CN105694538A - Preparation method of low-oil-absorption-amount anticorrosion iron oxide red pigment - Google Patents
Preparation method of low-oil-absorption-amount anticorrosion iron oxide red pigment Download PDFInfo
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- CN105694538A CN105694538A CN201610014109.XA CN201610014109A CN105694538A CN 105694538 A CN105694538 A CN 105694538A CN 201610014109 A CN201610014109 A CN 201610014109A CN 105694538 A CN105694538 A CN 105694538A
- Authority
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- Prior art keywords
- ferric
- oxide red
- anticorrosion
- preparation
- oil absorption
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- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 239000001054 red pigment Substances 0.000 title abstract 4
- 239000003755 preservative agent Substances 0.000 claims abstract description 19
- 230000002335 preservative effect Effects 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims abstract description 7
- 230000000694 effects Effects 0.000 claims abstract description 7
- 239000006185 dispersion Substances 0.000 claims abstract description 6
- 238000001035 drying Methods 0.000 claims abstract description 6
- 239000012065 filter cake Substances 0.000 claims abstract description 6
- 238000000227 grinding Methods 0.000 claims abstract description 6
- 238000010438 heat treatment Methods 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims abstract description 6
- 239000002270 dispersing agent Substances 0.000 claims abstract description 5
- 239000004094 surface-active agent Substances 0.000 claims abstract description 5
- 239000003513 alkali Substances 0.000 claims abstract description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 27
- 229960005191 ferric oxide Drugs 0.000 claims description 26
- 238000010521 absorption reaction Methods 0.000 claims description 23
- 239000001062 red colorant Substances 0.000 claims description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 16
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 10
- HYYHQASRTSDPOD-UHFFFAOYSA-N hydroxylamine;phosphoric acid Chemical group ON.OP(O)(O)=O HYYHQASRTSDPOD-UHFFFAOYSA-N 0.000 claims description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 239000007795 chemical reaction product Substances 0.000 claims description 5
- 229940051164 ferric oxide yellow Drugs 0.000 claims description 5
- 239000001052 yellow pigment Substances 0.000 claims description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- 229920005610 lignin Polymers 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229920001732 Lignosulfonate Polymers 0.000 claims description 3
- 239000004117 Lignosulphonate Substances 0.000 claims description 3
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- 239000003945 anionic surfactant Substances 0.000 claims description 3
- 238000009833 condensation Methods 0.000 claims description 3
- 230000005494 condensation Effects 0.000 claims description 3
- 235000019357 lignosulphonate Nutrition 0.000 claims description 3
- 239000002736 nonionic surfactant Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- 238000010979 pH adjustment Methods 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 8
- 238000000576 coating method Methods 0.000 abstract description 6
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 239000002002 slurry Substances 0.000 abstract 2
- 238000004537 pulping Methods 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 5
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000002411 adverse Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/22—Compounds of iron
- C09C1/24—Oxides of iron
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/10—Treatment with macromolecular organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Paints Or Removers (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
The invention discloses a preparation method of low-oil-absorption-amount anticorrosion iron oxide red pigment.The method includes the following steps of firstly, preparing a preservative into a preservative water solution with concentration of 0.5-1.6%, and heating the preservative water solution for standby application till the temperature is 50-100 DEG C; secondly, putting an ordinary iron oxide red filter cake into a reaction barrel, and adding water into the reaction barrel for pulping to prepare slurry with concentration of 15-28%; thirdly, adding alkali liquor with concentration of 20-35% to the slurry under the effect of a high-speed dispersion plate to adjust the pH value to be 7.5-8.8, then sequentially adding a dispersing agent, a surface active agent and the preservative processed in the first step, dispersing the agents through paddles, drying the agents through the plate, and conducting vertical smashing and superfine powder grinding to prepare the fine low-oil-absorption-amount anticorrosion iron oxide red pigment easy to disperse.The prepared iron oxide red pigment is small in fineness and easy to disperse, well solves the problem of high viscosity in coatings and has quite good anticorrosion performance.
