CN105689638B - A kind of water base aluminium alloy compression casting releasing agent and preparation method thereof - Google Patents
A kind of water base aluminium alloy compression casting releasing agent and preparation method thereof Download PDFInfo
- Publication number
- CN105689638B CN105689638B CN201610236773.9A CN201610236773A CN105689638B CN 105689638 B CN105689638 B CN 105689638B CN 201610236773 A CN201610236773 A CN 201610236773A CN 105689638 B CN105689638 B CN 105689638B
- Authority
- CN
- China
- Prior art keywords
- parts
- releasing agent
- aluminium alloy
- water base
- heterogeneous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 238000005266 casting Methods 0.000 title claims abstract description 18
- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 13
- 230000006835 compression Effects 0.000 title claims abstract description 10
- 238000007906 compression Methods 0.000 title claims abstract description 10
- 238000002360 preparation method Methods 0.000 title abstract description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 12
- 229920000136 polysorbate Polymers 0.000 claims abstract description 12
- 229920002545 silicone oil Polymers 0.000 claims abstract description 11
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 8
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 8
- 150000001335 aliphatic alkanes Chemical group 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims abstract description 7
- 239000008367 deionised water Substances 0.000 claims abstract description 6
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 6
- 239000003643 water by type Substances 0.000 claims abstract description 5
- 238000002844 melting Methods 0.000 claims abstract description 4
- 230000008018 melting Effects 0.000 claims abstract description 4
- -1 AEO9 Polymers 0.000 claims description 7
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 4
- 229920000053 polysorbate 80 Polymers 0.000 claims description 4
- 238000000034 method Methods 0.000 claims 1
- 150000002191 fatty alcohols Chemical class 0.000 abstract description 10
- 239000003921 oil Substances 0.000 abstract description 8
- 239000006082 mold release agent Substances 0.000 abstract description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 229910052751 metal Inorganic materials 0.000 abstract description 6
- 239000002184 metal Substances 0.000 abstract description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 5
- 230000004048 modification Effects 0.000 abstract description 5
- 238000012986 modification Methods 0.000 abstract description 5
- 229910052710 silicon Inorganic materials 0.000 abstract description 5
- 239000010703 silicon Substances 0.000 abstract description 5
- 238000010438 heat treatment Methods 0.000 abstract description 3
- 150000003014 phosphoric acid esters Chemical class 0.000 abstract description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 239000000203 mixture Substances 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 239000004411 aluminium Substances 0.000 description 5
- 239000003995 emulsifying agent Substances 0.000 description 5
- 239000001993 wax Substances 0.000 description 5
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 150000001336 alkenes Chemical class 0.000 description 3
- 230000001804 emulsifying effect Effects 0.000 description 3
- 230000008676 import Effects 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000004512 die casting Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- IEQAICDLOKRSRL-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-dodecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO IEQAICDLOKRSRL-UHFFFAOYSA-N 0.000 description 1
- 241001272567 Hominoidea Species 0.000 description 1
- MKYLOMHWHWEFCT-UHFFFAOYSA-N Manthidine Natural products C1C2=CC=3OCOC=3C=C2C2C3=CC(OC)C(O)CC3N1C2 MKYLOMHWHWEFCT-UHFFFAOYSA-N 0.000 description 1
- SNFRINMTRPQQLE-JQWAAABSSA-N Montanin Chemical group O[C@H]([C@@]1(CO)O[C@H]1[C@H]1[C@H]2O3)[C@]4(O)C(=O)C(C)=C[C@H]4[C@]11OC3(CCCCCCCCCCC)O[C@@]2(C(C)=C)C[C@H]1C SNFRINMTRPQQLE-JQWAAABSSA-N 0.000 description 1
- SNFRINMTRPQQLE-OFGNMXNXSA-N Montanin Natural products O=C1[C@@]2(O)[C@@H](O)[C@@]3(CO)O[C@H]3[C@@H]3[C@H]4[C@@]5(C(=C)C)O[C@](CCCCCCCCCCC)(O4)O[C@@]3([C@H](C)C5)[C@@H]2C=C1C SNFRINMTRPQQLE-OFGNMXNXSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 241000153282 Theope Species 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- QTZPBQMTXNEKRX-UHFFFAOYSA-N Voacristine pseudoindoxyl Natural products N1C2=CC=C(OC)C=C2C(=O)C21CCN(C1)C3C(C(C)O)CC1CC32C(=O)OC QTZPBQMTXNEKRX-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229950008882 polysorbate Drugs 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 210000000697 sensory organ Anatomy 0.000 description 1
