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CN105563964B - Composite material for airborne radome and preparation method thereof - Google Patents

Composite material for airborne radome and preparation method thereof Download PDF

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Publication number
CN105563964B
CN105563964B CN201511027347.6A CN201511027347A CN105563964B CN 105563964 B CN105563964 B CN 105563964B CN 201511027347 A CN201511027347 A CN 201511027347A CN 105563964 B CN105563964 B CN 105563964B
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layer
skin layer
epoxy resin
composite material
outer skin
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CN105563964A (en
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曾竟成
尹昌平
邢素丽
肖加余
鞠苏
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National University of Defense Technology
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/065Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01QANTENNAS, i.e. RADIO AERIALS
    • H01Q1/00Details of, or arrangements associated with, antennas
    • H01Q1/42Housings not intimately mechanically associated with radiating elements, e.g. radome
    • H01Q1/422Housings not intimately mechanically associated with radiating elements, e.g. radome comprising two or more layers of dielectric material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02Composition of the impregnated, bonded or embedded layer
    • B32B2260/021Fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04Impregnation, embedding, or binder material
    • B32B2260/046Synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/20Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/21Anti-static
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • B32B2307/3065Flame resistant or retardant, fire resistant or retardant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/71Resistive to light or to UV
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145Rot proof, resistant to bacteria, mildew, mould, fungi
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/726Permeability to liquids, absorption
    • B32B2307/7265Non-permeable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00Vehicles
    • B32B2605/18Aircraft

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Abstract

The invention discloses a kind of airborne radome composite and preparation method thereof, wherein airborne radome includes face coat, exterior skin layer, laminboard layer and Inner Mongol cortex with composite, laminboard layer is located between exterior skin layer and Inner Mongol cortex, and face coat is coated on exterior skin layer surface;The thickness of exterior skin layer is 0.2~1mm;Laminboard layer is made of polymethacrylimide foam, structure in a rectangular trapezoid, and its short side thickness is 4~30mm, and long side thickness is 4.5mm~34mm;The thickness of Inner Mongol cortex is 0.2~1mm.Its preparation method includes:Hand paste dipping prepare Inner Mongol cortex prepreg, be coated with sandwich layer material, solidification, hand paste dipping prepare exterior skin layer prepreg, solidification, sprayed surface coating, solidification.The airborne radome composite of the present invention has that environmental resistance is excellent, integrated carrying ability is good, the advantages such as high wave transmission rate can be kept in two waveband.

Description

一种机载天线罩用复合材料及其制备方法Composite material for airborne radome and preparation method thereof

技术领域technical field

本发明涉及航天材料技术领域,尤其涉及一种机载天线罩用树脂基复合材料及其制备方法。The invention relates to the technical field of aerospace materials, in particular to a resin-based composite material for an airborne radome and a preparation method thereof.

背景技术Background technique

机载天线罩是飞行器的重要部件,它的作用是保护内部天线在工作过程中免受恶劣环境的影响,同时保证天线正常工作,即在天线工作频率范围内具有较高的透波率。The airborne radome is an important part of the aircraft. Its function is to protect the internal antenna from the harsh environment during the working process, and at the same time ensure the normal operation of the antenna, that is, it has a high transmittance within the operating frequency range of the antenna.

天线罩的性能与所选材料的性能密切相关,天线罩材料应具有以下特征:The performance of the radome is closely related to the performance of the selected material, and the radome material should have the following characteristics:

1、结构承载性能好,满足服役载荷条件下的强度和刚度要求;1. The structure has good load-bearing performance and meets the strength and stiffness requirements under service load conditions;

2、介电常数和介电损耗小,低的介电常数会降低反射,使反射对辐射模式和插入损耗的影响降低到最小;2. The dielectric constant and dielectric loss are small, and the low dielectric constant will reduce the reflection, so that the influence of reflection on the radiation mode and insertion loss is minimized;

3、质轻,降低天线罩整体重量,进而提高装备有效载荷比;3. Light weight, reducing the overall weight of the radome, thereby increasing the payload ratio of the equipment;

4、耐环境性能优良,能有效抵抗服役条件下的高低温、低气压、淋雨、太阳辐照、湿热、霉菌、盐雾、砂尘等恶劣的环境载荷;4. Excellent environmental resistance, can effectively resist high and low temperature, low air pressure, rain, solar radiation, damp heat, mold, salt spray, sand and dust and other harsh environmental loads under service conditions;

5、良好的工艺性,实现低成本制备。5. Good manufacturability, realizing low-cost preparation.

天线罩材料主要包括有机材料和无机非金属材料两大类。其中,陶瓷、微晶玻璃、陶瓷基复合材料等无机材料是为满足马赫数较高的飞行器的天线罩发展起来的,该类材料须承受更高的工作温度和更恶劣的环境。Radome materials mainly include organic materials and inorganic non-metallic materials. Among them, inorganic materials such as ceramics, glass-ceramics, and ceramic-based composite materials are developed to meet the radome of aircraft with a higher Mach number. Such materials must withstand higher operating temperatures and harsher environments.

而有机材料是指树脂基复合材料,树脂基复合材料是天线罩应用的最早的材料,也是目前在航空航天领域应用最为广泛的天线罩材料,它主要适用于飞行马赫数较小的飞行器。武器装备的升级换代和性能大幅提升,对树脂基复合材料天线罩性能提出越来越高的要求。对于某些天线来说,为了提高工作效能,该天线要求在两个波段内工作,这就意味着与之匹配的天线罩也应在两个波段保持高透波率。现有树脂基复合材料虽然能够在一个波段内实现宽频高透波率,但是目前还没有能够在两个波段内保持高透波率的天线罩材料。Organic materials refer to resin-based composite materials. Resin-based composite materials are the earliest materials used in radome applications and are currently the most widely used radome materials in the aerospace field. They are mainly suitable for aircraft with a small flying Mach number. The upgrading and performance of weapons and equipment have been greatly improved, and higher and higher requirements are placed on the performance of resin-based composite radomes. For some antennas, in order to improve work efficiency, the antenna is required to work in two bands, which means that the matching radome should also maintain high transmittance in the two bands. Although the existing resin-based composite materials can achieve broadband and high wave transmittance in one wave band, there is no radome material that can maintain high wave transmittance in two wave bands.

