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CN105731969B - A kind of inorganic ecological decoration sheet material of photocatalysis and its production method - Google Patents

A kind of inorganic ecological decoration sheet material of photocatalysis and its production method Download PDF

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CN105731969B
CN105731969B CN201610119278.XA CN201610119278A CN105731969B CN 105731969 B CN105731969 B CN 105731969B CN 201610119278 A CN201610119278 A CN 201610119278A CN 105731969 B CN105731969 B CN 105731969B
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inorganic
pore
ecological
sheet material
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CN105731969A (en
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韦华
童军
温发华
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Hubei Gelinsen New Building Materials Science And Technology (yingcheng) Co Ltd
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Hubei Gelinsen Green Materials Ltd By Share Ltd
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    • C—CHEMISTRY; METALLURGY
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    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • C04B28/145—Calcium sulfate hemi-hydrate with a specific crystal form
    • C04B28/147—Calcium sulfate hemi-hydrate with a specific crystal form beta-hemihydrate
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    • C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators or shrinkage compensating agents
    • C04B22/06—Oxides, Hydroxides
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    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04—Portland cements
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    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/08—Slag cements
    • C—CHEMISTRY; METALLURGY
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    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • C04B28/145—Calcium sulfate hemi-hydrate with a specific crystal form
    • C04B28/146—Calcium sulfate hemi-hydrate with a specific crystal form alpha-hemihydrate
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    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
    • C04B2103/0072—Biodegradable materials
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    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/60—Agents for protection against chemical, physical or biological attack
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    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
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    • C04B2103/69—Fungicides
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    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00008—Obtaining or using nanotechnology related materials
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    • C04B2111/00017—Aspects relating to the protection of the environment
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    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00603—Ceiling materials
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    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C04B2111/2038—Resistance against physical degradation
    • C04B2111/2061—Materials containing photocatalysts, e.g. TiO2, for avoiding staining by air pollutants or the like
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    • C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
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    • C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Finishing Walls (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of inorganic ecological decoration sheet material of photocatalysis and its production method, the inorganic ecological decoration sheet material of photocatalysis, it is characterised in that described ecological decoration sheet material is prepared by the raw material of following parts by weight：1.0~8.0 parts of pore catalysis materials, 100 parts of inorganic ecology gelling powders, 1.5~20 parts of reinforcing fibers and/or glass fiber reticular cloth, 0.3~5.0 part of hydrophobicity waterproofing agent, 18.5~68.0 parts of liquid mediums.Above-mentioned raw materials through photocatalysis it is supported, it is inorganic ecology gelling powder pretreatment, mix, cast or compacting extruding or injection molding, maintenance dry, process of surface treatment environmental series decoration plate material is made, can be used as smallpox, wallboard, the material extensive use such as material, outer curtain wall, retaining outside unlimited plastic decoration expressive force and excellent mechanical property, with more ecological functions such as purification air, antibacterial and mouldproof, anti-fouling and self-cleanings.

Description

A kind of inorganic ecological decoration sheet material of photocatalysis and its production method
Technical field
The present invention relates to decorative building material field, have in particular to one kind under illumination condition decompose environment harmful gas, Antibacterial and mouldproof, the photocatalysis ecological decoration sheet material of anti-fouling and self-cleaning and its production method.
Background technology
Since Fujishima in 1972 etc. has found the TiO of raying2Since lasting redox reaction occurs for surface, It is the maximally effective approach of volatile harmful gase in degraded room air that photocatalysis technology, which is asserted, while it is micro- to decompose surface attachment It is biological and it is super hydrophilic effect and reduce adhesive force of the organic dirt surface in building material surface, so as to mitigate environment harmful gas dirt Dye, antibacterial, antifouling purpose.
Reach more than 2,000 hundred million yuan every year in Japanese photocatalysis or photocatalyst market, and increased every year with more than 10% speed, In the Chinese annual market capacity for there are 10,000,000,000 yuan, count within 2010 and developed with the growth rate of every annual 13%, it is contemplated that 10 years Domestic market scale is up to tens billion of members afterwards.The market of such potentiality, just relying on it, there is pernicious gas decomposition, antibacterial to prevent The ecological functions such as mould, antifouling, and the application technology and product of photocatalysis at present or photocatalyst are：
1st, photocatalyst coating and coating or immersion applications technology, relevant photocatalysis spraying technology scheme disclosed in patent document Have：CN202047555U, CN202045937U, CN202463029U, CN2763394Y, CN1896438A, its common feature are Photocatalyst coating is coated with base material (artificial sand rock plate, composited aluminum and plastic decking, color steel, composite floor board) surface, its substantive characteristics is The application of light catalyzed coating and coat, because surface weatherability influence, exist top layer come off, top layer closing cause catalyst to lose Effect；
2nd, catalysis material embedding-pyrosol application technology, relevant photocatalysis embedding-high temperature disclosed in patent document are molten Glue technical scheme has：CN101952116A, CN101024170A, its common feature are ceramics, the glass for high-temperature fusion technique Glass makes its product have purification, antibacterial, antifouling effect with pyrosol method combination photocatalysis technology；
3rd, the high-temperature oxydation application technology of catalysis material, known technology is photocatalytic metal sheet material, by Titanium plus not Noble metal to 1% forms, and its surface is formed TiO with surface oxidation method2, the harmful gas of oxidation is decomposed under ultraviolet irradiation Body；
4th, application technology, a kind of photocatalyst verdelite grain solid polymer composite face disclosed in patent document are mixed in catalysis material In material and preparation method thereof CN102320777A, using resin as gluing matrix, filled out with being mixed in tourmaline, quartz sand, light catalase Fill and be prepared into a kind of functional form solid polymer composite plane materiel.Known technology has photocatalysis concrete segment, mixes TiO by interior2Micro mist is extremely Concrete segment is used for the laying of highway, makes it have except the function of nitrogen oxides in vehicle exhaust, due to NOxGenerated after oxidation Product HNO3Surface is adsorbed in, it is necessary to which regular removing regeneration just can guarantee that TiO2Photocatalytic effect, it is only suitable in area of heavy rainfull Use.
Photocatalysis technology as improve purification of air, antibacterial and mouldproof, antifouling cutting edge technology, be with improve human lives, The space environment of work is value, meanwhile, its oxidation Decomposition is not an independent process, and it includes gas diffusion, absorption, divided Solution and desorption process, its photocatalysis must be application space surface action in the most strong place of cross-ventilation, and adhere to On with porous carrier, could the preferably diffusion beneficial to gas and the absorption of pernicious gas and catabolite it is de- Attached, thus using photocatalysis technology to rely on, the decorative panel vector product that must be applied with space environment will turn into photocatalysis skill Art scale application field.
And decorative panel mainly includes polymer matrix decorative panel, Metal Substrate decorative panel, inorganic decorative panel at present, wherein polymerizeing Thing base decorative panel is thought with resin type dalle, such as acrylic, man-made glass, PVC board, composite laminate, wood-plastic clad plate, thousand Plate is representative, is waited because harsh high temperature sintering be present or dissolve technique or addition thermoplastic resin and adhesive, because single is put down Face type product expressive force, thermosol deformation and organic matter thermal decomposition pollution sources formed physical property with the drawbacks of ecological performance differentiation and Using limited；Metal Substrate decorative panel is with magnesium-aluminum alloy plate, stainless steel plate, copper coin, galvanized sheet, aluminum-pinch, aluminium-plastic panel etc. by crowded Cost is higher while pressing technique formation single product expressive force, and it is raw itself not possess sound-absorbing, heat-insulated, purification of air decomposition etc. yet State property energy, application charges it is high and in the application because of thickness deficiency when easily sagging deformation the defects of；And with glass in inorganic decorative panel Glass body, ceramic matrix decorative panel make its application limitation because of itself fragility and ecological drawback.And with gypsum-based decorative plate material Thistle board, high-strength crystal plasterboard, mineral wool board, pre-injection type glass fiber reinforced gypsum composite (GRG) and cement Base decorative panel such as glass fibre increases the answering for representative such as cement composite material (GRC) and inorganic mineral base low-temp ceramics plate (CBC) With technology and product with inorganic coagulation material normal temperature pour into a mould suppress or extruding or injection molding, manufacturing condition is gentle, because Its excellent plastic and pliability, single-curved surface, hyperboloid, the various geometries of three-dimensional clad can, hollow out decorative pattern, embossment figure can be formed While the designs such as case, non-linearity plastic decoration expressive force, also with non-ignitable fire prevention and because of different degrees of microcosmic presence Porous and the absorbing sound and lowering noise, the environment-friendly function such as insulation that assign, having possessed basic improves human lives, the spatial loop of work The demand in border, as decoration smallpox, decorative wall panels, the building materials maturation scale application such as material, exterior wall, but carrying with environmental consciousness Formaldehyde that high and modern scientific research shows, toluene, pathogenic bacteria etc. increasingly threaten human health, it is necessary to further improve people The resistance to space environment quality with existence of class, therefore how photocatalysis technology is combined with inorganic decorating board, i.e., it can make full use of Photo catalyzed air purifying, antibacterial and mouldproof, anti-pollution function, but it is rationally special using the surface characteristic and microcellular structure of inorganic decorating board Sign, formed beneficial to the ecological ornamental plate for improving space environment.
