CN105601040A - Ferric salt nitrogen and phosphorous removal device - Google Patents
Ferric salt nitrogen and phosphorous removal device Download PDFInfo
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- CN105601040A CN105601040A CN201610016350.6A CN201610016350A CN105601040A CN 105601040 A CN105601040 A CN 105601040A CN 201610016350 A CN201610016350 A CN 201610016350A CN 105601040 A CN105601040 A CN 105601040A
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 title claims description 24
- 229910052757 nitrogen Inorganic materials 0.000 title claims description 13
- 150000003839 salts Chemical class 0.000 title claims description 8
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 title 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 115
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 115
- 239000011574 phosphorus Substances 0.000 claims abstract description 115
- 150000002505 iron Chemical class 0.000 claims abstract description 64
- 238000000926 separation method Methods 0.000 claims abstract description 36
- 239000010802 sludge Substances 0.000 claims abstract description 32
- 238000003756 stirring Methods 0.000 claims abstract description 29
- 238000006243 chemical reaction Methods 0.000 claims abstract description 27
- 230000001105 regulatory effect Effects 0.000 claims abstract description 25
- 238000002156 mixing Methods 0.000 claims abstract description 22
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000011144 upstream manufacturing Methods 0.000 claims abstract description 19
- 238000004062 sedimentation Methods 0.000 claims abstract description 17
- 239000013049 sediment Substances 0.000 claims abstract description 14
- 238000005192 partition Methods 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 229910052742 iron Inorganic materials 0.000 claims abstract description 10
- 239000002912 waste gas Substances 0.000 claims abstract description 10
- 238000005273 aeration Methods 0.000 claims abstract description 9
- 238000001914 filtration Methods 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 5
- 239000002351 wastewater Substances 0.000 claims description 52
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 44
- 238000000034 method Methods 0.000 claims description 20
- 238000001556 precipitation Methods 0.000 claims description 13
- 239000000945 filler Substances 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 11
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 6
- 238000004065 wastewater treatment Methods 0.000 claims description 6
- 238000005842 biochemical reaction Methods 0.000 claims description 5
- 238000009826 distribution Methods 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 238000012856 packing Methods 0.000 claims description 4
- 230000005484 gravity Effects 0.000 claims description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 2
- 239000011259 mixed solution Substances 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 description 12
- 238000010170 biological method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000010586 diagram Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 238000012851 eutrophication Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000192710 Microcystis aeruginosa Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003653 coastal water Substances 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 159000000014 iron salts Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- DPTATFGPDCLUTF-UHFFFAOYSA-N phosphanylidyneiron Chemical compound [Fe]#P DPTATFGPDCLUTF-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
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- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
Abstract
一种铁盐脱氮除磷装置,包括调节池、铁盐脱氮除磷池和折流式曝气生化滤池;铁盐脱氮除磷池包括除磷搅拌混合反应区、沉淀分离区、生化脱氮区和过滤区,除磷搅拌混合反应区中上部设有铁盐脱氮除磷池进水管和回流管,除磷搅拌混合反应区设有除磷剂添加和计量系统,除磷搅拌混合反应区和沉淀分离区之间设有隔板,沉淀分离区底部设置有沉淀物排放阀;生化脱氮区位于沉淀分离区的上部,沉淀分离区和生化脱氮区之间设有隔网,隔网上部布设有铁屑,过滤区位于生化脱氮区的上部,过滤区中设有脱氮区滤料,铁盐脱氮除磷池的上部设有废气收集管;折流式曝气生化滤池中上部为圆柱形、下部为圆锥形结构,包括下流区、上流区和污泥区。
An iron salt denitrification and phosphorus removal device includes a regulating tank, an iron salt denitrification and phosphorus removal tank and a baffle type aerated biochemical filter; the iron salt denitrification and phosphorus removal tank includes a phosphorus removal stirring mixing reaction zone, a sedimentation separation zone, The biochemical denitrification area and filtration area, the upper part of the phosphorus removal stirring and mixing reaction area are equipped with iron salt denitrification and phosphorus removal pool inlet pipes and return pipes, and the phosphorus removal stirring mixing reaction area is equipped with a phosphorus removal agent adding and metering system. There is a partition between the mixing reaction area and the sedimentation separation area, and a sediment discharge valve is installed at the bottom of the sedimentation separation area; the biochemical denitrification area is located on the upper part of the sedimentation separation area, and there is a partition net between the sedimentation separation area and the biochemical denitrification area , the upper part of the net is equipped with iron filings, the filter area is located in the upper part of the biochemical denitrification area, the filter material of the denitrification area is set in the filter area, and the upper part of the iron salt denitrification and phosphorus removal tank is equipped with a waste gas collection pipe; baffled aeration The upper part of the biochemical filter is cylindrical and the lower part is a conical structure, including the downstream area, the upstream area and the sludge area.
