CN105750357A - Fabrication method of zirconium alloy pipe - Google Patents
Fabrication method of zirconium alloy pipe Download PDFInfo
- Publication number
- CN105750357A CN105750357A CN201610220190.7A CN201610220190A CN105750357A CN 105750357 A CN105750357 A CN 105750357A CN 201610220190 A CN201610220190 A CN 201610220190A CN 105750357 A CN105750357 A CN 105750357A
- Authority
- CN
- China
- Prior art keywords
- pipe
- zirconium alloy
- alloy pipe
- resistance furnace
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910001093 Zr alloy Inorganic materials 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 title abstract description 4
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000011521 glass Substances 0.000 claims abstract description 24
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052802 copper Inorganic materials 0.000 claims abstract description 10
- 239000010949 copper Substances 0.000 claims abstract description 10
- 238000001816 cooling Methods 0.000 claims abstract description 9
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 5
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 5
- 239000000843 powder Substances 0.000 claims abstract description 5
- 239000000428 dust Substances 0.000 claims description 13
- 238000005461 lubrication Methods 0.000 claims description 13
- 238000002360 preparation method Methods 0.000 claims description 10
- 238000005253 cladding Methods 0.000 claims description 8
- 238000003754 machining Methods 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 abstract description 5
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 5
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 238000004321 preservation Methods 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 7
- 229910052726 zirconium Inorganic materials 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
- B21C37/00—Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
- B21C37/06—Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of tubes or metal hoses; Combined procedures for making tubes, e.g. for making multi-wall tubes
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Extrusion Of Metal (AREA)
Abstract
The invention discloses a fabrication method of a zirconium alloy pipe. A pipe blank with a through hole is mechanically machined, is preheated and subjected to heat preservation in an electric resistance furnace, is heated in the electric resistance furnace after being coated with a glass antioxidant, then is lubricated with glass powder and is broached by a broaching machine; the blank is air-cooled to room temperature and mechanically machined, then is clad with red copper skin, is then placed in the electric resistance furnace to be heated to 600-800 DEG C, and is extruded in an extruder; and finally, the copper skin coating the inner and outer surfaces of the blank is removed after air cooling is finished, therefore, the zirconium alloy pipe is obtained. The fabricated zirconium alloy pipe has high quality, cannot be oxidized easily, is unlikely absorb hydrogen, is corrosion-resistant, and has long life, high yield and stable performance.
Description
Technical field
The present invention relates to technical field of alloy, specifically the preparation method of a kind of zirconium alloy pipe.
Background technology
Zirconium is a kind of rare metal, has the characteristics such as surprising corrosion resistance, high fusing point, the hardness of superelevation and intensity, is widely used in Aero-Space, military project, nuclear reaction, atomic energy field.Zirconium and zircaloy plasticity are good, can be made into tubing, sheet material, bar and silk material, and wherein tubing is major product.The processing technique of zirconium and zircaloy depends on fundamental property and the nuclear reactor particular/special requirement to zirconium component of zirconium.The fundamental property of zirconium is: is easily polluted by oxygen, nitrogen, hydrogen etc., easy sticking mould, has allomorphism to change.The requirement of zirconium component is that dimensional accuracy is high by nuclear reactor, and microstructural requirements is strict, stable performance.Therefore on prepared by this compo pipe, there is the problems such as suction hydrogen oxidizable, easy, and traditional preparation methods lumber recovery is relatively low, waste metal.
Summary of the invention
The preparation method that it is an object of the invention to provide a kind of zirconium alloy pipe, with the problem solving to propose in above-mentioned background technology.
For achieving the above object, the present invention provides following technical scheme:
A kind of preparation method of zirconium alloy pipe, concrete preparation process is as follows:
(1) Slug preparing, prepares the pipe with through hole by machining, and this pipe one end is with horn mouth, reduce and bore macropore metal loss, and horn mouth is for counter-bore head location and glass dust lubrication；
(2) preheating 100～200 DEG C in resistance furnace, be incubated 1～2h, at pipe sprayed glass antioxidant, it is to avoid during high temperature, hydrogen problem is inhaled in the oxygen uptake of zircaloy；
(3) pipe puts into resistance furnace heating to 700～900 DEG C, is carrying out glass dust lubrication after carrying out glass dust lubrication or sensed stove temperature raising；After glass dust lubrication, enter staving press and carry out reaming, improve the lumber recovery of zircaloy；
(4) after reaming, blank air cooling, to room temperature, carries out machining or Watch glass powder is removed in reconditioning, remove the glass hardening impurity on surface, it is to avoid bring surface defect in follow-up extrusion process；
(5) it is coated with sheet copper, after cladding is good, puts into resistance furnace and heat to 600～800 DEG C, after reaching temperature, enter extruder extruding, remove the copper sheet of surfaces externally and internally cladding after air cooling, obtain zirconium alloy pipe.