In technical scheme about photocatalysis technology and inorganic decorating material, CN103011684A discloses one kind and can exhaled The self-cleaning diatom soil matrix functional decoration walltile of suction, energy and production method, by spraying nanometer base dioxy in mould brick body surface face Change titanium composite photocatalyst agent solution, then obtain through drying and roasting, exist the scattered inequality of nanometer based titanium dioxide composite photocatalyst, The problem of low value-added utilization.To assign the inorganic dresses such as existing gypsum base, cement base, inorganic mineral base by photocatalysis technology Adorn smallpox, wallboard, the product such as material, exterior wall it is ecological, both realized the scale application of photocatalysis technology, while also to the mankind The space environment live, to work closely bound up improves the patent document and public affairs for the inorganic ecological ornamental plate of photocatalysis of making contributions Technology is known there is not yet document report.
The content of the invention
Present invention aim to solve the deficiency of above-mentioned background technology, there is provided one kind is born with visible-light response type pore The inorganic ecological ornamental plate of photocatalysis and its production method of load.
The technical scheme is that：A kind of inorganic ecological decoration sheet material of photocatalysis, it is characterised in that described ecology dress Decoratice board is prepared by the raw material of following parts by weight：1.0~8.0 parts of pore catalysis materials, 100 parts of inorganic ecology gellings Powder, 1.5~20 parts of reinforcing fibers and/or glass fiber reticular cloth, 0.3~5.0 part of hydrophobicity waterproofing agent, 18.5~68.0 parts of liquid Medium.
Preferably, the pore catalysis material by：Photochemical catalyst, pore-foaming agent, water are by weight 5~50：1~8：42~ Pore forms photocatalysis foam support after 94 compoundings.
Further, the photochemical catalyst is perovskite composite oxide La1-xSrxMO3Nanocatalyst, M be Mn or Co, x are 0 or 0.4, and the photochemical catalyst fineness is 400~2000 mesh；The pore-foaming agent is lauryl sodium sulfate, fatty alcohol One or more in polyethenoxy ether sodium sulfate, α-sodium olefin sulfonate.
Preferably, it is described it is inorganic ecology gelling powder by：Inorganic coagulation material, ecological mineral powder by weight 60~ 87：13~40 compoundings form, and the inorganic ecology gelling powder fineness is 130~220 mesh.
Further, the inorganic coagulation material is the one or more in gypsum, cement, slag micropowder, stone sand；It is described Ecological mineral powder be diatomite, vermiculite power, tourmaline anion powder, sepiolite powder, zeolite powder, one kind in attapulgite or It is a variety of.Gypsum is one or both of natural alpha-semi water plaster stone or natural β-semi-hydrated gypsum in inorganic coagulation material；Slag is micro- Powder is rich in SiO2、Al2O3, CaO commercially available slag micropowder product.
Preferably, the reinforcing fiber is the one or more in glass fibre, string, mineral fibres, described to hate Watery water-proofing agent is the one or more in methyl silicon sodium alcoholate, methyl silanol potassium or polysiloxanes.
Preferably, the liquid medium is by water, polyvinyl alcohol, modifying agent by weight 100：0~1.5：0~0.5 compounding Form, the modifying agent is the one or more in sodium citrate, aluminum sulfate, alum.
The present invention also provides a kind of production method of the inorganic ecological decoration sheet material of above-mentioned photocatalysis, it is characterised in that by such as Lower step is completed：
(1) preparation of pore catalysis material：By photochemical catalyst, pore-foaming agent, water by weight 5~50：1~8:42~94 After being stirred, the pore catalysis material of foam support is formed by pore；
(2) preparation of inorganic ecology gelling powder：By inorganic coagulation material, ecological mineral powder be milled to fineness for 130~ By weight 60~87 after 220 mesh：13~40 mixing are re-dubbed inorganic ecology gelling powder；
(3) stir：It is 0.3~5.0 part of hydrophobicity waterproofing agent, 18.5~68.0 parts of liquid phase mediums, step (1) by parts by weight 100 parts of inorganic ecology gelling powders of the middle gained of 1.0~8.0 parts of pore catalysis materials of middle gained, step (2) are mixed into row Action of forced stirring；
(4) prepared by sheet material：Gained compound is dried to obtain photocatalysis ecological decoration sheet material through being molded, conserving.
Preferably, added in the step (3) in reinforcing fiber blending and/or step (4) and add fiberglass mesh molding with cloth, The reinforcing fiber and/or glass fiber reticular cloth parts by weight added is 1.5~20 parts.I.e.：It is fine when adding enhancing in only step (3) When glass fiber reticular cloth during dimension or is only added in step (4), the reinforcing fiber or glass fiber reticular cloth parts by weight of addition are 1.5~20 Part；When step (3) adds reinforcing fiber and adds glass fiber reticular cloth in step (4) simultaneously, the reinforcing fiber of addition, glass fiber net Lattice cloth total weight parts are 1.5~20 parts.
Preferably, described reinforcing fiber is the one or more in glass fibre, string, mineral fibres, described Pre-processed before string mixing through sodium metasilicate, the aqueous solution soaking of lime, boiling, dehydration.
Preferably, it is shaped in step (4)：Using moulding by casting, form, compressing, shaping of precoating, cast-in-place The abundant aquation of material is molded by shaping, extrusion forming or sprayup process；Conserving drying is：Treat to be stripped after the completion of aquation, lead to Natural drying or dry kiln drying or hydrothermal curing are crossed to equilibrium moisture content≤4.5% one-tenth semi-finished product, the natural drying time For 7 to 15 days；The dry kiln dries its temperature and is set as 50~65 DEG C, 10~12 hours time；The hydrothermal curing time For 28~30 days；Dry sheet material is surface-treated to obtain various products, is surface-treated and is：Through grinding process after drying, By products application design using coating, baking vanish, UV plated films, silk-screen, it is gold stamping in one or more surface treatment modes, treat its table Face solidifies.
The ecological decoration sheet material produced in the present invention includes：Ceiling ecological decoration sheet material, wallboard ecological decoration sheet material, imitate Stone ecological decoration sheet material, imitation wood ecological decoration sheet material, outer curtain wall ecological decoration sheet material.
Preferably, when ecological decoration sheet material is ceiling ecological decoration sheet material, wallboard ecological decoration sheet material, imitative stone ecology dress During decoratice board：The reinforcing fiber of selection is one or both of glass fibre, mineral fibres, and glass fibre length is 15~18 ㎜, mineral fibres length are 70-120 μm.
Preferably, when ecological decoration sheet material is imitation wood ecological decoration sheet material：The reinforcing fiber of selection is string, is planted Fibres are one or both of sugarcane fiber or wood fiber, and string pretreatment is：String is broken for growing Spend 0.5~160 ㎜, the ㎜ of width 0.5~5, the ㎜ of thickness 0.1~5 chip or short silk shape, using sodium metasilicate, lime it is water-soluble Liquid soaking cooking after 2 hours centrifugal drying to moisture content ＜ 3.5%, the wherein dosage of sodium metasilicate be string gross mass 0.5%, 3.0% that the dosage of lime is string gross mass, sodium metasilicate, lime total mass concentration are 3% in the aqueous solution, Digestion temperature is that room temperature is extremely seethed with excitement.
Preferably, when ecological decoration sheet material is outer curtain wall ecological decoration sheet material：Add reinforcing fiber and/or fiberglass mesh Cloth, reinforcing fiber are that length is 15~18 ㎜ glass fibres, and fiberglass mesh Gridding specification is the ㎜ of 3 × 3 ㎜~10 × 10.
The present invention using photocatalysis technology and inorganic decorating board production technology as support, with visible-light response type light urged by creativeness Agent and photocatalysis pore is supported and the inorganic distinctive porous microstructure of ecological sizing material, is assigned by photocatalysis technology Give existing inorganic decorating smallpox, wallboard, the product such as material, outer curtain wall it is ecological.The present invention is compared with existing product and technology Had the following advantages that：
(1) visible-light response type catalyst is used, with La1-xSrxMO3Type (M=Mn, Co；X=0,0.4) nano-particle is Catalyst particle, because its part La is by the Sr manganese systems substituted and co-containing mixed oxide, there is the heterogeneous of crystal structure defects, to waving Hair property organic matter has significant catalytic activity, the nano-crystal TiO with routine2Or nanocrystalline metals doping type TiO2With more for room The catalytic activity of interior volatile organic matter, especially formaldehyde, toluene and VOCs, and can be to visible light-responded, rather than need routine The distinctive illumination condition of photocatalysis.
