CN105623179A - Anti-yellowing halogen-free flame retardant thermoplastic elastomer and preparation method thereof - Google Patents
Anti-yellowing halogen-free flame retardant thermoplastic elastomer and preparation method thereof Download PDFInfo
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- CN105623179A CN105623179A CN201510917888.XA CN201510917888A CN105623179A CN 105623179 A CN105623179 A CN 105623179A CN 201510917888 A CN201510917888 A CN 201510917888A CN 105623179 A CN105623179 A CN 105623179A
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- thermoplastic elastomer
- halogen
- free flame
- retardant thermoplastic
- color inhibition
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 64
- 229920002725 thermoplastic elastomer Polymers 0.000 title claims abstract description 57
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 238000004383 yellowing Methods 0.000 title abstract description 10
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 title abstract 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000000463 material Substances 0.000 claims abstract description 32
- 239000003921 oil Substances 0.000 claims abstract description 22
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 21
- 239000010703 silicon Substances 0.000 claims abstract description 21
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 12
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 229920001971 elastomer Polymers 0.000 claims abstract description 12
- 239000005060 rubber Substances 0.000 claims abstract description 11
- 238000011049 filling Methods 0.000 claims abstract description 10
- 239000000314 lubricant Substances 0.000 claims abstract description 9
- 229920006124 polyolefin elastomer Polymers 0.000 claims abstract description 5
- 230000005764 inhibitory process Effects 0.000 claims description 43
- 150000003440 styrenes Chemical class 0.000 claims description 20
- 238000002156 mixing Methods 0.000 claims description 19
- 229920005989 resin Polymers 0.000 claims description 17
- 239000011347 resin Substances 0.000 claims description 17
- 239000002994 raw material Substances 0.000 claims description 16
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- 239000003963 antioxidant agent Substances 0.000 claims description 11
- 230000003078 antioxidant effect Effects 0.000 claims description 11
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 10
- 239000005977 Ethylene Substances 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 10
- 229920006465 Styrenic thermoplastic elastomer Polymers 0.000 claims description 9
- 239000003086 colorant Substances 0.000 claims description 9
- 239000000945 filler Substances 0.000 claims description 9
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- -1 styrene-ethylene-butylene-styrene Chemical group 0.000 claims description 9
- 229920001577 copolymer Polymers 0.000 claims description 8
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 7
- ZJOLCKGSXLIVAA-UHFFFAOYSA-N ethene;octadecanamide Chemical compound C=C.CCCCCCCCCCCCCCCCCC(N)=O.CCCCCCCCCCCCCCCCCC(N)=O ZJOLCKGSXLIVAA-UHFFFAOYSA-N 0.000 claims description 7
- 238000002347 injection Methods 0.000 claims description 7
- 239000007924 injection Substances 0.000 claims description 7
- 238000001746 injection moulding Methods 0.000 claims description 7
- 238000005453 pelletization Methods 0.000 claims description 7
- 229920001169 thermoplastic Polymers 0.000 claims description 7
- 239000004416 thermosoftening plastic Substances 0.000 claims description 7
- 229920000428 triblock copolymer Polymers 0.000 claims description 7
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 claims description 6
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical group C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 6
- 239000012965 benzophenone Substances 0.000 claims description 6
- 238000002485 combustion reaction Methods 0.000 claims description 6
- 235000019304 dilauryl thiodipropionate Nutrition 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 6
- YTXCAJNHPVBVDJ-UHFFFAOYSA-N octadecyl propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CC YTXCAJNHPVBVDJ-UHFFFAOYSA-N 0.000 claims description 6
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 6
- 229940124543 ultraviolet light absorber Drugs 0.000 claims description 6
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 6
- 239000003508 Dilauryl thiodipropionate Substances 0.000 claims description 5
- ZTOCZRQYNNKUDA-UHFFFAOYSA-N OCC(CO)(CO)CO.C(C)(C)(C)C=1C(=C(C=C(C1)C(C)(C)C)CCC(=O)O)O Chemical compound OCC(CO)(CO)CO.C(C)(C)(C)C=1C(=C(C=C(C1)C(C)(C)C)CCC(=O)O)O ZTOCZRQYNNKUDA-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 claims description 4