As the further scheme of the present invention: in described step (1), the through-hole diameter of pipe is 40～80mm.
As the present invention further scheme: in described step (2), counter bore diameter is big 8～10mm than squeezing needle diameter.
Compared with prior art, the invention has the beneficial effects as follows: the zirconium alloy pipe quality that the present invention prepares is good, not easily oxidized, not easily inhaling hydrogen, corrosion-resistant, the life-span is long, and lumber recovery is high, stable performance.
Detailed description of the invention
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is only a part of embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, the every other embodiment that those of ordinary skill in the art obtain under not making creative work premise, broadly fall into the scope of protection of the invention.
Embodiment 1
(1) blank prepares: external diameter 357mm after machining, length 700mm, center-hole diameter 80mm, horn mouth, flared end diameter 191mm, angle 48 ° are processed in one end；
(2) in resistance furnace, preheat 200 DEG C, be incubated 1h, at pipe sprayed glass antioxidant；
(3) pipe puts into resistance furnace heating to 700 DEG C；Glass dust lubrication is being carried out after carrying out glass dust lubrication or sensed stove temperature raising；After glass dust lubrication, enter staving press small deformation amount reaming, counter bore diameter 191mm；
(4) after reaming blank air cooling to room temperature；Carry out machining or Watch glass powder is removed in reconditioning；
(5) being coated with sheet copper, after cladding is good, puts into resistance furnace and heat to 600 DEG C, after reaching temperature, enter extruder extruding, remove the copper sheet of surfaces externally and internally cladding, obtain zirconium alloy pipe after air cooling, zirconium alloy pipe specification is external diameter 220mm, wall thickness 22mm.
Embodiment 2
(1) blank prepares: external diameter 302mm after machining, length 600mm, center-hole diameter 65mm, horn mouth, flared end diameter 135mm, angle 48 ° are processed in one end；
(2) in resistance furnace, preheat 100 DEG C, be incubated 2h, at pipe sprayed glass antioxidant；
(3) pipe puts into resistance furnace heating to 900 DEG C；Glass dust lubrication is being carried out after carrying out glass dust lubrication or sensed stove temperature raising；After glass dust lubrication, enter staving press small deformation amount reaming, counter bore diameter 135mm；
(4) after reaming blank air cooling to room temperature；Carry out machining or Watch glass powder is removed in reconditioning；
(5) it is coated with sheet copper；After cladding is good, putting into resistance furnace and heat to 800 DEG C, after reaching, enter extruder extruding, remove the copper sheet of surfaces externally and internally cladding, obtain zirconium alloy pipe after air cooling, zirconium alloy pipe specification is external diameter 160mm, wall thickness 20mm.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when without departing substantially from the spirit of the present invention or basic feature, it is possible to realize the present invention in other specific forms.Therefore, no matter from which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the invention rather than described above limits, it is intended that all changes in the implication of the equivalency dropping on claim and scope included in the present invention.
Claims (3)
1. the preparation method of a zirconium alloy pipe, it is characterised in that concrete preparation process is as follows:
(1) Slug preparing, prepares the pipe with through hole by machining, and this pipe one end is with horn mouth；
(2) in resistance furnace, preheat 100～200 DEG C, be incubated 1～2h, at pipe sprayed glass antioxidant；
(3) pipe puts into resistance furnace heating to 700～900 DEG C, is carrying out glass dust lubrication after carrying out glass dust lubrication or sensed stove temperature raising；After glass dust lubrication, enter staving press and carry out reaming；
(4) after reaming, blank air cooling, to room temperature, carries out machining or Watch glass powder is removed in reconditioning；
(5) it is coated with sheet copper, after cladding is good, puts into resistance furnace and heat to 600～800 DEG C, after reaching temperature, enter extruder extruding, remove the copper sheet of surfaces externally and internally cladding after air cooling, obtain zirconium alloy pipe.
2. the preparation method of zirconium alloy pipe according to claim 1, it is characterised in that in described step (1), the through-hole diameter of pipe is 40～80mm.
