A kind of layer-twisted optical fiber ribbon cable
The application is that name is called: matrix material and adopt the fibre ribbon of this resin and optical cable, the applying date to be: the divisional application of the patent of invention that October 05, application number in 2014 are 201410519527.5.
Technical field
The invention belongs to material and technical field of cables, especially relate to matrix material and adopt fibre ribbon and the optical cable of this resin.
Background technology
Optical fiber is as the main carriers of communication, and use amount increases day by day; Optical fiber mainly uses in field of signal transmissions at present, as mobile phone signal, TV signal, control signal, prison Kong signal etc., conventional optical fiber is silica-based optical fiber at present, optical fiber mainly lose part be fibre core, core diameter is conventionally in 9 μ m left and right, and that the core diameter of multimode fibre is conventional is 50 μ m and 62.5 μ m; Also have covering outward at fibre core, covering has coat outward. Because the core diameter of optical fiber is relatively thin, and in air or in water, contain a large amount of hydrogen ions and hydroxide ion, easy and silica bound, causes the fracture of fibre core or perhaps the fracture of optical fiber, affects the transmission of optical signal. For this reason, in optical cable industry, carry out constantly research and protection around protection optical fiber, as optical fiber is contacted with ointment, optical fiber has been immersed in ointment, itself and moisture are isolated, so just realized protection. But this mode, needs a large amount of ointment on the one hand, the use of ointment has caused the pollution of environment, the significant wastage of resource, has caused cost high; More very, conventionally optical fiber can be inserted in loose sleeve pipe, in loose sleeve pipe, fill fine cream, then outside loose sleeve pipe also be filled to greasy for preventing water around, further isolate moisture. Caused the increasing of cost, and ointment environment is unfriendly, more difficult removal when use, therefore, has all brought great inconvenience to production manufacturer and user.
For conventional optical cable, be loose fine structure, multifiber is placed in a loose sleeve pipe, if desired increase the message capacity of optical fiber, need stranded many loose sleeve pipes, form cable core, then form optical cable. Another kind of mode is in the time needing the optical cable of larger core number, conventionally multifiber is put into band, form fibre ribbon, then multifiber band is realized by stacked mode, then shoestring is put into loose sleeve pipe, factice for filling or other suitable material that blocks water in the gap of pine sleeve pipe, reach the function of optical cable water-blocking.
Obviously, the application of ointment has also caused the increase of cost, the pollution of environment, the difficulty of construction. Although also there is at present both at home and abroad the structure of so-called Full-dry optical cable, they are that dry type material water-proof material and optical fiber or fibre ribbon are put together, reach the object blocking water, and obviously, this block-water effect is also irrational principle.
Summary of the invention
In order to address the above problem, the object of the invention is to disclose a kind of matrix material, disclose further the fibre ribbon and the optical cable that adopt this matrix material, they are realized by the following technical solutions.
Matrix material, is characterized in that it comprises following raw material by weight: polyacrylic resin: the ultra-violet curing agent that 90~95 parts, commercially available model are 3091: the ultraviolet initiator that 3~5 parts, commercially available model are UV500: the polyisobutene that 6~8 parts, commercially available model are PB2400: the macromolecular thermoplastic synthetic rubber that 5~8 parts, commercially available model are SV150: the cable antioxidant that 3~5 parts, commercially available model are L-1035: 1~2 part, manganese carboxylate: 1~2 part, carboxylic acid potassium: 1~2 part, sodium fluoride: 2~4 parts.
Above-mentioned matrix material, most preferred formula is: it comprises following raw material by weight: polyacrylic resin: the ultra-violet curing agent that 93 parts, commercially available model are 3091: the ultraviolet initiator that 4 parts, commercially available model are UV500: the polyisobutene that 7 parts, commercially available model are PB2400: the macromolecular thermoplastic synthetic rubber that 6 parts, commercially available model are SV150: the cable antioxidant that 4 parts, commercially available model are L-1035: 1.5 parts, manganese carboxylate: 1.5 parts, carboxylic acid potassium: 15. parts, sodium fluoride: 3 parts.
Above-mentioned matrix material, more preferably formula is: it comprises following raw material by weight: polyacrylic resin: the ultra-violet curing agent that 90 parts, commercially available model are 3091: the ultraviolet initiator that 3 parts, commercially available model are UV500: the polyisobutene that 6 parts, commercially available model are PB2400: the macromolecular thermoplastic synthetic rubber that 5 parts, commercially available model are SV150: the cable antioxidant that 3 parts, commercially available model are L-1035: 1 part, manganese carboxylate: 1 part, carboxylic acid potassium: 1 part, sodium fluoride: 2 parts.