- 150000003376 silicon Chemical class 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C3/00—Selection of compositions for coating the surfaces of moulds, cores, or patterns
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Mold Materials And Core Materials (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of water base aluminium alloy compression casting releasing agent, it is made up of the component of following mass ratio：100 150 parts of modification organic silicon oils, 10 20 parts of OPEs, 10 15 parts of heterogeneous ten alcohol polyoxyethylene ethers, 8 10 parts of long-chain fatty alcohol APEOs, 10 15 parts of tweens, 500 800 parts of deionized waters.The invention also discloses the preparation method containing the water base aluminium alloy compression casting releasing agent in addition, by the phenyl modified organic silicone oil of long alkane chain, OPE, heterogeneous ten alcohol polyoxyethylene ether, long-chain fatty alcohol APEO, tween heating melting, then) and then by said components stir, cool to 55 DEG C 75 DEG C, then deionized water is slowly dropped into batches, and being stirred for half an hour is prepared.Water based mold release agent prepared by the present invention can be used for the production of the die-cast metal product such as aluminium alloy, and demolding performace is good, can effectively improve cast product surface quality, improve casting finish and integrality.
Description
Technical field
The invention belongs to foundry facing and its synthesis technology field, and in particular to a kind of water base aluminium alloy compression casting takes off
Mould agent and preparation method thereof.
Background technology
Die casting is auto industry, the important support of electronic product industry.Releasing agent is that production die cast metal product must can not
Few auxiliary agent.Its main function, which is to aid in die cast metal product, to be removed from the molds, and has kept product
Whole property and aft-loaded airfoil.The wherein water based mold release agent of emulsion form is compared with traditional oil base releasing agent, with good cooling results, no
Produce accumulation, surface quality of continuous castings is good, contribute to reduce internal porosity and it is safe to use, cleaning, it is pollution-free the advantages that, be mesh
Preceding casting mold-releasing agent main product.
The die cast metal releasing agent of domestic market, it is broadly divided into two class：First, come as the U.S., Japan and other countries
Import releasing agent.The demolding performace of import releasing agent is good, casting of appearance of cast almost zero defect；Emulsifying effectiveness is good, when being diluted with water, nothing
Water-oil separating phenomenon；Sense organ is good, pollution-free to container.Because its price is high, mainly made by joint venture and some brand enterprises
With.Second, domestic releasing agent, demolding performace is preferable, but emulsifying effectiveness is undesirable.Domestic releasing agent generally existing film forming is bright and clean
Degree is poor, and emulsion is unstable and the problems such as unstable product quality so that some larger die casting producers of the country are so far still
Use import releasing agent product.In order to solve the above-mentioned technical problem, the present invention comes therefrom.
The content of the invention
Present invention aims at provide a kind of highly diluted better than, emulsifying effectiveness, stable performance, film-formation result good water-based aluminium
Alloy die cast releasing agent and preparation method thereof.The releasing agent can be stored and used for a long time, while the preparation method of the releasing agent
Step is simple, and raw material is easy to get.
Technical scheme is used by first aspect present invention solves technical problem：A kind of water base aluminium alloy compression casting demoulding
Agent, it is made up of the component of following mass ratio：100-150 parts modification organic silicon oil, 10-20 parts OPE, 10-15 parts
Heterogeneous ten alcohol polyoxyethylene ether, 8-10 part long-chain fatty alcohols APEO, 10-15 parts tween, 500-800 part deionized waters.
