A kind of battery sorting method
Technical field
The present invention relates to a kind of battery sorting method, more particularly to a kind of lithium-ion-power cell dynamic conformance sorting side
Method.
Background technology
It is more next to the demand of lithium-ion-power cell as electric automobile is increasingly prevailing and the intensified competition of new energy industry
It is bigger, while also more and more harsh, the either list of the application of stack battery module or stack battery module is required it
Body battery, weighs the uniformity that its important references best in quality is exactly lithium ion battery, and battery consistency is good for it
The benefit of application is self-evident, is led since lithium ion battery makes system, technology, inconsistent in technique and raw material type selecting
The different batches battery that each producer or same producer produce is caused all there are different degrees of performance difference, with electric in groups
Pond module increases monomer lithium ion battery demand, to ensure the property in terms of stack battery module life, efficiency and security
There can be outstanding performance, battery industry and academia are being directed to the method how research improves battery consistency always.
Ripe lithium ion battery sorting technology is partial to static separating method at present, and specific method is the constant pressure for detecting battery
Discharge capacity after charging, shelve after open-circuit voltage and 1KHz AC internal Resistance, according to the statistics Distribution value of this three parameters,
Carry out some grades of classification.This set sorting technology of current industrialization be based on lithium ion battery applications in the digital product epoch and
It is derived, the battery that this stepping technology sorts out is in integrated more series parallel structure, and reply is more multiple
Still there are many technology blind areas in miscellaneous applying working condition, not enough targetedly, for being applicable in current vehicle-mounted electrokinetic cell system or storage
The PACK requirements of energy system requirements.
The content of the invention
In order to solve the above technical problems, the object of the present invention is to provide a kind of battery sorting method, coefficient of standard deviation is used
The dynamic conformance of charge-discharge parameter in monomer lithium ion battery test process is assessed, uses the operating mode of simulated battery application terminal
The outstanding single battery of method sorting uniformity.
The battery sorting method of the present invention, including step:
(1) constant current charge-discharge is carried out three weeks with the multiplying power of 0.2C~1C to empty state single battery, with the charge and discharge in last week
Electric data do data analysis;
(2) normal distribution of battery capacity is counted, the coefficient of standard deviation for picking out capacity distribution is less than or equal to 1% electricity
Pond;
(3) coulombic efficiency of battery charging and discharging is calculated, the normal distribution of battery coulombic efficiency is counted, picks out discharge and recharge storehouse
The coefficient of standard deviation of human relations efficiency is less than or equal to 1% battery;
(4) energy efficiency of battery charging and discharging is calculated, the normal distribution of energy content of battery efficiency is counted, picks out battery charge and discharge
The coefficient of standard deviation of electric energy amount efficiency is less than or equal to 1% battery;
(5) single battery selected in the step (4) is mended into electricity 50%SOC, places in 45 DEG C of environment and stand 7 days, counted
Calculate and stand front and rear pressure difference and counted, pick out single battery of the coefficient of standard deviation less than 1% as spec battery.
Further, calculated in step (2)-(4) battery capacity, coulombic efficiency and energy efficiency average value,
Standard deviation and coefficient of standard deviation, if the battery capacity of sorting the coefficient of standard deviation of coulombic efficiency and energy efficiency be more than
1%, sub-elected again with range method meet battery capacity coulombic efficiency and energy efficiency distribution coefficient of standard deviation be less than or equal to
1% battery.
Further, the range method is:Calculate battery capacity coulombic efficiency and energy efficiency and the pole of its average value
Difference, rejecting and the very poor maximum battery of average value, then calculate average value, standard deviation and the standard deviation system of selected battery
Number, until the poor coefficient of mark is less than or equal to 1%.
According to the above aspect of the present invention, the battery sorting method of the present invention is tested using coefficient of standard deviation assessment monomer lithium ion battery
During charge-discharge parameter dynamic conformance, use the outstanding list of operating mode method sorting uniformity of simulated battery application terminal
Body battery, the battery pack for the single battery composition that method using the present invention sorts, battery capacity keep preferable one
Cause property.
Described above is only the general introduction of technical solution of the present invention, in order to better understand the technological means of the present invention,
And can be practiced according to the content of specification, described in detail below with presently preferred embodiments of the present invention as after.
Embodiment
With reference to embodiment, the embodiment of the present invention is described in further detail.Following embodiments are used for
Illustrate the present invention, but be not limited to the scope of the present invention.
When sorting battery, constant current charge-discharge first is carried out three weeks with the multiplying power of 0.5C to empty state single battery, with last week
Discharge and recharge data do data analysis.By single battery discharge and recharge three weeks, mainly single battery is allowed to tend in this process
Stable state, is used as analysis data so that the result of analysis is accurately and reliably using the discharge and recharge data in last week.Analyzed
After data, the section that battery capacity sorts is set to 1050~1100mAh grades, selects the battery of battery capacity qualification;To qualification
Battery calculated, that is, calculate average value, standard deviation and the coefficient of standard deviation of battery capacity;Judge the mark of battery capacity
Whether quasi- difference coefficient is more than 1%, and 1% battery is more than for coefficient of standard deviation, is sorted again with range method;Battery is calculated to hold
Amount and the very poor value of average value, rejecting and the very poor maximum battery of average value, then calculate the average value of selected battery, standard
Difference and coefficient of standard deviation, are less than or equal to 1% until marking poor coefficient, sub-elect and meet that the coefficient of standard deviation of capacity distribution is small
In the battery equal to 1%.Battery charging and discharging coulombic efficiency is calculated again, and sorting mode is sorted such as capacity, sub-elects discharge and recharge storehouse
Human relations efficiency standard difference coefficient meets the battery less than or equal to 1%.Then battery charging and discharging energy efficiency is calculated, sorting mode is such as
Sorted with capacity, sub-elect charge-discharge energy efficiency standard difference coefficient and meet to be less than or equal to 1% battery.Finally, will be final
The single battery selected mends electricity 50%SOC, places in 45 DEG C of environment and stands 7 days, calculates and stands front and rear pressure difference and counted,
Single battery of the coefficient of standard deviation less than 1% is picked out as spec battery.
The above is only the preferred embodiment of the present invention, is not intended to limit the invention, it is noted that for this skill
For the those of ordinary skill in art field, without departing from the technical principles of the invention, can also make it is some improvement and
Modification, these improvements and modifications also should be regarded as protection scope of the present invention.