Above-mentioned matrix material, more preferably formula is: it comprises following raw material by weight: polyacrylic resin: the ultra-violet curing agent that 95 parts, commercially available model are 3091: the ultraviolet initiator that 5 parts, commercially available model are UV500: the polyisobutene that 8 parts, commercially available model are PB2400: the macromolecular thermoplastic synthetic rubber that 8 parts, commercially available model are SV150: the cable antioxidant that 5 parts, commercially available model are L-1035: 2 parts, manganese carboxylate: 2 parts, carboxylic acid potassium: 2 parts, sodium fluoride: 4 parts.
Commercially available model is that the macromolecular thermoplastic synthetic rubber of SV150 is produced by Infineum company; Commercially available model is that the cable antioxidant of L-1035 is produced by Ciba (China) Co., Ltd.
The formula of above-mentioned matrix material, through test, has reached following technical performance index: 25 DEG C time: viscosity: 3800 ± 200MPas; Modulus: 850 ± 50MPa; Percentage elongation: >=20%; Anti-intensity: the 25 ± 5MPa that stretches; 25 DEG C, pressure are 2 standard atmospheric pressures, soaking time 180 days: infiltration probability: be not more than ten thousand/.
Above-mentioned matrix material is at the MS of Austrian import fibre ribbon and with machine and domestic fibre ribbon and be with on machine and produce, speed of production is from 200m/min~1400m/min, the fibre ribbon of manufacturing is smooth, smooth, and indices has all reached the requirement of YD/T979-2009.
A kind of fibre ribbon, it includes 2~24 optical fiber 2, it is characterized in that described optical fiber is horizontally, and the distance maximum between the center of adjacent fiber is 270 μ m, the flatness maximum of fibre ribbon is 35 μ m, and described optical fiber is by 1 integral coating of matrix material described above.
A kind of optical cable; the restrictive coating 6 that it includes loose sleeve pipe 3, be coated on protective layer 4 outside loose sleeve pipe, be positioned at reinforcement 5 outside protective layer, protective layer and reinforcement are enveloped; it is characterized in that in loose sleeve pipe, thering are many fibre ribbons described above; the matrix material 1 that has multifiber 2 in every fibre ribbon and multifiber integral coating is lived, does not contain the fibre ribbon visible filler of eyesight in addition in the gap of loose sleeve pipe.
A kind of layer-twisted optical fiber ribbon cable, it includes the many loose sleeve pipes 3 that are positioned at outside reinforcement 5, be arranged in the little gasket for packing 7 of the external series gap of adjacent loose sleeve pipe, pine sleeve pipe and little gasket for packing have protective layer 4 outward, the outer extrusion molding of protective layer is coated with restrictive coating 6, it is characterized in that in every loose sleeve pipe, thering are many fibre ribbons described above, the matrix material 1 that there is multifiber 2 in every fibre ribbon and multifiber integral coating is lived, in the gap of pine sleeve pipe, do not contain the fibre ribbon visible filler of other eyesight in addition, pine sleeve pipe, reinforcement, little gasket for packing, in the gap that protective layer forms, do not contain the visible filler of eyesight.
A kind of layer-twisted optical fiber ribbon cable, it includes the loose sleeve pipe 3 and the large gasket for packing that are positioned at outside reinforcement 5, be arranged in the little gasket for packing 7 of the external series gap of the external series gap of adjacent loose sleeve pipe and adjacent loose sleeve pipe and large gasket for packing and the external series gap of adjacent large gasket for packing, pine sleeve pipe and large gasket for packing and little gasket for packing have protective layer 4 outward, the outer extrusion molding of protective layer is coated with restrictive coating 6, it is characterized in that in every loose sleeve pipe, thering are many fibre ribbons described above, the matrix material 1 that there is multifiber 2 in every fibre ribbon and multifiber integral coating is lived, in the gap of pine sleeve pipe, do not contain the fibre ribbon visible filler of other eyesight in addition, pine sleeve pipe, reinforcement, large gasket for packing, little gasket for packing, in the gap that protective layer forms, do not contain the visible filler of eyesight.
Optical cable described above, the material that it is characterized in that described loose sleeve pipe is polybutylene terephthalate (PBT) or polypropylene or polytetrafluoroethylene (PTFE).