Description
技术领域technical field
本发明涉及废水处理技术领域,具体涉及一种铁盐脱氮除磷装置。The invention relates to the technical field of wastewater treatment, in particular to an iron salt denitrification and dephosphorization device.
背景技术Background technique
氮磷污染所致的湖泊“水华”及近海“赤潮”频频发生,已危及农业、渔业、旅游业等诸多行业,并对饮水卫生和食品安全构成严重威胁。氮磷污染物量大面广,其控制已成为我国亟待解决的重大环保课题。The frequent occurrence of "water blooms" in lakes and "red tides" in coastal waters caused by nitrogen and phosphorus pollution has endangered many industries such as agriculture, fishery, tourism, and poses a serious threat to drinking water sanitation and food safety. The amount of nitrogen and phosphorus pollutants is large and wide, and its control has become a major environmental protection issue to be solved urgently in our country.
由于氮素污染的种种危害,废水氮素污染控制得到了国际社会的广泛重视。废水脱氮技术主要分为物化法和生物法两大类。其中,生物法因其经济有效、环境友好等优点而得到广泛应用。废水生物脱氮主要包括硝化作用、反硝化作用、短程硝化作用和厌氧氨氧化作用,包括以硝化工艺、反硝化工艺为代表的传统生物脱氮技术和以短程硝化工艺、厌氧氨氧化工艺为代表的新型生物脱氮技术。随着生物脱氮理论与技术的突破,以短程硝化工艺和厌氧氨氧化工艺为代表的新型生物脱氮技术不断涌现。废水生物处理技术是废水治理的主流技术,以短程硝化.厌氧氨氧化工艺为代表的新型脱氮技术,为废水的高效、低耗脱氮带来了前景。但由于短程硝化工艺和厌氧氨氧化工艺的控制比较复杂,厌氧氨氧化菌难以培养且倍增时间很长等问题的限制,实际工程应用迄今为数较少。以硝化、反硝化工艺为代表的传统脱氮技术在未来一段时间内仍将是废水生物脱氮的主流技术。在废水处理技术中,经过生物处理,废水COD浓度基本达标,但氮磷浓度依然超标。对于这类低C:N比废水,传统生物脱氮工艺已显乏力,这是因为反硝化过程需要电子供体,通常由有机物提供。碳源相对不足已成为传统生物脱氮技术的重大瓶颈因子。Due to the various hazards of nitrogen pollution, the control of nitrogen pollution in wastewater has received extensive attention from the international community. Wastewater denitrification technologies are mainly divided into two categories: physical and chemical methods and biological methods. Among them, the biological method has been widely used because of its advantages of cost-effectiveness and environmental friendliness. Biological denitrification of wastewater mainly includes nitrification, denitrification, short-cut nitrification and anammox A new type of biological denitrification technology represented. With the breakthrough of biological nitrogen removal theory and technology, new biological nitrogen removal technologies represented by short-cut nitrification process and anammox process continue to emerge. Wastewater biological treatment technology is the mainstream technology of wastewater treatment. The new denitrification technology represented by short-range nitrification and anammox process has brought prospects for efficient and low-consumption denitrification of wastewater. However, due to the complexity of the control of the short-cut nitrification process and the anammox process, the difficulty of cultivating anammox bacteria and the long doubling time and other limitations, the number of practical engineering applications has so far been small. The traditional denitrification technology represented by nitrification and denitrification process will remain the mainstream technology for wastewater biological denitrification for a period of time in the future. In wastewater treatment technology, after biological treatment, the concentration of COD in wastewater basically reaches the standard, but the concentration of nitrogen and phosphorus still exceeds the standard. For such wastewater with a low C:N ratio, the traditional biological denitrification process has been weak, because the denitrification process requires electron donors, usually provided by organic matter. The relative shortage of carbon sources has become a major bottleneck factor for traditional biological denitrification technologies.