Description
Technical field
The present invention relates to technical field of pigment preparation, the preparation method being specifically related to a kind of low oil absorption ferric anticorrosion ferric oxide red colorant。
Background technology
The basic chemical expression of ferrum oxide is Fe2O3, there is multiple different shape in it, and the ferrum oxide of different shape presents different colors。Ferrum oxide is nontoxic, cheap, is widely used in the various fields such as building materials, coating, rubber the important base material of function admirable。Present domestic coating industry to the demand of iron oxide red just in cumulative year after year, and the high oil absorption of iron oxide red is that its development is had adverse effect on, by the modifying surface set up the project to iron oxide red, thus reducing oil absorption, improve its dispersibility and wettability, coating industry is made certain facilitation。
Summary of the invention
(1) solve the technical problem that
For the deficiencies in the prior art, the preparation method that the invention provides a kind of low oil absorption ferric anticorrosion ferric oxide red colorant, made ferric oxide red colorant fineness is little, easily disperse, and well solves its high viscosity problem in coating, and has good Corrosion Protection。
(2) technical scheme
For realizing object above, the present invention is achieved by the following technical programs:
The preparation method of a kind of low oil absorption ferric anticorrosion ferric oxide red colorant, comprises the following steps:
(1) preservative is made into the aqueous solution of 0.5～1.6%, and heating is to 50～100 DEG C, standby；
(2) put into add water in reaction container by common iron oxide red filter cake and pull an oar, be made into the serosity of 15～28%；
(3) it be 20%～35% lye pH adjustment value is 7.5～8.8 that serosity adds concentration under high speed dispersion dish effect, it is sequentially added into the preservative that dispersant, surfactant and step (1) processed subsequently, disperse through blade, tray drying, Verticle grinding is ultra-fine beats powder, produces low oil absorption ferric anticorrosion ferric oxide yellow pigment trickle, that be easily dispersed。
Preferably, described preservative is hydroxylamine phosphate, its preparation process is: organic amine is hardened by adding alkaline earth oxide, ferrum oxide, zinc oxide, manganese oxide or its corresponding hydroxide with the solution of phosphoric acid reaction products, thus generating hydroxylamine phosphate。
Preferably, described dispersant is condensation sodium sulfonate or lignin。
Preferably, described surfactant is one or more in lignosulphonates, nonionic surfactant, anion surfactant。
Preferably, described alkali liquor is sodium hydroxide or ammonia。
Preferably, the particle diameter of described low oil absorption ferric anticorrosion ferric oxide red colorant is 10～40 orders。
(3) beneficial effect
The preparation method that the invention provides a kind of low oil absorption ferric anticorrosion ferric oxide red colorant, made ferric oxide red colorant fineness is little, easily disperse, and well solves its high viscosity problem in coating, and has good Corrosion Protection。
Detailed description of the invention
For making the purpose of the embodiment of the present invention, technical scheme and advantage clearly, below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that, described embodiment is a part of embodiment of the present invention, rather than whole embodiments。Based on the embodiment in the present invention, the every other embodiment that those of ordinary skill in the art obtain under not making creative work premise, broadly fall into the scope of protection of the invention。
Embodiment 1:
The preparation method of a kind of low oil absorption ferric anticorrosion ferric oxide red colorant of the present embodiment, comprises the following steps:
(1) preservative is made into the aqueous solution of 0.8%, and heating is to 60 DEG C, standby；
(2) put into add water in reaction container by common iron oxide red filter cake and pull an oar, be made into the serosity of 15%；
(3) it is that 20% sodium hydroxide adjusts pH value to be 7.5 that serosity adds concentration under high speed dispersion dish effect, it is sequentially added into the preservative that condensation sodium sulfonate, lignosulphonates and step (1) processed subsequently, disperse through blade, tray drying, Verticle grinding is ultra-fine beats powder, produces low oil absorption ferric anticorrosion ferric oxide yellow pigment trickle, that be easily dispersed。
The preservative of step (1) is hydroxylamine phosphate, and its preparation process is: the solution of organic amine and phosphoric acid reaction products is hardened by adding ferrum oxide, thus generating hydroxylamine phosphate。
Embodiment 2:
The preparation method of a kind of low oil absorption ferric anticorrosion ferric oxide red colorant of the present embodiment, comprises the following steps:
(1) preservative is made into the aqueous solution of 1.2%, and heating is to 80 DEG C, standby；
