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CN105671679A - High-moisture-conducting and heat-insulating fibers - Google Patents

High-moisture-conducting and heat-insulating fibers Download PDF

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Publication number
CN105671679A
CN105671679A CN201610208101.7A CN201610208101A CN105671679A CN 105671679 A CN105671679 A CN 105671679A CN 201610208101 A CN201610208101 A CN 201610208101A CN 105671679 A CN105671679 A CN 105671679A
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CN
China
Prior art keywords
parts
moisture
conducting
bamboo charcoal
heat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610208101.7A
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Chinese (zh)
Inventor
叶澄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wenzhou Hongchengxiang Technology Co Ltd
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Wenzhou Hongchengxiang Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wenzhou Hongchengxiang Technology Co Ltd filed Critical Wenzhou Hongchengxiang Technology Co Ltd
Priority to CN201610208101.7A priority Critical patent/CN105671679A/en
Publication of CN105671679A publication Critical patent/CN105671679A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/22Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/92Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/12Applications used for fibers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention relates to high-moisture-conducting and heat-insulating fibers. The high-moisture-conducting and heat-insulating fibers are prepared through the following steps: step 1, pre-carbonizing bamboo charcoal powder; step 2, carrying out activation treatment on the bamboo charcoal powder; step 3, preparing to obtain a nano bamboo charcoal powder body; step 5, uniformly mixing polyester slices, a silane coupling agent, zinc stearate used as a surfactant and liquid wax to form a fused polyester matter; step 6, uniformly mixing the bamboo charcoal powder body, a hydrophilic moisture-conducting finishing and the fused polyester matter at a ratio to form a mixture; step 7, weaving the mixture through a pelletizer to form master batches; step 8, after uniformly mixing the master batches and the polyester slices, and fusing and spinning to form high-moisture-conducting and heat-insulating fibers; and step 9, drafting and winding the high-moisture-conducting and heat-insulating fibers obtained by the step 8 to form high-moisture-conducting and heat-insulating fiber filaments. The invention has the advantages that a manufacturing method of the high-moisture-conducting and heat-insulating fibers is provided; the high-moisture-conducting and heat-insulating fibers are functional fibers which have a soft and comfortable body feeling, are ventilated and have no body sticking feeling, and have the functions of insulating heat, conducting moisture and automatically adjusting the temperature and the moisture.