磷素是导致水体富营养化的主要致因之一,废水除磷是防止水体富营养化的有效途径。废水除磷技术主要分为化学法和生物法两大类。生物法因其经济有效、环境友好等优点而得到广泛应用。但同时也面临着反应时间长、设备占地面积大、污泥处理困难等问题。化学除磷法因其经济高效、操作简便、效果可靠,且不易受废水水质影响等优点而被推广应用。迄今为止,化学除磷法仍是主要除磷工艺。化学除磷主要通过向废水中投加化学药剂形成不溶性磷酸盐沉淀物,然后经过固液分离将磷从污水中去除。由于铁系絮凝剂价格便宜,且对多种水质条件下的磷污染物均有良好的去除效果,因此应用广泛,废水化学除磷技术是防治水体磷污染的有效途径。虽然铁盐被广泛用于废水除磷,展现了工艺简单、除磷高效、运行稳定等优势,但仍存在着药剂投加量大、污泥产量高等问题,因此,铁盐除磷工艺亟待系统优化。Phosphorus is one of the main causes of water eutrophication, and phosphorus removal from wastewater is an effective way to prevent water eutrophication. Wastewater phosphorus removal technology is mainly divided into two categories: chemical method and biological method. Biological methods have been widely used because of their advantages of cost-effectiveness and environmental friendliness. But at the same time, it also faces problems such as long reaction time, large equipment footprint, and difficult sludge treatment. The chemical phosphorus removal method has been popularized and applied because of its advantages of cost-effectiveness, simple operation, reliable effect, and not easily affected by the quality of wastewater. So far, chemical phosphorus removal method is still the main phosphorus removal process. Chemical phosphorus removal mainly forms insoluble phosphate precipitates by adding chemicals to wastewater, and then removes phosphorus from sewage through solid-liquid separation. Because iron-based flocculants are cheap and have good removal effects on phosphorus pollutants under various water quality conditions, they are widely used. Chemical phosphorus removal technology from wastewater is an effective way to prevent phosphorus pollution in water bodies. Although iron salt is widely used in wastewater phosphorus removal, showing the advantages of simple process, efficient phosphorus removal, and stable operation, there are still problems such as large dosage of chemicals and high sludge production. Therefore, the iron salt phosphorus removal process needs to be systematically developed optimization.
发明内容Contents of the invention
本发明要解决的技术问题是:为了解决上述高氮磷废水处理中的难题,本发明提供一种铁盐脱氮除磷装置。The technical problem to be solved by the present invention is: in order to solve the above-mentioned difficult problems in the treatment of high-nitrogen and phosphorus wastewater, the present invention provides an iron salt denitrification and dephosphorization device.
本发明解决其技术问题所采用的技术方案是:一种铁盐脱氮除磷装置,包括调节池、铁盐脱氮除磷池和折流式曝气生化滤池,所述调节池、铁盐脱氮除磷池和折流式曝气生化滤池依次连通。The technical solution adopted by the present invention to solve the technical problem is: a device for denitrification and dephosphorization of iron salts, including a regulating tank, a denitrification and dephosphorization tank for ferric salts and a baffle type aerated biochemical filter, the regulating tank, iron The salt denitrification and phosphorus removal tank and the baffle type aerated biochemical filter are connected in sequence.
所述的调节池包括调节池进水管和调节池出水管,用于调节高氮磷废水的水质和水量。The regulating pond includes a regulating pond inlet pipe and a regulating pond outlet pipe for regulating the water quality and water quantity of high nitrogen and phosphorus wastewater.
所述的铁盐脱氮除磷池包括除磷搅拌混合反应区、沉淀分离区、生化脱氮区和过滤区;所述的除磷搅拌混合反应区中上部设有铁盐脱氮除磷池进水管和接收来自生化脱氮区的废水的回流管,除磷搅拌混合反应区上部设有除磷剂添加和计量系统,除磷搅拌混合反应区中部设有搅拌装置,除磷搅拌混合反应区的底部设计有45度角的倾斜底板或弧形底板,避免产生水流死角;所述的除磷搅拌混合反应区和沉淀分离区之间设有隔板,隔板和铁盐脱氮除磷池的底板形成水流通道,沉淀分离区底部设计成锥形结构,在锥形结构的下端设置有沉淀物排放阀;所述的生化脱氮区位于沉淀分离区的上部,沉淀分离区和生化脱氮区之间设有隔网,隔网上部布设有铁屑;所述的过滤区位于生化脱氮区的上部,过滤区中设有脱氮区滤料,过滤区的上部设有铁盐脱氮除磷池溢水堰,铁盐脱氮除磷池溢水堰连接铁盐脱氮除磷池出水管;铁盐脱氮除磷池的上部设有锥形上盖,锥形上盖的顶端设有废气收集管。The iron salt denitrification and phosphorus removal pool includes a phosphorus removal stirring and mixing reaction area, a precipitation separation area, a biochemical denitrification area and a filtration area; the upper part of the phosphorus removal stirring mixing reaction area is equipped with an iron salt denitrification and phosphorus removal pool The water inlet pipe and the return pipe for receiving wastewater from the biochemical denitrification area, the phosphorus removal agent addition and metering system are installed in the upper part of the phosphorus removal stirring mixing reaction area, the stirring device is installed in the middle of the phosphorus removal stirring mixing reaction area, and the phosphorus removal stirring mixing reaction area The bottom of the tank is designed with a 45-degree inclined bottom plate or an arc-shaped bottom plate to avoid dead corners of water flow; a partition is provided between the stirring and mixing reaction zone for phosphorus removal and the precipitation separation zone, and the partition and the iron salt denitrification and phosphorus removal pool The bottom plate of the bottom plate forms a water flow channel, and the bottom of the sedimentation separation area is designed as a conical structure, and a sediment discharge valve is arranged at the lower end of the conical structure; There is a screen between the areas, and iron filings are arranged on the upper part of the screen; the filter area is located on the upper part of the biochemical denitrification area, and the filter material of the denitrification area is provided in the filter area, and the iron salt denitrification area is installed on the upper part of the filter area. The overflow weir of the phosphorus removal tank, the overflow weir of the iron salt denitrification and phosphorus removal tank is connected to the outlet pipe of the iron salt denitrification and phosphorus removal tank; the upper part of the iron salt denitrification and phosphorus removal tank is provided with a conical upper cover, and the top of the Exhaust gas collection pipe.
