CN105698550B - The sintering smoke purifying system and method for a kind of energy-saving and emission-reduction - Google Patents
The sintering smoke purifying system and method for a kind of energy-saving and emission-reduction Download PDFInfo
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F27D17/00—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
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Abstract
本发明的目的是针对于现有烧结烟气净化技术中存在的问题,提供一种节能减排的烧结烟气净化系统及方法,属于烧结烟气净化技术领域。该系统包括烧结机、烟气分配器、烧结机底部风箱、烧结机大烟道、电除尘器、烧结主抽风机、1#风机、2#风机、吸附塔、烟囱、物料输送设备和再生塔;并且,该系统在烧结机大烟道内设有换热器,或者该系统还设有一个除尘器,各装置间通过管道依次连接。该方法包括烧结机烟气热利用、吸附塔吸附和活性焦再生。本系统和方法在有效控制烟气温度、充分利用含热废气、降低活性焦烟气净化装置规模、避免二次污染和实现资源循环利用的基础上,实现减少投资和运行费用。
The object of the present invention is to solve the problems existing in the existing sintering flue gas purification technology, and provide a sintering flue gas purification system and method for energy saving and emission reduction, belonging to the technical field of sintering flue gas purification. The system includes sintering machine, flue gas distributor, sintering machine bottom air box, sintering machine large flue, electric dust collector, sintering main exhaust fan, 1# fan, 2# fan, adsorption tower, chimney, material conveying equipment and regeneration tower ; Moreover, the system is equipped with a heat exchanger in the large flue of the sintering machine, or the system is also equipped with a dust collector, and the devices are connected in sequence through pipelines. The method includes heat utilization of flue gas of sintering machine, adsorption of adsorption tower and regeneration of active coke. The system and method reduce investment and operating costs on the basis of effectively controlling flue gas temperature, making full use of hot waste gas, reducing the scale of activated coke flue gas purification devices, avoiding secondary pollution, and realizing resource recycling.
Description
技术领域technical field
本发明属于烧结烟气净化技术领域,具体涉及一种节能减排的烧结烟气净化系统及方法。The invention belongs to the technical field of sintering flue gas purification, and in particular relates to an energy-saving and emission-reducing sintering flue gas purification system and method.
背景技术Background technique
烧结生产过程中产生大量烟气,烟气中含有的SOx、NOx、颗粒物、重金属和二噁英等物质对环境造成污染。随着国家环保要求日益严格,多重污染物综合治理的技术是烟气治理发展的必然趋势。活性焦烟气净化工艺能够在脱硫的基础上实现低温脱硝,同时对粉尘、重金属及二噁英等污染物有一定的脱除效果。此外,脱硫副产物为高品质硫酸,可以回收硫资源,符合循环经济的理念,是当前世界公认的最具前途的多种污染物综合治理技术。但活性焦烟气净化工艺应用于烧结烟气治理时,还存在以下问题:A large amount of flue gas is produced during the sintering production process, and substances such as SOx, NOx, particulate matter, heavy metals and dioxins contained in the flue gas pollute the environment. With the increasingly stringent national environmental protection requirements, the technology of comprehensive treatment of multiple pollutants is an inevitable trend in the development of flue gas treatment. The activated coke flue gas purification process can realize low-temperature denitrification on the basis of desulfurization, and has a certain removal effect on dust, heavy metals, dioxins and other pollutants. In addition, the by-product of desulfurization is high-quality sulfuric acid, which can recover sulfur resources, conforms to the concept of circular economy, and is currently recognized as the most promising comprehensive treatment technology for various pollutants in the world. However, when the activated coke flue gas purification process is applied to sintering flue gas treatment, there are still the following problems:
(1)烧结烟气温度控制(1) Sintering flue gas temperature control
烧结烟气温度波动较大,正常运行时温度为120~180℃;而活性焦烟气净化工艺要求入口烟气温度不超过150℃,如入口烟气温度高于150℃,容易造成活性焦床层出现超温现象,影响系统正常运行。中国专利ZL2013102748101公布了一种烟气降温的方法:通过向系统中兑入冷空气及喷入冷却水对烟气进行降温。但兑入冷空气会增加下游风机和吸附塔的负荷,增加系统能耗和投资;烟气量增加会降低烟气与活性焦床层的接触时间,影响净化效果;喷入冷却水降温存在腐蚀性问题,下游烟气管道、风机、吸附塔等设施需提高防腐等级,同时烟气中水含量增加会降低氮氧化物去除效果。The temperature of the sintering flue gas fluctuates greatly, and the temperature is 120-180°C during normal operation; while the activated coke flue gas purification process requires the inlet flue gas temperature not to exceed 150°C, if the inlet flue gas temperature is higher than 150°C, it is easy to cause the active coke bed layer overheating phenomenon, affecting the normal operation of the system. Chinese patent ZL2013102748101 discloses a method for cooling flue gas: cooling the flue gas by mixing cold air into the system and spraying cooling water. However, adding cold air will increase the load of downstream fans and adsorption towers, increasing system energy consumption and investment; increasing the amount of flue gas will reduce the contact time between flue gas and activated coke bed, affecting the purification effect; spraying cooling water to cool down will cause corrosion To solve the problem of corrosion resistance, the downstream flue gas pipelines, fans, adsorption towers and other facilities need to improve the anti-corrosion level. At the same time, the increase of water content in the flue gas will reduce the removal effect of nitrogen oxides.
(2)活性焦再生过程中热烟气外排(2) Exhaust of hot flue gas during active coke regeneration
如图1所示,现有技术中采用类似于壳管式换热器的再生塔进行活性焦的再生,活性焦从现有技术再生塔404的顶部进入,先经加热段加热至360~420℃,再经冷却段冷却至80~120℃,最后到达再生塔404底部。在加热段:400~470℃的高温热风经换热后温度变为300~350℃经风机401排出,一部分热风返回煤气燃烧器402循环利用,另一部分热风外排;在冷却段:常温空气经风机403进入再生塔404换热后外排,外排冷却空气温度为80~120℃。综上,再生塔中加热段和冷却段均存在含热废气外排现象,造成能源浪费。中国专利申请CN201410427293公布了一种活性焦再生过程中余热利用的方法:部分热风用于煤气预热后外排;外排冷却空气部分用于煤气燃烧的助燃空气,另一部分直接排放。但该工艺方法仍然存在含热废气外排现象,能源未能完全回收利用。As shown in Figure 1, in the prior art, a regeneration tower similar to a shell-and-tube heat exchanger is used to regenerate active coke. °C, then cooled to 80-120 °C through the cooling section, and finally reached the bottom of the regeneration tower 404. In the heating section: the high-temperature hot air at 400-470°C is exchanged and the temperature becomes 300-350°C and discharged by the fan 401, part of the hot air is returned to the gas burner 402 for recycling, and the other part is discharged outside; in the cooling section: normal temperature air is passed through The fan 403 enters the regeneration tower 404 for heat exchange and discharges outside, and the cooling air temperature of the discharge outside is 80-120°C. In summary, both the heating section and the cooling section of the regeneration tower have the phenomenon of exhaustion of hot exhaust gas, resulting in energy waste. Chinese patent application CN201410427293 discloses a method for utilizing waste heat in the regeneration process of activated coke: part of the hot air is used for gas preheating and exhausted; part of the exhausted cooling air is used for combustion-supporting air for gas combustion, and the other part is directly discharged. However, this process method still has the phenomenon of exhaust gas containing heat, and the energy cannot be fully recovered.
(3)活性焦烟气净化工艺投资大(3) Large investment in activated coke flue gas purification process
同等烟气量条件下,活性焦烟气净化工艺的初期投资一般为湿法、半干法脱硫工艺初期投资的2~3倍,这也限制了活性焦烟气净化工艺的推广应用。因此降低活性焦烟气净化装置的规模,以减少投资和运行费用是活性焦烟气净化工艺推广应用必须解决的问题。Under the condition of the same flue gas volume, the initial investment of activated coke flue gas purification process is generally 2 to 3 times of the initial investment of wet and semi-dry desulfurization process, which also limits the popularization and application of activated coke flue gas purification process. Therefore, reducing the scale of activated coke flue gas purification equipment to reduce investment and operating costs is a problem that must be solved for the promotion and application of activated coke flue gas purification technology.
(4)活性焦烟气净化工艺中的二次污染(4) Secondary pollution in activated coke flue gas purification process
活性焦烟气净化工艺中存在二次污染问题:如活性焦再生过程中产生的高SO2浓度气体用于生产浓硫酸时,会有废气产生,该废气中含有SOx、硫酸酸雾等;活性焦循环过程中会有破损,破损的活性焦经振动筛筛分后产生的固体废物(焦粉)。There are secondary pollution problems in the flue gas purification process of activated coke : for example, when the high SO2 concentration gas generated in the regeneration process of activated coke is used to produce concentrated sulfuric acid, waste gas will be generated, which contains SOx, sulfuric acid mist, etc.; There will be damage during the coke cycle, and the damaged activated coke will be sieved by a vibrating sieve to produce solid waste (coke powder).
