CN105648844A - A kind of high wear-resistant printing impregnated paper and its preparation method - Google Patents
A kind of high wear-resistant printing impregnated paper and its preparation method Download PDFInfo
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- D—TEXTILES; PAPER
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- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/22—Structures being applied on the surface by special manufacturing processes, e.g. in presses
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B29/00—Layered products comprising a layer of paper or cardboard
- B32B29/06—Layered products comprising a layer of paper or cardboard specially treated, e.g. surfaced, parchmentised
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- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/02—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by a sequence of laminating steps, e.g. by adding new layers at consecutive laminating stations
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C08G12/30—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with substituted triazines
- C08G12/32—Melamines
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/26—Aminoplasts
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/22—Structures being applied on the surface by special manufacturing processes, e.g. in presses
- D21H27/26—Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures
- D21H27/28—Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures treated to obtain specific resistance properties, e.g. against wear or weather
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/12—Coating on the layer surface on paper layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/20—Inorganic coating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/554—Wear resistance
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Abstract
Description
技术领域 technical field
本发明涉及浸渍纸技术领域，具体涉及一种高耐磨印刷浸渍纸及其制备方法。 The invention relates to the technical field of impregnated paper, in particular to a high wear-resistant printing impregnated paper and a preparation method thereof.
背景技术 Background technique
浸渍纸由无纺布木浆与PE及植物纤维混合制成，具有超强的吸收力和抗溶解能力，广泛地应用于橱柜、衣柜以及复合地板的贴面中。 Impregnated paper is made of non-woven wood pulp mixed with PE and plant fibers. It has super absorption and anti-solution ability, and is widely used in cabinets, wardrobes and composite floor veneers.
以前的浸渍纸原纸卷由于采用无纺布木浆与PE及植物纤维混合制成，耐磨效果不佳。 The previous impregnated paper base paper rolls are made of non-woven wood pulp mixed with PE and plant fibers, and the wear resistance is not good.
因此，现有技术有待于改进和提高。 Therefore, the prior art needs to be improved and improved.
发明内容 Contents of the invention
为了克服现有技术中存在的缺点和不足，本发明的目的在于提供一种高耐磨印刷浸渍纸，该浸渍纸具有良好的耐磨性能，结构简单，成本低，实用性强。 In order to overcome the shortcomings and deficiencies in the prior art, the purpose of the present invention is to provide a high wear-resistant printing impregnated paper, which has good wear resistance, simple structure, low cost and strong practicability.
本发明的另一目的在于提供一种高耐磨印刷浸渍纸的制备方法，该制备方法工艺简单，操作控制方便，质量稳定，生产效率高，生产成本低，可大规模工业化生产。 Another object of the present invention is to provide a method for preparing high wear-resistant printing impregnated paper. The preparation method has simple process, convenient operation and control, stable quality, high production efficiency, low production cost, and large-scale industrial production.
本发明的目的通过下述技术方案实现：一种高耐磨印刷浸渍纸，包括原纸层、贴合于原纸层上表面的印刷木纹层、贴合于印刷木纹层上表面的耐磨层、以及贴合于耐磨层上表面的耐磨胶膜层。 The purpose of the present invention is achieved through the following technical solutions: a high wear-resistant printing impregnated paper, including a base paper layer, a printed wood grain layer attached to the upper surface of the base paper layer, and a wear-resistant layer attached to the upper surface of the printed wood grain layer , and a wear-resistant adhesive film layer attached to the upper surface of the wear-resistant layer.
本发明的高耐磨印刷浸渍纸通过在原纸层上设置耐磨胶膜层和耐磨层，使得制造出来的浸渍纸具有良好的耐磨性能，结构简单，成本低，实用性强。 The high wear-resistant printing impregnated paper of the present invention is provided with a wear-resistant adhesive film layer and a wear-resistant layer on the base paper layer, so that the manufactured impregnated paper has good wear resistance, simple structure, low cost and strong practicability.
优选的，所述印刷木纹层由水性油墨经印刷制得。本发明通过采用水性油墨经印刷制得的印刷木纹层，其印刷效果好，使得制造出来的浸渍纸具有良好的耐磨性能。 Preferably, the printed wood grain layer is made by printing with water-based ink. In the present invention, the printed wood grain layer prepared by printing with water-based ink has good printing effect, so that the manufactured impregnated paper has good wear resistance.
优选的，所述水性油墨由如下重量百分比的原料组成：水性树脂3%-8%、分散剂0.15%-0.4%、润湿剂0.15%-0.4%、颜料8%-13%、其它助剂4%-12%，水余量。 Preferably, the water-based ink is composed of the following raw materials in weight percentage: water-based resin 3%-8%, dispersant 0.15%-0.4%, wetting agent 0.15%-0.4%, pigment 8%-13%, other additives 4%-12%, water balance.
