CN105746521B - A kind of composition pesticide of fluorine-containing lice sulfanilamide (SN) and biogenic substances - Google Patents
A kind of composition pesticide of fluorine-containing lice sulfanilamide (SN) and biogenic substances Download PDFInfo
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- CN105746521B CN105746521B CN201610087542.6A CN201610087542A CN105746521B CN 105746521 B CN105746521 B CN 105746521B CN 201610087542 A CN201610087542 A CN 201610087542A CN 105746521 B CN105746521 B CN 105746521B
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- pleocidin
- lice sulfanilamide
- fluorine lice
- benzoate
- emamectin
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/22—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
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Abstract
The invention discloses a kind of composition pesticide of fluorine-containing lice sulfanilamide (SN) and biogenic substances, the composition is characterized mainly in that：Including active components A and active constituent B.Wherein active components A is fluorine lice sulfanilamide (SN), and active constituent B is arbitrarily one kind, and active components A and the weight ratio of active constituent B 1 in avermectin, emamectin-benzoate, pleocidin, ethyl pleocidin:80~80:1, wettable powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, micro-capsule suspension, microcapsule suspension suspending agent is made in composition.The present composition can be used for preventing the various pests in various crop, and have apparent synergistic effect, and reduce pesticide usage amount, and to safety of human and livestock, no poisoning, Environmental compatibility is good；Preparation adhesion strength enhances, resistance of rainwater washing against.
Description
The application is divisional application, and original application is that " one kind contains for the patent application of Shaanxi Welch Crop Protection Co., Ltd.
The composition pesticide of fluorine lice sulfanilamide (SN) and biogenic substances ", the application Wei ︰ 201210106597.9 of original application, original application day are
2012.04.12。
Technical field
The invention belongs to technical field of pesticide, it is related to the composition pesticide of a kind of fluorine-containing lice sulfanilamide (SN) and biogenic substances for preventing
Control the application of crop pest.
Background technology
Avermectin (abamectin) molecular formula：C48H72O14(B1a)·C47H70O14(B1b).Avermectin is a kind of big
Cyclic lactone disaccharide compounds.Avermectin is the natural products detached from edaphon, has to insect and mite class and touches
It kills and stomach poison function and has faint fumigation action, no systemic action.But it has very strong osmosis to blade, can kill table
Subcutaneous pest, and the longevity of residure is long, its not ovicidal.Its mechanism of action its interference nervous physiology unlike general insecticide is lived
Dynamic, stimulation release r- aminobutyric acids, and r- aminobutyric acids have an inhibiting effect to the nerve conduction of arthropod, mite class is at, deutonymph
Occurs paralysis symptom after being contacted with medicament with larva with insect, inactive not feeding is dead after 2-4 days.Because not causing insect
Rapid dehydration, so its lethal effect is slower.Though but have direct killing effect to predatism and parasite, because of plant
Remained on surface is few, therefore small to the damage of beneficial insect.
Emamectin-benzoate (emamectin benzoate) chemical molecular formula：C49H75NO13·C7H6O2。
Emamectin-benzoate be it is a kind of efficiently, wide spectrum, the longevity of residure length insecticidal/acaricidal agent, the mechanism of action be hinder do harm to
Worm kinesitherapy nerve information is transmitted and keeps body paralysis dead.The mode of action also has action of contace poison based on stomach toxicity, to crop without interior
Absorption energy, but effectively penetrate into and apply crop epidermal tissue, thus there is the longer longevity of residure.To mite class, coleoptera and Homoptera
Pest has high activity, soil and in degradable noresidue, it is free from environmental pollution, in normal dosage ranges to beneficial insect and
Natural enemy, people, animal safety, can be with most of combined use of pesticides.
The mechanism of action of pleocidin (spinosad), pleocidin is very novel and unique, is different from general big ring
Lactone compound, unique chemical constitution determine its unique insecticidal mechanism.Pleocidin, which has insect, quickly to be touched
It kills and ingests toxicity, it is the nerveous system by stimulating insect that it, which has the distinctive poisoning symptom of never poison, its mechanism of action,
System, increases its constitutive activity, causes non-functional flesh to shrink, failure, and with trembling and benumbing, show nicotine type nicotinic acetyl
Choline receptor causes acetylcholine extended release to be reacted by sustained activation.Pleocidin also act on simultaneously γ-aminobutyric acid by
Body changes the function of GABA gate chloride channels, further promotes the raising of its insecticidal activity.
Ethyl pleocidin (spinetoram) chemical molecular formula：C42H69NO10, ethyl pleocidin is by ethyl mostly sterilization
Two kinds of groups of element-J and ethyl pleocidin-L are grouped as, and the nervous system of insect are acted on, to diamondback moth, beet armyworm, leaf mining
The control effect that fly, thrips, prodenia litura, bean-pod borer have had.
In the real process of agricultural production, the problem of pest control, evil mite most easily produce is the generation of drug resistance.No
It is compounded with kind ingredient, is to prevent the very common method of resistant insect, evil mite.Heterogeneity is compounded, according to reality
Application effect, to judge that certain compounding is synergy, adduction or antagonism.In most cases, the compounding effect of pesticide
All it is additive effect, really has the compounding of synergistic effect seldom, especially synergistic effect is clearly, co-toxicity coefficient is very high answers
With just less.It is found through inventor's a large number of experiments, it is fluorine lice sulfanilamide (SN) and avermectin, emamectin-benzoate, more
After bacteriocidin, ethyl pleocidin compounding, synergistic effect is notable, and Environmental compatibility is fabulous, considerably reduces pesticide usage amount.
Invention content
Composition pesticide proposed by the present invention is in addition to including fluorine lice sulfanilamide (SN) and avermectin, emamectin benzoate benzoic acid
Also include suitable surfactant and load outside two kinds of active components of any one in salt, pleocidin, ethyl pleocidin
Body.
A kind of composition pesticide of fluorine lice sulfanilamide (SN) and biogenic substances, including active components A and active constituent B, feature exist
In：Active components A be fluorine lice sulfanilamide (SN), active constituent B be selected from avermectin, emamectin-benzoate, pleocidin,
It is arbitrary a kind of in ethyl pleocidin, and active components A and the weight ratio of active constituent B are 1:80~80:1.
The composition pesticide, it is characterised in that：Active components A and the weight ratio of active constituent B are 1:40~60:1.
The composition pesticide, it is characterised in that：The weight ratio of fluorine lice sulfanilamide (SN) and avermectin is 1:10~20:1.
The composition pesticide, it is characterised in that：The weight ratio of fluorine lice sulfanilamide (SN) and emamectin-benzoate
It is 1:10~30:1.
The composition pesticide, it is characterised in that：The weight ratio of fluorine lice sulfanilamide (SN) and pleocidin is 1:10~20:1.
The composition pesticide, it is characterised in that：The weight ratio of fluorine lice sulfanilamide (SN) and ethyl pleocidin is 1:10~10:
1。
The composition pesticide, it is characterised in that：Composition is made wettable powder, water dispersible granules, suspending agent, hangs
Emulsion, aqueous emulsion, microemulsion, micro-capsule suspension, microcapsule suspension-suspendinagent agent.
The composition pesticide is used to prevent the application of crop pests, and the crops include rice, wheat, cotton
Flower, fruit tree, vegetables, tea tree, flowers, corn；The pest includes：Rice leaf roller, striped rice borer, yellow rice borer, planthopper, pickles
Moth, cabbage caterpillar, aphid, thrips, mite class, scale insect, chafer, weevil, suction pulp worm, 2 committee noctuid insect, citrus fruit fly.
The present invention composition pesticide in include at least a kind of surfactant, in favor of application when active component in water
Dispersion.Surface-active contents are the 5%~30% of total formulation weight, and surplus is solid or liquid diluent.The present invention's
Surfactant selected by composition pesticide is known in those skilled in the art：Dispersant, wetting agent, breast can be selected from
One or more of agent or antifoaming agent.
Include following constituent content when wettable powder is made：Active components A 0.1%~80%, active constituent B
0.1%~80%, dispersant 3%~15%, wetting agent 2%~10%, filler surplus.
Composition includes following constituent content when water dispersible granules are made：Active components A 0.1%~80%, active constituent
B0.1%~80%, dispersant 3%~12%, wetting agent 1%~10%, disintegrant 1%~10%, binder 0~8%, are filled out
Expect surplus.
Composition includes following constituent content when suspending agent is made：Active components A 0.1%~60%, active constituent
It is B0.1%~60%, dispersant 2~10%, wetting agent 2~10%, antifoaming agent 0.1~2%, thickener 0.05~2%, freeze proof
Agent 0~8%, deionized water add to 100%.