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical group O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- 235000014692 zinc oxide Nutrition 0.000 claims description 4
- 230000003712 anti-aging effect Effects 0.000 claims description 3
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims description 3
- DUWWHGPELOTTOE-UHFFFAOYSA-N n-(5-chloro-2,4-dimethoxyphenyl)-3-oxobutanamide Chemical compound COC1=CC(OC)=C(NC(=O)CC(C)=O)C=C1Cl DUWWHGPELOTTOE-UHFFFAOYSA-N 0.000 claims description 3
- 229940059574 pentaerithrityl Drugs 0.000 claims description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- DXGIRFAFSFKYCF-UHFFFAOYSA-N propanehydrazide Chemical compound CCC(=O)NN DXGIRFAFSFKYCF-UHFFFAOYSA-N 0.000 claims description 3
- 235000019260 propionic acid Nutrition 0.000 claims description 3
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 2
- RNDPRJBLDRFSEY-UHFFFAOYSA-N [Ni].C(CCC)N.C(C)(C)(CC(C)(C)C)C1=CC=C(C=C1)O Chemical compound [Ni].C(CCC)N.C(C)(C)(CC(C)(C)C)C1=CC=C(C=C1)O RNDPRJBLDRFSEY-UHFFFAOYSA-N 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 239000012752 auxiliary agent Substances 0.000 claims description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 2
- 239000008116 calcium stearate Substances 0.000 claims description 2
- 235000013539 calcium stearate Nutrition 0.000 claims description 2
- 239000010779 crude oil Substances 0.000 claims description 2
- SEQVSYFEKVIYCP-UHFFFAOYSA-L magnesium hypophosphite Chemical compound [Mg+2].[O-]P=O.[O-]P=O SEQVSYFEKVIYCP-UHFFFAOYSA-L 0.000 claims description 2
- 229910001381 magnesium hypophosphite Inorganic materials 0.000 claims description 2
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 claims description 2
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 2
- 238000012360 testing method Methods 0.000 abstract description 8
- 238000009413 insulation Methods 0.000 abstract description 3
- 230000032683 aging Effects 0.000 abstract description 2
- 238000004513 sizing Methods 0.000 abstract description 2
- 239000000806 elastomer Substances 0.000 abstract 1
- 239000002131 composite material Substances 0.000 description 15
- 239000006096 absorbing agent Substances 0.000 description 5
- UWSMKYBKUPAEJQ-UHFFFAOYSA-N 5-Chloro-2-(3,5-di-tert-butyl-2-hydroxyphenyl)-2H-benzotriazole Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O UWSMKYBKUPAEJQ-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- TWDJIKFUVRYBJF-UHFFFAOYSA-N Cyanthoate Chemical compound CCOP(=O)(OCC)SCC(=O)NC(C)(C)C#N TWDJIKFUVRYBJF-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 206010051246 Photodermatosis Diseases 0.000 description 1
- XDMNVWYLTWJFPH-UHFFFAOYSA-N [N].[P].[P] Chemical group [N].[P].[P] XDMNVWYLTWJFPH-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 150000008301 phosphite esters Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000008845 photoaging Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
- B29C2948/9259—Angular velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to an anti-yellowing halogen-free flame retardant thermoplastic elastomer and a preparation method thereof. The elastomer comprises the following components in parts by weight: 100 parts of a styrene thermoplastic elastomer, 20 to 60 parts of rubber filling oil, 5 to 20 parts of a polyolefin elastomer, 20 to 60 parts of a phosphorus-nitrogenous flame retardant, 5 to 15 parts of flame-retardant silicon master batch, 0.1 to 1.8 parts of a lubricating agent, 0.45 to 0.6 part of an aging resisting agent, 0.01 to 5 parts of an anti-yellowing agent, and 1 to 8 parts of other assistants. The invention further provides a preparation method of the anti-yellowing halogen-free flame retardant thermoplastic elastomer. Wires prepared from the anti-yellowing halogen-free flame retardant thermoplastic elastomer provided by the invention are excellent in anti-yellowing property, the CIELAB color difference is smaller than 1, the wires can be resistant to UV grade IV or above, and a sizing material of the anti-yellowing halogen-free flame retardant thermoplastic elastomer is environment-friendly and good in flame retardant property, various properties like insulation and sheath of the wires are excellent, and the flame retardant property passes VW-1 test; besides, the wires are mainly applied to consumer electronics product wires, such as data lines, earphone lines and the like.
Description
Technical field
The present invention relates to the insulation of the consumer electronics products such as a kind of data wire, earphone cord and sheath technical field, particularly relating to a kind of color inhibition halogen-free flame-retardant thermoplastic elastomer and preparation method thereof, this color inhibition halogen-free flame-retardant thermoplastic elastomer has good fire resistance and anti-yellowing property.