本发明的水性油墨通过采用上述原料，并严格控制各原料的重量配比，其印刷效果好，使得制造出来的浸渍纸具有良好的耐磨性能。 The water-based ink of the present invention adopts the above-mentioned raw materials and strictly controls the weight ratio of each raw material, so that the printing effect is good, and the impregnated paper produced has good wear resistance.
优选的，所述水性树脂是由水溶性丙烯酸树脂和马来松香改性丙烯酸树脂以重量比2-4:1组成的混合物。 Preferably, the water-based resin is a mixture of water-soluble acrylic resin and maleic rosin-modified acrylic resin in a weight ratio of 2-4:1.
本发明的水性油墨通过将采用水溶性丙烯酸树脂和马来松香改性丙烯酸树脂作为水性树脂复配使用，并控制其重量比为2-4:1，制得的水性油墨印刷效果好，使得制造出来的浸渍纸具有良好的耐磨性能。 The water-based ink of the present invention uses water-soluble acrylic resin and maleic rosin-modified acrylic resin as water-based resin compounding, and controls its weight ratio to be 2-4:1, and the printing effect of the prepared water-based ink is good, making the The resulting impregnated paper has good abrasion resistance.
所述分散剂是由六偏磷酸钠、聚丙烯酰胺和十二烷基硫酸钠以重量比1.8-2.6:0.8-1.2:1组成的混合物。 The dispersant is a mixture composed of sodium hexametaphosphate, polyacrylamide and sodium lauryl sulfate in a weight ratio of 1.8-2.6:0.8-1.2:1.
本发明的水性油墨通过采用六偏磷酸钠、聚丙烯酰胺和十二烷基硫酸钠作为分散剂复配使用，并控制其重量比为1.8-2.6:0.8-1.2:1，其分散效果好，制得的水性油墨印刷效果好，使得制造出来的浸渍纸具有良好的耐磨性能。 The water-based ink of the present invention is compounded and used as a dispersant by adopting sodium hexametaphosphate, polyacrylamide and sodium lauryl sulfate, and controls its weight ratio to be 1.8-2.6:0.8-1.2:1, and its dispersion effect is good, The prepared water-based ink has good printing effect, so that the manufactured impregnated paper has good wear resistance.
所述润湿剂是由聚氧乙烯烷基酚醚、聚氧乙烯脂肪醇醚和聚氧乙烯聚氧丙烯嵌段共聚物以重量比1:0.5-1.5:1.4-2.2组成的混合物。 The wetting agent is a mixture composed of polyoxyethylene alkylphenol ether, polyoxyethylene fatty alcohol ether and polyoxyethylene polyoxypropylene block copolymer in a weight ratio of 1:0.5-1.5:1.4-2.2.
本发明的水性油墨通过采用聚氧乙烯烷基酚醚、聚氧乙烯脂肪醇醚和聚氧乙烯聚氧丙烯嵌段共聚物作为润湿剂复配使用，并控制其重量比为1:0.5-1.5:1.4-2.2，其润湿效果好，制得的水性油墨印刷效果好，使得制造出来的浸渍纸具有良好的耐磨性能。 The water-based ink of the present invention is compounded and used as a wetting agent by adopting polyoxyethylene alkylphenol ether, polyoxyethylene fatty alcohol ether and polyoxyethylene polyoxypropylene block copolymer, and controls its weight ratio to be 1:0.5- 1.5:1.4-2.2, its wetting effect is good, and the printing effect of the prepared water-based ink is good, so that the manufactured impregnated paper has good wear resistance.
所述颜料为磷酸钴紫、酞青蓝、酞青绿、炭黑、永固红和联苯胺黄中的至少一种。 The pigment is at least one of cobalt phosphate violet, phthalocyanine blue, phthalocyanine green, carbon black, permanent red and benzidine yellow.
本发明的水性油墨通过采用上述颜料，其染色效果好，制得的水性油墨印刷效果好，使得制造出来的浸渍纸具有良好的耐磨性能。 The water-based ink of the present invention has good dyeing effect by using the above-mentioned pigment, and the prepared water-based ink has good printing effect, so that the manufactured impregnated paper has good wear resistance.
所述其它助剂是由流平剂、消泡剂和稳定剂以重量比0.1-0.5：0.4-0.8:1组成的混合物。 The other additives are a mixture of leveling agent, defoamer and stabilizer in a weight ratio of 0.1-0.5:0.4-0.8:1.
本发明的水性油墨通过采用流平剂、消泡剂和稳定剂作为其它助剂复配使用，并控制其重量比为0.1-0.5：0.4-0.8:1，制得的水性油墨印刷效果好，使得制造出来的浸渍纸具有良好的耐磨性能。 The water-based ink of the present invention is compounded and used as other auxiliary agents by adopting leveling agent, defoamer and stabilizer, and its weight ratio is controlled to be 0.1-0.5:0.4-0.8:1, and the printing effect of the prepared water-based ink is good. The impregnated paper produced has good wear resistance.