Preferably, the modification organic silicon oil is selected from the phenyl modified organic silicone oil of long alkane chain, polyether modified silicon oil, hydroxyl and changed
Property silicone oil one or two kinds of any of the above combination.
Preferably, the OPE is selected from any one poly- second of oxidation of 98-100 DEG C or 100-120 DEG C of fusing point
Alkene wax.
Preferably, the long-chain fatty alcohol APEO is selected from AEO7, AEO8 or AEO9.
Preferably, the tween is Tween 80.
The second aspect of the present invention provides a kind of preparation method of water base aluminium alloy compression casting releasing agent, and it includes following step
Suddenly：
(1) modification organic silicon oil, OPE, heterogeneous ten alcohol polyoxyethylene ether, long-chain fatty alcohol polyoxyethylene are taken
Ether, tween, melting is heated after said components are mixed；
(2) and then stir, cool to 55 DEG C -75 DEG C,
(3) deionized water is then slowly dropped into batches, is stirred for uniformly being prepared.
Preferably, the step (2) stirs 0.5-2 hours at 2000-3000 revs/min, cools to 60 DEG C.
Pass through above-mentioned technical proposal, the present invention is acted synergistically using composite emulsifier make it that the system of obtained releasing agent is equal
First, composition not free settling and good into fruit is imitated.
OPE, also known as OPE waxes, OPE waxes have the properties such as viscosity is low, softening point is high, hardness is good, nontoxic
Property, heat endurance is good, and high-temperature volatile is low, to filler, dispersed splendid, the existing extremely excellent external lubricity of pigment, has again
Stronger internal lubrication effect, also with coupled action, the production efficiency of plastic processing can be improved, reduces production cost, with gathering
Olefin resin etc. has good compatibility, and anti humility performance at normal temperatures is good, and chemical-resistant resistance ability is strong, and excellent electrical properties can
Improve finished appearance, be the preferable production for substituting montanin wax, river wax, atoleine, microcrystalline wax, natural paraffin wax, Tissuemat E etc.
Product.
Heterogeneous ten alcohol polyoxyethylene ether belongs to isomery alcohol ether, is efficient dispersant, wetting agent and emulsifying agent, without phenyl ring
Structure, it is the substitute that APES is excellent in textile auxiliary and detergent.
AEO (AEO), also known as polyoxyethylene aliphatic alcohol ether.It is to develop in nonionic surfactant
Kind most fast, dosage is maximum.Such surfactant is formed by polyethylene glycol (PEG) and fatty alcohol condensation
Ether, represented with below general formula：RO (CH2CH2O) nH, wherein n is the degree of polymerization, because of the degree of polymerization of polyethylene glycol and the kind of fatty alcohol
Class is different and has different kinds.Trade name Brij (Brij), if Brij30 and Brij is by different number of polyethylene glycol
Formed with laurate polycondensation, can all be used as O/W type emulsifying agents.When carbochain R is C7~9, during n=5, the fatty alcohol polyoxy second of generation
Alkene ether is industrially referred to as penetrating agent JFC (Penetrating agent JFC).
Tween (or polysorbate) is nonionic surface active agent, has foreign odor, warm and slight bitter, is a series of polyoxy second
Alkene removes the partial fatty acid ester of water sorbierite.It is widely used as the solubilizer of emulsifying agent and oily substance.Tween-80 is oleate.
Preferably, a kind of preparation method of water base aluminium alloy compression casting releasing agent, it comprises the following steps：By modified organic silicon
Oil, OPE, heterogeneous ten alcohol polyoxyethylene ether, long-chain fatty alcohol APEO, Tween 80 heating melting, Ran Hou
2000-3000 revs/min of stirring half an hour, 60 DEG C or so are cooled to, is then slowly dropped into deionized water in batches, is stirred for half an hour
It is prepared.