Background technology
Thermoplastic elastomer (TPE) is a kind of tartan with rubber and plastic properties, due to especially excellent flexibility, comfortableness, applies more and more extensive in recent years. In electrical type consumer products, styrene analog thermoplastic elastomer cable requires to occupy a tiny space on high-end data wire at some. Styrene analog thermoplastic elastomer itself there is also some shortcomings, such as: the easy xanthochromia of white or light styrene analog thermoplastic elastomer, affects the outward appearance of material; Styrene analog thermoplastic elastomer oxygen index (OI) after oil-filled is extremely low, belongs to combustible material. Wire rod in consumer electronics product and new-energy automobile field all faces heat, photoaging causes the xanthochromia of wire rod, simultaneously for high-end consumption electronic product, environmental protection and fire-retardant problem is also had significantly high requirement.
Summary of the invention
An object of the present invention is in that for the problems referred to above, it is provided that a kind of color inhibition halogen-free flame-retardant thermoplastic elastomer, this color inhibition halogen-free flame-retardant thermoplastic elastomer has good fire resistance and anti-yellowing property.
The two of the purpose of the present invention are in that the preparation method providing above-mentioned color inhibition halogen-free flame-retardant thermoplastic elastomer.
To achieve the above object of the invention, a kind of color inhibition halogen-free flame-retardant thermoplastic elastomer provided by the present invention, with parts by weight, its composition of raw materials is made up of following component:
In a preferred embodiment of the invention, described styrene analog thermoplastic elastomer is styrene-ethylene-butylene-styrene triblock copolymer, and styrene mass content is 10-45%.
In a preferred embodiment of the invention, described polyolefin elastomer includes ethylene and one or more the mixing in vinyl acetate copolymer, ethylene and acrylate copolymer, ethylene and hexene copolymer, ethylene and octene copolymer.
In a preferred embodiment of the invention, described rubber filling oil is technical white oil or naphthene base crude oil.
In a preferred embodiment of the invention, described polyolefin elastomer is selected from TAFMER resin or Exact resin, if vistanex is the DF840 resin in TAFMER series; 8201 resins in Exact series. TAFMER resin is the resin that Mitsui chemical company produces, and Exact resin provides for Exxon Mobil Corporation, all can buy from market.
In a preferred embodiment of the invention, described color inhibition agent is benzophenone type ultraviolet light absorber, 2-(2'-hydroxyl-3', 5'-di-tert-butyl phenyl) the one or any two or more mixture of the following material such as-5-chlorobenzotriazole, 2,2-thiobiss (4-tert-octyl phenol) n-butylamine nickel salt.
The present invention selects fire-retardant silicon master batch and the composite use of phosphor nitrogen combustion inhibitor. In flame-retardant system of the present invention, fire-retardant silicon master batch can be polymerized with styrene analog thermoplastic elastomer, vistanex, has again an oozing property mutually, and can promote the generation of carbon-coating, and then stops spreading of flame. Phosphor nitrogen combustion inhibitor because having promoted the carbonization of phosphorus in the existence of nitrogen component, therefore there is phosphorus phosphorus-nitrogen coordinated fire-retardant effect, with the fire-retardant mechanism of gas phase fire retardant and condensed phase, and not halogen-containing, also not adopting stibium oxide is synergist, when phosphor nitrogen combustion inhibitor and silicon master batch fire retardant join use in polymer, material surface can generate one layer of uniform carbonaceous foam layer, effect heat insulation, oxygen barrier can be played, and prevent molten drop phenomenon, there is fabulous anti-flammability.
In a preferred embodiment of the invention, described phosphor nitrogen combustion inhibitor is hypophosphites or melamine cyanurate. Described hypophosphites includes hypo-aluminum orthophosphate or magnesium hypophosphite etc. It addition, melamine cyanurate is as a kind of nitrogenated flame retardant, based on gas phase fire retardant mechanism.
In a preferred embodiment of the invention, the concentration of the silicon polymer in described fire-retardant silicon master batch is 30-50%, and described silicon polymer is linear or branching polysiloxanes.
In a preferred embodiment of the invention, described lubricant is the one or any two or more mixture in ethylene bis stearic acid amide, ethylene double; two oleamide, zinc stearate, calcium stearate, Tissuemat E. The effect of lubricant is to make this material be prone to processing, will not adhesion in machine barrel.
In a preferred embodiment of the invention; described antiaging agent is �� (3'5'-di-t-butyl-4'-hydroxy phenyl) propanoic acid octadecyl ester, four [3-(3; 5-di-tert-butyl-hydroxy phenyl) propanoic acid] tetramethylolmethane, tricresyl phosphite (2; 4-di-tert-butyl ester group), dilauryl thiodipropionate, 1; 2-[��-(3; 5-di-t-butyl-4 hydroxyl) phenyl] propionyl hydrazine, one or any two or more mixture in N, N'-diacetyl adipyl two hydrazides. The effect of antiaging agent is the aging life-span extending this material.