Optical cable described above, the material that it is characterized in that described little gasket for packing is polypropylene or polyethylene.
Optical cable described above, the material that it is characterized in that described large gasket for packing is polypropylene or polyethylene.
Optical cable described above, the material that it is characterized in that described protective layer is steel band or aluminium strip or steel wire.
Optical cable described above, the material that it is characterized in that described reinforcement is steel wire or copper wire or fiberglass-reinforced plastic lever.
Optical cable described above, the material that it is characterized in that described restrictive coating is low density polyethylene (LDPE) or medium density polyethylene or high density polyethylene (HDPE) or polyvinyl chloride or low smoke and zero halogen polyethylene or nylon.
Matrix material in the present invention has makes the beneficial effects such as simple, product qualified rate is high, raw material is easily purchased, fibre ribbon in the present invention, owing to having adopted above-mentioned matrix material, the material of matrix material is to refuse water type, therefore, and when moisture enters, due to stopping of matrix material layer, moisture can not invaded optical fiber, and optical fiber can not cause because of hydrionic introducing the increase of loss, the even fracture of optical fiber, and the cost increase that in fibre ribbon, also tape tree refers to is quite few, and the speed of production of fibre ribbon has no effect, optical cable in the present invention, because fibre ribbon has had block-water performance, therefore no longer need factice for filling, water-proofing powder, the material that blocks water such as water blocking yarn, be not only in loose sleeve pipe and do not need, and also do not need in cable core gap, therefore saved widely optical cable cost, make to construct more convenient, production environment is more clean, when inspection and construction, do not need to adopt cloth or stationery material to carry out wiping to ointment, when use because ointment does not exist, therefore do not pollute the environment, owing to not needing the ointment class material that blocks water, therefore optical cable weight obviously alleviates, cost of transportation obviously reduces, and the trouble of having saved buying and having stored.
Therefore, the present invention has following main beneficial effect: fibre ribbon block-water performance is better, optical cable cost is lower, more low-carbon environment-friendly, weight lighter, check and construct more convenient, production environment is more clean.
Brief description of the drawings
Fig. 1 is the first embodiment cross-sectional structure schematic diagram of the present invention's fibre ribbon of using matrix material.
Fig. 2 is the second embodiment cross-sectional structure schematic diagram of the present invention's fibre ribbon of using matrix material.
Fig. 3 is the cross-sectional structure schematic diagram that the present invention uses the 3rd embodiment of fibre ribbon.
Fig. 4 is the cross-sectional structure schematic diagram that the present invention uses the 4th embodiment of fibre ribbon.
Detailed description of the invention
In the present invention, embodiment 1 is matrix material embodiment, the embodiment that embodiment 2,3 is fibre ribbon, the embodiment that embodiment 4,5,6 is optical cable.
Embodiment 1
Matrix material, is characterized in that it comprises following raw material by weight: polyacrylic resin: the ultra-violet curing agent that 90~95 parts, commercially available model are 3091: the ultraviolet initiator that 3~5 parts, commercially available model are UV500: the polyisobutene that 6~8 parts, commercially available model are PB2400: the macromolecular thermoplastic synthetic rubber that 5~8 parts, commercially available model are SV150: the cable antioxidant that 3~5 parts, commercially available model are L-1035: 1~2 part, manganese carboxylate: 1~2 part, carboxylic acid potassium: 1~2 part, sodium fluoride: 2~4 parts.
Above-mentioned matrix material, most preferred formula is: it comprises following raw material by weight: polyacrylic resin: the ultra-violet curing agent that 93 parts, commercially available model are 3091: the ultraviolet initiator that 4 parts, commercially available model are UV500: the polyisobutene that 7 parts, commercially available model are PB2400: the macromolecular thermoplastic synthetic rubber that 6 parts, commercially available model are SV150: the cable antioxidant that 4 parts, commercially available model are L-1035: 1.5 parts, manganese carboxylate: 1.5 parts, carboxylic acid potassium: 15. parts, sodium fluoride: 3 parts.
Above-mentioned matrix material, more preferably formula is: it comprises following raw material by weight: polyacrylic resin: the ultra-violet curing agent that 90 parts, commercially available model are 3091: the ultraviolet initiator that 3 parts, commercially available model are UV500: the polyisobutene that 6 parts, commercially available model are PB2400: the macromolecular thermoplastic synthetic rubber that 5 parts, commercially available model are SV150: the cable antioxidant that 3 parts, commercially available model are L-1035: 1 part, manganese carboxylate: 1 part, carboxylic acid potassium: 1 part, sodium fluoride: 2 parts.