The advantages of the present invention are：
(1) present invention is used as high efficiency composition emulsifying agent by carrying out rational allocation, by reasonable group that studies various components
Close and match, mix the metal mold release agent with excellent demolding performace, water base casting mold-releasing agent produced by the invention has
Highly diluted than, it is easy emulsification, stripping result is excellent the characteristics of.
(2) water based mold release agent prepared by the present invention can be used for the production of the die-cast metal product such as aluminium alloy, demolding performace
Well, it can effectively improve cast product surface quality, improve casting finish and integrality.
Embodiment
Such scheme is described further below in conjunction with specific embodiment.It should be understood that these embodiments are to be used to illustrate
The present invention and be not limited to limit the scope of the present invention.The implementation condition used in embodiment can be done according to the condition of specific producer
Further adjustment, unreceipted implementation condition is usually the condition in normal experiment.
Embodiment 1
The composition of the water based mold release agent in mass ratio is：The phenyl modified organic silicone oil of 100 parts long alkane chain, 10 parts of fusing points are
100-120 DEG C of OPE, 10 parts of heterogeneous ten alcohol polyoxyethylene ethers, 8 parts of AEO9,10 parts of Tween 80s, 500 parts of deionizations
Water.
The phenyl modified organic silicone oil of long alkane chain, OPE, heterogeneous ten alcohol polyoxyethylene ether, long-chain fatty alcohol are gathered
Oxygen vinethene, tween, heating is allowed to melt after said components are mixed, and 2000-3000 revs/min of stirring half an hour, cools to
60 DEG C or so, deionized water is then slowly dropped into batches, and being stirred for half an hour is prepared.
Embodiment 2
The composition of the water based mold release agent in mass ratio is：The phenyl modified organic silicone oil of 150 parts long alkane chain, 15 parts of 98-100
DEG C OPE, 15 parts of heterogeneous ten alcohol polyoxyethylene ethers, 10 parts of AEO9,10 parts of Tween 80s, 700 parts of deionized waters.
Preparation method is the same as embodiment 1.
Comparative example
The composition of the water based mold release agent in mass ratio is：150 parts of silicone oil, 15 parts of 98-100 DEG C of OPEs, 15
Part heterogeneous ten alcohol polyoxyethylene ether, 10 parts of AEO9,10 parts of Tween 80s, 700 parts of deionized waters.
Preparation method is the same as embodiment 1.
The Performance for the casting mold-releasing agent that embodiment is prepared with common silicone oil
Demolding performace detection method is：Casting mold-releasing agent is diluted by a certain percentage with deionized water and (dilutes 150 here
Times), dilution even application on 280 DEG C of steel plates polished smooth have been heated to, spraying steel plate releasing agent part in 5 seconds
Molten aluminum liquid is inserted, is taken out after 15 seconds.
Evaluate releasing agent performance standard：Grade distinguishing demolding performace is pressed with plate quality change after leaching aluminium, soaks quality after aluminium
It is good to increase few demolding performace, it is on the contrary then poor.Assuming that it is m1 not soak aluminium front spring quality, quality increases to m2 after soaking aluminium, then soaks
Plate quality increase percentage is G=(m2-m1)/m1 × 100% before and after aluminium.As G≤0.1%, performance is excellent；0.1%<G
When≤0.5%, performance is good；During G >=0.5%, during performance is.
Application effect contrast is as shown in the table：
Contrasted by the casting mold-releasing agent prepared with common silicone oil, releasing agent provided by the invention has highly diluted
Than, composition not free settling, have good demoulding property the characteristics of.
The foregoing examples are merely illustrative of the technical concept and features of the invention, its object is to allow the person skilled in the art to be
Present disclosure can be understood and implemented according to this, it is not intended to limit the scope of the present invention.It is all smart according to the present invention
The equivalent transformation or modification that refreshing essence is done, should all be included within the scope of the present invention.