综上,现有的活性焦烟气净化工艺存在烟气温度控制方式不合理、含热废气外排、能源浪费、初期投资大、产生二次污染等缺点,需要开发适合烧结机生产的活性焦烟气净化工艺和方法,在有效控制烟气温度、充分利用含热废气、降低活性焦烟气净化装置规模和避免二次污染的基础上,实现减少投资和运行费用。In summary, the existing activated coke flue gas purification process has disadvantages such as unreasonable flue gas temperature control, hot exhaust gas discharge, energy waste, large initial investment, and secondary pollution. It is necessary to develop active coke suitable for sintering machine production The flue gas purification process and method, on the basis of effectively controlling the flue gas temperature, making full use of the heat-containing waste gas, reducing the scale of the activated coke flue gas purification device and avoiding secondary pollution, can reduce investment and operating costs.
发明内容Contents of the invention
本发明的目的是针对于现有技术中存在的问题,提供一种节能减排的烧结烟气净化系统及方法,在有效控制烟气温度、充分利用含热废气、降低活性焦烟气净化装置规模和避免二次污染的基础上,实现减少投资和运行费用。The purpose of the present invention is to solve the problems existing in the prior art, and provide an energy-saving and emission-reducing sintering flue gas purification system and method. On the basis of large scale and avoiding secondary pollution, the investment and operating costs can be reduced.
一种节能减排的烧结烟气净化系统,包括烧结机、烟气分配器、烧结机底部风箱、烧结机大烟道、电除尘器、烧结主抽风机、1#风机、2#风机、吸附塔、烟囱、物料输送设备和再生塔;A sintering flue gas purification system for energy saving and emission reduction, including sintering machine, flue gas distributor, bellows at the bottom of sintering machine, large flue duct of sintering machine, electrostatic precipitator, sintering main exhaust fan, 1# fan, 2# fan, adsorption towers, chimneys, material handling equipment and regeneration towers;
该系统在烧结机大烟道内还设有换热器,烧结机、烧结机底部风箱、烧结机大烟道、电除尘器、烧结主抽风机、1#风机、吸附塔和烟囱通过管道依次连接,而且烧结主抽风机的出口通过支路引出的循环烟气管道与2#风机入口连接;其中,上述系统中,所述烟气分配器位于烧结机台车上,2#风机的出口与烟气分配器通过管道连接;所述吸附塔设有进气口和出气口,吸附塔和再生塔均设有进料口和出料口,吸附塔出料口通过物料输送设备与再生塔进料口连接,吸附塔进料口通过物料输送设备与再生塔出料口相连接;The system also has a heat exchanger in the large flue of the sintering machine, and the sintering machine, the bellows at the bottom of the sintering machine, the large flue of the sintering machine, the electrostatic precipitator, the sintering main exhaust fan, the 1# fan, the adsorption tower and the chimney are connected in sequence through pipes , and the outlet of the sintering main exhaust fan is connected to the inlet of the 2# fan through the circulating flue gas pipe drawn from the branch; wherein, in the above system, the flue gas distributor is located on the sintering machine trolley, and the outlet of the 2# fan is connected to the flue gas The gas distributor is connected through pipelines; the adsorption tower is provided with an air inlet and an air outlet, and both the adsorption tower and the regeneration tower are provided with a feed inlet and a discharge outlet, and the outlet of the adsorption tower is fed through the material conveying equipment and the regeneration tower The inlet of the adsorption tower is connected with the outlet of the regeneration tower through the material conveying equipment;
所述再生塔为现有技术中的再生塔,再生塔由上至下设有加热段、抽气段和冷却段,活性焦从再生塔顶部进料口进入,经加热段、抽气段、冷却段,最后到达再生塔底部出料口;加热段设有高温热风进口和出口,外部设有3#风机和热风炉,高温热风进口通过管道与热风炉出口相连,高温热风出口通过管道连接至3#风机入口,3#风机出口通过管道与热风炉进口相连;再生塔抽气段设有出气口,外部设有接触法制酸系统,出气口与制酸系统的气体入口通过管道相连;再生塔冷却段设有冷却空气进口和出口,外部设有4#风机,4#风机出口与冷却空气进口连接;The regeneration tower is a regeneration tower in the prior art. The regeneration tower is provided with a heating section, an air extraction section and a cooling section from top to bottom. The cooling section finally reaches the discharge port at the bottom of the regeneration tower; the heating section is equipped with a high-temperature hot air inlet and outlet, and a 3# fan and a hot-blast stove are installed outside. The inlet of the 3# fan and the outlet of the 3# fan are connected to the inlet of the hot blast stove through pipes; the exhaust section of the regeneration tower is equipped with a gas outlet, and a contact method acid system is installed on the outside, and the gas outlet is connected to the gas inlet of the acid system through a pipeline; the regeneration tower The cooling section is equipped with a cooling air inlet and outlet, and a 4# fan is installed outside, and the outlet of the 4# fan is connected to the cooling air inlet;
或者,另一种结构的节能减排的烧结烟气净化系统,包括烧结机、烟气分配器、烧结机底部风箱、烧结机大烟道、电除尘器、烧结主抽风机、1#风机、2#风机、吸附塔、烟囱、物料输送设备和再生塔;Or, another energy-saving and emission-reducing sintering flue gas purification system, including sintering machine, flue gas distributor, sintering machine bottom bellows, sintering machine large flue, electric dust collector, sintering main exhaust fan, 1# fan, 2# fan, adsorption tower, chimney, material conveying equipment and regeneration tower;
该系统还设有一个除尘器,烧结机与烧结机底部风箱通过管道连接,烧结机底部风箱中的头部数个风箱和尾部数个风箱通过管道与除尘器连接,剩余的烧结机底部风箱、烧结机大烟道、电除尘器、烧结主抽风机、1#风机、吸附塔和烟囱通过管道依次连接,除尘器通过管道与2#风机入口连接;The system is also equipped with a dust collector. The sintering machine is connected to the bottom bellows of the sintering machine through pipelines. The several bellows at the head and the tail several bellows in the bottom bellows of the sintering machine are connected to the dust collector through pipelines. The remaining bellows at the bottom of the sintering machine, The large flue of the sintering machine, the electrostatic precipitator, the sintering main exhaust fan, the 1# fan, the adsorption tower and the chimney are connected in sequence through pipes, and the dust collector is connected with the inlet of the 2# fan through pipes;
其中,上述系统中,所述烟气分配器位于烧结机台车上,2#风机的出口与烟气分配器通过管道连接;所述吸附塔设有进气口和出气口,吸附塔和再生塔均设有进料口和出料口,吸附塔出料口通过物料输送设备与再生塔进料口连接,吸附塔进料口通过物料输送设备与再生塔出料口相连接;Wherein, in the above system, the flue gas distributor is located on the sintering machine trolley, and the outlet of the 2# fan is connected to the flue gas distributor through a pipeline; the adsorption tower is provided with an air inlet and an air outlet, and the adsorption tower and regeneration The towers are equipped with feed inlets and outlets, the outlet of the adsorption tower is connected to the inlet of the regeneration tower through material conveying equipment, and the inlet of the adsorption tower is connected to the outlet of the regeneration tower through material conveying equipment;
所述再生塔为现有技术中的再生塔,再生塔由上至下设有加热段、抽气段和冷却段,活性焦从再生塔顶部进料口进入,经加热段、抽气段、冷却段,最后到达再生塔底部出料口;加热段设有高温热风进口和出口,外部设有3#风机和热风炉,高温热风进口通过管道与热风炉出口相连,高温热风出口通过管道连接至3#风机入口,3#风机出口通过管道与热风炉进口相连;再生塔抽气段设有出气口,外部设有接触法制酸系统,出气口与制酸系统的气体入口通过管道相连;再生塔冷却段设有冷却空气进口和出口,外部设有4#风机,4#风机出口与冷却空气进口连接;The regeneration tower is a regeneration tower in the prior art. The regeneration tower is provided with a heating section, an air extraction section and a cooling section from top to bottom. The cooling section finally reaches the discharge port at the bottom of the regeneration tower; the heating section is equipped with a high-temperature hot air inlet and outlet, and a 3# fan and a hot-blast stove are installed outside. The inlet of the 3# fan and the outlet of the 3# fan are connected to the inlet of the hot blast stove through pipes; the exhaust section of the regeneration tower is equipped with a gas outlet, and a contact method acid system is installed on the outside, and the gas outlet is connected to the gas inlet of the acid system through a pipeline; the regeneration tower The cooling section is equipped with a cooling air inlet and outlet, and a 4# fan is installed outside, and the outlet of the 4# fan is connected to the cooling air inlet;
较好的,上述两种结构的系统中,再生塔加热段和再生塔冷却段均为管壳换热形式;Preferably, in the systems of the above two structures, the heating section of the regeneration tower and the cooling section of the regeneration tower are both in the form of shell and tube heat exchange;
当热风炉为煤气燃烧炉时,可充分利用钢铁厂富余的煤气作为燃料,在整体上节约燃料成本;When the hot blast stove is a gas-fired furnace, the surplus gas in the iron and steel plant can be fully utilized as fuel to save fuel costs as a whole;
更进一步的,上述两种结构的系统中,3#风机出口设置支路管道与2#风机入口相连,并且再生塔冷却段的冷却空气出口与2#风机入口通过管道相连;Furthermore, in the systems of the above two structures, the outlet of the 3# fan is provided with a branch pipeline connected to the inlet of the 2# fan, and the cooling air outlet of the cooling section of the regeneration tower is connected to the inlet of the 2# fan through a pipeline;
再进一步的,上述两种结构的系统中,再生塔底部还设有振动筛,振动筛设有进料口,大颗粒物料出口和小颗粒物料出口;再生塔的出料口与振动筛进料口连接,振动筛的大颗粒物料出口通过物料输送设备与吸附塔进料口连接,振动筛的小颗粒物料出口连接至系统外的烧结机配料系统;Furthermore, in the systems of the above two structures, a vibrating screen is also provided at the bottom of the regeneration tower, and the vibrating screen is provided with a feed inlet, a large particle material outlet and a small particle material outlet; the discharge port of the regeneration tower is connected to the vibrating screen feed The large particle material outlet of the vibrating screen is connected to the inlet of the adsorption tower through the material conveying equipment, and the small particle material outlet of the vibrating screen is connected to the sintering machine batching system outside the system;
更好的,上述两种结构的系统中,接触法制酸系统设有出气口,并将出气口通过管道连接至1#风机的入口;Even better, in the systems of the above two structures, the contact method acid system is provided with an air outlet, and the air outlet is connected to the inlet of the 1# fan through a pipeline;
最佳的,上述两种结构的系统中,在循环烟气管道上设置无级调节阀;在循环烟气管道引出点与接触法制酸系统出气口和1#风机入口管道连接点之间的管道上设置无级调节阀;在与吸附塔进出气口连接的管道上分别设置无级调节阀;在3#风机出口与2#风机入口连接的管道上设置无级调节阀和节流阀;在再生塔冷却段的冷却空气出口与2#风机入口连接的管道上设置无级调节阀和节流阀;在接触法制酸系统出气口与1#风机入口连接的管道上设置无级调节阀;在2#风机入口端设置与空气联通的空气支路管道,并在该管道上设置无级调节阀和节流阀。Optimally, in the systems of the above two structures, a stepless regulating valve is set on the circulating flue gas pipeline; the pipeline between the outlet point of the circulating flue gas pipeline and the gas outlet of the contact acid system and the connection point of the 1# fan inlet pipeline Set a stepless regulating valve on the top; set a stepless regulating valve on the pipeline connected to the inlet and outlet of the adsorption tower; set a stepless regulating valve and a throttling valve on the pipeline connecting the outlet of the 3# fan and the inlet of the 2# fan; Set a stepless regulating valve and a throttling valve on the pipeline connecting the cooling air outlet of the cooling section of the tower to the inlet of the 2# fan; set a stepless regulating valve on the pipeline connecting the outlet of the contact acid system to the inlet of the 1# fan; #The air branch pipeline connected with the air is set at the inlet of the fan, and a stepless regulating valve and a throttle valve are set on the pipeline.
