CN105647603B - A kind of processing method of organic wastewater and its micro emulsion diesel fuel of preparation - Google Patents
A kind of processing method of organic wastewater and its micro emulsion diesel fuel of preparation Download PDFInfo
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- CN105647603B CN105647603B CN201511026473.XA CN201511026473A CN105647603B CN 105647603 B CN105647603 B CN 105647603B CN 201511026473 A CN201511026473 A CN 201511026473A CN 105647603 B CN105647603 B CN 105647603B
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- organic wastewater
- diesel fuel
- micro emulsion
- organic
- emulsifying agent
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- 239000002283 diesel fuel Substances 0.000 title claims abstract description 77
- 239000002351 wastewater Substances 0.000 title claims abstract description 70
- 239000004530 micro-emulsion Substances 0.000 title claims abstract description 47
- 238000003672 processing method Methods 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title description 4
- 239000003960 organic solvent Substances 0.000 claims abstract description 30
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 24
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 16
- 239000000839 emulsion Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 12
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000000654 additive Substances 0.000 claims description 10
- 230000000996 additive effect Effects 0.000 claims description 10
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 claims description 10
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 8
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 8
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 8
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 8
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims description 6
- 239000002736 nonionic surfactant Substances 0.000 claims description 6
- 229920001219 Polysorbate 40 Polymers 0.000 claims description 5
- NWGKJDSIEKMTRX-MDZDMXLPSA-N Sorbitan oleate Chemical compound CCCCCCCC\C=C\CCCCCCCC(=O)OCC(O)C1OCC(O)C1O NWGKJDSIEKMTRX-MDZDMXLPSA-N 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 235000010483 polyoxyethylene sorbitan monopalmitate Nutrition 0.000 claims description 5
- 239000000249 polyoxyethylene sorbitan monopalmitate Substances 0.000 claims description 5
- 229940101027 polysorbate 40 Drugs 0.000 claims description 5
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 4
- HVUMOYIDDBPOLL-UHFFFAOYSA-N 2-(3,4-Dihydroxyoxolan-2-yl)-2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)C1OCC(O)C1O HVUMOYIDDBPOLL-UHFFFAOYSA-N 0.000 claims description 4
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 4
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 claims description 4
- 238000013329 compounding Methods 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 4
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 4
- 229920000053 polysorbate 80 Polymers 0.000 claims description 4
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 3
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 claims description 3
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 claims description 3
- 229940113124 polysorbate 60 Drugs 0.000 claims description 3
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 6
- XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 claims 2
- LWZFANDGMFTDAV-BURFUSLBSA-N [(2r)-2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O LWZFANDGMFTDAV-BURFUSLBSA-N 0.000 claims 2
- -1 polysorbas20 Substances 0.000 claims 2
- 235000011067 sorbitan monolaureate Nutrition 0.000 claims 2
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 14
- 238000012545 processing Methods 0.000 abstract description 9
- 239000002699 waste material Substances 0.000 abstract description 8
- 239000010842 industrial wastewater Substances 0.000 abstract description 7
- 239000002994 raw material Substances 0.000 abstract description 7
- 230000007613 environmental effect Effects 0.000 abstract description 6
- 239000010815 organic waste Substances 0.000 abstract description 6
- 238000004064 recycling Methods 0.000 abstract description 6
- 238000004065 wastewater treatment Methods 0.000 abstract description 5
- 239000002440 industrial waste Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 description 9
- 239000007789 gas Substances 0.000 description 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 239000003208 petroleum Substances 0.000 description 6
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 4
- 239000003463 adsorbent Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 210000000481 breast Anatomy 0.000 description 3
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical class OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 3
- 238000004880 explosion Methods 0.000 description 3
- 239000000976 ink Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000002912 waste gas Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical class CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003546 flue gas Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000013618 particulate matter Substances 0.000 description 2
- 235000013772 propylene glycol Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/32—Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1826—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms poly-hydroxy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2300/00—Mixture of two or more additives covered by the same group of C10L1/00 - C10L1/308
- C10L2300/40—Mixture of four or more components
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Heat Treatment Of Water, Waste Water Or Sewage (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The present invention relates to the recycling technical field of industrial wastewater, more particularly to a kind of processing method of organic wastewater, comprise the following steps：At normal temperatures and pressures, it is added to after organic wastewater, 0# diesel oil, emulsifying agent and auxiliary agent being mixed by proportioning in emulsion reactor, under 3000~8000r/min rotating speed, shears scattered 5~20min, obtain micro emulsion diesel fuel；Organic solvent content in the organic wastewater reaches 10wt%~40wt%；The present invention is using industrial organic waste water as primary raw material, micro emulsion diesel fuel is mixed with 0# diesel oil, emulsifying agent and auxiliary agent, Industrial Wastewater Treatment problem is efficiently solved, reduces the processing cost of manufacturing enterprise's three industrial wastes, veritably realizes the environmental protection policy of " turning waste into wealth "；The invention further relates to micro emulsion diesel fuel prepared by this method, its every quality index is substantially suitable with 0# diesel oil, is that a kind of transparent good, long shelf-life, cost be cheap, environment protecting significantly cleans diesel oil.