In a preferred embodiment of the invention, other auxiliary agent described is the mixing of a kind of in filler, coloring agent, antioxidant or any two kinds.
In a preferred embodiment of the invention, described filler is one or more the mixing that Petropols, high styrene resin, ancient horse rise in resin, calcium carbonate.
In a preferred embodiment of the invention, described coloring agent is a kind of or arbitrarily two or more mixing in titanium dioxide, Griffith's zinc white., zinc oxide, toner.
In a preferred embodiment of the invention, described antioxidant is selected from (�� (3'5'-di-t-butyl-4'-hydroxy phenyl) propanoic acid octadecyl ester, four [3-(3,5-di-tert-butyl-hydroxy phenyl) propanoic acid] tetramethylolmethane, tricresyl phosphite (2,4-di-tert-butyl ester group), or arbitrarily two or more mixing in dilauryl thiodipropionate.
As the preparation method of the color inhibition halogen-free flame-retardant thermoplastic elastomer of second aspect present invention, it comprises the following steps:
1) each raw material is weighed by formula;
2) elastic for styrene analog thermoplastic being sufficiently mixed with rubber filling oil under 50 DEG C of conditions is obtained oil-filled good styrenic thermoplastic elastomer;
3) oil-filled good styrenic thermoplastic elastomer is mixed 30-60 minute with other raw materials in horizontal mixer the material obtaining mixing;
4) material that the material of mixing is extruded in double screw extruder is carried out tie rod, cooling, pelletizing, be subsequently poured in injection moulding machine injection mo(u)lding, place stable.
In a preferred embodiment of the invention, described step 4) in, each section of temperature of described extruder is from charge door, it is followed successively by 150��160 DEG C, 175��190 DEG C, 190��200 DEG C, 200��210 DEG C, 210��220 DEG C, 200��210 DEG C, head temperature 210��215 DEG C, engine speed is 300-600r/min.
Compared with prior art, present invention have the advantage that
(1) present invention adopts color inhibition UV absorbers, be aided with phosphite ester kind antioxidant, phenolic antioxidant etc. composition antioxidant, take into account the heat-resisting xanthochromia of material and the requirement of fast light xanthochromia simultaneously, CIELAB color difference less than 1, uv-resistant more than 4 grades;
(2) flame-retardant system of the present invention is by composite use phosphor nitrogen combustion inhibitor and fire-retardant silicon master batch, and styrene analog thermoplastic elastomer material has the excellent mechanical property of comparison and a fire resistance while reaching UL94V-0 grade, fire-retardant reaches VO level;
(3) fire proofing of the present invention is environmentally friendly, and during burning, low cigarette is without molten drop, will not discharge toxic gas, and production process is safe and reliable.
Detailed description of the invention
Make specifically to describe in detail further to the inventive method with embodiment below.
The formula of embodiment 1 to embodiment 5 is in Table 1
Embodiment 1
Composition and part by weight according to the color inhibition halogen-free flame-retardant thermoplastic elastomer in embodiment 1 in table 1 weigh each raw material; Wherein styrene analog thermoplastic elastomer is styrene-ethylene-butylene-styrene triblock copolymer, and styrene-content is 30%; The concentration of the silicon polymer in fire-retardant silicon master batch is 40%; Lubricant ethylene bis stearic acid amide; Vistanex is DF840; Color inhibition agent is benzophenone type ultraviolet light absorber; What filler was Petropols with calcium carbonate is composite, and mass ratio between the two is 3:2; Antioxidant be four [3-(3,5-di-tert-butyl-hydroxy phenyl) propanoic acid] tetramethylolmethane, tricresyl phosphite (2,4-di-tert-butyl ester group), dilauryl thiodipropionate composite, the mass ratio before three is 1:2:1; Coloring agent is toner.
The step of the preparation method of the color inhibition halogen-free flame-retardant thermoplastic elastomer of this embodiment is as follows:
1) styrene analog thermoplastic elasticity is sufficiently mixed with rubber filling oil under 50 DEG C of conditions;
2) oil-filled good styrenic thermoplastic elastomer is mixed 30-60 minute with other raw materials in horizontal mixer;
3) material that the material of mixing is extruded in double screw extruder is carried out tie rod, cooling, pelletizing, be subsequently poured in injection moulding machine injection mo(u)lding, place stable, test mechanical performance and the fire resistance of this material. Each section of temperature of extruder, from charge door, is followed successively by 150��160 DEG C, 175��190 DEG C, 190��200 DEG C, 200��210 DEG C, 210��220 DEG C, 200��210 DEG C, and head temperature 210��215 DEG C, engine speed is 400r/min.