Description

A kind of height leads wet thermal fiber
Technical field
The present invention relates to a kind of functional fibre fabric, be specially a kind of height and lead wet thermal fiber.
Background technology
Along with the raising of people's living standard, the fabric being used for making underwear is had higher requirement, does not require nothing more than durable, and require to have higher warmth retention property, skin-friendly and comfort level, also need to have stronger suction, wet transmitting performance, good springiness simultaneously.
At present, commercially available underwear fabric, although disclosure satisfy that the requirement of people in some aspects, but, also need to further raising generally.
Summary of the invention
For the deficiencies in the prior art, the technical problem that the present invention intends to solve is to provide a kind of high manufacture method leading wet thermal fiber, will possess body-sensing soft comfortable, ventilative without viscous body sense, warming, lead the wet functional fibre being automatically adjusted humiture.
To achieve these goals, the present invention adopts the following technical scheme that a kind of height leads wet thermal fiber, and this fiber is prepared by following steps:
Step one, the mixing of bamboo charcoal powder, dispersant and softening water is made bamboo carbon powder serum is kept 20min at the temperature of 400~450 DEG C by grinding so that bamboo charcoal powder obtains pre-carbonization;
Step 2, the bamboo charcoal powder after pre-carbonization is carried out at the temperature of about 1800 DEG C activation processing, after carrying out activation processing, make bamboo charcoal powder form cellular loose structure;
Step 3, step 2 is prepared bamboo charcoal powder nanorize it is processed into the bamboo-carbon powder of 50~100 nanometers;
Step 4, preparing and hydrophilic lead dressing agent, this is hydrophilic leads dressing agent and includes the component of following parts by weight:
Polyox-yethylene-polyoxypropylene block copolymer 4-10 part
Organic silicon modified polyurethane resin 10-15 part
Ethylene bis stearamide 15-20 part
Diboron trioxide 3-6 part
Fatty alcohol-polyoxyethylene ether 2-8 part
Firming agent 10-12 part
Microfine diatomaceous 1-4 part
Nano silicon 7-15 part
Nano magnesia 3-6 part
Aluminium chloride hexahydrate 8-10 part
Vitamin E2-3 parts
Solvent 50-100 part;
Step 5, polyester slice, silane coupler, zinc stearate and liquid wax as surfactant are at high temperature uniformly mixed to form the polyester thing of molten according to 100: 2~5: 4~6: 9~10 mass ratios;
Step 6, described bamboo-carbon powder, the hydrophilic polyester thing leading dressing agent and molten are uniformly mixed to form mixture according to 1: 1: 8-12 mass ratio;
Step 7, by described mixture through comminutor weaving formed master batch;
Step 8, by described master batch again with polyester slice according to after 1: 20~45 mass ratio Homogeneous phase mixing and form height through melt spinning and lead wet thermal fiber silk;
Step 9, by step 8 obtain described height lead wet thermal fiber silk through drawing-off winding formed height lead wet thermal fiber long filament.
Preferably, described hydrophilic lead dressing agent and preferably include the component of following weight portion:
Polyox-yethylene-polyoxypropylene block copolymer 7 parts
Organic silicon modified polyurethane resin 12 parts
Ethylene bis stearamide 18 parts
Diboron trioxide 5 parts
Fatty alcohol-polyoxyethylene ether 5 parts
11 parts of firming agent
Microfine diatomaceous 2 parts
Nano silicon 12 parts
Nano magnesia 5 parts
Aluminium chloride hexahydrate 9 parts
Vitamin E2 .5 part
Solvent 75 parts.
Preferably, it is the 3 ~ 6% of total weight of fiber that described height leads bamboo charcoal content in wet thermal fiber, leads wet rate >=70%, breathability >=800mm/s.
This fiber above-mentioned, temperature value as required: in the hydrophilic various material mixture ratios leading dressing agent and fiber manufacture process, by constant for material, predetermined temperature, the structure and the performance that vary with temperature material have reversibility, when temperature raises or reduces, material can carry out self regulation along curve automatically, and reaches " intellectuality " hotness conduction temperature adjustment function.
Compared with the prior art, the superiority of technical solution of the present invention is:
1, the fiber of this structure, fastness is good, wash resistant, even if extexine fiber galls, function powder material is without running off easily, and hotness conduction memory function is lasting.
2, this fiber, extexine is very thin, soft comfortable is as good as with natural fiber.
3, this fiber, continues warmth sensation at low temperatures and conducts considerably beyond its synthetic fibers and the insulation of natural fiber, warming effect, be 3 times of its synthetic fibers, 8 times of natural fiber.
4, this fiber, takes out in ice cold water, and contact skin moment is warm.
