only need fluorine-containing cleaning
Agent is good for glue trace and solder flux residual scavenging effect, and requires fluorine-containing cleaning agent component safety and environmental protection, and rate of volatilization is fast, toxicity
Low, smell is small, nonflammable.The cleaning agent used is most of for solvent of the fluorochemical as fluorine-containing cleaning agent, it is main excellent
Point is non-ignitable or nonflammable, i.e., good cleaning performance is issued in nonflammable premise, and what is used in the past is widest main
It is 1,1,2- trifluorotrichloroethane (abbreviation CFC-113), CFC-113 has the solubility property, good of appropriateness as cleaning solvent
Selectivity, low viscosity, low surface tension, high wellability, quick-drying the advantages that, and with non-ignitable, less toxic, low corrosion, change
The feature such as and thermostabilization, so particularly suitable for members such as electronics, motor, precision optical machinery, resin processing and precision optics
The cleaning of device, and dry solvent can be used as to use.But the ODP values of CFC-113 are the finger that 0.8, ODP is ozone depletion potential
Mark characterization, ODP numerical value is higher, represents bigger to the damage capability of ozone.So this also just illustrates CFC-113 to atmospheric advection layer
Ozone layer have destroying infection.So developed country forbids using on January 1st, 1996 to it, China is also complete in 2006
The full use for having eliminated CFC-113.
The relatively low solvent of CFC-113 and ODP values, which can be substituted, mainly hydrogen fluorochlorohydrocarbon class, hydrogen fluorohydrocarbon class, perfluoroalkanes, hydrogen
Fluorine ethers, chlorinated hydrocarbon, hydrogen bromine hydro carbons etc..The wherein ODP values more as low as 0 of perfluoroalkanes and hydrofluoroether class, can be selected as CFC-
113 more environmentally friendly substitutes.But reach for different cleaning requirements, cleaning way and cleaning environment, one-component difficulty or ease
Preferable cleaning performance, so needing to mix composition composition with other solvents with different qualities, to meet various differences
Cleaning requirement.
The content of the invention
The object of the present invention is to provide a kind of electronic component cleaning agent, the cleaning agent is using ODP as based on 0 hydrofluoroether class
Want solvent and other components to be engaged, meet environmental protection, low toxicity, the requirement of low temperature chamber effect, which has good cleaning
Can, while foam is low, corrosion-free, volatilization is small, and residual is few, and viscosity is low, and electronic component can be cleaned well, while not
Harmful effect can be caused to electronic component.
The technical solution adopted by the present invention is a kind of electronic component cleaning agent, includes the component of following parts by weight:
Poly-epoxy succinic acid:2~8 parts;APG- alkyl polyglycosides:1~5 part;
Acidic cleaner:0.1~3 part;SAS- sodium secondary alkyl sulfonate:1~7 part;
Hydrofluoroether:6~20 parts;Water-soluble organic amine pH adjusting agent:1~3 part;
Defoamer:0.1~1 part;Methyl epichlorohydrin:0.1~3 part;
Stabilizer:0.1~3 part;Organic solvent:5~12 parts.
Preferably, the acidic cleaner is Loprazolam or ethane sulfonic acid.
Preferably, the hydrofluoroether is fluoro hydrofluoroether or its mixture containing C5~C10.
Preferably, the stabilizer is containing the fluorinated alcohols of C2-C7 or its mixture.
Preferably, the organic solvent be ethanol, the mixture of two kinds of acetone, ethanol percentage by weight for 50%~
80%, acetone percentage by weight is 20%~50%.
Preferably, the water-soluble organic amine pH adjusting agent is monoethanolamine, diethanol amine, triethanolamine, cyclohexylamine,
One or more in 2-amino-2-methyl-1-propanol.