一种节能减排的烧结烟气净化方法,利用了上述两种结构的节能减排的烧结烟气净化系统,包括如下步骤:An energy-saving and emission-reducing sintering flue gas purification method utilizes the energy-saving and emission-reducing sintering flue gas purification system of the above two structures, including the following steps:
1)烧结机烟气热利用1) Heat utilization of sintering machine flue gas
采用如下方法a或b:Use method a or b as follows:
方法a:烧结机烧结产生的高温烟气经烧结机底部风箱进入烧结大烟道,烟气经换热器换热,再经电除尘器、烧结主抽风机的除尘和加压后,一部分烟气经1#风机加压后进入吸附塔,其余烟气作为循环烟气通过循环烟气管道进入2#风机前端的管道内;Method a: The high-temperature flue gas generated by the sintering of the sintering machine enters the large sintering flue through the bellows at the bottom of the sintering machine. The gas enters the adsorption tower after being pressurized by the 1# fan, and the rest of the flue gas enters the pipe at the front end of the 2# fan as the circulating flue gas through the circulating flue gas pipeline;
方法b:将烧结机头部部分风箱的低温烟气和烧结机尾部部分风箱的高温烟气通入管道中混合作为循环烟气,经过除尘器除尘进入2#风机前端的管道内,其余风箱的烟气进入烧结大烟道,经电除尘器除尘、烧结主抽风机和1#风机加压后进入吸附塔;Method b: The low-temperature flue gas from the bellows at the head part of the sintering machine and the high-temperature flue gas from the bellows at the tail of the sintering machine are passed into the pipeline and mixed as circulating flue gas, and the dust is removed by the dust collector and enters the pipeline at the front end of the 2# fan. The flue gas enters the large sintering flue, and after being dedusted by the electrostatic precipitator, pressurized by the sintering main exhaust fan and 1# fan, it enters the adsorption tower;
2)吸附塔吸附2) adsorption tower adsorption
输送到吸附塔中的烧结烟气,与吸附塔内部的活性焦进行接触,烟气内的SO2、NOx、颗粒物、二噁英等污染物被活性焦吸附,净化后的烟气经烟囱排放;The sintering flue gas transported to the adsorption tower is in contact with the active coke inside the adsorption tower, SO 2 , NOx, particulate matter, dioxin and other pollutants in the flue gas are adsorbed by the active coke, and the purified flue gas is discharged through the chimney ;
3)活性焦再生3) Active coke regeneration
吸附了污染物的活性焦从吸附塔转移到再生塔,活性焦由再生塔的顶部进入,经加热段、抽气段和冷却段处理后得到再生,最后到达再生塔底部;The activated coke that has adsorbed pollutants is transferred from the adsorption tower to the regeneration tower, and the activated coke enters from the top of the regeneration tower, is regenerated after being treated in the heating section, pumping section and cooling section, and finally reaches the bottom of the regeneration tower;
在加热段:经热风炉加热至400~470℃的高温热风从再生塔加热段一侧进入,与流经加热段的活性焦进行不接触换热将活性焦加热,高温热风温度变为300~350℃,然后从加热段的另一侧输出;一部分换热后的高温热风作为外排热风经3#风机加压后进入2#风机前端的管道内,另一部分返回热风炉经加热重新作为高温热风使用;In the heating section: the high-temperature hot air heated to 400~470℃ by the hot blast stove enters from the side of the heating section of the regeneration tower, and conducts non-contact heat exchange with the active coke flowing through the heating section to heat the active coke, and the temperature of the high-temperature hot air becomes 300~ 350°C, and then output from the other side of the heating section; part of the high-temperature hot air after heat exchange is used as the external hot air, pressurized by the 3# fan, and then enters the pipeline at the front end of the 2# fan, and the other part returns to the hot blast stove and is heated again as a high temperature Hot air use;
当热风炉为煤气燃烧器时,可利用钢厂富余的煤气作为燃料来源,整体上节约了燃料成本;When the hot blast stove is a gas burner, the surplus gas of the steel plant can be used as the fuel source, which saves the fuel cost as a whole;
在抽气段:活性焦在加热段再生过程中产生的高SO2浓度气体由抽气段排出进入接触法制酸系统,制取98%硫酸,制酸系统制取硫酸产生的尾气经过1#风机加压后进入吸附塔,尾气中含有的污染物被吸附塔中的活性焦吸附去除,得到净化的尾气由烟囱排出;In the gas extraction section: the high SO 2 concentration gas produced during the regeneration of the active coke in the heating section is discharged from the exhaust section into the contact acid system to produce 98% sulfuric acid, and the tail gas produced by the acid system passes through the 1# fan After pressurized, it enters the adsorption tower, and the pollutants contained in the tail gas are adsorbed and removed by the active coke in the adsorption tower, and the purified tail gas is discharged from the chimney;
在冷却段:作为冷却空气的常温空气经4#风机加压后从再生塔冷却段的一侧进入,与流经冷却段的活性焦进行不接触换热,将活性焦冷却后,冷却空气升温至80~120℃,外排进入2#风机前端的管道内;In the cooling section: the normal temperature air used as cooling air enters from the side of the cooling section of the regeneration tower after being pressurized by the 4# fan, and conducts non-contact heat exchange with the active coke flowing through the cooling section. After cooling the active coke, the cooling air heats up To 80 ~ 120 ℃, the external discharge enters the pipe at the front end of the 2# fan;
再生后的活性焦由再生塔排出进入振动筛,筛分后粒径≥1.5mm的活性焦颗粒返回吸附塔继续工作,粒径<1.5mm的活性焦颗粒收集后进入烧结机配料系统,作为烧结原料重新利用;The regenerated active coke is discharged from the regeneration tower into the vibrating screen, and the activated coke particles with a particle size ≥ 1.5mm after screening are returned to the adsorption tower to continue working. raw material reuse;
上述步骤1)中产生的循环烟气、步骤3)中在加热段产生的外排热风和冷却段产生的外排冷却空气在2#风机入口前端的管道内混合形成混合烟气后,进入2#风机加压,再经过烟气分配器,最终返回烧结机料面参与烧结过程,并且,应控制进入烟气分配器前混合烟气中氧气含量,如氧气含量不足,应打开空气支路管道上的节流阀和无级调节阀,通过吸入空气调整氧气含量;The circulating flue gas generated in the above step 1), the outer hot air generated in the heating section and the outer cooling air generated in the cooling section in step 3) are mixed in the pipe at the front end of the 2# fan inlet to form a mixed flue gas, and then enter the 2 #The fan is pressurized, then passes through the flue gas distributor, and finally returns to the material surface of the sintering machine to participate in the sintering process, and the oxygen content in the mixed flue gas before entering the flue gas distributor should be controlled. If the oxygen content is insufficient, the air branch pipe should be opened Throttle valve and stepless regulating valve on the top, adjust the oxygen content by inhaling air;
较好的,上述烧结烟气净化方法的步骤1)方法a中,通过调整换热器内水流量来调整换热量,以保证进入吸附塔的烟气温度为120~140℃;同时控制进入吸附塔的烟气量占总烧结烟气量的50%~80%,进入2#风机入口前端的循环烟气量占总烧结烟气量的20%~50%,从而有效降低吸附塔规模,减少投资和运行费用;Preferably, in step 1) method a of the above-mentioned sintering flue gas purification method, the heat exchange rate is adjusted by adjusting the water flow rate in the heat exchanger, so as to ensure that the temperature of the flue gas entering the adsorption tower is 120-140°C; The flue gas volume of the adsorption tower accounts for 50% to 80% of the total sintering flue gas volume, and the circulating flue gas volume entering the front end of the 2# fan inlet accounts for 20% to 50% of the total sintering flue gas volume, thereby effectively reducing the scale of the adsorption tower. Reduce investment and operating costs;
经换热器换热后产生蒸汽或热水可作为热源使用,例如,蒸汽可并入厂区蒸汽管网或进入汽轮机组发电;The steam or hot water generated after heat exchange by the heat exchanger can be used as a heat source, for example, the steam can be integrated into the steam pipe network of the factory area or enter the steam turbine unit to generate electricity;