本发明采用的流平剂、消泡剂和稳定剂均为本领域常用的流平剂、消泡剂和稳定剂，均可以通过市售购买获得，不属于本发明的保护范围。 The leveling agent, defoamer and stabilizer used in the present invention are all commonly used leveling agents, defoamers and stabilizers in the art, all can be obtained through commercial purchase, and do not belong to the protection scope of the present invention.
优选的，所述耐磨层的原料为氧化铝。本发明通过采用氧化铝作为耐磨层的原料，其耐磨性能好。 Preferably, the raw material of the wear-resistant layer is alumina. The invention adopts aluminum oxide as the raw material of the wear-resistant layer, which has good wear-resistant performance.
优选的，所述耐磨胶膜层的原料为耐磨三胺胶。本发明通过采用耐磨三胺胶作为耐磨胶膜层的原料，使得制造出来的浸渍纸具有良好的耐磨性能。 Preferably, the raw material of the wear-resistant adhesive film layer is wear-resistant triamine adhesive. In the invention, the wear-resistant triamine glue is used as the raw material of the wear-resistant film layer, so that the manufactured impregnated paper has good wear resistance.
优选的，所述耐磨三胺胶包括如下重量份的原料：甲醛3.5-8.5份、三聚氰胺3.5-8.0份、邻苯二甲酸二（2-乙基己酯）0.5-2.5份、二甘醇0.3-3.2份和水1.8-4.2份。 Preferably, the wear-resistant melamine glue includes the following raw materials in parts by weight: 3.5-8.5 parts of formaldehyde, 3.5-8.0 parts of melamine, 0.5-2.5 parts of bis(2-ethylhexyl) phthalate, diethylene glycol 0.3-3.2 parts and water 1.8-4.2 parts.
本发明的耐磨三胺胶通过采用上述原料，并严格控制各原料的重量配比，制得的耐磨三胺胶耐磨性能好，防水性好，化学活性高，热稳定性好，耐沸水性，耐化学药品性和电绝缘性好。 The wear-resistant triamine glue of the present invention adopts the above-mentioned raw materials and strictly controls the weight ratio of each raw material, and the wear-resistant triamine glue prepared has good wear resistance, good water resistance, high chemical activity, good thermal stability, and Boiling water resistance, chemical resistance and good electrical insulation.
优选的，所述耐磨三胺胶的制备方法包括如下步骤： Preferably, the preparation method of the wear-resistant triamine glue comprises the steps of:
（1）取3.5-8.5份甲醛、0.5-2.5份邻苯二甲酸二（2-乙基己酯）、0.3-3.2份二甘醇和1.8-4.2份水投入反应釜中，均匀搅拌至pH值为9.3-9.5； (1) Take 3.5-8.5 parts of formaldehyde, 0.5-2.5 parts of bis(2-ethylhexyl phthalate), 0.3-3.2 parts of diethylene glycol and 1.8-4.2 parts of water into the reaction kettle, and stir evenly until the pH value 9.3-9.5;
（2）加入3.5-8.0份三聚氰胺，加热至89-91℃，然后升温至90-93℃并保温60-90min，至水溶比为1:2.5-3.5； (2) Add 3.5-8.0 parts of melamine, heat to 89-91°C, then raise the temperature to 90-93°C and keep it warm for 60-90min until the water solubility ratio is 1:2.5-3.5;
（3）降温至40-45℃，至水溶比为1:1.2-1.8，出料，制得所述耐磨三胺胶。 (3) Lower the temperature to 40-45°C until the water-soluble ratio is 1:1.2-1.8, and discharge to obtain the wear-resistant triamine glue.
优选的，所述原纸层的比重为70-80g/m2；所述印刷木纹层的比重为2-4g/m2；所述耐磨层的比重为10-15g/m2；所述耐磨胶膜层的比重为90-100g/m2。 Preferably, the specific gravity of the base paper layer is 70-80g/m 2 ; the specific gravity of the printed wood grain layer is 2-4g/m 2 ; the specific gravity of the wear-resistant layer is 10-15g/m 2 ; The specific gravity of the wear-resistant adhesive film layer is 90-100g/m 2 .
本发明的三胺胶的制备方法工艺简单，操作控制方便，质量稳定，生产效率高，生产成本低，可大规模工业化生产。 The preparation method of the triamine glue of the present invention has the advantages of simple process, convenient operation and control, stable quality, high production efficiency, low production cost, and large-scale industrial production.
一种高耐磨印刷浸渍纸的制备方法，包括如下步骤： A preparation method for high wear-resistant printing impregnated paper, comprising the steps of:
A、取原纸层，在原纸层的上表面印刷一层水性油墨，干燥后形成印刷木纹层； A. Take the base paper layer, print a layer of water-based ink on the upper surface of the base paper layer, and form a printed wood grain layer after drying;
B、在印刷木纹层的上表面涂布一层氧化铝乳液，干燥后形成耐磨层； B. Apply a layer of alumina emulsion on the upper surface of the printed wood grain layer, and form a wear-resistant layer after drying;
C、在耐磨层的上表面涂布一层耐磨三胺胶，固化后形成耐磨胶膜层，制得高耐磨印刷浸渍纸。 C. Coating a layer of wear-resistant triamine glue on the upper surface of the wear-resistant layer, and forming a wear-resistant film layer after curing to obtain a high wear-resistant printing impregnated paper.