(2) with existing gypsum-based decorative plate material in Thistle board, high-strength crystal plasterboard, mineral wool board, pre-injection type glass Glass fibre increases cement composite material (GRC), inorganic in fiber reinforcement gypsum composite (GRG) and cement base dalle Mineral base low-temp ceramics plate (CBC) compares, and is assigned in non-ignitable fire prevention and because porous existing for microcosmic in various degree The environmental protection of the basis such as absorbing sound and lowering noise, insulation functionally, is assigned by inherent inorganic decorating board microcellular structure and photocatalysis technology Give cleaning harmful gas decomposition, antibacterial and mouldproof, soil resistance etc. ecological, directly beneficial to improvement space environment quality.It, which is purified, makees With mechanism, antibacterial and mouldproof mechanism to carry out the physical absorption of pernicious gas and organic matter by inorganic coagulation material microporous properties, React to form OH (hydroxyl free radical), O by photocatalytic redox2 -(peroxy radical) and with very strong oxidation point Solution ability, the C-C keys that can be destroyed in pernicious gas and organic matter, C-H keys, C-N keys, C-O keys, O-H keys, N-H keys, assign Give product that there is purification air, antibacterial and mouldproof performance；And it is antifouling it is ecological be that oxidation and super is decomposed by catalysis material Hydrophilic interaction is realized.
(3) be sufficiently reserved using the excellent plasticity of inorganic coagulation material, after spreading out property, with gentle process conditions using pour into a mould Or compacting or extruding or injection molding mode, you can it is unlimited to form abundant embossment skin texture, ornamental engraving grid, non-linear moulding etc. Plastic decoration expressive force, products application cover the indoor and outdoor spaces surface closely bound up with human lives, work, expand and are lifted Photocatalysis existing application technology.
(4) photocatalysis technology action principle is taken full advantage of, is application space surface in the most strong place of cross-ventilation, Using in inorganic coagulation material in micropore as carrier, form the pernicious gas of completion and organic gas diffusion, absorption, decompose and de- Attached process, ecological performance are notable.Its purifying formaldehyde rate be 95%, clean-up effect persistence up to 90%, staphylococcus aureus resists Bacterium rate is up to 95%, and Escherichia coli antibiotic rate is up to 99%.
Brief description of the drawings
Fig. 1 is the process chart of the present invention
Embodiment
The present invention is described in further detail with specific embodiment below in conjunction with the accompanying drawings.
Perovskite composite oxide La in the present invention1-xSrxMO3Nanocatalyst is by published Chinese invention patent (publication number CN1947834A) " is used for the La for eliminating volatile organic matter1-xSrxMO3The preparation method of nanocatalyst " is prepared into Arrive.LaMnO is made in embodiment 1-4 respectively in the patent3、La0.6Sr0.4MnO3、LaCoO3、La0.6Sr0.4CoO3Nano-particle, this La in invention1-xSrxMO3Nanocatalyst can be LaMnO3、La0.6Sr0.4MnO3、LaCoO3、La0.6Sr0.4CoO3In one kind Or several mixtures.The perovskite composite oxide La used in the embodiment of the present invention1-xSrxMO3Nanocatalyst fineness is 400~2000 mesh.
Embodiment 1
The present embodiment ecological decoration sheet material is ceiling ecological decoration sheet material
1st, formula composition in parts by weight：
1.8 parts of pore catalysis material：By La1-xSrxMO3Type nanocatalyst (LaMnO3Nano-particle), pore-foaming agent (ten Sodium dialkyl sulfate K12), water is by weight 5：1：94 compound and obtain；
Inorganic 100 parts of powder of ecology gelling：By inorganic coagulation material 84 parts of (natural 80 parts of β-semi-hydrated gypsum, silicate cements 4 parts of mud) and 16 parts of ecological mineral powder (8 parts of diatomite, 3 parts of tourmaline anion powder, 5 parts of attapulgite) compounding and obtain；
1.5 parts of reinforcing fiber：Length is in 15~18 ㎜ glass fibres；
1.5 parts of hydrophobicity waterproofing agent：Methyl silicon sodium alcoholate；
68 parts of liquid medium：By water, polyvinyl alcohol, sodium citrate, alum by weight 100：1.2：0.3：0.15 Compound and obtain.(material in bracket of the embodiment of the present invention represents the concrete composition of component before bracket, is single substance in bracket Shi Ze represents all materials of component before the bracket)
2nd, as shown in figure 1, being by the process for producing of above-mentioned raw materials formula：
(1) preparation of pore catalysis material：By 0.09 part of La1-xSrxMO3Type nanocatalyst, 0.18 part of pore-foaming agent, 1.692 parts of water, after measuring, being stirred respectively, 1.8 parts of pore photocatalysis materials of suspended porous foam are formed using pore machine Material；
(2) preparation of inorganic ecology gelling powder：By 84 parts of inorganic coagulation material, 16 parts of ecological mineral powder through physics powder It is milled to 130~220 mesh, mixing is re-dubbed 100 parts of inorganic ecology gelling powders；
(3) stir：As obtained by parts by weight in formula are 1.5 parts of hydrophobicity waterproofing agents, 68 parts of liquid mediums and step (1) 100 parts of gained inorganic ecology gelling powders in 1.8 parts of pore catalysis materials, step (2), and 1.5 parts of reinforcing fibers are mixed Close action of forced stirring；
(4) it is molded：Using moulding by casting mode；
(5) drying is conserved：Treat to be stripped after the completion of aquation, by spontaneously drying 7~15 days to equilibrium moisture content≤4.5%；
(6) it is surface-treated：Through polishing or criticizing ash processing after drying, by products application design using coating, baking vanish, UV platings One or more surface treatment modes in film, silk-screen, gold stamping or other materials veneer, given birth to after its surface cure for ceiling State dalle.
Embodiment 2
The present embodiment ecological decoration sheet material is wallboard ecological decoration sheet material
1st, formula composition in parts by weight：
5.5 parts of pore catalysis material：By La1-xSrxMO3Type nanocatalyst (La0.6Sr0.4MnO3Nano-particle), cause Hole agent (lauryl sodium sulfate), water are by weight 10：4：86 compound and obtain；
Inorganic 100 parts of powder of ecology gelling：By inorganic coagulation material 80 parts of (natural 7 parts of alpha-semi water plaster stone, natural β-half water 63 parts of gypsum, 10 parts of white portland cement) and 20 parts of ecological mineral powder (15 parts of diatomite, tourmaline anion powder 3.0 Part, 2.0 parts of attapulgite) compound and obtain.
13.5 parts of reinforcing fiber：1.5 parts of glass fibre, 12 parts of mineral fibres (grow in various embodiments of the present invention by glass fibre Degree is that 15~18 ㎜, mineral fibres length are 70 μm~120 μm)；
1.5 parts of hydrophobicity waterproofing agent：Polysiloxanes；
62 parts of liquid medium：By water, polyvinyl alcohol, sodium citrate, aluminum sulfate, alum by weight 100：1.2： 0.3：0.1：0.1 compounds and obtains.
2nd, as shown in figure 1, being by the process for producing of above-mentioned raw materials formula：
(1) preparation of pore catalysis material：By 0.55 part of La1-xSrxMO3Type nanocatalyst, 0.22 part of pore-foaming agent, 4.73 parts of water, after measuring, being stirred respectively, 5.5 parts of pore catalysis materials of suspended porous foam are formed using pore machine；
(2) preparation of inorganic ecology gelling powder：By 80 parts of inorganic coagulation material, 20 parts of ecological mineral powder through physics powder It is milled to 130~220 mesh, mixing is re-dubbed 100 parts of inorganic ecology gelling powders；
(3) stir：As obtained by parts by weight in formula are 1.5 parts of hydrophobicity waterproofing agents, 62 parts of liquid mediums and step (1) 100 parts of gained inorganic ecology gelling powders in 5.5 parts of pore catalysis materials, step (2), and 13.5 parts of reinforcing fibers are mixed Close action of forced stirring；
(4) it is molded：Using form mode；
(5) drying is conserved：Treat to be stripped after the completion of aquation, by spontaneously drying 7~15 days to equilibrium moisture content≤4.5%；
(6) it is surface-treated：Through polishing or criticizing ash processing after drying, by products application design using coating, baking vanish, UV platings One or more surface treatment modes in film, silk-screen, gold stamping or other materials veneer, it is wallboard ecology after its surface cure Dalle.
Embodiment 3
The present embodiment ecological decoration sheet material is imitative stone ecological decoration sheet material
1st, formula composition in parts by weight：
3.8 parts of pore catalysis material：By La1-xSrxMO3Type nanocatalyst (LaCoO3Nano-particle), pore-foaming agent (ten Sodium dialkyl sulfate), water is by weight 50：5：45 compound and obtain；
Inorganic 100 parts of powder of ecology gelling：By inorganic coagulation material 87 parts of (natural 80 parts of alpha-semi water plaster stone, white silicic acid 7.0 parts of salt cement), 13 parts of ecological mineral powder (5 parts of diatomite, 3.0 parts of vermiculite power, 3.0 parts of tourmaline anion powder, zeolite 2.0 parts of powder), compound and obtain.
10 parts of reinforcing fiber：2 parts of glass fibre, 8 parts of mineral fibres；
1.8 parts of hydrophobicity waterproofing agent：Methyl silanol potassium；
20.8 parts of liquid medium：By water, polyvinyl alcohol by weight 100：1.5 compound and obtain.