上述烧结烟气净化方法的步骤1)方法b中,通过调整头部低温风箱和尾部高温风箱的数目,以保证进入吸附塔的烟气温度为120~140℃;同时控制进入吸附塔的烟气量占总烧结烟气量的50%~80%,进入2#风机入口前端的循环烟气量占总烧结烟气量的20%~50%,从而有效降低电除尘器、烧结主抽风机和吸附塔规模,从而减少投资和运行费用;In step 1) method b of the above-mentioned sintering flue gas purification method, by adjusting the number of low-temperature wind boxes at the head and high-temperature wind boxes at the tail, to ensure that the temperature of the flue gas entering the adsorption tower is 120-140°C; at the same time, the temperature of the flue gas entering the adsorption tower is controlled The amount of circulating flue gas that enters the front end of the 2# fan inlet accounts for 20% to 50% of the total sintering flue gas volume, thereby effectively reducing the electrostatic precipitator, sintering main exhaust fan and Adsorption tower scale, thereby reducing investment and operating costs;
上述烧结烟气净化方法的步骤3)中,进入再生塔加热段的高温热风温度为400~470℃,换热后温度降为300~350℃;冷却段外排冷却空气温度为80~120℃;温度较高的外排热风和外排冷却空气最终返回烧结机料面,从而避免了含热废气直接外排,将能源完全回收利用;同时制酸系统产生的尾气经吸附塔处理后再排放,避免了污染环境;In step 3) of the above sintering flue gas purification method, the temperature of the high-temperature hot air entering the heating section of the regeneration tower is 400-470°C, and the temperature drops to 300-350°C after heat exchange; the temperature of the cooling air discharged from the cooling section is 80-120°C ;The higher temperature exhausted hot air and outer cooling air are finally returned to the material surface of the sintering machine, thus avoiding the direct discharge of hot waste gas and completely recycling the energy; at the same time, the tail gas produced by the acid system is treated by the adsorption tower before being discharged , to avoid polluting the environment;
上述烧结烟气净化方法的步骤3)中,混合烟气进入烟气分配器前,氧气含量应占混合烟气体积的15%以上;In step 3) of the above sintering flue gas purification method, before the mixed flue gas enters the flue gas distributor, the oxygen content should account for more than 15% of the volume of the mixed flue gas;
上述烧结烟气净化方法,可通过设置在管道上的无级调节阀和节流阀来调节不同管道内气体的流量,以保证不同管道内的压力平衡;例如,设置在循环烟气管道上的无级调节阀,在循环烟气管道引出点与接触法制酸系统出气口和1#风机入口管道连接点之间的管道上的无级调节阀,在与吸附塔进气口和出气口连接的管道上的无级调节阀,在3#风机出口与2#风机入口连接的管道上的无级调节阀和节流阀,在再生塔冷却段的冷却空气出口与2#风机入口连接的管道上的无级调节阀和节流阀,在接触法制酸系统出气口与1#风机入口连接的管道上的无级调节阀,以及在空气支路管道上的无级调节阀和节流阀。The above-mentioned sintering flue gas purification method can adjust the flow of gas in different pipelines through stepless regulating valves and throttle valves installed on the pipelines to ensure the pressure balance in different pipelines; for example, the Stepless regulating valve, a stepless regulating valve on the pipeline between the outlet point of the circulating flue gas pipeline and the gas outlet of the contact method acid system and the connection point of the 1# fan inlet pipeline, connected to the inlet and outlet of the adsorption tower The stepless regulating valve on the pipeline, the stepless regulating valve and throttling valve on the pipeline connecting the 3# fan outlet and the 2# fan inlet, and the stepless regulating valve and throttling valve on the pipeline connecting the cooling air outlet of the cooling section of the regeneration tower and the 2# fan inlet The stepless regulating valve and throttle valve, the stepless regulating valve on the pipeline connecting the outlet of the contact acid system with the inlet of the 1# fan, and the stepless regulating valve and throttle valve on the air branch pipeline.
与现有技术相比,本发明的优势在于:Compared with the prior art, the present invention has the advantages of:
1、本系统在有效控制烟气温度、充分利用含热废气、降低活性焦烟气净化装置规模和避免二次污染的基础上,实现减少投资和运行费用。1. On the basis of effectively controlling flue gas temperature, making full use of hot waste gas, reducing the scale of activated coke flue gas purification equipment and avoiding secondary pollution, the system can reduce investment and operating costs.
2、该方法中,烧结烟气显热经换热器吸收后可用于生产蒸汽或热水,或者烧结烟气显热返回烧结机料面,降低烧结燃料消耗;从而在有效控制外排烟气温度的同时,实现能源循环利用。2. In this method, the sensible heat of the sintering flue gas can be used to produce steam or hot water after being absorbed by the heat exchanger, or the sensible heat of the sintering flue gas can be returned to the material surface of the sintering machine, reducing the consumption of sintering fuel; thus effectively controlling the exhaust gas At the same time, energy recycling is realized.
3、该方法中,活性焦再生阶段产生的外排热风和外排冷却空气最终返回烧结机料面,避免了含热废气外排,能源完全回收利用。3. In this method, the exhausted hot air and cooled air generated in the active coke regeneration stage are finally returned to the material surface of the sintering machine, which avoids the exhaustion of hot waste gas and completely recycles energy.
4、该方法中,进入吸附塔的烟气量为总烟气量的50%~80%,可有效降低吸附塔规模,从而减少投资和运行费用。4. In this method, the amount of flue gas entering the adsorption tower is 50% to 80% of the total flue gas amount, which can effectively reduce the scale of the adsorption tower, thereby reducing investment and operating costs.
5、该方法中,接触法制酸系统产生的尾气经吸附塔处理后排放,避免污染环境;活性焦再生过程中产生的焦粉返回烧结机配料系统,作为烧结原料再利用;避免了二次污染。5. In this method, the tail gas produced by the contact method acid production system is discharged after being treated by the adsorption tower to avoid environmental pollution; the coke powder produced during the regeneration of activated coke is returned to the sintering machine batching system for reuse as sintering raw materials; secondary pollution is avoided .
附图说明Description of drawings
图1、为现有技术的再生塔示意图;Fig. 1, is the regeneration tower schematic diagram of prior art;
图2、为本发明实施例1的烧结烟气净化系统示意图;Fig. 2 is a schematic diagram of a sintering flue gas purification system according to Embodiment 1 of the present invention;
图3、为本发明实施例2的烧结烟气净化系统示意图;Fig. 3 is a schematic diagram of a sintering flue gas purification system according to Embodiment 2 of the present invention;
其中,1-烧结机,2-烧结机底部风箱,3-烧结机大烟道,4-换热器,5-电除尘器,6-烧结主抽风机,7-1#风机,8-吸附塔,9-烟囱,10-1#带式输送机,11-1#斗提机,12-2#斗提机,13-再生塔,14-振动筛,15-烧结机配料系统,16-2#带式输送机,17-3#风机,18-煤气燃烧器,19-接触法制酸系统,20-4#风机,21-2#风机,22-烟气分配器,23-除尘器,24-2#风机入口前端的管道,1301-再生塔加热段,1302-再生塔抽气段,1303-再生塔冷却段,V1~V8-无级调节阀1~8,M1~M3-节流阀1~3,L-循环烟气管道,401-风机1,402-煤气燃烧器,403-风机2,404-现有技术再生塔;Among them, 1-sintering machine, 2-air box at the bottom of sintering machine, 3-big flue of sintering machine, 4-heat exchanger, 5-electric dust collector, 6-sintering main exhaust fan, 7-1# fan, 8-adsorption Tower, 9-chimney, 10-1# belt conveyor, 11-1# bucket elevator, 12-2# bucket elevator, 13-regeneration tower, 14-vibrating screen, 15-sintering machine batching system, 16- 2# belt conveyor, 17-3# fan, 18-gas burner, 19-contact acid system, 20-4# fan, 21-2# fan, 22-flue gas distributor, 23-dust collector, 24-The pipeline at the front end of the fan inlet of 2#, 1301-heating section of regeneration tower, 1302-pumping section of regeneration tower, 1303-cooling section of regeneration tower, V1~V8-stepless regulating valve 1~8, M1~M3-throttling Valves 1-3, L-circulating flue gas pipeline, 401-fan 1, 402-gas burner, 403-fan 2, 404-existing technology regeneration tower;
箭头指示方向为物料或气体的流向。The direction indicated by the arrow is the flow direction of material or gas.