发明内容Contents of the invention

本发明要解决的技术问题是克服现有技术的不足,提供一种结构承载性能好、耐环境性能优良、低密度且能够在双波段内保持高透波率的机载天线罩用复合材料,还提供了该机载天线罩用复合材料的制备方法。The technical problem to be solved by the present invention is to overcome the deficiencies of the prior art, and provide a composite material for an airborne radome with good structural load-bearing performance, excellent environmental resistance, low density and high wave transmittance in dual bands, The preparation method of the composite material for the airborne radome is also provided.

为解决上述技术问题,本发明采用如下技术方案:In order to solve the problems of the technologies described above, the present invention adopts the following technical solutions:

一种机载天线罩用复合材料,包括表面涂层、外蒙皮层、夹芯层和内蒙皮层,所述夹芯层夹设于外蒙皮层和内蒙皮层之间,所述表面涂层涂覆于所述外蒙皮层表面;所述外蒙皮层的厚度为0.2~1mm;所述夹芯层采用聚甲基丙烯酰亚胺泡沫制成,呈直角梯形结构,其短边厚度为4~30mm,长边厚度为4.5mm~34mm;所述内蒙皮层的厚度为0.2~1mm。A composite material for an airborne radome, comprising a surface coating, an outer skin layer, a sandwich layer and an inner skin layer, the sandwich layer being sandwiched between the outer skin layer and the inner skin layer, the surface coating layer on the surface of the outer skin layer; the thickness of the outer skin layer is 0.2-1mm; the sandwich layer is made of polymethacrylimide foam, which is a right-angled trapezoidal structure, and the thickness of its short side is 4-30mm , the thickness of the long side is 4.5mm-34mm; the thickness of the inner skin layer is 0.2-1mm.

上述的机载天线罩用复合材料,优选的,所述夹芯层为聚甲基丙烯酰亚胺泡沫制成的直角梯形,外蒙皮层设置于所述夹心层的斜边上,内蒙皮层设置于与所述夹芯层的斜边相对的直角边上;所述夹芯层的短边厚度为4~30mm,所述夹芯层的长边厚度比所述短边厚0.5~4mm;所述外蒙皮层和内蒙皮层为均匀等厚的矩形。For the above-mentioned composite material for airborne radome, preferably, the sandwich core layer is a right-angled trapezoid made of polymethacrylimide foam, the outer skin layer is arranged on the hypotenuse of the sandwich layer, and the inner skin layer is arranged On the right-angled side opposite to the hypotenuse of the sandwich layer; the thickness of the short side of the sandwich layer is 4-30 mm, and the thickness of the long side of the sandwich layer is 0.5-4 mm thicker than the short side; The outer skin layer and the inner skin layer are uniform and equal-thick rectangles.

上述的机载天线罩用复合材料,优选的,所述表面涂层包括底漆层、抗雨蚀漆层和防静电漆层,所述抗雨蚀漆层设置于所述底漆层和所述防静电漆层中间,所述底漆层涂覆于所述外蒙皮层表面。The composite material for the above-mentioned airborne radome, preferably, the surface coating includes a primer layer, a rain erosion-resistant paint layer and an antistatic paint layer, and the rain-resistant paint layer is arranged on the primer layer and the In the middle of the antistatic paint layer, the primer layer is coated on the surface of the outer skin layer.

上述的机载天线罩用复合材料,优选的,所述底漆层的材料为H01-89,厚度为0.03±0.01mm;所述抗雨蚀漆层的材料为SF55-49,厚度为0.15±0.02mm;所述防静电漆层的材料为SDT99-49,厚度为0.03~0.05mm。The above-mentioned composite material for airborne radome, preferably, the material of the primer layer is H01-89, and the thickness is 0.03±0.01mm; the material of the rain-resistant paint layer is SF55-49, and the thickness is 0.15± 0.02mm; the material of the antistatic paint layer is SDT99-49, and the thickness is 0.03-0.05mm.

上述的机载天线罩用复合材料,优选的,所述外蒙皮层采用纤维布增强环氧树脂体系复合材料;所述纤维布增强环氧树脂体系复合材料由多层纤维布通过环氧树脂体系粘贴而成;所述纤维布为石英纤维平纹布、石英纤维斜纹布和石英纤维缎纹布中的一种;所述环氧树脂体系包括环氧树脂和固化剂。进一步优选的,所述环氧树脂为LT5089A,固化剂为LT5089B。For the above-mentioned composite material for airborne radome, preferably, the outer skin layer adopts a fiber cloth reinforced epoxy resin system composite material; the fiber cloth reinforced epoxy resin system composite material is composed of multiple layers of fiber cloth through the It is pasted together; the fiber cloth is one of quartz fiber plain weave, quartz fiber twill and quartz fiber satin weave; the epoxy resin system includes epoxy resin and a curing agent. Further preferably, the epoxy resin is LT5089A, and the curing agent is LT5089B.

上述的机载天线罩用复合材料,优选的,所述外蒙皮层中,所述外蒙皮层用纤维布的体积百分含量为35%~55%,所述环氧树脂体系的体积百分含量为65%~45%;所述环氧树脂体系中,所述固化剂的添加量为环氧树脂质量的30%。For the above-mentioned composite material for an airborne radome, preferably, in the outer skin layer, the volume percentage of the fiber cloth for the outer skin layer is 35% to 55%, and the volume percentage of the epoxy resin system is The content is 65%-45%; in the epoxy resin system, the addition amount of the curing agent is 30% of the mass of the epoxy resin.

上述的机载天线罩用复合材料,优选的,所述内蒙皮层材料采用纤维布增强环氧树脂体系复合材料;所述纤维布增强环氧树脂体系复合材料由多层纤维布通过环氧树脂体系粘贴而成;所述纤维布为石英纤维平纹布、石英纤维斜纹布和石英纤维缎纹布的一种;所述环氧树脂体系包括环氧树脂和固化剂。进一步优选的,所述环氧树脂为LT5089A,固化剂为LT5089B。For the above-mentioned composite material for airborne radome, preferably, the inner skin layer material adopts fiber cloth reinforced epoxy resin system composite material; the fiber cloth reinforced epoxy resin system composite material is composed of multiple layers of fiber cloth through It is pasted together; the fiber cloth is one of quartz fiber plain weave, quartz fiber twill and quartz fiber satin weave; the epoxy resin system includes epoxy resin and a curing agent. Further preferably, the epoxy resin is LT5089A, and the curing agent is LT5089B.