Detailed description of the invention
By the examples below, technical scheme is described in further detail.
Embodiment one:
A kind of height leads wet thermal fiber, it is characterised in that this manufacture method is undertaken by following technique:
Step one, the mixing of bamboo charcoal powder, dispersant and softening water is made bamboo carbon powder serum is kept 20min at the temperature of 400 DEG C by grinding so that bamboo charcoal powder obtains pre-carbonization;
Step 2, the bamboo charcoal powder after pre-carbonization is carried out at the temperature of about 1800 DEG C activation processing, after carrying out activation processing, make bamboo charcoal powder form cellular loose structure;
Step 3, step 2 is prepared bamboo charcoal powder nanorize it is processed into the bamboo-carbon powder of 50 nanometers;
Step 4, preparing and hydrophilic lead dressing agent, this is hydrophilic leads dressing agent and includes the component of following parts by weight:
Polyox-yethylene-polyoxypropylene block copolymer 4 parts
Organic silicon modified polyurethane resin 10 parts
Ethylene bis stearamide 15 parts
Diboron trioxide 3 parts
Fatty alcohol-polyoxyethylene ether 2 parts
10 parts of firming agent
Microfine diatomaceous 1 part
Nano silicon 7 parts
Nano magnesia 3 parts
Aluminium chloride hexahydrate 8 parts
Vitamin E2 part
Solvent 50 parts;
Step 5, polyester slice, silane coupler, zinc stearate and liquid wax as surfactant are at high temperature uniformly mixed to form the polyester thing of molten according to 100: 2: 4: 9 mass ratios;
Step 6, described bamboo-carbon powder, the hydrophilic polyester thing leading dressing agent and molten are uniformly mixed to form mixture according to 1: 1: 8 mass ratio;
Step 7, by described mixture through comminutor weaving formed master batch;
Step 8, by described master batch again with polyester slice according to after 1: 20 mass ratio Homogeneous phase mixing and form height through melt spinning and lead wet thermal fiber silk;
Step 9, by step 8 obtain described height lead wet thermal fiber silk through drawing-off winding formed height lead wet thermal fiber long filament.
After tested, it is the 3% of total weight of fiber that described height leads bamboo charcoal content in wet thermal fiber, and leading wet rate is 82%, and breathability is 950mm/s.
Embodiment two:
A kind of height leads wet thermal fiber, it is characterised in that this manufacture method is undertaken by following technique:
Step one, the mixing of bamboo charcoal powder, dispersant and softening water is made bamboo carbon powder serum is kept 20min at the temperature of 450 DEG C by grinding so that bamboo charcoal powder obtains pre-carbonization;
Step 2, the bamboo charcoal powder after pre-carbonization is carried out at the temperature of about 1800 DEG C activation processing, after carrying out activation processing, make bamboo charcoal powder form cellular loose structure;
Step 3, step 2 is prepared bamboo charcoal powder nanorize it is processed into the bamboo-carbon powder of 100 nanometers;
Step 4, preparing and hydrophilic lead dressing agent, this is hydrophilic leads dressing agent and includes the component of following parts by weight:
Polyox-yethylene-polyoxypropylene block copolymer 10 parts
Organic silicon modified polyurethane resin 15 parts
Ethylene bis stearamide 20 parts
Diboron trioxide 6 parts
Fatty alcohol-polyoxyethylene ether 8 parts
12 parts of firming agent
Microfine diatomaceous 4 parts
Nano silicon 15 parts
Nano magnesia 6 parts
Aluminium chloride hexahydrate 10 parts
Vitamin E 3 parts
Solvent 100 parts;
Step 5, polyester slice, silane coupler, zinc stearate and liquid wax as surfactant are at high temperature uniformly mixed to form the polyester thing of molten according to 100: 5: 6: 10 mass ratios;
Step 6, described bamboo-carbon powder, the hydrophilic polyester thing leading dressing agent and molten are uniformly mixed to form mixture according to 1: 1: 12 mass ratio;
Step 7, by described mixture through comminutor weaving formed master batch;
Step 8, by described master batch again with polyester slice according to after 1: 45 mass ratio Homogeneous phase mixing and form height through melt spinning and lead wet thermal fiber silk;
Step 9, by step 8 obtain described height lead wet thermal fiber silk through drawing-off winding formed height lead wet thermal fiber long filament.
After tested, it is the 5.8% of total weight of fiber that described height leads bamboo charcoal content in wet thermal fiber, and leading wet rate is 94%, and breathability is 1000mm/s.
The above; it is only the specific embodiment of the present invention; but protection scope of the present invention is not limited thereto; any those of ordinary skill in the art are in the technical scope that disclosed herein; the change can expected without creative work or replacement, all should be encompassed within protection scope of the present invention. Therefore, protection scope of the present invention should be as the criterion with claims protection defined.