本发明的有益效果在于：本发明的高耐磨印刷浸渍纸通过在原纸层上设置耐磨胶膜层和耐磨层，使得制造出来的浸渍纸具有良好的耐磨性能，结构简单，成本低，实用性强。 The beneficial effect of the present invention is that: the high wear-resistant printing impregnated paper of the present invention is provided with a wear-resistant adhesive film layer and a wear-resistant layer on the base paper layer, so that the manufactured impregnated paper has good wear resistance, simple structure and low cost , Strong practicability.
本发明的制备方法工艺简单，操作控制方便，质量稳定，生产效率高，生产成本低，可大规模工业化生产。 The preparation method of the invention has the advantages of simple process, convenient operation and control, stable quality, high production efficiency, low production cost and large-scale industrial production.
附图说明 Description of drawings
图1是本发明的局部剖视图； Fig. 1 is a partial sectional view of the present invention;
附图标记为：1—原纸层、2—印刷木纹层、3—耐磨层、4—耐磨胶膜层。 Reference signs are: 1—base paper layer, 2—printed wood grain layer, 3—wear-resistant layer, 4—wear-resistant film layer.
具体实施方式 detailed description
为了便于本领域技术人员的理解，下面结合实施例及附图1对本发明作进一步的说明，实施方式提及的内容并非对本发明的限定。 In order to facilitate the understanding of those skilled in the art, the present invention will be further described below in conjunction with the embodiments and the accompanying drawing 1, and the contents mentioned in the embodiments are not intended to limit the present invention.
实施例1 Example 1
见图1，一种高耐磨印刷浸渍纸，包括原纸层1、贴合于原纸层1上表面的印刷木纹层2、贴合于印刷木纹层2上表面的耐磨层3、以及贴合于耐磨层3上表面的耐磨胶膜层4。 See Fig. 1, a kind of high wear-resisting printed impregnated paper, comprises base paper layer 1, the printed wood grain layer 2 that is attached to the upper surface of base paper layer 1, the wear-resistant layer 3 that is attached to the upper surface of printed wood grain layer 2, and The wear-resistant adhesive film layer 4 attached to the upper surface of the wear-resistant layer 3 .
所述印刷木纹层2由水性油墨经印刷制得。 The printed wood grain layer 2 is made by printing with water-based ink.
所述水性油墨由如下重量百分比的原料组成：水性树脂3%、分散剂0.15%、润湿剂0.15%、颜料8%、其它助剂4%，水余量。 The water-based ink is composed of the following raw materials in weight percentage: 3% water-based resin, 0.15% dispersant, 0.15% wetting agent, 8% pigment, 4% other additives, and the balance of water.
所述水性树脂是由水溶性丙烯酸树脂和马来松香改性丙烯酸树脂以重量比2:1组成的混合物；所述分散剂是由六偏磷酸钠、聚丙烯酰胺和十二烷基硫酸钠以重量比1.8:0.8:1组成的混合物；所述润湿剂是由聚氧乙烯烷基酚醚、聚氧乙烯脂肪醇醚和聚氧乙烯聚氧丙烯嵌段共聚物以重量比1:0.5:1.4组成的混合物；所述颜料为磷酸钴紫、酞青蓝、酞青绿、炭黑、永固红和联苯胺黄中的至少一种；所述其它助剂是由流平剂、消泡剂和稳定剂以重量比0.1：0.4:1组成的混合物。 The water-based resin is a mixture of water-soluble acrylic resin and maleic rosin modified acrylic resin with a weight ratio of 2:1; the dispersant is composed of sodium hexametaphosphate, polyacrylamide and sodium lauryl sulfate The mixture that weight ratio 1.8:0.8:1 is formed; Described wetting agent is by polyoxyethylene alkylphenol ether, polyoxyethylene fatty alcohol ether and polyoxyethylene polyoxypropylene block copolymer with weight ratio 1:0.5: The mixture of 1.4 composition; The pigment is at least one of cobalt phosphate violet, phthalocyanine blue, phthalocyanine green, carbon black, permanent red and benzidine yellow; the other additives are composed of leveling agent, defoamer and stabilizer in a weight ratio of 0.1:0.4:1.
所述耐磨层3的原料为氧化铝。 The raw material of the wear-resistant layer 3 is alumina.
所述耐磨胶膜层4的原料为耐磨三胺胶。 The raw material of the wear-resistant film layer 4 is wear-resistant melamine glue.