上述的机载天线罩用复合材料,优选的,所述内蒙皮层中,所述内蒙皮层用纤维布的体积百分含量为35%~55%,所述环氧树脂体系的体积百分含量为65%~45%;所述环氧树脂体系中,所述固化剂的添加量为环氧树脂质量的30%。For the above-mentioned composite material for airborne radome, preferably, in the inner skin layer, the volume percentage of the fiber cloth for the inner skin layer is 35% to 55%, and the volume percentage of the epoxy resin system is 65%-45%; in the epoxy resin system, the amount of the curing agent added is 30% of the mass of the epoxy resin.

作为一个总的技术构思,本发明还提供了一种上述机载天线罩用复合材料的制备方法,包括以下步骤:As a general technical concept, the present invention also provides a method for preparing the composite material for the above-mentioned airborne radome, comprising the following steps:

S1、将环氧树脂和固化剂混合后制成环氧树脂体系,以所述环氧树脂体系为粘结剂,采用手糊工艺将多层纤维布逐层浸渍得到内蒙皮层预浸料;S1. Mix the epoxy resin and the curing agent to prepare an epoxy resin system, use the epoxy resin system as a binder, and use a hand lay-up process to impregnate the multi-layer fiber cloth layer by layer to obtain an inner skin layer prepreg;

S2、将夹芯层材料铺覆步骤S1制备得到的所述内蒙皮层预浸料上,按压;S2. Lay the sandwich layer material on the inner skin layer prepreg prepared in step S1, and press;

S3、采用真空袋压方法,将所述内蒙皮层预浸料在50~70℃下固化4~6h得到夹芯层-内蒙皮层预制体;S3. Using a vacuum bagging method, curing the inner skin layer prepreg at 50-70° C. for 4-6 hours to obtain a sandwich layer-inner skin layer prefabricated body;

S4、将环氧树脂和固化剂混合后制成环氧树脂体系,以所述环氧树脂体系为粘结剂,在所述夹芯层-内蒙皮层预制体的夹芯层表面采用手糊工艺将多层纤维布逐层浸渍得到外蒙皮层预浸料;S4. Mix the epoxy resin and curing agent to make an epoxy resin system, use the epoxy resin system as a binder, and use a hand lay-up process on the surface of the sandwich layer of the sandwich layer-inner skin layer prefabricated body The outer skin layer prepreg is obtained by impregnating the multi-layer fiber cloth layer by layer;

S5、采用真空袋压方法,将所述外蒙皮层预浸料在50~70℃固化4~6h得到外蒙皮层-夹芯层-内蒙皮层预制体;S5. Using a vacuum bagging method, curing the outer skin layer prepreg at 50-70°C for 4-6 hours to obtain an outer skin layer-sandwich layer-inner skin layer prefabricated body;

S6、在所述外蒙皮层-夹芯层-内蒙皮层预制体的外蒙皮层表面喷涂表面涂层,然后固化,得到机载天线罩用复合材料。S6. Spraying a surface coating on the surface of the outer skin layer of the outer skin layer-sandwich layer-inner skin layer prefabricated body, and then curing to obtain a composite material for an airborne radome.

上述的制备方法,优选的,所述步骤S6具体包括以下步骤:In the above-mentioned preparation method, preferably, the step S6 specifically includes the following steps:

S6-1、在所述外蒙皮层-夹芯层-内蒙皮层预制体的外蒙皮层外表面喷涂底漆胶液,喷涂完成后,室温下晾干24h,形成底漆层;S6-1. Spray primer glue on the outer surface of the outer skin layer of the outer skin layer-sandwich layer-inner skin layer prefabricated body. After the spraying is completed, dry it at room temperature for 24 hours to form a primer layer;

S6-2、在所述底漆层外表面喷涂抗雨蚀漆胶液,喷涂完成后,室温下晾干2h,形成抗雨蚀漆层;S6-2. Spray the rain-erosion-resistant paint glue solution on the outer surface of the primer layer, and after the spraying is completed, dry it at room temperature for 2 hours to form a rain-erosion-resistant paint layer;

S6-3、在所述抗雨蚀漆层外表面均匀喷涂防静电漆胶液,喷涂完成后,室温下晾干12h,形成防静电漆层;S6-3. Evenly spray anti-static paint glue on the outer surface of the rain-resistant paint layer. After spraying, dry it at room temperature for 12 hours to form an anti-static paint layer;

S6-4、在60~80℃下固化8~10h。S6-4. Curing at 60-80°C for 8-10 hours.

本发明的创新点在于:The innovation point of the present invention is:

本发明的机载天线罩用复合材料,包括表面涂层、外蒙皮层、夹芯层和内蒙皮层,夹芯层设于外蒙皮层和内蒙皮层之间,表面涂层涂覆于外蒙皮层表面。其中外蒙皮层和内蒙皮层是保持结构承载能力的前提,将外蒙皮层的厚度控制在0.2~1mm,内蒙皮层的厚度控制在0.2~1mm,一方面保持其承载能力,满足飞行器的气动载荷的要求;另一方面可以保持复合材料的高透波率。夹芯层采用聚甲基丙烯酰亚胺泡沫制成,在达到强化结构、减轻重量目的的同时,还能够通过调整到达接收天线的反射波的相位,使得内、外蒙皮的反射波幅度相等,相位相反,相互抵消,达到零反射效果,实现在不同波段内保持透波率。夹芯层的实际厚度可依据天线罩内天线的工作条件和透波要求进行设计。The airborne radome composite material of the present invention comprises a surface coating, an outer skin layer, a sandwich layer and an inner skin layer, the sandwich layer is arranged between the outer skin layer and the inner skin layer, and the surface coating is coated on the outer skin layer surface. Among them, the outer skin layer and the inner skin layer are the prerequisites for maintaining the structural bearing capacity. The thickness of the outer skin layer is controlled at 0.2-1mm, and the thickness of the inner skin layer is controlled at 0.2-1mm. On the one hand, the bearing capacity is maintained to meet the requirements of the aerodynamic load of the aircraft. Requirements; on the other hand, it can maintain the high wave transmittance of the composite material. The sandwich layer is made of polymethacrylimide foam. While achieving the purpose of strengthening the structure and reducing weight, it can also adjust the phase of the reflected wave reaching the receiving antenna so that the amplitude of the reflected wave of the inner and outer skins is equal. , the phases are opposite, cancel each other out, achieve zero reflection effect, and maintain the transmittance in different wave bands. The actual thickness of the sandwich layer can be designed according to the working conditions of the antenna in the radome and the requirements of wave penetration.