Description
Technical field
The present invention relates to the recycling technical field of industrial wastewater, more particularly to a kind of processing method of organic wastewater and
Its micro emulsion diesel fuel prepared.
Background technology
Organic solvent in the manufacturings such as coating, ink, adhesive due to excellent solvability, being used as solvent
Or diluent is widely used；Specifically such as：In the production and process for preparation of oil paint and ink, the usage amount of organic solvent
Account for more than the 60% of coating and total ink；The usage amount of organic solvent is about in adhesive industry, in solvent type adhesive
To 50% with first-class.While a large amount of uses, necessarily lead to substantial amounts of organic wastewater waste gas, will if directly being discharged without processing
Serious environmental pollution is caused, endangers the living environment of the mankind.And with the appearance of all kinds of environmentally friendly laws and regulations, waste water and gas
Discharge receives increasing limitation, its processing cost more and more higher, is gradually evolved into the heavy burden of enterprise, governs enterprise
The further development of industry.Therefore, how to turn waste into wealth, make full use of waste resource, mitigating manufacturing enterprise's burden turns into industry
The problem of one common concern of engineers and technicians.
At this stage, mainly there are burning method and absorption method for the processing method of organic exhaust gas.Burning method is by organic exhaust gas
Directly burn, but directly burning may cause waste gas burning insufficient, produce substantial amounts of toxic and harmful gas, especially meeting
During to effumability fuel gas, it this may result in exploding if reaching its explosion limit and running into naked light, cause accident；Therefore, directly
The method for connecing burning disposal organic exhaust gas is very limited in actual applications.Absorption method is to pass through organic exhaust gas equipped with suction
The adsorption tower of attached dose (such as activated carbon, hydrophobic molecule sieve), it is useless to reach purification to the adsorptivity of organic exhaust gas using adsorbent
The purpose of gas；This method is gentleer, has the advantages that high treating effect, equipment are simple, has been obtained in actual production extensively
Using；But its difficult point is：Adsorbent absorption organic exhaust gas reaches after saturation state, it is necessary to being passed through steam carries out stripping, makes
Adsorbent is freed, and adsorbent is freed will produce substantial amounts of organic wastewater.Therefore, how effectively quick processing organic wastewater turns into
The problem that numerous engineers and technicians face.
At present, organic wastewater is generally handled with directly burning or being distilled to recover the method for organic solvent.It is wherein direct
Burning can realize the harmless treatment of organic wastewater substantially, but there is calorific value caused by organic wastewater burning it is relatively low,
The shortcomings that treatment effeciency is not high, and when organic solvent content is relatively low in waste water, organic wastewater may be caused not burn；Cause
This, the method that organic wastewater directly burns can not fully meet the wastewater treatment demand of manufacturing enterprise.And it is distilled to recover organic molten
The method of agent, it is possible to achieve the recycling of organic solvent, but a variety of organic solvents, Wu Fa are usually contained in organic wastewater
It is separately recovered in single flash；In addition, the method high energy consumption of organic solvent is recovered by distillation, processing cost occupies height always
Under not, and the organic solvent purity that recovery obtains is low, can only typically be used as the cleaning solvent of plant equipment, use range quilt
Limit significantly.Therefore, how to realize the low cost effectively recycling of organic wastewater turns into urgent problem.