2nd, as shown in figure 1, being by the process for producing of above-mentioned raw materials formula：
(1) preparation of pore catalysis material：By 1.9 parts of La1-xSrxMO3Type nanocatalyst, 0.19 part of dodecyl sulphur Sour sodium (K12), 1.71 parts of water, after measuring, being stirred respectively, 3.8 parts of pores of suspended porous foam are formed using pore machine Catalysis material；
(2) preparation of inorganic ecology gelling powder：By 87 parts of inorganic coagulation material, 13 parts of ecological mineral powder through physics powder It is milled to 130~220 mesh, mixing is re-dubbed 100 parts of inorganic ecology gelling powders；
(3) stir：It is obtained by 1.8 parts of hydrophobicity waterproofing agents, 20.8 parts of liquid mediums and step (1) by parts by weight in formula 3.8 parts of pore catalysis materials, in step (2) gained 100 parts of inorganic ecology gelling powders, and 10 parts of reinforcing fibers are strong System stirring；
(4) it is molded：Using compressing mode, 6.0 MPas of briquetting pressure, 3~10 minutes dwell times；
(5) drying is conserved：Treat to be stripped after the completion of aquation, dried by spontaneously drying 7 to 15 days or dry kiln, drying temperature It is set as 50~65 DEG C, dries 10~12 hours to equilibrium moisture content≤4.5% one-tenth semi-finished product；
(6) it is surface-treated：Through polishing or batch ash processing after drying, baked by products application design using metal baking finish, imitative stone Paint carries out surface coating and obtains the imitative stone ecological decoration sheet material that can be decorated directly as facing.
Embodiment 4
The present embodiment ecological decoration sheet material is imitation wood ecological decoration sheet material
1st, formula composition in parts by weight：
3.0 parts of pore catalysis material：By La1-xSrxMO3Type nanocatalyst (La0.6Sr0.4CoO3Nano-particle), cause Hole agent (α-sodium olefin sulfonate AOS), water are 30 by weight：1：69 compound and obtain；
Inorganic 100 parts of powder of ecology gelling：By inorganic coagulation material 85 parts of (natural 5 parts of alpha-semi water plaster stone, natural β-half water 73 parts of gypsum, 7.0 parts of white portland cement), 15 parts of ecological mineral powder (5 parts of diatomite, 3.0 parts of tourmaline anion powder, 7.0 parts of vermiculite power) compound and obtain；
12 parts of reinforcing fiber：String (sugarcane fiber)；
1.5 parts of hydrophobicity waterproofing agent：Polysiloxanes；
22.75 parts of liquid medium：Water, polyvinyl alcohol, sodium citrate are by weight 100：1.5：0.25 compounds and obtains；
2. as shown in figure 1, it is by the process for producing of above-mentioned raw materials formula：
(1) preparation of pore catalysis material：By 0.9 part of La1-xSrxMO3Type nanocatalyst, 0.03 part of α-alkenyl sulfuric acid Sodium AOS, 2.07 parts of water, after measuring, being stirred respectively, 3 parts of pore photocatalysis of suspended porous foam are formed using pore machine Material；
(2) preparation of inorganic ecology gelling powder：By 85 parts of inorganic coagulation material, 15 parts of ecological mineral powder through physics powder It is milled to 130~220 mesh, mixing is re-dubbed 100 parts of inorganic ecology gelling powders；
(3) string pre-processes：12 parts of sugarcane fibers are broken for the ㎜ of length 3~18, the ㎜ of width 0.5~5, thickness 0.1~5 ㎜ chip or short silk shape, using sodium metasilicate, lime aqueous solution soaking boiling 2 hours after centrifugal drying extremely 12 parts are taken after moisture content ＜ 3.5%.(dosage of wherein sodium metasilicate is the 0.5% of sugarcane fiber gross mass, the dosage of lime is sugarcane The 3.0% of slag total fiber mass, sodium metasilicate, lime total mass concentration are 3% in the aqueous solution, and digestion temperature is room temperature to seething with excitement)；
(4) stir：It is 1.5 parts of hydrophobicity waterproofing agents by parts by weight in formula, 22.75 parts of liquid mediums and step (1) institute 3 parts of pore catalysis materials, 100 parts of the middle gained of step (2) the inorganic ecology gelling powders obtained, and 12 parts of reinforcing fibers pass through Cross the gains mixing action of forced stirring of pretreatment；
(5) it is molded：Using compressing mode, 10.0 MPas of briquetting pressure, 3~10 minutes dwell times；
(6) drying is conserved：Treat to be stripped after the completion of aquation, dried by spontaneously drying 7 to 15 days or dry kiln, drying temperature It is set as 50~65 DEG C, dries 10~12 hours to equilibrium moisture content≤4.5% one-tenth semi-finished product；
(7) it is surface-treated：Through putty plated film, polishing after drying, designed by products application using spraying, baking vanish, UV Plated film, silk-screen, it is gold stamping in one or more surface treatment modes, into imitation wood ecological ornamental plate after its surface cure.
Embodiment 5
The present embodiment ecological decoration sheet material is outer curtain wall ecological decoration sheet material
1st, formula composition in parts by weight：
2.5 parts of pore catalysis material：By La1-xSrxMO3Type nanocatalyst (LaMnO3、La0.6Sr0.4MnO3Nanoparticle Son is by weight 10:1 mixes), pore-foaming agent (sodium sulfate of polyethenoxy ether of fatty alcohol AES), water is by weight 40：5：55 is multiple Match somebody with somebody and obtain；
Inorganic 100 parts of powder of ecology gelling：It is raw by inorganic coagulation material 82 parts (32 parts of portland cement, 50 parts of stone sands) 18 parts of state mineral powder (5 parts of diatomite, 8.0 parts of tourmaline anion powder, 5.0 parts of zeolite powder) is compounded and obtained.
2 parts of reinforcing fiber：Glass fibre；
1.2 parts of glass fiber reticular cloth：The ㎜ glass fiber reticular cloths of grid specification 5 × 5；
4.8 parts of hydrophobicity waterproofing agent：Methyl silicon sodium alcoholate；
20.8 parts of liquid medium：Water, sodium citrate are by weight 100：0.25 matches somebody with somebody.
2nd, as shown in figure 1, process for producing：
(1) preparation of pore catalysis material：By 1.0 parts of La1-xSrxMO3Type nanocatalyst, 0.125 part of poly alkyl alcohol Oxygen ethene ether sodium sulfate AES, 1.375 parts of water, after measuring, being stirred respectively, suspended porous foam is formed using pore machine 2.5 parts of pore catalysis materials；
(2) preparation of inorganic ecology gelling powder：By 82 parts of inorganic coagulation material, 18 parts of ecological mineral powder through physics powder It is milled to 130~220 mesh, mixing is re-dubbed 100 parts of inorganic ecology gelling powders；
(3) stir：As 4.8 parts of hydrophobicity waterproofing agents, 20.8 parts of liquid mediums and 2.5 parts obtained by step (1) in formula 100 parts of gained inorganic ecology gelling powders in pore catalysis material, step (2), and 2 parts of reinforcing fiber mixing pressures are stirred Mix；
(4) it is molded：Using three layers of compressing mode, 6.0 MPas of briquetting pressure, 3~10 minutes dwell times, centre one Layer uniformly lays 1.2 parts of glass fiber reticular cloths；
(5) drying is conserved：Treat to be stripped after the completion of aquation, dried by spontaneously drying 7 to 15 days or dry kiln, drying temperature It is set as 50~65 DEG C, dries 10~12 hours to equilibrium moisture content≤4.5% one-tenth semi-finished product；
(6) it is surface-treated：Through polishing or batch ash processing after drying, baked by products application design using metal baking finish, imitative stone Paint progress surface coating obtains can be directly as outer curtain wall decorative sheet.
Embodiment 6
The present embodiment ecological decoration sheet material is ceiling ecological decoration sheet material
1st, formula composition in parts by weight：
1 part of pore catalysis material：By La1-xSrxMO3Type nanocatalyst (LaMnO3Nano-particle), pore-foaming agent (12 Sodium alkyl sulfate K12), water is by weight 5：1：94 compound and obtain；
Inorganic 100 parts of powder of ecology gelling：By 60 parts (natural alpha-semi water plaster stones) of inorganic coagulation material and ecological mineral powder 40 parts of body (10 parts of diatomite, 10 parts of vermiculite power, 10 parts of tourmaline anion powder, 10 parts of sepiolite powder) is compounded and obtained；
1.5 parts of reinforcing fiber：Mineral fibres；
0.3 part of hydrophobicity waterproofing agent：Polysiloxanes；
18.5 parts of liquid medium：By water, polyvinyl alcohol by weight 100：0.8 compounds and obtains.