Embodiment 2
Composition and part by weight according to the color inhibition halogen-free flame-retardant thermoplastic elastomer in embodiment 2 in table 1 weigh each raw material; Wherein styrene analog thermoplastic elastomer is styrene-ethylene-butylene-styrene triblock copolymer, and styrene-content is 40%; The concentration of the silicon polymer in fire-retardant silicon master batch is 45%; Lubricant ethylene bis stearic acid amide, vistanex is DF840; Color inhibition agent be benzophenone type ultraviolet light absorber and 2-(2'-hydroxyl-3', 5'-di-tert-butyl phenyl)-5-chlorobenzotriazole UV absorbers composite, mass ratio between the two is 1: 1; Filler be Petropols, high styrene resin, calcium carbonate composite, the mass ratio 2:1:1 of three; Antioxidant be tricresyl phosphite (2,4-di-tert-butyl ester group), both dilauryl thiodipropionates composite, the mass ratio of the two is 2:1; Coloring agent is toner.
The step of the preparation method of the color inhibition halogen-free flame-retardant thermoplastic elastomer of this embodiment is as follows:
1) styrene analog thermoplastic elasticity is sufficiently mixed with rubber filling oil under 50 DEG C of conditions;
2) oil-filled good styrenic thermoplastic elastomer is mixed 30-60 minute with other raw materials in horizontal mixer;
3) material that the material of mixing is extruded in double screw extruder is carried out tie rod, cooling, pelletizing, be subsequently poured in injection moulding machine injection mo(u)lding, place stable, test mechanical performance and the fire resistance of this material. Each section of temperature of extruder, from charge door, is followed successively by 150��160 DEG C, 175��190 DEG C, 190��200 DEG C, 200��210 DEG C, 210��220 DEG C, 200��210 DEG C, and head temperature 210��215 DEG C, engine speed is 300r/min.
Embodiment 3
Each raw material is weighed according to the composition of color inhibition halogen-free flame-retardant thermoplastic elastomer in embodiment 3 in table 1 and part by weight; Wherein styrene analog thermoplastic elastomer is styrene-ethylene-butylene-styrene triblock copolymer, and styrene-content is 40%; The concentration of the silicon polymer in fire-retardant silicon master batch is 45%; Lubricant ethylene bis stearic acid amide; Vistanex is 8210; Color inhibition agent is 2-(2'-hydroxyl-3', 5'-di-tert-butyl phenyl)-5-chlorobenzotriazole UV absorbers, filler be Petropols, ancient horse rise resin, calcium carbonate three composite, the mass ratio 2:1:1 of three; Antioxidant be �� (3'5'-di-t-butyl-4'-hydroxy phenyl) propanoic acid octadecyl ester, 1,2-[��-(3,5-di-t-butyl-4 hydroxyl) phenyl] propionyl hydrazine, N, N'-diacetyl adipyl two hydrazides three composite, the mass ratio of three is 1:1:2; Coloring agent is toner.
The step of the preparation method of the color inhibition halogen-free flame-retardant thermoplastic elastomer of this embodiment is as follows:
1) styrene analog thermoplastic elasticity is sufficiently mixed with rubber filling oil under 50 DEG C of conditions;
2) oil-filled good styrenic thermoplastic elastomer is mixed 30-60 minute with other raw materials in horizontal mixer;
3) material that the material of mixing is extruded in double screw extruder is carried out tie rod, cooling, pelletizing, be subsequently poured in injection moulding machine injection mo(u)lding, place stable, test mechanical performance and the fire resistance of this material. Each section of temperature of extruder, from charge door, is followed successively by 150��160 DEG C, 175��190 DEG C, 190��200 DEG C, 200��210 DEG C, 210��220 DEG C, 200��210 DEG C, and head temperature 210��215 DEG C, engine speed is 350r/min.
Embodiment 4
Each raw material is weighed according to the composition of color inhibition halogen-free flame-retardant thermoplastic elastomer in embodiment 4 in table 1 and part by weight; Wherein styrene analog thermoplastic elastomer is styrene-ethylene-butylene-styrene triblock copolymer, and styrene-content is 40%; The concentration of the silicon polymer in fire-retardant silicon master batch is 45%; Lubricant ethylene bis stearic acid amide; Vistanex is 8210, described color inhibition agent be benzophenone type ultraviolet light absorber and 2-(2'-hydroxyl-3', 5'-di-tert-butyl phenyl)-5-chlorobenzotriazole UV absorbers composite, mass ratio between the two is 2:3; Filler is that ancient horse rises the composite of resin and calcium carbonate, and mass ratio between the two is 2:3; Antioxidant be �� (3'5'-di-t-butyl-4'-hydroxy phenyl) propanoic acid octadecyl ester, four [3-(3,5-di-tert-butyl-hydroxy phenyl) propanoic acid] both tetramethylolmethane acid calcium composite, mass ratio between the two is 2:1; Coloring agent is toner.