Above-mentioned matrix material, more preferably formula is: it comprises following raw material by weight: polyacrylic resin: the ultra-violet curing agent that 95 parts, commercially available model are 3091: the ultraviolet initiator that 5 parts, commercially available model are UV500: the polyisobutene that 8 parts, commercially available model are PB2400: the macromolecular thermoplastic synthetic rubber that 8 parts, commercially available model are SV150: the cable antioxidant that 5 parts, commercially available model are L-1035: 2 parts, manganese carboxylate: 2 parts, carboxylic acid potassium: 2 parts, sodium fluoride: 4 parts.
Commercially available model is that the macromolecular thermoplastic synthetic rubber of SV150 is produced by Infineum company; Commercially available model is that the cable antioxidant of L-1035 is produced by Ciba (China) Co., Ltd.
The formula of above-mentioned matrix material, through test, has reached following technical performance index: 25 DEG C time: viscosity: 3800 ± 200MPas; Modulus: 850 ± 50MPa; Percentage elongation: >=20%; Anti-intensity: the 25 ± 5MPa that stretches; 25 DEG C, pressure are 2 standard atmospheric pressures, soaking time 180 days: infiltration probability: be not more than ten thousand/.
Above-mentioned matrix material is at the MS of Austrian import fibre ribbon and with machine and domestic fibre ribbon and be with on machine and produce, speed of production is from 200m/min~1400m/min, the fibre ribbon of manufacturing is smooth, smooth, and indices has all reached the requirement of YD/T979-2009.
Embodiment 2
Ask for an interview Fig. 1, a kind of fibre ribbon, it includes 6 optical fiber 2, it is characterized in that described optical fiber is horizontal, distance maximum between the center of adjacent fiber is 270 μ m, and the flatness maximum of fibre ribbon is 35 μ m, and described optical fiber is implemented 1 integral coating of matrix material described in example 1.
Embodiment 3
Ask for an interview Fig. 2, a kind of fibre ribbon, it includes 12 optical fiber 2, it is characterized in that described optical fiber is horizontal, distance maximum between the center of adjacent fiber is 270 μ m, and the flatness maximum of fibre ribbon is 35 μ m, and described optical fiber is implemented 1 integral coating of matrix material described in example 1.
In fibre ribbon described in embodiment, the quantity of optical fiber is not limited to 6 and 12, also can be other integer root in 2~24.
Embodiment 4
Ask for an interview Fig. 3; a kind of optical cable; the restrictive coating 6 that it includes loose sleeve pipe 3, be coated on protective layer 4 outside loose sleeve pipe, be positioned at reinforcement 5 outside protective layer, protective layer and reinforcement are enveloped; it is characterized in that in loose sleeve pipe, thering are many fibre ribbons described above; the matrix material 1 that has multifiber 2 in every fibre ribbon and multifiber integral coating is lived, does not contain the fibre ribbon visible filler of eyesight in addition in the gap of loose sleeve pipe.
Embodiment 5
Ask for an interview Fig. 4, a kind of layer-twisted optical fiber ribbon cable, it includes the 3 and 1 large gasket for packing of 4 loose sleeve pipes being positioned at outside reinforcement 5, be arranged in the little gasket for packing 7 of the external series gap of adjacent loose sleeve pipe and adjacent loose sleeve pipe and the external series gap of large gasket for packing, pine sleeve pipe and large gasket for packing and little gasket for packing have protective layer 4 outward, the outer extrusion molding of protective layer is coated with restrictive coating 6, it is characterized in that having in every loose sleeve pipe the fibre ribbon described in many embodiments 2 or embodiment 3, the matrix material 1 that there is multifiber 2 in every fibre ribbon and multifiber integral coating is lived, in the gap of pine sleeve pipe, do not contain the fibre ribbon visible filler of other eyesight in addition, pine sleeve pipe, reinforcement, large gasket for packing, little gasket for packing, in the gap that protective layer forms, do not contain the visible filler of eyesight.
