CN105623095A - Modified polypropylene material for electric vehicle - Google Patents
Modified polypropylene material for electric vehicle Download PDFInfo
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- CN105623095A CN105623095A CN201610104824.2A CN201610104824A CN105623095A CN 105623095 A CN105623095 A CN 105623095A CN 201610104824 A CN201610104824 A CN 201610104824A CN 105623095 A CN105623095 A CN 105623095A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/005—Additives being defined by their particle size in general
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical Kinetics & Catalysis (AREA)
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- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a modified polypropylene material for an electric vehicle and a preparing method of the modified polypropylene material.Raw materials including, by weight, 100-120 parts of polypropylene, 15-30 parts of metallocene polyolefin elastomer, 3-6 parts of glass fibers, 5-15 parts of a modified nanometer filling material, 8-14 parts of ethylene bis stearamide, 0.5-0.9 part of chlorinated polyethylene and 0.2-0.6 part of an antioxidant are weighed, wherein the modified nanometer filling material is obtained by modifying a nanometer filling material with alkyl alkoxyl siloxane, the nanometer filling material is prepared by mixing mica, silicon carbide and boron nitride at 5:1:1 by weight, and the weight ratio of the nanometer filling material to alkyl alkoxyl siloxane is 89:1.According to the modified polypropylene material for the electric vehicle and the preparing method of the modified polypropylene material, on the basis that the original performance of a polypropylene material is ensured, the flying stone impact resistance and scratch resistance of the modified polypropylene material are improved the surface tension and the paint adhesive force of the modified polypropylene material are improved, and the modified polypropylene material is especially suitable for serving as materials for accessories of the electric vehicle.
Description
Technical field
The present invention relates to a kind of modified polypropylene material, particularly relate to a kind of electric motor car modified polypropylene material and preparation method thereof.
Background technology
1873, Englishman's Robert's Dai Weisen one-shot battery was used as power and has invented electric automobile, but does not list the affirming score of the world in. Generally acknowledge that first electric automobile was born in 1881 in the world, invention artificial France engineer Gustaf Te Lufu, this is one is the tricycle of power with lead-acid battery, occurs in that the electric motor car as electric power of NI-G, Ni-MH battery, lithium ion battery, fuel cell later successively.
Electric motor car in the market refers to the max. speed pure electric vehicle lower than 50 kilometers/hour, includes electric sightseeing vehicle, electric golf cart, electric patrol car, electric sanitation truck, electric transporting vehicle, electrically propelled traction vehicle, electronic engineering truck, mobility scooter for old people and extraordinary repacking electric motor car etc. Due to characteristics such as simple to operate, the broad view of electric motor car, practical, pollution-free, low energy consumption, increasingly it is widely applied to the regional place such as large-scale parks, scenic spot, closing community, villa quarter, holiday village, garden type hotel, city walking street at present.
Polypropylene (PP) is one of five big general-purpose plastics, and its yield is only second to PE and PVC and occupies the 3rd, is widely used in the fields such as automobile, Aero-Space, electronic apparatus, packaging, construction material and medical apparatus and instruments. Polypropylene abundance, cheap; Having good mechanical performance, electrical insulating property is good and the advantage such as stress crack resistant, and also has good chemical stability, and processing and forming easily, can be used for injecting, extrudes and the multiple method such as hollow molding, can make various products expeditiously. But polypropylene has the disadvantage in that the pending methyl group on l) building block reduces the pliability of chain, and spherocrystal granule is bigger so that it is brittle, and impact resistance is poor, high temperature rigid deficiency. 2) it is a kind of non-polar polymer, its dyeability, caking property, antistatic behaviour and all poor with inorganic phase capacitive. 3) machine-shaping shrinkage factor is big, and the dimensional stability of its goods is relatively low. 4) ageing-resistant degradation property is poor. These shortcomings limit the application of the polypropylene raw material as some target product (including injection grade, fibre-grade, film-grade etc.) or PP Pipe Compound. Accordingly, it would be desirable to improve its combination property, in order to it is carried out the exploitation of the degree of depth.