The step of the preparation method of the color inhibition halogen-free flame-retardant thermoplastic elastomer of this embodiment is as follows:
1) styrene analog thermoplastic elasticity is sufficiently mixed with rubber filling oil under 50 DEG C of conditions;
2) oil-filled good styrenic thermoplastic elastomer is mixed 30-60 minute with other raw materials in horizontal mixer;
3) material that the material of mixing is extruded in double screw extruder is carried out tie rod, cooling, pelletizing, be subsequently poured in injection moulding machine injection mo(u)lding, place stable, test mechanical performance and the fire resistance of this material. Each section of temperature of extruder, from charge door, is followed successively by 150��160 DEG C, 175��190 DEG C, 190��200 DEG C, 200��210 DEG C, 210��220 DEG C, 200��210 DEG C, and head temperature 210��215 DEG C, engine speed is 400r/min.
Embodiment 5
Each raw material is weighed according to the composition of color inhibition halogen-free flame-retardant thermoplastic elastomer in embodiment 5 in table 1 and part by weight; Wherein styrene analog thermoplastic elastomer is styrene-ethylene-butylene-styrene triblock copolymer, and styrene-content is 40%; The concentration of the silicon polymer in fire-retardant silicon master batch is 45%; Lubricant ethylene bis stearic acid amide, vistanex is DF840 and 8210 interworking, color inhibition agent be benzophenone type ultraviolet light absorber and 2-(2'-hydroxyl-3', 5'-di-tert-butyl phenyl)-5-chlorobenzotriazole UV absorbers composite, mass ratio between the two is 3:2; Filler is the composite of Petropols, high styrene resin and calcium carbonate three, the mass ratio 2:1:1 of three; Antioxidant be four [3-(3,5-di-tert-butyl-hydroxy phenyl) propanoic acid] tetramethylolmethane, both N, N'-diacetyl adipyl two hydrazides composite, mass ratio between the two is 1:2; Coloring agent is toner.
The step of the preparation method of the color inhibition halogen-free flame-retardant thermoplastic elastomer of this embodiment is as follows:
1) styrene analog thermoplastic elasticity is sufficiently mixed with rubber filling oil under 50 DEG C of conditions;
2) oil-filled good styrenic thermoplastic elastomer is mixed 30-60 minute with other raw materials in horizontal mixer;
3) material that the material of mixing is extruded in double screw extruder is carried out tie rod, cooling, pelletizing, be subsequently poured in injection moulding machine injection mo(u)lding, place stable, test mechanical performance and the fire resistance of this material. Each section of temperature of extruder, from charge door, is followed successively by 150��160 DEG C, 175��190 DEG C, 190��200 DEG C, 200��210 DEG C, 210��220 DEG C, 200��210 DEG C, and head temperature 210��215 DEG C, engine speed is 350r/min.
The performance test results of the thermoplastic elastomer (TPE) sample Related product in embodiment 1-5 is in Table 2:
Note: yellowness index test experiments condition: light source UV-A340 lamp, irradiance: 0.76w/m2
At black standard temperature 60 DEG C �� 3 DEG C, irradiation exposes 8h;
4h is exposed without irradiation condensation at blackness standard 50 DEG C �� 3 DEG C;
Experimental period: 96h
By test result above it can be seen that color inhibition index �� E��1.5 are 4-5 level levels above, anti-yellowing property highlights, and sizing material halogen-free environmental and fire resistance are good, and each performance of wire rod aspect is better than, and fire-retardant can pass through VW-1.
The invention is not limited in above-mentioned detailed description of the invention, be familiar with the research staff of the art and also can make multiple change according to this, but any be equal to the present invention or similar change all should be contained within the scope of the claims.
Claims (17)
1. a color inhibition halogen-free flame-retardant thermoplastic elastomer, it is characterised in that with parts by weight, its composition of raw materials is made up of following component:
2. a kind of color inhibition halogen-free flame-retardant thermoplastic elastomer as claimed in claim 1, it is characterised in that described styrene analog thermoplastic elastomer is styrene-ethylene-butylene-styrene triblock copolymer, and styrene mass content is 10-45%.
3. a kind of color inhibition halogen-free flame-retardant thermoplastic elastomer as claimed in claim 1, it is characterized in that, described polyolefin elastomer includes ethylene and one or more the mixing in vinyl acetate copolymer, ethylene and acrylate copolymer, ethylene and hexene copolymer, ethylene and octene copolymer.