具体实施方式detailed description
实施例1Example 1
一种节能减排的烧结烟气净化系统,如图2所示,包括烧结机1、烧结机底部风箱2、烧结机大烟道3、换热器4、电除尘器5、烧结主抽风机6、1#风机7、吸附塔8、烟囱9、1#带式输送机10、1#斗提机11、2#斗提机12、再生塔13、振动筛14、烧结机配料系统15、2#带式输送机16、3#风机17、煤气燃烧器18、接触法制酸系统19、4#风机20、2#风机21、烟气分配器22;A sintering flue gas purification system for energy saving and emission reduction, as shown in Figure 2, including a sintering machine 1, a sintering machine bottom bellows 2, a sintering machine large flue 3, a heat exchanger 4, an electric dust collector 5, and a sintering main exhaust fan 6. 1# fan 7, adsorption tower 8, chimney 9, 1# belt conveyor 10, 1# bucket elevator 11, 2# bucket elevator 12, regeneration tower 13, vibrating screen 14, sintering machine batching system 15, 2# belt conveyor 16, 3# fan 17, gas burner 18, contact acid system 19, 4# fan 20, 2# fan 21, flue gas distributor 22;
其中,烧结机1与烧结机底部风箱2连接,烧结机底部风箱2与烧结机大烟道3连接,烧结机大烟道3与烧结主抽风机6连接,烧结主抽风机6与1#风机7连接,1#风机7与吸附塔8连接,吸附塔8与烟囱9连接,上述连接均由管道连接;Among them, the sintering machine 1 is connected to the bellows 2 at the bottom of the sintering machine, the bellows 2 at the bottom of the sintering machine is connected to the large flue 3 of the sintering machine, the large flue 3 of the sintering machine is connected to the sintering main exhaust fan 6, and the sintering main exhaust fan 6 is connected to the 1# fan 7 connection, the 1# fan 7 is connected with the adsorption tower 8, and the adsorption tower 8 is connected with the chimney 9, and the above connections are all connected by pipelines;
烟气分配器22位于烧结机1台车上;换热器4在烧结机大烟道3内;循环烟气管道L的前端通过无级调节阀6V6与主抽风机6出口连接,末端连接到2#风机入口前端的管道24;2#风机21出口与烟气分配器22连接;The flue gas distributor 22 is located on the sintering machine 1 trolley; the heat exchanger 4 is in the large flue 3 of the sintering machine; the front end of the circulating flue gas pipe L is connected to the outlet of the main exhaust fan 6 through a stepless regulating valve 6V6, and the end is connected to The pipe 24 at the front end of the 2# fan inlet; the outlet of the 2# fan 21 is connected to the flue gas distributor 22;
再生塔13包括上部的再生塔加热段1301、中间再生塔抽气段1302的和下部的再生塔冷却段1303,再生塔加热段1301和再生塔冷却段1303均为管壳换热形式,再生塔13上部设有进料口,下部设有出料口;The regeneration tower 13 includes an upper regeneration tower heating section 1301, an intermediate regeneration tower air extraction section 1302 and a lower regeneration tower cooling section 1303. Both the regeneration tower heating section 1301 and the regeneration tower cooling section 1303 are in the form of shell and tube heat exchange, and the regeneration tower 13 The upper part is provided with a material inlet, and the lower part is provided with a material outlet;
再生塔加热段1301设有高温热风进口和出口,高温热风进口通过管道与煤气燃烧器18出口相连,高温热风出口通过管道连接至3#风机17入口,3#风机17出口与煤气燃烧器18进口通过管道相连,同时3#风机17通过管道经无级调节阀4V4和节流阀1M1与循环烟气管道L相连;The heating section 1301 of the regeneration tower is equipped with a high-temperature hot air inlet and outlet. The high-temperature hot air inlet is connected to the outlet of the gas burner 18 through a pipeline, and the high-temperature hot air outlet is connected to the inlet of the 3# fan 17 through a pipeline, and the outlet of the 3# fan 17 is connected to the inlet of the gas burner 18. It is connected through pipelines, while 3# fan 17 is connected with circulating flue gas pipeline L through pipelines through stepless regulating valve 4V4 and throttle valve 1M1;
再生塔抽气段1302设有出气口,出气口通过管道与接触法制酸系统19进气口相连,制酸系统19的出气口通过管道经无级调节阀7V7连接至1#风机7前部管道;The air extraction section 1302 of the regeneration tower is provided with an air outlet, which is connected to the air inlet of the contact acid system 19 through a pipeline, and the air outlet of the acid system 19 is connected to the front pipe of the 1# fan 7 through a pipeline through a stepless regulating valve 7V7 ;
再生塔冷却段1303设有冷却空气进口和出口,4#风机20出口通过管道与冷却空气进口连接,冷却空气出口通过管道经无级调节阀5V5和节流阀2M2与循环烟气管道L相连;The cooling section 1303 of the regeneration tower is provided with a cooling air inlet and outlet. The outlet of the 4# fan 20 is connected to the cooling air inlet through a pipeline, and the cooling air outlet is connected to the circulating flue gas pipeline L through a pipeline through a stepless regulating valve 5V5 and a throttle valve 2M2;
振动筛14设有进料口、大颗粒物料出口和小颗粒物料出口;The vibrating screen 14 is provided with a feed inlet, a large particle material outlet and a small particle material outlet;
吸附塔8设有进、出气口和进、出料口;The adsorption tower 8 is provided with inlet and outlet ports and inlet and outlet ports;
1#带式输送机10、2#带式输送机16、1#斗提机11、2#斗提机12组成了物料输送设备;1# belt conveyor 10, 2# belt conveyor 16, 1# bucket elevator 11, 2# bucket elevator 12 constitute the material conveying equipment;
再生塔13底部出料口连接至振动筛14的进料口;振动筛14底部大颗粒物料出口通过2#斗提机12、2#带式输送机16连接至吸附塔8顶部进料口;振动筛14底部小颗粒物料出口连接至系统外的烧结机配料系统15;吸附塔8底部出料口通过1#带式输送机10、1#斗提机11连接至再生塔13顶部进料口;The discharge port at the bottom of the regeneration tower 13 is connected to the feed port of the vibrating screen 14; the large particle material outlet at the bottom of the vibrating screen 14 is connected to the feed port at the top of the adsorption tower 8 through 2# bucket elevator 12 and 2# belt conveyor 16; The small particle material outlet at the bottom of the vibrating screen 14 is connected to the sintering machine batching system 15 outside the system; the bottom outlet of the adsorption tower 8 is connected to the top feed inlet of the regeneration tower 13 through 1# belt conveyor 10 and 1# bucket elevator 11 ;
吸附塔8进气口端管道设置无级调节阀2V2,吸附塔8出气口端管道设置无级调节阀3V3;The pipeline at the inlet end of the adsorption tower 8 is equipped with a stepless regulating valve 2V2, and the pipeline at the gas outlet end of the adsorption tower 8 is equipped with a stepless regulating valve 3V3;
在循环烟气管道L引出点与制酸系统19出气口和1#风机入口管道连接点之间的管道上设置无级调节阀1V1;Set a stepless regulating valve 1V1 on the pipeline between the outlet point of the circulating flue gas pipeline L and the connection point between the gas outlet of the acid system 19 and the inlet pipeline of the 1# fan;
在循环烟气管道L末端处设置空气支路管道与空气联通,空气支路管道上设置无级调节阀8V8和节流阀3M3。An air branch pipe is set at the end of the circulating flue gas pipe L to communicate with the air, and a stepless regulating valve 8V8 and a throttle valve 3M3 are set on the air branch pipe.
