CN105616186B - Refill of eyebrow pencil and preparation method thereof - Google Patents
Refill of eyebrow pencil and preparation method thereof Download PDFInfo
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- CN105616186B CN105616186B CN201610050646.XA CN201610050646A CN105616186B CN 105616186 B CN105616186 B CN 105616186B CN 201610050646 A CN201610050646 A CN 201610050646A CN 105616186 B CN105616186 B CN 105616186B
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- Prior art keywords
- refill
- eyebrow
- powder
- iron oxide
- chalk
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- 210000004709 eyebrow Anatomy 0.000 title claims abstract description 66
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 77
- 239000000843 powder Substances 0.000 claims abstract description 67
- 229920000881 Modified starch Polymers 0.000 claims description 64
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 60
- IEKHISJGRIEHRE-UHFFFAOYSA-N 16-methylheptadecanoic acid;propan-2-ol;titanium Chemical compound [Ti].CC(C)O.CC(C)CCCCCCCCCCCCCCC(O)=O.CC(C)CCCCCCCCCCCCCCC(O)=O.CC(C)CCCCCCCCCCCCCCC(O)=O IEKHISJGRIEHRE-UHFFFAOYSA-N 0.000 claims description 55
- 239000004368 Modified starch Substances 0.000 claims description 46
- 239000003086 colorant Substances 0.000 claims description 46
- 235000019426 modified starch Nutrition 0.000 claims description 46
- 239000003755 preservative agent Substances 0.000 claims description 46
- 230000002335 preservative effect Effects 0.000 claims description 46
- 239000004094 surface-active agent Substances 0.000 claims description 46
- 239000008367 deionised water Substances 0.000 claims description 32
- 229910021641 deionized water Inorganic materials 0.000 claims description 32
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 32
- 229940100486 rice starch Drugs 0.000 claims description 31
- 239000006185 dispersion Substances 0.000 claims description 28
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 28
- 238000000227 grinding Methods 0.000 claims description 26
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 claims description 26
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 22
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 20
- 229960005323 phenoxyethanol Drugs 0.000 claims description 20
- 239000003945 anionic surfactant Substances 0.000 claims description 17
- 238000001035 drying Methods 0.000 claims description 17
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 16
- 238000001125 extrusion Methods 0.000 claims description 16
- 238000002156 mixing Methods 0.000 claims description 16
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 claims description 16
- MXOAEAUPQDYUQM-QMMMGPOBSA-N (S)-chlorphenesin Chemical compound OC[C@H](O)COC1=CC=C(Cl)C=C1 MXOAEAUPQDYUQM-QMMMGPOBSA-N 0.000 claims description 14
- NCZPCONIKBICGS-UHFFFAOYSA-N 3-(2-ethylhexoxy)propane-1,2-diol Chemical compound CCCCC(CC)COCC(O)CO NCZPCONIKBICGS-UHFFFAOYSA-N 0.000 claims description 14
- 229960003993 chlorphenesin Drugs 0.000 claims description 14
- 238000007599 discharging Methods 0.000 claims description 14
- 229940100524 ethylhexylglycerin Drugs 0.000 claims description 14
- 239000002736 nonionic surfactant Substances 0.000 claims description 14
- 239000004408 titanium dioxide Substances 0.000 claims description 8
- 239000004288 Sodium dehydroacetate Substances 0.000 claims description 4
- 229940079839 sodium dehydroacetate Drugs 0.000 claims description 4
- 235000019259 sodium dehydroacetate Nutrition 0.000 claims description 4
- DSOWAKKSGYUMTF-GZOLSCHFSA-M sodium;(1e)-1-(6-methyl-2,4-dioxopyran-3-ylidene)ethanolate Chemical compound [Na+].C\C([O-])=C1/C(=O)OC(C)=CC1=O DSOWAKKSGYUMTF-GZOLSCHFSA-M 0.000 claims description 4
- 238000010009 beating Methods 0.000 claims description 2
- 238000009740 moulding (composite fabrication) Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 12
- 241001391944 Commicarpus scandens Species 0.000 abstract description 9
- 239000002537 cosmetic Substances 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract description 2
- 238000002464 physical blending Methods 0.000 abstract description 2
- 239000002253 acid Substances 0.000 abstract 1
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 abstract 1
- 239000002994 raw material Substances 0.000 description 12
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
- 239000011737 fluorine Substances 0.000 description 4
- 229910052731 fluorine Inorganic materials 0.000 description 4
- 239000004519 grease Substances 0.000 description 3
- ANZUDYZHSVGBRF-UHFFFAOYSA-N 3-ethylnonane-1,2,3-triol Chemical compound CCCCCCC(O)(CC)C(O)CO ANZUDYZHSVGBRF-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 230000009471 action Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention relates to a refill of a eyebrow chalk and a preparation method thereof. Fluorophlogopite powder is introduced into the refill to enhance the cohesion of the refill, so that the problem that the refill of the eyebrow chalk is easy to break is solved; the toner treated by the triisostearic acid titanium isopropoxide salt is used for improving the skin-adhering property, so that the cosmetic effect is more skin-adhering natural. A water system is adopted in the system, and the wax base and the oil component are not contained, so that the effect of easy makeup removal is achieved, and meanwhile, the product obtained by the physical blending method can realize the concept of green, safety and environmental protection.