Additionally, the surface of polypropylene modified material is easy to, under the shock of foreign body (such as slungshot), partial fracture occurs, expose the mineral powder filled inside matrix, under slungshot clashes into, namely produce white point. And the surface of some parts of electric motor car is highly susceptible to the shock of slungshot in using environment, and electric motor car parts also usually inevitably collide with hard thing in transport and use procedure, and produce cut on surface thus affecting the outward appearance of product. Therefore how to improve the anti-slungshot impact of polypropylene material, anti-scratch performance also just causes increasing concern.
Additionally, owing to polypropylene material is non-polar material, surface can be low, make the poor compatibility of itself and most polymers, not easily infiltration, bonding and printing, paintability is poor, as when using in the electric motor car parts of paint spraying, will be low with the adhesion strength of paint because of it, and certain methods must be adopted to improve its polarity. It addition, for some electric motor car parts, it is sometimes desirable to carry out bonding with other materials, it is also desirable to polypropylene material has good adhesive property. Usual plastic part is in order to improve material surface tension, namely PASS is improved, before application, firstly the need of carrying out surface treatment, the dust greasy dirt of antistatic and absorption is eliminated by solvent, carry out surface modification with flame, corona discharge, surfactant, gas plasma etc., improve the polar group on surface, strengthen coating adhesion. This kind of technological difficulties be should be formed uniform surface, again can not overtreating, otherwise can cause the polymer chain scission on surface, thus the performance affected, the polarity therefore improving polypropylene material becomes an extremely attractive problem.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art, it is provided that a kind of modified polypropylene material, this polypropylene material has the anti-slungshot impact of excellence, anti-scratch performance, and has surface tension and the PASS of raising.
Technical scheme is as follows: a kind of electric motor car modified polypropylene material, and raw materials by weight portion weighs:
Polypropylene 100��120 parts, metallocene polyolefin elastomers 15��30 parts, glass fibre 3��6 parts, modified Nano packing material 5��15 parts, ethylene bis stearamide 8��14 parts, chlorinated polyethylene 0.5��0.9 part, 0.2��0.6 part of antioxidant.
Described antioxidant is selected from ��-(4-hydroxy phenyl-3,5-di-t-butyl) positive octadecanol ester of propanoic acid, four [��-(3,5-di-tert-butyl-hydroxy phenyl) propanoic acid] pentaerythritol ester or their mixture.
Described modified Nano packing material is to be obtained via alkylakoxysiloxanes is modified by nano-composite material, and wherein nano-composite material is mixed by weight 5:1:1 by Muscovitum, carborundum, boron nitride; The weight ratio of described nano-composite material and alkylakoxysiloxanes is 89:1.
Described nano-composite material particle size is 5��200nm, it is preferable that 10��150nm, more preferably 10nm��100nm, it is particularly preferred to 15��30nm.
Described alkylakoxysiloxanes is selected from below general formula:
Wherein group R1And R3It is C independently of one another1-C18Alkyl, its can comprise have one or more selected from N, O, Cl, P and S series heteroatomic substituent group, group R2Identical or different and R2It is hydrogen atom or there is 1-6 carbon atom, it is preferable that there is the alkyl of 1 or 2 carbon atom, i.e. methyl or ethyl, and (n+m) represents have 2-50, it is preferable that 2-30, it is particularly preferred to 3-20, be in particular the oligomeric degree of the numerical value of 3-15. These are advantageously has 2-50 (all numerical value between including), it is preferable that the average degree of oligomerisation of 2-30, average molar mass is preferably the oligomer mixture of 300-10000g/mol (all numerical value between including). This silane low polymer can exist as line style, ring-type and/or branching unit. The molal weight of described oligomer or the determination of average molar mass can such as carry out by means of gpc analysis.