4. a kind of color inhibition halogen-free flame-retardant thermoplastic elastomer as claimed in claim 1, it is characterised in that described rubber filling oil is technical white oil or naphthene base crude oil.
5. a kind of color inhibition halogen-free flame-retardant thermoplastic elastomer as claimed in claim 1, it is characterised in that described polyolefin elastomer is selected from TAFMER resin or Exact resin.
6. a kind of color inhibition halogen-free flame-retardant thermoplastic elastomer as claimed in claim 1, it is characterized in that, described color inhibition agent is benzophenone type ultraviolet light absorber, 2-(2'-hydroxyl-3', 5'-di-tert-butyl phenyl) the one or any two or more mixture of the following material such as-5-chlorobenzotriazole, 2,2-thiobiss (4-tert-octyl phenol) n-butylamine nickel salt.
7. a kind of color inhibition halogen-free flame-retardant thermoplastic elastomer as claimed in claim 1, it is characterised in that described phosphor nitrogen combustion inhibitor is hypophosphites or melamine cyanurate.
8. a kind of color inhibition halogen-free flame-retardant thermoplastic elastomer as claimed in claim 7, it is characterised in that described hypophosphites includes hypo-aluminum orthophosphate or magnesium hypophosphite.
9. a kind of color inhibition halogen-free flame-retardant thermoplastic elastomer as claimed in claim 1, it is characterised in that the concentration of the silicon polymer in described fire-retardant silicon master batch is 30-50%, and described silicon polymer is linear or branching polysiloxanes.
10. a kind of color inhibition halogen-free flame-retardant thermoplastic elastomer as claimed in claim 1, it is characterized in that, described lubricant is the one or any two or more mixture in ethylene bis stearic acid amide, ethylene double; two oleamide, zinc stearate, calcium stearate, Tissuemat E.
11. a kind of color inhibition halogen-free flame-retardant thermoplastic elastomer as claimed in claim 1; it is characterized in that; described antiaging agent is �� (3'5'-di-t-butyl-4'-hydroxy phenyl) propanoic acid octadecyl ester, four [3-(3; 5-di-tert-butyl-hydroxy phenyl) propanoic acid] tetramethylolmethane, tricresyl phosphite (2; 4-di-tert-butyl ester group), dilauryl thiodipropionate, 1; 2-[��-(3; 5-di-t-butyl-4 hydroxyl) phenyl] propionyl hydrazine, one or any two or more mixture in N, N'-diacetyl adipyl two hydrazides.
12. color inhibition halogen-free flame-retardant thermoplastic elastomer as claimed in claim 1 a kind of, it is characterised in that other auxiliary agent described is the mixing of a kind of in filler, coloring agent, antioxidant or any two kinds.
13. color inhibition halogen-free flame-retardant thermoplastic elastomer as claimed in claim 12 a kind of, it is characterised in that described filler is one or more the mixing that Petropols, high styrene resin, ancient horse rise in resin, calcium carbonate.
14. a kind of color inhibition halogen-free flame-retardant thermoplastic elastomer as claimed in claim 12, it is characterised in that described coloring agent is a kind of or arbitrarily two or more mixing in titanium dioxide, Griffith's zinc white., zinc oxide, toner.
15. a kind of color inhibition halogen-free flame-retardant thermoplastic elastomer as claimed in claim 12, it is characterized in that, described antioxidant is selected from (�� (3'5'-di-t-butyl-4'-hydroxy phenyl) propanoic acid octadecyl ester, four [3-(3,5-di-tert-butyl-hydroxy phenyl) propanoic acid] tetramethylolmethane, tricresyl phosphite (2,4-di-tert-butyl ester group), or arbitrarily two or more mixing in dilauryl thiodipropionate.
16. the preparation method of the color inhibition halogen-free flame-retardant thermoplastic elastomer described in claim 1 to 15 any one claim, it is characterised in that comprise the following steps:
1) each raw material is weighed by formula;
2) elastic for styrene analog thermoplastic being sufficiently mixed with rubber filling oil under 50 DEG C of conditions is obtained oil-filled good styrenic thermoplastic elastomer;
3) oil-filled good styrenic thermoplastic elastomer is mixed 30-60 minute with other raw materials in horizontal mixer the material obtaining mixing;
4) material that the material of mixing is extruded in double screw extruder is carried out tie rod, cooling, pelletizing, be subsequently poured in injection moulding machine injection mo(u)lding, place stable.