所述的铁盐脱氮除磷池出水管与折流式曝气生化滤池进水管连通。The outlet pipe of the iron salt denitrification and phosphorus removal tank is connected with the water inlet pipe of the baffle type aerated biochemical filter.
所述折流式曝气生化滤池中上部为圆柱形、下部为圆锥形结构,包括下流区、上流区和污泥区;所述下流区位于折流式曝气生化滤池的圆柱形结构的中部,为圆柱形结构,下流区上部设有折流式曝气生化滤池进水管和折流式曝气生化滤池布水管,下流区中部设有下流区填料,下流区下部设有下流区曝气管,所述下流区的底部设有折流板,所述的折流板的纵断面呈喇叭状;所述上流区位于下流区的外围、折流板的上部,上流区中部设有上流区填料,下部设有上流区曝气管,上流区上部的出口处设有折流式曝气生化滤池溢水堰;所述污泥区位于折流式曝气生化滤池的底部、下流区和上流区的下部,污泥区的底部设有折流式曝气生化滤池污泥排放阀。The upper part of the baffle type aerated biochemical filter is cylindrical and the lower part is a conical structure, including a downstream area, an upper flow area and a sludge area; the downstream area is located in the cylindrical structure of the baffled aerated biochemical filter The middle part is a cylindrical structure. The upper part of the downstream area is equipped with a baffle type aerated biochemical filter inlet pipe and a baffled aerated biochemical filter water distribution pipe. Area aeration pipe, the bottom of the downstream area is provided with a baffle plate, and the longitudinal section of the baffle plate is trumpet-shaped; There is filler in the upstream area, the lower part is equipped with an aeration pipe in the upstream area, and the outlet of the upper part of the upstream area is provided with an overflow weir of a baffled aerated biochemical filter; the sludge area is located at the bottom of the baffled biochemical aerated filter, The lower part of the downstream zone and the upstream zone, and the bottom of the sludge zone are provided with a baffle type aerated biochemical filter sludge discharge valve.
一种采用上述铁盐脱氮除磷装置进行废水处理的方法,具有如下步骤:A method for wastewater treatment using the above-mentioned iron salt denitrification and phosphorus removal device has the following steps:
①废水通过调节池进水管进入调节池,调节水质和水量。①Wastewater enters the regulating pond through the inlet pipe of the regulating pond to adjust the water quality and quantity.
②然后废水通过铁盐脱氮除磷池进水管进入铁盐脱氮除磷池,与来自回流管的回流废水和来自除磷剂添加和计量系统的除磷剂混合,搅拌装置对混合液进行搅拌混合,进行化学除磷反应,反应后的废水通过隔板和铁盐脱氮除磷池的底板形成的水流通道进入沉淀分离区进行固液分离,沉淀物在重力的作用下下沉到沉淀分离区的下部,通过底部的沉淀物排放阀排出。② Then the wastewater enters the iron salt denitrification and phosphorus removal tank through the inlet pipe of the iron salt denitrification and phosphorus removal tank, and is mixed with the return wastewater from the return pipe and the dephosphorization agent from the dephosphorization agent addition and metering system, and the mixed solution is mixed by the stirring device Stir and mix to carry out chemical phosphorus removal reaction. After the reaction, the waste water enters the sedimentation separation area through the water flow channel formed by the separator and the bottom plate of the iron salt denitrification and phosphorus removal tank for solid-liquid separation, and the sediment sinks to the sedimentation area under the action of gravity. The lower part of the separation zone is discharged through the sediment discharge valve at the bottom.