2nd, as shown in figure 1, being by the process for producing of above-mentioned raw materials formula：
(1) preparation of pore catalysis material：By 0.05 part of La1-xSrxMO3Type nanocatalyst, 0.01 part of dodecyl Sodium sulphate K12,0.94 part of water, after measuring, being stirred respectively, 1 part of pore light of suspended porous foam is formed using pore machine Catalysis material；
(2) preparation of inorganic ecology gelling powder：By 60 parts of inorganic coagulation material, 40 parts of ecological mineral powder through physics powder It is milled to 130~220 mesh, mixing is re-dubbed 100 parts of inorganic ecology gelling powders；
(3) stir：It is obtained by 0.3 part of hydrophobicity waterproofing agent, 18.5 parts of liquid mediums and step (1) by parts by weight in formula 1 part of pore catalysis material, in step (2) gained 100 parts of inorganic ecology gelling powders, and 1.5 parts of reinforcing fibers are strong System stirring；
(4) it is molded：Using moulding by casting or molding mode of precoating；
(5) drying is conserved：Treat to be stripped after the completion of aquation, treat to be stripped after the completion of aquation, using hydrothermal curing 28~30 days extremely Equilibrium moisture content≤4.5%；
(6) it is surface-treated：Through polishing or criticizing ash processing after drying, by products application design using coating, baking vanish, UV platings One or more surface treatment modes in film, silk-screen, gold stamping or other materials veneer, given birth to after its surface cure for ceiling State dalle.
Embodiment 7
The present embodiment ecological decoration sheet material is wallboard ecological decoration sheet material
1st, formula composition in parts by weight：
3 parts of pore catalysis material：By La1-xSrxMO3Type nanocatalyst (La0.6Sr0.4MnO3Nano-particle), pore Agent (α-sodium olefin sulfonate AOS), water are by weight 15：3：82 compound and obtain；
Inorganic 100 parts of powder of ecology gelling：By 65 parts (natural β-semi-hydrated gypsums) of inorganic coagulation material and ecological mineral powder 35 parts of body (5 parts of tourmaline anion powder, 10 parts of sepiolite powder, 10 parts of zeolite powder, 10 parts of attapulgite) is compounded and obtained.
5 parts of reinforcing fiber：Glass fibre；
0.6 part of hydrophobicity waterproofing agent：Methyl silicon sodium alcoholate；
20 parts of liquid medium：By water, polyvinyl alcohol by weight 100：1.5 compound and obtain.
2nd, as shown in figure 1, being by the process for producing of above-mentioned raw materials formula：
(1) preparation of pore catalysis material：By 0.45 part of La1-xSrxMO3Type nanocatalyst, 0.09 part of pore-foaming agent, 2.46 parts of water, after measuring, being stirred respectively, 3 parts of pore catalysis materials of suspended porous foam are formed using pore machine；
(2) preparation of inorganic ecology gelling powder：By 65 parts of inorganic gel material, 35 parts of ecological mineral powder through physics grinding 100 parts of inorganic ecology gelling powders are re-dubbed to 130~220 mesh, mixing；
(3) stir：As obtained by parts by weight in formula are 0.6 part of hydrophobicity waterproofing agent, 20 parts of liquid mediums and step (1) 100 parts of gained inorganic ecology gelling powders in 3 parts of pore catalysis materials, step (2), and 5 parts of reinforcing fiber mixing are strong System stirring；
(4) it is molded：Using moulding by casting or form or extrusion forming or injection molding mode；
(5) drying is conserved：Treat to be stripped after the completion of aquation, by spontaneously drying 7~15 days to equilibrium moisture content≤4.5%；
(6) it is surface-treated：Through polishing or criticizing ash processing after drying, by products application design using coating, baking vanish, UV platings One or more surface treatment modes in film, silk-screen, gold stamping or other materials veneer, it is wallboard ecology after its surface cure Dalle.
Embodiment 8
The present embodiment ecological decoration sheet material is imitative stone ecological decoration sheet material
1st, formula composition in parts by weight：
5 parts of pore catalysis material：By La1-xSrxMO3Type nanocatalyst (LaCoO3Nano-particle), dodecyl sulphur Sour sodium (K12), water are by weight 25：5：70 compound and obtain；
Inorganic 100 parts of powder of ecology gelling：By 70 parts of inorganic coagulation material (for containing CaO39.87%, SiO234.24%th, Al2O313.83% slag micropowder, 39.87% represents slag micropowder mass percent shared by CaO, SiO2、 Al2O3Similarly), ecological 30 parts of mineral powder (10 parts of diatomite, 10 parts of vermiculite power, 10 parts of tourmaline anion powder) compounds and obtained.
10 parts of reinforcing fiber：Glass fibre；
2.5 parts of hydrophobicity waterproofing agent：Polysiloxanes；
40 parts of liquid medium：By water, sodium citrate, aluminum sulfate by weight 100：0.1：0.1 compounds and obtains.
2nd, as shown in figure 1, being by the process for producing of above-mentioned raw materials formula：
(1) preparation of pore catalysis material：By 1.25 parts of La1-xSrxMO3Type nanocatalyst, 0.25 part of pore-foaming agent, 3.5 parts of water, after measuring, being stirred respectively, 5 parts of pore catalysis materials of suspended porous foam are formed using pore machine；
(2) preparation of inorganic ecology gelling powder：By 70 parts of inorganic coagulation material, 30 parts of ecological mineral powder through physics powder It is milled to 130~220 mesh, mixing is re-dubbed 100 parts of inorganic ecology gelling powders；
(3) stir：As obtained by parts by weight in formula are 2.5 parts of hydrophobicity waterproofing agents, 40 parts of liquid mediums and step (1) 100 parts of gained inorganic ecology gelling powders in 5 parts of pore catalysis materials, step (2), and 10 parts of reinforcing fibers force to stir Mix；
(4) it is molded：Using compressing mode, 6.0 MPas of briquetting pressure, 3~10 minutes dwell times；
(5) drying is conserved：Treat to be stripped after the completion of aquation, dried by spontaneously drying 7 to 15 days or dry kiln, drying temperature It is set as 50~65 DEG C, dries 10~12 hours to equilibrium moisture content≤4.5% one-tenth semi-finished product；
(6) it is surface-treated：Through polishing or batch ash processing after drying, baked by products application design using metal baking finish, imitative stone Paint carries out surface coating and obtains the imitative stone ecological decoration sheet material that can be decorated directly as facing.
Embodiment 9
The present embodiment ecological decoration sheet material is imitation wood ecological decoration sheet material
1st, formula composition in parts by weight：
6 parts of pore catalysis material：By La1-xSrxMO3Type nanocatalyst (La0.6Sr0.4CoO3Nano-particle), pore Agent (α-sodium olefin sulfonate), water are 30 by weight：7：63 compound and obtain；
Inorganic 100 parts of powder of ecology gelling：By inorganic coagulation material, 87 parts (contain CaO39.87%, SiO234.24%th, Al2O313.83% 67 parts of slag micropowder, 20 parts of white portland cement), 13 parts of ecological mineral powder it is (6 parts of zeolite powder, concavo-convex 7 parts of rod powder) compound and obtain；
15 parts of reinforcing fiber：String (wood fiber)；
4 parts of hydrophobicity waterproofing agent：Methyl silanol potassium；
60 parts of liquid medium：Water, sodium citrate, alum are by weight 100：0.2：0.3 compounds and obtains；
2. as shown in figure 1, it is by the process for producing of above-mentioned raw materials formula：
(1) preparation of pore catalysis material：By 1.8 parts of La1-xSrxMO3Type nanocatalyst, 0.42 part of α-alkenyl sulfuric acid Sodium AOS, 3.78 parts of water, after measuring, being stirred respectively, 6 parts of pore photocatalysis of suspended porous foam are formed using pore machine Material；
(2) preparation of inorganic ecology gelling powder：By 87 parts of inorganic coagulation material, 13 parts of ecological mineral powder through physics powder It is milled to 130~220 mesh, mixing is re-dubbed 100 parts of inorganic ecology gelling powders；
(3) string pre-processes：15 parts of wood fibers are broken for the ㎜ of length 3~18, the ㎜ of width 0.5~5, thickness 0.1~5 ㎜ chip or short silk shape, using sodium metasilicate, lime aqueous solution soaking boiling 2 hours after centrifugal drying extremely 12 parts are taken after moisture content ＜ 3.5%, (dosage of wherein sodium metasilicate is the 0.5% of wood fiber gross mass, the dosage of lime is wood Consider the 3.0% of total fiber mass to be worth doing, aqueous solution sodium metasilicate, lime total mass concentration are 3%, and digestion temperature is that room temperature is extremely seethed with excitement)；
(4) stir：It is 4 parts of hydrophobicity waterproofing agents, 60 parts of liquid mediums and 6 obtained by step (1) as parts by weight in formula 100 parts of inorganic ecology gelling powders of the middle gained of part pore catalysis material, step (2), and 15 parts of wood fibers pass through in advance The gains mixing action of forced stirring of processing；
(5) it is molded：Using compressing mode, 10.0 MPas of briquetting pressure, 3~10 minutes dwell times；
(6) drying is conserved：Treat to be stripped after the completion of aquation, dried by spontaneously drying 7 to 15 days or dry kiln, drying temperature It is set as 50~65 DEG C, dries 10~12 hours to equilibrium moisture content≤4.5% one-tenth semi-finished product；
(7) it is surface-treated：Through putty plated film, polishing after drying, designed by products application using spraying, baking vanish, UV Plated film, silk-screen, it is gold stamping in one or more surface treatment modes, into imitation wood ecological ornamental plate after its surface cure.