Description
Technical Field
The invention relates to a refill of a cosmetic pencil for eyebrow parts and a preparation method thereof, in particular to a refill of an eyebrow chalk which is not easy to break and a preparation method thereof.
Background
The eyebrow chalk is a cosmetic for drawing eyebrows, and eyebrow powder drawn by rubbing in the eyebrow chalk can be naturally and uniformly filled in gaps between eyebrows, so that the cosmetic effect is natural. Meanwhile, the eyebrow chalk is fine and smooth in quality and free of wax and oil, so that the eyebrow shape of the user is exquisite and clear from the beginning to the end of the painting from the first second on the painting, and the eyebrow chalk is zero in halation and free of color change.
However, the refill of the eyebrow chalk is easy to break, which increases the subsequent processing cost, and also causes the customer to greatly reduce the usability, so that the problem of improving the refill of the eyebrow chalk is urgent. Meanwhile, the existing eyebrow chalk has the phenomenon that the material is not easy to be fed after the base makeup is used, so that the makeup effect is not adhered to the skin and is unnatural. Therefore, the quality problem of the eyebrow chalk is particularly improved.
Aiming at the problems that the refill of the eyebrow chalk is easy to break and the dressing effect is not adhered to the skin, the refill of the eyebrow chalk which is not easy to break and has the dressing effect of being adhered to the skin naturally is developed by technical personnel in the field to develop the application of eyebrow products.
Disclosure of Invention
In order to solve the technical defect that the refill of the eyebrow chalk is easy to break, the fluorophlogopite powder is added into the refill of the eyebrow chalk in a blending mode, and the cohesion of the refill is increased through the hydrogen bond action of fluorine elements, so that the problem that the refill is easy to break is solved.
The invention aims to provide a refill of eyebrow chalk, which contains fluorophlogopite powder, talcum powder, a coloring agent, modified starch, a preservative, a surfactant and deionized water, wherein the contents of the components are as follows in parts by weight:
fluorophlogopite powder: 3-15;
talc powder: 20-40 parts of;
colorant: 35-55;
modified starch: 10-20;
preservative: 0.1 to 1;
surfactant (b): 2-8;
deionized water: 10-25;
the colorant is a combination of several of iron oxide black, iron oxide yellow, iron oxide red, titanium dioxide, iron oxide black treated by isopropyl titanium triisostearate, iron oxide yellow treated by isopropyl titanium triisostearate and iron oxide red treated by isopropyl titanium triisostearate;
the modified starch is one or a combination of more of modified corn starch, modified glutinous rice starch and modified rice starch;
the preservative is one or a combination of more of chlorphenesin, sodium dehydroacetate, phenoxyethanol, caprylyl glycol and ethylhexyl glycerin;
the surfactant is one or the combination of two of anionic surfactant and nonionic surfactant.
The diameter of the refill of the eyebrow chalk is 3-6 mm, the breaking force is 200g/1 mm-600 g/1mm, and the hardness is 1000g/1 mm-3000 g/1 mm.
The invention also provides a preparation method of the pen core, which comprises the following steps: uniformly grinding fluorophlogopite powder, talcum powder, a coloring agent and modified starch into a powder phase by using a grinding machine; then uniformly beating the preservative, the surfactant and the deionized water into a water phase by using a dispersion machine under the condition of 4000-10000 r/min for 3-10 min; then mixing the powder phase and the water phase for 2-15 minutes by using a dispersion machine under the condition of 300-1500 revolutions per minute; and then carrying out extrusion forming and drying, and discharging when the water content in the refill of the eyebrow chalk is less than or equal to 10% to obtain the refill of the eyebrow chalk.
The extrusion forming is completed under the condition of 1-80 MPa.
The drying is carried out for 4-12 hours at the temperature of 40-80 ℃.