Certainly, in a kind of layer-twisted optical fiber ribbon cable described above, can also there be many loose sleeve pipes and many large gasket for packings, or there are a loose sleeve pipe and many large gasket for packings, or there is other many loose sleeve pipes and a gasket for packing, now, a kind of optical cable, it includes the loose sleeve pipe 3 and the large gasket for packing that are positioned at outside reinforcement 5, be arranged in the little gasket for packing 7 of the external series gap of the external series gap of adjacent loose sleeve pipe and adjacent loose sleeve pipe and large gasket for packing and the external series gap of adjacent large gasket for packing, pine sleeve pipe and large gasket for packing and little gasket for packing have protective layer 4 outward, the outer extrusion molding of protective layer is coated with restrictive coating 6, it is characterized in that having in every loose sleeve pipe the fibre ribbon described in many embodiments 2 or embodiment 3, the matrix material 1 that there is multifiber 2 in every fibre ribbon and multifiber integral coating is lived, in the gap of pine sleeve pipe, do not contain the fibre ribbon visible filler of other eyesight in addition, pine sleeve pipe, reinforcement, large gasket for packing, little gasket for packing, in the gap that protective layer forms, do not contain the visible filler of eyesight.
Certainly,, in embodiment 4-6, in loose sleeve pipe, only there is a fibre ribbon and also should be the application's protection domain.
Embodiment 6
A kind of layer-twisted optical fiber ribbon cable, it includes the many loose sleeve pipes 3 that are positioned at outside reinforcement 5, be arranged in the little gasket for packing 7 of the external series gap of adjacent loose sleeve pipe, pine sleeve pipe and little gasket for packing have protective layer 4 outward, the outer extrusion molding of protective layer is coated with restrictive coating 6, it is characterized in that in every loose sleeve pipe, thering are many fibre ribbons described above, the matrix material 1 that there is multifiber 2 in every fibre ribbon and multifiber integral coating is lived, in the gap of pine sleeve pipe, do not contain the fibre ribbon visible filler of other eyesight in addition, pine sleeve pipe, reinforcement, little gasket for packing, in the gap that protective layer forms, do not contain the visible filler of eyesight.
Embodiment 4 is to any one layer-twisted optical fiber ribbon cable described in embodiment 6, and the material that it is characterized in that described loose sleeve pipe is polybutylene terephthalate (PBT) or polypropylene or polytetrafluoroethylene (PTFE).
A kind of layer-twisted optical fiber ribbon cable described in embodiment 5, the material that it is characterized in that described little gasket for packing is polypropylene or polyethylene.
A kind of layer-twisted optical fiber ribbon cable described in embodiment 5, the material that it is characterized in that described large gasket for packing is polypropylene or polyethylene.
Embodiment 4 is to any one optical cable described in embodiment 6, and the material that it is characterized in that described protective layer is steel band or aluminium strip or steel wire.
Embodiment 4 is to any one optical cable described in embodiment 6, and the material that it is characterized in that described reinforcement is steel wire or copper wire or fiberglass-reinforced plastic lever.
Embodiment 4 is to any one optical cable described in embodiment 6, and the material that it is characterized in that described restrictive coating is low density polyethylene (LDPE) or medium density polyethylene or high density polyethylene (HDPE) or polyvinyl chloride or nylon.
Matrix material in the present invention has makes the beneficial effects such as simple, product qualified rate is high, raw material is easily purchased, fibre ribbon in the present invention, owing to having adopted above-mentioned matrix material, the material of matrix material is to refuse water type, therefore, and when moisture enters, due to stopping of matrix material layer, moisture can not invaded optical fiber, and optical fiber can not cause because of hydrionic introducing the increase of loss, the even fracture of optical fiber, and the cost increase that in fibre ribbon, also tape tree refers to is quite few, and the speed of production of fibre ribbon has no effect, optical cable in the present invention, because fibre ribbon has had block-water performance, therefore no longer need factice for filling, water-proofing powder, the material that blocks water such as water blocking yarn, be not only in loose sleeve pipe and do not need, and also do not need in cable core gap, therefore saved widely optical cable cost, make to construct more convenient, production environment is more clean, when inspection and construction, do not need to adopt cloth or stationery material to carry out wiping to ointment, when use because ointment does not exist, therefore do not pollute the environment, owing to not needing the ointment class material that blocks water, therefore optical cable weight obviously alleviates, cost of transportation obviously reduces, and the trouble of having saved buying and having stored.
Therefore, the present invention has following main beneficial effect: fibre ribbon block-water performance is better, optical cable cost is lower, more low-carbon environment-friendly, weight lighter, check and construct more convenient, production environment is more clean.
The present invention is not limited to above-mentioned preferred forms, should be appreciated that design of the present invention can be by other various forms enforcement utilizations, and they drop in protection scope of the present invention equally.