Embodiment 10
The present embodiment ecological decoration sheet material is outer curtain wall ecological decoration sheet material
1st, formula composition in parts by weight：
8 parts of the supported material of photocatalysis：By La1-xSrxMO3Type nanocatalyst (La0.6Sr0.4MnO3Nano-particle), cause Hole agent (sodium sulfate of polyethenoxy ether of fatty alcohol AES), water are by weight 50：8：42 compound and obtain；
Inorganic 100 parts of powder of ecology gelling：By 80 parts of (natural 20 parts of alpha-semi water plaster stone, natural β-half of inorganic coagulation material 20 parts of water gypsum, 20 parts of portland cement, 20 parts of quartz sand), ecological 20 parts of mineral powder (zeolite powder) compounds and obtained.
10 parts of reinforcing fiber：Glass fibre；
10 parts of glass fiber reticular cloth：The ㎜ glass fiber reticular cloths of grid specification 3 × 3；
5 parts of hydrophobicity waterproofing agent：Polysiloxanes；
68 parts of liquid medium：Water, polyvinyl alcohol, sodium citrate, aluminum sulfate, alum are by weight 100：1.5：0.1： 0.2：0.2 compounds and obtains.
2nd, as shown in figure 1, process for producing：
(1) preparation of pore catalysis material：By 4 parts of La1-xSrxMO3Type nanocatalyst, 0.64 part of fatty alcohol polyoxy second Alkene ether sodium sulfate AES, 3.36 parts of water, after measuring, being stirred respectively, 8 parts of causes of suspended porous foam are formed using pore machine Aperture photocatalysis material；
(2) inorganic ecology gelling powder compounding：By 80 parts of inorganic coagulation material, 20 parts of ecological mineral powder through physics grinding 100 parts of inorganic ecology gelling powders are re-dubbed to 130~220 mesh, mixing；
(3) stir：As 5 parts of hydrophobicity waterproofing agents, 68 parts of liquid mediums and 8 parts of pore light obtained by step (1) in formula 100 parts of gained inorganic ecology gelling powders in catalysis material, step (2), and 10 parts of glass fibre action of forced stirring；
(4) it is molded：Using compressing mode, 6.0 MPas of briquetting pressure, 3~10 minutes dwell times, middle one layer 10 parts of glass fiber reticular cloths of even laying；
(5) drying is conserved：Treat to be stripped after the completion of aquation, dried by spontaneously drying 7 to 15 days or dry kiln, drying temperature It is set as 50~65 DEG C, dries 10~12 hours to equilibrium moisture content≤4.5% one-tenth semi-finished product；
(6) it is surface-treated：Through polishing or batch ash processing after drying, baked by products application design using metal baking finish, imitative stone Paint progress surface coating obtains can be directly as outer curtain wall decorative sheet.
Embodiment 11
The present embodiment ecological decoration sheet material is ceiling ecological decoration sheet material
1st, formula composition in parts by weight：
1 part of pore catalysis material：By La1-xSrxMO3Type nanocatalyst (LaMnO3、La0.6Sr0.4MnO3Nano-particle By weight 1：1 mixes), (lauryl sodium sulfate and α-sodium olefin sulfonate are by weight 1 for pore-foaming agent：1 mixes), Water is by weight 10：2：88 compound and obtain；
Inorganic 100 parts of powder of ecology gelling：By inorganic coagulation material 60 parts (portland cements) and ecological mineral powder 40 Part (diatomite) compounds and obtained；
20 parts of reinforcing fiber：10 parts of glass fibre, 10 parts of mineral fibres；
0.3 part of hydrophobicity waterproofing agent：Methyl silicon sodium alcoholate；
18.5 parts of liquid medium：By water, polyvinyl alcohol by weight 100：0.5 compounds and obtains.
2nd, as shown in figure 1, being by the process for producing of above-mentioned raw materials formula：
(1) preparation of pore catalysis material：By 0.1 part of La1-xSrxMO3Type nanocatalyst, 0.02 part of dodecyl sulphur Sour sodium, 0.88 part of water, after measuring, being stirred respectively, 1 part of pore photocatalysis material of suspended porous foam is formed using pore machine Material；
(2) preparation of inorganic ecology gelling powder：By 60 parts of inorganic coagulation material, 40 parts of ecological mineral powder through physics powder It is milled to 130~220 mesh, mixing is re-dubbed 100 parts of inorganic ecology gelling powders；
(3) stir：It is obtained by 0.3 part of hydrophobicity waterproofing agent, 18.5 parts of liquid mediums and step (1) by parts by weight in formula 1 part of pore catalysis material, in step (2) gained 100 parts of inorganic ecology gelling powders, and 20 parts of reinforcing fibers mixing Action of forced stirring；
(4) it is molded：Using moulding by casting or form mode；
(5) drying is conserved：Treat to be stripped after the completion of aquation, by spontaneously drying 7~15 days to equilibrium moisture content≤4.5%；
(6) it is surface-treated：Through polishing or criticizing ash processing after drying, by products application design using coating, baking vanish, UV platings One or more surface treatment modes in film, silk-screen, gold stamping or other materials veneer, given birth to after its surface cure for ceiling State dalle.
Embodiment 12
The present embodiment ecological decoration sheet material is wallboard ecological decoration sheet material
1st, formula composition in parts by weight：
6 parts of pore catalysis material：By La1-xSrxMO3Type nanocatalyst (La0.6Sr0.4MnO3、LaCoO3Nano-particle By weight 2：1 mixes), (sodium sulfate of polyethenoxy ether of fatty alcohol and α-sodium olefin sulfonate are by weight 2 for pore-foaming agent：1 is mixed Conjunction forms), water is by weight 20：4：76 compound and obtain；
Inorganic 100 parts of powder of ecology gelling：By inorganic coagulation material, 68 parts (contain CaO39.87%, SiO234.24%th, Al2O313.83% 28 parts of slag micropowder, 40 parts of portland cement) and 32 parts of ecological mineral powder (attapulgite) compounding and .
12 parts of reinforcing fiber：12 parts of mineral fibres；
2 parts of hydrophobicity waterproofing agent：Polysiloxanes；
25 parts of liquid medium：By water, polyvinyl alcohol by weight 100：1.5 compound and obtain.
2nd, as shown in figure 1, being by the process for producing of above-mentioned raw materials formula：
(1) preparation of pore catalysis material：By 1.2 parts of La1-xSrxMO3Type nanocatalyst, 0.24 part of pore-foaming agent, 4.56 parts of water, after measuring, being stirred respectively, 6 parts of pore catalysis materials of suspended porous foam are formed using pore machine；
(2) preparation of inorganic ecology gelling powder：By 68 parts of inorganic gel material, 32 parts of ecological mineral powder through physics grinding 100 parts of inorganic ecology gelling powders are re-dubbed to 130~220 mesh, mixing；
(3) stir：It is 2 parts of hydrophobicity waterproofing agents, 25 parts of liquid mediums and 6 obtained by step (1) as parts by weight in formula 100 parts of inorganic ecology gelling powders of the middle gained of part pore catalysis material, step (2), and 12 parts of reinforcing fibers mix by force System stirring；
(4) it is molded：Using shaping or the cast-in-place molding mode of precoating；
(5) drying is conserved：Treat to be stripped after the completion of aquation, using hydrothermal curing 28~30 days to equilibrium moisture content≤4.5%；
(6) it is surface-treated：Through polishing or criticizing ash processing after drying, by products application design using coating, baking vanish, UV platings One or more surface treatment modes in film, silk-screen, gold stamping or other materials veneer, it is wallboard ecology after its surface cure Dalle.
Embodiment 13
The present embodiment ecological decoration sheet material is imitative stone ecological decoration sheet material
1st, formula composition in parts by weight：
8 parts of pore catalysis material：By La1-xSrxMO3Type nanocatalyst (LaCoO3、La0.6Sr0.4CoO3Nano-particle By weight 3：1 mixes), (lauryl sodium sulfate and sodium sulfate of polyethenoxy ether of fatty alcohol are by weight 5 for pore-foaming agent：1 Mix), water is by weight 30：6：64 compound and obtain；
Inorganic 100 parts of powder of ecology gelling：By inorganic coagulation material 78 parts of (natural 28 parts of alpha-semi water plaster stone, silicate cements 20 parts of mud, 30 parts of quartz sand), 22 parts of ecological mineral powder (tourmaline anion powder) compounding and obtain.
9 parts of reinforcing fiber：Mineral fibres；
3 parts of hydrophobicity waterproofing agent：1 part of polysiloxanes, 2 parts of methyl silicon sodium alcoholate；
35 parts of liquid medium：By water, aluminum sulfate by weight 100：0.2 compounds and obtains.