Has the advantages that:
1. the fluorophlogopite powder is introduced to enhance the cohesion, so that the pen core is not easy to break.
2. The cosmetic effect is more natural and lasting by adopting the modified toner.
3. The pure water system does not contain wax and oil, and is easy to disassemble.
4. Simple operation process, low cost and economic and practical effect.
Detailed Description
The invention will be further illustrated with reference to specific embodiments. It should be understood that these examples are for illustrative purposes only and are not intended to limit the scope of the present invention. Further, it should be understood that various changes or modifications of the present invention may be made by those skilled in the art after reading the teaching of the present invention, and such equivalents may fall within the scope of the present invention as defined in the appended claims.
The refill of the eyebrow pencil is prepared from fluorophlogopite powder, talcum powder, a coloring agent, modified starch, a preservative, a surfactant and deionized water in a blending mode, and the product obtained in a physical blending mode can realize the concept of green, safety and environmental protection. Meanwhile, the fluorophlogopite powder is added into the pen core, the fluorine element is the element with the largest electronegativity, the cohesion of the pen core can be enhanced through the hydrogen bond effect between the fluorine elements, and meanwhile, the fluorine element can migrate to the surface of the pen core for enrichment in the subsequent drying process due to the small surface free energy of the fluorophlogopite, so that the pen core is more compact, the problem that the pen core is easy to break can be solved, and a foundation is laid for subsequent processing; because certain grease is on the surface of the skin, the base makeup is generally carried out during makeup, and the base makeup products also generally contain the grease, the powder treated by the isopropyl titanium triisostearate is adopted in the invention, according to the principle of similarity and intermiscibility, the powder generated by the pen core of the eyebrow chalk through friction is more easily combined with the grease, and the makeup effect can be more skin-friendly and natural. The system adopts a water system and does not contain wax base and oil component, thereby achieving the effect of easy removal of the make-up effect.
The refill of the eyebrow chalk is 3-6 mm in diameter, the breaking force of the refill of the eyebrow chalk is 200g/1 mm-600 g/1mm, and the hardness of the refill is 1000g/1 mm-3000 g/1 mm.
Example 1
The raw materials are weighed according to the following weight portions,
sericite powder: 10;
talc powder: 35;
colorant: 40;
modified starch: 20;
preservative: 0.5;
surfactant (b): 5;
deionized water: 20;
the colorant described above was a combination of black iron oxide treated with isopropyl titanium triisostearate, yellow iron oxide treated with isopropyl titanium triisostearate, and red iron oxide treated with isopropyl titanium triisostearate, and the mass ratio of black iron oxide treated with isopropyl titanium triisostearate, yellow iron oxide treated with isopropyl titanium triisostearate, and red iron oxide treated with isopropyl titanium triisostearate was 3:1: 1.
The modified starch is a combination of modified corn starch, modified glutinous rice starch and modified rice starch, and the mass ratio of the modified corn starch, the modified glutinous rice starch and the modified rice starch is 2:1: 1.5.
The preservative is a combination of chlorphenesin, phenoxyethanol, caprylyl glycol and ethylhexylglycerin, and the mass ratio of chlorphenesin, phenoxyethanol, caprylyl glycol and ethylhexylglycerin is 1:2:2: 1.
The surfactant as described above is an anionic surfactant.
Pulverizing sericite powder, pulvis Talci, colorant, and modified starch into powder phase; then the preservative, the surfactant and the deionized water are beaten into a water phase uniformly by a dispersion machine under the condition of 6000 revolutions per minute for 10 minutes; then uniformly mixing the powder phase and the water phase for 6 minutes by using a dispersion machine under the condition of 500 revolutions per minute; and finally, carrying out extrusion forming under the condition of 10MPa, drying for 10 hours at the temperature of 60 ℃, testing that the water content of the pencil lead is 0.1%, and discharging to obtain the pencil lead of the eyebrow chalk. The diameter of the prepared refill of the eyebrow chalk is 6mm, the breaking force is 80g/1mm, and the hardness is 600g/1 mm.
Example 2
The raw materials are weighed according to the following weight portions,
fluorophlogopite powder: 10;
talc powder: 35;
colorant: 40;
modified starch: 20;
preservative: 0.5;
surfactant (b): 5;
deionized water: 20;
the colorant described above was a combination of black iron oxide treated with isopropyl titanium triisostearate, yellow iron oxide treated with isopropyl titanium triisostearate, and red iron oxide treated with isopropyl titanium triisostearate, and the mass ratio of black iron oxide treated with isopropyl titanium triisostearate, yellow iron oxide treated with isopropyl titanium triisostearate, and red iron oxide treated with isopropyl titanium triisostearate was 3:1: 1.