所述耐磨三胺胶包括如下重量份的原料：甲醛3.5份、三聚氰胺3.5份、邻苯二甲酸二（2-乙基己酯）0.5份、二甘醇0.3份和水1.8份。 The wear-resistant melamine glue includes the following raw materials in parts by weight: 3.5 parts of formaldehyde, 3.5 parts of melamine, 0.5 parts of bis(2-ethylhexyl) phthalate, 0.3 parts of diethylene glycol and 1.8 parts of water.
所述耐磨三胺胶的制备方法包括如下步骤： The preparation method of described wear-resistant triamine glue comprises the steps:
（1）取3.5份甲醛、0.5份邻苯二甲酸二（2-乙基己酯）、0.3份二甘醇和1.8份水投入反应釜中，均匀搅拌至pH值为9.3； (1) Put 3.5 parts of formaldehyde, 0.5 parts of bis(2-ethylhexyl phthalate), 0.3 parts of diethylene glycol and 1.8 parts of water into the reactor, and stir evenly until the pH value is 9.3;
（2）加入3.5份三聚氰胺，加热至89℃，然后升温至90℃并保温60min，至水溶比为1:2.5； (2) Add 3.5 parts of melamine, heat to 89°C, then raise the temperature to 90°C and keep it warm for 60 minutes until the water solubility ratio is 1:2.5;
（3）降温至40℃，至水溶比为1:1.2，出料，制得所述三胺胶。 (3) Lower the temperature to 40°C until the water-soluble ratio is 1:1.2, and discharge to obtain the triamine glue.
所述原纸层1的比重为70g/m2；所述印刷木纹层2的比重为2g/m2；所述耐磨层3的比重为10g/m2；所述耐磨胶膜层4的比重为90g/m2。 The specific gravity of the base paper layer 1 is 70g/m 2 ; the specific gravity of the printed wood grain layer 2 is 2g/m 2 ; the specific gravity of the wear-resistant layer 3 is 10g/m 2 ; the wear-resistant adhesive film layer 4 The specific gravity is 90g/m 2 .
一种高耐磨印刷浸渍纸的制备方法，包括如下步骤： A preparation method of high wear-resistant printing impregnated paper, comprising the steps of:
A、取原纸层1，在原纸层1的上表面印刷一层水性油墨，干燥后形成印刷木纹层2； A, take the base paper layer 1, print a layer of water-based ink on the upper surface of the base paper layer 1, and form the printed wood grain layer 2 after drying;
B、在印刷木纹层2的上表面涂布一层氧化铝乳液，干燥后形成耐磨层3； B. Coating a layer of aluminum oxide emulsion on the upper surface of the printed wood grain layer 2, and forming a wear-resistant layer 3 after drying;
C、在耐磨层3的上表面涂布一层耐磨三胺胶，固化后形成耐磨胶膜层4，制得高耐磨印刷浸渍纸。 C. Coating a layer of wear-resistant triamine adhesive on the upper surface of the wear-resistant layer 3, and forming a wear-resistant adhesive film layer 4 after curing to obtain a high wear-resistant printing impregnated paper.
实施例2 Example 2
本实施例与上述实施例1的不同之处在于： The difference between this embodiment and the above-mentioned embodiment 1 is:
所述水性油墨由如下重量百分比的原料组成：水性树脂4%、分散剂0.2%、润湿剂0.2%、颜料9%、其它助剂6%，水余量。 The water-based ink is composed of the following raw materials in weight percentage: 4% water-based resin, 0.2% dispersant, 0.2% wetting agent, 9% pigment, 6% other additives, and the balance of water.
所述水性树脂是由水溶性丙烯酸树脂和马来松香改性丙烯酸树脂以重量比2.5:1组成的混合物；所述分散剂是由六偏磷酸钠、聚丙烯酰胺和十二烷基硫酸钠以重量比2:0.9:1组成的混合物；所述润湿剂是由聚氧乙烯烷基酚醚、聚氧乙烯脂肪醇醚和聚氧乙烯聚氧丙烯嵌段共聚物以重量比1:0.8:1.6组成的混合物；所述颜料为磷酸钴紫、酞青蓝、酞青绿、炭黑、永固红和联苯胺黄中的至少一种；所述其它助剂是由流平剂、消泡剂和稳定剂以重量比0.2：0.5:1组成的混合物。 The water-based resin is a mixture of water-soluble acrylic resin and maleic rosin modified acrylic resin with a weight ratio of 2.5:1; the dispersant is composed of sodium hexametaphosphate, polyacrylamide and sodium lauryl sulfate A mixture of weight ratio 2:0.9:1; the wetting agent is made of polyoxyethylene alkylphenol ether, polyoxyethylene fatty alcohol ether and polyoxyethylene polyoxypropylene block copolymer in a weight ratio of 1:0.8: The mixture of 1.6 composition; Described pigment is at least one in cobalt phosphate violet, phthalocyanine blue, phthalocyanine green, carbon black, permanent red and benzidine yellow; Described other auxiliary agent is made of leveling agent, defoamer and stabilizer in a weight ratio of 0.2:0.5:1.