The present invention includes at least following beneficial effect:
(1) present invention using hydrofluoroether as primary solvent, it is auxiliary to be equipped with other compositions, have rate of volatilization it is relatively fast, without sudden strain of a muscle
Point, it is non-ignitable, storage stability is good, it is weaker with respect to CFC-113 solvabilities, but safer environmental protection, by adding polycyclic oxygen amber
Amber acid can strengthen APG- alkyl polyglycosides, SAS- sodium secondary alkyl sulfonate effects, reduce the surface tension of electronic component, help to increase
The dirt-removing power of strong hydrofluoroether;
(2) foam of the invention is low, corrosion-free, and volatilization is small, and residual is few, and viscosity is low, can well to electronic component into
Row cleaning, while harmful effect will not be caused to electronic component, chemical balance can be kept by adding stabilizer, reduce surface
Power, prevents light, thermal decomposition or oxygenolysis, adds water-soluble organic amine pH adjusting agent, washing process can be met to electronics zero
Part not damaged, by introducing the organic solvent and methyl epichlorohydrin of specific proportioning, can improve the rate of volatilization of cleaning agent,
Possesses fast and efficiently feature.
Embodiment
Carry out the embodiment that the present invention will be described in detail below with reference to specific embodiment, how skill is applied to the present invention whereby
Art means solve technical problem, and reach technique effect realizes that process can fully understand and implement according to this.
Unless otherwise specified, the conventional hand that the technological means employed in embodiment is well known to those skilled in the art
Section, used raw material is also available commercial.The various processes and method not being described in detail are as known in the art
Conventional method.
A kind of electronic component cleaning agent, includes the component of following parts by weight:
Poly-epoxy succinic acid:2~8 parts;APG- alkyl polyglycosides:1~5 part;
Acidic cleaner:0.1~3 part;SAS- sodium secondary alkyl sulfonate:1~7 part;
Hydrofluoroether:6~20 parts;Water-soluble organic amine pH adjusting agent:1~3 part;
Defoamer:0.1~1 part;Methyl epichlorohydrin:0.1~3 part;
Stabilizer:0.1~3 part;Organic solvent:5~12 parts.
Further improved as of the invention, the acidic cleaner is Loprazolam or ethane sulfonic acid.Acidic cleaner can
Effectively to remove the dirt of the more difficult removing such as iron rust, greasy dirt.
Further improved as of the invention, the hydrofluoroether is containing C5~C10Fluoro hydrofluoroether or its mixture, it is more excellent
Choosing, the hydrofluoroether is nine fluorine butyl methyl ethers or the mixture of other analogs, and hydrofluoroether has electronical elements surface dirt
There are preferable dissolving, cleaning performance.To the surface residue of electronic component, scaling powder, rosin, resin, greasy dirt, finger mark, dust
There is excellent cleaning performance, and clean in the organic system needed at a lower temperature and carry out, possess fast and efficiently feature.
Further improved as of the invention, the stabilizer is containing C2-C7Fluorinated alcohols or its mixture, more preferably
The mixture of trifluoroethanol or its analog.
Further improved as of the invention, the organic solvent is ethanol, the mixture of two kinds of acetone, ethanol weight percent
Than for 50%~80%, acetone percentage by weight is 20%~50%.Organic solvent is to dissolve it in the effect of the cleaning agent
His component, at the same cleaning agent need volatile organic system and it is quick, efficiently therefore select the mixing of ethanol and both acetone
Thing can not only meet the performance for dissolving other components, the cleaning performance of cleaning agent be improved, also so that entirely as organic solvent
Cleaning agent has volatile organic system, can effectively reduce the wash residue of cleaning agent.
Further improved as of the invention, the water-soluble organic amine pH adjusting agent is monoethanolamine, diethanol amine, three second
One or more in hydramine, cyclohexylamine, 2-amino-2-methyl-1-propanol.
Table 1 lists the concrete component and its content of different embodiments and comparative example.
1~4 specific component of 1 embodiment 1~3 of table and comparative example
The preparation method of above-mentioned electronic component cleaning agent is:
Each component is configured according to weight proportion, by poly-epoxy succinic acid, APG- alkyl polyglycosides, acidic cleaner,
Organic solvent, hydrofluoroether, defoamer mixing, under 800~1000 revs/min of stirrings, are heated to 40~50 DEG C, and adding water solubility has
Machine amine pH adjusting agent, methyl epichlorohydrin, stabilizer, SAS- sodium secondary alkyl sulfonate continue stirring 10~15 minutes up to described
Electronic component cleaning agent.