③沉淀后的废水通过沉淀分离区和生化脱氮区之间的隔网进入生化脱氮区,废水将隔网上的铁屑溶解为二价铁,含二价铁的废水进入生化脱氮区进行生化脱氮,生化脱氮后的废水进入过滤区进行过滤,过滤后的废水通过铁盐脱氮除磷池溢水堰、铁盐脱氮除磷池出水管进入折流式曝气生化滤池进水管。③The wastewater after precipitation enters the biochemical denitrification area through the separation net between the sedimentation separation area and the biochemical denitrification area. Biochemical denitrification, the wastewater after biochemical denitrification enters the filter area for filtration, and the filtered wastewater enters the baffled aerated biochemical filter through the overflow weir of the iron salt denitrification and phosphorus removal tank and the outlet pipe of the iron salt denitrification and phosphorus removal tank. water pipe.
④铁盐脱氮除磷池产生的甲烷废气通过铁盐脱氮除磷池锥形上盖顶端的废气收集管收集排放。④ The methane waste gas generated by the iron salt denitrification and phosphorus removal tank is collected and discharged through the waste gas collection pipe on the top of the conical upper cover of the iron salt denitrification and phosphorus removal tank.
⑤废水通过折流式曝气生化滤池进水管、折流式曝气生化滤池布水管进入折流式曝气生化滤池的下流区,下流区曝气管产生的空气与废水在下流区填料中交汇发生生化反应,同时下流区填料对废水进行过滤,废水通过折流板后进入上流区,在上流区填料中发生生化反应,同时上流区填料对废水进行过滤,下流区和上流区产生的污泥下沉到污泥区,通过污泥区底部的污泥排放阀排放出去,折流式曝气生化滤池处理后的水通过折流式曝气生化滤池溢水堰达标排放。⑤Wastewater enters the downstream area of the baffled aerated biochemical filter through the water inlet pipe of the baffled aerated biochemical filter and the water distribution pipe of the baffled aerated biochemical filter. Biochemical reactions occur at the intersection of the fillers, and at the same time, the fillers in the downstream area filter the wastewater. The sludge sinks to the sludge area and is discharged through the sludge discharge valve at the bottom of the sludge area, and the water treated by the baffle type aerated biochemical filter is discharged up to the standard through the overflow weir of the baffle type aerated biochemical filter.
⑥铁盐脱氮除磷池产生的沉淀物和折流式曝气生化滤池产生的剩余污泥脱水后外运。⑥ The sediment produced by the iron salt denitrification and phosphorus removal tank and the remaining sludge produced by the baffle type aerated biochemical filter are dehydrated and then shipped out.
本发明的有益效果是:因地制宜,基建投资少,维护方便,能耗较低,对高氮磷废水具有比较好的处理效果。The invention has the beneficial effects of adapting measures to local conditions, less infrastructure investment, convenient maintenance, lower energy consumption, and better treatment effect on high-nitrogen and phosphorus wastewater.
附图说明Description of drawings
下面结合附图和实施例对本发明进一步说明。The present invention will be further described below in conjunction with the accompanying drawings and embodiments.
图1是本发明实施例铁盐脱氮除磷池的结构示意图。Fig. 1 is a schematic structural view of an iron salt denitrification and dephosphorization pool according to an embodiment of the present invention.
图1中:1.铁盐脱氮除磷池,1-1.除磷搅拌混合反应区,1-2.沉淀分离区,1-3.生化脱氮区,1-4.过滤区,1-5.铁盐脱氮除磷池进水管,1-6.回流管,1-7.除磷剂添加和计量系统,1-8.搅拌装置,1-9.隔板,1-10.沉淀物排放阀,1-11.隔网,1-12.脱氮区滤料,1-13.铁盐脱氮除磷池溢水堰,1-14.上盖,1-15.废气收集管。In Figure 1: 1. Iron salt denitrification and phosphorus removal pool, 1-1. Phosphorus removal stirring mixed reaction zone, 1-2. Precipitation separation zone, 1-3. Biochemical denitrification zone, 1-4. Filtration zone, 1 -5. Inlet pipe of iron salt denitrification and phosphorus removal pool, 1-6. Return pipe, 1-7. Dephosphorization agent addition and metering system, 1-8. Stirring device, 1-9. Partition plate, 1-10. Sediment discharge valve, 1-11. Screen separation, 1-12. Filter material in denitrification area, 1-13. Overflow weir of iron salt denitrification and phosphorus removal tank, 1-14. Upper cover, 1-15. Waste gas collection pipe .