所述三胺胶包括如下重量份的原料：甲醛5份、三聚氰胺5份、邻苯二甲酸二（2-乙基己酯）1份、二甘醇1份和水2.1份。 The melamine glue includes the following raw materials in parts by weight: 5 parts of formaldehyde, 5 parts of melamine, 1 part of bis(2-ethylhexyl) phthalate, 1 part of diethylene glycol and 2.1 parts of water.
所述三胺胶的制备方法包括如下步骤： The preparation method of described triamine glue comprises the steps:
（1）取5份甲醛、1份邻苯二甲酸二（2-乙基己酯）、1份二甘醇和2.1份水投入反应釜中，均匀搅拌至pH值为9.3-9.5； (1) Put 5 parts of formaldehyde, 1 part of bis(2-ethylhexyl phthalate), 1 part of diethylene glycol and 2.1 parts of water into the reaction kettle, and stir evenly until the pH value is 9.3-9.5;
（2）加入5份三聚氰胺，加热至90℃，然后升温至91℃并保温70min，至水溶比为1:2.8； (2) Add 5 parts of melamine, heat to 90°C, then raise the temperature to 91°C and keep it warm for 70min until the water solubility ratio is 1:2.8;
（3）降温至41℃，至水溶比为1:1.4，出料，制得所述三胺胶。 (3) Cool down to 41°C until the water-soluble ratio is 1:1.4, and discharge to obtain the triamine glue.
所述原纸层1的比重为72g/m2；所述印刷木纹层2的比重为2.5g/m2；所述耐磨层3的比重为11g/m2；所述耐磨胶膜层4的比重为92g/m2。 The specific gravity of the base paper layer 1 is 72g/m 2 ; the specific gravity of the printed wood grain layer 2 is 2.5g/m 2 ; the specific gravity of the wear-resistant layer 3 is 11g/m 2 ; the wear-resistant adhesive film layer 4 has a specific gravity of 92 g/m 2 .
实施例3 Example 3
本实施例与上述实施例1的不同之处在于： The difference between this embodiment and the above-mentioned embodiment 1 is:
所述水性油墨由如下重量百分比的原料组成：水性树脂5%、分散剂0.25%、润湿剂0.25%、颜料10%、其它助剂8%，水余量。 The water-based ink is composed of the following raw materials in weight percentage: 5% water-based resin, 0.25% dispersant, 0.25% wetting agent, 10% pigment, 8% other additives, and the balance of water.
所述水性树脂是由水溶性丙烯酸树脂和马来松香改性丙烯酸树脂以重量比3:1组成的混合物；所述分散剂是由六偏磷酸钠、聚丙烯酰胺和十二烷基硫酸钠以重量比2.2:1:1组成的混合物；所述润湿剂是由聚氧乙烯烷基酚醚、聚氧乙烯脂肪醇醚和聚氧乙烯聚氧丙烯嵌段共聚物以重量比1:1:1.8组成的混合物；所述颜料为磷酸钴紫、酞青蓝、酞青绿、炭黑、永固红和联苯胺黄中的至少一种；所述其它助剂是由流平剂、消泡剂和稳定剂以重量比0.3：0.6:1组成的混合物。 The water-based resin is a mixture of water-soluble acrylic resin and maleic rosin modified acrylic resin with a weight ratio of 3:1; the dispersant is composed of sodium hexametaphosphate, polyacrylamide and sodium lauryl sulfate The mixture that weight ratio 2.2:1:1 forms; Described wetting agent is to be by polyoxyethylene alkylphenol ether, polyoxyethylene fatty alcohol ether and polyoxyethylene polyoxypropylene block copolymer with weight ratio 1:1: The mixture of 1.8 composition; Described pigment is at least one in cobalt phosphate violet, phthalocyanine blue, phthalocyanine green, carbon black, permanent red and benzidine yellow; Described other auxiliary agent is made of leveling agent, defoamer and stabilizer in a weight ratio of 0.3:0.6:1.
所述三胺胶包括如下重量份的原料：甲醛6份、三聚氰胺6份、邻苯二甲酸二（2-乙基己酯）1.5份、二甘醇1.8份和水2.8份。 The melamine glue includes the following raw materials in parts by weight: 6 parts of formaldehyde, 6 parts of melamine, 1.5 parts of bis(2-ethylhexyl) phthalate, 1.8 parts of diethylene glycol and 2.8 parts of water.
所述三胺胶的制备方法包括如下步骤： The preparation method of described triamine glue comprises the steps:
（1）取6份甲醛、1.5份邻苯二甲酸二（2-乙基己酯）、1.8份二甘醇和2.8份水投入反应釜中，均匀搅拌至pH值为9.4； (1) Put 6 parts of formaldehyde, 1.5 parts of bis(2-ethylhexyl phthalate), 1.8 parts of diethylene glycol and 2.8 parts of water into the reactor, and stir evenly until the pH value is 9.4;
（2）加入6份三聚氰胺，加热至90℃，然后升温至92℃并保温75min，至水溶比为1:3； (2) Add 6 parts of melamine, heat to 90°C, then raise the temperature to 92°C and keep it warm for 75 minutes until the water solubility ratio is 1:3;
（3）降温至42℃，至水溶比为1:1.5，出料，制得所述三胺胶。 (3) Cool down to 42°C until the water-soluble ratio is 1:1.5, and discharge to obtain the triamine glue.