3. the preparation method of zirconium alloy pipe according to claim 1, it is characterised in that in described step (2), counter bore diameter is big 8～10mm than squeezing needle diameter.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610220190.7A CN105750357A (en) | 2016-04-11 | 2016-04-11 | Fabrication method of zirconium alloy pipe |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610220190.7A CN105750357A (en) | 2016-04-11 | 2016-04-11 | Fabrication method of zirconium alloy pipe |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105750357A true CN105750357A (en) | 2016-07-13 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610220190.7A Pending CN105750357A (en) | 2016-04-11 | 2016-04-11 | Fabrication method of zirconium alloy pipe |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105750357A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107042247A (en) * | 2016-12-26 | 2017-08-15 | 中核北方核燃料元件有限公司 | The preparation method and extrusion die of a kind of U Zr compo pipes |
| CN107116339A (en) * | 2017-05-03 | 2017-09-01 | 中国核动力研究设计院 | A kind of zirconium alloy cladding tubing preparation technology |
| CN111842532A (en) * | 2019-04-28 | 2020-10-30 | 国核宝钛锆业股份公司 | Zirconium alloy pipe preparation method and zirconium alloy pipe prepared based on method |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0895247A1 (en) * | 1997-08-01 | 1999-02-03 | Siemens Power Corporation | Method of manufacturing zirconium niobium tin alloys for nuclear fuel rods and structural parts for high burnup |
| CN1249011A (en) * | 1997-03-12 | 2000-03-29 | “切佩茨基机械加工厂”股份公司 | Method for producing tubing products based on zircon alloys |
| CN101512671A (en) * | 2006-08-24 | 2009-08-19 | 威斯丁豪斯电气瑞典有限公司 | Water reactor fuel cladding tube |
| US20100108204A1 (en) * | 2008-05-09 | 2010-05-06 | Korea Atomic Energy Research Institute | Zirconium alloy composition for nuclear fuel cladding tube forming protective oxide film, zirconium alloy nuclear fuel cladding tube manufactured using the composition, and method of manufacturing the zirconium alloy nuclear fuel cladding tube |
| CN101704178A (en) * | 2009-10-29 | 2010-05-12 | 西北锆管有限责任公司 | Method for processing thin-walled tube of zirconium alloy specially used by nuclear reactor |
| CN101875070A (en) * | 2009-11-30 | 2010-11-03 | 西部金属材料股份有限公司 | Method for preparing zirconium and zirconium alloy pipe |
| CN104962836A (en) * | 2015-06-05 | 2015-10-07 | 山西太钢不锈钢股份有限公司 | Corrosion-resistance iron-based austenite oil well pipe and manufacturing method thereof |
-
2016
- 2016-04-11 CN CN201610220190.7A patent/CN105750357A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1249011A (en) * | 1997-03-12 | 2000-03-29 | “切佩茨基机械加工厂”股份公司 | Method for producing tubing products based on zircon alloys |
| EP0895247A1 (en) * | 1997-08-01 | 1999-02-03 | Siemens Power Corporation | Method of manufacturing zirconium niobium tin alloys for nuclear fuel rods and structural parts for high burnup |
| CN101512671A (en) * | 2006-08-24 | 2009-08-19 | 威斯丁豪斯电气瑞典有限公司 | Water reactor fuel cladding tube |
| US20100108204A1 (en) * | 2008-05-09 | 2010-05-06 | Korea Atomic Energy Research Institute | Zirconium alloy composition for nuclear fuel cladding tube forming protective oxide film, zirconium alloy nuclear fuel cladding tube manufactured using the composition, and method of manufacturing the zirconium alloy nuclear fuel cladding tube |
| CN101704178A (en) * | 2009-10-29 | 2010-05-12 | 西北锆管有限责任公司 | Method for processing thin-walled tube of zirconium alloy specially used by nuclear reactor |
| CN101875070A (en) * | 2009-11-30 | 2010-11-03 | 西部金属材料股份有限公司 | Method for preparing zirconium and zirconium alloy pipe |
| CN104962836A (en) * | 2015-06-05 | 2015-10-07 | 山西太钢不锈钢股份有限公司 | Corrosion-resistance iron-based austenite oil well pipe and manufacturing method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107042247A (en) * | 2016-12-26 | 2017-08-15 | 中核北方核燃料元件有限公司 | The preparation method and extrusion die of a kind of U Zr compo pipes |
| CN107116339A (en) * | 2017-05-03 | 2017-09-01 | 中国核动力研究设计院 | A kind of zirconium alloy cladding tubing preparation technology |
| CN111842532A (en) * | 2019-04-28 | 2020-10-30 | 国核宝钛锆业股份公司 | Zirconium alloy pipe preparation method and zirconium alloy pipe prepared based on method |
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Application publication date: 20160713 |
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