The modified starch is a combination of modified corn starch, modified glutinous rice starch and modified rice starch, and the mass ratio of the modified corn starch, the modified glutinous rice starch and the modified rice starch is 2:1: 1.5.
The preservative is a combination of chlorphenesin, phenoxyethanol, caprylyl glycol and ethylhexylglycerin, and the mass ratio of chlorphenesin, phenoxyethanol, caprylyl glycol and ethylhexylglycerin is 1:2:2: 1.
The surfactant as described above is an anionic surfactant.
Uniformly grinding fluorophlogopite powder, talcum powder, a coloring agent and modified starch into a powder phase by using a grinding machine; then the preservative, the surfactant and the deionized water are beaten into a water phase uniformly by a dispersion machine under the condition of 6000 revolutions per minute for 10 minutes; then uniformly mixing the powder phase and the water phase for 6 minutes by using a dispersion machine under the condition of 500 revolutions per minute; and finally, carrying out extrusion forming under the condition of 10MPa, drying for 10 hours at the temperature of 60 ℃, testing that the water content of the pencil lead is 0.1%, and discharging to obtain the pencil lead of the eyebrow chalk. The prepared refill of the eyebrow chalk has a diameter of 6mm, a breaking force of 590g/1mm and a hardness of 2900g/1 mm.
Example 3
The raw materials are weighed according to the following weight portions,
fluorophlogopite powder: 8;
talc powder: 35;
colorant: 42;
modified starch: 20;
preservative: 0.5;
surfactant (b): 4;
deionized water: 20;
the colorant described above was a combination of black iron oxide treated with isopropyl titanium triisostearate, yellow iron oxide treated with isopropyl titanium triisostearate, and red iron oxide treated with isopropyl titanium triisostearate, the mass ratio of black iron oxide treated with isopropyl titanium triisostearate, yellow iron oxide treated with isopropyl titanium triisostearate, and red iron oxide treated with isopropyl titanium triisostearate was 3:2: 1.
The modified starch is a combination of modified corn starch, modified glutinous rice starch and modified rice starch, and the mass ratio of the modified corn starch, the modified glutinous rice starch and the modified rice starch is 2:1: 1.5.
The preservative is a combination of chlorphenesin, phenoxyethanol, caprylyl glycol and ethylhexylglycerin, and the mass ratio of chlorphenesin, phenoxyethanol, caprylyl glycol and ethylhexylglycerin is 1:2:2: 1.
The surfactant as described above is an anionic surfactant.
Uniformly grinding fluorophlogopite powder, talcum powder, a coloring agent and modified starch into a powder phase by using a grinding machine; then the preservative, the surfactant and the deionized water are beaten into a water phase uniformly by a dispersion machine under the condition of 6000 revolutions per minute for 10 minutes; then uniformly mixing the powder phase and the water phase for 6 minutes by using a dispersion machine under the condition of 500 revolutions per minute; and finally, carrying out extrusion forming under the condition of 1MPa, drying for 12 hours at the temperature of 50 ℃, testing that the water content of the pencil lead is 0.3%, and discharging to obtain the pencil lead of the eyebrow chalk. The prepared lead of the eyebrow chalk has the diameter of 6mm, the breaking force of 500g/1mm and the hardness of 2500g/1 mm.
Example 4
The raw materials are weighed according to the following weight portions,
fluorophlogopite powder: 3;
talc powder: 20;
colorant: 35;
modified starch: 10;
preservative: 0.1;
surfactant (b): 2;
deionized water: 10;
the colorant described above was a combination of black iron oxide treated with isopropyl titanium triisostearate, yellow iron oxide treated with isopropyl titanium triisostearate, and red iron oxide treated with isopropyl titanium triisostearate, and the mass ratio of black iron oxide treated with isopropyl titanium triisostearate, yellow iron oxide treated with isopropyl titanium triisostearate, and red iron oxide treated with isopropyl titanium triisostearate was 3:1: 1.
The modified starch is a combination of modified corn starch, modified glutinous rice starch and modified rice starch, and the mass ratio of the modified corn starch, the modified glutinous rice starch and the modified rice starch is 2:1: 1.5.
The preservative is a combination of chlorphenesin, phenoxyethanol, caprylyl glycol and ethylhexylglycerin, and the mass ratio of chlorphenesin, phenoxyethanol, caprylyl glycol and ethylhexylglycerin is 1:2:2: 1.