所述原纸层1的比重为75g/m2；所述印刷木纹层2的比重为3g/m2；所述耐磨层3的比重为12g/m2；所述耐磨胶膜层4的比重为95g/m2。 The specific gravity of the base paper layer 1 is 75g/m 2 ; the specific gravity of the printed wood grain layer 2 is 3g/m 2 ; the specific gravity of the wear-resistant layer 3 is 12g/m 2 ; the wear-resistant adhesive film layer 4 The specific gravity is 95g/m 2 .
实施例4 Example 4
本实施例与上述实施例1的不同之处在于： The difference between this embodiment and the above-mentioned embodiment 1 is:
所述水性油墨由如下重量百分比的原料组成：水性树脂7%、分散剂0.3%、润湿剂0.3%、颜料12%、其它助剂10%，水余量。 The water-based ink is composed of the following raw materials in weight percentage: 7% of water-based resin, 0.3% of dispersant, 0.3% of wetting agent, 12% of pigment, 10% of other additives, and the balance of water.
所述水性树脂是由水溶性丙烯酸树脂和马来松香改性丙烯酸树脂以重量比3.5:1组成的混合物；所述分散剂是由六偏磷酸钠、聚丙烯酰胺和十二烷基硫酸钠以重量比2.4:1.1:1组成的混合物；所述润湿剂是由聚氧乙烯烷基酚醚、聚氧乙烯脂肪醇醚和聚氧乙烯聚氧丙烯嵌段共聚物以重量比1:1.2:2组成的混合物；所述颜料为磷酸钴紫、酞青蓝、酞青绿、炭黑、永固红和联苯胺黄中的至少一种；所述其它助剂是由流平剂、消泡剂和稳定剂以重量比0.4：0.7:1组成的混合物。 The water-based resin is a mixture of water-soluble acrylic resin and maleic rosin modified acrylic resin with a weight ratio of 3.5:1; the dispersant is composed of sodium hexametaphosphate, polyacrylamide and sodium lauryl sulfate The mixture that weight ratio 2.4:1.1:1 is formed; Described wetting agent is by polyoxyethylene alkylphenol ether, polyoxyethylene fatty alcohol ether and polyoxyethylene polyoxypropylene block copolymer with weight ratio 1:1.2: 2 mixtures; the pigment is at least one of cobalt phosphate violet, phthalocyanine blue, phthalocyanine green, carbon black, permanent red and benzidine yellow; the other additives are composed of leveling agent, defoamer and stabilizer in a weight ratio of 0.4:0.7:1.
所述三胺胶包括如下重量份的原料：甲醛7份、三聚氰胺7份、邻苯二甲酸二（2-乙基己酯）2份、二甘醇2.5份和水3.5份。 The melamine glue includes the following raw materials in parts by weight: 7 parts of formaldehyde, 7 parts of melamine, 2 parts of bis(2-ethylhexyl) phthalate, 2.5 parts of diethylene glycol and 3.5 parts of water.
所述三胺胶的制备方法包括如下步骤： The preparation method of described triamine glue comprises the steps:
（1）取7份甲醛、2份邻苯二甲酸二（2-乙基己酯）、2.5份二甘醇和3.5份水投入反应釜中，均匀搅拌至pH值为9.4； (1) Put 7 parts of formaldehyde, 2 parts of bis(2-ethylhexyl phthalate), 2.5 parts of diethylene glycol and 3.5 parts of water into the reaction kettle, and stir evenly until the pH value is 9.4;
（2）加入7份三聚氰胺，加热至90℃，然后升温至91℃并保温80min，至水溶比为1:3.2； (2) Add 7 parts of melamine, heat to 90°C, then raise the temperature to 91°C and keep it warm for 80min until the water solubility ratio is 1:3.2;
（3）降温至44℃，至水溶比为1:1.7，出料，制得所述三胺胶。 (3) Cool down to 44°C until the water-soluble ratio is 1:1.7, and discharge to obtain the triamine glue.
所述原纸层1的比重为78g/m2；所述印刷木纹层2的比重为3.5g/m2；所述耐磨层3的比重为1.4g/m2；所述耐磨胶膜层4的比重为98g/m2。 The specific gravity of the base paper layer 1 is 78g/m 2 ; the specific gravity of the printed wood grain layer 2 is 3.5g/m 2 ; the specific gravity of the wear-resistant layer 3 is 1.4g/m 2 ; the wear-resistant adhesive film Layer 4 has a specific gravity of 98 g/m 2 .
