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CN105613527A - Weeding composition with synergism - Google Patents

Weeding composition with synergism Download PDF

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Publication number
CN105613527A
CN105613527A CN201610173948.6A CN201610173948A CN105613527A CN 105613527 A CN105613527 A CN 105613527A CN 201610173948 A CN201610173948 A CN 201610173948A CN 105613527 A CN105613527 A CN 105613527A
Authority
CN
China
Prior art keywords
florasulam
chloropyridine ester
fluorine chloropyridine
azoles grass
weeds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610173948.6A
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Chinese (zh)
Inventor
杨会营
刘晓娇
吴勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing Yanhua Yongle Biotechnology Co Ltd
Original Assignee
Beijing Yanhua Yongle Biotechnology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beijing Yanhua Yongle Biotechnology Co Ltd filed Critical Beijing Yanhua Yongle Biotechnology Co Ltd
Priority to CN201610173948.6A priority Critical patent/CN105613527A/en
Publication of CN105613527A publication Critical patent/CN105613527A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647Triazoles; Hydrogenated triazoles
    • A01N43/6531,2,4-Triazoles; Hydrogenated 1,2,4-triazoles

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention belongs to the technical field of pesticides, and relates to a weeding composition with synergism. The weeding composition is characterized by comprising three active components of halauxifen-methyl, florasulam and carfentrazone. The weeding composition is wide in weeding spectrum, remarkable in weeding effect, long in lasting period and safe and environment-friendly.