The surfactant as described above is a combination of an anionic surfactant and a nonionic surfactant, wherein the mass ratio of the anionic surfactant to the nonionic surfactant is 3: 1.
Uniformly grinding fluorophlogopite powder, talcum powder, a coloring agent and modified starch into a powder phase by using a grinding machine; then the preservative, the surfactant and the deionized water are beaten into a water phase uniformly by a dispersion machine under the condition of 4000 revolutions per minute for 10 minutes; then uniformly mixing the powder phase and the water phase for 2 minutes by using a dispersion machine under the condition of 300 revolutions per minute; and finally, carrying out extrusion forming under the condition of 20MPa, drying for 12 hours at the temperature of 40 ℃, testing that the water content of the pencil lead is 0.1%, and discharging to obtain the pencil lead of the eyebrow chalk. The prepared refill of the eyebrow chalk has the diameter of 3mm, the breaking force of 200g/1mm and the hardness of 1000g/1 mm.
Example 5
The raw materials are weighed according to the following weight portions,
fluorophlogopite powder: 15;
talc powder: 40;
colorant: 55;
modified starch: 20;
preservative: 1;
surfactant (b): 8;
deionized water: 25;
the colorant is a combination of black iron oxide, yellow iron oxide, red iron oxide and titanium dioxide, and the mass ratio of the black iron oxide, the yellow iron oxide, the red iron oxide and the titanium dioxide is 3:1:1: 2.
The modified starch as described above is a modified corn starch.
The preservative is phenoxyethanol.
The surfactant as described above is a combination of an anionic surfactant and a nonionic surfactant, wherein the mass ratio of the anionic surfactant to the nonionic surfactant is 4: 1.
Uniformly grinding fluorophlogopite powder, talcum powder, a coloring agent and modified starch into a powder phase by using a grinding machine; then the preservative, the surfactant and the deionized water are beaten into a water phase uniformly by a dispersion machine under the condition of 10000 r/min for 3 minutes; then mixing the powder phase and the water phase for 15 minutes by a dispersion machine under the condition of 1000 revolutions per minute; and finally, carrying out extrusion forming under the condition of 80MPa, drying for 4 hours at the temperature of 80 ℃, testing that the water content of the pencil lead is 0.01%, and discharging to obtain the pencil lead of the eyebrow chalk. The diameter of the prepared refill of the eyebrow chalk is 6mm, the breaking force is 600g/1mm, and the hardness is 3000g/1 mm.
Example 6
The raw materials are weighed according to the following weight portions,
fluorophlogopite powder: 10;
talc powder: 30, of a nitrogen-containing gas;
colorant: 40;
modified starch: 15;
preservative: 0.5;
surfactant (b): 5;
deionized water: 15;
the colorant is a combination of yellow iron oxide, titanium dioxide and black iron oxide treated by isopropyl titanium triisostearate, and the mass ratio of the yellow iron oxide to the black iron oxide treated by the isopropyl titanium triisostearate is as follows: 1:2:3.
The modified starch as described above is a modified glutinous rice starch.
The preservative sodium dehydroacetate as described above.
The surfactant as described above is a nonionic surfactant.
Uniformly grinding fluorophlogopite powder, talcum powder, a coloring agent and modified starch into a powder phase by using a grinding machine; then the preservative, the surfactant and the deionized water are uniformly beaten into a water phase by a dispersion machine for 6 minutes under the condition of 8000 revolutions per minute; then uniformly mixing the powder phase and the water phase by using a dispersion machine under the condition of 1200 revolutions per minute for 8 minutes; and finally, carrying out extrusion forming under the condition of 60MPa, drying for 8 hours at the temperature of 60 ℃, testing that the water content of the pencil lead is 0.2%, and discharging to obtain the pencil lead of the eyebrow chalk. The prepared refill of the eyebrow chalk has a diameter of 4mm, breaking force of 400g/1mm and hardness of 2000g/1 mm.
Example 7
The raw materials are weighed according to the following weight portions,
fluorophlogopite powder: 8;
talc powder: 25;
colorant: 38;
modified starch: 16;
preservative: 0.6;
surfactant (b): 5;
deionized water: 18;
the colorant mentioned above is a combination of black iron oxide, yellow iron oxide treated with isopropyl titanium triisostearate, and red iron oxide treated with isopropyl titanium triisostearate, and the mass ratio of black iron oxide, yellow iron oxide treated with isopropyl titanium triisostearate, and red iron oxide treated with isopropyl titanium triisostearate is 1:1: 1.
The modified starch as described above is a modified rice starch.