2nd, as shown in figure 1, being by the process for producing of above-mentioned raw materials formula：
(1) preparation of pore catalysis material：By 2.4 parts of La1-xSrxMO3Type nanocatalyst, 0.48 part of pore-foaming agent, 5.12 parts of water, after measuring, being stirred respectively, 8 parts of pore catalysis materials of suspended porous foam are formed using pore machine；
(2) preparation of inorganic ecology gelling powder：By 78 parts of inorganic coagulation material, 22 parts of ecological mineral powder through physics powder It is milled to 130~220 mesh, mixing is re-dubbed 100 parts of inorganic ecology gelling powders；
(3) stir：It is 3 parts of hydrophobicity waterproofing agents, 35 parts of liquid mediums and 8 obtained by step (1) as parts by weight in formula 100 parts of gained inorganic ecology gelling powders in part pore catalysis material, step (2), and 9 parts of reinforcing fibers pressures are stirred Mix；
(4) it is molded：Using compressing mode, 6.0 MPas of briquetting pressure, 3~10 minutes dwell times；
(5) drying is conserved：Treat to be stripped after the completion of aquation, dried by spontaneously drying 7 to 15 days or dry kiln, drying temperature It is set as 50~65 DEG C, dries 10~12 hours to equilibrium moisture content≤4.5% one-tenth semi-finished product；
(6) it is surface-treated：Through polishing or batch ash processing after drying, baked by products application design using metal baking finish, imitative stone Paint carries out surface coating and obtains the imitative stone ecological decoration sheet material that can be decorated directly as facing.
Embodiment 14
The present embodiment ecological decoration sheet material is imitation wood ecological decoration sheet material
1st, formula composition in parts by weight：
6 parts of pore catalysis material：By La1-xSrxMO3Type nanocatalyst (LaMnO3、La0.6Sr0.4MnO3、LaCoO3Receive Rice corpuscles is by weight 1:1:1 mixing), pore-foaming agent (α-sodium olefin sulfonate), water by weight be 40：8：52 compound and obtain；
Inorganic 100 parts of powder of ecology gelling：By inorganic coagulation material 87 parts of (natural 50 parts of β-semi-hydrated gypsum, white silicic acid 20 parts of salt cement, contain CaO39.87%, SiO234.24%th, Al2O317 parts of 13.83% slag micropowder), ecological mineral powder 13 parts (sepiolite powder) is compounded and obtained；
1.5 parts of reinforcing fiber：String (1 part of wood fiber, 0.5 part of sugarcane fiber)；
4 parts of hydrophobicity waterproofing agent：2 parts of polysiloxanes, 2 parts of methyl silanol potassium；
50 parts of liquid medium：Water, alum are by weight 100：0.4 compounds and obtains；
2. as shown in figure 1, it is by the process for producing of above-mentioned raw materials formula：
(1) photocatalysis is supported：By 2.4 parts of La1-xSrxMO3Type nanocatalyst, 0.48 part of α-alkenyl sodium sulphate AOS, 3.12 parts of water, after measuring, being stirred respectively, 6 parts of pore catalysis materials of suspended porous foam are formed using pore machine；
(2) inorganic ecology gelling powder compounding：By 87 parts of inorganic coagulation material, 13 parts of ecological mineral powder through physics grinding 100 parts of inorganic ecology gelling powders are re-dubbed to 130~220 mesh, mixing；
(3) string pre-processes：1 part of wood fiber and 0.5 part of sugarcane fiber are broken for the ㎜ of length 3~18, width 0.5~5 ㎜, the ㎜ of thickness 0.1~5 chip or short silk shape, using sodium metasilicate, lime aqueous solution soaking boiling 2 hours after Centrifugal drying is to taking 12 parts after moisture content ＜ 3.5%, and (wherein the dosage of sodium metasilicate is wood fiber and the total matter of sugarcane fiber The 0.5% of amount, the dosage of lime is wood fiber and sugarcane fiber gross mass 3.0%, aqueous solution sodium metasilicate, lime gross mass Concentration is 3%, and digestion temperature is that room temperature is extremely seethed with excitement)；
(4) stir：It is 4 parts of hydrophobicity waterproofing agents, 50 parts of liquid mediums and 6 obtained by step (1) as parts by weight in formula 100 parts of inorganic ecology gelling powders of the middle gained of part pore catalysis material, step (2), and 1.5 parts of strings pass through in advance The gains action of forced stirring of processing；
(5) it is molded：Using compressing mode, 10.0 MPas of briquetting pressure, 3~10 minutes dwell times；
(6) drying is conserved：Treat to be stripped after the completion of aquation, dried by spontaneously drying 7 to 15 days or dry kiln, drying temperature It is set as 50~65 DEG C, dries 10~12 hours to equilibrium moisture content≤4.5% one-tenth semi-finished product；
(7) it is surface-treated：Through putty plated film, polishing after drying, designed by products application using spraying, baking vanish, UV Plated film, silk-screen, it is gold stamping in one or more surface treatment modes, into imitation wood ecological ornamental plate after its surface cure.
Embodiment 15
The present embodiment ecological decoration sheet material is outer curtain wall ecological decoration sheet material
As shown in figure 1, formula and process for producing by weight is：
(1) preparation of pore catalysis material：By 2.5 parts of La1-xSrxMO3Type nanocatalyst (LaMnO3、 La0.6Sr0.4MnO3、LaCoO3、La0.6Sr0.4CoO3Nano-particle is by weight 1:1:1：1 mixes), 0.05 part of pore-foaming agent (lauryl sodium sulfate, sodium sulfate of polyethenoxy ether of fatty alcohol, α-sodium olefin sulfonate are by weight 1:1:1 mixes), 2.45 parts of water, after measuring, being stirred respectively, 5 parts of pore catalysis materials of suspended porous foam are formed using pore machine；
(2) inorganic ecology gelling powder compounding：By 75 parts of inorganic coagulation material (natural 10 parts of alpha-semi water plaster stone, natural β- 10 parts of semi-hydrated gypsum, 35 parts of portland cement, 20 parts of quartz sand), ecological mineral powder 25 parts (attapulgites) is through physics grinding 100 parts of inorganic ecology gelling powders are re-dubbed to 130~220 mesh, mixing；
(3) stir：By 5 parts of hydrophobicity waterproofing agents (3 parts of polysiloxanes, 1 part of methyl silicon sodium alcoholate, 1 part of methyl silanol potassium), 68 (water, polyvinyl alcohol, sodium citrate, aluminum sulfate, alum are by weight 100 for part liquid medium：1.5：0.1：0.2：0.2 is multiple With) with 5 parts of pore catalysis materials obtained by step (1), in step (2) gained 100 parts of inorganic ecology gelling powders, 0.5 Part glass fibre mixing action of forced stirring；
(4) it is molded：Using compressing mode, 6.0 MPas of briquetting pressure, 3~10 minutes dwell times, middle one layer 1 part of ㎜ glass fiber reticular cloth of grid specification 10 × 10 of even laying；
(5) drying is conserved：Treat to be stripped after the completion of aquation, dried by spontaneously drying 7 to 15 days or dry kiln, drying temperature It is set as 50~65 DEG C, dries 10~12 hours to equilibrium moisture content≤4.5% one-tenth semi-finished product；
(6) it is surface-treated：Through polishing or batch ash processing after drying, baked by products application design using metal baking finish, imitative stone Paint progress surface coating obtains can be directly as outer curtain wall decorative sheet.
Embodiment 16
The present embodiment ecological decoration sheet material is outer curtain wall ecological decoration sheet material
2nd, as shown in figure 1, formula and process for producing by weight are：
(1) preparation of pore catalysis material：By 2.5 parts of La1-xSrxMO3Type nanocatalyst (La0.6Sr0.4CoO3Nanometer Particle), 0.05 part of pore-foaming agent (α-sodium olefin sulfonate), 2.45 parts of water, after measuring, being stirred respectively, formed using pore machine 5 parts of pore catalysis materials of suspended porous foam；
(2) inorganic ecology gelling powder compounding：By 60 parts of inorganic coagulation material (natural 20 parts of alpha-semi water plaster stone, natural β- 20 parts of semi-hydrated gypsum, 20 parts of portland cement), ecological mineral powder 40 parts (attapulgites) is through physics grinding to 130~220 Mesh, mixing are re-dubbed 100 parts of inorganic ecology gelling powders；
(3) stir：5 parts of hydrophobicity waterproofing agents (2 parts of polysiloxanes, 2 parts of methyl silicon sodium alcoholate, 1 part of methyl silanol potassium), 68 parts (water, polyvinyl alcohol, sodium citrate are by weight 100 for liquid medium：1.5：0.5 compounding) with step (1) obtained by 5 parts of pore light 100 parts of gained inorganic ecology gelling powder action of forced stirring in catalysis material, step (2)；
(4) it is molded：Using compressing mode, 6.0 MPas of briquetting pressure, 3~10 minutes dwell times, middle one layer 1.5 parts of ㎜ glass fiber reticular cloths of grid specification 3 × 3 of even laying；
(5) drying is conserved：Treat to be stripped after the completion of aquation, dried by spontaneously drying 7 to 15 days or dry kiln, drying temperature It is set as 50~65 DEG C, dries 10~12 hours to equilibrium moisture content≤4.5% one-tenth semi-finished product；
(6) it is surface-treated：Through polishing or batch ash processing after drying, baked by products application design using metal baking finish, imitative stone Paint progress surface coating obtains can be directly as outer curtain wall decorative sheet.