Claims (2)
1. a kind of water base aluminium alloy compression casting releasing agent, it is characterised in that it is made up of the component of following mass parts：100 parts of long alkane
The phenyl modified organic silicone oil of chain, 10 parts of fusing points be 100-120 DEG C of OPE, 10 parts of heterogeneous ten alcohol polyoxyethylene ethers, 8 parts
AEO9,10 parts of Tween 80s, 500 parts of deionized waters, it is prepared by the following method：
(1) the phenyl modified organic silicone oil of long alkane chain, OPE, heterogeneous ten alcohol polyoxyethylene ether, AEO9, Tween 80 are taken,
Melting is heated after mixing；
(2) and then by said components stir, cool to 55 DEG C -75 DEG C,
(3) deionized water is then slowly dropped into batches, is stirred for uniformly being prepared.
2. water base aluminium alloy compression casting releasing agent according to claim 1, it is characterised in that the step (2) is in 2000-
3000 revs/min of stirring 0.5-2 hours, cool to 60 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610236773.9A CN105689638B (en) | 2016-04-18 | 2016-04-18 | A kind of water base aluminium alloy compression casting releasing agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610236773.9A CN105689638B (en) | 2016-04-18 | 2016-04-18 | A kind of water base aluminium alloy compression casting releasing agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105689638A CN105689638A (en) | 2016-06-22 |
| CN105689638B true CN105689638B (en) | 2018-03-27 |
Family
ID=56217053
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610236773.9A Active CN105689638B (en) | 2016-04-18 | 2016-04-18 | A kind of water base aluminium alloy compression casting releasing agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105689638B (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107790617A (en) * | 2016-08-29 | 2018-03-13 | 镇江佳鑫精工设备有限公司 | A kind of Cast Iron Die pours releasing agent with cast aluminium |
| CN106424539A (en) * | 2016-10-08 | 2017-02-22 | 常州创索新材料科技有限公司 | Preparation method of aluminum alloy pressure casting mold releasing agent |
| CN106566637A (en) * | 2016-10-26 | 2017-04-19 | 广西大学 | Aluminum alloy waterborne emulsion release agent |
| CN107034002B (en) * | 2017-05-22 | 2020-01-10 | 中山市润发纺织材料有限公司 | Environment-friendly aqueous demolding release composition |
| CN107335777A (en) * | 2017-07-01 | 2017-11-10 | 佛山市高质压铸材料有限公司 | Casting mold-releasing agent and preparation method thereof |
| CN108176805B (en) * | 2017-12-25 | 2019-09-20 | 上海氟聚化学产品股份有限公司 | A kind of aqua type aluminum alloy mould release agent and preparation method thereof |
| CN108130182B (en) * | 2017-12-29 | 2020-08-14 | 中天东方氟硅材料有限公司 | PC component release agent emulsion and preparation method thereof |
| CN108339930B (en) * | 2018-02-09 | 2020-06-02 | 富兰克润滑科技（太仓）有限公司 | Water-based release agent applied to aluminum alloy die castings and preparation method thereof |
| CN108515142A (en) * | 2018-07-13 | 2018-09-11 | 安徽思源三轻智能制造有限公司 | A kind of aluminium alloy compression casting releasing agent and preparation method thereof |
| CN109014023B (en) * | 2018-08-29 | 2020-07-10 | 昆山帝邦铸造科技有限公司 | Water-based release agent and preparation method and use method thereof |
| CN108788002B (en) * | 2018-08-29 | 2020-01-21 | 昆山帝邦铸造科技有限公司 | Heat-resistant aluminum alloy die-casting release agent and preparation method and use method thereof |
| CN109054980A (en) * | 2018-09-19 | 2018-12-21 | 广东赛米克新材料有限公司 | One kind being used for copper, aluminium and its alloy hot-die forging and forming high temperature resistant environment-protective release agent |
| CN109014026A (en) * | 2018-10-16 | 2018-12-18 | 上海樱花化研化工科技有限公司 | Mold release compositions and preparation method thereof |
| CN113751666B (en) * | 2021-09-30 | 2023-05-05 | 和县科嘉阀门铸造有限公司 | Water-based die-casting release agent for aluminum alloy casting |