Description

There is the herbicidal composition of synergism
Technical field
The invention belongs to technical field of pesticide, specifically contain the herbicidal composition with synergism of fluorine chloropyridine ester, florasulam and azoles grass ketone.
Background technology
Wheat is grass, is the widest food crop that distribute in the world, and sown area is the hat of food crop. China's wheat planting is with a long history, and distributional region covers Henan, Shandong, Jiangsu, Hebei, Hubei, Anhui etc. and economizes. Weeds are one of main harm of harm wheat growth, in order to make improving yield of wheat, it is necessary to prevented and treated by weeds of wheat. In recent years, wheat field herbicide is rationally selected closely to become the important technical links guaranteeing that wheat is kept the safety in production, but owing to drug of choice is improper or operation technique is not in place, prevention effect is undesirable or causes the phenomenons such as poisoning to occur repeatedly. Therefore urgent needs are a kind of so both saves manpower and materials to environment and crop safety, the weedicide that control of weeds effect is good again, and also environmentally safe and human health brings safely guarantee.
Fluorine chloropyridine ester (halauxifen-methyl) is the wheat field herbicide developed by Tao Nongke company of the U.S. (DowAgroSciences), for preventing and treating broadleaf weeds after bud. This one-tenth belongs to pyridine carboxylic acid class weedicide. Fluorine chloropyridine ester is the first product in the new chemical type of aryl-pyridine acid in synthetically grown element class weedicide. It simulates the effect of high dosage plant growth regulator, causes the overstimulation of specific growth hormone regulatory gene, multiple process of growth of interference sensitive plant. Almost noresidue effect after this weedicide bud aftertreatment, to after medication 10 months plantation many rotation crops, can choice big. Tender Catchweed Bedstraw Herb, chickweed and cannabis weeds carry out resistance management. In addition, fluorine chloropyridine ester is degraded in the environment fast by microorganism, for follow-up crop-planting provides bigger handiness.
Florasulam (florasulam) is the triazolo pyrimidine sulphonyl class ultra-high efficiency weedicide developed by DowAgroscience company, and florasulam is inner sucting conduction type weedicide, it is possible to conduct to weeds complete stool, and thus herbicide is thorough, can not recur. Efficacy stability at low temperatures, this point is that other weedicides are incomparable. This composition is mainly used in wheat paddock and prevents and kill off broadleaf weeds. Florasulam is inner sucting conduction type weedicide, can be absorbed by plant leaf and root system, accumulates and make plant progressively dead in meristematic tissue. This weedicide possesses the advantage of biological activity height, broad weed-killing spectrum, and owing to its action target ALS enzyme does not relate to humans and animals, therefore humans and animals is had very high security by this kind of weedicide.
Azoles grass ketone (carfentrazone-ethyl) is a kind of contact killing type selective herbicide, for preventing and treating wheat paddock broadleaved herb and nutgrass flatsedge, when there being light, in chlcrophyll biosynthesis process, by suppressing proporphyrinogen oxidase to cause the accumulation of poisonous intermediate, thus destroy the cytolemma of weeds, make blade withered, dead rapidly. This composition herbicide speed is fast, and little by low temperature effect, medication chance is wide, can medication when temperature drops to very low before the winter, also can rob spring frequently in the timely medication in rainy day gap in rainfall, and succession crop is fool proof, be the fine herbicide that wheatland is eliminated spring.
The use lack of standardization of current weedicide result in the report that constantly there are weedicide resistance and poisoning in various places. The composite mixed of agricultural chemicals alleviates poisoning at present, it is to increase the most economical effective method of drug effect, meanwhile, various weedicide is because of the difference of its chemical composition, physico-chemical property, and herbicide scope is also different, and herbicide mixture can expand the herbicidal spectrum of compound preparation. Therefore we are by herbicide mixtures different for careless to fluorine chloropyridine ester, florasulam and azoles ketone three kinds of herbicide effect modes, to reduce the generation of resistance, expand herbicide spectrum, reduce the impact on edatope, it is to increase economic benefit.
Summary of the invention
It is an object of the invention to the shortcoming for prior art, it is provided that the herbicidal composition that a kind of herbicidal effect is good, quick-acting height, lasting period are long, simultaneously environmentally safe, easy to use, to reducing peasant's dispenser cost, it is to increase economic benefit. It is specifically related to the herbicidal composition with synergism of fluorine chloropyridine ester, florasulam and azoles grass ketone.
Utilize above-mentioned herbicidal composition, it is equipped with the known auxiliary agent of those skilled in that art and method, makes and dispersible oil-suspending agent, water dispersible granules, suspended emulsion agent.
In described herbicidal composition, containing fluorine chloropyridine ester 1%-20%, florasulam 1%-20%, azoles grass ketone 1%-40%.
Described herbicidal composition is mainly used in control wheat paddock broadleaf weeds.
The advantage that described herbicidal composition has and useful effect: 1. effective constituent is unique to the mode of action of wheat, with existing weedicide without obvious cross resistance; 2. formulation is novel, it is possible to improve effective constituent drug effect; 3. to wheat safety, to succession crop safety; 4. ternary herbicide mixture, it is possible to significantly improve drug effect, has good synergism.
Embodiment
After verifying that fluorine chloropyridine ester, florasulam and azoles grass ketone three kinds of effective constituents are composite, the control of wheat paddock broadleaf weeds there is good synergism, first applicant tests under room temperature condition of pot, close herbicidal effect to determine fluorine chloropyridine ester, florasulam, azoles grass ketone and different blended combo thereof, evaluate its combined action.
The common Tender Catchweed Bedstraw Herb of test and Selection wheat paddock, field thistle are as target weeds.
The preparation of test medicine:
Fluorine chloropyridine ester solution: the fluorine former medicine of chloropyridine ester accurately taking certainweight 95%, dissolves by proper amount of methanol, adds the clear water containing 0.1% tween 80 emulsifying agent, is stirred to evenly, solution containing certain effective constituent.