为了进一步实现天线罩在双波段内保持高透波率,本发明将夹心层的厚度设计为非均匀等厚,具体是将夹芯层设计为直角梯形结构。天线罩的实际应用过程中,天线与天线罩相对位置的变化将引起电磁波入射角的变化,从而影响天线罩的透波性能,本发明通过将夹芯层厚度设计为非均匀等厚,厚度的变化过程,可以满足不同波段内的透波性能要求。天线罩对电磁波传输性能影响主要表现在对电磁波的吸收与反射,而入射角和壁厚则决定了电磁波的反射和透射比例,也即任何已选定材料和结构形式的天线罩的功率传输特性(插入损耗和插入相位延迟IPD)都是入射角和厚度的函数。夹芯层应用的优点在于选择一定厚度的低密度芯层,在达到强化结构、减轻重量目的的同时,更为重要的是来调整到达接收天线的反射波的相位,使得零反射设计成为可能。如此在进行夹芯层的厚度设计时,可根据天线罩内天线的工作条件,设计计算得到最佳的芯层厚度,使得内、外蒙皮的反射波幅度相等,相位相反,相互抵消。In order to further realize that the radome maintains a high wave transmittance in the dual-band, the present invention designs the thickness of the sandwich layer to be non-uniform and equal in thickness, specifically, the sandwich layer is designed as a right-angled trapezoidal structure. In the actual application process of the radome, the change of the relative position between the antenna and the radome will cause the change of the incident angle of the electromagnetic wave, thereby affecting the wave-transmitting performance of the radome. The change process can meet the wave-transparency performance requirements in different bands. The influence of the radome on the transmission performance of electromagnetic waves is mainly reflected in the absorption and reflection of electromagnetic waves, while the incident angle and wall thickness determine the reflection and transmission ratio of electromagnetic waves, that is, the power transmission characteristics of any radome with selected materials and structural forms (Insertion Loss and Insertion Phase Delay IPD) are both a function of incident angle and thickness. The advantage of sandwich layer application is to select a low-density core layer with a certain thickness. While achieving the purpose of strengthening the structure and reducing weight, it is more important to adjust the phase of the reflected wave reaching the receiving antenna, making zero reflection design possible. In this way, when designing the thickness of the sandwich layer, the optimal core layer thickness can be designed and calculated according to the working conditions of the antenna in the radome, so that the reflected waves of the inner and outer skins have equal amplitudes, opposite phases, and cancel each other out.

与现有技术相比,本发明的优点在于:Compared with the prior art, the present invention has the advantages of:

(1)本发明提出的树脂基复合材料耐环境性能优良,经过实际试验考核,可耐受耐高低温、耐低气压、耐淋雨、耐太阳辐照、防湿热、防霉菌、防盐雾、耐砂尘、耐液体、耐温-湿-高、防静电、雨冲击和雨蚀等多种环境条件。(1) The resin-based composite material proposed by the present invention has excellent environmental resistance performance, and can withstand high and low temperature resistance, low air pressure resistance, rain resistance, solar radiation resistance, damp heat resistance, mold resistance, and salt spray resistance through actual test assessment. , Sand and dust resistance, liquid resistance, temperature-humidity-high, anti-static, rain impact and rain erosion and other environmental conditions.

(2)本发明提出的树脂基复合材料整体承载能力好,满足机载天线罩的力学环境载荷要求。(2) The resin-based composite material proposed by the present invention has a good overall bearing capacity and meets the mechanical environmental load requirements of the airborne radome.

(3)由于采用夹芯层变厚度设计方法,本发明提出的树脂基复合材料可在双波段内保持高透波率,这是已有技术方案都无法实现的。此外,本发明的树脂基复合材料密度低,可有效降低产品整体重量,进而提高装备有效载荷比;成型工艺性好,成本较低,本发明的树脂基复合材料是一种适用于具有双波段要求的机载天线罩的材料体系,具有广阔的市场前景。(3) Due to the variable thickness design method of the sandwich layer, the resin-based composite material proposed by the present invention can maintain a high wave transmittance in the dual-wave band, which cannot be realized by the existing technical solutions. In addition, the resin-based composite material of the present invention has a low density, which can effectively reduce the overall weight of the product, thereby increasing the payload ratio of the equipment; the molding process is good and the cost is low. The resin-based composite material of the present invention is a kind of dual-band The material system required for the airborne radome has broad market prospects.

附图说明Description of drawings

为使本发明实施例的目的、技术方案和优点更加清楚,下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整的描述。In order to make the purpose, technical solutions and advantages of the embodiments of the present invention more clear, the technical solutions in the embodiments of the present invention will be clearly and completely described below in conjunction with the drawings in the embodiments of the present invention.

图1为本发明的机载天线罩用复合材料截面示意图。Fig. 1 is a schematic cross-sectional view of a composite material for an airborne radome of the present invention.

图2为本发明实施例1中制得的机载天线罩用复合材料试样照片。Fig. 2 is a photograph of a sample of a composite material for an airborne radome prepared in Example 1 of the present invention.

图例说明:illustration:

在附图中,A1、表面涂层之防静电漆层;A2、表面涂层之抗雨蚀漆层;A3、表面涂层之底漆层;B、外蒙皮层;C、夹芯层;D、内蒙皮层。In the accompanying drawings, A 1 , the antistatic paint layer of the surface coating; A 2 , the anti-rain erosion paint layer of the surface coating; A 3 , the primer layer of the surface coating; B, the outer skin layer; Core layer; D, inner skin layer.

具体实施方式detailed description

以下结合说明书附图和具体优选的实施例对本发明作进一步描述,但并不因此而限制本发明的保护范围。The present invention will be further described below in conjunction with the accompanying drawings and specific preferred embodiments, but the protection scope of the present invention is not limited thereby.

实施例Example

以下实施例中所采用的材料和仪器均为市售。其中作为底漆胶液的H01-89环氧涂料、作为抗雨蚀胶液的SF55-49脂肪族涂料、作为防静电胶液的SDT99-49脂肪族涂料均购于中海油常州涂料化工研究院;LT5089A环氧树脂和LT5089B固化剂购自惠利树脂有限公司;牌号为ROHACELL 71IG-F的PMI泡沫购自德国德固赛公司;牌号分别为B型-斜纹-0.20和B型-斜纹-0.10的石英纤维斜纹布,购自荆州菲利华石英玻璃有限公司。All materials and instruments used in the following examples are commercially available. Among them, the H01-89 epoxy coating as the primer glue, the SF55-49 aliphatic coating as the anti-rain erosion glue, and the SDT99-49 aliphatic coating as the antistatic glue were all purchased from CNOOC Changzhou Paint Chemical Research Institute; LT5089A epoxy resin and LT5089B curing agent were purchased from Huili Resin Co., Ltd.; the PMI foam with the brand name ROHACELL 71IG-F was purchased from Degussa Company in Germany; the brands were B-twill-0.20 and B-twill-0.10 respectively Quartz fiber twill was purchased from Jingzhou Feilihua Quartz Glass Co., Ltd.