实施例2Example 2
一种节能减排的烧结烟气净化系统,如图3所示,包括烧结机1、烧结机底部风箱2、烧结机大烟道3、电除尘器5、烧结主抽风机6、1#风机7、吸附塔8、烟囱9、1#带式输送机10、1#斗提机11、2#斗提机12、再生塔13、振动筛14、烧结机配料系统15、2#带式输送机16、3#风机17、煤气燃烧器18、接触法制酸系统19、4#风机20、2#风机21、烟气分配器22、除尘器23;A sintering flue gas purification system for energy saving and emission reduction, as shown in Figure 3, including sintering machine 1, sintering machine bottom bellows 2, sintering machine large flue 3, electric dust collector 5, sintering main exhaust fan 6, and #1 fan 7. Adsorption tower 8, chimney 9, 1# belt conveyor 10, 1# bucket elevator 11, 2# bucket elevator 12, regeneration tower 13, vibrating screen 14, sintering machine batching system 15, 2# belt conveyor Machine 16, 3# fan 17, gas burner 18, contact acid system 19, 4# fan 20, 2# fan 21, flue gas distributor 22, dust collector 23;
其中,烧结机1与烧结机底部风箱2连接,烧结机底部风箱2的头部数个风箱和尾部数个风箱与除尘器23连接,其余的风箱与烧结机大烟道3连接,烧结机大烟道3与电除尘器5连接,电除尘器5与烧结主抽风机6连接,烧结主抽风机6与1#风机7连接,1#风机7与吸附塔8连接,吸附塔8与烟囱9连接,上述连接均由管道连接;除尘器23通过管道与2#风机入口前端的管道24连接;2#风机21出口与烟气分配器22连接;Among them, the sintering machine 1 is connected to the bellows 2 at the bottom of the sintering machine, several bellows at the head and several bellows at the tail of the bellows 2 at the bottom of the sintering machine are connected to the dust collector 23, and the remaining bellows are connected to the large flue 3 of the sintering machine, and the large bellows of the sintering machine The flue 3 is connected to the electrostatic precipitator 5, the electrostatic precipitator 5 is connected to the sintering main exhaust fan 6, the sintering main exhaust fan 6 is connected to the 1# fan 7, the 1# fan 7 is connected to the adsorption tower 8, the adsorption tower 8 is connected to the chimney 9 Connection, the above connections are all connected by pipelines; the dust collector 23 is connected to the pipeline 24 at the front end of the inlet of the 2# fan through the pipeline; the outlet of the 2# fan 21 is connected to the flue gas distributor 22;
再生塔13包括上部的再生塔加热段1301、中间的再生塔抽气段1302和下部的再生塔冷却段1303,再生塔加热段1301和再生塔冷却段1303均为管壳换热形式,再生塔13上部设有进料口,下部设有出料口;The regeneration tower 13 includes an upper regeneration tower heating section 1301, a middle regeneration tower air extraction section 1302 and a lower regeneration tower cooling section 1303. Both the regeneration tower heating section 1301 and the regeneration tower cooling section 1303 are in the form of shell and tube heat exchange, and the regeneration tower 13 The upper part is provided with a material inlet, and the lower part is provided with a material outlet;
再生塔加热段1301设有高温热风进口和出口,高温热风进口通过管道与煤气燃烧器18出口相连,高温热风出口通过管道连接至3#风机17入口,3#风机17出口与煤气燃烧器18进口通过管道相连,同时3#风机通过管道经无级调节阀4V4和节流阀1M1与2#风机入口前端的管道24连接;The heating section 1301 of the regeneration tower is equipped with a high-temperature hot air inlet and outlet. The high-temperature hot air inlet is connected to the outlet of the gas burner 18 through a pipeline, and the high-temperature hot air outlet is connected to the inlet of the 3# fan 17 through a pipeline, and the outlet of the 3# fan 17 is connected to the inlet of the gas burner 18. It is connected through the pipeline, and the 3# fan is connected to the pipeline 24 at the front end of the inlet of the 2# fan through the pipeline through the stepless regulating valve 4V4 and the throttle valve 1M1;
再生塔抽气段1302设有出气口,出气口通过管道与接触法制酸系统19进气口相连,制酸系统19的出气口通过管道经无级调节阀7V7连接至1#风机7前端管道;The air extraction section 1302 of the regeneration tower is provided with an air outlet, which is connected to the air inlet of the contact acid system 19 through a pipeline, and the air outlet of the acid system 19 is connected to the front-end pipeline of the 1# fan 7 through a pipeline through a stepless regulating valve 7V7;
再生塔冷却段1303设有冷却空气进口和出口,4#风机20出口通过管道与冷却空气进口连接,冷却空气出口通过管道经无级调节阀5V5和节流阀2M2与2#风机入口前端的管道24连接;The cooling section 1303 of the regeneration tower is equipped with a cooling air inlet and outlet, the outlet of the 4# fan 20 is connected to the cooling air inlet through a pipeline, and the cooling air outlet passes through the pipeline through the stepless regulating valve 5V5 and the throttle valve 2M2 and the pipeline at the front end of the 2# fan inlet 24 connections;
振动筛14设有进料口、大颗粒物料出口和小颗粒物料出口;The vibrating screen 14 is provided with a feed inlet, a large particle material outlet and a small particle material outlet;
吸附塔8设有进、出气口和进、出料口;The adsorption tower 8 is provided with inlet and outlet ports and inlet and outlet ports;
1#带式输送机10、2#带式输送机16、1#斗提机11、2#斗提机12组成了物料输送设备;1# belt conveyor 10, 2# belt conveyor 16, 1# bucket elevator 11, 2# bucket elevator 12 constitute the material conveying equipment;
再生塔13底部出料口连接至振动筛14的进料口;振动筛14底部大颗粒物料出口通过2#斗提机12、2#带式输送机16连接至吸附塔8顶部进料口;振动筛14底部小颗粒物料出口连接至系统外的烧结机配料系统15;吸附塔8底部出料口通过1#带式输送机10、1#斗提机11连接至再生塔13顶部进料口;The discharge port at the bottom of the regeneration tower 13 is connected to the feed port of the vibrating screen 14; the large particle material outlet at the bottom of the vibrating screen 14 is connected to the feed port at the top of the adsorption tower 8 through 2# bucket elevator 12 and 2# belt conveyor 16; The small particle material outlet at the bottom of the vibrating screen 14 is connected to the sintering machine batching system 15 outside the system; the bottom outlet of the adsorption tower 8 is connected to the top feed inlet of the regeneration tower 13 through 1# belt conveyor 10 and 1# bucket elevator 11 ;
吸附塔8进气口端管道设置无级调节阀2V2,吸附塔8出气口端管道设置无级调节阀3V3;The pipeline at the inlet end of the adsorption tower 8 is equipped with a stepless regulating valve 2V2, and the pipeline at the gas outlet end of the adsorption tower 8 is equipped with a stepless regulating valve 3V3;
2#风机入口前端的管道24设置空气支路管道与空气联通,空气支路管道上设置无级调节阀8V8和节流阀3M3。The pipe 24 at the front end of the 2# fan inlet is provided with an air branch pipe to communicate with the air, and a stepless regulating valve 8V8 and a throttle valve 3M3 are arranged on the air branch pipe.
实施例3Example 3
利用实施例1的节能减排的烧结烟气净化系统进行烧结烟气净化的方法,包括如下步骤:The method for purifying sintering flue gas using the energy-saving and emission-reducing sintering flue gas purification system of Embodiment 1 comprises the following steps:
1)烧结机烟气热利用1) Heat utilization of sintering machine flue gas
烧结机烧结产生的高温烟气经烧结机底部风箱进入烧结大烟道,烟气经换热器换热,通过电除尘器、烧结主抽风机,一部分烟气由1#风机加压后进入吸附塔,另一部分烟气作为循环烟气由循环烟气管道进入2#风机前端的管道内;通过调整换热器内水的流量,来调整换热量,保证烟气入塔温度控制在120~140℃;换热器换热后产生蒸汽或热水作为热源,蒸汽可并入厂区蒸汽管网或进入汽轮机组发电;同时控制返回烧结机料面的烟气占总烧结烟气的20%~50%,进入吸附塔的烟气量为总烟气量的50%~80%,从而有效降低吸附塔规模,减少投资和运行费用;The high-temperature flue gas generated by the sintering of the sintering machine enters the large sintering flue through the bellows at the bottom of the sintering machine. The flue gas passes through the heat exchanger for heat exchange, and passes through the electric dust collector and the sintering main exhaust fan. Part of the flue gas is pressurized by the 1# fan and enters the adsorption The other part of the flue gas enters the pipe at the front end of the 2# fan from the circulating flue gas pipe as the circulating flue gas; by adjusting the flow of water in the heat exchanger, the heat exchange is adjusted to ensure that the temperature of the flue gas entering the tower is controlled at 120~ 140°C; after heat exchange by the heat exchanger, steam or hot water is generated as a heat source, and the steam can be incorporated into the steam pipe network of the plant or enter the steam turbine unit for power generation; at the same time, the flue gas returning to the material surface of the sintering machine is controlled to account for 20% of the total sintering flue gas 50%, the flue gas volume entering the adsorption tower is 50% to 80% of the total flue gas volume, thereby effectively reducing the scale of the adsorption tower, reducing investment and operating costs;
2)吸附塔吸附2) adsorption tower adsorption
输送到吸附塔中的烧结烟气,与吸附塔内部的活性焦进行接触,使得烟气内的SO2、NOx、颗粒物、二噁英等污染物被活性焦吸附,净化后的烟气经烟囱排放;The sintering flue gas transported to the adsorption tower is in contact with the active coke inside the adsorption tower, so that SO 2 , NOx, particulate matter, dioxins and other pollutants in the flue gas are adsorbed by the active coke, and the purified flue gas passes through the chimney emission;
3)活性焦再生3) Active coke regeneration
吸附了污染物的活性焦从吸附塔底部转移到再生塔中,活性焦从再生塔的顶部进入,经加热段、抽气段和冷却段再生后,最后到达再生塔底部;The activated coke that has adsorbed pollutants is transferred from the bottom of the adsorption tower to the regeneration tower, and the activated coke enters from the top of the regeneration tower, and after being regenerated in the heating section, pumping section and cooling section, it finally reaches the bottom of the regeneration tower;