Florasulam solution: the former medicine of florasulam accurately taking certainweight 95%, dissolves by proper amount of methanol, adds the clear water containing 0.1% tween 80 emulsifying agent, is stirred to evenly, solution containing certain effective constituent.
Azoles grass ketone solution: the azoles grass former medicine of ketone accurately taking certainweight 95%, dissolves by proper amount of methanol, adds the clear water containing 0.1% tween 80 emulsifying agent, be stirred to evenly, solution containing certain effective constituent.
Blank solution: the water adding the tween 80 emulsifying agent of equivalent 0.1% with the methyl alcohol of equivalent.
Test method is as follows:
After adopting the inspection of colby method mixed, medicament is to the activity of Tender Catchweed Bedstraw Herb and field thistle, at the soil of the polypots amount of setting of high 7cm, diameter 10cm, 20, the seed for examination weeds is evenly sowed in polypots, the thin sand and soil that lid 0.5cm-1cm is thick, it is placed on room temperature (about 20 DEG C) to cultivate, the above-mentioned former drug solns prepared carries out composite and is diluted to the liquid of finite concentration gradient, until weed growth to carrying out stem leaf spraying process during the 3-5 leaf phase, every alms bowl spraying liquid 1ml, each processes 4 repetitions, it may also be useful to blank solution compares. After process, test materials is placed in room temperature and cultivates, and the growing state of routine observation weeds, estimates damage symptoms and the growth-inhibiting situation of target weeds after 21 days, weighs strain fresh heavy, calculates fresh weight inhibition (%).
E0=A+B+C
E in formula0It it is the theoretical anti-effect after three kinds of effective constituent mixtures, weeds suppressed, E is the anti-effect of actual measurement suppressed by weeds after three kinds of effective constituent mixtures, A is that fluorine chloropyridine ester is at this dose to the anti-effect of target weeds, B is that florasulam is at this dose to the anti-effect of target weeds, C be azoles grass ketone at this dose to the anti-effect of target weeds, E-E0For the combined action coefficient of mixture preparation, in order to evaluate the synergy of two kinds of effective constituents, work as E-E0> 10% is synergism, E-E0<-10% is antagonistic action, E-E0Value between theoretical value �� 10% for adding and act on.
Table 1 fluorine chloropyridine ester, florasulam and azoles grass ketone different ratio are to the raw survey test-results of Tender Catchweed Bedstraw Herb weeding activity
Upper table is it may be seen that composite between three kinds of effective constituents, and combined action coefficient has all exceeded 17%, and the anti-effect of Tender Catchweed Bedstraw Herb is had obvious synergism.
Table 2 fluorine chloropyridine ester, florasulam and azoles grass ketone different ratio are to the raw survey test-results of field thistle weeding activity
Upper table is it may be seen that composite between three kinds of effective constituents, and combined action coefficient has all exceeded 17%, and the anti-effect of field thistle is had good synergism.
Below by way of specific examples in order to further describe the present invention, but the present invention is absolutely not only only limitted to these embodiments following. In formula, per-cent is all weight percentage, and the former medicine used and auxiliary agent are other producers and provide. Formulation examples is as follows:
Embodiment 16% fluorine chloropyridine ester florasulam azoles grass ketone dispersibles oil-suspending agent
Embodiment 220% fluorine chloropyridine ester florasulam azoles grass ketone suspended emulsion agent
Embodiment 330% fluorine chloropyridine ester florasulam azoles grass ketone dispersibles oil-suspending agent
Embodiment 460% fluorine chloropyridine ester florasulam azoles grass ketone water dispersible granules
Embodiment 520% fluorine chloropyridine ester florasulam azoles grass ketone water dispersible granules
Embodiment 628% fluorine chloropyridine ester florasulam azoles grass ketone water dispersible granules
Embodiment 712% fluorine chloropyridine ester florasulam azoles grass ketone suspended emulsion agent
Embodiment 840% fluorine chloropyridine ester florasulam azoles grass ketone water dispersible granules
Embodiment 960% fluorine chloropyridine ester florasulam azoles grass ketone water dispersible granules
Embodiment 1021% fluorine chloropyridine ester florasulam azoles grass ketone water dispersible granules
Above embodiment is selected to carry out preventing and treating the field efficacy experiment of weeds of wheat, the effect of weeds in wheat paddock is prevented and treated to determine to fill a prescription, simultaneously by comparing with fluorine chloropyridine ester, florasulam and azoles grass ketone single dose medicament mixed with bucket, it is determined that the synergistic effect after composite, is specifically implemented as follows:
Experiment: wheat field herbicide experiment prevented and treated by 20% fluorine chloropyridine ester florasulam azoles grass ketone water dispersible granules (English formulation title: WDG) and different preparation. Test site is Xinyang Prefecture of Henan Province, time is on March 5th, 2015, test medicine is all prepared according to above-mentioned example and is used the bucket between two of 10% fluorine chloropyridine ester water dispersible granules (English formulation title: WDG), 10% florasulam wettable powder (English formulation title: WP), 40% azoles grass ketone water dispersible granules (English formulation title: WDG) and above-mentioned three kinds of single doses to infiltrate row comparison, medicament carries out stem leaf even spraying after being watered, protect water more than three days after dispenser. Each processes three repetitions, community random alignment, plot area 100m2, respondent is Tender Catchweed Bedstraw Herb and the field thistle in field. Wheat is occurred by visual test medicament without poisoning. The record dispenser weather data of a week, specific as follows:
Climatological data between table 3 trial period
Anti-effect calculates according to the following equation:
Test-results is such as following table:
The test of pesticide effectiveness result of table 4 fluorine chloropyridine ester florasulam azoles grass ketone and different agents control weeds of wheat
From above-mentioned data this it appears that, after fluorine chloropyridine ester, florasulam and azoles grass ketone ternary built, all embodiments to the anti-effect of Tender Catchweed Bedstraw Herb and field thistle all more than 90%, far above fluorine chloropyridine ester, florasulam, azoles grass ketone three kinds of single doses and the three kinds of single doses mixed anti-effects to two kinds of weeds of bucket between two, difference and significantly. Formulation is advanced, and synergism is remarkable, to wheat safety without poisoning.