17. preparation method as claimed in claim 16, it is characterized in that, described step 4) in, each section of temperature of described extruder is from charge door, it is followed successively by 150��160 DEG C, 175��190 DEG C, 190��200 DEG C, 200��210 DEG C, 210��220 DEG C, 200��210 DEG C, head temperature 210��215 DEG C, engine speed is 300-600r/min.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006117823A1 (en) * | 2005-04-29 | 2006-11-09 | So.F.Ter. Spa | Self-extinguishing thermoplastic elastomeric material for filling synthetic surfaces designed for recreational-sports activities, in particular football fields |
| CN101100593A (en) * | 2007-05-22 | 2008-01-09 | 深圳职业技术学院 | Environment-friendly SEBS thermoplastic elastomer sealing strip material and preparation method thereof |
| CN103289286A (en) * | 2012-02-28 | 2013-09-11 | 五行材料科技（江苏）有限公司 | Novel halogen-free flame-retardant thermoplastic elastomer material and preparation method thereof |
| CN104530654A (en) * | 2014-12-24 | 2015-04-22 | 上海至正道化高分子材料股份有限公司 | Flame-retardant TPE outer sheath material for new-energy charging cable, preparation method and TPE outer sheath |
| CN104559020A (en) * | 2014-12-31 | 2015-04-29 | 东莞市技塑塑胶科技有限公司 | Special halogen-free anti-static flame-retardant material for TPE (thermal plastic elastomer) molding and preparation method for special halogen-free anti-static flame-retardant material |
| CN105038087A (en) * | 2015-08-19 | 2015-11-11 | 深圳市沃尔核材股份有限公司 | Halogen-free flame retardant high-tear-resistance wire and cable compound for electric vehicles and wire and cable production method |
-
2015
- 2015-12-10 CN CN201510917888.XA patent/CN105623179A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006117823A1 (en) * | 2005-04-29 | 2006-11-09 | So.F.Ter. Spa | Self-extinguishing thermoplastic elastomeric material for filling synthetic surfaces designed for recreational-sports activities, in particular football fields |
| CN101100593A (en) * | 2007-05-22 | 2008-01-09 | 深圳职业技术学院 | Environment-friendly SEBS thermoplastic elastomer sealing strip material and preparation method thereof |
| CN103289286A (en) * | 2012-02-28 | 2013-09-11 | 五行材料科技（江苏）有限公司 | Novel halogen-free flame-retardant thermoplastic elastomer material and preparation method thereof |
| CN104530654A (en) * | 2014-12-24 | 2015-04-22 | 上海至正道化高分子材料股份有限公司 | Flame-retardant TPE outer sheath material for new-energy charging cable, preparation method and TPE outer sheath |
| CN104559020A (en) * | 2014-12-31 | 2015-04-29 | 东莞市技塑塑胶科技有限公司 | Special halogen-free anti-static flame-retardant material for TPE (thermal plastic elastomer) molding and preparation method for special halogen-free anti-static flame-retardant material |
| CN105038087A (en) * | 2015-08-19 | 2015-11-11 | 深圳市沃尔核材股份有限公司 | Halogen-free flame retardant high-tear-resistance wire and cable compound for electric vehicles and wire and cable production method |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110527315A (en) * | 2018-05-23 | 2019-12-03 | 天津泰煜辉新材料科技有限公司 | A kind of high-elasticity halogen-free flame-resistant thermoplastic elastomer and preparation method thereof |
| CN110835468A (en) * | 2018-08-16 | 2020-02-25 | 欧菲影像技术（广州）有限公司 | Thermoplastic elastomer composition, preparation method and application thereof |
| CN110835468B (en) * | 2018-08-16 | 2022-02-22 | 欧菲影像技术（广州）有限公司 | Thermoplastic elastomer composition, preparation method and application thereof |
| CN109206829A (en) * | 2018-08-22 | 2019-01-15 | 宁波市青湖弹性体科技有限公司 | A kind of resistance to precipitation halogen-free flame-retardant thermoplastic elastomer composition of high yellowing-resistant and preparation method thereof |
| CN109206829B (en) * | 2018-08-22 | 2020-12-01 | 宁波市青湖弹性体科技有限公司 | High-yellowing-resistance precipitation-resistance halogen-free flame-retardant thermoplastic elastomer composition and preparation method thereof |
| CN109749334A (en) * | 2018-12-11 | 2019-05-14 | 广东聚石化学股份有限公司 | A kind of halogen-free flame-retardant thermoplastic elastomer and its preparation method and application of the anti-UV of xenon lamp |
| CN109851922A (en) * | 2019-03-14 | 2019-06-07 | 东莞市汇泽实业有限公司 | A kind of V0 flame retardant rating heat discoloration thermoplastic elastomer (TPE) TPE and preparation method thereof |
| CN111286109A (en) * | 2020-04-17 | 2020-06-16 | 上海赛科石油化工有限责任公司 | Preparation method of anti-yellowing high-density polyethylene |
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Application publication date: 20160601 |