实施例5 Example 5
本实施例与上述实施例1的不同之处在于： The difference between this embodiment and the above-mentioned embodiment 1 is:
所述水性油墨由如下重量百分比的原料组成：水性树脂8%、分散剂0.4%、润湿剂0.4%、颜料13%、其它助剂12%，水余量。 The water-based ink is composed of the following raw materials in weight percentage: 8% water-based resin, 0.4% dispersant, 0.4% wetting agent, 13% pigment, 12% other additives, and the balance of water.
所述水性树脂是由水溶性丙烯酸树脂和马来松香改性丙烯酸树脂以重量比4:1组成的混合物；所述分散剂是由六偏磷酸钠、聚丙烯酰胺和十二烷基硫酸钠以重量比2.6:1.2:1组成的混合物；所述润湿剂是由聚氧乙烯烷基酚醚、聚氧乙烯脂肪醇醚和聚氧乙烯聚氧丙烯嵌段共聚物以重量比1:1.5:2.2组成的混合物；所述颜料为磷酸钴紫、酞青蓝、酞青绿、炭黑、永固红和联苯胺黄中的至少一种；所述其它助剂是由流平剂、消泡剂和稳定剂以重量比0.5：0.8:1组成的混合物。 The water-based resin is a mixture of water-soluble acrylic resin and maleic rosin modified acrylic resin with a weight ratio of 4:1; the dispersant is composed of sodium hexametaphosphate, polyacrylamide and sodium lauryl sulfate. A mixture of weight ratio 2.6:1.2:1; the wetting agent is made of polyoxyethylene alkylphenol ether, polyoxyethylene fatty alcohol ether and polyoxyethylene polyoxypropylene block copolymer in a weight ratio of 1:1.5: 2.2 The mixture of composition; The pigment is at least one of cobalt phosphate violet, phthalocyanine blue, phthalocyanine green, carbon black, permanent red and benzidine yellow; the other additives are composed of leveling agent, defoamer and stabilizer in a weight ratio of 0.5:0.8:1.
所述三胺胶包括如下重量份的原料：甲醛8.5份、三聚氰胺8.0份、邻苯二甲酸二（2-乙基己酯）2.5份、二甘醇3.2份和水4.2份。 The melamine glue includes the following raw materials in parts by weight: 8.5 parts of formaldehyde, 8.0 parts of melamine, 2.5 parts of bis(2-ethylhexyl) phthalate, 3.2 parts of diethylene glycol and 4.2 parts of water.
所述三胺胶的制备方法包括如下步骤： The preparation method of described triamine glue comprises the steps:
（1）取8.5份甲醛、2.5份邻苯二甲酸二（2-乙基己酯）、3.2份二甘醇和4.2份水投入反应釜中，均匀搅拌至pH值为9.5； (1) Put 8.5 parts of formaldehyde, 2.5 parts of bis(2-ethylhexyl phthalate), 3.2 parts of diethylene glycol and 4.2 parts of water into the reactor, and stir evenly until the pH value is 9.5;
（2）加入8.0份三聚氰胺，加热至91℃，然后升温至90-93℃并保温90min，至水溶比为1:3.5； (2) Add 8.0 parts of melamine, heat to 91°C, then raise the temperature to 90-93°C and keep it warm for 90min until the water solubility ratio is 1:3.5;
（3）降温至45℃，至水溶比为1:1.8，出料，制得所述三胺胶。 (3) Cool down to 45°C until the water-soluble ratio is 1:1.8, and discharge to obtain the triamine glue.
所述原纸层1的比重为80g/m2；所述印刷木纹层2的比重为4g/m2；所述耐磨层3的比重为15g/m2；所述耐磨胶膜层4的比重为100g/m2。 The specific gravity of the base paper layer 1 is 80g/m 2 ; the specific gravity of the printed wood grain layer 2 is 4g/m 2 ; the specific gravity of the wear-resistant layer 3 is 15g/m 2 ; the wear-resistant adhesive film layer 4 The specific gravity is 100g/m 2 .
本发明的高耐磨印刷浸渍纸通过在原纸层上设置耐磨胶膜层和耐磨层，使得制造出来的浸渍纸具有良好的耐磨性能，结构简单，成本低，实用性强。 The high wear-resistant printing impregnated paper of the present invention is provided with a wear-resistant adhesive film layer and a wear-resistant layer on the base paper layer, so that the manufactured impregnated paper has good wear resistance, simple structure, low cost and strong practicability.
本发明的制备方法工艺简单，操作控制方便，质量稳定，生产效率高，生产成本低，可大规模工业化生产。 The preparation method of the invention has the advantages of simple process, convenient operation and control, stable quality, high production efficiency, low production cost and large-scale industrial production.
上述实施例为本发明较佳的实现方案，除此之外，本发明还可以其它方式实现，在不脱离本发明构思的前提下任何显而易见的替换均在本发明的保护范围之内。 The above-mentioned embodiments are preferred implementation solutions of the present invention. In addition, the present invention can also be realized in other ways, and any obvious replacements are within the protection scope of the present invention without departing from the concept of the present invention.
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