The preservative is phenoxyethanol.
The surfactant as described above is a combination of an anionic surfactant and a nonionic surfactant, wherein the mass ratio of the anionic surfactant to the nonionic surfactant is 2:1.
Uniformly grinding fluorophlogopite powder, talcum powder, a coloring agent and modified starch into a powder phase by using a grinding machine; then the preservative, the surfactant and the deionized water are beaten into a water phase by a dispersion machine for 7 minutes under the condition of 8000 revolutions per minute; then uniformly mixing the powder phase and the water phase by using a dispersion machine under the condition of 700 revolutions per minute for 8 minutes; and finally, carrying out extrusion forming under the condition of 50MPa, drying for 5 hours at the temperature of 60 ℃, testing that the water content of the pencil lead is 2%, and discharging to obtain the pencil lead of the eyebrow chalk. The prepared refill of the eyebrow chalk has a diameter of 4.5mm, breaking force of 450g/1mm and hardness of 2500g/1 mm.
Example 8
The raw materials are weighed according to the following weight portions,
fluorophlogopite powder: 8;
talc powder: 25;
colorant: 38;
modified starch: 19;
preservative: 0.6;
surfactant (b): 7;
deionized water: 20;
the colorant described above was a combination of black iron oxide treated with isopropyl titanium triisostearate, yellow iron oxide treated with isopropyl titanium triisostearate, and red iron oxide treated with isopropyl titanium triisostearate, the mass ratio of black iron oxide treated with isopropyl titanium triisostearate, yellow iron oxide treated with isopropyl titanium triisostearate, and red iron oxide treated with isopropyl titanium triisostearate was 3:2: 1.
The modified starch is a combination of modified corn starch and modified glutinous rice starch, and the mass ratio of the modified corn starch to the modified glutinous rice starch is 1:1.
The preservative is a combination of phenoxyethanol, caprylyl glycol and ethylhexyl glycerin, and the mass ratio of the phenoxyethanol to the caprylyl glycol to the ethylhexyl glycerin is 2:1:1.
The surfactant as described above is a combination of an anionic surfactant and a nonionic surfactant, wherein the mass ratio of the anionic surfactant to the nonionic surfactant is 1: 2.
Uniformly grinding fluorophlogopite powder, talcum powder, a coloring agent and modified starch into a powder phase by using a grinding machine; then the preservative, the surfactant and the deionized water are uniformly beaten into a water phase by a dispersion machine under the condition of 6000 revolutions per minute for 8 minutes; then uniformly mixing the powder phase and the water phase by using a dispersion machine under the condition of 600 revolutions per minute for 8 minutes; and finally, carrying out extrusion forming under the condition of 60MPa, drying for 8 hours at the temperature of 60 ℃, testing that the water content of the pencil lead is 0.5%, and discharging to obtain the pencil lead of the eyebrow chalk. The prepared refill of the eyebrow chalk has a diameter of 4.5mm, a breaking force of 400g/1mm and a hardness of 2000g/1 mm.
Example 9
The raw materials are weighed according to the following weight portions,
fluorophlogopite powder: 13;
talc powder: 30, of a nitrogen-containing gas;
colorant: 50;
modified starch: 15;
preservative: 0.5;
surfactant (b): 6;
deionized water: 20;
the colorant is a combination of black iron oxide, yellow iron oxide, red iron oxide and titanium dioxide, and the mass ratio of the black iron oxide, the yellow iron oxide, the red iron oxide and the titanium dioxide is 2:1:1: 2.
The modified starch is modified corn starch and modified rice starch, and the mass ratio of the modified corn starch to the modified rice starch is 1: 2.
The preservative is a combination of chlorphenesin and phenoxyethanol, and the mass ratio of chlorphenesin to phenoxyethanol is 1:1.
The surfactant as described above is an anionic surfactant.
Uniformly grinding fluorophlogopite powder, talcum powder, a coloring agent and modified starch into a powder phase by using a grinding machine; then the preservative, the surfactant and the deionized water are uniformly beaten into a water phase by a dispersion machine for 6 minutes under the condition of 8000 revolutions per minute; then mixing the powder phase and the water phase for 2 minutes by a dispersion machine under the condition of 1500 revolutions per minute; and finally, carrying out extrusion forming under the condition of 60MPa, drying for 6 hours at the temperature of 50 ℃, testing that the water content of the pencil lead is 1%, and discharging to obtain the pencil lead of the eyebrow chalk. The prepared refill of the eyebrow chalk has the diameter of 3mm, the breaking force of 400g/1mm and the hardness of 1800g/1 mm.