| CN114682731A (en) * | 2022-04-24 | 2022-07-01 | 连云港倍力达新材料有限公司 | Mold release agent for aluminum alloy LED lamp product |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101898227A (en) * | 2010-07-28 | 2010-12-01 | 启东尤希路化学工业有限公司 | Environment-friendly magnesium alloy release agent |
| CN102658351B (en) * | 2012-05-02 | 2013-10-09 | 厦门大学 | Fluorine-free aluminum-zinc alloy water-based release agent and preparation method thereof |
| CN104338894A (en) * | 2013-08-05 | 2015-02-11 | 天津高博铝业有限公司 | Aluminum alloy water-based mold release agent and preparation method thereof |
| CN103831393B (en) * | 2013-12-30 | 2016-05-25 | 上海福岛新材料科技有限公司 | A kind of water-based aluminium alloy compression casting releasing agent and preparation method thereof |
| CN105218826A (en) * | 2015-08-28 | 2016-01-06 | 苏州兴业材料科技股份有限公司 | A kind of modified silicon oil and water base casting mold-releasing agent therefrom |
-
2016
- 2016-04-18 CN CN201610236773.9A patent/CN105689638B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN105689638A (en) | 2016-06-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105689638B (en) | A kind of water base aluminium alloy compression casting releasing agent and preparation method thereof | |
| CN105728639B (en) | Water-based aluminum alloy mould release agent and preparation method thereof | |
| CN103831393B (en) | A kind of water-based aluminium alloy compression casting releasing agent and preparation method thereof | |
| CN102658351B (en) | Fluorine-free aluminum-zinc alloy water-based release agent and preparation method thereof | |
| CN108176805B (en) | A kind of aqua type aluminum alloy mould release agent and preparation method thereof | |
| CN107999692B (en) | Die-casting aluminum alloy water-based release agent and preparation method thereof | |
| CN101029268B (en) | Lubricating and cooling emulsified oil for fine drawing of copper alloy wire and production method thereof | |
| CN109228057B (en) | Tire release agent and preparation method thereof | |
| CN108339930A (en) | A kind of water based mold release agent and preparation method thereof applied to aluminum alloy die casting | |
| CN107384562B (en) | Aluminum alloy water-based die-casting release agent and preparation method thereof | |
| CN109014023B (en) | Water-based release agent and preparation method and use method thereof | |
| CN102205390A (en) | Environmentally-friendly casting mold-releasing agent and preparation method thereof | |
| CN105218826A (en) | A kind of modified silicon oil and water base casting mold-releasing agent therefrom | |
| CN101406928A (en) | Organosilicon microemulsion antisticking agent and preparation method thereof | |
| CN107335777A (en) | Casting mold-releasing agent and preparation method thereof | |
| CN113201417A (en) | Ultrasonic cleaning agent and preparation method thereof | |
| CN104789263B (en) | A kind of multifunctional emulsified wax and preparation method thereof | |
| CN108856643B (en) | A mold release agent for ultra-thin magnesium alloy die-casting parts in the frame frame of 3C electronic products | |
| CN106368057B (en) | A kind of water-based lubricant and preparation method thereof | |
| CN106398848A (en) | Water-based mold release agent composition, preparation method and application | |
| CN110281433A (en) | A kind of industrial release agent of rubber-moulding and preparation method thereof | |
| JP5532600B2 (en) | Die-cast mold release agent composition and emulsion-type die-cast mold release agent using the same | |
| JPH0257117B2 (en) | ||
| CN104004571B (en) | A kind of Drawing Lubricant for High Speed Aluminium Rod Drawing Machine of low-friction coefficient | |
| CN107803460B (en) | A kind of release agent and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |