CN105655150A - Electrochemical power supply electrode - Google Patents
Electrochemical power supply electrode Download PDFInfo
- Publication number
- CN105655150A CN105655150A CN201610113996.6A CN201610113996A CN105655150A CN 105655150 A CN105655150 A CN 105655150A CN 201610113996 A CN201610113996 A CN 201610113996A CN 105655150 A CN105655150 A CN 105655150A
- Authority
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- China
- Prior art keywords
- collector
- power source
- electrochemical power
- active material
- projection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011149 active material Substances 0.000 claims abstract description 38
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 20
- 229910001416 lithium ion Inorganic materials 0.000 claims description 20
- 239000003990 capacitor Substances 0.000 claims description 15
- 150000001875 compounds Chemical class 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- 239000000446 fuel Substances 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 238000007639 printing Methods 0.000 claims description 4
- 229910000831 Steel Inorganic materials 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 238000004080 punching Methods 0.000 claims description 3
- 230000003068 static effect Effects 0.000 claims description 3
- 239000010959 steel Substances 0.000 claims description 3
- 230000009471 action Effects 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims 2
- 230000000149 penetrating effect Effects 0.000 abstract 1
- 230000001737 promoting effect Effects 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- 230000009286 beneficial effect Effects 0.000 description 9
- 238000005516 engineering process Methods 0.000 description 9
- 239000003792 electrolyte Substances 0.000 description 8
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 7
- 229910052744 lithium Inorganic materials 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000005030 aluminium foil Substances 0.000 description 5
- 239000011230 binding agent Substances 0.000 description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 5
- 239000006258 conductive agent Substances 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 230000006872 improvement Effects 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000011889 copper foil Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 229910021389 graphene Inorganic materials 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- -1 polytetrafluoroethylene Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000009881 electrostatic interaction Effects 0.000 description 1
- 239000011796 hollow space material Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/66—Current collectors
- H01G11/70—Current collectors characterised by their structure
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/70—Carriers or collectors characterised by shape or form
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0247—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Power Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Cell Electrode Carriers And Collectors (AREA)
Abstract
The invention relates to an electrochemical power supply electrode formed by compositing active material layers and a current collector. Three-dimensional protrusions are formed on the surface of the current collector, each protrusion is of a hollow structure with the two ends opened, the openings at the bottom ends of the protrusions are connected with the current collector in an opened mode, penetrating holes are formed in the current collector, and the protrusions are arranged on the two sides of the current collector in a staggered mode. By means of the three-dimensional protrusion structure, the bonding force between the active material layers and the current collector is increased, the electrode density is increased, the internal resistance is reduced, and performance promoting and service life prolonging of an electrochemical power supply are facilitated.
Description
Technical field
The present invention relates to electrochemical field, particularly, the present invention relates to a kind of electrochemical power source electrode, this electrode can be applicable to multiple electrochemical power source, comprises ultracapacitor, lithium-ion capacitor, mixed capacitor, fuel cell and lithium ion battery.
Background technology
Electrochemical power source is a kind of stored energy and releasing device, it carries out the conversion of energy by the mode of physics or chemistry, for various electricity consumption facilities provide energy source and power, relate to the many aspects of social life, there is portability and ease of use, be widely used in the fields such as electronic product, electric tool, wind energy, solar energy, automobile, aviation. This electrochemical power source comprises ultracapacitor, lithium-ion capacitor, mixed capacitor, fuel cell and lithium ion battery etc.
Electrode is the core parts of electrochemical power source, is the key factor that affects electrochemical power source performance. Electrode is composited by active material layer and collector. Active material layer comprises active material, conductive agent and binding agent, and wherein active material is the main material of electrode, for capacity is provided; Conductive agent is for improving the electric conductivity of electrode; Binding agent is for being bonded together active material, conductive agent and collector, and collector is used for supporting active material layer and electron transfer passage is provided.
Prior art is all generally that active material layer is compounded on ganoid collector and makes electrode, there is following defect in this technology: 1, the adhesion strength of active material layer and collector is inadequate, with the prolongation of service time, charge and discharge cycles increased frequency, part active material can come off from collector, affects electrode performance and life-span; 2, collector and active material are Surface Contact, and contact area is limited, and internal resistance is bigger than normal; 3, when electrode is assembled into electrochemical power source, need to electrode roll around or be superimposed as contact utmost point group comparatively closely, will cause fluid injection time electrolyte be difficult to infiltrate utmost point group inside, along with the carrying out of charge and discharge cycles, electrode interior electrolyte scarcity, causes electrochemical power source performance to reduce or damages; 4, in prior art, for solving active material and collector adhesion strength and internal resistance problem, some technique is to be situated between to introduce one deck conducting resinl again, but the introducing of conducting resinl has increased the cost such as manufacturing process and material, equipment, and increases the chance of introducing impurity; 5, in prior art, some technique is to produce by physics or chemical means the hole of running through or not running through on collector, and the problems referred to above are had to certain improvement, but effect is not too obvious.
Summary of the invention
In order to solve the deficiencies in the prior art, not only electrode performance is good, the life-span is long to the invention provides one, and internal resistance is little, power source performance is not easy the electrochemical power source electrode that reduces or damage.
The present invention realizes in the following manner: a kind of electrochemical power source electrode, and by active material layer with collector is compound forms. Described collection liquid surface has 3 D stereo projection; Described projection is the hollow structure of both ends open; The opening of described bump bottom ends is connected with collector is open, and forms the hole running through on collector; Described projection is staggered in collector both sides.
As preferably, the ratio that the area of described hole accounts for collector area is 10-80%. The rapid osmotic of electrolyte when the existence of hole is beneficial to fluid injection on collector, and can make electrolyte fully enter electrode group inside, prevent with charge and discharge cycles carry out and the deficient phenomenon of electrolyte that occurs. Pore structure can also alleviate the quality of collector, thereby alleviates electrochemical power source quality, is beneficial to lightness and the miniaturization of electrochemical power source.
As preferably, the centre-to-centre spacing between described hole is 0.05-1mm. The active material that is positioned at the upper and lower both sides of collector can be realized directly contact by open projection, is beneficial to ionic conduction, reduces internal resistance.
As preferably, described projection is the 5%-50% of active material layer thickness perpendicular to the height of collection liquid surface. Compound tense part active material enters protruding hollow space, increases active material and collector contact area, increases electrode density, and improves adhesion, extends electrode life, reduces consumption of binder, reduces internal resistance.
As preferably, the generation type of described projection comprise to collector shear, punching press, burn into laser. Projection, for collector itself is processed, forms without additionally collector being introduced to other materials, thereby reduces material cost and the probability of introducing impurity.
As preferably, described collector material comprises copper, aluminium, nickel, steel.
As preferably, the described compound mode of action comprises static, pressure, heat, printing, coating. Active material layer can increase cohesive force with the collector with three-dimensional projection is compound, thereby can select to be more applicable to and flexile complex method according to material behavior, expands the material scope of application of active material.
A kind of electrochemical power source, the electrochemical power source electrode that electrode uses this invention technology to provide is provided.
As preferably, described electrochemical power source comprises ultracapacitor, lithium-ion capacitor, mixed capacitor, fuel cell and lithium ion battery. The technology of the present invention is applicable to above-mentioned electrochemical power source. It should be noted that, the technology of the present invention is particularly useful for lithium-ion capacitor. Its collector of technological requirement of the pre-embedding lithium of lithium-ion capacitor must have through hole to provide migrating channels to lithium ion, prior art is all that collector additional processing is formed to through hole, and the lithium ion of the technology of the present invention can, directly by the open hollow part transmission of 3 D stereo projection, complete pre-embedding lithium.
Beneficial effect of the present invention: improve the adhesion of active material layer and collector, extend electrochemical power source service life; Increase the active material quality of unit are, increase electrode density, raising capacity, energization density; Reduce consumption of binder, reduce internal resistance, improve power density; Alleviate collector quality, reduce electrochemical power source quality or volume; Reduce power module quantity or volume, be beneficial to power module lightness and miniaturization, reduce costs; Be beneficial to electrolyte and infiltrate rapidly electrode interior, prevent electrolyte scarcity; The technology of the present invention is particularly useful for lithium-ion capacitor.
Brief description of the drawings
Fig. 1 is a kind of electrochemical power source electrode sectional structure schematic diagram of the present invention;
Fig. 2 is the sectional structure schematic diagram of prior art electrode;
In figure; 1, active material layer, 2, collector, 3, projection, 4, hole, 5, common collector.
Detailed description of the invention
Below in conjunction with specification drawings and specific embodiments, substantive distinguishing features of the present invention is further described.