实施例1:Example 1:

一种如图1所示的机载天线罩用复合材料,主要用于制备在Ka和Ku波段内工作的天线罩。其结构为:由外至里依次设置有表面涂层A、外蒙皮层B、夹芯层C、内蒙皮层D,其中夹芯层C设于外蒙皮层B和内蒙皮层D之间,表面涂层A涂覆于外蒙皮层B表面。A composite material for an airborne radome as shown in Figure 1, which is mainly used to prepare radome working in Ka and Ku bands. Its structure is: a surface coating A, an outer skin layer B, a sandwich layer C, and an inner skin layer D are sequentially arranged from outside to inside, wherein the sandwich layer C is arranged between the outer skin layer B and the inner skin layer D, and the surface coating Layer A is applied to the surface of outer skin layer B.

其中表面涂层包括底漆层A3、抗雨蚀漆层A2和防静电漆层A1,抗雨蚀漆层A2设置于底漆层A3和防静电漆层A1中间,底漆层A3涂覆于外蒙皮层B表面。底漆层厚度为0.03mm;抗雨蚀层厚度为0.15mm;防静电层厚度为0.04mm。Wherein the surface coating comprises primer layer A3, anti-rain erosion paint layer A2 and antistatic paint layer A1, rain erosion resistant paint layer A2 is arranged in the middle of primer layer A3 and antistatic paint layer A1, and primer layer A3 is coated on The surface of the outer skin layer B. The thickness of the primer layer is 0.03mm; the thickness of the anti-rain erosion layer is 0.15mm; the thickness of the antistatic layer is 0.04mm.

外蒙皮层以石英纤维斜纹布为外蒙皮层用增强材料,通过手糊工艺将多层石英纤维斜纹布逐层浸渍得到外蒙皮层预浸料。外蒙皮层用环氧树脂胶液的成分包括LT5089A环氧树脂(购自惠利树脂有限公司)和用量为LT5089A环氧树脂质量30%的LT5089B固化剂(购自惠利树脂有限公司)。外蒙皮层的纤维体积百分含量为45%,厚度为0.5mm。The outer skin layer uses quartz fiber twill as the reinforcing material for the outer skin layer, and the multi-layer quartz fiber twill cloth is impregnated layer by layer by hand lay-up process to obtain the outer skin layer prepreg. The composition of the epoxy resin glue for the outer skin layer includes LT5089A epoxy resin (purchased from Huili Resin Co., Ltd.) and LT5089B curing agent (purchased from Huili Resin Co., Ltd.) with an amount of 30% of the mass of LT5089A epoxy resin. The fiber volume percentage of the outer skin layer is 45%, and the thickness is 0.5 mm.

夹芯层采用ROHACELL 71IG-F的PMI泡沫(购自德国德固赛公司),将PMI泡沫加工成直角梯形,外蒙皮层设置于夹心层的斜边上,内蒙皮层设置于与夹芯层的斜边相对的直角边上,夹芯层的短边厚度为15.8mm,所述夹芯层的长边厚度为17.2mm。外蒙皮层和内蒙皮层为均匀等厚的矩形。The sandwich layer adopts ROHACELL 71IG-F PMI foam (purchased from Degussa, Germany). The PMI foam is processed into a right-angled trapezoid. On the right-angle side opposite to the hypotenuse, the thickness of the short side of the sandwich layer is 15.8 mm, and the thickness of the long side of the sandwich layer is 17.2 mm. The outer skin layer and the inner skin layer are uniform and equal-thick rectangles.

内蒙皮层以石英纤维斜纹布为内蒙皮层用增强材料,内蒙皮层用增强材料通过内蒙皮层用树脂胶液粘贴在一起形成内蒙皮层。内蒙皮层用树脂胶液的成分包括LT5089A环氧树脂(购自惠利树脂有限公司)和用量为LT5089A环氧树脂质量30%的LT5089B固化剂(购自惠利树脂有限公司)。内蒙皮层的纤维体积含量为45%,厚度为0.5mm。The inner skin layer uses quartz fiber twill as the reinforcing material for the inner skin layer, and the reinforcing material for the inner skin layer is pasted together by the inner skin layer with resin glue to form the inner skin layer. The resin glue solution for the inner skin layer includes LT5089A epoxy resin (purchased from Huili Resin Co., Ltd.) and LT5089B curing agent (purchased from Huili Resin Co., Ltd.) with an amount of 30% of the mass of LT5089A epoxy resin. The inner skin layer has a fiber volume content of 45% and a thickness of 0.5 mm.

本实施例的机载天线罩用复合材料的制备方法,具体包括以下步骤:The preparation method of the composite material for the airborne radome of the present embodiment specifically comprises the following steps:

1、制备内蒙皮层预浸料:1. Preparation of inner skin layer prepreg:

1.1、配制内蒙皮层用树脂胶液:准备LT5089A环氧树脂和LT5089B固化剂,按照固化剂用量为树脂用量30%的比例配制内蒙皮层用树脂胶液,待用。1.1. Preparation of resin glue solution for inner skin layer: prepare LT5089A epoxy resin and LT5089B curing agent, and prepare resin glue solution for inner skin layer according to the ratio of the amount of curing agent to 30% of the resin amount, and set it aside.

1.2、裁剪内蒙皮层增强材料:按照试样形状和尺寸裁剪2层牌号为B型-斜纹-0.20的石英纤维斜纹布和1层牌号为B型-斜纹-0.10的石英纤维斜纹布,作为内蒙皮层用增强材料。1.2. Cutting the reinforcement material of the inner skin layer: according to the shape and size of the sample, cut 2 layers of quartz fiber twill cloth with grade B-twill-0.20 and 1 layer of quartz fiber twill cloth with grade B-twill-0.10, as reinforcement for the inner skin layer Material.