The method of modifying of described modified Nano packing material, comprises the steps: to add 1 weight portion alkylakoxysiloxanes formation solvent in 150 pbw acetone; 89 weight portion nano-composite materials are added in above-mentioned solvent, ultrasonic disperse 5 minutes; Put into 60 DEG C of dry 24h of drying baker, allow acetone fully be evaporated; Finally solid pressure is carefully sifted out through molecular sieve.
Technical scheme farther includes, the preparation method of a kind of electric motor car modified polypropylene material, comprises the steps:
1. weigh polypropylene, metallocene polyolefin elastomers, glass fibre, modified Nano packing material, ethylene bis stearamide, chlorinated polyethylene, antioxidant in proportion, then mix 8-15 minute under the rotating speed of high-speed mixer 500-800 rev/min;
2. the material that 1. step mixes is thrown in double screw extruder, melt extrude, prepare nano modification PP electric four-wheel vehicle and strengthen aging resistance PP Pipe Compound.
Wherein double-screw extruder screw rotating speed is 300-600 rev/min, and extrusion temperature is 180-240 DEG C.
The invention has the beneficial effects as follows:
The present invention, by adopting alkylakoxysiloxanes that the packing material containing super hard nano granule is modified, makes polypropylene material have the anti-slungshot impact of excellence, anti-scratch performance, and has surface tension and the PASS of raising. Modified polypropylene material case hardness is more than 76HA, and surface tension is more than 42Dynes/cm, is particularly suitable for application as electric accessory motor material.
Detailed description of the invention
Below in conjunction with being that the invention will be further described for embodiment.
Embodiment 1
Polypropylene 100 parts, metallocene polyolefin elastomers 15 parts, glass fibre 3 parts, modified Nano packing material 5 parts, ethylene bis stearamide 9 parts, chlorinated polyethylene 0.5 part, 0.2 part of antioxidant.
Described antioxidant is four [��-(3,5-di-tert-butyl-hydroxy phenyl) propanoic acid] pentaerythritol ester.
Described modified Nano packing material is to be obtained via alkylakoxysiloxanes is modified by nano-composite material, and wherein nano-composite material is mixed by weight 5:1:1 by Muscovitum, carborundum, boron nitride; The weight ratio of described nano-composite material and alkylakoxysiloxanes is 89:1.
Prepare electric motor car modified polypropylene material as steps described below:
1. weigh polypropylene, metallocene polyolefin elastomers, glass fibre, modified Nano packing material, ethylene bis stearamide, chlorinated polyethylene, antioxidant in proportion, then mix 8-15 minute under the rotating speed of high-speed mixer 500-800 rev/min;
2. the material that 1. step mixes is thrown in double screw extruder, melt extrude, prepare nano modification PP electric four-wheel vehicle and strengthen aging resistance PP Pipe Compound.
Wherein double-screw extruder screw rotating speed is 300-600 rev/min, and extrusion temperature is 180-240 DEG C.
Embodiment 2
Polypropylene 115 parts, metallocene polyolefin elastomers 25 parts, glass fibre 5 parts, modified Nano packing material 10 parts, ethylene bis stearamide 11 parts, chlorinated polyethylene 0.8 part, 0.4 part of antioxidant.
Described antioxidant is ��-(4-hydroxy phenyl-3,5-di-t-butyl) positive octadecanol ester of propanoic acid.
Described modified Nano packing material is to be obtained via alkylakoxysiloxanes is modified by nano-composite material, and wherein nano-composite material is mixed by weight 5:1:1 by Muscovitum, carborundum, boron nitride; The weight ratio of described nano-composite material and alkylakoxysiloxanes is 89:1.
Processing step is with embodiment 1.
Embodiment 3
Polypropylene 120 parts, metallocene polyolefin elastomers 25 parts, glass fibre 6 parts, modified Nano packing material 15 parts, ethylene bis stearamide 12 parts, chlorinated polyethylene 0.9 part, 0.6 part of antioxidant.