(2) put into add water in reaction container by common iron oxide red filter cake and pull an oar, be made into the serosity of 25%；
(3) it is that 25% sodium hydroxide adjusts pH value to be 8.2 that serosity adds concentration under high speed dispersion dish effect, it is sequentially added into the preservative that lignin, nonionic surfactant and step (1) processed subsequently, disperse through blade, tray drying, Verticle grinding is ultra-fine beats powder, produces low oil absorption ferric anticorrosion ferric oxide yellow pigment trickle, that be easily dispersed。
The preservative of step (1) is hydroxylamine phosphate, and its preparation process is: the solution of organic amine and phosphoric acid reaction products is hardened by adding alkaline earth oxide, thus generating hydroxylamine phosphate。
Embodiment 3:
The preparation method of a kind of low oil absorption ferric anticorrosion ferric oxide red colorant of the present embodiment, comprises the following steps:
(1) preservative is made into the aqueous solution of 1.6%, and heating is to 100 DEG C, standby；
(2) put into add water in reaction container by common iron oxide red filter cake and pull an oar, be made into the serosity of 28%；
(3) it is that 35% ammonia adjusts pH value to be 8.8 that serosity adds concentration under high speed dispersion dish effect, it is sequentially added into the preservative that lignin, anion surfactant and step (1) processed subsequently, disperse through blade, tray drying, Verticle grinding is ultra-fine beats powder, produces low oil absorption ferric anticorrosion ferric oxide yellow pigment trickle, that be easily dispersed。
The preservative of step (1) is hydroxylamine phosphate, and its preparation process is: the solution of organic amine and phosphoric acid reaction products is hardened by adding manganese oxide, thus generating hydroxylamine phosphate。
It should be noted that, in this article, the relational terms of such as first and second or the like is used merely to separate an entity or operation with another entity or operating space, and not necessarily requires or imply the relation that there is any this reality between these entities or operation or sequentially。And, term " includes ", " comprising " or its any other variant are intended to comprising of nonexcludability, so that include the process of a series of key element, method, article or equipment not only include those key elements, but also include other key elements being not expressly set out, or also include the key element intrinsic for this process, method, article or equipment。When there is no more restriction, statement " including ... " key element limited, it is not excluded that there is also other identical element in including the process of described key element, method, article or equipment。
Above example is only in order to illustrate technical scheme, it is not intended to limit, although the present invention being described in detail with reference to previous embodiment, it will be understood by those within the art that: the technical scheme described in foregoing embodiments still can be modified by it, or wherein portion of techniques feature is carried out equivalent replacement；And these amendments or replacement, do not make the essence of appropriate technical solution depart from the spirit and scope of various embodiments of the present invention technical scheme。
Claims (6)
1. the preparation method of a low oil absorption ferric anticorrosion ferric oxide red colorant, it is characterised in that comprise the following steps:
(1) preservative is made into the aqueous solution of 0.5～1.6%, and heating is to 50～100 DEG C, standby；
(2) put into add water in reaction container by common iron oxide red filter cake and pull an oar, be made into the serosity of 15～28%；
(3) it be 20%～35% lye pH adjustment value is 7.5～8.8 that serosity adds concentration under high speed dispersion dish effect, it is sequentially added into the preservative that dispersant, surfactant and step (1) processed subsequently, disperse through blade, tray drying, Verticle grinding is ultra-fine beats powder, produces low oil absorption ferric anticorrosion ferric oxide yellow pigment trickle, that be easily dispersed。
2. the preparation method of low oil absorption ferric anticorrosion ferric oxide red colorant according to claim 1, it is characterized in that, described preservative is hydroxylamine phosphate, its preparation process is: organic amine is hardened by adding alkaline earth oxide, ferrum oxide, zinc oxide, manganese oxide or its corresponding hydroxide with the solution of phosphoric acid reaction products, thus generating hydroxylamine phosphate。
3. the preparation method of low oil absorption ferric anticorrosion ferric oxide red colorant according to claim 1, it is characterised in that described dispersant is condensation sodium sulfonate or lignin。
4. the preparation method of low oil absorption ferric anticorrosion ferric oxide red colorant according to claim 1, it is characterised in that described surfactant is one or more in lignosulphonates, nonionic surfactant, anion surfactant。