1.3、手糊浸渍:在阳模上铺覆1层牌号为B型-斜纹-0.10的石英纤维斜纹布,用内蒙皮层用树脂胶液进行均匀浸渍;然后再分别铺覆2层牌号为B型-斜纹-0.20的石英纤维斜纹布,每铺覆1层就用树脂胶液均匀浸渍,得到内蒙皮层预浸料,控制内蒙皮层预浸料中纤维体积分数为45%。1.3. Hand lay-up impregnation: Spread 1 layer of quartz fiber twill cloth with grade B-twill-0.10 on the male mold, and use the inner skin layer to impregnate evenly with resin glue; then spread 2 layers of grade B-type- The twill-0.20 quartz fiber twill fabric is uniformly impregnated with resin glue solution for each layer of covering to obtain the inner skin layer prepreg, and the fiber volume fraction in the inner skin layer prepreg is controlled to be 45%.

2、铺覆夹芯层:2. Cover the sandwich layer:

将设计并加工后的PMI泡沫铺覆在内蒙皮层预浸料之上,按压到位。Lay the designed and processed PMI foam on the prepreg of the inner skin layer and press it in place.

3、内蒙皮层/夹芯层的真空袋压固化:3. Vacuum bag pressure curing of inner skin layer/sandwich layer:

在内蒙皮层预浸料/夹芯层上依次铺覆隔离膜、导流介质和真空袋膜,在60℃下固化4h,使内蒙皮层用树脂胶液固化。固化完成后,依次去除真空袋膜、导流介质和隔离膜,并对其表面进行修整处理,得到夹芯层-内蒙皮层预制体。On the prepreg/sandwich layer of the inner skin layer, the isolation film, the diversion medium and the vacuum bag film are sequentially laid, and cured at 60°C for 4 hours, so that the inner skin layer is cured with the resin glue. After the curing is completed, the vacuum bag film, the diversion medium and the isolation film are removed in sequence, and the surface is trimmed to obtain a sandwich layer-inner skin layer prefabricated body.

4、制备外蒙皮层预浸料:4. Prepare the outer skin layer prepreg:

4.1、配制外蒙皮层用树脂胶液:准备LT5089A环氧树脂和LT5089B固化剂,按照固化剂用量为树脂用量30%的比例配制外蒙皮层用树脂胶液,待用。4.1. Prepare the resin glue solution for the outer skin layer: prepare LT5089A epoxy resin and LT5089B curing agent, prepare the resin glue solution for the outer skin layer according to the ratio of the amount of curing agent to 30% of the resin amount, and set it aside.

4.2、裁剪外蒙皮层增强材料:按照试样形状和尺寸裁剪2层牌号为B型-斜纹-0.20的石英纤维斜纹布和1层牌号为B型-斜纹-0.10的石英纤维斜纹布,做为外蒙皮层用增强材料。4.2. Cutting the reinforcement material of the outer skin layer: according to the shape and size of the sample, cut 2 layers of quartz fiber twill cloth with the brand name B-twill-0.20 and 1 layer of quartz fiber twill cloth with the brand name B-twill-0.10 as the outer cover Reinforcement material for cortex.

4.3、手糊浸渍:在夹芯层上铺覆2层牌号为B型-斜纹-0.20的石英纤维斜纹布,每铺覆1层用外蒙皮层用树脂胶液进行均匀浸渍;然后再铺覆1层牌号为B型-斜纹-0.10的石英纤维斜纹布,得到外蒙皮层预浸料,控制外蒙皮层预浸料中纤维体积分数为45%。4.3. Hand lay-up impregnation: Lay 2 layers of quartz fiber twill cloth with grade B-twill-0.20 on the sandwich layer, and use the outer skin layer to impregnate evenly with resin glue for each layer; The layer designation is B-type-twill-0.10 quartz fiber twill cloth to obtain the outer skin layer prepreg, and the fiber volume fraction in the outer skin layer prepreg is controlled to be 45%.

5、外蒙皮层的真空袋压固化:5. Vacuum bag pressure curing of the outer skin layer:

在外蒙皮层预浸料上依次隔离膜、导流介质和真空袋膜,在60℃下固化4h,使外蒙皮层用树脂胶液固化。固化完成后,依次去除真空袋膜、导流介质和隔离膜,脱模,对外蒙皮层表面进行修整和打磨处理,得到外蒙皮层-夹芯层-内蒙皮层预制体。On the prepreg of the outer skin layer, the isolation film, the diversion medium and the vacuum bag film are sequentially cured at 60°C for 4 hours, so that the resin glue solution for the outer skin layer is cured. After the curing is completed, the vacuum bag film, the diversion medium and the isolation film are removed in sequence, the mold is demoulded, and the surface of the outer skin layer is trimmed and polished to obtain the outer skin layer-sandwich layer-inner skin layer prefabricated body.

6、表面涂层制备:6. Surface coating preparation:

6.1、底漆层的制备:准备环氧涂料H01-89,在外蒙皮层-夹芯层-内蒙皮层预制体的外蒙皮层外表面均匀喷涂,喷涂时控制底漆层厚度为0.03±0.01mm,喷涂完成后,室温下晾干24h,形成底漆层。6.1. Preparation of primer layer: prepare epoxy coating H01-89, and spray evenly on the outer surface of the outer skin layer of the outer skin layer-sandwich layer-inner skin layer prefabricated body. When spraying, control the thickness of the primer layer to 0.03±0.01mm, After spraying, let it dry at room temperature for 24 hours to form a primer layer.

6.2、抗雨蚀漆层制备:准备脂肪族抗雨蚀层涂料SF55-49,在底漆层外表面均匀喷涂抗雨蚀层涂料,喷涂时控制抗雨蚀层厚度为0.15±0.02mm,喷涂完成后,室温下晾干2h,形成抗雨蚀漆层。6.2. Preparation of anti-rain erosion paint layer: Prepare aliphatic anti-rain erosion layer coating SF55-49, and spray the anti-rain erosion layer coating evenly on the outer surface of the primer layer. After completion, dry at room temperature for 2 hours to form a rain-corrosion resistant paint layer.

6.3、防静电漆层制备:准备脂肪族防静电层涂料SDT99-49,在抗雨蚀层外表面均匀喷涂防静电层涂料,喷涂时控制防静电层厚度为0.03~0.05mm,喷涂完成后,室温下晾干12h,形成防静电漆层。6.3. Preparation of anti-static paint layer: prepare aliphatic anti-static layer coating SDT99-49, and spray anti-static layer coating evenly on the outer surface of rain erosion-resistant layer. When spraying, control the thickness of the anti-static layer to 0.03-0.05mm. After spraying, Dry at room temperature for 12 hours to form an antistatic paint layer.