Antioxidant is selected from four [��-(3,5-di-tert-butyl-hydroxy phenyl) propanoic acid] pentaerythritol ester.
Described modified Nano packing material is to be obtained via alkylakoxysiloxanes is modified by nano-composite material, and wherein nano-composite material is mixed by weight 5:1:1 by Muscovitum, carborundum, boron nitride; The weight ratio of described nano-composite material and alkylakoxysiloxanes is 89:1.
Processing step is with embodiment 1.
Comparative example 1
Polypropylene 115 parts, metallocene polyolefin elastomers 25 parts, glass fibre 5 parts, nano-composite material 10 parts, ethylene bis stearamide 11 parts, chlorinated polyethylene 0.8 part, 0.4 part of antioxidant.
Described antioxidant is ��-(4-hydroxy phenyl-3,5-di-t-butyl) positive octadecanol ester of propanoic acid.
Described nano-composite material is mixed by weight 5:1:1 by Muscovitum, carborundum, boron nitride.
Processing step is with embodiment 1.
Comparative example 2
Polypropylene 115 parts, metallocene polyolefin elastomers 25 parts, glass fibre 5 parts, nano mica 10 parts, ethylene bis stearamide 11 parts, chlorinated polyethylene 0.8 part, 0.4 part of antioxidant.
Described antioxidant is ��-(4-hydroxy phenyl-3,5-di-t-butyl) positive octadecanol ester of propanoic acid.
Processing step is with embodiment 1.
Above-described embodiment, comparative example the performance test results:
Note: each test event is all undertaken by concerned countries standard
Above-described embodiment is the present invention preferably embodiment; but embodiments of the present invention are also not restricted to the described embodiments; the change made under other any spirit without departing from the present invention and principle, modification, replacement, combination, simplification; all should be the substitute mode of equivalence, be included within protection scope of the present invention.
Claims (4)
1. an electric motor car modified polypropylene material, raw materials by weight portion weighs: polypropylene 100��120 parts, metallocene polyolefin elastomers 15��30 parts, glass fibre 3��6 parts, modified Nano packing material 5��15 parts, ethylene bis stearamide 8��14 parts, chlorinated polyethylene 0.5��0.9 part, 0.2��0.6 part of antioxidant; Described modified Nano packing material is to be obtained via alkylakoxysiloxanes is modified by nano-composite material, and wherein nano-composite material is mixed by weight 5:1:1 by Muscovitum, carborundum, boron nitride; The weight ratio of described nano-composite material and alkylakoxysiloxanes is 89:1; Described alkylakoxysiloxanes is selected from below general formula:
Wherein group R1And R3It is C independently of one another2-C16Alkyl, its can comprise have one or more selected from N, O, Cl, P and S series heteroatomic substituent group, group R2Identical or different and R2Being hydrogen atom or have 1-6 carbon atom, n+m represents the oligomeric degree with 2-50 numerical value; Described alkylakoxysiloxanes is average molar mass is the oligomer mixture of 300-10000g/mol.
2. electric motor car modified polypropylene material as claimed in claim 1, it is characterised in that: R in described alkyl alkoxy silica formula2For methyl or ethyl, n+m represents the oligomeric degree with 3-15 numerical value.
3. electric motor car modified polypropylene material as claimed in claim 1, it is characterized in that: antioxidant is selected from ��-(4-hydroxy phenyl-3,5-di-t-butyl) the positive octadecanol ester of propanoic acid, four [��-(3,5-di-tert-butyl-hydroxy phenyl) propanoic acid] pentaerythritol ester or their mixture.