在加热段:经煤气燃烧器加热至400~470℃的高温热风从再生塔加热段一侧进入,与流经加热段的活性焦进行不接触换热将活性焦加热,然后从加热段的另一侧输出,换热后的高温热风温度变为300~350℃;换热后的高温热风一部分进入2#风机前端的管道内,另一部分返回煤气燃烧器经加热作为高温热风使用;In the heating section: the high-temperature hot air heated to 400-470°C by the gas burner enters from one side of the heating section of the regeneration tower, conducts non-contact heat exchange with the active coke flowing through the heating section to heat the active coke, and then flows from the other side of the heating section Output from one side, the temperature of the high-temperature hot air after heat exchange becomes 300-350°C; part of the high-temperature hot air after heat exchange enters the pipe at the front end of the 2# fan, and the other part returns to the gas burner to be heated and used as high-temperature hot air;
使用煤气燃烧器作为热风炉,可利用钢厂富余的煤气作为燃料来源,整体上节约了燃料成本;Using a gas burner as a hot blast stove can use the surplus gas in the steel plant as a fuel source, saving fuel costs as a whole;
在抽气段:活性焦再生过程中产生的高SO2浓度气体由抽气段排出进入接触法制酸系统,制取98%硫酸,制酸系统产生的尾气经过1#风机进入吸附塔,尾气中含有的SOx、硫酸酸雾等污染物被吸附塔中的活性焦吸附去除; In the gas extraction section: the high SO2 concentration gas produced during the regeneration of active coke is discharged from the exhaust section into the contact acid system to produce 98% sulfuric acid. The tail gas generated by the acid system enters the adsorption tower through the 1# fan, and Pollutants such as SOx and sulfuric acid mist are adsorbed and removed by the active coke in the adsorption tower;
在冷却段:作为冷却空气的常温空气从再生塔冷却段的一侧进入,与流经冷却段的活性焦进行不接触换热,将活性焦冷却后常温空气升温至80~120℃外排,外排的冷却空气进入2#风机前端的管道内;In the cooling section: normal-temperature air as cooling air enters from one side of the cooling section of the regeneration tower, and conducts non-contact heat exchange with the active coke flowing through the cooling section. The cooling air discharged outside enters the pipe at the front end of the 2# fan;
混合烟气进入烟气分配器时氧气的体积比应在15%以上,若烟气中氧气浓度不足,应打开空气支路管道上的节流阀和无级调节阀,通过吸入空气调整氧浓度;When the mixed flue gas enters the flue gas distributor, the volume ratio of oxygen should be above 15%. If the oxygen concentration in the flue gas is insufficient, the throttle valve and stepless regulating valve on the air branch pipe should be opened to adjust the oxygen concentration by inhaling air. ;
高温热风进入再生塔温度为400~470℃,换热后温度降为300~350℃;外排冷却空气温度为80~120℃;换热后的部分高温热风和外排冷却空气返回烧结机料面,避免了含热废气外排,能源完全回收利用;同时制酸系统尾气经吸附塔处理后排放,避免污染环境;The temperature of the high-temperature hot air entering the regeneration tower is 400-470°C, and the temperature drops to 300-350°C after heat exchange; the temperature of the external cooling air is 80-120°C; part of the high-temperature hot air and external cooling air after heat exchange are returned to the sintering machine material On the one hand, the exhaust of hot exhaust gas is avoided, and the energy is completely recycled; at the same time, the tail gas of the acid production system is discharged after being treated by the adsorption tower, so as to avoid polluting the environment;
再生后的活性焦由再生塔底部排出进入振动筛,筛分后粒径≥1.5mm的活性焦颗粒返回吸附塔继续工作,粒径<1.5mm的活性焦颗粒收集后进入烧结机配料系统,作为烧结原料循环利用;The regenerated active coke is discharged from the bottom of the regeneration tower into the vibrating screen, and the activated coke particles with a particle size ≥ 1.5mm after sieving are returned to the adsorption tower to continue working. Sintering raw material recycling;
由于各管道内气体来源和气体量不同,可通过设置在管道上的无级调节阀和节流阀来调节不同管道内气体的流量,以保证不同管道内的压力平衡;例如设置在循环烟气管道上的无级调节阀,在循环烟气管道引出点与制酸系统出气口和1#风机入口管道连接点之间的管道上的无级调节阀,在与吸附塔进气口和出气口连接的管道上的无级调节阀,在3#风机出口与2#风机入口连接的管道上的无级调节阀和节流阀,在再生塔冷却段的冷却空气出口与2#风机入口连接的管道上的无级调节阀和节流阀,在制酸系统出气口与1#风机入口连接的管道上的无级调节阀,以及在空气支路管道上的无级调节阀和节流阀。Due to the different gas sources and gas volumes in each pipeline, the flow of gas in different pipelines can be adjusted through stepless regulating valves and throttle valves installed on the pipelines to ensure the pressure balance in different pipelines; The stepless regulating valve on the pipeline, the stepless regulating valve on the pipeline between the lead-out point of the circulating flue gas pipeline and the gas outlet of the acid making system and the connection point of the 1# fan inlet pipeline, is connected with the inlet and outlet of the adsorption tower The stepless regulating valve on the connected pipeline, the stepless regulating valve and throttling valve on the pipeline connecting the outlet of the 3# fan with the inlet of the 2# fan, the outlet of the cooling air in the cooling section of the regeneration tower connected with the inlet of the 2# fan The stepless regulating valve and throttle valve on the pipeline, the stepless regulating valve on the pipeline connecting the outlet of the acid making system with the inlet of the 1# fan, and the stepless regulating valve and throttle valve on the air branch pipeline.
实施例4Example 4
利用实施例2的节能减排的烧结烟气净化系统进行烧结烟气净化的方法,包括如下步骤:The method for purifying sintering flue gas by utilizing the energy-saving and emission-reducing sintering flue gas purification system of Embodiment 2 comprises the following steps:
1)烧结机烟气热利用1) Heat utilization of sintering machine flue gas
将烧结机头部部分风箱的低温烟气和烧结机尾部部分风箱的高温烟气通入管道中混合作为循环烟气,经过除尘器除尘进入2#风机前端的管道内,其余风箱的烟气进入烧结大烟道,经电除尘器、烧结主抽风机和1#风机后进入吸附塔;通过调整头部低温风箱和尾部高温风箱的数目保证进入吸附塔的烟气温度为120~140℃;混合后的循环烟气占总烧结烟气的20%~50%,进入吸附塔的烟气量为总烟气量的50%~80%,从而有效降低电除尘器、烧结主抽风机和吸附塔规模,从而减少投资和运行费用;The low-temperature flue gas from the bellows at the head part of the sintering machine and the high-temperature flue gas from the bellows at the tail of the sintering machine are passed into the pipeline and mixed as circulating flue gas. After dust removal by the dust collector, it enters the pipeline at the front end of the 2# fan, and the flue gas from the rest of the bellows enters the pipeline. The large sintering flue enters the adsorption tower after passing through the electrostatic precipitator, sintering main exhaust fan and 1# fan; by adjusting the number of low-temperature wind boxes at the head and high-temperature wind boxes at the tail, the temperature of the flue gas entering the adsorption tower is guaranteed to be 120-140°C; The final circulating flue gas accounts for 20% to 50% of the total sintering flue gas, and the flue gas volume entering the adsorption tower is 50% to 80% of the total flue gas volume, thereby effectively reducing the dust consumption of the electrostatic precipitator, sintering main exhaust fan and adsorption tower. scale, thereby reducing investment and operating costs;
2)吸附塔吸附2) adsorption tower adsorption
输送到吸附塔中的烧结烟气,与吸附塔内部的活性焦进行接触,使得烟气内的SO2、NOx、颗粒物、二噁英等污染物被活性焦吸附,净化后的烟气经烟囱排放;The sintering flue gas transported to the adsorption tower is in contact with the active coke inside the adsorption tower, so that SO 2 , NOx, particulate matter, dioxins and other pollutants in the flue gas are adsorbed by the active coke, and the purified flue gas passes through the chimney emission;
3)活性焦再生3) Active coke regeneration
吸附了污染物的活性焦从吸附塔底部转移到再生塔中,活性焦从再生塔的顶部进入,经加热段、抽气段和冷却段再生后,最后到达再生塔底部;The activated coke that has adsorbed pollutants is transferred from the bottom of the adsorption tower to the regeneration tower, and the activated coke enters from the top of the regeneration tower, and after being regenerated in the heating section, pumping section and cooling section, it finally reaches the bottom of the regeneration tower;
在加热段:经煤气燃烧器加热至400~470℃的高温热风从再生塔加热段一侧进入,与流经加热段的活性焦进行不接触换热将活性焦加热,然后从加热段的另一侧输出,换热后的高温热风温度变为300~350℃;换热后的高温热风一部分进入2#风机前端的管道内,另一部分返回煤气燃烧器经加热作为高温热风使用;In the heating section: the high-temperature hot air heated to 400-470°C by the gas burner enters from one side of the heating section of the regeneration tower, conducts non-contact heat exchange with the active coke flowing through the heating section to heat the active coke, and then flows from the other side of the heating section Output from one side, the temperature of the high-temperature hot air after heat exchange becomes 300-350°C; part of the high-temperature hot air after heat exchange enters the pipe at the front end of the 2# fan, and the other part returns to the gas burner to be heated and used as high-temperature hot air;
使用煤气燃烧器作为热风炉,可利用钢厂富余的煤气作为燃料来源,整体上节约了燃料成本;Using a gas burner as a hot blast stove can use the surplus gas in the steel plant as a fuel source, saving fuel costs as a whole;