Embodiment 17
The present embodiment ecological decoration sheet material is outer curtain wall ecological decoration sheet material
2nd, as shown in figure 1, formula and process for producing by weight are：
(1) preparation of pore catalysis material：By 0.9 part of La1-xSrxMO3Type nanocatalyst (LaMnO3Nano-particle), 0.03 part of pore-foaming agent (lauryl sodium sulfate), 2.07 parts of water, after measuring, being stirred respectively, utilize pore machine to be formed and suspend 3 parts of pore catalysis materials of porous foam；
(2) inorganic ecology gelling powder compounding：By 75 parts of inorganic coagulation material (natural 10 parts of alpha-semi water plaster stone, natural β- 10 parts of semi-hydrated gypsum, 35 parts of portland cement, 20 parts of quartz sand), ecological mineral powder 25 parts (attapulgites) is through physics grinding 100 parts of inorganic ecology gelling powders are re-dubbed to 130~220 mesh, mixing；
(3) stir：By 4 parts of hydrophobicity waterproofing agents (polysiloxanes), 40 parts of liquid mediums (water, polyvinyl alcohol, lemons in formula Lemon acid sodium, aluminum sulfate, alum are by weight 100：1.2：0.1：0.2：0.2 compounding) with step (1) obtained by 3 parts of pores 100 parts of gained inorganic ecology gelling powder action of forced stirring in catalysis material, step (2)；
(4) it is molded：Using compressing mode, 6.0 MPas of briquetting pressure, 3~10 minutes dwell times, middle one layer 10 parts of ㎜ glass fiber reticular cloths of grid specification 5 × 5 of even laying；
(5) drying is conserved：Treat to be stripped after the completion of aquation, dried by spontaneously drying 7 to 15 days or dry kiln, drying temperature It is set as 50~65 DEG C, dries 10~12 hours to equilibrium moisture content≤4.5% one-tenth semi-finished product；
(6) it is surface-treated：Through polishing or batch ash processing after drying, baked by products application design using metal baking finish, imitative stone Paint progress surface coating obtains can be directly as outer curtain wall decorative sheet.
Embodiment 18
The present embodiment ecological decoration sheet material is outer curtain wall ecological decoration sheet material
As shown in figure 1, formula and process for producing by weight is：
(1) preparation of pore catalysis material：By 2.5 parts of La1-xSrxMO3Type nanocatalyst (LaMnO3、 La0.6Sr0.4MnO3、LaCoO3、La0.6Sr0.4CoO3Nano-particle is by weight 1:10:5：1 mixes), 0.05 part of pore-foaming agent (lauryl sodium sulfate, sodium sulfate of polyethenoxy ether of fatty alcohol, α-sodium olefin sulfonate are by weight 1:10:1 mixes), 2.45 parts of water, after measuring, being stirred respectively, 5 parts of pore catalysis materials of suspended porous foam are formed using pore machine；
(2) inorganic ecology gelling powder compounding：By 75 parts of inorganic coagulation material (natural 10 parts of alpha-semi water plaster stone, natural β- 10 parts of semi-hydrated gypsum, 35 parts of portland cement, 20 parts of quartz sand), ecological mineral powder 25 parts (attapulgites) is through physics grinding 100 parts of inorganic ecology gelling powders are re-dubbed to 130~220 mesh, mixing；
(3) stir：5 parts of hydrophobicity waterproofing agents (3 parts of polysiloxanes, 1 part of methyl silicon sodium alcoholate, 1 part of methyl silanol potassium), 68 parts (water, polyvinyl alcohol, sodium citrate, aluminum sulfate, alum are by weight 100 for liquid medium：0.5：0.1：0.2：0.2 compounding) Force to stir with 100 parts of inorganic ecology gelling powders of gained in 5 parts of pore catalysis materials obtained by step (1), step (2) Mix；
(4) it is molded：Using compressing mode, 6.0 MPas of briquetting pressure, 3~10 minutes dwell times, middle one layer 20 parts of ㎜ glass fiber reticular cloths of grid specification 10 × 10 of even laying；
(5) drying is conserved：Treat to be stripped after the completion of aquation, dried by spontaneously drying 7 to 15 days or dry kiln, drying temperature It is set as 50~65 DEG C, dries 10~12 hours to equilibrium moisture content≤4.5% one-tenth semi-finished product；
(6) it is surface-treated：Through polishing or batch ash processing after drying, baked by products application design using metal baking finish, imitative stone Paint progress surface coating obtains can be directly as outer curtain wall decorative sheet.
Performance test：Ecological decoration sheet material performance is made in embodiment 1-15 as shown in following table 1-3.
Ecological decoration sheet material performance test is made in the embodiment 1-5 of table 1
Ecological decoration sheet material performance test is made in the embodiment 6-10 of table 2
Ecological decoration sheet material performance test is made in the embodiment 11-15 of table 3

Claims (7)

1. a kind of inorganic ecological decoration sheet material of photocatalysis, it is characterised in that described ecological decoration sheet material is by following parts by weight Raw material be prepared：1.0~8.0 parts of pore catalysis materials, 100 parts of inorganic ecology gelling powders, 1.5~20 parts of enhancings are fine Dimension and/or glass fiber reticular cloth, 0.3~5.0 part of hydrophobicity waterproofing agent, 18.5~68.0 parts of liquid mediums；Pore catalysis material By：Photochemical catalyst, pore-foaming agent, water are by weight 5~50：1~8：Pore forms photocatalysis foam support after 42~94 compoundings； The photochemical catalyst is perovskite composite oxide La1-xSrxMO3Nanocatalyst, M is Mn or Co, x are 0 or 0.4, described Photochemical catalyst fineness is 400~2000 mesh；The pore-foaming agent be lauryl sodium sulfate, sodium sulfate of polyethenoxy ether of fatty alcohol, One or more in α-sodium olefin sulfonate.
2. the inorganic ecological decoration sheet material of photocatalysis as claimed in claim 1, it is characterised in that the inorganic ecology gelling powder By：Inorganic coagulation material, ecological mineral powder are by weight 60~87：13~40 compoundings form, the inorganic ecological gel powder Material fineness is 130~220 mesh.
3. the inorganic ecological decoration sheet material of photocatalysis as claimed in claim 2, it is characterised in that the inorganic coagulation material is stone One or more in cream, cement, slag micropowder；The ecological mineral powder is diatomite, vermiculite power, tourmaline anion One or more in powder, sepiolite powder, zeolite powder, attapulgite.
4. the inorganic ecological decoration sheet material of photocatalysis as claimed in claim 1, it is characterised in that the reinforcing fiber is glass fibers One or more in dimension, string, mineral fibres, the hydrophobicity waterproofing agent be methyl silicon sodium alcoholate, methyl silanol potassium or One or more in polysiloxanes.
5. the inorganic ecological decoration sheet material of photocatalysis as claimed in claim 1, it is characterised in that the liquid medium is by water, poly- Vinyl alcohol, modifying agent are by weight 100：0~1.5：0~0.5 compounding forms, and the modifying agent is sodium citrate, aluminum sulfate, sulphur One or more in sour aluminium potassium.
6. a kind of production method of photocatalysis ecological decoration sheet material as claimed in claim 1, it is characterised in that complete as follows Into：
(1) preparation of pore catalysis material：By photochemical catalyst, pore-foaming agent, water by weight 5~50：1~8:42~94 stirrings After mixing, the pore catalysis material of foam support is formed by pore；
(2) preparation of inorganic ecology gelling powder：It is 130~220 mesh that inorganic coagulation material, ecological mineral powder are milled into fineness Afterwards by weight 60~87：13~40 mixing are re-dubbed inorganic ecology gelling powder；
(3) stir：It is 0.3~5.0 part of hydrophobicity waterproofing agent by parts by weight, institute in 18.5~68.0 parts of liquid phase mediums, step (1) 1.0~8.0 parts of pore catalysis materials, 100 parts of the middle gained of step (2) the inorganic ecology gelling powders obtained are mixed into capable pressure Stirring；
(4) prepared by sheet material：Gained compound is dried to obtain photocatalysis ecological decoration sheet material through being molded, conserving；
Add in the step (3) in reinforcing fiber blending and/or step (4) and add fiberglass mesh molding with cloth, addition it is described Reinforcing fiber and/or glass fiber reticular cloth parts by weight are 1.5~20 parts.
7. production method as claimed in claim 6, it is characterised in that described reinforcing fiber be glass fibre, string, One or more in mineral fibres, through sodium metasilicate, the aqueous solution soaking of lime, boiling, dehydration before the string mixing Pretreatment.
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Denomination of invention: Photocatalysis inorganic ecological decorative board and its production method

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