A kind of electrochemical power source electrode as shown in Figure 1, by active material layer 1 with collector 2 is compound forms. There is 3 D stereo projection 3 on described collector 2 surfaces; Described projection is the hollow structure of both ends open; The opening of described bump bottom ends is connected with collector is open, and forms the hole 4 running through on collector; Described projection is staggered in collector both sides. Described projection is the cube of hollow, can regular or irregular shape, can give an example as mountain peak shape, fibrous etc. Described protruding both ends open can be rule and irregular various geometries, can give an example as circular, oval etc. Collector material comprises copper, aluminium, nickel, steel etc. Described projection be by collector itself is sheared, the mode such as punching press, burn into laser processes.
Fig. 2 is the sectional structure schematic diagram of prior art electrode. Common collector is ganoid slab construction. Comparison diagram 1 and Fig. 2, can obviously see, the electrode of the technology of the present invention, and active material can enter the hollow bumps inside on collector, increases the active material of unit are, increases electrode density, raising capacity and energy density. And the two ends that the active material that is positioned at the upper and lower both sides of collector can be opened by projection directly contact, be beneficial to the conduction of ion, reduce internal resistance.
The ratio that the area of described hole accounts for collector area is preferably 10-80%. On collector, the existence of hole is beneficial to note increases unit are active material quality, and can make electrolyte fully enter fast electrode interior. Meanwhile, pore structure can also alleviate the quality of collector, thereby alleviates electrochemical power source quality, is beneficial to lightness and the miniaturization of electrochemical power source.
The preferred 5-100um of thickness of described collector, more specifically, preferably 8-50um. Described projection is preferably the 5%-50% of active material layer thickness perpendicular to the height of collection liquid surface, concrete height number is preferably 5-80um. The concrete numerical value of height can be determined according to practical condition adjustment, all should be considered as specific embodiments of the invention.
The compound various ways such as static, pressure, heat, printing, coating that can pass through of active material layer and collector are realized. Concrete complex method can be determined according to material behavior and Production requirement, all should be considered as specific embodiments of the invention. In addition, before compound, can carry out pretreatment to collector. Particularly, can give an example as, scribble in advance intermediate layer at collection liquid surface, the main component of described intermediate layer is conductive materials and binding agent, can further increase the simultaneously further reduction internal resistance of bond strength of active material layer and collector.
Electrochemical power source electrode of the present invention is applicable to field of electrochemical power source, comprises the fields such as ultracapacitor, lithium-ion capacitor, mixed capacitor, fuel cell and lithium ion battery. Technical scheme of the present invention is particularly useful for lithium-ion capacitor field. Lithium-ion capacitor is due to the particular/special requirement of its pre-embedding lithium technique, in the time of assembling, need to pack lithium sheet in utmost point group one side in advance, then lithium ion will embed in every layer of active material through collector, thereby this just requires collector must have through hole to provide migrating channels for lithium ion. Prior art is all that collector additional processing is formed to through hole, and the lithium ion of the technology of the present invention can, directly by the open hollow part transmission of 3 D stereo projection, can complete pre-embedding lithium without additional processing.
The invention is not restricted to above-mentioned embodiment, but can in scope of the present invention as claimed in claim, carry out various improvement. These improvement are included within the scope of the present invention.
Embodiment
Embodiment 1
Active carbon and conductive carbon black and polytetrafluoroethylene (PTFE) mix and blend, be pressed into the carbon film of thickness 100um. It is 80% that collector adopts porosity, and hole centre-to-centre spacing is 0.05mm, the aluminium foil that thickness is 20um, and the vertical height of projection is 50um. Carbon film is pressed on aluminium foil by roller, obtains activated carbon electrodes.
Embodiment 2
Lithium titanate and conductive carbon black and Kynoar are mixed to join in crassitude ketone solvent and stir into slurry. It is 50% that collector adopts porosity, and hole centre-to-centre spacing is 1mm, the Copper Foil that thickness is 8um, and the vertical height of projection is 20um. Slurry is coated on Copper Foil, and obtaining active material layer thickness is the lithium titanate electrode of 80um.
Embodiment 3
Graphene and conductive black and acrylic resin are mixed to form uniform granulate mixture. It is 60% that collector adopts porosity, and hole centre-to-centre spacing is 0.4mm, the nickel foil that thickness is 30um, and the vertical height of projection is 16um. Granulate mixture is sprayed on nickel foil by electrostatic interaction, forms the Graphene electrodes that active material layer thickness is 160um.
Embodiment 4
Graphite, conductive agent, polyvinylpyrrolidone are mixed to join and in water, stir into slurry. It is 10% that collector adopts porosity, and hole centre-to-centre spacing is 0.8mm, the aluminium foil that thickness is 15um, and the vertical height of projection is 5um. Slurry printing is shifted on aluminium foil, obtained the graphite electrode that active material layer thickness is 20um.