5. the preparation method of low oil absorption ferric anticorrosion ferric oxide red colorant according to claim 1, it is characterised in that described alkali liquor is sodium hydroxide or ammonia。
6. the preparation method of low oil absorption ferric anticorrosion ferric oxide red colorant according to claim 1, it is characterised in that the particle diameter of described low oil absorption ferric anticorrosion ferric oxide red colorant is 10～40 orders。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610014109.XA CN105694538A (en) | 2016-01-05 | 2016-01-05 | Preparation method of low-oil-absorption-amount anticorrosion iron oxide red pigment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610014109.XA CN105694538A (en) | 2016-01-05 | 2016-01-05 | Preparation method of low-oil-absorption-amount anticorrosion iron oxide red pigment |
Publications (1)
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| CN105694538A true CN105694538A (en) | 2016-06-22 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201610014109.XA Pending CN105694538A (en) | 2016-01-05 | 2016-01-05 | Preparation method of low-oil-absorption-amount anticorrosion iron oxide red pigment |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113105757A (en) * | 2021-04-06 | 2021-07-13 | 湖州师范学院 | Narrow-particle-size-distribution low-oil-absorption iron oxide yellow pigment and preparation method thereof |
Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1269816A (en) * | 1997-03-09 | 2000-10-11 | 皮格门坦涂料用防腐蚀颜料有限公司 | Anti-corrosive pigments |
| JP2003105571A (en) * | 2001-09-25 | 2003-04-09 | Nisshin Kako Kk | Corrosion inhibition method for surface of stainless steel molding |
| JP2003105556A (en) * | 2001-09-25 | 2003-04-09 | Nisshin Kako Kk | Stainless steel molding having improved corrosion resistance |
| CN1429281A (en) * | 2000-03-24 | 2003-07-09 | 日进化工株式会社 | Anticorrosive agent for stainless steel and method of anticorrosive treatment of stainless steel |
| JP2006199548A (en) * | 2005-01-21 | 2006-08-03 | Showa Denko Kk | Method of manufacturing hydroxyl amine |
| CN101054349A (en) * | 2006-04-12 | 2007-10-17 | 中国石油化学工业开发股份有限公司 | Method for producing hydroxylamine |
| CN101191022A (en) * | 2006-12-01 | 2008-06-04 | 德清凯孚颜料有限公司 | Heavy iron oxide yellow and preparation method thereof |
| CN101418141A (en) * | 2008-12-05 | 2009-04-29 | 南通宝聚颜料有限公司 | Low oil absorption ferric oxide yellow pigment |
| CN100503742C (en) * | 2003-02-10 | 2009-06-24 | 杭州萧湘颜料化工有限公司 | Particulate ferric oxide red pigment and method for producing the same |
| CN102604438A (en) * | 2012-02-21 | 2012-07-25 | 升华集团德清华源颜料有限公司 | Iron oxide yellow pigment with low oil absorption |
| CN102604436A (en) * | 2012-02-21 | 2012-07-25 | 升华集团德清华源颜料有限公司 | Preparation method of low oil absorption iron oxide yellow |
| CN102732073A (en) * | 2012-06-13 | 2012-10-17 | 天长市银狐漆业有限公司 | Coating composition for protecting metal surface |
| CN104046056A (en) * | 2014-04-24 | 2014-09-17 | 铜陵市陵阳化工有限责任公司 | Preparation method of high-performance iron oxide black for automotive topcoat |
| CN104559341A (en) * | 2014-12-12 | 2015-04-29 | 浙江联合颜料有限公司 | Nano fine-grained iron oxide red |
-
2016
- 2016-01-05 CN CN201610014109.XA patent/CN105694538A/en active Pending
Patent Citations (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1269816A (en) * | 1997-03-09 | 2000-10-11 | 皮格门坦涂料用防腐蚀颜料有限公司 | Anti-corrosive pigments |
| CN1429281A (en) * | 2000-03-24 | 2003-07-09 | 日进化工株式会社 | Anticorrosive agent for stainless steel and method of anticorrosive treatment of stainless steel |
| JP2003105571A (en) * | 2001-09-25 | 2003-04-09 | Nisshin Kako Kk | Corrosion inhibition method for surface of stainless steel molding |
| JP2003105556A (en) * | 2001-09-25 | 2003-04-09 | Nisshin Kako Kk | Stainless steel molding having improved corrosion resistance |
| CN100503742C (en) * | 2003-02-10 | 2009-06-24 | 杭州萧湘颜料化工有限公司 | Particulate ferric oxide red pigment and method for producing the same |
| JP2006199548A (en) * | 2005-01-21 | 2006-08-03 | Showa Denko Kk | Method of manufacturing hydroxyl amine |
| CN101054349A (en) * | 2006-04-12 | 2007-10-17 | 中国石油化学工业开发股份有限公司 | Method for producing hydroxylamine |
| CN101191022A (en) * | 2006-12-01 | 2008-06-04 | 德清凯孚颜料有限公司 | Heavy iron oxide yellow and preparation method thereof |
| CN101418141A (en) * | 2008-12-05 | 2009-04-29 | 南通宝聚颜料有限公司 | Low oil absorption ferric oxide yellow pigment |
| CN102604438A (en) * | 2012-02-21 | 2012-07-25 | 升华集团德清华源颜料有限公司 | Iron oxide yellow pigment with low oil absorption |
| CN102604436A (en) * | 2012-02-21 | 2012-07-25 | 升华集团德清华源颜料有限公司 | Preparation method of low oil absorption iron oxide yellow |
| CN102732073A (en) * | 2012-06-13 | 2012-10-17 | 天长市银狐漆业有限公司 | Coating composition for protecting metal surface |
| CN104046056A (en) * | 2014-04-24 | 2014-09-17 | 铜陵市陵阳化工有限责任公司 | Preparation method of high-performance iron oxide black for automotive topcoat |
| CN104559341A (en) * | 2014-12-12 | 2015-04-29 | 浙江联合颜料有限公司 | Nano fine-grained iron oxide red |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113105757A (en) * | 2021-04-06 | 2021-07-13 | 湖州师范学院 | Narrow-particle-size-distribution low-oil-absorption iron oxide yellow pigment and preparation method thereof |
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Application publication date: 20160622 |