Claims (2)

1. one kind has the herbicidal composition of synergism, it is characterized in that: described herbicidal composition activeconstituents is made up of fluorine chloropyridine ester, florasulam, azoles grass ketone, the weight percent of described fluorine chloropyridine ester is 1%��20%, the weight percent of florasulam is 1%��20%, and the weight percent of azoles grass ketone is 1%��40%.
2. herbicidal composition according to claim 1, it is characterised in that: it is made up of effective constituent and auxiliary material and dispersibles oil-suspending agent, water dispersible granules, suspended emulsion agent.
CN201610173948.6A 2016-03-24 2016-03-24 Weeding composition with synergism Pending CN105613527A (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108402058A (en) * 2018-03-07 2018-08-17 陕西上格之路生物科学有限公司 A kind of ternary weeding composition containing florasulam
CN114258919A (en) * 2021-12-31 2022-04-01 王剑英 Weeding composition

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101808520A (en) * 2007-08-27 2010-08-18 陶氏益农公司 Synergistic herbicidal composition containing certain pyridine or pyrimidine carboxylic acids and certain cereal and rice herbicides
CN102316728A (en) * 2008-11-24 2012-01-11 陶氏益农公司 Safening 6-(trisubstituted phenyl)-4-amino-2-pyridinecarboxylate herbicide injury on direct seeded and transplanted paddy rice
CN104170830A (en) * 2014-09-19 2014-12-03 联保作物科技有限公司 Wheat field weeding composition and preparation thereof
WO2014206835A1 (en) * 2013-06-26 2014-12-31 Basf Se Methods for improving the efficacy of anionic herbicides under hard water conditions and suitable compositions
CN104902755A (en) * 2013-01-10 2015-09-09 美国陶氏益农公司 Safening of 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid and derviatives thereof on cereal crops

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101808520A (en) * 2007-08-27 2010-08-18 陶氏益农公司 Synergistic herbicidal composition containing certain pyridine or pyrimidine carboxylic acids and certain cereal and rice herbicides
CN102316728A (en) * 2008-11-24 2012-01-11 陶氏益农公司 Safening 6-(trisubstituted phenyl)-4-amino-2-pyridinecarboxylate herbicide injury on direct seeded and transplanted paddy rice
CN104902755A (en) * 2013-01-10 2015-09-09 美国陶氏益农公司 Safening of 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid and derviatives thereof on cereal crops
WO2014206835A1 (en) * 2013-06-26 2014-12-31 Basf Se Methods for improving the efficacy of anionic herbicides under hard water conditions and suitable compositions
CN104170830A (en) * 2014-09-19 2014-12-03 联保作物科技有限公司 Wheat field weeding composition and preparation thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108402058A (en) * 2018-03-07 2018-08-17 陕西上格之路生物科学有限公司 A kind of ternary weeding composition containing florasulam
CN114258919A (en) * 2021-12-31 2022-04-01 王剑英 Weeding composition

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