Example 10
The raw materials are weighed according to the following weight portions,
fluorophlogopite powder: 11;
talc powder: 31;
colorant: 40;
modified starch: 15;
preservative: 0.5;
surfactant (b): 5;
deionized water: 15;
the colorant is a combination of yellow iron oxide, titanium dioxide and black iron oxide treated by isopropyl titanium triisostearate, and the mass ratio of the yellow iron oxide to the black iron oxide treated by the isopropyl titanium triisostearate is as follows: 3:1:4.
The modified starch as described above is a modified corn starch.
The preservative sodium dehydroacetate as described above.
The surfactant as described above is a nonionic surfactant.
Uniformly grinding fluorophlogopite powder, talcum powder, a coloring agent and modified starch into a powder phase by using a grinding machine; then the preservative, the surfactant and the deionized water are beaten into a water phase by a dispersion machine under the condition of 7000 r/min for 6 minutes; then uniformly mixing the powder phase and the water phase by using a dispersion machine under the condition of 600 revolutions per minute for 9 minutes; and finally, carrying out extrusion forming under the condition of 60MPa, drying for 8 hours at the temperature of 60 ℃, testing that the water content of the pencil lead is 0.1%, and discharging to obtain the pencil lead of the eyebrow chalk. The prepared refill of the eyebrow chalk has the diameter of 4mm, the breaking force of 400g/1mm and the hardness of 2000g/1 mm.
Example 11
The raw materials are weighed according to the following weight portions,
fluorophlogopite powder: 10;
talc powder: 28;
colorant: 38;
modified starch: 16;
preservative: 0.6;
surfactant (b): 7;
deionized water: 20;
the colorant mentioned above is a combination of black iron oxide, yellow iron oxide treated with isopropyl titanium triisostearate, and red iron oxide treated with isopropyl titanium triisostearate, and the mass ratio of black iron oxide, yellow iron oxide treated with isopropyl titanium triisostearate, and red iron oxide treated with isopropyl titanium triisostearate is 2:1:1.
The modified starch as described above is a modified rice starch.
The preservative is phenoxyethanol, caprylyl glycol and ethylhexyl glycerol, wherein the mass ratio of the phenoxyethanol to the caprylyl glycol to the ethylhexyl glycerol is 1:1: 2.
The surfactant as described above is an anionic surfactant.
Uniformly grinding fluorophlogopite powder, talcum powder, a coloring agent and modified starch into a powder phase by using a grinding machine; then the preservative, the surfactant and the deionized water are beaten into a water phase by a dispersion machine for 7 minutes under the condition of 7500 r/min; then uniformly mixing the powder phase and the water phase by using a dispersion machine under the condition of 700 revolutions per minute for 8 minutes; and finally, carrying out extrusion forming under the condition of 50MPa, drying for 7 hours at the temperature of 60 ℃, testing that the water content of the pencil lead is 2%, and discharging to obtain the pencil lead of the eyebrow chalk. The diameter of the prepared refill of the eyebrow chalk is 4mm, the breaking force is 440g/1mm, and the hardness is 2450g/1 mm.
Example 12
The raw materials are weighed according to the following weight portions,
fluorophlogopite powder: 12;
talc powder: 25;
colorant: 50;
modified starch: 15;
preservative: 0.5;
surfactant (b): 8;
deionized water: 25;
the colorant mentioned above is a combination of black iron oxide treated with isopropyl titanium triisostearate, yellow iron oxide treated with isopropyl titanium triisostearate and red iron oxide treated with isopropyl titanium triisostearate, and the mass ratio of black iron oxide treated with isopropyl titanium triisostearate, yellow iron oxide treated with isopropyl titanium triisostearate and red iron oxide treated with isopropyl titanium triisostearate is 3:1: 2.
The modified starch is a combination of modified corn starch, modified glutinous rice starch and modified rice starch, and the mass ratio of the modified corn starch, the modified glutinous rice starch and the modified rice starch is 1:2: 1.5.
The preservative is a combination of chlorphenesin, phenoxyethanol, caprylyl glycol and ethylhexylglycerin, and the mass ratio of chlorphenesin, phenoxyethanol, caprylyl glycol and ethylhexylglycerin is 1:2:2: 1.
The surfactant as described above is a combination of an anionic surfactant and a nonionic surfactant, wherein the mass ratio of the anionic surfactant to the nonionic surfactant is 1:1.