The content of the invention
For above-mentioned the deficiencies in the prior art, an object of the present invention is the provision of a kind for the treatment of of Organic Wastewater side
Method；
The second object of the present invention is the micro emulsion diesel fuel for providing above method preparation.
To achieve these goals, technical scheme is as follows：
A kind of processing method of organic wastewater, comprises the following steps：At normal temperatures and pressures, obtained organic waste will be collected
Water, 0# diesel oil, emulsifying agent and auxiliary agent are added in emulsion reactor after being mixed by proportioning, in 3000~8000r/min rotating speed
Under, scattered 5~20min is sheared, obtains micro emulsion diesel fuel；Organic solvent content in wherein described organic wastewater for 10wt%~
40wt%.
The processing method of organic wastewater of the present invention, using industrial organic waste water as primary raw material, with 0# diesel oil, emulsifying agent and helping
Agent is mixed with micro emulsion diesel fuel, efficiently solves Industrial Wastewater Treatment problem, reduces the place of manufacturing enterprise's three industrial wastes
Cost is managed, veritably realizes the environmental protection policy of " turning waste into wealth "；And the micro emulsion diesel fuel production technology letter prepared by the present invention
Single, production equipment less investment, raw material is cheap and easy to get, and petroleum resources can be realized while organic wastewater effective recycling is realized
Clean utilization, be worth in industry be widely popularized.
It is preferred that by weight percentage, the proportioning is 0# diesel oil 60%~90%, organic wastewater 5%~35%, breast
Agent 0.5%~10% and auxiliary agent 0.1%~5%.
It is preferred that the organic wastewater includes water and organic solvent, the organic solvent is acetone, butanone, cyclohexanone, first
One kind or more in benzene, dimethylbenzene, glycol monoethyl ether, propylene glycol monomethyl ether, propylene glycol monomethyl ether acetate, ethyl acetate
Kind.
It is preferred that nonionic surfactant of the emulsifying agent for compounding, the nonionic surfactant is sapn
20th, two kinds in span 40, sorbester p18, sorbester p17, polysorbas20, polysorbate40, polysorbate60, Tween 80, OP-10, EL-10, EL-12
Or a variety of mixtures.
It is preferred that the HLB value (hydrophilic lipophilic balance) of the emulsifying agent is 3~9.
It is preferred that the auxiliary agent includes polar additive, the polar additive be methanol, ethanol, propyl alcohol, isopropanol,
One or more in butanol, amylalcohol, n-hexyl alcohol, 1,2- propane diols, glycerine, ethylene glycol, 1,4- butanediols；The polarity adds
Add agent to help to strengthen interfacial film strength and can improve emulsion property, and the burning to emulsion has obvious combustion-supporting effect, its
It is necessary for being prepared in micro emulsion diesel fuel.
A kind of micro emulsion diesel fuel, by weight percentage, including 0# diesel oil 60%~90%, organic wastewater 5%~35%,
Emulsifying agent 0.5%~10% and auxiliary agent 0.1%~5%；Wherein, the organic solvent content in the organic wastewater reaches 10wt%
~40wt%, i.e. by mass percentage, the content 10%~40% of organic solvent in the organic wastewater.
It is preferred that the organic wastewater includes water and organic solvent, the organic solvent is acetone, butanone, cyclohexanone, first
One kind or more in benzene, dimethylbenzene, glycol monoethyl ether, propylene glycol monomethyl ether, propylene glycol monomethyl ether acetate, ethyl acetate
Kind.
It is preferred that nonionic surfactant of the emulsifying agent for compounding, the nonionic surfactant is sapn
20th, two kinds in span 40, sorbester p18, sorbester p17, polysorbas20, polysorbate40, polysorbate60, Tween 80, OP-10, EL-10, EL-12
Or a variety of mixtures.
It is preferred that the HLB value (hydrophilic lipophilic balance) of the emulsifying agent is 3~9.
It is preferred that the auxiliary agent includes polar additive, the polar additive be methanol, ethanol, propyl alcohol, isopropanol,
One or more in butanol, amylalcohol, n-hexyl alcohol, 1,2- propane diols, glycerine, ethylene glycol, 1,4- butanediols；The polarity adds
Add agent to help to strengthen interfacial film strength and can improve emulsion property, and the burning to emulsion has obvious combustion-supporting effect, its
It is necessary for being prepared in micro emulsion diesel fuel.