6.4、固化:整体放入烘箱中,在60℃下固化10h,表面进行修整,完成机载天线罩用复合材料的制备。6.4. Curing: put the whole in an oven, cure at 60°C for 10 hours, and trim the surface to complete the preparation of the composite material for the airborne radome.

将实施例1的机载天线罩用复合材料进行透波性能检测,检测结果参见表1。The composite material used for the airborne radome in Example 1 was tested for wave transmission performance, and the test results are shown in Table 1.

表1:机载天线罩用复合材料透波性能试验结果表Table 1: Test results of wave transmission performance of composite materials for airborne radome

从表1数据可以看出:本实施例制备的机载天线罩用复合材料在Ka和Ku两个波段内都保持高透波率,透波率和交叉极化隔离度都满足要求。It can be seen from the data in Table 1 that the airborne radome composite material prepared in this example maintains high wave transmittance in both Ka and Ku bands, and both wave transmittance and cross-polarization isolation meet the requirements.

将实施例1的机载天线罩用复合材料进行环境性能检测,检测结果参见表2。The composite material used for the airborne radome in Example 1 was tested for environmental performance, and the test results are shown in Table 2.

表2:机载天线罩用复合材料环境性能试验结果表Table 2: Environmental performance test results of composite materials for airborne radome

从表2中数据可以看出,本发明的机载天线罩用复合材料在耐高低温、耐低气压、耐淋雨、耐太阳辐照、防湿热、防霉菌、防盐雾、耐砂尘、耐液体、耐温-湿-高、防静电等复杂的环境条件下,整体结构承载能力良好。As can be seen from the data in Table 2, the airborne radome composite material of the present invention is resistant to high and low temperature, low air pressure, rain resistance, solar radiation resistance, heat and humidity resistance, mildew resistance, salt spray resistance, and sand and dust resistance. , liquid resistance, temperature-humidity-high, anti-static and other complex environmental conditions, the overall structure has a good bearing capacity.

以上所述,仅是本发明的较佳实施例而已,并非对本发明作任何形式上的限制。虽然本发明已以较佳实施例揭示如上,然而并非用以限定本发明。任何熟悉本领域的技术人员,在不脱离本发明的精神实质和技术方案的情况下,都可利用上述揭示的方法和技术内容对本发明技术方案做出许多可能的变动和修饰,或修改为等同变化的等效实施例。因此,凡是未脱离本发明技术方案的内容,依据本发明的技术实质对以上实施例所做的任何简单修改、等同替换、等效变化及修饰,均仍属于本发明技术方案保护的范围内。The above descriptions are only preferred embodiments of the present invention, and do not limit the present invention in any form. Although the present invention has been disclosed above with preferred embodiments, it is not intended to limit the present invention. Any person familiar with the art, without departing from the spirit and technical solutions of the present invention, can use the methods and technical content disclosed above to make many possible changes and modifications to the technical solutions of the present invention, or modify them to be equivalent Variations of equivalent embodiments. Therefore, any simple modifications, equivalent replacements, equivalent changes and modifications made to the above embodiments according to the technical essence of the present invention, which do not deviate from the technical solutions of the present invention, still fall within the protection scope of the technical solutions of the present invention.

Claims (9)