在抽气段:活性焦再生过程中产生的高SO2浓度气体由抽气段排出进入接触法制酸系统,制取98%硫酸,制酸系统产生的尾气经过1#风机进入吸附塔,尾气中含有的SOx、硫酸酸雾等污染物被吸附塔中的活性焦吸附去除; In the gas extraction section: the high SO2 concentration gas produced during the regeneration of active coke is discharged from the exhaust section into the contact acid system to produce 98% sulfuric acid. The tail gas generated by the acid system enters the adsorption tower through the 1# fan, and Pollutants such as SOx and sulfuric acid mist are adsorbed and removed by the active coke in the adsorption tower;
在冷却段:作为冷却空气的常温空气从再生塔冷却段的一侧进入,与流经冷却段的活性焦进行不接触换热,将活性焦冷却后常温空气升温至80~120℃外排,外排的冷却空气进入2#风机前端的管道内;In the cooling section: normal-temperature air as cooling air enters from one side of the cooling section of the regeneration tower, and conducts non-contact heat exchange with the active coke flowing through the cooling section. The cooling air discharged outside enters the pipe at the front end of the 2# fan;
混合烟气进入烟气分配器前氧气的体积比应在15%以上,若氧气浓度不足,应打开空气支路管道上的节流阀和无级调节阀,通过吸入空气调整氧浓度;高温热风进入再生塔温度为400~470℃,换热后温度降为300~350℃;外排冷却空气温度为80~120℃;换热后的部分高温热风和外排冷却空气返回烧结机料面,避免了含热废气外排,能源完全回收利用;同时制酸系统尾气经吸附塔处理后排放,避免污染环境;Before the mixed flue gas enters the flue gas distributor, the volume ratio of oxygen should be above 15%. If the oxygen concentration is insufficient, the throttle valve and stepless regulating valve on the air branch pipe should be opened to adjust the oxygen concentration by inhaling air; high temperature hot air The temperature entering the regeneration tower is 400-470°C, and the temperature drops to 300-350°C after heat exchange; the temperature of the cooling air outside is 80-120°C; part of the high-temperature hot air and cooling air after heat exchange return to the material surface of the sintering machine, It avoids the exhaust of hot waste gas, and the energy is completely recycled; at the same time, the tail gas of the acid production system is discharged after being treated by the adsorption tower, so as to avoid polluting the environment;
再生后的活性焦由再生塔底部排出进入振动筛,筛分后粒径≥1.5mm的活性焦颗粒返回吸附塔继续工作,粒径<1.5mm的活性焦颗粒收集后进入烧结机配料系统,作为烧结原料循环利用;The regenerated active coke is discharged from the bottom of the regeneration tower into the vibrating screen, and the activated coke particles with a particle size ≥ 1.5mm after sieving are returned to the adsorption tower to continue working. Sintering raw material recycling;
由于各管道内气体来源和气体量不同,可通过设置在管道上的无级调节阀和节流阀来调节不同管道内气体的流量,以保证不同管道内的压力平衡;例如设置在与吸附塔进气口和出气口连接的管道上的无级调节阀,在3#风机出口与2#风机入口连接的管道上的无级调节阀和节流阀,在再生塔冷却段的冷却空气出口与2#风机入口连接的管道上的无级调节阀和节流阀,在制酸系统出气口与1#风机入口连接的管道上的无级调节阀,以及在空气支路管道上的无级调节阀和节流阀。Due to the different gas sources and gas volumes in each pipeline, the flow of gas in different pipelines can be adjusted through stepless regulating valves and throttle valves installed on the pipelines to ensure the pressure balance in different pipelines; The stepless regulating valve on the pipe connecting the air inlet and the air outlet, the stepless regulating valve and throttle valve on the pipe connecting the 3# fan outlet and the 2# fan inlet, the cooling air outlet and the cooling section of the regeneration tower cooling section The stepless regulating valve and throttling valve on the pipeline connected to the inlet of the 2# fan, the stepless regulating valve on the pipe connecting the outlet of the acid system to the inlet of the 1# fan, and the stepless regulation on the air branch pipeline valves and throttle valves.
具体应用实例Specific application examples
以450m2烧结机为例,选取活性焦烟气净化技术进行烟气治理。应用例1:采用实施例1中的系统,烧结烟气先经过烧结大烟道内换热器,换热后的烟气温度为120~140℃;换热器产生的蒸汽用于发电;在烧结主抽风机后30%烟气返回烧结机料面,剩余的70%烟气进入活性焦吸附塔中;再生过程中产生的部分高温热风和外排冷却空气返回烧结机料面;接触法制酸系统产生的尾气返回吸附塔。Taking the 450m 2 sintering machine as an example, the activated coke flue gas purification technology is selected for flue gas treatment. Application example 1: Using the system in Example 1, the sintering flue gas first passes through the heat exchanger in the large sintering flue, and the temperature of the flue gas after heat exchange is 120-140°C; the steam generated by the heat exchanger is used for power generation; After the main exhaust fan, 30% of the flue gas returns to the material surface of the sintering machine, and the remaining 70% of the flue gas enters the activated coke adsorption tower; part of the high-temperature hot air and external cooling air generated during the regeneration process return to the material surface of the sintering machine; the contact method acid system The tail gas produced is returned to the adsorption tower.
应用例2:采用实施例2中的系统,将烧结机头部部分风箱的低温烟气和烧结机尾部部分风箱的高温烟气混合(混合后烟气体积占总烟气体积的30%),混合后的烟气返回烧结机料面,其余风箱的烟气(烟气体积占总烟气体积的70%)进入烧结大烟道,经电除尘器、烧结主抽风机和1#风机后进入吸附塔;再生过程中产生的部分高温热风和外排冷却空气返回烧结机料面;接触法制酸系统产生的尾气返回吸附塔。Application example 2: using the system in Example 2, mixing the low-temperature flue gas from the wind box at the head part of the sintering machine with the high-temperature flue gas from the wind box at the tail part of the sintering machine (the mixed flue gas volume accounts for 30% of the total flue gas volume), The mixed flue gas returns to the material surface of the sintering machine, and the flue gas from the remaining bellows (the flue gas volume accounts for 70% of the total flue gas volume) enters the sintering large flue, and enters after passing through the electric dust collector, the sintering main exhaust fan and the 1# fan Adsorption tower; part of the high-temperature hot air and exhausted cooling air generated during the regeneration process returns to the material surface of the sintering machine; the tail gas generated by the contact method acid system returns to the adsorption tower.
对比例1:烧结烟气全部进入活性焦吸附塔中,高温热风和外排冷却空气均直接排放;接触法制酸系统产生的尾气直接排放。Comparative Example 1: All the sintering flue gas enters the activated coke adsorption tower, and the high-temperature hot air and external cooling air are all discharged directly; the tail gas produced by the contact method acid production system is directly discharged.
表1、对比结果Table 1. Comparison results
从表1可以看出:It can be seen from Table 1:
1)应用例1和应用例2中,30%烧结烟气返回烧结机料面,70%烟气进入活性焦吸附塔中,可有效的降低活性焦净化装置的规模,从而减少投资约4000万元;应用例2中可同时降低电除尘器和烧结主抽风机规模,进一步降低投资;1) In application example 1 and application example 2, 30% of the sintering flue gas returns to the material surface of the sintering machine, and 70% of the flue gas enters the activated coke adsorption tower, which can effectively reduce the scale of the active coke purification device, thereby reducing investment by about 40 million Yuan; in application example 2, the scale of the electrostatic precipitator and the sintering main exhaust fan can be reduced at the same time, further reducing the investment;
2)应用例1和应用例2中,活性焦净化装置处理烟气量降低,可降低运行费用约1.5元/t烧结矿;2) In application example 1 and application example 2, the amount of flue gas treated by the activated coke purification device is reduced, which can reduce the operating cost by about 1.5 yuan/t of sinter;
3)应用例1和应用例2可有效降低污染物排放总量,如表1所示,排放浓度相同,烟气量降低30%,则污染物排放总量降低30%;3) Application example 1 and application example 2 can effectively reduce the total amount of pollutant discharge, as shown in Table 1, if the emission concentration is the same, the amount of flue gas is reduced by 30%, and the total amount of pollutant discharge is reduced by 30%;
4)应用例1中换热器产生的蒸汽用于发电,发电量为2~4kW·h/t烧结矿,可有效回收烧结烟气中的热量;实施例2中高温烧结烟气返回烧结料面,可降低烧结燃料消耗;4) The steam generated by the heat exchanger in application example 1 is used for power generation, and the power generation capacity is 2-4kW·h/t sinter, which can effectively recover the heat in the sintering flue gas; the high-temperature sintering flue gas in embodiment 2 is returned to the sintering material Surface, can reduce sintering fuel consumption;
5)应用例1和应用例2有效控制烟气温度为120~140℃;有利于活性焦烟气净化装置平稳运行;5) Application example 1 and application example 2 effectively control the temperature of the flue gas at 120-140°C; it is conducive to the smooth operation of the activated coke flue gas purification device;
6)对比例1中,高温热风和冷却空气直接外排,造成能源浪费;实施例1和实施例2中,将高温热风和冷却空气返回烧结机料面,可降低烧结燃料消耗。6) In Comparative Example 1, the high-temperature hot air and cooling air are directly discharged outside, resulting in energy waste; in Examples 1 and 2, the high-temperature hot air and cooling air are returned to the material surface of the sintering machine, which can reduce the consumption of sintering fuel.
7)对比例1中,接触法制酸系统尾气直接排放,造成二次污染;应用例1和应用例2中,将接触法制酸系统尾气经吸附塔净化后排放,能避免二次污染。7) In comparative example 1, the tail gas of the contact method acid production system is directly discharged, causing secondary pollution; in application example 1 and application example 2, the tail gas of the contact method acid production system is discharged after being purified by the adsorption tower, which can avoid secondary pollution.
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