4. the preparation method of electric motor car modified polypropylene material as described in as arbitrary in claim 1-3, carries out as steps described below:
1. weigh polypropylene, metallocene polyolefin elastomers, glass fibre, modified Nano packing material, ethylene bis stearamide, chlorinated polyethylene, antioxidant in proportion, then mix 8-15 minute under the rotating speed of high-speed mixer 500-800 rev/min;
2. the material that 1. step mixes is thrown in double screw extruder, melt extrude, prepare electric motor car modified polypropylene material;
Wherein double-screw extruder screw rotating speed is 300-600 rev/min, and extrusion temperature is 180-240 DEG C.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610104824.2A CN105623095A (en) | 2016-02-25 | 2016-02-25 | Modified polypropylene material for electric vehicle |
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| CN201610104824.2A CN105623095A (en) | 2016-02-25 | 2016-02-25 | Modified polypropylene material for electric vehicle |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107513219A (en) * | 2017-09-20 | 2017-12-26 | 阜南县鲲鹏塑业科技有限公司 | A kind of preparation method of easy dyeing plastic master batch |
| CN111087685A (en) * | 2019-12-17 | 2020-05-01 | 会通新材料股份有限公司 | High-polarity modified master batch and preparation method and application thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1678664A (en) * | 2002-08-22 | 2005-10-05 | 德古萨公司 | Composition acting as coupling agent for filled and peroxidically crosslinking rubber compounds |
| CN101067032A (en) * | 2007-06-11 | 2007-11-07 | 浙江大学 | A kind of composite modified polypropylene and preparation method thereof |
| CN101885875A (en) * | 2010-08-06 | 2010-11-17 | 常州市曙光车业有限公司 | Formula of raw materials used for manufacturing automotive plastic parts |
| CN103030882A (en) * | 2012-12-04 | 2013-04-10 | 合肥杰事杰新材料股份有限公司 | Recycled material for preparing vehicle bumper and preparation method of such recycled material |
| CN104194146A (en) * | 2014-08-06 | 2014-12-10 | 惠州市沃特新材料有限公司 | Polypropylene composition and preparation method thereof |
| CN104629190A (en) * | 2015-02-09 | 2015-05-20 | 杭州波达塑料科技股份有限公司 | Modified polypropylene composite material for cable guides and preparation method thereof |
| CN105153541A (en) * | 2015-08-31 | 2015-12-16 | 苏州莱特复合材料有限公司 | Car steering wheel composite material and preparation method thereof |
-
2016
- 2016-02-25 CN CN201610104824.2A patent/CN105623095A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1678664A (en) * | 2002-08-22 | 2005-10-05 | 德古萨公司 | Composition acting as coupling agent for filled and peroxidically crosslinking rubber compounds |
| CN101067032A (en) * | 2007-06-11 | 2007-11-07 | 浙江大学 | A kind of composite modified polypropylene and preparation method thereof |
| CN101885875A (en) * | 2010-08-06 | 2010-11-17 | 常州市曙光车业有限公司 | Formula of raw materials used for manufacturing automotive plastic parts |
| CN103030882A (en) * | 2012-12-04 | 2013-04-10 | 合肥杰事杰新材料股份有限公司 | Recycled material for preparing vehicle bumper and preparation method of such recycled material |
| CN104194146A (en) * | 2014-08-06 | 2014-12-10 | 惠州市沃特新材料有限公司 | Polypropylene composition and preparation method thereof |
| CN104629190A (en) * | 2015-02-09 | 2015-05-20 | 杭州波达塑料科技股份有限公司 | Modified polypropylene composite material for cable guides and preparation method thereof |
| CN105153541A (en) * | 2015-08-31 | 2015-12-16 | 苏州莱特复合材料有限公司 | Car steering wheel composite material and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107513219A (en) * | 2017-09-20 | 2017-12-26 | 阜南县鲲鹏塑业科技有限公司 | A kind of preparation method of easy dyeing plastic master batch |
| CN111087685A (en) * | 2019-12-17 | 2020-05-01 | 会通新材料股份有限公司 | High-polarity modified master batch and preparation method and application thereof |
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