Table 2 lists the test result of embodiment 1~3 and comparative example 1~4.
The test result of 2 embodiment 1~3 of table and comparative example 1~4
Detection project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 | Comparative example 4 |
Corrosivity | 0.1 | 0.1 | 0.1 | 0.4 | 0.7 | 0.2 | 0.1 |
Rust-preventing characteristic | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
Washing power | 97% | 98% | 97% | 90% | 89% | 92% | 91% |
Wash residue | 0.01 | 0.01 | 0.01 | 0.04 | 0.05 | 0.1 | 0.1 |
Pollution | Nothing | Nothing | Nothing | Nothing | Nothing | Nothing | Nothing |
Although embodiment of the present invention is disclosed as above, it is not restricted in specification and embodiment listed
With it can be applied to various suitable the field of the invention completely, can be easily for those skilled in the art
Realize other modification, therefore under the universal limited without departing substantially from claim and equivalency range, it is of the invention and unlimited
In specific details.
Claims (1)
1. a kind of electronic component cleaning agent, it is characterised in that include the component of following parts by weight:
Poly-epoxy succinic acid:2~8 parts;APG- alkyl polyglycosides:1~5 part;
Acidic cleaner:0.1~3 part;SAS- sodium secondary alkyl sulfonate:1~7 part;
Hydrofluoroether:6~20 parts;Water-soluble organic amine pH adjusting agent:1~3 part;
Defoamer:0.1~1 part;Methyl epichlorohydrin:0.1~3 part;
Stabilizer:0.1~3 part;Organic solvent:5~12 parts;
The acidic cleaner is Loprazolam or ethane sulfonic acid, the hydrofluoroether for the fluoro hydrofluoroether containing C5~C10 or its
Mixture, the stabilizer be the organic solvent is ethanol containing the fluorinated alcohols of C2-C7 or its mixture, two kinds of acetone it is mixed
Compound, ethanol percentage by weight are 50%~80%, and acetone percentage by weight is 20%~50%, the water-soluble organic amine pH
Conditioning agent is monoethanolamine, the one or more in diethanol amine, triethanolamine, cyclohexylamine, 2-amino-2-methyl-1-propanol.
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CN108148685A (en) * | 2017-12-25 | 2018-06-12 | 柳州智臻智能机械有限公司 | A kind of electronic component cleaning compositions and preparation method thereof |
CN111073765A (en) * | 2019-12-11 | 2020-04-28 | 长沙凯泽工程设计有限公司 | Preparation method of electronic circuit board cleaning detergent |
CN113201743B (en) * | 2021-04-08 | 2022-06-21 | 浙江工业大学 | Rust remover suitable for electronic devices and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0511091A1 (en) * | 1991-04-25 | 1992-10-28 | Colgate-Palmolive Company | Hard surface cleaner |
CN1330567A (en) * | 1998-12-16 | 2002-01-09 | 3M创新有限公司 | Microemulsions containing water and hydrofluoroethers |
CN1894186A (en) * | 2003-12-18 | 2007-01-10 | 3M创新有限公司 | Azeotrope-like compositions and their use |
CN105199859A (en) * | 2015-09-17 | 2015-12-30 | 惠州学院 | Semiconductor surface cleaning agent and preparation method thereof |
-
2016
- 2016-04-07 CN CN201610213084.6A patent/CN105754765B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0511091A1 (en) * | 1991-04-25 | 1992-10-28 | Colgate-Palmolive Company | Hard surface cleaner |
CN1330567A (en) * | 1998-12-16 | 2002-01-09 | 3M创新有限公司 | Microemulsions containing water and hydrofluoroethers |
CN1894186A (en) * | 2003-12-18 | 2007-01-10 | 3M创新有限公司 | Azeotrope-like compositions and their use |
CN105199859A (en) * | 2015-09-17 | 2015-12-30 | 惠州学院 | Semiconductor surface cleaning agent and preparation method thereof |
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