图2是本发明实施例折流式曝气生化滤池的结构示意图。Fig. 2 is a schematic structural view of a baffle type aerated biochemical filter according to an embodiment of the present invention.
图2中:2.折流式曝气生化滤池,2-1.下流区,2-2.上流区,2-3.污泥区,2-4.折流式曝气生化滤池进水管,2-5.折流式曝气生化滤池布水管,2-6.下流区填料,2-7.下流区曝气管,2-8.折流板,2-9.上流区填料,2-10.折流式曝气生化滤池溢水堰,2-11.污泥排放阀。Among Fig. 2: 2. baffle type aerated biochemical filter, 2-1. downstream area, 2-2. upflow area, 2-3. sludge area, 2-4. baffle type aerated biochemical filter enters Water pipes, 2-5. Distributing pipes of baffled aerated biochemical filter, 2-6. Filling in downstream area, 2-7. Aeration pipe in downstream area, 2-8. Baffle plate, 2-9. Filling in upstream area , 2-10. Baffled aerated biochemical filter overflow weir, 2-11. Sludge discharge valve.
图3是本发明实施例的工艺流程图。Fig. 3 is a process flow diagram of an embodiment of the present invention.
具体实施方式detailed description
现在结合附图对本发明作进一步详细的说明。这些附图均为简化的示意图,仅以示意方式说明本发明的基本结构,因此其仅显示与本发明有关的构成。The present invention is described in further detail now in conjunction with accompanying drawing. These drawings are all simplified schematic diagrams, and only illustrate the basic structure of the present invention in a schematic manner, so they only show the configurations related to the present invention.
实施例Example
如图1~图3所示,本发明一种铁盐脱氮除磷装置,包括调节池、铁盐脱氮除磷池1和折流式曝气生化滤池2,所述调节池、铁盐脱氮除磷池1和折流式曝气生化滤池2依次连通。As shown in Figures 1 to 3, an iron salt denitrification and phosphorus removal device of the present invention includes a regulating tank, a ferric salt denitrification and phosphorus removal tank 1 and a baffle type aerated biochemical filter tank 2, the regulating tank, iron The salt denitrification and phosphorus removal tank 1 and the baffle type aerated biochemical filter tank 2 are connected in sequence.
所述的调节池包括调节池进水管和调节池出水管,用于调节高氮磷废水的水质和水量。The regulating pond includes a regulating pond inlet pipe and a regulating pond outlet pipe for regulating the water quality and water quantity of high nitrogen and phosphorus wastewater.
所述的铁盐脱氮除磷池1包括除磷搅拌混合反应区1-1、沉淀分离区1-2、生化脱氮区1-3和过滤区1-4;所述的除磷搅拌混合反应区1-1中上部设有铁盐脱氮除磷池进水管1-5和接收来自生化脱氮区的废水的回流管1-6,除磷搅拌混合反应区上部设有除磷剂添加和计量系统1-7,除磷搅拌混合反应区中部设有搅拌装置1-8,除磷搅拌混合反应区的底部设计有45度角的倾斜底板或弧形底板,避免产生水流死角;所述的除磷搅拌混合反应区和沉淀分离区之间设有隔板1-9,隔板和铁盐脱氮除磷池的底板形成水流通道,沉淀分离区底部设计成锥形结构,在锥形结构的下端设置有沉淀物排放阀1-10;所述的生化脱氮区1-3位于沉淀分离区1-2的上部,沉淀分离区和生化脱氮区之间设有隔网1-11,隔网上部布设有铁屑;所述的过滤区1-4位于生化脱氮区1-3的上部,过滤区中设有脱氮区滤料1-12,过滤区的上部设有铁盐脱氮除磷池溢水堰1-13,铁盐脱氮除磷池溢水堰连接铁盐脱氮除磷池出水管;铁盐脱氮除磷池的上部设有锥形上盖1-14,锥形上盖的顶端设有废气收集管1-15。The iron salt denitrification and phosphorus removal pool 1 includes a phosphorus removal stirring and mixing reaction zone 1-1, a precipitation separation zone 1-2, a biochemical denitrification zone 1-3 and a filtration zone 1-4; the phosphorus removal stirring and mixing The upper part of the reaction zone 1-1 is equipped with the inlet pipe 1-5 of the iron salt denitrification and phosphorus removal pool and the return pipe 1-6 for receiving the wastewater from the biochemical denitrification zone. And the metering system 1-7, the middle part of the phosphorus removal stirring mixing reaction zone is provided with a stirring device 1-8, and the bottom of the phosphorus removal stirring mixing reaction zone is designed with an inclined bottom plate or an arc bottom plate at an angle of 45 degrees, so as to avoid the dead angle of water flow; A partition 1-9 is arranged between the stirred mixing reaction zone and the precipitation separation zone for phosphorus removal, and the partition plate and the bottom plate of the iron salt denitrification and phosphorus removal tank form a water flow channel, and the bottom of the precipitation separation zone is designed as a conical structure. The lower end of the structure is provided with a sediment discharge valve 1-10; the biochemical denitrification zone 1-3 is located on the upper part of the sedimentation separation zone 1-2, and a screen 1-11 is arranged between the sedimentation separation zone and the biochemical denitrification zone , the upper part of the net is equipped with iron filings; the filter area 1-4 is located on the top of the biochemical denitrification area 1-3, the filter area is provided with a denitrification area filter material 1-12, and the upper part of the filter area is provided with iron salt The overflow weir 1-13 of the denitrification and phosphorus removal pool, the overflow weir of the iron salt denitrification and phosphorus removal pool is connected to the outlet pipe of the iron salt denitrification and phosphorus removal pool; the upper part of the iron salt denitrification and phosphorus removal pool is provided with a conical upper cover 1-14, The top of the conical loam cake is provided with a waste gas collecting pipe 1-15.