Claims (3)

1. lead wet thermal fiber for one kind high, it is characterised in that this fiber is prepared by following steps:
Step one, the mixing of bamboo charcoal powder, dispersant and softening water is made bamboo carbon powder serum is kept about 20min at the temperature of 400~450 DEG C by grinding so that bamboo charcoal powder obtains pre-carbonization;
Step 2, the bamboo charcoal powder after pre-carbonization is carried out at the temperature of about 1800 DEG C activation processing, after carrying out activation processing, make bamboo charcoal powder form cellular loose structure;
Step 3, step 2 is prepared bamboo charcoal powder nanorize it is processed into the bamboo-carbon powder of 50~100 nanometers;
Step 4, preparing and hydrophilic lead dressing agent, this is hydrophilic leads dressing agent and includes the component of following parts by weight:
Polyox-yethylene-polyoxypropylene block copolymer 4-10 part
Organic silicon modified polyurethane resin 10-15 part
Ethylene bis stearamide 15-20 part
Diboron trioxide 3-6 part
Fatty alcohol-polyoxyethylene ether 2-8 part
Firming agent 10-12 part
Microfine diatomaceous 1-4 part
Nano silicon 7-15 part
Nano magnesia 3-6 part
Aluminium chloride hexahydrate 8-10 part
Vitamin E2-3 parts
Solvent 50-100 part;
Step 5, polyester slice, silane coupler, zinc stearate and liquid wax as surfactant are at high temperature uniformly mixed to form the polyester thing of molten according to 100: 2~5: 4~6: 9~10 mass ratios;
Step 6, described bamboo-carbon powder, the hydrophilic polyester thing leading dressing agent and molten are uniformly mixed to form mixture according to 1: 1: 8-12 mass ratio;
Step 7, by described mixture through comminutor weaving formed master batch;
Step 8, by described master batch again with polyester slice according to after 1: 20~45 mass ratio Homogeneous phase mixing and form height through melt spinning and lead wet thermal fiber silk;
Step 9, by step 8 obtain described height lead wet thermal fiber silk through drawing-off winding formed height lead wet thermal fiber long filament.
2. a kind of height according to claim 1 leads wet thermal fiber, it is characterised in that: described hydrophilic lead dressing agent and preferably include the component of following weight portion:
Polyox-yethylene-polyoxypropylene block copolymer 7 parts
Organic silicon modified polyurethane resin 12 parts
Ethylene bis stearamide 18 parts
Diboron trioxide 5 parts
Fatty alcohol-polyoxyethylene ether 5 parts
11 parts of firming agent
Microfine diatomaceous 2 parts
Nano silicon 12 parts
Nano magnesia 5 parts
Aluminium chloride hexahydrate 9 parts
Vitamin E2 .5 part
Solvent about 75 parts.
3. a kind of height according to claim 1 and 2 leads wet thermal fiber, it is characterised in that: it is the 3 ~ 6% of total weight of fiber that described height leads bamboo charcoal content in wet thermal fiber, leads wet rate >=70%, breathability >=800mm/s.
CN201610208101.7A 2016-04-06 2016-04-06 High-moisture-conducting and heat-insulating fibers Pending CN105671679A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610208101.7A CN105671679A (en) 2016-04-06 2016-04-06 High-moisture-conducting and heat-insulating fibers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610208101.7A CN105671679A (en) 2016-04-06 2016-04-06 High-moisture-conducting and heat-insulating fibers

Publications (1)

Publication Number Publication Date
CN105671679A true CN105671679A (en) 2016-06-15

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Country Status (1)

Country Link
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108823732A (en) * 2018-06-28 2018-11-16 东莞职业技术学院 A kind of production method of thermal fabric
CN109706622A (en) * 2018-12-29 2019-05-03 杭州协业超纤有限公司 A kind of Compound Fabric and its preparation process of straight spinning formula superfine fibre and elastic screen cloth
CN111188115A (en) * 2019-11-20 2020-05-22 江苏箭鹿毛纺股份有限公司 Warm-keeping fabric and production method thereof
CN117866414A (en) * 2024-01-10 2024-04-12 广东中鼎科技发展有限公司 High-biobased TPU composite material and preparation method thereof

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Publication number Priority date Publication date Assignee Title
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JP4355945B2 (en) * 2004-11-08 2009-11-04 住友金属鉱山株式会社 Near-infrared absorbing fiber and fiber product using the same
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CN105440769A (en) * 2015-12-30 2016-03-30 曲少春 Anti-UV absorber used for coating and preparation method thereof

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JP4355945B2 (en) * 2004-11-08 2009-11-04 住友金属鉱山株式会社 Near-infrared absorbing fiber and fiber product using the same
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CN101215729A (en) * 2008-01-10 2008-07-09 孙嘉良 Binchotan fibre
CN102797159A (en) * 2012-08-24 2012-11-28 上海洋帆实业有限公司 Method for preparing intelligent waterproof moisture permeable tent fabric
CN103556307A (en) * 2013-10-29 2014-02-05 衢州净力竹炭科技有限公司 Process for processing bamboo charcoal fibers
CN104389100A (en) * 2014-11-29 2015-03-04 滁州惠智科技服务有限公司 Fluorescent sunscreen fabric production method
CN105440769A (en) * 2015-12-30 2016-03-30 曲少春 Anti-UV absorber used for coating and preparation method thereof

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杨建忠: "《新型纺织材料及应用》", 31 October 2011 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108823732A (en) * 2018-06-28 2018-11-16 东莞职业技术学院 A kind of production method of thermal fabric
CN109706622A (en) * 2018-12-29 2019-05-03 杭州协业超纤有限公司 A kind of Compound Fabric and its preparation process of straight spinning formula superfine fibre and elastic screen cloth
CN111188115A (en) * 2019-11-20 2020-05-22 江苏箭鹿毛纺股份有限公司 Warm-keeping fabric and production method thereof
CN117866414A (en) * 2024-01-10 2024-04-12 广东中鼎科技发展有限公司 High-biobased TPU composite material and preparation method thereof
CN117866414B (en) * 2024-01-10 2024-07-09 广东中鼎科技发展有限公司 High-biobased TPU composite material and preparation method thereof

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