Composition includes following constituent content when suspension emulsion is made：Active components A 0.1%~60%, active constituent
B0.1%~60%, emulsifier 2%~12%, dispersant 2%~10%, antifoaming agent 0.1%~2%, thickener 0.05%~
2%, antifreeze 0~8%, stabilizer 0~5%, solvent 0~15%, deionized water add to 100%.
Composition includes following constituent content when aqueous emulsion is made：Activity ingredient A 0.1%~60%, active constituent
B0.1%~60%, solvent 0~30%, emulsifier 1%~15%, antifreeze 0~10%, thickener 0.05%~2%, defoaming
Agent 0.01%~2%, deionized water supply surplus.
Comprising following constituent content active components A 0.1%~60%, active constituent B when microemulsion is made in composition
0.1%~60%, solvent 0~30%, emulsifier 3%~20%, antifreeze 0~10%, thickener 0~2%, antifoaming agent
0.01%~2%, stabilizer 0~4%, deionized water surplus.
It includes following constituent content that micro-capsule suspension, which is made, in composition：Active components A 0.1%~60%, active constituent
B0.1%~60%, macromolecule cyst material 1%~12%, surfactant 2%~10%, organic solvent 1%~15%, breast
Agent 1%~8%, pH adjusting agent 0.1%~5%, deionized water adds to 100%.
Composition includes following constituent content when microcapsule suspension-suspendinagent agent is made：Active components A 0.1%~60% is lived
Property ingredient B 0.1%~60%, macromolecule cyst material 2%~12%, surfactant 3%~15%, organic solvent 1%~
5%, emulsifier 1%~6%, antifoaming agent 0.1%~5%, thickener 0.05%~2%, pH adjusting agent 0.1%~5%, water add
To 100%.
The wettable powder the key technical indexes of the present invention：
The water dispersible granules the key technical indexes of the present invention：
The suspending agent the key technical indexes of the present invention：
The suspension emulsion the key technical indexes of the present invention：
The aqueous emulsion the key technical indexes of the present invention：
The microemulsion the key technical indexes of the present invention：
The microcapsule suspending agent the key technical indexes of the present invention：
The microcapsule suspension-suspendinagent agent the key technical indexes of the present invention：
The advantage of the invention is that：
(1) fluorine lice sulfanilamide (SN) and avermectin, emamectin-benzoate, pleocidin, ethyl pleocidin are multiple
After matching, there is notable synergistic and lasting effect；
(2) expand prevention spectrum, on rice, wheat, cotton, fruit tree, vegetables, tea tree, corn rice leaf roller, two
Change snout moth's larva, yellow rice borer, planthopper, diamondback moth, cabbage caterpillar, aphid, thrips, mite class, scale insect, chafer, weevil, suction pulp worm, two
Point committee noctuid, citrus fruit fly etc. have greater activity；
(3) dosage for reducing pesticide reduces residual quantity of the pesticide on crop, alleviates environmental pollution；
(4) to safety of human and livestock, Environmental compatibility is good, is not likely to produce drug resistance.
Specific implementation mode
With reference to embodiment to further instruction of the present invention, the percentage in embodiment is weight percentage, but
The present invention is not limited thereto.
Application Example one
1 16.2% fluorine lice sulfanilamide (SN) avermectin wettable powder of embodiment
Fluorine lice sulfanilamide (SN) 16%, avermectin 0.2%, alkylnaphthalene sulfonate 5%, lauryl sodium sulfate 5%, kaolin add
To 100%, mixture carries out air-flow crushing, and 16.2% fluorine lice sulfanilamide (SN) avermectin wettable powder is made.
Avermectin, which is changed to emamectin-benzoate, pleocidin, ethyl pleocidin, can form new reality
Apply example.2 55% fluorine lice sulfanilamide (SN) avermectin wettable powder of embodiment
Fluorine lice sulfanilamide (SN) 50%, avermectin 5%, bis- (alkyl) naphthalenesulfonate formaldehyde condensation compounds 6%, dodecyl benzene sulfonic acid
Sodium 4%, attapulgite add to 100%, and mixture carries out air-flow crushing, and 55% fluorine lice sulfanilamide (SN) avermectin wettable powder is made
Agent.
Avermectin, which is changed to emamectin-benzoate, pleocidin, ethyl pleocidin, can form new reality
Apply example.3 20% fluorine lice sulfanilamide (SN) avermectin water dispersible granules of embodiment
Fluorine lice sulfanilamide (SN) 18%, avermectin 2%, naphthalene sulfonic acid-formaldehyde condensation product 5%, Nekal BX 4.5%, sodium bicarbonate
1.9%, kaolin adds to 100%, is mixed to prepare 20% fluorine lice sulfanilamide (SN) avermectin water dispersible granules.
Avermectin, which is changed to emamectin-benzoate, pleocidin, ethyl pleocidin, can form new reality
Apply example.4 81% fluorine lice sulfanilamide (SN) avermectin water dispersible granules of embodiment
Fluorine lice sulfanilamide (SN) 1%, avermectin 80%, wetting and penetrating agent F 2.5%, aryl phenol polyoxyethylene succinate sulfonic acid
Salt 4%, urea 2%, precipitated calcium carbonate add to 100%, are mixed to prepare 81% fluorine lice sulfanilamide (SN) avermectin water dispersible granules.
Avermectin, which is changed to emamectin-benzoate, pleocidin, ethyl pleocidin, can form new reality
Apply example.5 42% fluorine lice sulfanilamide (SN) avermectin suspending agent of embodiment
Fluorine lice sulfanilamide (SN) 40%, avermectin 2%, octylphenol polyethylene oxyethylene group ether sulfate 6%, tea seed cake 3.8%, silicone
0.1%, hydroxymethyl cellulose 0.16%, ethylene glycol 3.8%, deionized water add to 100%, are mixed to prepare 42% fluorine lice sulfanilamide (SN)
Avermectin suspending agent.
Avermectin, which is changed to emamectin-benzoate, pleocidin, ethyl pleocidin, can form new reality
Apply example.6 15% fluorine lice sulfanilamide (SN) avermectin suspending agent of embodiment
Fluorine lice sulfanilamide (SN) 10%, avermectin 5%, polycarboxylate 6.5%, spaonin powder 5%, silicone oil 0.12%, Arab
Glue 0.15%, propylene glycol 4%, deionized water add to 100%, are mixed to prepare 15% fluorine lice sulfanilamide (SN) avermectin suspending agent.
Avermectin, which is changed to emamectin-benzoate, pleocidin, ethyl pleocidin, can form new reality
Apply example.7 20% fluorine lice sulfanilamide (SN) avermectin suspension emulsion of embodiment
Fluorine lice sulfanilamide (SN) 15%, avermectin 5%, lignosulfonates 4.8%, spaonin powder 5.2%, phenyl phenol polyoxy second
Base ether phosphate 6%, butyl ether 8%, C10~20Saturated fat acids 0.09%, polyvinylpyrrolidone 0.11%, polyethylene glycol
3.0%, deionized water adds to 100%, is mixed to prepare 20% fluorine lice sulfanilamide (SN) avermectin suspension emulsion.
Avermectin, which is changed to emamectin-benzoate, pleocidin, ethyl pleocidin, can form new reality
Apply example.8 40% fluorine lice sulfanilamide (SN) avermectin suspension emulsion of embodiment
Fluorine lice sulfanilamide (SN) 32%, avermectin 8%, alkyl benzene sulfonate calcium salt 5%, spaonin powder 4%, triethanolamine salt 6%, ring
Hexanone 5%, silicone oil 0.08%, phenolic resin 0.15%, propylene glycol 3.1%, deionized water add to 100%, are mixed to prepare 40%
Fluorine lice sulfanilamide (SN) avermectin suspension emulsion.
Avermectin, which is changed to emamectin-benzoate, pleocidin, ethyl pleocidin, can form new reality
Apply example.9 7.5% fluorine lice sulfanilamide (SN) avermectin micro-emulsion of embodiment
Fluorine lice sulfanilamide (SN) 5%, avermectin 2.5%, alkylphenol-formaldehyde resin polyoxyethyl ether 7%, N- pyrrolidones 9%,
Polyethylene glycol 1%, polyvinylpyrrolidone 0.18%, C8~10Aliphatic alcohols 0.12%, deionized water supply 100%, mixing system
Obtain 7.5% fluorine lice sulfanilamide (SN) avermectin micro-emulsion.
Avermectin, which is changed to emamectin-benzoate, pleocidin, ethyl pleocidin, can form new reality
Apply example.10 10% fluorine lice sulfanilamide (SN) avermectin micro-emulsion of embodiment
Fluorine lice sulfanilamide (SN) 8%, avermectin 2%, acetonitrile 6%, polyvinylpyrrolidone 0.2%, phenyl phenol polyoxyethyl ether
7%, silicone compound 1.4%, deionized water supply 100%, and 10% fluorine lice sulfanilamide (SN) avermectin micro-emulsion is made.
Avermectin, which is changed to emamectin-benzoate, pleocidin, ethyl pleocidin, can form new reality
Apply example.11 30% fluorine lice sulfanilamide (SN) abamectin aqueous emulsion of embodiment
Fluorine lice sulfanilamide (SN) 20%, avermectin 10%, methanol 4%, ethylene glycol monomethyl ether 5.5%, epoxy ethane-epoxy propane are embedding
Section copolymer 6%, Arabic gum 0.18%, silicone 0.11%, deionized water adds to 100%, is mixed to prepare 30% fluorine lice sulphur
Amine abamectin aqueous emulsion.
Avermectin, which is changed to emamectin-benzoate, pleocidin, ethyl pleocidin, can form new reality
Apply example.12 15% fluorine lice sulfanilamide (SN) abamectin aqueous emulsion of embodiment
Fluorine lice sulfanilamide (SN) 5%, avermectin 10%, acetonitrile 3.5%, vegetable oil 5.5%, alkylaryl polyoxypropylene polyoxy second
Alkene ether 7%, polyvinylpyrrolidone 0.12%, C10~20Saturated fat acids 0.11%, deionized water adds to 100%, through mixing
15% fluorine lice sulfanilamide (SN) abamectin aqueous emulsion is made.
Avermectin, which is changed to emamectin-benzoate, pleocidin, ethyl pleocidin, can form new reality
Apply example.13 20% fluorine lice sulfanilamide (SN) avermectin microcapsule suspending agent of embodiment
Fluorine lice sulfanilamide (SN) 10%, avermectin 10%, deformation lactoprotein 3%, polyisocyanate 2%, spaonin powder 5%, naphthalene sulphur
Sour formaldehyde condensation products sodium salt 2.8%, propyl alcohol 4%, sorbitan fatty acid ester polyoxyethylene ether 5%, PH conditioning agent hydroxides
Sodium and hydrochloric acid amount to 3.6%, deionized water and add to 100% parts by weight, and it is outstanding that 20% fluorine lice sulfanilamide (SN) avermectin microcapsule is made
Floating agent.
Avermectin, which is changed to emamectin-benzoate, pleocidin, ethyl pleocidin, can form new reality
Apply example.14 6% fluorine lice sulfanilamide (SN) avermectin microcapsule suspension of embodiment-suspending agent
Fluorine lice sulfanilamide (SN) 0.5%, avermectin 5.5%, polyfunctional group acyl halide dihydric alcohol 5%, maltose 2%, silkworm excrement
2.5%, ethyl acetate 7%, alkylphenol-formaldehyde resin polyoxyethyl ether 5%, alkylaryl polyoxyethylene polyoxypropylene ether again 3%,
C8~10Aliphatic alcohols 0.15%, phenolic resin 1.2%, PH conditioning agents sodium hydroxide and hydrochloric acid amount to 3.9%, water and add to 100%
6% fluorine lice sulfanilamide (SN) avermectin microcapsule suspension-suspending agent is made in parts by weight.
Avermectin, which is changed to emamectin-benzoate, pleocidin, ethyl pleocidin, can form new reality
Apply example.15 10% fluorine lice sulfanilamide (SN) emamectin-benzoate wettable powder of embodiment
Fluorine lice sulfanilamide (SN) 9%, emamectin-benzoate 1%, ester polyoxyethylene be phonetic 5%, spaonin powder 4%, recessed
Convex stick soil adds to 100%, and mixture carries out air-flow crushing, and 10% fluorine lice sulfanilamide (SN) emamectin-benzoate is made can
Wet powder.
Emamectin-benzoate, which is changed to avermectin, pleocidin, ethyl pleocidin, can form new reality
Apply example.16 60% fluorine lice sulfanilamide (SN) emamectin-benzoate wettable powder of embodiment
Fluorine lice sulfanilamide (SN) 50%, emamectin-benzoate 10%, polyoxyethylene carboxylate 5%, silkworm excrement 5%,
Kaolin adds to 100%, and mixture carries out air-flow crushing, and 60% fluorine lice sulfanilamide (SN) emamectin-benzoate is made can
Wet powder.
Emamectin-benzoate, which is changed to avermectin, pleocidin, ethyl pleocidin, can form new reality
Apply example.17 12% fluorine lice sulfanilamide (SN) emamectin-benzoate water dispersible granules of embodiment
Fluorine lice sulfanilamide (SN) 9%, emamectin-benzoate 3%, aliphatic amine polyoxyethylene be phonetic 6%, tea seed cake 5%, chlorine
Change aluminium 2.5%, bentonite add to 100%, and it is water-dispersed to be mixed to prepare 12% fluorine lice sulfanilamide (SN) emamectin-benzoate
Granula.
Emamectin-benzoate, which is changed to avermectin, pleocidin, ethyl pleocidin, can form new reality
Apply example.18 62% fluorine lice sulfanilamide (SN) emamectin-benzoate water dispersible granules of embodiment
Fluorine lice sulfanilamide (SN) 60%, emamectin-benzoate 2%, sldium lauryl sulfate 5%, alkyl benzene sulfonate calcium salt
5%, ammonium sulfate 1.8%, kaolin add to 100%, are mixed to prepare 62% fluorine lice sulfanilamide (SN) emamectin-benzoate
Water dispersible granules.
Emamectin-benzoate, which is changed to avermectin, pleocidin, ethyl pleocidin, can form new reality
Apply example.19 20% fluorine lice sulfanilamide (SN) emamectin benzoate suspending agent of embodiment
The phonetic formaldehyde condensation products sulfuric acid of fluorine lice sulfanilamide (SN) 15%, emamectin-benzoate 5%, alkylphenol-polyethenoxy
Salt 5%, spaonin powder 3%, C8~10Aliphatic alcohols 0.1%, aluminum magnesium silicate 0.15%, propylene glycol 3.6%, deionized water add to
100%, it is mixed to prepare 20% fluorine lice sulfanilamide (SN) emamectin benzoate suspending agent.
Emamectin-benzoate, which is changed to avermectin, pleocidin, ethyl pleocidin, can form new reality
Apply example.20 15% fluorine lice sulfanilamide (SN) emamectin benzoate suspending agent of embodiment
Fluorine lice sulfanilamide (SN) 12%, emamectin-benzoate 3%, lignosulfonates 6%, silkworm excrement 4%, C8~10Fat
Fat alcohols 0.07%, white dextrin 0.15%, triethylene glycol 2%, deionized water add to 100%, are mixed to prepare 15% fluorine lice sulfanilamide (SN)
Emamectin benzoate suspending agent.
Emamectin-benzoate, which is changed to avermectin, pleocidin, ethyl pleocidin, can form new reality
Apply example.21 30.5% fluorine lice sulfanilamide (SN) emamectin-benzoate suspension emulsion of embodiment
Fluorine lice sulfanilamide (SN) 30%, emamectin-benzoate 0.5%, alkyl aryl polyoxyethylene ether 5%, pull open powder
BX5%, benzyl dimethyl phenol polyoxyethyl ether 6%, butanol 8%, C10~20Saturated fat acids 0.1%, polyvinylpyrrolidone
0.12%, polyethylene glycol 3.8%, deionized water add to 100%, are mixed to prepare 30.5% fluorine lice sulfanilamide (SN) emamectin benzoate
Benzoate suspension emulsion.
Emamectin-benzoate, which is changed to avermectin, pleocidin, ethyl pleocidin, can form new reality
Apply example.22 8.2% fluorine lice sulfanilamide (SN) emamectin-benzoate suspension emulsion of embodiment
Fluorine lice sulfanilamide (SN) 0.2%, emamectin-benzoate 8%, fatty alcohol polyoxyethylene ether 5%, dodecane
Base benzene sulfonic acid sodium salt 4%, alkyl biphenyl ether disulfonic acid magnesium salts 6%, N- pyrrolidones 5%, silicone 0.08%, phenolic resin
0.15%, propylene glycol 4%, deionized water add to 100%, are mixed to prepare 8.2% fluorine lice sulfanilamide (SN) emamectin benzoate benzene first
Hydrochlorate suspension emulsion.
Emamectin-benzoate, which is changed to avermectin, pleocidin, ethyl pleocidin, can form new reality
Apply example.23 11% fluorine lice sulfanilamide (SN) emamectin benzoate microemulsion of embodiment
Fluorine lice sulfanilamide (SN) 1%, emamectin-benzoate 10%, phenyl phenol polyoxyethyl ether 7%, cyclohexanone 4%,
Crosslinked polyvinylpyrrolidone 0.15%, capric acid 0.15%, deionized water supplies 100%, is mixed to prepare 11% fluorine lice sulfanilamide (SN)
Emamectin benzoate microemulsion.
Emamectin-benzoate, which is changed to avermectin, pleocidin, ethyl pleocidin, can form new reality
Apply example.24 20% fluorine lice sulfanilamide (SN) emamectin-benzoate aqueous emulsion of embodiment
Fluorine lice sulfanilamide (SN) 10%, emamectin-benzoate 10%, toluene 4%, 3-methyl cyclohexanol ketenes 5%, benzene
Ethyl phenol polyoxyethanyl polypropylene-base ether 6%, aluminum magnesium silicate 0.18%, silicone 0.05%, deionized water adds to 100%, mixes
It closes and 20% fluorine lice sulfanilamide (SN) emamectin-benzoate aqueous emulsion is made.
Emamectin-benzoate, which is changed to avermectin, pleocidin, ethyl pleocidin, can form new reality
Apply example.25 12% fluorine lice sulfanilamide (SN) emamectin-benzoate aqueous emulsion of embodiment
Fluorine lice sulfanilamide (SN) 10%, emamectin-benzoate 2%, acetonitrile 3.5%, solvent naphtha 5.5%, epoxy second
Alkane-propylene oxide block copolymer 5%, phenolic resin 0.12%, silicone oil 0.09%, deionized water adds to 100%, is made through mixing
Obtain 12% fluorine lice sulfanilamide (SN) emamectin-benzoate aqueous emulsion.
Emamectin-benzoate, which is changed to avermectin, pleocidin, ethyl pleocidin, can form new reality
Apply example.26 15% fluorine lice sulfanilamide (SN) emamectin-benzoate micro-capsule suspension of embodiment
Fluorine lice sulfanilamide (SN) 5%, emamectin-benzoate 10%, polyfunctional group acyl halide dihydric alcohol 3%, alginic acid
Sodium 2%, sldium lauryl sulfate 5%, lignosulfonates 5%, N- pyrrolidones 4%, epoxy ethane-epoxy propane block copolymerization
Object 5%, PH conditioning agents sodium hydroxide and citric acid amount to 2.8%, deionized water and add to 100% parts by weight, and 15% fluorine lice is made
Sulfanilamide (SN) emamectin-benzoate micro-capsule suspension.
Emamectin-benzoate, which is changed to avermectin, pleocidin, ethyl pleocidin, can form new reality
Apply example.27 12% fluorine lice sulfanilamide (SN) emamectin-benzoate microcapsule suspension-suspendinagent agent of embodiment
Fluorine lice sulfanilamide (SN) 2%, emamectin-benzoate 10%, urea 5%, formaldehyde 3%, tea seed cake 2.5%, butyl ether
7%, phenethyl phenol polyoxyethanyl polypropylene-base ether 5%, fatty alcohol polyoxyethylene ether 3%, silicone 1.6%, sodium tripolyphosphate
1.2%, PH conditioning agents sodium hydroxide and hydrochloric acid is total 3%, water adds to 100% parts by weight, and 12% fluorine lice sulfalene ammonia is made
Base abamectin benzoate microcapsule suspension-suspendinagent agent.
Emamectin-benzoate, which is changed to avermectin, pleocidin, ethyl pleocidin, can form new reality
Apply example.28 80% fluorine lice sulfanilamide (SN) pleocidin wettable powder of embodiment
Fluorine lice sulfanilamide (SN) 60%, pleocidin 20%, lignosulfonates 6%, lauryl sodium sulfate 5%, attapulgite
100% is added to, mixture carries out air-flow crushing, and 80% fluorine lice sulfanilamide (SN) pleocidin wettable powder is made.
Effective active composition pleocidin is changed to emamectin-benzoate, avermectin, ethyl to sterilize more
Element forms new embodiment.
29 30% fluorine lice sulfanilamide (SN) pleocidin wettable powder of embodiment
Fluorine lice sulfanilamide (SN) 20%, pleocidin 10%, fatty alcohol polyoxyethylene ether 6%, Nekal BX 5%, kaolin add
To 100%, mixture carries out air-flow crushing, and 30% fluorine lice sulfanilamide (SN) pleocidin wettable powder is made.
Effective active composition pleocidin is changed to avermectin, emamectin-benzoate, ethyl to sterilize more
Element forms new embodiment.
30 60% fluorine lice sulfanilamide (SN) pleocidin water dispersible granules of embodiment
Fluorine lice sulfanilamide (SN) 20%, pleocidin 40%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5%, silkworm excrement 6%, glucose
2.6%, bentonite adds to 100%, is mixed to prepare 60% fluorine lice sulfanilamide (SN) pleocidin water dispersible granules.
Effective active composition pleocidin is changed to avermectin, emamectin-benzoate, ethyl to sterilize more
Element forms new embodiment.
31 30% fluorine lice sulfanilamide (SN) pleocidin water dispersible granules of embodiment
Fluorine lice sulfanilamide (SN) 15%, pleocidin 15%, neopelex 5%, octyl phenol polyoxyethylene ether sulfuric acid
Salt 6%, ammonium sulfate 2%, kaolin add to 100%, are mixed to prepare
30% fluorine lice sulfanilamide (SN) pleocidin water dispersible granules.
Effective active composition pleocidin is changed to avermectin, emamectin-benzoate, ethyl to sterilize more
Element forms new embodiment.
32 15% fluorine lice sulfanilamide (SN) pleocidin suspension of embodiment
Fluorine lice sulfanilamide (SN) 10%, pleocidin 5%, alkyl benzene sulfonate calcium salt 5%, lauryl sodium sulfate 4%, silicone oil
0.1%, sodium tripolyphosphate 0.2%, glycerine 4%, deionized water add to 100%, are mixed to prepare 15% fluorine lice sulfanilamide (SN) and kill more
Rhzomorph suspending agent.
Effective active composition pleocidin is changed to avermectin, emamectin-benzoate, ethyl to sterilize more
Element forms new embodiment.
33 30% fluorine lice sulfanilamide (SN) pleocidin suspension of embodiment
Fluorine lice sulfanilamide (SN) 25%, pleocidin 5%, polycarboxylate 6%, tea seed cake 4%, silicone 0.07%, xanthans
0.14%, glycerine 3%, deionized water add to 100%, are mixed to prepare 30% fluorine lice sulfanilamide (SN) pleocidin suspension.
Effective active composition pleocidin is changed to avermectin, emamectin-benzoate, ethyl to sterilize more
Element forms new embodiment.
34 10% fluorine lice sulfanilamide (SN) pleocidin suspension emulsion of embodiment
Fluorine lice sulfanilamide (SN) 5%, pleocidin 5%, alkyl benzene sulfonate calcium salt 6%, wetting and penetrating agent F 4%, alkylphenol formaldehyde
Resin polyoxyethyl ether 6%, ethylene glycol monomethyl ether 5%, C10~20Saturated fat acids 0.1%, polyvinyl alcohol 0.12%, poly- second two
Alcohol 2.5%, deionized water add to 100%, are mixed to prepare 10% fluorine lice sulfanilamide (SN) pleocidin suspension emulsion.
Effective active composition pleocidin is changed to avermectin, emamectin-benzoate, ethyl to sterilize more
Element forms new embodiment.
35 25% fluorine lice sulfanilamide (SN) pleocidin suspension emulsion of embodiment
Fluorine lice sulfanilamide (SN) 5%, pleocidin 20%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 7%, sldium lauryl sulfate 6%, benzene second
Base fluosite polyoxyethyl ether 6%, ethyl acetate 4%, C8~10Aliphatic alcohols 0.1%, methylcellulose 0.15%, glycerine
4%, deionized water adds to 100%, is mixed to prepare 25% fluorine lice sulfanilamide (SN) pleocidin suspension emulsion.
Effective active composition pleocidin is changed to avermectin, emamectin-benzoate, ethyl to sterilize more
Element forms new embodiment.
36 21% fluorine lice sulfanilamide (SN) pleocidin microemulsion of embodiment
Fluorine lice sulfanilamide (SN) 20%, pleocidin 1%, propyl alcohol 6%, phenolic resin 0.18%, alkylaryl polyoxyethylene polyoxy
Propylene ether 6%, silicone 0.14%, deionized water supplies 100%, and 21% fluorine lice sulfanilamide (SN) pleocidin microemulsion is made.
Effective active composition pleocidin is changed to avermectin, emamectin-benzoate, ethyl to sterilize more
Element forms new embodiment.
37 20% fluorine lice sulfanilamide (SN) pleocidin microemulsion of embodiment
Fluorine lice sulfanilamide (SN) 15%, pleocidin 5%, cyclohexanone 6%, sodium acrylate 0.19%, sorbitan monostearate
7%, C8~10Aliphatic alcohols 0.09%, triethylene glycol 3.5%, deionized water supplies 100%, and 20% fluorine lice sulfanilamide (SN) is made and sterilizes more
Plain microemulsion.
Effective active composition pleocidin is changed to avermectin, emamectin-benzoate, ethyl to sterilize more
Element forms new embodiment.
38 25% fluorine lice sulfanilamide (SN) pleocidin aqueous emulsion of embodiment
Fluorine lice sulfanilamide (SN) 15%, pleocidin 10%, acetonitrile 5%, toluene 5%, alkyl biphenyl ether disulfonic acid magnesium salts 6%, Huang
Virgin rubber 0.18%, silicone compound 0.08%, ethylene glycol 4%, deionized water adds to 100%, is mixed to prepare 25% fluorine lice sulphur
Amine pleocidin aqueous emulsion.
Effective active composition pleocidin is changed to avermectin, emamectin-benzoate, ethyl to sterilize more
Element forms new embodiment.
39 30.5% fluorine lice sulfanilamide (SN) pleocidin aqueous emulsion of embodiment
Fluorine lice sulfanilamide (SN) 30%, pleocidin 0.5%, n,N-Dimethylformamide 5%, N-octylpyrrolidone 5%, alkane
Base fluosite polyoxyethyl ether 6%, xanthans 0.18%, C8~10Aliphatic alcohols 0.06%, deionized water adds to 100%,
It is mixed to prepare 30.5% fluorine lice sulfanilamide (SN) pleocidin aqueous emulsion.
Effective active composition pleocidin is changed to avermectin, emamectin-benzoate, ethyl to sterilize more
Element forms new embodiment.
40 11% fluorine lice sulfanilamide (SN) spinosad microcapsule suspending agent of embodiment
Fluorine lice sulfanilamide (SN) 1%, pleocidin 10%, urea 3%, sodium alginate 3%, sldium lauryl sulfate 5%, alkyl phenol are poly-
Ethylene oxide is phonetic 2.8%, vegetable oil 6%, styrene polyoxyethylene ether ammonium sulfate salt 5%, ph conditioning agents sodium hydroxide and hydrochloric acid are total
Meter 4%, deionized water adds to 100% parts by weight, and 11% fluorine lice sulfanilamide (SN) spinosad microcapsule suspending agent is made.
Effective active composition pleocidin is changed to avermectin, emamectin-benzoate, ethyl to sterilize more
Element forms new embodiment.
41 21% fluorine lice sulfanilamide (SN) pleocidin microcapsule suspension-suspendinagent agent of embodiment
Fluorine lice sulfanilamide (SN) 20%, pleocidin 1%, gelatin 5%, Arabic gum 2%, lauryl sodium sulfate 2.5%, plant
Oil 6%, phenethyl phenol formaldehyde resin polyoxyethyl ether 5%, silicone compound 0.06%, gather castor oil polyoxyethylene ether 3%
Vinylpyrrolidone 1.2%, ph conditioning agents sodium hydroxide and hydrochloric acid total 3.8%, deionized water adds to 100% parts by weight, system
Obtain 21% fluorine lice sulfanilamide (SN) pleocidin microcapsule suspension-suspendinagent agent.
Effective active composition pleocidin is changed to avermectin, emamectin-benzoate, ethyl to sterilize more
Element forms new embodiment.
42 60% fluorine lice sulfanilamide (SN) ethyl pleocidin wettable powder of embodiment
Fluorine lice sulfanilamide (SN) 50%, ethyl pleocidin 10%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 4%, dodecyl benzene sulfonic acid
Sodium 5%, diatomite add to 100%, and mixture carries out air-flow crushing, and 60% fluorine lice sulfanilamide (SN) ethyl pleocidin wettable is made
Pulvis.
Effective active composition ethyl pleocidin is changed to emamectin-benzoate, avermectin, more sterilizations
Element forms new embodiment.
43 30% fluorine lice sulfanilamide (SN) ethyl pleocidin wettable powder of embodiment
The phonetic formaldehyde condensation products sulfate 5% of fluorine lice sulfanilamide (SN) 15%, ethyl pleocidin 15%, alkylphenol-polyethenoxy, soap
Angle powder 4%, kaolin add to 100%, and mixture carries out air-flow crushing, and it is wettable that 30% fluorine lice sulfanilamide (SN) ethyl pleocidin is made
Property pulvis.
Effective active composition ethyl pleocidin is changed to avermectin, emamectin-benzoate, more sterilizations
Element forms new embodiment.
44 25% fluorine lice sulfanilamide (SN) ethyl pleocidin water dispersible granules of embodiment
Fluorine lice sulfanilamide (SN) 15%, ethyl pleocidin 10%, alkylphenol-polyethenoxy be phonetic 6%, tea seed cake 4%, aluminium chloride 3%,
Precipitated calcium carbonate adds to 100%, is mixed to prepare 25% fluorine lice sulfanilamide (SN) ethyl pleocidin water dispersible granules.
Effective active composition ethyl pleocidin is changed to avermectin, emamectin-benzoate, more sterilizations
Element forms new embodiment.
45 50% fluorine lice sulfanilamide (SN) ethyl pleocidin water dispersible granules of embodiment
The phonetic formaldehyde contracting of fluorine lice sulfanilamide (SN) 40%, ethyl pleocidin 10%, sldium lauryl sulfate 5%, alkylphenol-polyethenoxy
It closes object sulfate 6%, sodium carbonate 2%, kaolin and adds to 100%, be mixed to prepare 50% fluorine lice sulfanilamide (SN) ethyl pleocidin water
Dispersible granule.
Effective active composition ethyl pleocidin is changed to avermectin, emamectin-benzoate, more sterilizations
Element forms new embodiment.
46 30% fluorine lice sulfanilamide (SN) ethyl pleocidin suspending agent of embodiment
Fluorine lice sulfanilamide (SN) 20%, ethyl pleocidin 10%, polycarboxylate 5%, neopelex 4%, silicone
0.1%, phenolic resin 0.2%, glycerine 4%, deionized water add to 100%, are mixed to prepare 30% fluorine lice sulfanilamide (SN) ethyl and kill more
Rhzomorph suspending agent.
Effective active composition ethyl pleocidin is changed to avermectin, emamectin-benzoate, more sterilizations
Element forms new embodiment.
47 20% fluorine lice sulfanilamide (SN) ethyl pleocidin suspending agent of embodiment
The phonetic formaldehyde condensation products sulfate 5% of fluorine lice sulfanilamide (SN) 5%, ethyl pleocidin 15%, alkylphenol-polyethenoxy, bay
Alcohol sodium sulphate 4%, C8~10Aliphatic alcohols 0.07%, guar gum 0.14%, diethylene glycol (DEG) 3%, deionized water add to 100%, mixing system
Obtain 20% fluorine lice sulfanilamide (SN) ethyl pleocidin suspending agent.
Effective active composition ethyl pleocidin is changed to avermectin, emamectin-benzoate, more sterilizations
Element forms new embodiment.
48 25% fluorine lice sulfanilamide (SN) ethyl pleocidin suspension emulsion of embodiment
Fluorine lice sulfanilamide (SN) 20%, ethyl pleocidin 5%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, tea seed cake 4%, phenethyl phenol
Formaldehyde resin polyoxyethyl ether 6%, butyl ether 5%, silicone oil 0.1%, white dextrin 0.12%, diethylene glycol (DEG) 3.5%, deionized water add to
100%, it is mixed to prepare 25% fluorine lice sulfanilamide (SN) ethyl pleocidin suspension emulsion.
Effective active composition ethyl pleocidin is changed to avermectin, emamectin-benzoate, more sterilizations
Element forms new embodiment.
49 35% fluorine lice sulfanilamide (SN) ethyl pleocidin suspension emulsion of embodiment
Fluorine lice sulfanilamide (SN) 25%, ethyl pleocidin 10%, alkylphenol-polyethenoxy be phonetic 7%, lauryl sodium sulfate 6%,
Thermally coupled distillation columns 6%, N- pyrrolidones 4%, C10~20Saturated fat acids (such as capric acid) and amide
0.07%, hydroxymethyl cellulose 0.15%, ethylene glycol 4%, deionized water add to 100%, are mixed to prepare 35% fluorine lice sulfanilamide (SN)
Ethyl pleocidin suspension emulsion.
Effective active composition ethyl pleocidin is changed to avermectin, emamectin-benzoate, more sterilizations
Element forms new embodiment.
50 11% fluorine lice sulfanilamide (SN) ethyl pleocidin microemulsion of embodiment
Fluorine lice sulfanilamide (SN) 10%, ethyl pleocidin 1%, cyclohexanone 5%, xanthans 0.12%, sorbitol anhydride monostearate
Ester 6%, C8~10Aliphatic alcohols 0.14%, deionized water supplies 100%, and 11% fluorine lice sulfanilamide (SN) ethyl pleocidin micro emulsion is made
Agent.
Effective active composition ethyl pleocidin is changed to avermectin, emamectin-benzoate, more sterilizations
Element forms new embodiment.
51 30% fluorine lice sulfanilamide (SN) ethyl pleocidin aqueous emulsion of embodiment
Fluorine lice sulfanilamide (SN) 20%, ethyl pleocidin 10%, solvent naphtha 5%, vegetable oil 5%, styrene polyoxyethylene ether sulphur
Acid ammonium salt salt 6%, Arabic gum 0.11%, silicone 0.08%, triethylene glycol 4%, deionized water adds to 100%, is mixed to prepare
30% fluorine lice sulfanilamide (SN) ethyl pleocidin aqueous emulsion.
Effective active composition ethyl pleocidin is changed to avermectin, emamectin-benzoate, more sterilizations
Element forms new embodiment.
52 25% fluorine lice sulfanilamide (SN) ethyl pleocidin aqueous emulsion of embodiment
Fluorine lice sulfanilamide (SN) 12.5%, ethyl pleocidin 12.5%, 3-methyl cyclohexanol ketenes 5%, propyl alcohol 5%, phenethyl phenol
Formaldehyde resin polyoxyethyl ether 6%, sodium tripolyphosphate 0.18%, C10~20Saturated fat acids (such as capric acid) and amide 0.11%,
Deionized water adds to 100%, is mixed to prepare 25% fluorine lice sulfanilamide (SN) ethyl pleocidin aqueous emulsion.
Effective active composition ethyl pleocidin is changed to avermectin, emamectin-benzoate, more sterilizations
Element forms new embodiment.
53 30% fluorine lice sulfanilamide (SN) ethyl pleocidin micro-capsule suspension of embodiment
Fluorine lice sulfanilamide (SN) 10%, ethyl pleocidin 20%, polyisocyanate 4%, formaldehyde 3%, lauryl sodium sulfate
5%, the phonetic formaldehyde condensation products sulfate 2.8% of alkylphenol-polyethenoxy, acetonitrile 6%, alkyl biphenyl ether disulfonic acid magnesium salts 5%, ph
Conditioning agent sodium hydroxide and citric acid amount to 2.6%, deionized water and add to 100% parts by weight, and 30% fluorine lice sulfanilamide (SN) second is made
Quito bacteriocidin micro-capsule suspension.
Effective active composition ethyl pleocidin is changed to avermectin, emamectin-benzoate, more sterilizations
Element forms new embodiment.
54 20% fluorine lice sulfanilamide (SN) ethyl pleocidin microcapsule suspension-suspendinagent agent of embodiment
Fluorine lice sulfanilamide (SN) 10%, ethyl pleocidin 10%, deformation lactoprotein 5%, polyvinyl alcohol 2%, detergent alkylate sulphur
Sour sodium 2.5%, ethyl acetate 6%, ethylene oxide-propylene oxide block copolymer 5%, nonylphenol polyoxyethylene ether 3%, silicone
Class compound 0.6%, crosslinked polyvinylpyrrolidone 1.2%, sodium hydroxide 0.4%, citric acid 0.5%, water add to 100% weight
Part is measured, 20% fluorine lice sulfanilamide (SN) ethyl pleocidin microcapsule suspension-suspendinagent agent is made.
Effective active composition ethyl pleocidin is changed to avermectin, emamectin-benzoate, more sterilizations
Element forms new embodiment.
The embodiment of the present invention is the method being combined using Toxicity Determination and field trial.First pass through indoor virulence survey
It is fixed, the co-toxicity coefficient (CTC) after two kinds of medicaments compound by a certain percentage is defined, CTC ＜ 80 are antagonism, 80≤CTC≤120
For summation action, CTC ＞ 120 are synergistic effect, on this basis, then carry out field trial.
Test method：The mother liquor of each mixed agent is diluted to five series concentrations respectively when experiment, is respectively placed in beaker
It is spare.Using the first leaching leaf method that is followed by worm, by not in contact with the blade of the same size of any medicament in the liquid configured
It takes out, naturally dry, is put into insect box after immersion 5s, then connect for trying larva, raised under the conditions of 25 DEG C, often handle 3
Secondary repetition, it is 50 often to repeat test worm number used, while setting blank control, checks dead borer population in 72h, calculates the death rate and correction
The death rate acquires virulence regression equation and calculates LC50Value.If compareing the death rate is more than 10%, it is considered as invalid experiment.It calculates public
Formula is as follows：
Pest corrected mortality is converted into probit value (y), concentration for the treatment of (μ g/ml) is converted into logarithm (x), with minimum
Square law obtains virulence regression equation, and thus calculates the value of each medicament.Total poison system is calculated according to the abundant equations of Sun Yun
Number CTC.Calculation formula is following (using fluorine lice sulfanilamide (SN) as standard agent, toxicity index 100)：
TI × P activity of TI × P fluorine lice sulfanilamide (SN)+active constituent B of the theoretical toxicity index (TTI) of M=fluorine lice sulfanilamide (SN) at
Divide B
In formula：M is the mixture of different ratio；
P active constituents B is active constituent B shared ratios in the composition；
P fluorine lice sulfanilamide (SN) is fluorine lice sulfanilamide (SN) shared ratio in the composition.
Note：Active constituent B is in avermectin, emamectin-benzoate, pleocidin, ethyl pleocidin
It is arbitrary a kind of.
Application Example two：
For trying pest：Rice hoppers.
Experimental design：Having for fluorine lice sulfanilamide (SN), the former medicine of AVM and the two different ratio mixture is determined by pilot study
Imitate lethasl concentration range.
Toxicity test result one
1 fluorine lice sulfanilamide (SN) of table is with avermectin different ratio to the toxicity test of rice hoppers
As shown in Table 1, fluorine lice sulfanilamide (SN) fits over 80 with abamectin compounded prevention rice hoppers:1 to 1:It is malicious altogether when 80
Coefficient is all higher than 120, illustrates the two 80:1 to 1:Mixture shows synergistic effect in 80 ranges, especially when fluorine lice sulfanilamide (SN)
It must be matched 20 with avermectin:1 to 1:When 10, synergistic effect becomes apparent protrusion, wherein when fluorine lice sulfanilamide (SN) and avermectin
Weight ratio is 2:Co-toxicity coefficient is maximum when 1, and synergistic effect is the most apparent.It finds simultaneously, fluorine lice sulfanilamide (SN) is matched with avermectin
20:1、19:1、18:1、17:1、16:1、15:1、14:1、13:1、12:1、11:1、10:1、9:1、8:1、7:1、6:1、5:1、4:
1、3:1、2:1、1:1、1:2、1:3、1:4、1:5、1:6、1:7、1:8、1:9、1:Compounding is to rice leaf roller, rice borer when 10
Worm, planthopper, diamondback moth, cabbage caterpillar, aphid, thrips, mite class, scale insect, chafer, weevil, suction pulp worm, 2 committee noctuid insect,
Also there is the pests such as citrus fruit fly preferable synergistic effect, co-toxicity coefficient to be all higher than 120.
Application Example three：
For trying pest：Paddy rice rice leaf roller.
Experimental design：Fluorine lice sulfanilamide (SN), Methylaminoemamectin benzoate and the two are determined by pilot study not
With effective lethasl concentration range of proportioning mixture.
Toxicity test result two
2 fluorine lice sulfanilamide (SN) of table is with emamectin-benzoate different ratio to the toxicity test of paddy rice rice leaf roller
As shown in Table 2, fluorine lice sulfanilamide (SN) compounds matching for prevention paddy rice rice leaf roller with emamectin-benzoate
Than 80:1 to 1:When 80, co-toxicity coefficient is all higher than 120, illustrates the two 80:1 to 1:Mixture shows synergy in 80 ranges
Effect, especially when the proportioning of fluorine lice sulfanilamide (SN) and emamectin-benzoate is 30:1 to 1:When 10, synergistic effect is more
Obviously to protrude, wherein when fluorine lice sulfanilamide (SN) and emamectin-benzoate weight ratio are 3:Co-toxicity coefficient is maximum when 1, increases
Effect effect is the most apparent, finds simultaneously, and fluorine lice sulfanilamide (SN) is matched with emamectin-benzoate 30:1、29:1、28:1、
27:1、26:1、25:1、24:1、23:1、22:1、21:1、20:1、19:1、18:1、17:1、16:1、15:1、14:1、13:1、
12:1、11:1、10:1、9:1、8:1、7:1、6:1、5:1、4:1、3:1、2:1、1:1、1:2、1:3、1:4、1:5、1:6、1:7、1:
8、1:9、1:Compounding is to rice leaf roller, the snout moth's larva of rice, planthopper, diamondback moth, cabbage caterpillar, aphid, thrips, mite class, Jie when 10
The pests such as shell worm, chafer, weevil, suction pulp worm, 2 committee noctuid insect, citrus fruit fly also have preferable synergistic effect, altogether poison system
Number is all higher than 140.
Application Example four：
For trying pest：Wild cabbage diamondback moth.
Experimental design：Fluorine lice sulfanilamide (SN), ethyl pleocidin active compound and the two different ratio mixture are determined by pilot study
Effective lethasl concentration range.
Toxicity test result three
3 fluorine lice sulfanilamide (SN) of table is with ethyl pleocidin different ratio to the toxicity test of wild cabbage diamondback moth
As shown in Table 3, fluorine lice sulfanilamide (SN) prevents the proportioning of wild cabbage diamondback moth 80 with ethyl pleocidin compounding:1 to 1:80
When, co-toxicity coefficient is all higher than 120, illustrates the two 80:1 to 1:Mixture shows synergistic effect in 80 ranges, especially when
The proportioning of fluorine lice sulfanilamide (SN) and ethyl pleocidin is 20:1 to 1:When 10, synergistic effect becomes apparent protrusion, wherein when fluorine lice sulphur
Amine is 1 with ethyl pleocidin weight ratio:Co-toxicity coefficient is maximum when 1, and synergistic effect is the most apparent, finds simultaneously, fluorine lice sulfanilamide (SN)
It is matched 20 with ethyl pleocidin:1、10:1、9:1、8:1、7:1、6:1、5:1、4:1、3:1、2:1、1:1、1:2、1:3、1:
4、1:5、1:6、1:7、1:8、1:9、1:When 10, compounding to rice leaf roller, the snout moth's larva of rice, planthopper, diamondback moth, cabbage caterpillar,
The pests such as aphid, thrips, mite class, scale insect, chafer, weevil, suction pulp worm, 2 committee noctuid insect, citrus fruit fly also have preferable
Synergistic effect, co-toxicity coefficient is all higher than 150.
Application Example five：
For trying pest：Apple aphid.
Experimental design：Having for fluorine lice sulfanilamide (SN), pleocidin active compound and the two different ratio mixture is determined by pilot study
Imitate lethasl concentration range.
Toxicity test result four
4 fluorine lice sulfanilamide (SN) of table is with pleocidin different ratio to the toxicity test of apple aphid
As shown in Table 4, fluorine lice sulfanilamide (SN) prevents the proportioning of apple aphid 80 with pleocidin compound:1 to 1:It is malicious altogether when 80
Coefficient is all higher than 120, illustrates the two 80:1 to 1:Mixture shows synergistic effect in 80 ranges, especially when fluorine lice sulfanilamide (SN)
Proportioning with pleocidin is 20:1 to 1:When 10, synergistic effect becomes apparent protrusion, wherein when fluorine lice sulfanilamide (SN) and pleocidin
Weight ratio is 2:Co-toxicity coefficient is maximum when 1, and synergistic effect is the most apparent, finds simultaneously, and fluorine lice sulfanilamide (SN) is matched with pleocidin
20:1、19:1、18:1、17:1、16:1、15:1、14:1、13:1、12:1、11:1、10:1、9:1、8:1、7:1、6:1、5:1、4:
1、3:1、2:1、1:1、1:2、1:3、1:4、1:5、1:6、1:7、1:8、1:9、1:Compounding is to rice leaf roller, rice borer when 10,
Worm, planthopper, diamondback moth, cabbage caterpillar, aphid, thrips, mite class, scale insect, chafer, weevil, suction pulp worm, 2 committee noctuid insect,
Also there is the pests such as citrus fruit fly preferable synergistic effect, co-toxicity coefficient to be all higher than 140.
Application Example hexafluoro lice sulfanilamide (SN) and avermectin, emamectin-benzoate, pleocidin, ethyl are more
The effect experiment of bacteriocidin and its compounding prevention wild cabbage diamondback moth
This experiment is arranged in Qishan County of Baoji, Shaanxi province city, and test medicine is carried by Shaanxi Welch Crop Protection Co., Ltd.
For, 10% fluorine lice sulfanilamide (SN) suspending agent (autogamy) of comparison medicament, 2% abamectin emulsifiable concentrate (purchased in market), 3% emamectin benzoate benzene
The ethyl pleocidin suspending agent (purchased in market) of formates water dispersible granules, 5% pleocidin suspension (purchased in market), 60 grams per liters.
Experiment uses conventional spray-on process, wild cabbage diamondback moth insect pest index is investigated before medicine, in insect pest early period of origination dispenser, dispenser
It investigates insect pest indexes and calculates preventive effect within 1 day afterwards, 3 days, 7 days.Experimental result is as follows：
5 fluorine lice sulfanilamide (SN) of table and avermectin, emamectin-benzoate, pleocidin, ethyl pleocidin and
It compounds the prevention wild cabbage diamondback moth test of pesticide effectiveness
As can be seen from Table 5, fluorine lice sulfanilamide (SN) and avermectin, emamectin-benzoate, pleocidin, ethyl
Wild cabbage diamondback moth can be effectively prevented after pleocidin compound, control effect is superior to the preventive effect of single dose, and efficiency time is long.It is trying
It tests in scope of medication and has no adverse effects to target crop.
Seven fluorine lice sulfanilamide (SN) of Application Example and avermectin and its test of pesticide effectiveness of compounding prevention rice-stem borer
This experiment is arranged in Sichuan Province Bazhong City Pingchang County, and test medicine is carried by Shaanxi Welch Crop Protection Co., Ltd.
For, 10% fluorine lice sulfanilamide (SN) suspending agent (autogamy), 2% abamectin emulsifiable concentrate (purchased in market), 3% emamectin-benzoate water
The ethyl pleocidin suspending agent (purchased in market) of dispersible granule, 5% pleocidin suspension (purchased in market), 60 grams per liters.
Experiment uses conventional spray-on process, rice-stem borer insect pest index is investigated before medicine, in insect pest early period of origination dispenser, dispenser
It investigates insect pest indexes and calculates preventive effect within 1 day afterwards, 5 days, 7 days.Experimental result is as follows：
6 fluorine lice sulfanilamide (SN) of table and avermectin, emamectin-benzoate, pleocidin, ethyl pleocidin and
It compounds the prevention rice-stem borer test of pesticide effectiveness
As can be seen from Table 6, fluorine lice sulfanilamide (SN) and avermectin, emamectin-benzoate, pleocidin, ethyl
Rice-stem borer can be effectively prevented after pleocidin compound, control effect is superior to the preventive effect of single dose, and efficiency time is long.It is trying
It tests in scope of medication and has no adverse effects to target crop.
Application Example octafluoro lice sulfanilamide (SN) and avermectin, emamectin-benzoate, pleocidin, ethyl are more
Bacteriocidin and its compounding and its test of pesticide effectiveness of compounding prevention cotton boll worm
This experiment is arranged in Xi'an City, Shanxi Province Changan District, and test medicine is carried by Shaanxi Welch Crop Protection Co., Ltd.
For, 10% fluorine lice sulfanilamide (SN) suspending agent (autogamy), 2% abamectin emulsifiable concentrate (purchased in market), 3% emamectin-benzoate water
The ethyl pleocidin suspending agent (purchased in market) of dispersible granule, 5% pleocidin suspension (purchased in market), 60 grams per liters.
Experiment uses conventional spray-on process, cotton boll pests index is investigated before medicine, in insect pest early period of origination dispenser, dispenser
It investigates insect pest indexes and calculates preventive effect within 1 day afterwards, 5 days, 7 days.Experimental result is as follows：
7 fluorine lice sulfanilamide (SN) of table, avermectin, emamectin-benzoate, pleocidin, ethyl pleocidin and its
The compounding prevention cotton boll worm test of pesticide effectiveness
As can be seen from Table 7, fluorine lice sulfanilamide (SN) and avermectin, emamectin-benzoate, pleocidin, ethyl
Cotton boll worm can be effectively prevented after pleocidin compound, control effect is superior to the preventive effect of single dose, and efficiency time is long.It is trying
It tests in scope of medication and has no adverse effects to target crop.
Nine fluorine lice sulfanilamide (SN) of Application Example and avermectin, emamectin-benzoate, pleocidin, ethyl are more
Bacteriocidin and its compounding prevention rice hoppers test of pesticide effectiveness
This experiment is arranged in Shaanxi Province Weinan City Pucheng County, and test medicine is carried by Shaanxi Welch Crop Protection Co., Ltd.