所述的铁盐脱氮除磷池出水管与折流式曝气生化滤池进水管2-4连通。The outlet pipe of the iron salt denitrification and phosphorus removal tank is connected with the water inlet pipe 2-4 of the baffle type aerated biochemical filter.
所述折流式曝气生化滤池2的中上部为圆柱形、下部为圆锥形结构,包括下流区2-1、上流区2-2和污泥区2-3;所述下流区2-1位于折流式曝气生化滤池的圆柱形结构的中部,为圆柱形结构,下流区上部设有折流式曝气生化滤池进水管2-4和折流式曝气生化滤池布水管2-5,下流区中部设有下流区填料2-6,下流区下部设有下流区曝气管2-7,所述下流区的底部设有折流板2-8,所述的折流板2-8的纵断面呈喇叭状;所述上流区2-2位于下流区2-1的外围、折流板的上部,上流区中部设有上流区填料2-9,下部设有上流区曝气管,上流区上部的出口处设有折流式曝气生化滤池溢水堰2-10;所述污泥区2-3位于折流式曝气生化滤池的底部、下流区和上流区的下部,污泥区的底部设有污泥排放阀2-11。The middle and upper part of the baffle type aerated biochemical filter 2 is cylindrical, and the lower part is a conical structure, including a downstream zone 2-1, an upstream zone 2-2 and a sludge zone 2-3; the downstream zone 2- 1 Located in the middle of the cylindrical structure of the baffled aerated biochemical filter, it is a cylindrical structure, and the upper part of the downstream area is provided with the water inlet pipe 2-4 of the baffled aerated biochemical filter and the cloth of the baffled aerated biochemical filter The water pipe 2-5, the middle part of the downstream area is provided with the filler 2-6 in the downstream area, the lower part of the downstream area is provided with the aeration pipe 2-7 in the downstream area, and the bottom of the downstream area is provided with a baffle plate 2-8. The longitudinal section of the flow plate 2-8 is trumpet-shaped; the upper flow area 2-2 is located at the periphery of the lower flow area 2-1 and the upper part of the baffle, and the middle part of the upper flow area is provided with an upper flow area filler 2-9, and the lower part is provided with an upper flow area. District aeration pipe, the outlet of the upper part of the upstream area is provided with a baffle type aerated biochemical filter overflow weir 2-10; the sludge area 2-3 is located at the bottom of the baffled type aerated biochemical filter, the downstream area and A sludge discharge valve 2-11 is provided at the bottom of the upstream zone and the bottom of the sludge zone.
一种采用上述铁盐脱氮除磷装置进行废水处理的方法,具有如下步骤:A method for wastewater treatment using the above-mentioned iron salt denitrification and phosphorus removal device has the following steps:
①废水通过调节池进水管进入调节池,调节水质和水量。①Wastewater enters the regulating pond through the inlet pipe of the regulating pond to adjust the water quality and quantity.