Embodiment 5
Active carbon and conductive carbon black and polytetrafluoroethylene (PTFE) mix and blend, be first pressed into the carbon film of thickness 200um. It is 80% that collector adopts porosity, and hole centre-to-centre spacing is 0.1mm, the stainless steel that thickness is 30um, and the vertical height of projection is 10um. In advance at the thick intermediate layer of stainless steel surfaces coating 5um. Then carbon film is heat sealing on the aluminium foil that scribbles intermediate layer by the high-temperature roller of 210 DEG C, obtains activated carbon electrodes.
Claims (10)
1. an electrochemical power source electrode, by active material layer (1) and the compound formation of collector (2), there is 3 D stereo projection (3) on described collector (2) surface; Described projection is the hollow structure of both ends open; The opening of described bump bottom ends is connected with collector is open, and forms the hole (4) running through on collector; Described projection is staggered in collector both sides.
2. a kind of electrochemical power source electrode as claimed in claim 1, the ratio that the area that it is characterized in that described hole accounts for collector area is 10-80%.
3. a kind of electrochemical power source electrode as claimed in claim 1, is characterized in that the centre-to-centre spacing between described hole is 0.05-1mm.
4. a kind of electrochemical power source electrode as claimed in claim 1, is characterized in that described projection is the 5%-50% of active material layer thickness perpendicular to the height of collection liquid surface.
5. a kind of electrochemical power source electrode as claimed in claim 1, the mode that convexes to form described in it is characterized in that comprise to collector shear, punching press, burn into laser.
6. a kind of electrochemical power source electrode as claimed in claim 1, is characterized in that described collector material comprises copper, aluminium, nickel, steel.
7. a kind of electrochemical power source electrode as claimed in claim 1, is characterized in that the described compound mode of action comprises static, pressure, heat, printing, coating.
8. an electrochemical power source, is characterized in that electrode is by active material layer (1) and the compound formation of collector (2).
9. there is 3 D stereo projection (3) on collector described in (2) surface; Described projection is the hollow structure of both ends open; The opening of described bump bottom ends is connected with collector is open, and forms the hole (4) running through on collector; Described projection is staggered in collector both sides.
10. a kind of electrochemical power source as claimed in claim 8, is characterized in that described electrochemical power source comprises ultracapacitor, lithium-ion capacitor, mixed capacitor, fuel cell and lithium ion battery.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610113996.6A CN105655150A (en) | 2016-03-01 | 2016-03-01 | Electrochemical power supply electrode |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610113996.6A CN105655150A (en) | 2016-03-01 | 2016-03-01 | Electrochemical power supply electrode |
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CN105655150A true CN105655150A (en) | 2016-06-08 |
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CN201610113996.6A Pending CN105655150A (en) | 2016-03-01 | 2016-03-01 | Electrochemical power supply electrode |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107731546A (en) * | 2017-09-29 | 2018-02-23 | 程杰 | A kind of activated carbon electrodes and preparation method thereof |
CN108281595A (en) * | 2018-01-23 | 2018-07-13 | 青岛宏德精密机械有限公司 | A kind of lithium battery liner plate and its processing technology |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US20090269677A1 (en) * | 2008-04-23 | 2009-10-29 | Sony Corporation | Anode and secondary battery |
CN202259533U (en) * | 2011-09-02 | 2012-05-30 | 深圳市格瑞普电池有限公司 | Pole piece of lithium ion battery and lithium ion battery |
CN204118183U (en) * | 2014-08-01 | 2015-01-21 | 中国电子科技集团公司第十八研究所 | The three-dimensional current collector structure of lithium primary battery negative plate |
-
2016
- 2016-03-01 CN CN201610113996.6A patent/CN105655150A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090269677A1 (en) * | 2008-04-23 | 2009-10-29 | Sony Corporation | Anode and secondary battery |
CN202259533U (en) * | 2011-09-02 | 2012-05-30 | 深圳市格瑞普电池有限公司 | Pole piece of lithium ion battery and lithium ion battery |
CN204118183U (en) * | 2014-08-01 | 2015-01-21 | 中国电子科技集团公司第十八研究所 | The three-dimensional current collector structure of lithium primary battery negative plate |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107731546A (en) * | 2017-09-29 | 2018-02-23 | 程杰 | A kind of activated carbon electrodes and preparation method thereof |
CN108281595A (en) * | 2018-01-23 | 2018-07-13 | 青岛宏德精密机械有限公司 | A kind of lithium battery liner plate and its processing technology |
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Application publication date: 20160608 |