Beneficial effects of the present invention：
1. the micro emulsion diesel fuel prepared by the present invention is on the one hand in organic wastewater, emulsifying agent and polar additive low-carbon alcohols
Under effect so that whole profit System forming W/O structures, in burning, effect of micro-explosion can be produced so that micro emulsion diesel fuel can
Secondary-atomizing, so that micro emulsion diesel fuel burning is more complete；On the other hand, due to the presence of water and filling for micro emulsion diesel fuel
Divided combustion, the discharge of the harmful substances such as flue gas, particulate matter, carbon monoxide, nitric oxide can be significantly reduced, be advantageous to environment guarantor
Shield；And the micro emulsion diesel fuel prepared by the present invention is efficiently solved at industrial wastewater using industrial organic waste water as primary raw material
Problem is managed, reduces the processing cost of manufacturing enterprise's three industrial wastes, veritably realizes the environmental protection policy of " turning waste into wealth "；
2. organic wastewater, breast of the micro emulsion diesel fuel prepared by the present invention using organic solvent content as 10wt%~40wt%
The materials such as agent, polar additive instead of 0# diesel oil, and its using effect is suitable with 0# diesel oil；Therefore, can effectively save 10%
Petroleum resources above, be advantageous to alleviate pressure caused by petroleum resources growing tension.
Embodiment
Below in conjunction with specific embodiment, method for processing organic wastewater of the present invention and its micro emulsion diesel fuel being prepared are done
It is further described；It should be understood that following examples are merely to illustrate the present invention not for restriction the scope of the present invention.
Embodiment 1
A kind of processing method of organic wastewater, comprises the following steps：
At normal temperatures and pressures, emulsion reaction is added to after organic wastewater, 0# diesel oil, emulsifying agent and auxiliary agent being mixed by proportioning
In kettle, under 4000r/min rotating speed, scattered 20min is sheared, obtains micro emulsion diesel fuel；
Wherein, obtained micro emulsion diesel fuel, by mass percentage, including：0# diesel oil 65%, organic wastewater 30%, department
Disk 20 1%, sorbester p17 3%, propyl alcohol 1%；Specifically, by mass percentage, the organic solvent content in organic wastewater reaches
To 10%~40%.
Embodiment 2
A kind of processing method of organic wastewater, comprises the following steps：At normal temperatures and pressures, by organic wastewater, 0# diesel oil, breast
Agent and auxiliary agent are added in emulsion reactor after being mixed by proportioning, under 7000r/min rotating speed, are sheared scattered 10min, are obtained
To micro emulsion diesel fuel；
Wherein, obtained micro emulsion diesel fuel, by mass percentage, including：0# diesel oil 60%, organic wastewater 33%, department
Disk 60 4%, polysorbate40 2%, methanol 1%；Specifically, by mass percentage, the organic solvent content in organic wastewater reaches
To 10%~40%.
Embodiment 3
A kind of processing method of organic wastewater, comprises the following steps：
At normal temperatures and pressures, emulsion reaction is added to after organic wastewater, 0# diesel oil, emulsifying agent and auxiliary agent being mixed by proportioning
In kettle, under 5000r/min rotating speed, scattered 8min is sheared, obtains micro emulsion diesel fuel；
Wherein, obtained micro emulsion diesel fuel, by mass percentage, including：0# diesel oil 80%, organic wastewater 12%, department
Disk 40 4%, polysorbas20 1%, 1,4- butanediols 3%；Specifically, by mass percentage, the organic solvent in organic wastewater
Content reaches 10%~40%.
Embodiment 4
A kind of processing method of organic wastewater, comprises the following steps：
At normal temperatures and pressures, emulsion reaction is added to after organic wastewater, 0# diesel oil, emulsifying agent and auxiliary agent being mixed by proportioning
In kettle, under 6000r/min rotating speed, scattered 15min is sheared, obtains micro emulsion diesel fuel；
Wherein, obtained micro emulsion diesel fuel, by mass percentage, including：0# diesel oil 90%, organic wastewater 5%, EL-
10 3%, Tween 80 1%, n-amyl alcohol 1%；Specifically, by mass percentage, the organic solvent content in organic wastewater reaches
To 10%~40%.