1.一种机载天线罩用复合材料,其特征在于,包括表面涂层、外蒙皮层、夹芯层和内蒙皮层,所述夹芯层夹设于外蒙皮层和内蒙皮层之间,所述表面涂层涂覆于所述外蒙皮层表面;所述外蒙皮层的厚度为0.2~1mm;所述内蒙皮层的厚度为0.2~1mm;所述夹芯层为聚甲基丙烯酰亚胺泡沫制成的直角梯形,外蒙皮层设置于所述夹芯层的斜边上,内蒙皮层设置于与所述夹芯层的斜边相对的直角边上,所述夹芯层的短边厚度为4~30mm,所述夹芯层的长边厚度比短边厚0.5~4mm;所述外蒙皮层和内蒙皮层为均匀等厚的矩形。1. a composite material for airborne radome, is characterized in that, comprises surface coating, outer skin layer, sandwich layer and inner skin layer, and described sandwich layer is sandwiched between outer skin layer and inner skin layer, so The surface coating is coated on the surface of the outer skin layer; the thickness of the outer skin layer is 0.2-1 mm; the thickness of the inner skin layer is 0.2-1 mm; the sandwich layer is polymethacrylimide A right-angled trapezoid made of foam, the outer skin layer is arranged on the hypotenuse of the sandwich layer, the inner skin layer is arranged on the right-angle side opposite to the hypotenuse of the sandwich layer, and the thickness of the short side of the sandwich layer is 4-30 mm, the thickness of the long side of the sandwich layer is 0.5-4 mm thicker than the short side; the outer skin layer and the inner skin layer are rectangles with uniform thickness. 2.根据权利要求1所述的机载天线罩用复合材料,其特征在于,所述表面涂层包括底漆层、抗雨蚀漆层和防静电漆层,所述抗雨蚀漆层设置于所述底漆层和所述防静电漆层中间,所述底漆层涂覆于所述外蒙皮层表面。2. The composite material for airborne radome according to claim 1, wherein the surface coating comprises a primer layer, a rain-erosion-resistant paint layer and an antistatic paint layer, and the rain-erosion-resistant paint layer is provided with Between the primer layer and the antistatic paint layer, the primer layer is coated on the surface of the outer skin layer. 3.根据权利要求2所述的机载天线罩用复合材料,其特征在于,所述底漆层的材料为H01-89,厚度为0.03±0.01mm;所述抗雨蚀漆层的材料为SF55-49,厚度为0.15±0.02mm;所述防静电漆层的材料为SDT99-49,厚度为0.03~0.05mm。3. airborne radome composite material according to claim 2, is characterized in that, the material of described priming paint layer is H01-89, and thickness is 0.03 ± 0.01mm; The material of described rain erosion-resistant paint layer is SF55-49, the thickness is 0.15±0.02mm; the material of the antistatic paint layer is SDT99-49, the thickness is 0.03-0.05mm. 4.根据权利要求1所述的机载天线罩用复合材料,其特征在于,所述外蒙皮层采用纤维布增强环氧树脂体系复合材料;所述纤维布增强环氧树脂体系复合材料由多层纤维布通过环氧树脂体系粘贴而成;所述纤维布为石英纤维平纹布、石英纤维斜纹布和石英纤维缎纹布中的一种;所述环氧树脂体系包括环氧树脂和固化剂。4. composite material for airborne radome according to claim 1, is characterized in that, described outer skin layer adopts fiber cloth to strengthen epoxy resin system composite material; Described fiber cloth strengthens epoxy resin system composite material by multiple Layers of fiber cloth are bonded by an epoxy resin system; the fiber cloth is one of quartz fiber plain weave, quartz fiber twill and quartz fiber satin weave; the epoxy resin system includes epoxy resin and a curing agent. 5.根据权利要求4所述的机载天线罩用复合材料,其特征在于,所述外蒙皮层中,所述纤维布的体积百分含量为35%~55%,所述环氧树脂体系的体积百分含量为65%~45%;所述环氧树脂体系中,所述固化剂的添加量为环氧树脂质量的30%。5. The composite material for airborne radome according to claim 4, characterized in that, in the outer skin layer, the volume percentage of the fiber cloth is 35% to 55%, and the epoxy resin system The volume percentage content is 65%-45%; in the epoxy resin system, the addition amount of the curing agent is 30% of the mass of the epoxy resin. 6.根据权利要求1所述的机载天线罩用复合材料,其特征在于,所述内蒙皮层材料采用纤维布增强环氧树脂体系复合材料;所述纤维布增强环氧树脂体系复合材料由多层纤维布通过环氧树脂体系粘贴而成;所述纤维布为石英纤维平纹布、石英纤维斜纹布和石英纤维缎纹布的一种;所述环氧树脂体系包括环氧树脂和固化剂。6. The composite material for an airborne radome according to claim 1, wherein the inner skin layer material adopts a fiber cloth reinforced epoxy resin system composite material; the fiber cloth reinforced epoxy resin system composite material is composed of multiple Layers of fiber cloth are pasted by an epoxy resin system; the fiber cloth is one of quartz fiber plain weave, quartz fiber twill and quartz fiber satin weave; the epoxy resin system includes epoxy resin and a curing agent. 7.根据权利要求6所述的机载天线罩用复合材料,其特征在于,所述内蒙皮层中,所述纤维布的体积百分含量为35%~55%,所述环氧树脂体系的体积百分含量为65%~45%;所述环氧树脂体系中,所述固化剂的添加量为环氧树脂质量的30%。7. The composite material for airborne radome according to claim 6, characterized in that, in the inner skin layer, the volume percentage of the fiber cloth is 35% to 55%, and the epoxy resin system The volume percentage is 65%-45%; in the epoxy resin system, the addition amount of the curing agent is 30% of the mass of the epoxy resin. 8.一种权利要求1至7中任一项所述机载天线罩用复合材料的制备方法,其特征在于,包括以下步骤:8. A method for preparing a composite material for an airborne radome according to any one of claims 1 to 7, characterized in that, comprising the following steps: S1、将环氧树脂和固化剂混合后制成环氧树脂体系,以所述环氧树脂体系为粘结剂,采用手糊工艺将多层纤维布逐层浸渍得到内蒙皮层预浸料;S1. Mix the epoxy resin and the curing agent to prepare an epoxy resin system, use the epoxy resin system as a binder, and use a hand lay-up process to impregnate the multi-layer fiber cloth layer by layer to obtain an inner skin layer prepreg; S2、将夹芯层材料铺覆步骤S1制备得到的所述内蒙皮层预浸料上,按压;S2. Lay the sandwich layer material on the inner skin layer prepreg prepared in step S1, and press; S3、采用真空袋压方法,将所述内蒙皮层预浸料在50~70℃下固化4~6h得到夹芯层-内蒙皮层预制体;S3. Using a vacuum bagging method, curing the inner skin layer prepreg at 50-70° C. for 4-6 hours to obtain a sandwich layer-inner skin layer prefabricated body; S4、将环氧树脂和固化剂混合后制成环氧树脂体系,以所述环氧树脂体系为粘结剂,在所述夹芯层-内蒙皮层预制体的夹芯层表面采用手糊工艺将多层纤维布逐层浸渍得到外蒙皮层预浸料;S4. Mix the epoxy resin and curing agent to make an epoxy resin system, use the epoxy resin system as a binder, and use a hand lay-up process on the surface of the sandwich layer of the sandwich layer-inner skin layer prefabricated body The outer skin layer prepreg is obtained by impregnating the multi-layer fiber cloth layer by layer; S5、采用真空袋压方法,将所述外蒙皮层预浸料在50~70℃固化4~6h得到外蒙皮层-夹芯层-内蒙皮层预制体;S5. Using a vacuum bagging method, curing the outer skin layer prepreg at 50-70°C for 4-6 hours to obtain an outer skin layer-sandwich layer-inner skin layer prefabricated body; S6、在所述外蒙皮层-夹芯层-内蒙皮层预制体的外蒙皮层表面喷涂表面涂层,然后固化,得到机载天线罩用复合材料。S6. Spraying a surface coating on the surface of the outer skin layer of the outer skin layer-sandwich layer-inner skin layer prefabricated body, and then curing to obtain a composite material for an airborne radome. 9.根据权利要求8所述的制备方法,其特征在于,所述步骤S6具体包括以下步骤:9. The preparation method according to claim 8, wherein said step S6 specifically comprises the following steps: S6-1、在所述外蒙皮层-夹芯层-内蒙皮层预制体的外蒙皮层外表面喷涂底漆胶液,喷涂完成后,室温下晾干24h,形成底漆层;S6-1. Spray primer glue on the outer surface of the outer skin layer of the outer skin layer-sandwich layer-inner skin layer prefabricated body. After the spraying is completed, dry it at room temperature for 24 hours to form a primer layer; S6-2、在所述底漆层外表面喷涂抗雨蚀漆胶液,喷涂完成后,室温下晾干2h,形成抗雨蚀漆层;S6-2. Spray the rain-erosion-resistant paint glue solution on the outer surface of the primer layer, and after the spraying is completed, dry it at room temperature for 2 hours to form a rain-erosion-resistant paint layer; S6-3、在所述抗雨蚀漆层外表面均匀喷涂防静电漆胶液,喷涂完成后,室温下晾干12h,形成防静电漆层;S6-3. Evenly spray anti-static paint glue on the outer surface of the rain-resistant paint layer. After spraying, dry it at room temperature for 12 hours to form an anti-static paint layer; S6-4、在60~80℃下固化8~10h。S6-4. Curing at 60-80°C for 8-10 hours.
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