For, 10% fluorine lice sulfanilamide (SN) suspending agent (autogamy) of comparison medicament, 2% abamectin emulsifiable concentrate (purchased in market), 3% emamectin benzoate benzene
The ethyl pleocidin suspending agent (purchased in market) of formates water dispersible granules, 5% pleocidin suspension (purchased in market), 60 grams per liters.
Experiment uses conventional spray-on process, cotton pink bollworm insect pest index is investigated before medicine, in insect pest early period of origination dispenser, dispenser
It investigates insect pest indexes and calculates preventive effect within 1 day afterwards, 5 days, 7 days.Experimental result is as follows：
8 fluorine lice sulfanilamide (SN) of table, avermectin, emamectin-benzoate, pleocidin, ethyl pleocidin and its
The compounding prevention rice hoppers test of pesticide effectiveness
As can be seen from Table 8, fluorine lice sulfanilamide (SN) and avermectin, emamectin-benzoate, pleocidin, ethyl
Rice hoppers can be effectively prevented after pleocidin compound, control effect is superior to the preventive effect of single dose, and efficiency time is long.It is trying
It tests in scope of medication and has no adverse effects to target crop.
Ten fluorine lice sulfanilamide (SN) of Application Example and avermectin, emamectin-benzoate, pleocidin, ethyl are more
The test of pesticide effectiveness of bacteriocidin and its compounding prevention eggplant thrips
This experiment is arranged in Shaanxi Province Yangling District, and test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd., right
According to 10% fluorine lice sulfanilamide (SN) suspending agent (autogamy) of medicament, 2% abamectin emulsifiable concentrate (purchased in market), 3% emamectin benzoate benzoic acid
The ethyl pleocidin suspending agent (purchased in market) of brine dispersion granula, 5% pleocidin suspension (purchased in market), 60 grams per liters.
Experiment uses conventional spray-on process, eggplant thrips insect pest index is investigated before medicine, in insect pest early period of origination dispenser, after dispenser
It investigates insect pest indexes and calculates preventive effect within 1 day, 5 days, 7 days.Experimental result is as follows：
9 fluorine lice sulfanilamide (SN) of table, avermectin, emamectin-benzoate, pleocidin, ethyl pleocidin and its
The compounding prevention eggplant thrips test of pesticide effectiveness
As can be seen from Table 9, fluorine lice sulfanilamide (SN) and avermectin, emamectin-benzoate, pleocidin, ethyl
Eggplant thrips can be effectively prevented after pleocidin compound, control effect is superior to the preventive effect of single dose, and efficiency time is long.It is testing
It has no adverse effects to target crop in scope of medication.
11 fluorine lice sulfanilamide (SN) of Application Example and avermectin, emamectin-benzoate, pleocidin, ethyl
Pleocidin and its compounding prevention corn 2 committee noctuid insect test of pesticide effectiveness
This experiment is arranged in Xi'an City, Shanxi Province Changan District, and test medicine is carried by Shaanxi Welch Crop Protection Co., Ltd.
For, 10% fluorine lice sulfanilamide (SN) suspending agent (autogamy) of comparison medicament, 2% abamectin emulsifiable concentrate (purchased in market), 3% emamectin benzoate benzene
The ethyl pleocidin suspending agent (purchased in market) of formates water dispersible granules, 5% pleocidin suspension (purchased in market), 60 grams per liters.
Experiment investigates corn 2 committee noctuid insect insect pest index using conventional spray-on process before medicine, in insect pest early period of origination dispenser,
1 day after dispenser, investigates insect pest indexes and calculate preventive effect within 5 days, 7 days.Experimental result is as follows：
10 fluorine lice sulfanilamide (SN) of table, avermectin, emamectin-benzoate, pleocidin, ethyl pleocidin and
It compounds the prevention corn 2 committee noctuid insect test of pesticide effectiveness
As can be seen from Table 10, fluorine lice sulfanilamide (SN) and avermectin, emamectin-benzoate, pleocidin, second
Corn 2 committee noctuid insect can be effectively prevented after base pleocidin compound, control effect is superior to the preventive effect of single dose, and efficiency time
It is long.It has no adverse effects to target crop in experiment scope of medication.
Ten difluoro lice sulfanilamide (SN) of Application Example and avermectin, emamectin-benzoate, pleocidin, ethyl
The test of pesticide effectiveness of pleocidin and its compounding prevention cucumber aleyrodid
This experiment is arranged in XiaoShan, HangZhou City, Zhejiang Province area, and test medicine is carried by Shaanxi Welch Crop Protection Co., Ltd.
For, 10% fluorine lice sulfanilamide (SN) suspending agent (autogamy) of comparison medicament, 2% abamectin emulsifiable concentrate (purchased in market), 3% emamectin benzoate benzene
The ethyl pleocidin suspending agent (purchased in market) of formates water dispersible granules, 5% pleocidin suspension (purchased in market), 60 grams per liters.
Experiment uses conventional spray-on process, and investigating cucumber powder mite before medicine does harm to index, in insect pest early period of origination dispenser, after dispenser
It investigates insect pest indexes and calculates preventive effect within 1 day, 5 days, 7 days.Experimental result is as follows：
11 fluorine lice sulfanilamide (SN) of table, avermectin, emamectin-benzoate, pleocidin, ethyl pleocidin and
It compounds the prevention cucumber aleyrodid test of pesticide effectiveness
As can be seen from Table 11, fluorine lice sulfanilamide (SN) and avermectin, emamectin-benzoate, pleocidin, second
Cucumber aleyrodid can be effectively prevented after base pleocidin compound, control effect is superior to the preventive effect of single dose, and efficiency time is long.It is trying
It tests in scope of medication and has no adverse effects to target crop.
The experiment by different places throughout the country obtains afterwards, fluorine lice sulfanilamide (SN) and avermectin, emamectin benzoate
Wettable powder, water dispersible granules, suspending agent, suspension emulsion, water is made in benzoate, ethyl pleocidin, pleocidin compound
To rice leaf roller, the snout moth's larva of rice, the rice on all kinds of crops after emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent
The small reality of plant hopper, diamondback moth, cabbage caterpillar, aphid, thrips, mite class, scale insect, chafer, weevil, suction pulp worm, 2 committee noctuid insect, tangerine
The preventive effect of the common insect pests such as fly 95% or more, is better than single dose preventive effect, and synergistic effect is apparent.
Claims (7)
1. a kind of composition pesticide of fluorine-containing lice sulfanilamide (SN) and biogenic substances, including active components A and active constituent B, feature exist
In：Active components A is fluorine lice sulfanilamide (SN), and active constituent B is arbitrary a kind of in pleocidin, ethyl pleocidin, and activity
The weight ratio 1 of ingredient A and active constituent B:80~80:1.
2. composition pesticide according to claim 1, it is characterised in that：Active components A and the weight ratio of active constituent B are
1:40~60:1.
3. composition pesticide according to claim 2, it is characterised in that：The weight ratio of fluorine lice sulfanilamide (SN) and pleocidin is 1:
10~20:1.
4. composition pesticide according to claim 2, it is characterised in that：The weight ratio of fluorine lice sulfanilamide (SN) and ethyl pleocidin
It is 1:10~10:1.
5. the composition pesticide according to any one of Claims 1 to 4, it is characterised in that：Wettable is made in composition
Pulvis, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, micro-capsule suspension, microcapsule suspension-suspendinagent agent.
6. composition pesticide according to claim 5 is used to prevent the application of crop pests.
7. application according to claim 6, it is characterised in that institute's pest control includes：Rice leaf roller, striped rice borer, three change
Snout moth's larva, planthopper, diamondback moth, cabbage caterpillar, aphid, thrips, mite class, scale insect, chafer, weevil, suction pulp worm, 2 committee noctuid insect,
Citrus fruit fly.
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| CN201610087542.6A CN105746521B (en) | 2012-04-12 | 2012-04-12 | A kind of composition pesticide of fluorine-containing lice sulfanilamide (SN) and biogenic substances |
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Non-Patent Citations (2)
| Title |
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| "10%SIOC-I-002水乳剂配方研究";沈娟等;《上海化工》;20110430;第36卷(第04期);第6-9页 * |
| "氟虱磺胺(SIOC-I-002)对水稻褐飞虱的生物活性及田间防效";付群梅 等;《植物保护学报》;20120228;第39卷(第1期);第95-96页 * |
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Address after: 715500 Pucheng Shaanxi chemical base industrial park, Shaanxi, Weinan Patentee after: Shaanxi yitianfeng crop Technology Co.,Ltd. Address before: 715500 Pucheng Shaanxi chemical base industrial park, Shaanxi, Weinan Patentee before: Shaanxi Welch Crop Protection Co.,Ltd. |
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