Uniformly grinding fluorophlogopite powder, talcum powder, a coloring agent and modified starch into a powder phase by using a grinding machine; then the preservative, the surfactant and the deionized water are beaten into a water phase by a dispersion machine under the condition of 8000 revolutions per minute for 8 minutes; then uniformly mixing the powder phase and the water phase by using a dispersion machine under the condition of 600 revolutions per minute for 8 minutes; and finally, carrying out extrusion forming under the condition of 70MPa, drying for 10 hours at 65 ℃, testing that the water content of the pencil lead is 0.01%, and discharging to obtain the pencil lead of the eyebrow chalk. The breaking force of the prepared refill of the eyebrow chalk with the diameter of 4mm is 500g/1mm, and the hardness is 2750g/1 mm.
Claims (9)
1. A preparation method of a refill of an eyebrow pencil comprises the following steps: uniformly grinding fluorophlogopite powder, talcum powder, a coloring agent and modified starch into a powder phase by using a grinding machine; then uniformly beating the preservative, the surfactant and the deionized water into a water phase by using a dispersion machine under the condition of 4000-10000 r/min for 3-10 min; then mixing the powder phase and the water phase for 2-15 minutes by using a dispersion machine under the condition of 300-1500 revolutions per minute; then carrying out extrusion forming and drying, discharging when the water content in the refill of the eyebrow chalk is less than or equal to 10%, and obtaining the refill of the eyebrow chalk;
the obtained refill of the eyebrow pencil consists of the following components in parts by weight:
fluorophlogopite powder: 3-15;
talc powder: 20-40 parts of;
colorant: 35-55;
modified starch: 10-20;
preservative: 0.1 to 1;
surfactant (b): 2-8;
deionized water: 10 to 25.
2. The preparation method of the refill of the eyebrow pencil according to claim 1, wherein the extrusion molding is performed under a pressure of 1 to 80 MPa.
3. The preparation method of the refill of the eyebrow pencil according to claim 1 or 2, wherein the drying is carried out at 40 to 80 ℃ for 4 to 12 hours.
4. A refill of a eyebrow pencil prepared by the preparation method of any one of claims 1 to 3, which is characterized by comprising fluorophlogopite powder, talcum powder, a coloring agent, modified starch, a preservative, a surfactant and deionized water, wherein the contents of the components are as follows in parts by weight:
fluorophlogopite powder: 3-15;
talc powder: 20-40 parts of;
colorant: 35-55;
modified starch: 10-20;
preservative: 0.1 to 1;
surfactant (b): 2-8;
deionized water: 10 to 25.
5. The refill of a brow chalk according to claim 4, wherein the refill has a diameter of 3 to 6mm, a breaking force of 200g/1mm to 600g/1mm, and a hardness of 1000g/1mm to 3000g/1 mm.
6. A refill for a eyebrow chalk according to claim 4, wherein the coloring agent is one or a combination of black iron oxide, yellow iron oxide, red iron oxide, titanium dioxide, black iron oxide treated with isopropyl titanium triisostearate, yellow iron oxide treated with isopropyl titanium triisostearate, and red iron oxide treated with isopropyl titanium triisostearate.
7. A refill of eyebrow chalk, according to claim 4, wherein said modified starch is one or more selected from modified corn starch, modified glutinous rice starch and modified rice starch.
8. The refill of the eyebrow chalk, according to claim 4, wherein the preservative is one or a combination of more of chlorphenesin, sodium dehydroacetate, phenoxyethanol, caprylyl glycol and ethylhexyl glycerin.
9. The refill of eyebrow chalk, according to claim 4, wherein said surfactant is one or a combination of anionic surfactant and nonionic surfactant.
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| CN106691925A (en) * | 2016-12-13 | 2017-05-24 | 丽鑫生技化妆品（上海）有限公司 | Improved eyebrow pencil |
| CN107550757B (en) * | 2017-10-19 | 2020-01-21 | 浙江艳庄化妆品有限公司 | Eyebrow powder containing multiple dihydric alcohol compounds |
| CN108096072B (en) * | 2017-12-21 | 2020-07-10 | 广州神采化妆品有限公司 | Highlight foundation cream stick |
| CN109966175A (en) * | 2019-04-17 | 2019-07-05 | 中山市美源化妆品有限公司 | A kind of waterproof dumb light brow powder, and its manufacturing method |
| CN115869204B (en) * | 2022-12-19 | 2024-06-28 | 上海臻臣化妆品有限公司 | Blush powder product and preparation method thereof |
| CN116473874A (en) * | 2023-04-20 | 2023-07-25 | 上海创元化妆品有限公司 | Cosmetic pencil lead composition and preparation method thereof |
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