②然后废水通过铁盐脱氮除磷池进水管1-5进入铁盐脱氮除磷池1,与来自回流管1-6的回流废水和来自除磷剂添加和计量系统1-7的除磷剂混合,搅拌装置1-8对混合液进行搅拌混合,进行化学除磷反应,反应后的废水通过隔板1-9和铁盐脱氮除磷池的底板形成的水流通道进入沉淀分离区1-2进行固液分离,沉淀物在重力的作用下下沉到沉淀分离区的下部,通过底部的沉淀物排放阀1-10排出。② Then the wastewater enters the iron salt denitrification and phosphorus removal tank 1 through the inlet pipe 1-5 of the iron salt denitrification and phosphorus removal tank, and is mixed with the return wastewater from the return pipe 1-6 and the dephosphorization agent addition and metering system 1-7. Phosphorus agent is mixed, the mixing device 1-8 is used to stir and mix the mixed liquid, and the chemical phosphorus removal reaction is carried out, and the waste water after the reaction enters the sedimentation separation area through the water flow channel formed by the separator 1-9 and the bottom plate of the iron salt denitrification and phosphorus removal tank 1-2 for solid-liquid separation, the sediment sinks to the lower part of the sedimentation separation area under the action of gravity, and is discharged through the sediment discharge valve 1-10 at the bottom.
③沉淀后的废水通过沉淀分离区和生化脱氮区之间的隔网1-11进入生化脱氮区1-3,废水将隔网上的铁屑溶解为二价铁,含二价铁的废水进入生化脱氮区进行生物脱氮,生化脱氮后的废水进入过滤区1-4进行过滤,过滤后的废水通过铁盐脱氮除磷池溢水堰1-13、铁盐脱氮除磷池出水管进入折流式曝气生化滤池进水管2-4。③The wastewater after precipitation enters the biochemical denitrification zone 1-3 through the separation screen 1-11 between the precipitation separation area and the biochemical denitrification area, and the waste water dissolves the iron filings on the separation screen into ferrous iron. Enter the biochemical denitrification area for biological denitrification, the wastewater after biochemical denitrification enters the filter area 1-4 for filtration, and the filtered wastewater passes through the overflow weir 1-13 of the iron salt denitrification and phosphorus removal pool, and the iron salt denitrification and phosphorus removal pool The water outlet pipe enters the water inlet pipe 2-4 of the baffle type aerated biochemical filter.
④铁盐脱氮除磷池1产生的甲烷废气通过铁盐脱氮除磷池锥形上盖顶端的废气收集管1-15收集排放。④ The methane waste gas produced by the iron salt denitrification and phosphorus removal tank 1 is collected and discharged through the waste gas collection pipe 1-15 on the top of the conical upper cover of the iron salt denitrification and phosphorus removal tank.
⑤废水通过折流式曝气生化滤池进水管2-4、折流式曝气生化滤池布水管2-5进入折流式曝气生化滤池的下流区2-1,下流区曝气管2-7产生的空气与废水在下流区填料2-6中交汇发生生化反应,同时下流区填料2-6对废水进行过滤,废水通过折流板2-8后进入上流区2-2,在上流区填料2-9中发生生化反应,同时上流区填料2-9对废水进行过滤,下流区和上流区产生的污泥下沉到污泥区2-3,通过污泥区底部的污泥排放阀2-11排放出去,折流式曝气生化滤池处理后的水通过折流式曝气生化滤池溢水堰2-10达标排放。⑤Wastewater enters the downstream area 2-1 of the baffled aerated biochemical filter through the water inlet pipe 2-4 of the baffled aerated biochemical filter and the water distribution pipe 2-5 of the baffled aerated biochemical filter, and the downstream area is aerated The air generated by the pipe 2-7 and the waste water meet in the filler 2-6 in the downstream area to undergo a biochemical reaction. At the same time, the filler 2-6 in the downstream area filters the waste water, and the waste water enters the upstream area 2-2 after passing through the baffle plate 2-8. The biochemical reaction occurs in the packing 2-9 in the upstream area, and at the same time, the packing 2-9 in the upstream area filters the waste water, and the sludge produced in the downstream area and the upstream area sinks to the sludge area 2-3, and passes through the sludge at the bottom of the sludge area. The mud discharge valve 2-11 is discharged, and the water treated by the baffle type biochemical aerated filter is discharged up to the standard through the overflow weir 2-10 of the baffle type biochemical aerated filter.
⑥铁盐脱氮除磷池1产生的沉淀物和折流式曝气生化滤池2产生的剩余污泥脱水后外运。⑥ The sediment produced in the iron salt denitrification and phosphorus removal tank 1 and the excess sludge produced in the baffle type aerated biochemical filter 2 are dehydrated and transported outside.
以上述依据本发明的理想实施例为启示,通过上述的说明内容,相关工作人员完全可以在不偏离本项发明技术思想的范围内进行多样的变更以及修改。本项发明的技术性范围并不局限于说明书上的内容,必须要根据权利要求范围来确定其技术性范围。Inspired by the above-mentioned ideal embodiment according to the present invention, through the above-mentioned description content, relevant workers can make various changes and modifications within the scope of not departing from the technical idea of the present invention. The technical scope of the present invention is not limited to the content in the specification, but must be determined according to the scope of the claims.
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