Embodiment 5
A kind of processing method of organic wastewater, comprises the following steps：
At normal temperatures and pressures, emulsion reaction is added to after organic wastewater, 0# diesel oil, emulsifying agent and auxiliary agent being mixed by proportioning
In kettle, under 8000r/min rotating speed, scattered 20min is sheared, obtains micro emulsion diesel fuel；
Wherein, obtained micro emulsion diesel fuel, by mass percentage, including：0# diesel oil 73%, organic wastewater 21%, EL-
12 4%, OP-10 1%, n-hexyl alcohol 1%；Specifically, by mass percentage, the organic solvent content in organic wastewater reaches
10%~40%.
Micro emulsion diesel fuel made from above-described embodiment and 0# diesel oil are subjected to performance test, its performance data is compared as follows table
Shown in 1.
Table 1
As described in Table 1, the micro emulsion diesel fuel items quality index prepared by the present invention and 0# diesel oil are substantially suitable, storage 6
The problems such as water-oil separating, rotten, discoloration does not occur for more than individual month, it is that a kind of good transparency, long shelf-life, cost are cheap, environmentally friendly
Significant effect cleans diesel oil.
In summary, the processing method of organic wastewater of the present invention, using industrial organic waste water as primary raw material, with 0# diesel oil,
Emulsifying agent and auxiliary agent are mixed with micro emulsion diesel fuel, efficiently solve Industrial Wastewater Treatment problem, reduce manufacturing enterprise's work
The processing cost of the industry three wastes, veritably realize the environmental protection policy of " turning waste into wealth "；And the processing method of organic wastewater of the present invention
Simple production process, production equipment less investment, raw material is cheap and easy to get, can be real while organic wastewater effective recycling is realized
Existing petroleum resources clean utilization, are worth in industry being widely popularized.
The environmental benefit of micro emulsion diesel fuel prepared by the present invention：On the one hand added in organic wastewater, emulsifying agent and polarity
In the presence of agent low-carbon alcohols so that whole profit System forming W/O structures, in burning, effect of micro-explosion can be produced so that micro emulsion
Change diesel oil can secondary-atomizing so that micro emulsion diesel fuel burning it is more complete；On the other hand, the presence due to water and micro emulsion
Change the abundant burning of diesel oil, the discharge of the harmful substances such as flue gas, particulate matter, carbon monoxide, nitric oxide can be significantly reduced, had
Beneficial to environmental protection；And the micro emulsion diesel fuel prepared by the present invention efficiently solves using industrial organic waste water as primary raw material
Industrial Wastewater Treatment problem, the processing cost of manufacturing enterprise's three industrial wastes is reduced, veritably realize the ring of " turning waste into wealth "
Protect policy；
The economic benefit of micro emulsion diesel fuel prepared by the present invention：Using organic solvent content having as 10wt%~40wt%
The materials such as machine waste water, emulsifying agent, auxiliary agent instead of 0# diesel oil, and its using effect is suitable with 0# diesel oil；Therefore, can be effectively save
More than 10% petroleum resources, be advantageous to alleviate pressure caused by petroleum resources growing tension.
Above-described embodiment, simply presently preferred embodiments of the present invention, is not used for limiting the scope of the present invention, therefore all with this
The equivalent change or modification that construction, feature and principle described in invention claim are done, all should be included in right of the present invention will
Within the scope of asking.
Claims (10)
1. a kind of processing method of organic wastewater, it is characterised in that comprise the following steps：At normal temperatures and pressures, collection is obtained
Organic wastewater, 0# diesel oil, emulsifying agent and auxiliary agent by proportioning mix after be added in emulsion reactor, in 3000~8000r/
Under min rotating speed, scattered 5~20min is sheared, obtains micro emulsion diesel fuel；Organic solvent content in wherein described organic wastewater
For 10wt%~40wt%.
2. the processing method of organic wastewater according to claim 1, it is characterised in that：By weight percentage, the proportioning
For 0# diesel oil 60%~90%, organic wastewater 5%~35%, emulsifying agent 0.5%~10% and auxiliary agent 0.1%~5%.
3. the processing method of organic wastewater according to claim 1, it is characterised in that：The organic wastewater includes water and organic
Solvent, the organic solvent are acetone, butanone, cyclohexanone, toluene, dimethylbenzene, glycol monoethyl ether, propylene glycol monomethyl ether, third
One or more in glycol monomethyl ether acetate, ethyl acetate.
4. the processing method of organic wastewater according to claim 1, it is characterised in that：The emulsifying agent is the nonionic of compounding
Surfactant, the nonionic surfactant are span 20, span 40, sorbester p18, sorbester p17, polysorbas20, polysorbate40, told
Two or more mixtures in temperature 60, Tween 80, OP-10, EL-10, EL-12.
5. the processing method of organic wastewater according to claim 1, it is characterised in that：The auxiliary agent includes polar additive,
The polar additive is methanol, ethanol, propyl alcohol, isopropanol, butanol, amylalcohol, n-hexyl alcohol, 1,2-PD, glycerine, second two
One or more in alcohol, BDO.
A kind of 6. micro emulsion diesel fuel, it is characterised in that：By weight percentage, including 0# diesel oil 60%~90%, organic wastewater
5%~35%, emulsifying agent 0.5%~10% and auxiliary agent 0.1%~5%；Wherein, the organic solvent content in the organic wastewater
Reach 10wt%~40wt%；
The organic wastewater includes water and organic solvent, the organic solvent be acetone, butanone, cyclohexanone, toluene, dimethylbenzene,
One or more in glycol monoethyl ether, propylene glycol monomethyl ether, propylene glycol monomethyl ether acetate, ethyl acetate.
7. micro emulsion diesel fuel according to claim 6, it is characterised in that：The micro emulsion diesel fuel is made by following methods：Will
The organic wastewater, the 0# diesel oil, the emulsifying agent and the auxiliary agent are added in emulsion reactor after being mixed by proportioning, in
Under 3000~8000r/min rotating speed, scattered 5~20min is sheared, obtains the micro emulsion diesel fuel.
8. micro emulsion diesel fuel according to claim 6, it is characterised in that：The emulsifying agent is the non-ionic surface active of compounding
Agent, the nonionic surfactant are span 20, span 40, sorbester p18, sorbester p17, polysorbas20, polysorbate40, polysorbate60, told
Two or more mixtures in temperature 80, OP-10, EL-10, EL-12.
9. micro emulsion diesel fuel according to claim 6, it is characterised in that：The HLB value of the emulsifying agent is 3~9.
10. micro emulsion diesel fuel according to claim 6, it is characterised in that：The auxiliary agent includes polar additive, the polarity
Additive be methanol, ethanol, propyl alcohol, isopropanol, butanol, amylalcohol, n-hexyl alcohol, 1,2-PD, glycerine, ethylene glycol, Isosorbide-5-Nitrae-
One or more in butanediol.
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| AU9734401A (en) * | 2000-12-20 | 2002-06-27 | Lifnex Pty Ltd | A fuel |
| JP2003013076A (en) * | 2001-06-28 | 2003-01-15 | Takeshi Arakawa | Fuel oil and its production method |
| TW589369B (en) * | 2001-07-11 | 2004-06-01 | Kune-Muh Tsai | Emulsion fuel oil additive |
| CN100344737C (en) * | 2003-12-24 | 2007-10-24 | 上海精微粉溶机械设备有限公司 | Water-in-oil organic waste liquid emulsified fuel oil and method for preparing same |
| CN1869168A (en) * | 2006-06-27 | 2006-11-29 | 姜建华 | Blended diesel oil and its preparation method |
| CN101838567A (en) * | 2010-02-03 | 2010-09-22 | 珠海中水环保科技有限公司 | Biomass type desulfurized and emulsified heavy oil fuel |
| CN102719288A (en) * | 2012-01-01 | 2012-10-10 | 洛阳维琦太阳能技术有限公司 | Heavy oil or diesel oil synthesized from papermaking waste liquid and method for treating papermaking waste liquid |
| CN103642548B (en) * | 2013-12-25 | 2015-11-18 | 济南开发区星火科学技术研究院 | A kind of micro emulsion diesel fuel |
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